BR112015003688B1 - MIXTURE, AGRICULTURAL COMPOSITION, SEED, USE OF THE MIXTURE AND METHOD FOR THE CONTROL OF PHYTOPATHOGEN HARMFUL FUNGI - Google Patents

Abstract

mixture, agrochemical composition, seed, use of the mixture, methods for controlling harmful phytopathogenic fungi and for improving plant health the present invention relates to ternary fungicidal mixtures comprising at least one inhibitor of complex ii and at least one inhibitor of complex iii at site q0 as defined here and fluazinam, the composition comprising said mixtures and the use and methods of combating phytopathogenic fungi. the present invention also relates to seeds treated with at least such a mixture. in addition, the invention relates to processes for preparing mixtures and compositions of such mixtures.

Description

MIXTURE, AGRICULTURAL COMPOSITION, SEED, USE OF THE MIXTURE AND METHOD FOR THE CONTROL OF PHYTOPATHOGEN HARMFUL FUNGI

The present invention relates to ternary fungicidal mixtures comprising at least one complex II inhibitor and at least one complex III inhibitor at the Qo site as defined herein and fluazinam, the composition comprising said mixtures and the use and methods to combat phytopathogenic fungi. The present invention also relates to seeds treated with at least one such mixture. In addition, the invention relates to processes for preparing mixtures and compositions of such mixtures.

[002] Binary mixtures of the complex II inhibitor boscalide with one of the complex III inhibitors at the Qo site of pyraclostrobin, azoxystrobin, fluoxastrobin or trifloxystrobin or with fluazinam were mentioned in WO 98/08385 and WO 99/31981, respectively. Furthermore, WO 2007/017416 mentions, among others, binary fungicidal mixtures of the inhibitor of the complex II fluxpyroxade with one of the complex III inhibitors at the Qo site of pyraclostrobin, azoxystrobin, fluoxastrobin or trifloxystrobin or with fluazinam.

[003] Practical agricultural experience has shown that repeated and exclusive application of an individual active compound or a binary mixture in the control of harmful fungi leads in many cases to a rapid selection of the fungal strains that have developed natural or adapted resistance against the active compound in question. Effective control of these fungi with the active compound and / or binary mixture in question is no longer possible.

[004] To reduce the risk of selection of resistant fungal strains, mixtures of more than two different active compounds are used to control harmful fungi. By combining at least three active compounds with different mechanisms of action, it is possible to ensure successful control for a relatively long period of time.

[005] It is an objective of the present invention to provide, aiming an effective administration of resistance and effective control of harmful phytopathogenic fungi, in application rates that are the lowest possible, compositions that, in a reduced total amount of active compounds applied, have greater activity against harmful fungi (synergistic mixtures) and a broader spectrum of activity, in particular for certain indications.

[006] It has been properly verified that this objective is achieved by the mixtures and compositions, defined herein, comprising at least one compound I as defined here, at least one compound II as defined here and fluazinam.

[007] In addition, the simultaneous application, that is, together or separately, of a compound I, a compound II and fluazinam, or successive application of a compound I, a compound II and fluazinam, allows for better control of harmful fungi than is possible with binary mixtures or individual compounds alone (synergistic mixtures).

[008] The invention also relates to a method for the control of harmful phytopathogenic fungi using mixtures of at least one complex II inhibitor as defined here and pyraclostrobin and fluazinam and the use of a compound I and a compound II and fluazinam for the preparing such mixtures, and compositions comprising such mixtures and seeds comprising such mixtures or coated with that mixture.

[009] Thus, the present invention relates to mixtures comprising, as active components:
1) at least one compound I selected from:
fluxpyroxade, boscalide, benzovindiflupyr, bixafen, fluopiram, furametpir, isopyrazam, penflufen, pentiopirad, silkxane, tifluzamide, N- (4'-trifluoromethylthiobiphenyl-2-yl) -3-difluoromethyl-1-pyrolamide , N- (2- (1,3,3-trimethyl-butyl) -phenyl) -1,3-dimethyl-5-fluoro-1H-pyrazol-4-carboxamide, 3- (difluoromethyl) -1-methyl-N - (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 3- (trifluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide , 1,3-dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 3- (trifluoromethyl) -1,5-dimethyl-N- (1,1,3-trimethylindan -4-yl) pyrazol-4-carboxamide, 3- (difluoromethyl) -1,5-dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide and 1,3,5- trimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide;
and
2) at least one compound II selected from: pyraclostrobin, azoxystrobin, fluoxastrobin and trifloxystrobin;
and
flow.

[010] According to one embodiment, these ternary mixtures comprise component 1), component 2) and component 3) in a synergistically effective amount.

[011] In ternary mixtures according to the invention, that is, compositions comprising a compound I (component 1) and a compound II (component 2) and fluazinam (component 3), the weight ratio of compound I (component 1) and compound II (component 2) depends on the properties of the active substances used, it is generally in the range of 1:50 to 50: 1, regularly in the range of 1:20 to 20: 1, preferably in the range of 1:10 to 10 : 1, more preferably in the range of 1: 4 to 4: 1 and in particular in the range of 1: 2 to 2: 1, and the weight ratio of compound I (component 1) and fluazinam (component 3) is normally in the 1:50 to 50: 1, regularly in the 1:20 to 20: 1 range, preferably in the 1:10 to 10: 1 range, more preferably in the 1: 4 to 4: 1 range, and in particular in the range of 1: 2 to 2: 1. According to another embodiment, the weight ratio of component 1) and component 2) is in the range of 20: 1 to 1:20 and the weight ratio of component 1) and component 3) is in the range of 1: 1 to 1:50.

[012] In ternary mixtures according to the invention, that is, compositions comprising a compound I selected from boscalide, fluxpyroxade and benzovindiflupyr (as component 1) and a compound II selected from pyraclostrobin and azoxystrobin (component 2) and fluazinam (component 3), the weight ratio of compound I (component 1) and compound II (component 2) depends on the properties of the active substances used, usually in the range of 0.5: 1 to 1: 5, regularly in the range of 1: 1 to 1: 3, preferably in the range of 1: 1.5 to 1: 3, and in particular in the range of 1: 2, and the weight ratio of compound I (component 1) and fluazinam ( component 3) is normally in the range of 1: 1 to 1:50, regularly in the range of 1: 5 to 1:25, preferably in the range of 1: 5 to 1:15 and in particular in the range of 1:10.

[013] Any other active compounds (components 4) are, if desired, added in a weight ratio of 20: 1 to 1:20 to compound I (component 1).

[014] Compounds I and / or compounds II may be present in different crystalline modifications, which may differ in biological activity.

[015] According to one embodiment, in inventive mixtures, compound I is selected from fluxpyroxade, boscalidea, benzovindiflupyr and silkxane. According to another embodiment, in mixtures of the invention, compound I is selected from fluxpyroxade, boscalide and benzovindiflupyr. According to another embodiment, in mixtures of the invention, compound I is selected from fluxpyroxade and boscalide. According to another embodiment, in mixtures of the invention, compound I is boscalide. According to another embodiment, in mixtures of the invention, compound I is fluxpyroxade.

[016] According to an embodiment, in mixtures of the invention, compound II is selected from pyraclostrobin and azoxystrobin. According to another embodiment, in the mixtures of the invention, it is compound II pyraclostrobin.

[017] The mixtures and their compositions according to the invention can, in use as fungicides, also be present together with other active substances, for example, with herbicides, insecticides, fungicides, growth regulators, or with fertilizers, as a premix or, if applicable, not until immediately before use (tank mix).

[018] Mixing the ternary mixtures of the invention and the compositions containing them, respectively, in the form of use as fungicides with other fungicides results, in many cases, in obtaining an expansion of the fungicidal spectrum of activity or in preventing the development of resistance fungicides. In addition, in many cases, additional synergistic effects are obtained.

