[go: up one dir, main page]

Wappel et al., 2016 - Google Patents

Simple activation by acid of latent Ru-NHC-based metathesis initiators bearing 8-quinolinolate co-ligands

Wappel et al., 2016

View HTML
Document ID
13340597976988277245
Author
Wappel J
Fischer R
Cavallo L
Slugovc C
Poater A
Publication year
Publication venue
Beilstein Journal of Organic Chemistry

External Links

Snippet

A straightforward synthesis utilizing the ring-opening metathesis polymerization (ROMP) reaction is described for acid-triggered N, O-chelating ruthenium-based pre-catalysts bearing one or two 8-quinolinolate ligands. The innovative pre-catalysts were tested …
Continue reading at www.beilstein-journals.org (HTML) (other versions)

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS

Similar Documents

Publication Publication Date Title
US8604141B2 (en) High metathesis activity ruthenium and osmium metal carbene complexes
US6284852B1 (en) Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water
Urbina‐Blanco et al. Olefin metathesis featuring ruthenium indenylidene complexes with a sterically demanding NHC ligand
Paradiso et al. Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands
Bantu et al. Copper (I) 1, 3-R2-3, 4, 5, 6-tetrahydropyrimidin-2-ylidenes (R= mesityl, 2-propyl): synthesis, X-ray structures, immobilization and catalytic activity
Broggi et al. The influence of phosphane ligands on the versatility of ruthenium–indenylidene complexes in metathesis
Wappel et al. Simple activation by acid of latent Ru-NHC-based metathesis initiators bearing 8-quinolinolate co-ligands
Yang et al. O-Aryloxide-N-heterocyclic carbenes: Efficient synthesis of the proligands and their p-cymene ruthenium complexes
Vieille-Petit et al. Ruthenium olefin metathesis catalysts with N-heterocyclic carbene ligands bearing n-naphthyl side chains
Ferraz et al. Ionic Grubbs–Hoveyda Complexes for Biphasic Ring‐Opening Metathesis Polymerization in Ionic Liquids: Access to Low Metal Content Polymers
Dunbar et al. Improved Molecular Weight Control in Ring‐Opening Metathesis Polymerization (ROMP) Reactions with Ru‐Based Olefin Metathesis Catalysts Using N Donors and Acid: A Kinetic and Mechanistic Investigation
Opstal et al. Easily accessible ring opening metathesis and atom transfer radical polymerization catalysts based on arene, norbornadiene and cyclooctadiene ruthenium complexes bearing Schiff base ligands
US8981024B2 (en) Olefin metathesis
Leitgeb et al. On the isomerization of a trans-dichloro to a cis-dichloro amide-chelated ruthenium benzylidene complex and the catalytic scope of these species in olefin metathesis
JP2009215471A (en) Alternating copolymerization of epoxide and carbon dioxide using metal complex
US20090124772A1 (en) Process for producing organic transition metal complex compound, metathesis catalyst produced by using the same, ring-opening metathesis polymer obtainable with the metathesis catalyst, and process for producing the polymer
Öztürk et al. In situ modification of the Grubbs first generation catalyst: A highly controllable metathesis catalyst bearing tridentate Schiff base ligands
Żukowska et al. Consequences of the electronic tuning of latent ruthenium-based olefin metathesis catalysts on their reactivity
Opstal et al. Controlled radical polymerization mediated by cationic arene ruthenium complexes
Mariconda et al. Stereoselective Ring‐Opening Metathesis Polymerization of 7‐tert‐Butoxy‐bicyclo [2, 2, 1] hepta‐2, 5‐diene by NHC–Ruthenium Catalysts
Tkach et al. The Pd2 (CHCC6H5) 2 (C5H7O2) 3 (BF3) 2BF4 catalyst for the polymerization of norbornene
Krause Development of new Ruthenium Catalysts for homogeneous and heterogeneous Olefin-Metathesis
Buchmeiser Novel Cyclopolymerization Derived Conjugated Polyenes: Smart Materials For Electronics and Sensors
Balof Ruthenium-based olefin metathesis catalysts bearing pH-responsive ligands: External control of catalyst solubility and activity
Yu et al. Latent ruthenium initiators containing fluoro aryloxide ligands