AU708949B2 - An absorbent pad - Google Patents
An absorbent pad Download PDFInfo
- Publication number
- AU708949B2 AU708949B2 AU17129/97A AU1712997A AU708949B2 AU 708949 B2 AU708949 B2 AU 708949B2 AU 17129/97 A AU17129/97 A AU 17129/97A AU 1712997 A AU1712997 A AU 1712997A AU 708949 B2 AU708949 B2 AU 708949B2
- Authority
- AU
- Australia
- Prior art keywords
- pad
- sheet
- microperforated
- top sheet
- woven fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000002250 absorbent Substances 0.000 title claims description 50
- 230000002745 absorbent Effects 0.000 title claims description 50
- 239000004745 nonwoven fabric Substances 0.000 claims description 39
- 238000001816 cooling Methods 0.000 claims description 36
- 239000012530 fluid Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 13
- 229920003023 plastic Polymers 0.000 claims description 10
- 239000004033 plastic Substances 0.000 claims description 10
- 238000003475 lamination Methods 0.000 claims description 3
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 35
- 229920000642 polymer Polymers 0.000 description 26
- 229920000247 superabsorbent polymer Polymers 0.000 description 15
- -1 polyethylene Polymers 0.000 description 13
- 239000004744 fabric Substances 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 9
- 229920000573 polyethylene Polymers 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000002650 laminated plastic Substances 0.000 description 7
- 235000013372 meat Nutrition 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 5
- 235000013622 meat product Nutrition 0.000 description 5
- 230000002787 reinforcement Effects 0.000 description 5
- 239000004583 superabsorbent polymers (SAPs) Substances 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 229920001684 low density polyethylene Polymers 0.000 description 4
- 239000004702 low-density polyethylene Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 239000002808 molecular sieve Substances 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000005001 laminate film Substances 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 244000144977 poultry Species 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- 241000287828 Gallus gallus Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 150000001399 aluminium compounds Chemical class 0.000 description 1
- 229940077746 antacid containing aluminium compound Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003000 extruded plastic Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000002651 laminated plastic film Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000011176 pooling Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 235000020989 red meat Nutrition 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Description
WO 97/30909 PCT/AU97/00086 1
TITLE
AN ABSORBENT PAD FIELD OF THE INVENTION This invention relates to an absorbent pad and particularly to an absorbent pad for use in the food industry as a biofluid absorbent, or for a cooling pad.
BACKGROUND ART Absorbent pads are well-known and widely used in the food industry. One type of absorbent pad is used as a biofluid absorber and is placed between fresh meat and the plastic meat tray. The pad functions to absorb biofluids exuding from the meat.
A second type of known pad is used as a cooling pad and is initially swelled with water, frozen and then placed with food or other produce which is to be kept cool.
Both types of pads have internal absorbents and typically use superabsorbent polymers (SAP). These polymers are also well-known and a typical polymer is a cross-linked sodium polyacrylate. In order to allow the internal absorbent to absorb fluid efficiently, the polymer is usually finely ground.
The internal superabsorbent polymer creates some difficulties which must be overcome if the pad is to be safe and commercially successful. Firstly, it is necessary to ensure that the polymer stays within the pad at all times, even when swollen into a gel-like state.
Another problem with the superabsorbent polymers is that they are aggressive fluid absorbers and tend to desiccate the meat product by absorbing more than just the exuded biofluids.
To overcome the aggressive absorbing nature of the polymer, it is known to have absorbent pads formed with a bottom wall which is water permeable (and is typically a non-woven fabric), and a top wall formed from a totally liquid impermeable sheet.
A disadvantage with having a liquid impermeable top sheet is that biofluids run over the top sheet and fall away from the pad without the pad being able to absorb the biofluid through the bottom layer. This is particularly so if the meat product tray is stored or presented at an angle. Another disadvantage with thle impervious top layer is that if the meat tray is level, biofluids can pool on the top layer and ruin the meat by promotion of bacterial growth.
Attempts have been made to provide a large slit or a number of slits in the top wall of the pad to overcome the above disadvantage. However the biofluids are still not efficiently absorbed and have a tendency to run off the top sheet, or to pool.
Another problem with cooling pads is that when the pads are swollen with water, the superabsorbent polymer turns into a gel and exerts considerable pressure on the wall of the pad and can extrude through the pad wall. This is particularly so if the top wall of the pad is formed with a large slit or slits.
