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AR040413A1 - Heterociclilalquinos activos como herbicidas - Google Patents

Heterociclilalquinos activos como herbicidas

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Publication number
AR040413A1
AR040413A1 ARP030101900A AR040413A1 AR 040413 A1 AR040413 A1 AR 040413A1 AR P030101900 A ARP030101900 A AR P030101900A AR 040413 A1 AR040413 A1 AR 040413A1
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AR
Argentina
Prior art keywords
substituted
8alkyl
halogen
phenyl
represents hydrogen
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English (en)
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Syngenta Participations Ag
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Publication of AR040413A1 publication Critical patent/AR040413A1/es

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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/26—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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    • C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
    • C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D237/08—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D237/12—Halogen atoms or nitro radicals
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    • C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D237/10—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D237/20—Nitrogen atoms
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    • C07D—HETEROCYCLIC COMPOUNDS
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    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/30—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/42—One nitrogen atom
    • C—CHEMISTRY; METALLURGY
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    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/12—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D241/16—Halogen atoms; Nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D241/20—Nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D241/24—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D253/00—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00
    • C07D253/02—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00 not condensed with other rings
    • C07D253/06—1,2,4-Triazines
    • C07D253/065—1,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members
    • C07D253/07—1,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members with hetero atoms, or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Reivindicación 1: Un compuesto de fórmula (1) en la cual Q representa un elemento del grupo (2); Z es =N-, lN+-O-, ó =C(R1)-; n vale 0, 1, 2, 3 o 4;siendo cada R1, independientemente de los demás, halógeno, -CN, -SCN, -SFS, -NO2, -NR5R6, -CO2R7, -CONR8R9, -C(R10)=NOR11, -COR12, -OR13, -SR14, -SOR15, -SO2R16, -OSO2R17, C1-8alquilo, C2-8alquenilo, C2-8alquinilo o C3-6cicloalquilo; o representa C1-8alquilo, C2-8alquenilo, o C2-8alquinilo substituidos de una a cinco veces con halógeno o de una a tres veces con -CN, -NO2, -NR18R19, -CO2R20, -CONR21R22, -COR23, -C(R24)=NOR25, -C(S)NR26R27, -C(C1-4alquiltio)=NR28, -OR29, -SR30, -SOR31, -SO2R32 o con C3-6cicloalquilo; y/o cada R1, independientemente de los demás representa C3-6cicloalquilo substituido de una a cinco veces con halógeno, o de una a tres veces con -CN, -NO2, -NR18R19, -CO2R20, -CONR21R22, -COR23, -C(R24)=NOR25, -C(S)NR26R27, -C(C1-4alquiltio)=NR28, -SR30, -SOR31, -SO2R32 ó C3-6cicloalquilo; y/o cada R1, independientemente de los demás representa fenilo que por su parte puede estar substituido de una a cinco veces con halógeno o C1-4alquilo o de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o C1-4alquilsulfonilo; y/o dos substituyentes R1 adyacentes juntos forman un puente C1-7alquileno que puede estar interrumpido por 1 a 3 heteroátomos seleccionados entre oxígeno, nitrógeno y azufre y que puede estar substituido de una a cinco veces con halógeno o con C1-6alquilo, o de una a tres veces con C1-6alcoxi, siendo la cantidad total de átomos de anillo por lo menos de 5 y a lo sumo de 9; y/o dos substituyentes R1 adyacentes juntos forman un puente C2-7alquenileno que puede estar interrumpido por 1 a 3 heteroátomos seleccionados entre oxígeno, nitrógeno y azufre y que puede estar substituido de una a cinco veces con halógeno o C1-6alquilo o de una a tres veces con C1-6alcoxi, siendo la cantidad total de átomos de anillo por lo menos de 5 y a lo sumo de 9; R3 y R4 independientemente entre sí, representan hidrógeno, halógeno, -CN, C1-4alquilo o C1-4alcoxi; o R3 y R4 juntos forman C2-5alquileno; R5 representa hidrógeno o C1-8alquilo; R6 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o estar substituidos de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo, o R5 y R6 conjuntamente son una cadena C2-5alquileno que puede estar interrumpida por un átomo de oxígeno o de azufre; R7 representa hidrógeno, C1-8alquilo, C3-8alquenilo o C3-8alquinilo, o es C1-8alquilo, C3-8alquenilo o C3-8alquinilo substituidos de una a cinco veces con halógeno o de una a tres veces con substituido de una a tres veces con C1-4alcoxi o con fenilo, pudiendo el