[019] In accordance with the present invention, it may be preferred that the mixtures comprise, in addition to a compound I, a compound II and fluazinam, a compound IV (component 4), another active compound, preferably in a synergistically effective amount . Another embodiment refers to mixtures in which compound IV (component 4) is an active compound selected from groups A) to O):

• - inibidores de C14 desmetilase (fungicidas DMI): triazóis: azaconazol, bitertanol, bromuconazol, ciproconazol, difenoconazol, diniconazol, diniconazol-M, epoxiconazol, fenbuconazol, fluquinconazol, flusilazol, flutriafol, hexaconazol, imibenconazol, ipconazol, metconazol, miclobutanil, oxpoconazol, paclobutrazol, penconazol, propiconazol, protioconazol, simeconazol, tebuconazol, tetraconazol, triadimefon, triadimenol, triticonazol, uniconazol, 1-[rel-(2S;3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)-oxiranilmetil]-5-tiocianato-1H-[1, 2,4]triazol, 2-[rel-(2S;3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)-oxiranilmetil]-2H-[1,2,4]triazol-3-tiol, 2-[2-cloro-4-(4-clorofenóxi)fenil]-1-(1,2,4-triazol-1 -il)pentan-2-ol, 1 -[4-(4-clorofenóxi)-2-(trifluorometil)fenil]-1 -ciclopropil-2-(1,2,4-triazol-1-il) etanol, 2-[4-(4-clorofenóxi)-2-(trifluorometil)fenil]-1-(1,2,4-triazol-1 -il)butan-2-ol, 2-[2-cloro-4-(4-clorofenóxi)fenil]-1-(1,2,4-triazol-1-il)butan-2-ol, 2-[4-(4-clorofenóxi)-2-(trifluorometil)fenil]-3-metil-1-(1,2,4-triazol-1 -il)butan-2-ol, 2-[4-(4-clorofenóxi)-2-(trifluorometil)fenil]-1-(1,2,4-triazol-1-il)propan-2-ol, 2-[2-cloro-4-(4-clorofenóxi)fenil]-3-metil-1-(1,2,4-triazol-1-il)butan-2-ol, 2-[4-(4-clorofenóxi)-2-(trifluorometil)fenil]-1-(1,2,4-triazol-1-il)pentan-2-ol, 2-[4-(4-fluorofenóxi)-2-(trifluorometil)fenil]-1-(1,2,4-triazoM -il)propan-2-ol; imidazóis: imazalil, pefurazoato, prochloraz, triflumizol; pirimidinas, piridinas e piperazinas: fenarimol, nuarimol, pirifenox, triforina, [3-(4-cloro-2-fluoro-fenil)-5-(2,4-difluorofenil)isoxazol-4-il]-(3-piridil)metanol;
• - inibidores de Delta14-redutase: aldimorf, dodemorf, dodemorf-acetato, fenpropimorf, tridemorf, fenpropidin, piperalin, espiroxamina;
• - inibidores de 3-ceto redutase: fenexamida;

C) inibidores da síntese de ácido nucleico

• - fenilamidas ou fungicidas aminoácidos acila: benalaxil, benalaxil-M, kiralaxil, metalaxil, metalaxil-M (mefenoxam), ofurace, oxadixil;
• - outros: himexazol, octilinona, ácido oxolínico, bupirimato, 5-fluorocitosina, 5-fluoro-2-(p-tolilmetóxi)pirimidin-4-amina, 5-fluoro-2-(4-fluorofenilmetóxi)pirimidin-4-amina;

D) inibidores da divisão celular e citoesqueleto

• - inibidores de tubulina, como benzimidazóis, tiofanatos: benomil, carbendazim, fuberidazol, tiabendazol, tiofanato-metila; triazolopirimidinas: 5-cloro-7-(4-metil-piperidin-1-il)-6-(2,4,6-trifluorfenil)-[1,2,4] triazolo[1,5-a] pirimidina;
• - outros inibidores da divisão celular: diethofencarb, etaboxame, pencicuron, fluopicolida, zoxamide, metrafenona, piriofenona;

E) inibidores da síntese de aminoácidos e proteínas

• - inibidores da síntese de metionina (anilino-pirimidinas): ciprodinil, mepanipirim, pirimetanil;
• - inibidores da síntese de proteína: blasticidina-S, kasugamicina, cloridrato de kasugamicina-hidrato, mildiomicina, estreptomicina, oxitetraciclina, polioxina, validamicina A;

F) inibidores da transdução de sinal

• - inibidores da MAP / histidina quinase: fluoroimid, iprodiona, procimidona, vinclozolina, fenpiclonil, fludioxonil;
• - inibidores da proteína G: quinoxifena;

G) inibidores da síntese de lipídios e membrana

• - inibidores da biossíntese de fosfolipídios: edifenfos, iprobenfos, pirazofos, isoprotiolana;
• - peroxidação lipídica: dicloran, quintozene, tecnazeno, tolclofos-metila, bifenila, cloroneb, etridiazol;
• - biossíntese de fosfolipídios e deposição da parede celular: dimetomorf, flumorf, mandipropamida, pyrimorph, bentiavalicarb, iprovalicarb, valifenalato e éster (4-fluorfenílico) do ácudi N-(1-(1-(4-ciano-fenil) etanossulfonil)but-2-il)carbâmico;
• - compostos que afetam a permeabilidade da membrana celular e ácidos graxos: propamocarb, propamo-carb-clorídrico;
• - inibidores do ácido graxo amida hidrolase: oxathiapiprolin;

H) inibidores com ação de múltiplos sítios

• - substâncias ativas inorgânicas: mistura Bordeaux, acetato de cobre, hidróxido de cobre, oxicloreto de cobre, sulfato de cobre básico, enxofre;
• - tio- e ditiocarbamatos: ferbam, mancozeb, maneb, metam, metiram, propineb, tiram, zineb, ziram;
• - compostos organoclorados (por exemplo, ftalimidas, sulfamidas, cloronitrilas): anilazina, clorotalonil, captafol, captan, folpet, diclofluanida, diclorofeno, hexaclorobenzeno, pentaclorofenol e seus sais, ftalida, tolilfluanida, N-(4-cloro-2-nitro-fenil)-N-etil-4-metil-benzenossulfonamida;
• - guanidinas e outros: guanidina, dodina, base livre de dodina, guazatina, guazatina-acetato, iminoctadina, iminoctadina-triacetato, iminoctadina-tris(albesilato), ditianon, 2,6-dimetil-1 H,5H-[1,4]ditiino[2,3-c:5,6-c’] dipirrol-1,3,5,7(2H,6H)-tetraona;

I) inibidores da síntese da parede celular
- inibidores da síntese de glucano: validamicina, polioxina B; inibidores da síntese de melanina: piroquilon, triciclazol, carpropamid, diciclomet, fenoxanil;
indutores da defesa de plantas
- acibenzolar-S-metila, probenazol, isotianil, tiadinil, pro-hexadiona-cálcio; fosfonatos: fosetil, fosetil-alumínio, ácido fosforoso e seus sais;
K) modo desconhecido de ação

• - bronopol, quinometinato, ciflufenamida, cimoxanil, dazomet, debacarb, diclomezina, difenzoquat, difenzoquat-metilsulfato, difenilamin, fenpirazamina, flumetover, flusulfamida, flutianil, metasulfocarb, nitrapirina, nitrotal-isopropil, oxatiapiprolin, tolprocarb, 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{5-[2-(prop-2-in-1-ilóxi)fenil]-4,5-di-hidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona, 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1- [4-(4-{5-[2-fluoro-6-(prop-2-in-1-ilóxi)fenil]-4,5-di-hidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona, 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{5-[2-cloro-6-(prop-2-in-1-ilóxi)fenil]-4,5-di-hidro-1,2-oxazol-3-il}-1,3-tiazol-2-il)piperidin-1-il]etanona, oxina-cobre, proquinazid, tebufloquin, tecloftalam, triazoxida, 2-butóxi-6-iodo-3-propilcromen-4-ona, N-(ciclo-propilmetoxiimino-6-difluoro-metóxi-2,3-difluoro-fenil)-metil)-2-fenil-acetamida, N’-(4-(4-cloro-3-trifluorometil-fenóxi)-2,5-dimetil-fenil)-N-etil-N-metil formamidina, N’-(4-(4-fluoro-3-trifluorometil-fenóxi)-2,5-dimetil-fenil)-N-etil-N-metil formamidina, N’-(2-metil-5-trifluormetil-4-(3-trimetilsilanil-propóxi)-fenil)-N-etil-N-metil formamidina, N’-(5-difluorometil-2-metil-4-(3-trimetilsilanil-propóxi)-fenil)-N-etil-N-metil formamida, éster 6-terc-butil-8-flúor-2,3-dimetil-quinolin-4-ílico do ácido metóxi-acético, 3- [5-(4-metilfenil)-2,3-dimetil-isoxazolidin-3-il]-piridina, 3-[5-(4-cloro-fenil)-2,3-dimetil-isoxazolidin-3-il]-piridina (pirisoxazol), amida do ácido N-(6-metóxi-piridin-3-il)ciclopropanocarboxílico, 5-cloro-1-(4,6-dimetóxi-pirimidin-2-il)-2-metil-1H-benzimidazol, 2-(4-cloro-fenil)-N-[4-(3,4-dimetóxi-fenil)-isoxazol-5-il]-2-prop-2-inilóxi-acetamida, (Z)-3-amino-2-ciano-3-fenil-prop-2-enoato de etila, N- [6-[[(Z)-[(1-metiltetrazol-5-il)-fenil-metileno]amino]oximetil]-2-piridil]carbamato de terc-butila, N-[6-[[(ZH(1-metiltetrazol-5-il)-fenil-metileno]amino]oximetil]-2-piridil]carbamato de pentila, 2-[2-[(7,8-difluoro-2-metil-3-quinolil)óxi]-6-fluoro-fenil]propan-2-ol, 2-[2-fluoro-6-[(8-fluoro-2-metil-3-quinolil)óxi]fenil]propan-2-ol, 3-(5-fluoro-3,3,4,4-tetrametil-3,4-di-hidroisoquinolin-1-il)quinolina, 3-(4,4-difluoro-3,3-dimetil-3,4-di-hidroisoquinolin-1-il)quinolina, 3-(4,4,5-trifluoro-3,3-dimetil-3,4-di-hidroisoquinolin-1-il)quinolina;