Summary of the Invention The present invention is an absorbent pad which has a top sheet and a bottom sheet, the sheets being joined to form at least one cell, an absorbent located within the cell, characterised in that at least one of the sheets is formed as a lamination of two microperforated sheets each formed from a liquid impermeable sheet containing microperforations, and an intermediate "permeable layer sandwiched between the microperforated sheets, the to microperforations allowing fluid to pass therethrough and into the cell.
.4 The present invention has been developed to provide an absorbent pad which can be used both as a biofluid absorber and also as a cooling pad and which can at least reduce the abovementioned disadvantages or provide the public with a useful or commercial choice.
In one embodiment, the absorbent pad has a top sheet and a bottom sheet, the sheets being joined to form at least one cell, an absorbent located within the cell, characterised in that at least one of the sheets is formed from a liquid impermeable material containing microperforations to allow fluid to pass through the microperforations and into the cell.
It is preferred that the top sheet is formed from the microperforated material. The bottom sheet may be formed from similar material, or different material such as a water permeable non-woven sheet, a paper sheet, or a totally water impermeable sheet.
We find that the microperforations temper the .9* 9 9* *e a. 9 9 a WO 97/30909 PCT/AU97/00086 3 aggressiveness of the superabsorbent polymer within the cell or cells. That is, the microperforations minimise the drawing effect which results in undesired desiccation of the meat product. The drawing effect appears to be minimised to an acceptable level by having a large number of extremely small perforations in the sheet of the absorbent pad which can then be placed under the meat product.
The microperforations also appear to reduce or prevent pooling of biofluids on top of the absorbent pad and if the microperforations are spread over the top sheet of the absorbent pad, biofluid absorption can occur over a larger surface area than might be the case if the pad was only slotted or slitted.
The microperforations are typically spread over the sheet in a substantially homogenous fashion. It is however envisaged that parts of the sheet may not include microperforations and these parts may include the joins between adjacent cells.
The microperforations may have various shapes and sizes and may be circular, elliptical (cigar-shaped), polygonal (including rectangular, triangular and diamondshaped), irregular and the like. Depending on the process used to perforate the sheet, the formed perforations may have a flap or hinge portion adjacent the formed hole which still allows liquids to pass through the perforations.
The microperforations can be formed by hot pin perforating, cold pin perforating, open flame perforating, laser perforating, and by other suitable techniques. The different perforating processes may form different hole sizes and shapes.
A typical size of the microperforation can be between 10 to 200 microns. For instance, if the perforation is elliptical, it may have a size of approximately 20 microns X 90 microns, but this can vary between 10 microns and 200 microns, possibly even more, the larger size being determined by the aggressiveness of WO 97/30909 PCT/AU97/00086 4 the absorbing polymer or other type of absorbent.
The number of microperforations in the sheet may also vary as can be regularity or irregularity of the microperforations. There may be provided between 10 to 500 microperforations per square inch and we find a microperforation number of 330 per square inch to be suitable for our purposes. We find that the number of holes per square inch appears to affects only the absorption rate of the product.
The size of the absorbent pad itself can also vary depending on its use. We find that a typical pad may be about 400mm across and have an unlimited length with the consumer able to simply cut the pad lengthwise to suit. Each pad may have one or more cells, and we find that for a pad having a width of 400mm, there may be provided 6 or so cells. Each cell can be of any shape or size and we find a suitable size to be between 40mm to 100mm across.
The sheet containing the microperforations (which is typically the top sheet), can be formed from a plastic film. The plastic film can be a single film, a laminate film or other types of film. One type of useful film is a laminate formed from a polyester and a polyethylene. We find a suitable thickness to be a 12 micron polyester film laminated to a 30 micron polyethylene film. Other film thickness can be used if desired. We find that other types of plastics can be used such as nylon, other types of polyene film such as all types of polyethylenes and polypropylenes. We also find use for polyurethane and polyvinyl films. We find that the main property desired from the film is that it is able to be strong enough to resist wear and tear during use. We also find it desirable to choose a film which can accept printing inks such that the sheets of the pad, or at least one sheet of the pad, can be printed. We find it desirable from a consumer point of view that the films have a good opacity. If we form the pad by heat sealing the top sheet and the bottom sheet WO97/30909 PCT/AU97/00086 together, we prefer the films to be heat sealable.