fenilo por su parte estar substituido de una a cinco veces con halógeno o con C1-4alquilo o de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo, o C1-4alquilsulfonilo; R8 representa hidrógeno o C1-8alquilo; R9 representa hidrógeno o C1-8alquilo, o C1-8alquilo substituido de una a tres veces con -COOH, C1-8alcoxicarbonilo o -CN; o R9 representa C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; o R8 y R9 representan conjuntamente C2-5alquileno; R10 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo;R11 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, C1-4haloalquilo o C3-6haloalquenilo; R12 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo;R13 representa hidrógeno, C1-8alquilo, C3-8alquenilo o C3-8alquinilo; o R13 representa fenilo o fenil-C1-6alquilo, pudiendo por su parte el anillo fenilo estar substituido de una a cinco veces con C1-4alquilo o de una a tres veces con C1-4halo-alquilo, C1-4alcoxi, -CN, -NO2, C1-8alquiltio, C1-8alquilsulfinilo o C1-8alquilsulfonilo; o R13 representa C1-8alquilo substituido de una a cinco veces con halógeno o substituido de una a tres veces con -CN, C1-6alquilamino, di(C1-6alquil)amino o con C1-4alcoxi; R14 representa hidrógeno, C1-8alquilo, C3-8alquenilo o C3-8alquinilo, o C1-8alquilo substituido de una a cinco veces con o de una a tres veces con -CN o C1-4alcoxi; R15, R16 y R17 independientemente entre si representan cada uno de ellos C1-8alquilo, C3-8alquenilo o C3-8alquinilo, o C1-8alquilo substituido de una a cinco veces con halógeno o substituido de una a tres veces con -CN o C1-4alcoxi; R18 representa hidrógeno o C1-8alquilo; R19 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; o R18 y R19 conjuntamente representan una cadena C2-5alquileno que puede estar interrumpida por un átomo de oxígeno o de; R20 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; R21 representa hidrógeno o C1-8alquilo; R22 representa hidrógeno o C1-8alquilo, o es C1-8alquilo substituido de una a tres veces con -COOH, C1-8alcoxicarbonilo o -CN, o R22 representa C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; o R21 y R22 conjuntamente son una cadena C2-5alquileno; R23 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo; R24 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo; R25 representa hidrógeno, C1-4alquilo,C3-8alquenilo, C3-8alquinilo, C1-4haloalquilo o C3-6haloalquenilo; R26 representa hidrógeno o C1-8alquilo; R27 representa hidrógeno o C1-8alquilo, o es C1-8alquilo substituido de una a tres veces con -COOH, C1-8-alcoxicarbonilo o -CN, o R27 representa C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; o R26 y R27 conjuntamente representan una cadena C2-5alquileno; R28 representa hidrógeno o C1-8alquilo; R29 y R30 independientemente entre sí representan hidrógeno, C1-8alquilo,C3-8alquenilo o C3-8alquinilo, o C1-8alquilo substituido de una a cinco veces con halógeno o substituido de una a tres veces con -CN o C1-4alcoxi; R31 y R32 independientemente entre sí, representan C1-8alquilo, C3-8alquenilo o C3-8alquinilo, o C1-8alquilo substituido de una a cinco veces con halógeno o substituido de una a tres veces con -CN o C1-4alcoxi; m vale 0, 1, 2 o 3; cada uno de los R2 independientemente de los demás, representa halógeno, -CN, -SCN, -OCN, -N3, -SF5, -NO2, -NR33R34, -CO2R35, -CONR36R37, -C(R38)=NOR39, -COR40, -OR41, -SR42, -SOR43, -SO2R44, -OSO2R45, -N([CO]pR46)COR47, -N(OR54)COR55, -N(R56)SO2R57, -N(SO2R58)SO2R59, -N=C(OR60)R61, -CR62(OR63)OR64, -OC(O)NR65R66, -SC(O)NR67R68, -OC(S)NR69R70 o -N-ftalimida; y/o R2 representa un sistema de anillo heterocíclico de 5 a 7miembros que puede ser aromático, o estar saturado total o parcialmente y que puede contener de 1 a 4 heteroátomos seleccionados entre nitrógeno, oxígeno y azufre, pudiendo dicho sistema de anillo heterocíclico estar substituido de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, hidroxi-C1-4alquilo, C1-4alcoxi, C1-4alcoxi-C1-4alquilo, -CN, -NO2, C1-6alquiltio, C1-6alquilsulfinilo o C1-6alquilsulfonilo; R33 representa hidrógeno o C1-8alquilo; y R34 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, CH3C(O)-, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; o R33 y R34 representan conjuntamente una cadena C2-5alquileno que puede estar interrumpida por un átomo de oxígeno o con un átomo de azufre; R35 representa hidrógeno, C1-8alquilo,C3-8alquenilo o C3-8alquinilo, o representa C1-8alquilo, C3-8alquenilo o C3-8alquinilo substituidos de una a cinco veces con halógeno o substituido de una a tres veces con C1-4alcoxi o fenilo, pudiendo fenilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; R36 representa hidrógeno o C1-8alquilo; R37 representa hidrógeno o C1-8alquilo, o C1-8alquilo substituido de una a tres veces con -COOH, C1-8alcoxicarbonilo o -CN; o R37 representa C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo a su vez estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o estar substituidos de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; o R36 y R37 conjuntamente representan C3-5alquileno; R38 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo; R39 representa hidrógeno, C1-8alquilo, C3-8a
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