L) biopesticidas
L1) Pesticidas microbianos com atividade fungicida, bactericida, viricida e / ou ativador da defesa de plantas: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus amyloliquefaciens, B. mojavensis, B. pumilus, B. simplex, B. solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriófagos), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Fusarium oxysporum, Clonostachys rósea f. catenulate (também chamado Gliocladium catenulatum), Gliocladium roseum, Metschnikowia fructicola, Microdochium dimerum, Paenibacillus polymyxa, Pantoea agglomerans, Phlebiopsis gigantea, Pseudozyma flocculosa, Pythium oligandrum, Sphaerodes mycoparasitica, Streptomyces lvdicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperellum, T atroviride, T. fertile, T. gamsii, T. harmatum; mistura de T harzianum e T. viride; mistura de T. polysporum e T harzianum; T. stromaticum, T. virens (também chamado Gliocladium virens), T viride, Typhula phacorrhiza, Ulocladium oudema, U. oudemansii, Verticillium dahlia, vírus do mosaico amarelo da abobrinha (cepa não-virulenta);
L2) pesticidas bioquímicos com atividade fungicida, bactericida, viricida e / ou ativadora de defesa das plantas: quitosana (hidrolisado), laminarin, óleo de peixe Menhaden, natamicina, proteína da capa do vírus Plum pox, extrato de Reynoutria sachlinensis, ácido salicílico, óleo da árvore do chá;
L3) pesticidas microbianos com atividade inseticida, acaricida, moluscicida e / ou nematicida: Agrobacterium radiobacter, Bacillus firmus, B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, Beauveria bassiana, Burkholderia sp., Chromobacterium subtsugae, vírus da granulose Cydia pomonella, Isaria fumosorosea, Heterorhabditis bacteriophora, Lecanicillium longisporum, L. muscarium (anteriormente Verticillium lecanii), Metarhizium anisopliae, M. anisopliae var. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus poppiliae, Pasteuria spp., P. nishizawae, P. reneformis, P. usagae, Pseudomonas fluorescens, Steinernema carpocapsae, S. feltiae, S. kraussei, Streptomces galbus;
L4) pesticidas bioquímicos com atividade inseticida, acaricida, moluscicida, feromonas e / ou nematicida: L-carvona, citral, acetato de (E,Z)-7,9-dodecadien-1-ila, formato de etila, decadienoato de (E,Z)-2,4-etila (éster de pêra), (Z,Z,E)-7,11,13-hexadecatrienal, butirato de heptila, miristato de isopropila, senecioato de lavanulila, 2-metil 1-butanol, metil eugenol, jasmonato de metila, (E,Z)-2,13-octadecadien-1-ol, acetato de (E,Z)-2,13-octadecadien-1-ol, (E,Z)-3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanona, silicato de potássio, sorbitol actanoato, acetato de (E,Z,Z)-3,8,11-tetradecatrienila, acetato de (Z,E)-9,12-tetradecadien-1-ila, Z-7-tetradecen-2-ona, acetato de Z-9-tetradecen-1-ila, Z-11-tetradecenal, Z-11-tetradecen-1-ol, extrato de acácia negra, extrato de sementes e extrato de toranja, extrato de Chenopodium ambrosiodae, óleo Catnip, óleo de Neem, extrato Quillay, óleo Tagetes;
L5) pesticidas microbianos com atividade redutora do estresse de plantas, reguladora do crescimento de plantas, promotora do crescimento de plantas e / ou de aumento do rendimento: Azospirillum amazonense A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium sp., B. elkanii, B. japonicum, B. liaoningense, B. Lupini, Glomus intraradices, Mesorhizobium sp., Paenibacillus alvei, Penicillium bilaiae, Rhizobium leguminosarum bv. phaseolii, R. I. trifolii, R. I. bv. viciae P1NP3Cst, Sinorhizobium meliloti;
L6) pesticidas bioquímicos com atividade redutora do estresse de plantas, reguladora do crescimento de plantas e / ou aumento do rendimento de plantas: ácido abscísico, silicato de alumínio (caulim), 3-decen-2-ona, homobrassinlide, humatos, ácido jasmônico ou seus sais ou derivados, lisofosfatidil etanolamina, ácido poli-hidróxi polimérico, Ascophyllum nodosum (alga marinha norueguesa, alga marinha marrom) e extrato Ecklonia maxima (alga).
M) reguladores do crescimento
ácido abscísico, amidochlor, ancimidol, 6-benzilaminopurina, brassinolide, butralina, chlormequat (cloreto de chlormequat), cloreto de colina, ciclanilida, daminozide, dikegulac, dimetipina, 2,6-dimetilpuridina, ethephon, flumetralin, flurprimidol, flutiacet, forclorfenurão, ácido giberélico, inabenfide, ácido indol-3-acético, hidrazida maleica, mefluidida, mepiquat (cloreto de mepiquat), ácido naftalenoacético, N-6-benziladenina, paclobutrazol, pro-hexadiona (pro-hexadiona-cálcio), prohydrojasmon, tidiazurão, triapentenol, fosforotritioato de tributila, ácido 2,3,5-tri-iodobenzóico, trinexapac-etila e uniconazol;
N) herbicidas

• - acetamidas: acetoclor, alaclor, butaclor, dimetaclor, dimetenamida, flufenacet, mefenacet, metolaclor, metazacloro, napropamida, naproanilida, petoxamida, pretilaclor, propaclor, tenilclor;
• - derivados de aminoácidos: bilanafos, glifosato, glufosinato, sulfosato;
• - ariloxifenoxipropionatos: clodinafop, cyhalofop-butyl, fenoxaprop, fluazifop, haloxyfop, metamifop, propaquizafop, quizalofop, quizalofop-P-tefurila;
• - bipiridilas: diquat, paraquat;
• - (tio)carbamatos: asulam, butilato, carbetamida, desmedifame, dimepiperato, eptam (EPTC), esprocarb, molinato, orbencarb, fenmedifam, prosulfocarb, piributicarb, tiobencarb, trialato;
• - ciclohexanodionas: butroxidim, cletodim cicloxidime, profoxidime, setoxidim, tepraloxidim, tralcoxidim;
• - dinitroanilinas: benfluralina, etalfluralina, orizalina, pendimetalina, prodiamina, trifluralina;
• - difenil éteres: acifluorfen, aclonifen, bifenox, diclofop, etoxifen, fomesafen, lactofen, oxifluorfen;
• - hidroxibenzonitrilas: bromoxinil, diclobenil, ioxinil;
• - imidazolinonas: imazametabenz, imazamox, imazapic, imazapyr, imazaquin, imazetapyr;
• - ácidos fenóxi acéticos: clomeprop, ácido 2,4-diclorofenoxiacético (2,4-D), 2,4-DB, diclorprop, MCPA, MCPA-tioetila, MCPB, Mecoprop;
• - pirazinas: cloridazon, flufenpir-etil, flutiacet, norflurazon, piridato;
• - piridinas: aminopiralide, clopiralide, diflufenicão, ditiopir, fluridone, fluroxipir, picloram, picolinafena, tiazopir;
• - sulfonil ureias: amidosulfuron, azimsulfuron, bensulfuron, clorimuron-etil, clorsulfuron, cinossulfuron, ciclossulfamuron, etoxisulfuron, flazasulfuron, flucetosulfuron, flupirsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iodosulfuron, mesosulfuron, metazosulfuron, metsulfuron-metil, nicosulfuron, oxasulfuron, primisulfuron, prosulfuron, pirazosulfuron, rimsulfuron, sulfometuron, sulfosulfuron, tifensulfuron, triasulfuron, tribenuron, trifloxisulfuron, triflusulfuron, tritosulfuron, 1-((2-cloro-6-propil-imidazo[1,2-b] piridazin-3-il)sulfonil)-3-(4,6-dimetóxi-pirimidin-2-il)ureia;
• - triazinas: ametrina, atrazina, cianazina, dimetametrina, etiozina, hexazinona, metamitron, metribuzina, prometrina, simazina, terbutilazina, terbutrina, triaziflam;
• - ureias: clorotoluron, daimuron, diuron, fluometuron, isoproturon, linuron, meta-benzthiazuron, tebutiuron;
• - outros inibidores da acetolactato sintase: bispyribac-sódio, cloransulam-metil, diclosulam, florasulam, flucarbazona, flumetsulam, metosulam, orto-sulfamuron, penoxsulam, propoxicarbazona, pyribambenz-propyl, pyribenzoxim, pyriftalid, piriminobac-metil, pyrimisulfan, pyrithiobac, pyroxasulfone, piroxsulame;
• - outros: amicarbazone, aminotriazol, anilofos, beflubutamida, benazolina, bencarbazone, benfluresate, benzofenap, bentazone, benzobiciclon, biciclopirona, bromacil, bromobutida, butafenacil, butamifos, cafenstrole, carfentrazone, cinidon-etil, clortal, cinmetilina, clomazone, cumiluron, ciprossulfamida, dicamba, difenzoquat, diflufenzopir, Drechslera monoceras, endotal, etofumesato, etobenzanid, fenoxasulfone, fentrazamida, flumiclorac-pentil, flumioxazin, flupoxame, flurocloridona, flurtamone, indanofan, isoxabeno, isoxaflutol, lenacil, propanil, propizamida, quinclorac, quinmerac, mesotriona, ácido metil arsônico, naptalam, oxadiargyl, oxadiazon, oxaziclomefone, pentoxazona, pinoxaden, pyraclonil, piraflufen-etil, pyrasulfotole, pirazoxifeno, pirazolinato, quinoclamina, saflufenacil, sulcotriona, sulfentrazona, terbacilo, tefuryltrione, tembotriona, tiencarbazona, topramezona, éster etílico do ácido (3-[2-cloro-4-flúor-5-(3-metil-2,6-dioxo-4-trifluorometil-3,6-di-hidro-2H-pirimidin-1-il)-fenóxi]-piridin-2-ilóxi)-acético, éster metílico do ácido 6-amino-5-cloro-2-ciclopropil-pirimidina-4-carboxílico, 6-cloro-3-(2-ciclopropil-6-metil-fenóxi)-piridazin-4-ol, ácido 4-amino-3-cloro-6-(4-cloro-fenil)-5-flúor-piridina-2-carboxílico, éster metílico do ácido 4-amino-3-cloro-6- (4-cloro-2-fluoro-3-metóxi-fenil)-piridina-2-carboxílico e éster metílico da ácido 4-amino-3-cloro-6-(4-cloro-3-dimetilamino-2-fluoro-fenil)-piridina-2-carboxílico.