If the absorbent pad contains a microperforated top sheet and a different type of bottom sheet, one type of preferred bottom sheet is a non-woven fabric. Many types of non-woven fabrics are known in the art, and a suitable fabric is a 40g per square metre bi-component continuous filament which is pressure and temperature bonded. The filament can be made of a polyester core with a polyethylene sheath and this type of material is known. The filament may comprise a different type of sheath plastic such as polypropylene or a polypropylene polyethylene co-polymer. These filaments are desirable because a strong heat seal can be formed in the non-woven fabric. These non-woven fabrics have a good random distribution of the fibres to ensure that the pore size or holes in the fabric are small enough to prevent polymer from being shaken out of the pad, and also to prevent the swollen hydrated polymer from squeezing through the fabric.
It should be appreciated that there are many types of non-woven fabrics available in the marketplace which could fulfil our requirements.
If the top sheet is microperforated, we may desire to have the bottom sheet totally liquid impermeable and this type of sheet may be formed from any type of suitable water impermeable plastic film, or other type of film which may be available from time to time.
In order to reduce the possibility of absorbent egress from the cells in the pad, a further barrier sheet can be provided below the microperforated sheet. The barrier sheet is preferably of the type that will allow fluid to pass or wick through the sheet but will act as a barrier for the absorbent. Various types of papers can be used as the barrier sheet.
In a further variation, the top sheet may comprise a preformed multi-layer sheet composite. For instance, the top sheet can comprise an outermost microperforated sheet, an intermediate barrier sheet and WO 97/30909 PCT/AU97/00086 6 an innermost microperforated sheet to form a triple layer sheet composite. This multi-layer sheet can form the top sheet and/or the bottom sheet of the absorbent pad.
In order to strengthen the microperforated sheet, a further reinforcement sheet may be provided.
Occasionally, it is found that the pressure inside the absorbent pad is such that it can place an undesirable amount of strain on the microperforated sheet. This sheet, is weakened by having the microperforations in it, and there is a possibility that the microperforated sheet can tear or split. For instance, when the pad is used as an ice replacement pad, it is swollen with water and then frozen. The swelling and freezing creates considerable pressure within the pad. It is common to provide a flexible sheet having a number of absorbent cells within it. The flexible sheet can be swollen with water, frozen and then wrapped around the product which is to be kept cool. It is found that when the product is frozen, the microperforated sheet can approach its cold flex temperature which means that the film resists flexing and is susceptible to formation of cracks and tears.
For this reason, the absorbent pad can include the reinforcement sheet. The reinforcement sheet may be positioned behind the microperforated sheet. It is preferred that the reinforcement sheet does not appreciably prevent fluid from passing into the absorbent. Therefore, a preferred reinforcement sheet is a non-woven fabric, or a microperforated film.
The absorbent in the cell of the pad may comprise a single type of absorbent or mixture. Although may types of absorbents are known and used in absorbent pads, we find it desirable to use a superabsorbent polymer, as such polymers can absorb many times their weight in liquid, and although these polymers are aggressive absorbers, we have overcome or tempered this undesirable feature by using the microperforations.
A desired type of superabsorbent polymer include the family of sodium polyacrylates which are WO 97/30909 PCT/AU97/00086 7 sodium salts of cross-linked polyacrylic acid/polyalcohol grafted co-polymers. These polymers are known and are also known for their use in absorbent pads. Other types of absorbents which we find useful are the sodium carboxy methyl celluloses and these can be cross-linked with a number of different types of aluminium compounds to improve their gel strength qualities. Of course, other types of absorbents can be used with our microperforated pad.
We find that the commercial superabsorbent polymers come in two distinct shapes. The most common types of shape is an irregular granular or gravel shape, while the other shape is a more rounded spherical configuration.
We also find that the commercial superabsorbent polymers have varying particle sizes and typical particle sizes are as follows 850 micron and above: 0 2% 850 600 microns: 24 32% 600 500 microns: 20 28% 500 300 microns: 32 300 180 microns: 4 12% 180 90 microns: 0 4% 45 microns: 0 2% 45 microns and below: 0 0.1% Different batches of polymer can have different size ranges and size extremes such as up to or even above 2000 microns, and it will be appreciated that we can adjust our microperforation shape and size to compliment that of the absorbent we use in the cells to minimise or at least reduce undesirable loss of absorbent through the cell wall.
