Kotha et al., 2024 - Google Patents
Application of molybdenum hexacarbonyl in organic synthesisKotha et al., 2024
- Document ID
- 10146916642993199740
- Author
- Kotha S
- Gaikwad V
- Chaurasia U
- Publication year
- Publication venue
- Tetrahedron
External Links
Snippet
Here, we describe the role of Mo (CO) 6 in various organic transformations such as Pauson- Khand reaction, carbonyl insertion, epoxidation, oxidation, hydrogenation, reduction,[2+ 2+ 2] cycloaddition, and cyclization sequences. An overview of the reagent's utility and potential …
- 238000003786 synthesis reaction 0 title description 75
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/307—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of halogen; by substitution of halogen atoms by other halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. -COOH
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by C07D451/00 - C07D477/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07J—STEROIDS
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Exon et al. | Stereoselectivity of intramolecular dicobalt octacarbonyl alkene-alkyne cyclizations: short synthesis of dl-coriolin | |
| Ito et al. | An efficient and versatile generation of o-xylylenes by fluoride anion induced 1, 4 elimination of o-(. alpha.-trimethylsilylalkyl) benzyltrimethylammonium halides | |
| Lehr et al. | An efficient route to the musk odorant (R, Z)-5-muscenone via base-metal-catalysis | |
| Li et al. | Catalytic α-hydroxylation of ketones under CuBr2 or HBr/DMSO systems | |
| Burtoloso et al. | Metal carbene N–H insertion of chiral α, α′-dialkyl α-diazoketones. A novel and concise method for the stereocontrolled synthesis of fully substituted azetidines | |
| Kotha et al. | Application of molybdenum hexacarbonyl in organic synthesis | |
| Gastinger et al. | Synthesis and molecular structure of 1-(. pi.-cyclopentadienyl)-1-triphenylphosphine-2, 3, 4, 5-tetrakis (pentafluorophenyl) cobaltole | |
| US6667410B2 (en) | Conversion of α,β-unsaturated ketones and α,β-unsaturated esters into α-hydroxy ketones and α-hydroxy esters using Mn(III) catalyst, phenylsilane and dioxygen | |
| Jamieson et al. | Scope and limitations of ether-directed, metal-catalysed aza-Claisen rearrangements; improved stereoselectivity using non-coordinating solvents | |
| Clarke et al. | Synthetic studies on the DEF-rings of FR182877 and hexacyclinic acid | |
| Barluenga et al. | Copper-catalyzed dimerization of chromium Fischer carbene complexes: synthesis of dialkoxytrienes and their Nazarov-type cyclization to 2-alkoxy-2-cyclopentenones | |
| Takimoto et al. | Nickel-mediated carboxylative cyclization of enynes | |
| Paquette et al. | Thermochemical behavior of conjugated cis-bicyclo [5.1. 0] octenones, cis-and trans-bicyclo [5.2. 0] non-2-en-4-ones, and their methylene analogs | |
| Brummond et al. | The allenic Alder-ene reaction: constitutional group selectivity and its application to the synthesis of ovalicin | |
| Masuyama et al. | Regioselective radical cyclization initiated by the reaction of allylic hydroperoxides with iron (II) sulfate | |
| Ramachandran et al. | 1, 4-diazabicyclo [2.2. 2] octane-catalyzed self-and cross-condensation of α-acetylenic ketones | |
| Arai et al. | Powerful dienophiles for asymmetric Diels-Alder reactions:. alpha.-(2-exo-hydroxy-10-bornylsulfinyl) maleimides | |
| Stewart et al. | Synthesis of 1, 3-divinylcyclopentane derivatives from platina (IV) cyclobutane complexes | |
| Rigby | Transition metal-promotedhigher order cycloaddition reactions | |
| Estevan et al. | Rhodium (II) compounds with functionalized metalated phosphines as bridging ligands | |
| Madu et al. | Steric buttressing in the Pauson-Khand reactions of benzyl enynes | |
| US5859268A (en) | Process for the synthesis of α, β-unsaturated esters | |
| Slak | The Development of Chiral Titanocenes as Photoredox Catalysts | |
| Ma et al. | Template effects on the asymmetric cycloaddition reaction between 3, 4-dimethyl-1-phenylarsole and diphenylvinylphosphine and their arsenic elimination reaction | |
| JP3672969B2 (en) | Method for the synthesis of haloalkylferrocenes |