O) inseticidas

• - organo(tio)fosfatos: acefato, azametifos, azinfos-metila, clorpirifos, clorpirifós-metil, clorfenvinfos, diazinon, diclorvos, dicrotofos, dimetoato, dissulfotom, etiom, fenitrotiom, fentiom, isoxatiom, malation, metamidofos, metidatiom, metil-paratiom, mevinfos, monocrotofós, oxidemeton-metil, paraoxon, paration, fentoato, fosalona, fosmete, fosfamidon, forato, foxima, pirim ifós-metil, profenofos, protiofos, sulprofos, tetraclorvinfos, terbufos, triazofos, triclorfom;
• - carbamatos: alanicarb, aldicarb, bendiocarb, benfuracarb, carbaril, carbofuran, carbosulfan, fenoxicarb, furatiocarb, metiocarb, metomil, oxamil, pirimicarb, propoxur, tiodicarb, triazamato;
• - piretroides: aletrina, bifentrina, ciflutrina, cialotrina, cifenotrina, cipermetrina, alfa-cipermetrina, beta-cipermetrina, zeta-cipermetrina, deltametrina, esfenvalerato, etofenprox, fenpropatrina, fenvalerato, imiprotrina, lambda-cialotrina, permetrina, praletrina, piretrina I e II, resmetrina, silafluofeno, tau-fluvalinato, teflutrina, tetrametrina, tralometrina, transflutrina, proflutrina, dimeflutrina;
• - reguladores do crescimento de insetos: a) inibidores da síntese de quitina: benzoilureias: clorfluazuron, cyramazin, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron; buprofezin, diofenolan, hexitiazox, etoxazole, clofentazine; b) antagonistas de ecdisona: halofenozida, metoxifenozida, tebufenozida, azadiractina; c) juvenoides: piriproxifeno, metopreno, fenoxicarb; d) inibidores da biossíntese de lipídios: espirodiclofeno, espiromesifeno, spirotetramat;
• - compostos agonistas / antagonistas do receptor nicotínico: clotianidina, dinotefurano, flupiradifurona, imidacloprid, tiametoxame, nitenpiram, acetamiprid, tiacloprid, 1-2-cloro-tiazol-5-ilmetil)-2-nitrimino-3,5-dimetil-[1,3,5]triazinano;
• - compostos antagonistas de GABA: endosulfan, etiprole, fipronil, vaniliprole, pyrafluprole, piriprol, amida do ácido 5-amino-1-(2,6-dicloro-4-metil-fenil)-4-sulfinamoil-1H-pirazol-3-carbotióico;
• - inseticidas de lactonas macrocíclicas: abamectina, emamectina, milbemectina, lepimectina, spinosad, espinetorame;
• - acaricidas inibidores do transporte de elétrons na mitocôndria (METI) I: fenazaquina, pyridaben, tebufempirade, tolfenpyrad, flufenerim;
• - compostos METI II e III: acequinocil, fluacyprim, hidrametilnona;
• - desacopladores: clorfenapyr;
• - inibidores da fosforilação oxidativa: cyhexatin, diafentiuron, óxido de fenbutatin, propargite;
• - compostos disruptores de mudas: cryomazine;
• - inibidores da oxidase de função mista: piperonil butóxido;
• - bloqueadores do canal de sódio: indoxacarb, metaflumizona;
• - inibidores do receptor de rianodina: clorantraniliprol, ciantraniliprol, flubendiamida, N-[4,6-dicloro-2-[(dietil-lambda-4-sulfanilideno)carbamoil]-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida; N-[4-cloro-2-[(dietil-lambda-4-sulfanilideno)carbamoil]-6-metil-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida; N-[4-cloro-2-[(di-2-propil-lambda-4-sulfanilideno)carbamoil]-6-metil-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida; N-[4,6-dicloro-2-[(di-2-propil-lambda-4-sulfanilideno)carbamoil]-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida; N-[4,6-dicloro-2-[(dietil-lambda-4-sulfanilideno)carbamoil]-fenil]-2-(3-cloro-2-piridil)-5-(difluorometil)pirazol-3-carboxamida; N-[4,6-dibromo-2-[(di-2-propil-lambda-4-sulfanilideno)carbamoil]-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida; N-[4-cloro-2-[(di-2-propil-lambda-4-sulfanilideno)carbamoil]-6-ciano-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida; N-[4,6-dibromo-2-[(dietil-lambda-4-sulfanilideno)carbamoil]-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida;
• - Outros: benclothiaz, bifenazato, cartap, flonicamid, piridalil, pimetrozina, enxofre, tiociclam, cyenopyrafen, flupyrazofos, cyflumetofen, amidoflumet, imicyafos, bistrifluron, pyrifluquinazon e éster do ácido 1,1’-[(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-4-[[(2-ciclopropilacetil)óxi]metil]-1,3,4,4a,5,6,6a,12,12a,12b-deca-hidro-12-hidróxi-4,6a, 12b-trimetil-11-oxo-9-(3-piridinil)-2H,11 H-nafto[2,1-b]pirano[3,4-e]piran-3,6-di-il] ciclopropanoacético.