The amount of absorbent we use can of course vary depending upon the absorbent capacity and rate and depending upon how much liquid we wish to absorb.
A
typical superabsorbent polymer will absorb anywhere between 100g to 500g of tap water per gram of polymer.
We prefer that the polymer dosage in the cell WO 97/30909 PCT/AU97/00086 8 is such that the polymer is able to fully hydrate and is not prevented from full hydration. For this reason, we prefer that not too much polymer is added in each cell.
We find that when our pad is used as a cooling pad, consumers do not wish to believe that the cooling pad will absorb any other liquids from the surrounding area, and instead will only function as a cooling pad. For this reason, we like to ensure that the polymer can be fully hydrated before freezing if it is used as a cooling pad.
The pad itself can be formed in a number of different ways. One preferred way, and a way which has been used in other known pads, is to heat seal the top sheet and bottom sheet together. For this reason, we prefer that the top sheet and bottom sheet are formed from heat meltable materials, and these materials are known. Of course, we may also wish to simply glue the sheets together, or attach them by other means.
BRIEF DESCRIPTION OF THE FIGURES Embodiments of the pad will be described with reference to the following drawings in which Figures 1A and lB illustrate a fluid absorbing pad having a top sheet and a bottom sheet both being microperforated.
Figures 2A and 2B illustrate a fluid absorbing pad having a top microperforated sheet and a bottom nonwoven fabric sheet.
Figures 3A and 3B illustrate a fluid absorbing pad having a top microperforated sheet and a bottom paper sheet.
Figures 4A and 4B illustrate a cooling pad having a top sheet and a bottom sheet both being microperforated.
Figures 5A and 5B illustrate a cooling pad having a top sheet which is microperforated and a water impervious bottom sheet.
Figures 6A and 6B illustrate a cooling pad having a top sheet which is microperforated and a bottom WO 97/30909 PCT/AU9/00086 9 sheet formed from a non-woven fabric.
Figures 7A and 7B illustrate a fluid absorbing pad having top and bottom sheets which are microperforated and formed from three layers.
Figures 8A and 8B illustrate a fluid absorbing pad where the top sheet is microperforated and is formed from three layers and the bottom sheet is a non-woven fabric.
Figures 9A and 9B illustrate a fluid absorbing pad where the top sheet is microperforated and is formed from three layers and the bottom sheet is paper.
Figures 10A and 10B illustrate a cooling pad where the top sheet is microperforated and is formed from three layers and the bottom sheet is a non-woven fabric.
Figures 11A and 11B illustrate a cooling pad where the top sheet is microperforated and is formed from three layers and the bottom sheet is also formed from three layers.
Figures 12A and 12B illustrate a cooling pad where the top sheet is microperforated and is formed from three layers and the bottom sheet is water impervious.
Figures 13A and 13B illustrate a cooling pad where the top sheet is microperforated and is formed from two layers and the bottom sheet is formed from one layer.
Figures 14A and 14B illustrate a cooling pad where the top sheet and the bottom sheet are both formed from two layers.
Figures 15A and 15B illustrate a fluid absorbing pad where the top sheet and the bottom sheet are formed from two layers being a microperforated layer and an intermediate paper layer.
Figures 16A and 16B illustrate a fluid absorbing pad where the top sheet is formed from two layers being a microperforated layer and a paper layer, and the bottom sheet is a non woven fabric.
Figures 17A and 17B illustrate a fluid absorbing pad where the top sheet is formed two layers being a microperforated layer and a paper layer, and the WO 97/30909 PCT/AU97/00086 bottom sheet is-a paper.
Figure 18 illustrates a cooling pad where the top sheet and the bottom sheet are both formed from two layers being a microperforated layer and a non woven fabric layer.
Figure 19 illustrates a cooling pad where the top sheet is formed from two layers being a microperforated layer and a non woven fabric layer, and the bottom sheet is a non woven fabric.
Figure 20 illustrates a fluid absorbing pad where the top sheet is formed from two layers being a microperforated plastic co-extruded layer and a non woven fabric layer, and the bottom sheet is formed from two layers of non woven fabric.
