[go: up one dir, main page]

Kumalaputri et al., 2018 - Google Patents

Lewis acid catalyzed conversion of 5-hydroxymethylfurfural to 1, 2, 4-benzenetriol, an overlooked biobased compound

Kumalaputri et al., 2018

View HTML
Document ID
628980143766955212
Author
Kumalaputri A
Randolph C
Otten E
Heeres H
Deuss P
Publication year
Publication venue
ACS sustainable chemistry & engineering

External Links

Snippet

5-Hydroxymethylfurfural (HMF) is a platform chemical that can be produced from renewable carbohydrate sources. HMF can be converted to 1, 2, 4-benzenetriol (BTO) which after catalytic hydrodeoxygenation provides a route to cyclohexanone and cyclohexanol. This …
Continue reading at pubs.acs.org (HTML) (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/58—One oxygen atom, e.g. butenolide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems

Similar Documents

Publication Publication Date Title
Kumalaputri et al. Lewis acid catalyzed conversion of 5-hydroxymethylfurfural to 1, 2, 4-benzenetriol, an overlooked biobased compound
Pagan-Torres et al. Production of 5-hydroxymethylfurfural from glucose using a combination of Lewis and Brønsted acid catalysts in water in a biphasic reactor with an alkylphenol solvent
Gao et al. Transformation of chitin and waste shrimp shells into acetic acid and pyrrole
Ma et al. Autocatalytic production of 5-hydroxymethylfurfural from fructose-based carbohydrates in a biphasic system and its purification
Hu et al. Acid-catalyzed conversion of xylose in 20 solvents: insight into interactions of the solvents with xylose, furfural, and the acid catalyst
Tan-Soetedjo et al. Experimental and kinetic modeling studies on the conversion of sucrose to levulinic acid and 5-hydroxymethylfurfural using sulfuric acid in water
Yamaguchi et al. Catalytic conversion of biomass-derived carbohydrates to methyl lactate by acid–base bifunctional γ-Al2O3
Caes et al. Biomass to furanics: renewable routes to chemicals and fuels
Liu et al. Selective base-catalyzed isomerization of glucose to fructose
Wang et al. Highly efficient conversion of xylose residues to levulinic acid over FeCl3 catalyst in green salt solutions
Zuo et al. Optimization of Co/Mn/Br-catalyzed oxidation of 5-hydroxymethylfurfural to enhance 2, 5-furandicarboxylic acid yield and minimize substrate burning
Naim et al. Toward an Intensified Process of Biomass-Derived Monomers: the Influence of 5-(Hydroxymethyl) furfural byproducts on the gold-catalyzed synthesis of 2, 5-furandicarboxylic acid
Luo et al. A simple two-step method for the selective conversion of hemicellulose in pubescens to furfural
Zhang et al. Direct conversion of cellulose to glycolic acid with a phosphomolybdic acid catalyst in a water medium
Yan et al. One-pot synthesis of 2, 5-furandicarboxylic acid from fructose in ionic liquids
Carrasquillo-Flores et al. Mechanocatalytic depolymerization of dry (ligno) cellulose as an entry process for high-yield production of furfurals
Peleteiro et al. Simple and efficient furfural production from xylose in media containing 1-butyl-3-methylimidazolium hydrogen sulfate
Yang et al. Synergy of Lewis and Brønsted acids on catalytic hydrothermal decomposition of hexose to levulinic acid
Lin et al. Conversion of C5 carbohydrates into furfural catalyzed by SO3H-functionalized ionic liquid in renewable γ-valerolactone
Pyo et al. Batch and continuous flow production of 5-hydroxymethylfurfural from a high concentration of fructose using an acidic ion exchange catalyst
Kunnikuruvan et al. Mechanistic insights into the Brønsted acid-catalyzed dehydration of β-D-glucose to 5-hydroxymethylfurfural under ambient and subcritical conditions
Velasco Calderón et al. Mechanistic investigation into the formation of humins in acid-catalyzed biomass reactions
Tang et al. Dehydration of carbohydrates to 5-hydroxymethylfurfural over lignosulfonate-based acidic resin
Zhu et al. A comprehensive study on metal triflate-promoted hydrogenolysis of lactones to carboxylic acids: from synthetic and mechanistic perspectives
Schade et al. Direct catalytic route to biomass-derived 2, 5-furandicarboxylic acid and its use as monomer in a multicomponent polymerization