[020] The following list of active components (eg active substances and biopesticides), in conjunction with which compounds I can be used, is intended to illustrate the possible combinations, but are not limited to them:
A) Breathing inhibitors
- complex III inhibitors at the Qo site (for example, strobilurins): azoxystrobin, coumetoxystrobin,
coumoxystrobin, dimoxystrobin, enestroburin, phenaminstrobin, phenoxystrobin / fluphenoxystrobin fluoxastrobin, cresoxime-methyl, mandestrobin, metominostrobin, orisastrobin, picoxystrobin, pyraclostrobin, pyramethostrobin piraoxystrobin-2- (2- methyl-allylideneaminooxymethyl) -phenyl) -2-methoxy-imino-N-methyl-acetamide, pyribencarb, triclopyricarb / chlorodincarb, famoxadone, phenamidone;
- complex III inhibitors at the Qi site: [(3S, 6S, 7R, 8R) -8-benzyl-3 - [(3-acetoxy-4-methoxy-pyridine-2-carbonyl) 2-methylpropanoate 2-methylpropanoate amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl], [(3S, 6S, 7R, 8R) -8-benzyl-3 - [[3- (2-methylpropanoate] acetoxymethoxy) -4-methoxy-pyridine-2-carbonyl] amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl], [(3S, 6S, 7R, 8R] 2-methylpropanoate ) -8-benzyl-3 - [(3-isobutoxycarbonyloxy-4-methoxy-pyridine-2-carbonyl) amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl], 2- [(3S, 6S, 7R, 8R) -8-benzyl-3 - [[3- (1,3-benzodioxol-5-ylmethoxy) -4-methoxy-pyridine-2-carbonyl] amino] -6- methylpropanoate methyl-4,9-dioxo-1,5-dioxonan-7-yl]; 2- (3S, 6S, 7R, 8R) -3 - [[((3-hydroxy-4-methoxy-2-pyridinyl) carbonyl] amino] -6-methyl-4,9-dioxo-8- (phenylmethyl) ) -1,5-dioxonan-7-yl;
- complex II inhibitors (for example, carboxamides): benodanil, benzovindiflupyr, bixafen, boscalide, carboxine, fenfuram, fluopyrame, flutolanil, fluxpyroxade, furametpyr, isofetamid, isopyrazam, mepronil, oxycarboxine, puffifen, penflufen, penflufen N- (4'-trifluoromethylthiobiphenyl-2-yl) -3-difluoromethyl-1-methyl-1H-pyrazol-4-carboxamide, N- (2- (1,3,3-trimethyl-butyl) -phenyl) -1 , 3-dimethyl-5-fluoro-1H-pyrazol-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide, 3- (trifluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 1,3-dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 3- (trifluoromethyl) -1, 5-dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 1, 3,5-trimethyl-N- ( 1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide, N- (7-fluoro-1,1,3-trimethyl-indan-4-yl) -1,3-dimethyl-pyrazole-4- carboxamide, N- [2- (2,4-dichlorophenyl) -2-methoxy-1-methyl-ethyl] -3- (difluoromethyl) -1-methyl-pyrazole-4-carboxamide;
- other respiration inhibitors (eg complex I, uncouplers): diflumetorim, (5,8-difluoroquinazolin-4-yl) - {2- [2-fluoro-4- (4-trifluoromethylpyridin-2-yloxy) -phenyl ] -ethyl} -amine; nitrophenyl derivatives: binapacril, dinobuton, dinocap, fluazinam; ferimzone; organometallic compounds: phentin salts, such as fentin acetate, fentin chloride or fentin hydroxide; ametoctradine; and siltiofam;
B) sterol biosynthesis inhibitors (SBI fungicides)

• - C14 demethylase inhibitors (DMI fungicides): triazoles: azaconazole, bitertanol, bromuconazole, cyproconazole, diphenoconazole, diniconazole, diniconazole-M, epoxiconazole, fenbuconazole, fluquinconazole, flusilazole, methazolone, flacilazole, hexazol, hexane, paclobutrazol, penconazole, propiconazole, protioconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triticonazole, uniconazole, 1- [rel- (2S; 3R) -3- (2-chlorophenyl) -2- (2,4-difluorofen) -oxyranylmethyl] -5-thiocyanate-1H- [1, 2.4] triazole, 2- [rel- (2S; 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) -oxyranylmethyl] -2H- [1,2,4] triazole-3-thiol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) pentan- 2-ol, 1 - [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol, 2- [4- ( 4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) f enyl] -3-methyl-1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- ( 1,2,4-triazol-1-yl) propan-2-ol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -3-methyl-1- (1,2,4-triazole- 1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) pentan-2-ol, 2- [4- (4-fluorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazoM -yl) propan-2-ol; imidazoles: imazalil, pefurazoate, prochloraz, triflumizole; pyrimidines, pyridines and piperazines: fenarimol, nuarimol, pyrifenox, triforin, [3- (4-chloro-2-fluoro-phenyl) -5- (2,4-difluorophenyl) isoxazol-4-yl] - (3-pyridyl) methanol;
• - Delta14 reductase inhibitors: aldimorf, dodemorf, dodemorf-acetate, fenpropimorf, tridemorf, fenpropidin, piperalin, spiroxamine;
• - 3-keto reductase inhibitors: fenexamide;

C) nucleic acid synthesis inhibitors

• - phenylamides or fungicides acyl amino acids: benalaxyl, benalaxyl-M, kiralaxyl, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl;
• - others: himexazole, octylinone, oxolinic acid, bupyrime, 5-fluorocytosine, 5-fluoro-2- (p-tolylmethoxy) pyrimidin-4-amine, 5-fluoro-2- (4-fluorophenylmethoxy) pyrimidin-4-amine;

D) cell division and cytoskeleton inhibitors

• - tubulin inhibitors, such as benzimidazoles, thiophanates: benomyl, carbendazim, fuberidazole, thiabendazole, thiophanate-methyl; triazolopyrimidines: 5-chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorphenyl) - [1,2,4] triazolo [1,5-a] pyrimidine;
• - other cell division inhibitors: diethofencarb, etaboxam, pencicuron, fluopicolide, zoxamide, metrafenone, pyrophenone;

E) inhibitors of amino acid and protein synthesis

• - inhibitors of methionine synthesis (anilino-pyrimidines): cyprodinil, mepanipyrim, pyrimethanil;
• - protein synthesis inhibitors: blasticidin-S, kasugamycin, kasugamycin hydrochloride, mildiomycin, streptomycin, oxytetracycline, polyoxin, validamycin A;

F) signal transduction inhibitors

• - MAP / histidine kinase inhibitors: fluoroimid, iprodione, procymidone, vinclozoline, fenpiclonil, fludioxonil;
• - protein G inhibitors: quinoxyfen;

G) lipid and membrane synthesis inhibitors

• - phospholipid biosynthesis inhibitors: edifenfos, iprobenfos, pyrazophos, isoprothiolan;
• - lipid peroxidation: dichloran, quintozene, tecnazene, tolclofos-methyl, biphenyl, cloroneb, etridiazole;
• - phospholipid biosynthesis and cell wall deposition: dimetomorf, flumorf, mandipropamide, pyrimorph, bentiavalicarb, iprovalicarb, valifenalate and N- (1- (1- (4-cyano-phenyl) ethanesulfonyl) but ester (4-fluorphenyl) -2-yl) carbamic;
• - compounds that affect the permeability of the cell membrane and fatty acids: propamocarb, propamo-carb-hydrochloric;
• - fatty acid amide hydrolase inhibitors: oxathiapiprolin;

H) multi-site inhibitors

• - inorganic active substances: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulphate, sulfur;
• - thio- and dithiocarbamates: ferbam, mancozeb, maneb, metam, metiram, propineb, tiram, zineb, ziram;
• - organochlorine compounds (eg phthalimides, sulfamides, chloronitriles): anilazine, chlorothalonil, captafol, captan, folpet, diclofluanide, dichlorophene, hexachlorobenzene, pentachlorophenol and its salts, phthalide, tolylfluanide, N- (4-chloro-2-nit phenyl) -N-ethyl-4-methyl-benzenesulfonamide;
• - guanidines and others: guanidine, dodine, dodine-free base, guazatin, guazatin-acetate, iminoctadine, iminoctadine-triacetate, iminoctadine-tris (albesylate), dithianon, 2,6-dimethyl-1 H, 5H- [1,4 ] dithino [2,3-c: 5,6-c '] dipyrrol-1,3,5,7 (2H, 6H) -tetraone;

I) inhibitors of cell wall synthesis
- glucan synthesis inhibitors: validamycin, polyoxin B; inhibitors of melanin synthesis: piroquilon, tricyclazole, carpropamid, dicyclomethane, phenoxanil;
plant defense inducers
- acibenzolar-S-methyl, probenazole, isothianyl, thiadinyl, prohexadione-calcium; phosphonates: fosetil, fosetil-aluminum, phosphorous acid and its salts;
K) unknown mode of action