BEST MODE Referring to the figures, there are shown two types of absorbent pads one particularly suitable for absorbing biofluids (the pad of Figures 1 3, 7 9) and one particularly suitable as a cooling or heating pad (the pad of Figures 4 6, 10 12). The pads differ in the size of the cells, and the type of bottom sheet; the top sheet of each pad being microperforated.
Referring initially to the pads of Figures 1 3, these pads can be used as a red meat or poultry pad and can be positioned between a meat product and the meat tray. These pads find particular use in meat trays which are found for sale in supermarkets, butchers and the like.
The absorbent pad can come in two main sizes and absorption capacities. One type of pad can have an external dimension of 113mm X 169mm with an internal cell size of 50mm X 72.8mm. In each cell is provided 0.48g of Favor Pac 100th superabsorbent powder which is a sodium polyacrylate and is available commercially. The pad has an overall absorption capacity of about 108g of chicken biofluids. The other main size of the absorbing pad is used particularly in the poultry market and this pad has an external measurement of 141mm X 169mm with the WO 97/30909 PCT/AU97/00086 11 internal cell being 64mm X 72.8mm. 0.75g of the same superabsorbent polymer is placed in each cell giving the pad an absorption capacity of 120g of biofluids.
The absorbing pads of Figures 1 3 have a top sheet 10 constructed from a plastic laminate film which is a 12 micron polyester film adhered to a 30 micron polyethylene film. The film is microperforated to a perforation rate of 330 perforations per square inch.
The perforations are evenly spread through the top sheet, and each perforation is cigar-shaped having a perforation size of 20 micron across X 90 microns along.
Each pad has a number of cells or pouches 14 in which the absorbent is placed. The cells are totally sealed off around their edges by heat sealing or by other means.
The bottom sheet 11 of the absorbent pad of Figure 1 is identical to the top sheet such that this particular pad is microperforated on both sides. In Figure 2, the bottom sheet 12 is a water permeable nonwoven fabric, and in Figure 3, the bottom sheet 13 is a heat fusible paper. Other variations are also envisaged.
The pads of Figures 1 3, may include as an option one or two light-weight heat fusible paper sheets.
The function of these paper sheets is to act as a molecular sieve to stop any polymer migration. The paper sheets have a weight of 16.5g per square metre and are a blend of cellulose fibres and thermo plastic fibres and the sheet is itself commercially available.
In Figure 2, the bottom sheet 12 is a white polyester/viscose fibre blend which is resin bonded and has a low density polyethylene scatter coating on the inside of the product. The fabric has a typical weight of 65g per square metre with a 45g per square metre fibre/binder blend. With the low density polyethylene scatter coating on the inside of the product, we find that the fabric has an adequate thermal bond with other substrates. The non-woven fabric wets out instantaneously and draws liquids into the fabric once WO 97/30909 PCT/AU97/00086 12 contact has been made and to transport the liquids to the superabsorbent polymer.
In Figure 3, the bottom sheet 13 is a heavier weight heat fusible paper which is a blend of cellulostic and thermo plastic fibre and can have a weight of between 100g per square metre. Typically, the paper has 22% thermo plastic fibre and 78% cellulose fibre and is resin bonded to have a good wet strength. The paper has a good wetting and wicking action to assist in drawing fluids to the superabsorbent polymer.
Figures 4 6 show thermal pads such as cooling pads. The pads again have an array of separate cells in which the absorbent can be placed. In these embodiments, the top sheet 16 of the cooling pad is formed from a material identical to that of the absorbing pads of Figures 1 3. In Figure 5, the bottom sheet 17 of the cooling pad is formed from a totally water impermeable plastic or laminated film such that water can only be absorbed through the microperforated top sheet.
As we prefer that the polymer in the cell is fully hydrated, we do not find it useful to have any intermediate paper sheet such as found with the absorbent pad, as the paper sheet tends to reduce the bond strength and the cooling pad is under much more strain than the absorbing pad as much more water is absorbed by the polymer in the cooling pad before it is frozen. In Figure 4, the bottom sheet 18 is identical to the top sheet and in Figure 6, the bottom sheet 19 is a non-woven fabric.
