[go: up one dir, main page]

Christensen et al., 1980 - Google Patents

Reductive potentiometric stripping analysis for elements forming sparingly soluble mercury compounds with amalgamated metal as the reducing agent

Christensen et al., 1980

Document ID
9159927242029326412
Author
Christensen J
Kryger L
Mortensen J
Rasmussen J
Publication year
Publication venue
Analytica Chimica Acta

External Links

Snippet

The suitability of amalgamated metals as reducing agents in reductive potentiometric stripping analysis is demonstrated. The amalgams are generated in a mercury pool by electrolysis of dissolved metals. During the stripping process, the reducing agent, which is …
Continue reading at www.sciencedirect.com (other versions)

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416—Systems
    • G01N27/42—Measuring disposition or liberation of materials from an electrolyte; Coulometry, i.e. measuring coulomb-equivalent of material in an electrolyte
    • G01N27/423—Coulometry
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416—Systems
    • G01N27/4166—Systems measuring a particular property of an electrolyte
    • G01N27/4167—Systems measuring a particular property of an electrolyte pH
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416—Systems
    • G01N27/48—Polarography, i.e. measuring changes in current under a slowly-varying voltage
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28—Electrolytic cell components
    • G01N27/30—Electrodes, e.g. test electrodes; Half-cells
    • G01N27/301—Reference electrodes
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416—Systems
    • G01N27/4163—Systems checking the operation of, or calibrating, the measuring apparatus
    • G01N27/4165—Systems checking the operation of, or calibrating, the measuring apparatus for pH meters
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/404—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors
    • G01N27/4045—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors for gases other than oxygen
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/16—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
    • G01N31/162—Determining the equivalent point by means of a discontinuity
    • G01N31/164—Determining the equivalent point by means of a discontinuity by electrical or electrochemical means
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/16—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
    • G01N31/168—Determining water content by using Karl Fischer reagent
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by the preceding groups
    • G01N33/18—Water
    • G01N33/1813—Water specific cations in water, e.g. heavy metals
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403—Cells and electrode assemblies
    • G01N27/413—Concentration cells using liquid electrolytes measuring currents or voltages in voltaic cells

Similar Documents

Publication Publication Date Title
Brainina et al. Determination of heavy metals in wines by anodic stripping voltammetry with thick-film modified electrode
Wang et al. Carbon paste electrodes modified with cation-exchange resin in differential pulse voltammetry
Wang et al. Preconcentration and voltammetric measurement of mercury with a crown-ether modified carbon-paste electrode
Christensen et al. Reductive potentiometric stripping analysis for elements forming sparingly soluble mercury compounds with amalgamated metal as the reducing agent
Dillard Evaluation of micromolar compleximetric titrations for the determination of the complexing capacity of natural waters
Phillips et al. Application of Stripping Analysis to the Trace Determination of Tin.
Jurica et al. Calibrationless flow-through stripping coulometric determination of arsenic (III) and total arsenic in contaminated water samples after microwave assisted reduction of arsenic (V)
Pecsok et al. Polarographic Characteristics of Vanadium Complexed with Ethylenediamine Tetraacetic Acid
Zirino et al. Stripping polarography and the reduction of copper (II) in sea water at the hanging mercury drop electrode
Ball et al. Determination of Chloride by Cathodic Stripping Polarography. Application to Solutions of Uranyl Sulfate
Bilewicz et al. The determination of traces of thiocyanate and copper (II) ions by cathodic stripping voltammetry
Jagner et al. Computerized electroanalysis: Multiple scanning anodic stripping and its application to sea water
Udisti et al. Determination of gallium traces by differential pulse anodic stripping voltammetry
Dong et al. Preconcentration and determination of Bismuth (III) at a chemically modified electrode containing 1-(2-pyridylazo)-2-naphthol
Siska et al. Potentiometric determination of tetraphenylborate ions with silver nitrate. Determination of silver, potassium and thallium (I)
Khoo et al. Meta1 displacement at the zinc‐diethyldithiocarbamate‐modified carbon paste electrode for the selective preconcentration and stripping analysis of mercury (II)
Nikelly et al. Amperometric Titrations of Micromolar Solutions
Palrecha et al. Adsorptive stripping voltammetric determination of chromium in gallium
Ciszewski Determination of thallium in bismuth by differential pulse anodic-stripping voltammetry without preliminary separation
Bond et al. Polarographic studies in aqueous hydrofluoric acid using ac and dc rapid techniques
Beinrohr et al. Determination of manganese in water samples by galvanostatic stripping chronopotentiometry in a flow-through cell
Bond et al. Polarographic determination of total iron, iron (II) and iron (III) in zinc plant electrolyte
Zieglerová et al. A contribution to the use of chelating agents in anodic stripping voltammetry
Borodzinski et al. Electrode reaction of the Mn (II)/Mn (Hg) system in concentrated aqueous solutions of Ca (ClO4) 2 at higher temperatures
Bessette et al. High sensitivity coulometric analysis in acetonitrile