• - bronopol, quinomethinate, ciflufenamide, cymoxanil, dazomet, debacarb, diclomezine, difenzoquat, diphenylamin-methylsulfate, diphenylamin, phenpyrazamine, flumetover, flusulfamide, flutianyl, metasulfocarb, nitrapirin, nitrotal-isopropyl, tolpropyl, tolpi, tolopropyl, tolpi, bis (difluoromethyl) -1H-pyrazol-1-yl] -1- [4- (4- {5- [2- (prop-2-in-1-yloxy) phenyl] -4,5-dihydro- 1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl] ethanone, 2- [3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] - 1- [4- (4- {5- [2-fluoro-6- (prop-2-in-1-yloxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl] ethanone, 2- [3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] -1- [4- (4- {5 - [2-chloro-6- (prop-2-in-1-yloxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl ) piperidin-1-yl] ethanone, oxin-copper, proquinazid, tebufloquin, keyboardophthalam, triazoxide, 2-butoxy-6-iodo-3-propylchromen-4-one, N- (cyclo-propylmethoxyimino-6-difluoro-methoxy- 2,3-difluoro-phenyl) -methyl) -2-phenyl-acetamide, N '- (4- (4-chloro-3-trifluoromethyl-phenoxy) -2,5-dimethyl-phenyl) -N-ethyl -N-methyl formamidine, N '- (4- (4-fluoro-3-trifluoromethyl-phenoxy) -2,5-dimethyl-phenyl) -N-ethyl-N-methyl formamidine, N' - (2-methyl- 5-trifluormethyl-4- (3-trimethylsilanyl-propoxy) -phenyl) -N-ethyl-N-methyl formamidine, N '- (5-difluoromethyl-2-methyl-4- (3-trimethylsilanyl-propoxy) -phenyl) -N-ethyl-N-methyl formamide, methoxy-acetic acid 6-tert-butyl-8-fluor-2,3-dimethyl-quinolin-4-yl ester, 3- [5- (4-methylphenyl) -2 , 3-dimethyl-isoxazolidin-3-yl] -pyridine, 3- [5- (4-chloro-phenyl) -2,3-dimethyl-isoxazolidin-3-yl] -pyridine (pyrisoxazole), N- acid amide (6-methoxy-pyridin-3-yl) cyclopropanecarboxylic, 5-chloro-1- (4,6-dimethoxy-pyrimidin-2-yl) -2-methyl-1H-benzimidazole, 2- (4-chloro-phenyl) -N- [4- (3,4-dimethoxy-phenyl) -isoxazol-5-yl] -2-prop-2-ynyloxy-acetamide, (Z) -3-amino-2-cyano-3-phenyl-prop Ethyl -2-enoate, tert-butyl N- [6 - [[(Z) - [(1-methyltetrazol-5-yl) -phenyl-methylene] amino] oxymethyl] -2-pyridyl] carbamate, N- [6 - [[(ZH (1-methyltetrazol-5-yl) -phenyl-methylene] amino] oxymethyl] -2-pyridyl] pentyl carbamate, 2- [2 - [(7,8-difluoro -2-methyl-3-quinolyl) oxy] -6-fluoro-phenyl] propan-2-ol, 2- [2-fluoro-6 - [(8-fluoro-2-methyl-3-quinolyl) oxy] phenyl ] propan-2-ol, 3- (5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl) quinoline, 3- (4,4-difluoro-3,3 -dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline;

L) biopesticides
L1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or plant defense activator activity: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus amyloliquefaciens, B. mojavensis, B. pumilus, B. simplex, B. solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Fusarium oxysporum, Clonostachys rosea f. catenulate (also called Gliocladium catenulatum), Gliocladium roseum, Metschnikowia fructicola, Microdochium dimerum, Paenibacillus polymyxa, Pantoea agglomerans, Phlebiopsis gigantea, Pseudozyma flocculosa, Pythium oligandum, Talisoderma, Sphaerodes mycopathy, Sphaerodes mycopit , T. fertile, T. gamsii, T. harmatum; mixture of T harzianum and T. viride; mixture of T. polysporum and T harzianum; T. stromaticum, T. virens (also called Gliocladium virens), T viride, Typhula phacorrhiza, Ulocladium oudema, U. oudemansii, Verticillium dahlia, zucchini yellow mosaic virus (non-virulent strain);
L2) biochemical pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activity: chitosan (hydrolyzate), laminarin, Menhaden fish oil, natamycin, Plum pox virus cover protein, Reynoutria sachlinensis extract, salicylic acid, tea tree oil;
L3) microbial pesticides with insecticidal, acaricidal, molluscicidal and / or nematicidal activity: Agrobacterium radiobacter, Bacillus firmus, B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, Beauveria bassiana, Burkholderia sp., Chromobacterium subtsugae, Cydia pomonella granulose virus, Isaria fumosorosea, Heterorhabditis bacteriophora, Lecanicillium longisporum, L. muscarium (formerly Verticillium lecanii), Metarhizium anisopliae, M. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus poppiliae, Pasteuria spp., P. nishizawae, P. reneformis, P. usagae, Pseudomonas fluorescens, Steinernema carpocapsae, S. feltiae, S. kraussei, Streptomces galbus;
L4) biochemical pesticides with insecticidal, acaricidal, molluscicidal, pheromone and / or nematicidal activity: L-carvone, citral, (E, Z) -7,9-dodecadien-1-yl acetate, ethyl format, (E decadenoate) , Z) -2,4-ethyl (pear ester), (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulil senecioate, 2-methyl 1-butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, (E, Z) -2,13-octadecadien-1-ol, (E, Z) -3,13 -octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E, Z, Z) acetate -3,8,11-tetradecatrienyl acetate (Z, E ) -9,12-tetradecadien-1-yl, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecen-1-ol, black wattle extract, seed extract and grapefruit extract, Chenopodium ambrosiodae extract, Catnip oil, Neem oil, Quillay extract, Tagetes oil;
L5) microbial pesticides with plant stress reducing activity, regulating plant growth, promoting plant growth and / or increasing yield: Azospirillum amazonense A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium sp., B. elkanii, B. japonicum, B. liaoningense, B. Lupini, Glomus intraradices, Mesorhizobium sp., Paenibacillus alvei, Penicillium bilaiae, Rhizobium leguminosarum bv. phaseolii, RI trifolii, RI bv. viciae P1NP3Cst, Sinorhizobium meliloti;
L6) biochemical pesticides with plant stress reducing activity, regulating plant growth and / or increasing plant yield: abscisic acid, aluminum silicate (kaolin), 3-decen-2-one, homobrassinlide, humus, jasmonic acid or its salts or derivatives, lysophosphatidyl ethanolamine, polymeric polyhydroxy acid, Ascophyllum nodosum (Norwegian kelp, brown kelp) and Ecklonia maxima extract (seaweed).
M) growth regulators
abscisic acid, amidochlor, ancimidol, 6-benzylaminopurine, brassinolide, butralin, chlormequat (chlormequat chloride), choline chloride, cyclanilide, daminozide, dikegulac, dimethypine, 2,6-dimethylpuridine, ethephon, flumetralin, flumetralin, flumetralin, flumetralin, flumetralin, flumetralin, flumetralin gibberellic acid, inabenfide, indole-3-acetic acid, maleic hydrazide, mefluidide, mepiquat (mepiquat chloride), naphthalenoacetic acid, N-6-benzyladenine, paclobutrazol, pro-hexadione (pro-hexadione-calcium), prohydrozuronmon, tidhydrojasmon, triapentenol, tributyl phosphorotrithioate, 2,3,5-triiodiodobenzoic acid, trinexapac-ethyl and uniconazole;
N) herbicides