Figures 7 9 illustrate further embodiments of pads according to the invention. In these embodiments, the top sheet 20 of each pad is itself formed from a triple layer. The triple layer has an outermost sheet which is a microperforated 12 micron polyester film 21.
Immediately behind the sheet is a paper sheet 22 which can have a weight of 38g per square metre. Immediately behind paper sheet 22 is a second perforated polyethylene sheet 23 having a thickness of 25 microns. Thus, it can
_I
WO 97/30909 PCT/AU97/00086 13 be seen that top sheet 20 can be seen as a single sheet formed from three layers being two microperforated layers between which is sandwiched a paper layer. In Figure 7, the bottom layer 24 is also formed from an identical composite as the top layer such that the absorbing pad of Figure 7 is formed from two sheets each having a triple layer structure.
The pad of Figure 8 also has a triple layer top sheet 21 23, but in this pad, the bottom sheet is made from a non-woven fabric Figure 9 illustrates a pad where the top sheet is again formed from the triple layer 21 23 and the bottom sheet is formed from a heavy weight paper 31.
Figures 10 12 show further thermal pads which can be used as cooling pads or heating pads or can be seen as an ice replacement pad (as can the pads of Figures 4 In the pads illustrated in Figures 10 12, the top sheet is again formed from the triple layers 21 23 previously described. In Figure 10, the bottom sheet 32A is formed from non-woven fabric. In Figure 11, the bottom sheet 32B is formed from the triple layer structure identical to the top sheet while in Figure 12, the bottom sheet is formed from a non-perforated plastic laminated film 32C.
The triple layered top sheet as illustrated in Figures 7 12 has a 12 micron microperforated polyester top sheet which gives the product excellent strength and provides desirable properties under high temperature and pressure when manufacturing the finished goods. This particular sheet can be reverse printed for product description and advertising purposes. The intermediate paper layer acts as an extremely good molecular sieve to negate any unhydrated polymer and hydrated gel migration through the film. We find that the paper can also act as a transporter of fluids through the two microperforated layers and this is done both in the Z axis and the X Y axis. The intermediate paper layer can have a weight range of between 5g 100g per square metre as long as it WO 97/30909 PCT/AU97/00086 14 provides adequate retention of the absorbent powder both in the hydrated and hydrated form. The third layer of the triple layer structure can be a microperforated polyethylene film and this film can be a mixture of low density polyethylene and linear low density polyethylene with a view to being heat sealable to the bottom sheet to form the pad. Of course, and as described above, a number of different films can be used, for instance nylon, all types of polypropylenes, all types of polyethylenes, their mixtures, polyurethanes and polyvinyl resins.
In an embodiment, the triple layer sheet can be formed as follows. Firstly, the three layers are adhesively laminated together and cured. The unperforated cured sheet is run through a microfine perforator and perforated on one side only making sure that the perforation pins do not pass into the intermediate paper layer. The sheet is then turned over and passed through the microfine perforator, and again the perforating pins pass through the topmost layer only and do not pass through the intermediate paper layer. By having the intermediate paper layer intact and unperforated, it functions effectively as a molecular sieve and does not permit migration of polymer through the sheet.
It is noted that when biofluids of water come into contact with the outermost layer of this triple layer sheet, the fluid is drawn into the structure through the microfine perforations by the capillary action of the paper. The perforations on each side of the sheet need not line up and therefore liquid drawn through the three sheets need not adopt a linear path.
This appears also to have some benefit in retention of the polymer in the cells.
Referring to Figures 13A and 13B, there is illustrated a cooling pad 70 where the top sheet 71 is formed from a microperforated layer as described previously. Immediately behind the microperforated layer WO 97/30909 PCT/AU97/00086 is a non-woven -fabric 72. The non-woven fabric in the embodiment is an ELEVES T M fabric. The fabric is a white non-woven, 40g per square metre, bi-component continuous filament fabric. The bottom sheet 73 is formed from a non-perforated plastic laminated film.
Figures 14A and 14B show a similar structure except that the bottom sheet 75 is identical to the top sheet 76, with both sheets including outermost microperforated laminated plastic films 77A, 77B immediately behind which is a non-woven fabric 78A, 78B, an example of which is ELEVES T fabric.
