AR088124A1 - Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio - Google Patents
Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladioInfo
- Publication number
- AR088124A1 AR088124A1 ARP120101033A ARP120101033A AR088124A1 AR 088124 A1 AR088124 A1 AR 088124A1 AR P120101033 A ARP120101033 A AR P120101033A AR P120101033 A ARP120101033 A AR P120101033A AR 088124 A1 AR088124 A1 AR 088124A1
- Authority
- AR
- Argentina
- Prior art keywords
- optionally substituted
- preparation
- waste
- bifosphate
- bidented
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 239000002253 acid Substances 0.000 title abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract 2
- 125000004437 phosphorous atom Chemical group 0.000 abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract 2
- 239000002699 waste material Substances 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 230000006315 carbonylation Effects 0.000 abstract 1
- 238000005810 carbonylation reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- 239000010908 plant waste Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
- C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/32—Oxygen atoms
- C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Proceso de carbonilación para la preparación de un éster de ácido alcanoico que comprende hacer reaccionar: (a) un alqueno; (b) una fuente de Pd; (c) un ligando de fosfino bidentado de la fórmula (1): R¹R²P-R³-R-R⁴-PR⁵R⁶ (1) en donde P representa un átomo de fósforo; R¹, R², R⁵ y R⁶ pueden representar independientemente los mismos grupos o diferentes grupos orgánicos opcionalmente sustituidos que contienen un átomo de carbono terciario a través del cual el grupo se liga al átomo de fósforo; R³ y R⁴ representan independientemente grupos alquileno inferiores opcionalmente sustituidos y R representa un grupo aromático opcionalmente sustituido; (d) una fuente de aniones derivados de un ácido con un pKa < 3; (e) monóxido de carbono; y (f) un alcanol; caracterizado porque el proceso se realiza en la presencia de entre 0.1 y 3% en peso de agua. El proceso tiene ventajosamente un alto índice de conversión y es adecuado para la producción de dimetil adipato, adipato y hexametileno diamina y productos derivados de los mismos tales como nylon 6,6 de fuentes renovables tales como desperdicio de planta, desperdicio de aguas residuales en lugar de utilizar fuentes fósiles.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161470673P | 2011-04-01 | 2011-04-01 | |
| EP11160912 | 2011-04-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR088124A1 true AR088124A1 (es) | 2014-05-14 |
Family
ID=44140819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP120101033A AR088124A1 (es) | 2011-04-01 | 2012-03-27 | Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20140128631A1 (es) |
| EP (1) | EP2694467A1 (es) |
| CN (1) | CN103619801A (es) |
| AR (1) | AR088124A1 (es) |
| WO (1) | WO2012131027A1 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017135897A1 (en) * | 2016-02-02 | 2017-08-10 | Agency For Science, Technology And Research | A catalyst for the carbonylation of alkenes |
| EP3272728B1 (de) | 2016-07-19 | 2019-06-19 | Evonik Degussa GmbH | Verfahren zur alkoxycarbonylierung von alkoholen |
| DE102018114441A1 (de) | 2018-06-15 | 2019-08-01 | Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock | Verfahren zur Herstellung von endständig ungesättigtem Alkencarbonsäureester aus Lactonen |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2368366A (en) | 1942-08-21 | 1945-01-30 | Monsanto Chemicals | Process for the production of lactones |
| US3065263A (en) | 1959-11-17 | 1962-11-20 | Rayonier Inc | Process for the manufacture of levulinic acid |
| DE3609139A1 (de) | 1986-03-19 | 1987-09-24 | Basf Ag | Verfahren zur herstellung von 4-pentensaeureestern |
| DE3609138A1 (de) * | 1986-03-19 | 1987-09-24 | Basf Ag | Verfahren zur herstellung von alkencarbonsaeureestern |
| US4897497A (en) | 1988-04-26 | 1990-01-30 | Biofine Incorporated | Lignocellulose degradation to furfural and levulinic acid |
| US5608105A (en) | 1995-06-07 | 1997-03-04 | Biofine Incorporated | Production of levulinic acid from carbohydrate-containing materials |
| MY127358A (en) | 2000-03-14 | 2006-11-30 | Shell Int Research | Process for the carbonylation of ethylenically unsaturated compounds |
| US6835849B2 (en) | 2002-07-15 | 2004-12-28 | E. I. Du Pont De Nemours And Company | Synthesis of alkenoate esters from lactones and alcohols |
| EP1699750B1 (en) | 2003-12-19 | 2013-11-06 | Shell Internationale Research Maatschappij B.V. | A process for the preparation of an alkyl alkenoate |
| GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
| GB0713624D0 (en) * | 2007-07-13 | 2007-08-22 | Lucite Int Uk Ltd | Improved solvent for catalyst system |
| US8148553B2 (en) * | 2009-06-23 | 2012-04-03 | Wisconsin Alumni Research Foundation | Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities |
| US20120309613A1 (en) * | 2009-12-15 | 2012-12-06 | Lucite International Uk Limited | Carbonylation process |
| EA025474B1 (ru) * | 2011-06-21 | 2016-12-30 | ДСМ АйПи АССЕТС Б.В. | Способ получения валеролактона из левулиновой кислоты |
-
2012
- 2012-03-27 AR ARP120101033A patent/AR088124A1/es unknown
- 2012-03-30 CN CN201280016863.7A patent/CN103619801A/zh active Pending
- 2012-03-30 EP EP12711178.9A patent/EP2694467A1/en not_active Withdrawn
- 2012-03-30 US US14/008,683 patent/US20140128631A1/en not_active Abandoned
- 2012-03-30 WO PCT/EP2012/055768 patent/WO2012131027A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| US20140128631A1 (en) | 2014-05-08 |
| CN103619801A (zh) | 2014-03-05 |
| WO2012131027A1 (en) | 2012-10-04 |
| EP2694467A1 (en) | 2014-02-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |