MX2021007515A - Compuestos de heterociclil piridazina como fungicidas. - Google Patents
Compuestos de heterociclil piridazina como fungicidas.Info
- Publication number
- MX2021007515A MX2021007515A MX2021007515A MX2021007515A MX2021007515A MX 2021007515 A MX2021007515 A MX 2021007515A MX 2021007515 A MX2021007515 A MX 2021007515A MX 2021007515 A MX2021007515 A MX 2021007515A MX 2021007515 A MX2021007515 A MX 2021007515A
- Authority
- MX
- Mexico
- Prior art keywords
- heterocyclyl
- pyridazine
- fungicidal compounds
- compounds
- intermediates
- Prior art date
Links
- -1 Heterocyclyl pyridazine Chemical compound 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 title 1
- 230000000855 fungicidal effect Effects 0.000 title 1
- 230000003032 phytopathogenic effect Effects 0.000 abstract 2
- 241000233866 Fungi Species 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 244000005700 microbiome Species 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
- C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
- C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D237/24—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
- C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
- C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D237/12—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
- C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
- C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D237/14—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mycology (AREA)
- Microbiology (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente divulgación se refiere compuestos de heterociclil piridazina, procesos e intermedios para su preparación, así como los usos de los mismos para controlar microorganismos fitopatogénicos, tales como hongos fitopatogénicos.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18214866 | 2018-12-20 | ||
| PCT/EP2019/086373 WO2020127780A1 (en) | 2018-12-20 | 2019-12-19 | Heterocyclyl pyridazine as fungicidal compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2021007515A true MX2021007515A (es) | 2021-08-05 |
Family
ID=64755283
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2021007515A MX2021007515A (es) | 2018-12-20 | 2019-12-19 | Compuestos de heterociclil piridazina como fungicidas. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20230064576A1 (es) |
| EP (1) | EP3898620A1 (es) |
| JP (1) | JP7560460B2 (es) |
| KR (2) | KR102755270B1 (es) |
| CN (2) | CN119080765A (es) |
| AR (1) | AR117461A1 (es) |
| BR (1) | BR112021010152A2 (es) |
| CA (1) | CA3124013A1 (es) |
| CL (1) | CL2021001661A1 (es) |
| CO (1) | CO2021007995A2 (es) |
| EA (1) | EA202191668A1 (es) |
| EC (1) | ECSP21044312A (es) |
| MX (1) | MX2021007515A (es) |
| TW (1) | TWI840477B (es) |
| UY (1) | UY38524A (es) |
| WO (1) | WO2020127780A1 (es) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR117169A1 (es) * | 2018-11-28 | 2021-07-14 | Bayer Ag | (tio)amidas de piridazina como compuestos fungicidas |
| US20230064576A1 (en) * | 2018-12-20 | 2023-03-02 | Bayer Aktiengesellschaft | Heterocyclyl pyridazine as fungicidal compounds |
| WO2021239766A1 (en) * | 2020-05-27 | 2021-12-02 | Bayer Aktiengesellschaft | Active compound combinations |
| WO2021245087A1 (en) | 2020-06-04 | 2021-12-09 | Bayer Aktiengesellschaft | Heterocyclyl pyrimidines and triazines as novel fungicides |