The products illustrated in Figures 13A, 13B, 14A and 14B have a reinforcing sheet in the form of the non-woven fabric. The reinforcing sheet gives the microperforated sheet greater support and provides strength to the overall product. As the microperforations do weaken the laminate film, it is possible that when the product is hydrated fully, and the sheet is bent or twisted, the microperforated laminate can crack and tear therefore allowing the perforations to become larger in size and possibly allowing the superabsorbent polymer to pass through the pad. The pressure can be exacerbated by freezing the pad and wrapping sheet containing the frozen pads around articles that need to be kept cool. The already weakened film when cold may approach its cold flex temperature which causes the film to resist flexing and forcibly wrapping the film around articles can create cracks and tears.
The ELEVESM has a non-woven design which can substantially contain the polymer should cracking or tearing of the microperforated layer still occur.
Figures 15A and 15B illustrate a fluid absorbent pad 40 having four cells 41 (the number of cells being optional) The pad is formed from a top sheet and a bottom sheet. The top sheet is formed from two layers being a microperforated plastic laminate sheet 42 immediately behind which is an intermediate paper sheet 43. The bottom sheet is formed from the same two WO 97/30909 WO97/30909 PCT/AU97/00086 16 layers being an outer microperforated plastic laminate sheet 44 and an intermediate paper sheet Figures 16A and 16B show a pad 45 having four cells 46. The pad is a fluid absorbing pad having a top sheet formed from two layers being an outer microperforated plastic laminate sheet 47 and an intermediate paper sheet 48. In this pad, the bottom sheet 49 is formed from one layer of non-woven fabric.
Figures 17A and 17B show a fluid absorbing pad 50 having four cells 51. The top sheet is formed from two layers being an outermost microperforated plastic laminate sheet 52 and an intermediate paper sheet 53 while the bottom sheet 54 is formed from one layer of paper.
Figure 18 is a side view of a cooling pad where the top and bottom sheets are both formed from two layers being an outermost microperforated plastic laminate sheet 55B with a intermediate non-woven fabric sheet 56A, 56B.
Figure 19 illustrates a further cooling pad where the top sheet is formed from two layers being an outermost microperforated plastic laminate sheet 60 and an intermediate non-woven fabric sheet 61 while the bottom sheet is formed from one layer of non-woven fabric 62.
Figures 20A and 20B illustrate a fluid absorbing pad 65 having a number of separate cells therein. The pad has a top sheet formed from two layer being an outermost microperforated plastic co-extruded sheet 66 behind which is a non-woven fabric sheet 67.
The bottom sheet is formed from two layers 68, 69 each being a non-woven fabric.
The fluid absorbing pad comes in three main sizes being a twelve cell pad either 400mm X 141mm, or 200mm X 280mm, and a nine cell pad which is 200mm X 211mm. Other sizes are available.
In Figure 20, the absorbing pad is a four layer pad. The plastic is of a different type being a multi- WO 97/30909 PCT/AU97/00086 17 layered co-extruded film. The three different layers are made of either a high density polyethylene or low density polyethylene/linear low density polyethylene blends to adjust melting temperatures. The top layer of the pad is the co-extruded plastic with the second layers being a non-woven fabric. The bottom sheet is made of two nonwoven fabric layers.
It should be appreciated that various other changes and modifications can be made to the invention.
That is, it should be appreciated that the pad size and shape can vary, the type of top and bottom sheet can vary as long as at least one sheet has the microperforations, the type of polymer and the amount of polymer can also vary to suit. The pad can be used as a biofluid absorbing pad, as a cooling pad, as a heating pad (it being appreciated that the cooling pad, once swollen, can be heated to function as a "hot pack"). The pads can be used for humidity control in packaging and may find use in the fresh flower industry.
Claims (22)
1. An absorbent pad which has a top sheet and a bottom sheet, the sheets being joined, to form at least one cell, an absorbent located within the cell, characterised in that at least one of the sheets is formed as a lamination of two microperforated sheets each formed from a liquid impermeable sheet containing microperforations, and an intermediate permeable layer sandwiched between the microperforated sheets, the microperforations allowing fluid to pass therethrough and into the cell.
2. The pad of claim 1, wherein the top sheet is formed from the microperforated sheet.
3. The pad of claim 1, wherein the microperforations are spread over the microperforated sheet in a substantially homogenous fashion.