• - acetamides: acetochlor, alachlor, butachlor, dimetachlor, dimethenamide, flufenacet, mefenacet, metolachlor, metazachlor, napropamide, naproanilide, petoxamide, pretilachlor, propachlor, tenilchlor;
• - derivatives of amino acids: bilanafos, glyphosate, glufosinate, sulfosate;
• - aryloxyphenoxypropionates: clodinafop, cyhalofop-butyl, fenoxaprop, fluazifop, haloxyfop, metamifop, propaquizafop, quizalofop, quizalofop-P-tefuril;
• - bipyridyls: diquat, paraquat;
• - (thio) carbamates: asulam, butylate, carbetamide, demedipham, dimepiperate, eptam (EPTC), esprocarb, molinate, orbencarb, fenmedipham, prosulfocarb, pyributicarb, thiobencarb, trialate;
• - cyclohexanediones: butroxidim, cletodim cicloxidime, profoxidime, setoxidim, tepraloxidim, tralcoxidim;
• - dinitroanilines: benfluralina, etalfluralina, orizalina, pendimetalina, prodiamina, trifluralina;
• - diphenyl ethers: acifluorfen, aclonifen, bifenox, diclofop, ethoxyfen, fomesafen, lactofen, oxyfluorfen;
• - hydroxybenzonitriles: bromoxynil, diclobenyl, ioxynil;
• - imidazolinones: imazametabenz, imazamox, imazapic, imazapyr, imazaquin, imazetapyr;
• - phenoxy acetic acids: clomeprop, 2,4-dichlorophenoxyacetic acid (2,4-D), 2,4-DB, dichlorprop, MCPA, MCPA-thioethyl, MCPB, Mecoprop;
• - pyrazines: chloridazon, flufenpirethyl, flutiacet, norflurazon, pyridate;
• - pyridines: aminopyralide, clopyralide, diflufenicão, dithiopir, fluridone, fluroxypyr, picloram, picolinafena, tiazopir;
• - sulfonyl ureas: amidosulfuron, azimsulfuron, bensulfuron, chlorimuron-ethyl, chlorosulfuron, cinosulfuron, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupirsulfuron, metsulfuron, metulfuron, methanesulfuron, methanesulfuron, methanesulfuron, imazos prosulfuron, pirazosulfuron, rimsulfuron, sulfometuron, sulfosulfuron, tifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, 1 - ((2-chloro-6-propyl-imidazo [1,2-b] pyridazin-3) pyridazin-3-pyridazin-3-pyridazin-3-pyridazin -3- (4,6-dimethoxy-pyrimidin-2-yl) urea;
• - triazines: amethrine, atrazine, cyanazine, dimetamethrin, ethiozine, hexazinone, metamitron, metribuzin, promethin, simazine, terbuthylazine, terbutrin, triaziflam;
• - ureas: chlorotoluron, daimuron, diuron, fluometuron, isoproturon, linuron, meta-benzthiazuron, tebutiuron;
• - other acetolactate synthase inhibitors: bispyribac-sodium, cloransulam-methyl, diclosulam, florasulam, flucarbazone, flumetsulam, metosulam, orthosulfamuron, penoxsulam, propoxycarbazone, pyribambenz-propyl, pyribenzoxim, pyracenzone, pyracil , pyroxsulam;
• - others: amicarbazone, aminotriazole, anilofos, beflubutamide, benazoline, bencarbazone, benfluresate, benzofenap, bentazone, benzobicyclon, bicyclopyrone, bromacil, bromobutide, butafenacil, butamifos, cafenstrole, cyclosurine, etherylone, carmine, hydridone , dicamba, difenzoquat, diflufenzopyr, Drechslera monoceras, endotal, etofumesate, etobenzanid, phenoxasulfone, fentrazamide, flumichlorac-pentyl, flumioxazin, flupoxam, flurochloridone, flurtamone, indanofan, isoxabil, quoxacil, propoxyl, loxacil, isoxabol, loxacil, isoxabil, arsenic methyl acid, naptalam, oxadiargyl, oxadiazon, oxaziclomefone, pentoxazone, pinoxaden, pyraclonil, piraflufen-ethyl, pyrasulfotole, pyrazoxifene, pyrazolinate, quinoclamine, saflufenacil, sulcotrione, tyronazone, tertone, tertone, terbazone (3- [2-chloro-4-fluoro-5- (3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-2H-pyrimidin- 1-yl) -phenoxy] -pyridin-2-yloxy) -acetic, 6-amino-5-chloro-2-cyclopropyl-pyrimidine-4-carboxylic acid methyl ester, 6-chloro-3- (2-cyclopropyl- 6-methyl-phenoxy) -pyridazin-4-ol, 4-amino-3-chloro-6- (4-chloro-phenyl) -5-fluoro-pyridine-2-carboxylic acid, 4-amino- 3-chloro-6- (4-chloro-2-fluoro-3-methoxy-phenyl) -pyridine-2-carboxylic acid and 4-amino-3-chloro-6- (4-chloro-3-dimethylamino) methyl ester -2-fluoro-phenyl) -pyridine-2-carboxylic.

O) insecticides

• - organo (thio) phosphates: acephate, azametiphos, azymphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinfos, diazinon, dichlorvos, dicrotofos, dimetoate, disulfotom, etiom, fenitrothiom, fentiom, metoxathione, methoxyamide, methaxy, methoxyamide, methoxyamide, , mevinfos, monocrotofós, oxidemeton-methyl, paraoxon, paration, fentoate, fosalone, fosmete, fosfamidon, phorato, foxima, ifós-methyl pirim, profenofos, protiofos, sulprofos, tetrachlorvinfos, terbufos, triazofos, trichorfons;
• - carbamates: alanicarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, phenoxicarb, furatiocarb, metiocarb, metomyl, oxamil, pyrimicarb, propoxur, tiodicarb, triazamate;
• - pyrethroids: alethrin, bifentrin, cyflothrin, cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, sphenopherine, etofenprox, fenpropatrin, perminetrine, pretretrine, pyrethetrine, pretrine, pyrethetrine, pretrine, pyrethetrine, pyrethetrine, pretrine, pyrethetrine, pyrethetrine, pretrine, pyrethetrine, pretrine, pyrethetrine, pyrethetrine, pretrine, pyrethetrine, pyrethetrine, pretrine, pyrethetrine, pyrethetrine, pyrethetrine, pretrine, pyrethetrine. II, resmethrin, silafluofen, tau-fluvalinate, teflutrin, tetramethrin, tralometrine, transflutrin, proflutrin, dimeflutrin;
• - insect growth regulators: a) chitin synthesis inhibitors: benzoylureas: clorfluazuron, cyramazin, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron; buprofezin, diofenolan, hexitiazox, ethoxazole, clofentazine; b) ecdysone antagonists: halofenozide, methoxyfenozide, tebufenozide, azadiractin; c) juvenoids: pyriproxyphene, methoprene, phenoxycarb; d) lipid biosynthesis inhibitors: spirodiclofen, spiromesifene, spirotetramat;
• - nicotinic receptor agonist / antagonist compounds: clothianidin, dinotefuran, flupiradifurone, imidacloprid, thiamethoxam, nitenpiram, acetamiprid, thiacloprid, 1-2-chloro-thiazol-5-ylmethyl) -2-nitrimino-3,5-dimethyl- [1 , 3.5] triazinane;
• - GABA antagonistic compounds: endosulfan, etiprole, fipronil, vaniliprole, pyrafluprole, pyriprol, 5-amino-1- (2,6-dichloro-4-methyl-phenyl) -4-sulfinamoyl-1H-pyrazol-3 acid amide -carbothioic;
• - macrocyclic lactone insecticides: abamectin, emamectin, milbemectin, lepimectin, spinosad, spinetorame;
• - mitochondrial electron transport inhibiting mites (METI) I: phenazaquin, pyridaben, tebufempirade, tolfenpyrad, flufenerim;
• - METI II and III compounds: acequinocil, fluacyprim, hydramethylnone;
• - uncouplers: clorfenapyr;
• - oxidative phosphorylation inhibitors: cyhexatin, diafentiuron, fenbutatin oxide, propargite;
• - seedling disrupting compounds: cryomazine;
• - mixed-function oxidase inhibitors: piperonyl butoxide;
• - sodium channel blockers: indoxacarb, metaflumizone;
• - ryanodine receptor inhibitors: chlorantraniliprol, cyantraniliprol, flubendiamide, N- [4,6-dichloro-2 - [(diethyl-lambda-4-sulfanylidene) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl ) -5- (trifluoromethyl) pyrazol-3-carboxamide; N- [4-chloro-2 - [(diethyl-lambda-4-sulfanilidene) carbamoyl] -6-methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3- carboxamide; N- [4-chloro-2 - [(di-2-propyl-lambda-4-sulfanilidene) carbamoyl] -6-methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3-carboxamide; N- [4,6-dichloro-2 - [(di-2-propyl-lambda-4-sulfanilidene) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole- 3-carboxamide; N- [4,6-dichloro-2 - [(diethyl-lambda-4-sulfanilidene) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (difluoromethyl) pyrazol-3-carboxamide; N- [4,6-dibromo-2 - [(di-2-propyl-lambda-4-sulfanilidene) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole- 3-carboxamide; N- [4-chloro-2 - [(di-2-propyl-lambda-4-sulfanilidene) carbamoyl] -6-cyano-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3-carboxamide; N- [4,6-dibromo-2 - [(diethyl-lambda-4-sulfanilidene) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide;
• - Others: benclothiaz, biphenazate, cartap, flonicamid, pyridalil, pimetrozina, sulfur, thiocyclam, cyenopyrafen, flupyrazofos, cyflumetofen, amidoflumet, imicyafos, bistrifluron, pyrifluquinazon and 4,1, R, 3S acidic acid. , 6aS, 12R, 12aS, 12bS) -4 - [[(2-cyclopropylacetyl) oxy] methyl] -1,3,4,4a, 5,6,6a, 12,12a, 12b-decahydro-12- hydroxy-4,6a, 12b-trimethyl-11-oxo-9- (3-pyridinyl) -2H, 11 H-naphtho [2,1-b] pyran [3,4-e] pyran-3,6-di -yl] cyclopropanoacetic.

[021] Group L biopesticides, their preparation and their biological activity, for example, against harmful fungi and pests are known (e-Pesticide Manual V 5.2 (ISBN 978 1 901396 85 0) (2008-2011); http: / /www.epa.gov/opp00001/biopesticides/, see product lists there; http://www.omri.org/omri-lists, see lists there; Bio-Pesticides Database BPDB http://sitem.herts.ac .uk / aeru / bpdb /, see link A to Z there).