| US20230295138A1 (en) | 2020-06-04 | 2023-09-21 | Bayer Aktiengesellschaft | Heterocyclyl pyridines as novel fungicides |
| BR112022024413A2 (pt) * | 2020-06-10 | 2023-02-07 | Bayer Ag | Heterociclos substituídos com azabiciclila como fungicidas inovadores |
| WO2021255071A1 (en) | 2020-06-18 | 2021-12-23 | Bayer Aktiengesellschaft | 3-(pyridazin-4-yl)-5,6-dihydro-4h-1,2,4-oxadiazine derivatives as fungicides for crop protection |
| US20240016152A1 (en) * | 2020-06-18 | 2024-01-18 | Bayer Aktiengesellschaft | Active compound combinations |
| US20250064060A1 (en) | 2021-11-03 | 2025-02-27 | Bayer Aktiengesellschaft | Bis(hetero)aryl thioether (thio)amides as fungicidal compounds |
| WO2023094304A1 (en) | 2021-11-25 | 2023-06-01 | Syngenta Crop Protection Ag | Microbiocidal heterobiaryl amide derivatives |
| EP4441049A1 (en) | 2021-11-30 | 2024-10-09 | Bayer Aktiengesellschaft | Bis(hetero)aryl thioether oxadiazines as fungicidal compounds |
| WO2023166067A1 (en) | 2022-03-02 | 2023-09-07 | Syngenta Crop Protection Ag | Microbiocidal pyridazinone amide derivatives |
| US20250304566A1 (en) | 2022-05-03 | 2025-10-02 | Bayer Aktiengesellschaft | Crystalline forms of (5s)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4h-1,2,4-oxadiazine |
| WO2023213626A1 (en) | 2022-05-03 | 2023-11-09 | Bayer Aktiengesellschaft | Use of (5s)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4h-1,2,4-oxadiazine for controlling unwanted microorganisms |
| JP2025525006A (ja) | 2022-07-28 | 2025-08-01 | バイエル、アクチエンゲゼルシャフト | 2-クロロ-3-フルオロ-4-アルコキシ-アニリンおよび2-フルオロ-3-クロロフェノールの調製のためのプロセス |
| EP4608836A1 (en) | 2022-10-27 | 2025-09-03 | Syngenta Crop Protection AG | Microbiocidal heterobicyclic dihydrooxadiazine derivatives |
| CN120379969A (zh) | 2022-12-19 | 2025-07-25 | 先正达农作物保护股份公司 | 杀微生物的哒嗪二氢噁二嗪衍生物 |
| WO2024132895A1 (en) | 2022-12-19 | 2024-06-27 | Syngenta Crop Protection Ag | Microbiocidal dihydrooxadiazinyl pyridazinone compounds |
| WO2024149772A1 (en) | 2023-01-10 | 2024-07-18 | Syngenta Crop Protection Ag | Fungicidal compositions |
| WO2024200462A1 (en) | 2023-03-30 | 2024-10-03 | Bayer Aktiengesellschaft | PALLADIUM-CATALYZED CHEMOSELECTIVE MONO-α-ARYLATION OF O-PROTECTED HYDROXYACETONE |
| AR132937A1 (es) | 2023-06-14 | 2025-08-13 | Syngenta Crop Protection Ag | Composiciones fungicidas |
| WO2024256433A1 (en) | 2023-06-14 | 2024-12-19 | Syngenta Crop Protection Ag | Fungicidal compositions |
| WO2025031990A1 (en) | 2023-08-04 | 2025-02-13 | Syngenta Crop Protection Ag | Methods of controlling or preventing infestation of soybean plants by the phytopathogenic microorganism corynespora cassiicola |
| WO2025031913A1 (en) | 2023-08-04 | 2025-02-13 | Syngenta Crop Protection Ag | Methods of controlling or preventing infestation of plants by the phytopathogenic microorganism corynespora cassiicola |
| WO2025031989A1 (en) | 2023-08-04 | 2025-02-13 | Syngenta Crop Protection Ag | Methods of controlling or preventing infestation of plants by the phytopathogenic microorganism corynespora cassiicola |
| WO2025031668A1 (en) | 2023-08-09 | 2025-02-13 | Bayer Aktiengesellschaft | Azaheterobiaryl-substituted 4,5-dihydro-1h-2,4,5-oxadiazines as novel fungicides |
| WO2025032038A1 (en) | 2023-08-09 | 2025-02-13 | Bayer Aktiengesellschaft | Pyridazin-4-yloxadiazines as novel fungicides |
| WO2025036887A1 (en) | 2023-08-12 | 2025-02-20 | Syngenta Crop Protection Ag | Process for the preparation of 5,6-dihydro-4h-1,2,4-oxadiazine derivatives |