4. The pad of claim 1, wherein the microperforation are between 10 and 200 microns.
5. The pad of claim 4, comprising between 10 to 500 microperforations per square inch.
6. The pad of claim 1, having a width of between 200-500mm, between 2- cells extending across the pad, each cell being between 40mm to 100mm across.
7. The pad of claim 1, wherein the microperforated sheet is formed from plastic.
8. The pad of claim 1, comprising a fluid absorbing pad having a top sheet and a bottom sheet both being microperforated.
9. The pad of claim 1, comprising a fluid absorbing pad having a top microperforated sheet and a bottom non-woven fabric sheet.
The pad of claim 1, comprising a fluid absorbing pad having a top microperforated sheet and a bottom paper sheet.
11. The pad of claim 1, comprising a cooling pad having a top sheet and a bottom sheet both being microperforated.
12. The pad of claim 1, comprising a cooling pad having a top sheet which is microperforated and a water impervious bottom sheet.
13. The pad of claim 1, comprising a cooling pad having a top sheet which is microperforated and a bottom sheet formed from a non-woven fabric.
14. The pad of claim 1, wherein the top sheet is formed as the lamination.
15. The pad of claim 14, wherein the bottom sheet is formed from the same three layers as the top sheet. SM.. .T i\ AMENDED SHEET IPEA/AU
16. The pad of claim 14, wherein the bottom sheet is a non-woven fabric.
17. The pad of claim 14, wherein the bottom sheet is paper.
18. The pad of claim 14, 15, 16 or 17 comprising a cooling pad.
19. The pad of claim 14, comprising a cooling pad and where the bottom sheet is water impervious.
The pad of claim 1, comprising a cooling pad where the top sheet is formed from two layers being an outer microperforated layer and an inner non-woven fabric layer.
21. The pad of claim 1, wherein the bottom sheet is formed from two layers of non-woven fabric.
22. An absorbent pad substantially as hereinbefore described with reference to the accompanying drawings. Dated this Sixteenth day of June 1999 SEALED AIR CORPORATION Patent Attorneys for the Applicant: gRE F B RICE CO
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU17129/97A AU708949B2 (en) | 1996-02-22 | 1997-02-19 | An absorbent pad |
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPN8248 | 1996-02-22 | ||
| AUPN8248A AUPN824896A0 (en) | 1996-02-22 | 1996-02-22 | An absorbent pad |
| AUPN8949A AUPN894996A0 (en) | 1996-03-27 | 1996-03-27 | An absorbent pad |
| AUPN8949 | 1996-03-27 | ||
| AU17129/97A AU708949B2 (en) | 1996-02-22 | 1997-02-19 | An absorbent pad |
| PCT/AU1997/000086 WO1997030909A1 (en) | 1996-02-22 | 1997-02-19 | An absorbent pad |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU59576/99A Division AU5957699A (en) | 1996-02-22 | 1999-11-19 | An absorbent pad |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU1712997A AU1712997A (en) | 1997-09-10 |
| AU708949B2 true AU708949B2 (en) | 1999-08-19 |
Family
ID=27152342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU17129/97A Ceased AU708949B2 (en) | 1996-02-22 | 1997-02-19 | An absorbent pad |
Country Status (1)
| Country | Link |
|---|---|
| AU (1) | AU708949B2 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0353334A1 (en) * | 1988-08-05 | 1990-02-07 | Kimberly-Clark Corporation | Absorbent structure for absorbing food product liquids |
| AU4215193A (en) * | 1992-07-23 | 1994-01-27 | Aci Operations Pty. Limited | Absorbent pad |
| AU1157395A (en) * | 1994-02-07 | 1995-08-17 | Showa Denko Kabushiki Kaisha | Liquid-absorbent sheet and method for storing food using the same |
-
1997
- 1997-02-19 AU AU17129/97A patent/AU708949B2/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0353334A1 (en) * | 1988-08-05 | 1990-02-07 | Kimberly-Clark Corporation | Absorbent structure for absorbing food product liquids |
| AU4215193A (en) * | 1992-07-23 | 1994-01-27 | Aci Operations Pty. Limited | Absorbent pad |
| AU1157395A (en) * | 1994-02-07 | 1995-08-17 | Showa Denko Kabushiki Kaisha | Liquid-absorbent sheet and method for storing food using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1712997A (en) | 1997-09-10 |
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