| WO2025056724A1 (en) | 2023-09-13 | 2025-03-20 | Bayer Aktiengesellschaft | Iminoamide-type compounds as ligands for copper-catalyzed coupling reactions of (hetero)aryl halides |
| WO2025056725A1 (en) | 2023-09-13 | 2025-03-20 | Bayer Aktiengesellschaft | Process for the preparation of halogenated phenols via copper-catalyzed coupling reactions of halogenated aryl-halides |
| TW202513532A (zh) | 2023-09-15 | 2025-04-01 | 瑞士商先正達農作物保護股份公司 | 用於製備鏡像異構物富集的脂肪族胺之方法 |
| WO2025078128A1 (en) | 2023-10-11 | 2025-04-17 | Bayer Aktiengesellschaft | Pyridazin-3-one-4-yloxadiazines as novel fungicides |
| WO2025093606A1 (en) | 2023-11-03 | 2025-05-08 | Bayer Aktiengesellschaft | Process for preparation of substituted n-(2-chloroethyl)-n´-hydroxy-3-phenoxypyridazine-3- carboxamidines and substituted 3-(3-phenoxypyridazin-4-yl)-5,6-dihydro-4h-1,2,4-oxadiazines |
| WO2025104152A1 (en) | 2023-11-15 | 2025-05-22 | Syngenta Crop Protection Ag | Microbiocidal tetrahydroisoquinoline derivatives |
| WO2025114167A1 (en) | 2023-11-28 | 2025-06-05 | Syngenta Crop Protection Ag | Microbiocidal pyrazole derivatives |
| WO2025120070A1 (en) | 2023-12-08 | 2025-06-12 | Syngenta Crop Protection Ag | Polymorphs of a methoxyacrylate derivative |
| WO2025168620A1 (en) | 2024-02-07 | 2025-08-14 | Bayer Aktiengesellschaft | Heteroaryl-substituted 4,5-dihydro-1h-2,4,5-oxadiazines as novel fungicides |
| WO2025172368A1 (en) | 2024-02-13 | 2025-08-21 | Syngenta Crop Protection Ag | (5-isoxazol-3-yl)-[4-(pyrazol-4-yl)-3,4-dihydro-1h-isoquinolin-2-yl]methanone derivatives for use as fungicides |
| WO2025172374A1 (en) | 2024-02-13 | 2025-08-21 | Syngenta Crop Protection Ag | Microbiocidal pyrazole derivatives |
| WO2025172099A1 (en) * | 2024-02-15 | 2025-08-21 | Basf Se | Fungicidal compositions comprising 6-methyl-pyridazin derivatives |
| WO2025191053A1 (en) | 2024-03-14 | 2025-09-18 | Syngenta Crop Protection Ag | Microbiocidal pyrazole derivatives |
| WO2025202482A1 (en) | 2024-03-28 | 2025-10-02 | Syngenta Crop Protection Ag | Fungicidal compositions |
| WO2025202499A1 (en) | 2024-03-28 | 2025-10-02 | Syngenta Crop Protection Ag | Fungicidal compositions |
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| GB0614153D0 (en) * | 2006-07-17 | 2006-08-23 | Syngenta Participations Ag | Novel pyridazine derivatives |
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2019
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- 2019-12-19 CA CA3124013A patent/CA3124013A1/en active Pending
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| JP2022514651A (ja) | 2022-02-14 |
| ECSP21044312A (es) | 2021-07-30 |
| JP7560460B2 (ja) | 2024-10-02 |
| CN113454079A (zh) | 2021-09-28 |
| TW202039468A (zh) | 2020-11-01 |
| KR20250012731A (ko) | 2025-01-24 |
| TWI840477B (en) | 2024-05-01 |
| EP3898620A1 (en) | 2021-10-27 |
| CO2021007995A2 (es) | 2021-06-30 |
| CA3124013A1 (en) | 2020-06-25 |
| US20230064576A1 (en) | 2023-03-02 |
| CN113454079B (zh) | 2024-07-26 |
| AR117461A1 (es) | 2021-08-04 |
| CN119080765A (zh) | 2024-12-06 |
| KR20210106492A (ko) | 2021-08-30 |
| WO2020127780A1 (en) | 2020-06-25 |
| EA202191668A1 (ru) | 2021-11-10 |
| UY38524A (es) | 2020-07-31 |
| KR102755270B1 (ko) | 2025-01-22 |
| CL2021001661A1 (es) | 2021-12-03 |
| BR112021010152A2 (pt) | 2021-11-09 |
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