[022] Many of these biopesticides are registered and / or are commercially available: aluminum silicate (SCREEN ™ DUO from Certis LLC, USA), Agrobacterium radiobacter K1026 (eg, NOGALL from Becker Underwood Pty Ltd., Australia), A. radiobacter K84 (Tate et al, 1979; Nature 280, 697-699; for example, GALLTROL of AG Biochem, Inc., C, USA), Ampelomyces quisqualis M-10 (for example, AQ 10® of Intrachem Bio GmbH & Co. KG, Germany), Ascophyllum nodosum extract (Norwegian kelp, brown kelp) (for example, Becker's Underwood ORKA GOLD, South Africa), Aspergillus flavus USDA accession number NRRL 21882 isolated from a peanut in Georgia in 1991 by the US Department of Agriculture (USDA), National Peanut Research Laboratory (for example, in AFLA-GUARD® by Syngenta, CH), Aureobasidium pullulans (for example, BOTECTOR® by bio-ferm GmbH, Germany), Azospirillum brasilense XOH (e.g. AZOS from Xtreme Gardening, USA or RTI Reforestation Technolog ies International, USA), Bacillus amyloliquefaciens IT-45 (CNCM I-3800, NCBI 1091041) (for example, RHIZOCELL C from ITHEC, France), B. amyloliquefaciens subsp. plantarum MBI600 (NRRL B-50595, deposited with the United States Department of Agriculture) (for example, INTEGRAL®, CLARUTY, SUBTILEX NG by Becker Underwood, USA), B. firmus 1-1582 (WO09 / 126473, WO09 / 124707, VOTIVO ® from Bayer Crop Science LP, USA), B. pumilus QST 2808 (NRRL Accession No. B-30087) (eg SONATA® and BALLAD® Plus from AgraQuest Inc., USA), B. subtilis GB03 (eg , KODIAK by Gustafson, Inc., USA), B. subtilis GB07 (EPIC by Gustafson, Inc., USA), B. subtilis QST-713 (NRRL-No. B-21661 in RHAPSODY®, SERENADE® MAX and SERENADE® ASO from AgraQuest Inc., USA), B. subtilis var. amyloliquefaciens FZB24 (for example, TAEGRO® by Novozyme Biologicals, Inc., USA), B. subtilis var. amyloliquefaciens D747 (for example, Double Nickel 55 from Certis LLC, USA), Bacillus thuringiensis ssp. kurstaki SB4 (NRRL B-50753, for example BETA PRO® by Becker Underwood, South Africa), Beauveria bassiana GHA (BOTANIGARD® 22WGP by Laverlam Int Corp., USA), B. bassiana 12256 (for example, BIOEXPERT® SC from Live Sytems Tecnology SA, Colombia), B. bassiana PPRI number 5339 (ARSEF number 5339 in the USDA ARS collection of entomopathogenic fungi cultures; NRRL 50757) (eg, BROADBAND® by Becker Underwood, South Africa), Bradyrhizobium sp. (for example, VAULT® by Becker Underwood, USA), B. japonicum (for example, VAULT® by Becker Underwood, USA), B. pumilus KFP9F (NRRL B-50754; for example, in FUSION-P by Becker Underwood BioAg SA (Pty) Ltd., a BASF Company), (Candida oleophila I-82 (eg ASPIRE® from Ecogen Inc., USA), Candida saitoana (eg BIOCURE® (in mixture with lysozyme) and BIOCOAT® from Micro Flo Company, USA (BASF SE) and Arysta), Chitosan (for example, ARMOR-ZEN by BotriZen Ltd., NZ), Clonostachys rosea f. Catenulata, also called Gliocladium catenulatum (for example, J 1446 isolated: PRESTOP® from Verdera, Finland), Coniothyrium minitans CON / M / 91-08 (for example, Contans® WG from Prophyta, Germany), Cryphonectria parasitica (for example, Endothia parasitic from CNICM, France), Cryptococcus albidus (for example, YIELD PLUS® Anchor Bio-Technologies, South Africa), Ecklonia maxima extract (seaweed) (eg KELPAK SL from Kelp Products Ltd, South Africa), Fusarium oxysporum (eg BIOFOX ® from SIAPA, Italy, FUSACLEAN® from Natural Plant Protection, France), Glomus intraradices (eg MYC 4000 from ITHEC, France), Glomus intraradices RTI-801 (eg MYKOS from Xtreme Gardening, USA or RTI Reforestation Technologies International , USA), grapefruit pulp seeds and extract (eg BC-1000 from Chemie SA, Chile), Heterorhabditis bacteriophaga (eg NEMASYS® G from Becker Underwood Ltd., UK), Isaria fumosorosea Apopka-97 (ATCC 20874) (PFR-97 ™ from Certis LLC, USA), Lecanicillium muscarium (formerly Verticillium lecanii) (eg MYCOTAL from Koppert BV, Netherlands), Lecanicillium longisporum KV42 and KV71 (eg VERTALEC® from Koppert BV, Netherlands) , Metarhizium anisopliae var. acridum IMI 330189 (deposited in European Culture Collections CABI; NRRL 50758) (for example, GREEN MUSCLE® by Becker Underwood, South Africa), M. anisopliae FI-1045 (for example, BIOCANE® by Becker Underwood Pty Ltd, Australia) , M. anisopliae var. acridum FI-985 (for example, GREEN GUARD® SC of Becker Underwood Pty Ltd, Australia), M. anisopliae F52 (for example, MET52® Novozymes Biologicals BioAg Group, Canada), M. anisopliae ICIPE 69 (for example, METATHRIPOL from ICIPE, Kenya), Metschnikowia fructicola (for example, SHEMER® by Agrogreen, Israel), Microdochium dimerum (for example, ANTIBOT® by Agrauxine, France), Neem oil (for example, TRILOGY®, TRIACT® 70 CE by Certis LLC , USA), strain FE 9901 of Paecilomyces fumosoroseus (e.g., NO FLY ™ from Natural Industries, Inc., USA), P. Iilacinus DSM 15169 (e.g., NEMATA® SC from Live Systems Technology SA, Colombia), P. Iilacinus BCP2 (NRRL 50756, for example, PL GOLD by Becker Underwood BioAg SA Ltd, South Africa), mixture of Paenibacillus alvei NAS6G6 (NRRL B-50755) and Bacillus pumilus KFP9F (NRRL B-50754) (for example, in BAC -UP or FUSION-P by Becker Underwood, South Africa), Penicillium bilaiae (e.g. JUMP START® by Novozymes Biologicals BioAg Group, Canada), P hlebiopsis gigantea (for example, ROTSTOP® by Verdera, Finland), potassium silicate (for example, Sil-MATRIX ™ by Certis LLC, USA), Pseudozyma flocculosa (for example, SPORODEX® by Plant Products Co. Ltd., Canada) , Pythium oligandrum DV74 (for example, POLYVERSUM® by Remeslo SSRO, Biopreparaty, Czech Rep.), Reynoutria sachlinensis extract (for example, REGALIA® SC by Marrone Biolnnovations, Davis, CA, USA), Rhizobium leguminosarum bv. phaseolii (e.g., RHIZO-STICK from Becker Underwood, USA), R.I. trifolii (e.g., DORMAL by Becker Underwood, USA), R.I. bv. viciae P1NP3Cst (also referred to as 1435; New Phytol 179 (1), 224-235, 2008; for example, in Becker Underwood NODULATOR PL Peat Granule, USA, or Becker Underwood Nodulator XL PL, Canada), R.I. bv. viciae SU303 (e.g., NODULAID Group E from Becker Underwood, Australia), R.I. bv. viciae WSM1455 (for example, NODULAID Group F from Becker Underwood, Australia), Sinorhizobium meliloti MSDJ0848 (INRA, France), also known as strain 2011 or RCR2011 (Mol Gen Genomics (2004) 272: 1-17; for example, DORMAL ALFALFA from Becker Underwood, USA; NITRAGIN® Gold from Novozymes Biologicals BioAg Group, Canada), Steinernema carpocapsae (e.g., MILLENIUM® from Becker Underwood Ltd., UK), S. feltiae (NEMASHIELD® from BioWorks, Inc., USA; NEMASYS ® by Becker Underwood Ltd., UK), S. kraussei L137 (NEMASYS® L by Becker Underwood Ltd., UK), Streptomyces lydicus WYEC 108 (e.g. Actinovate® by Natural Industries, Inc., USA, US 5,403,584 ), S. violaceusniger YCED-9 (for example, DT-9® from Natural Industries, Inc., USA, US 5,968,503), Talaromyces flavus V1117b (for example, PROTUS® from Prophyta, Germany), Trichoderma asperellum SKT- 1 (for example, ECO-HOPE® by Kumiai Chemical Industry Co., Ltd., Japan), T atroviride LC52 (for example, SENTINEL® by Agrimm Technologies Ltd, NZ), T fe rtile JM41R (NRRL 50759, for example RICHPLUS ™ by Becker Underwood Bio SA Ag Ltd, South Africa), T harzianum T-22 (for example, PLANTSHIELD® by BioWorks Inc., USA), T harzianum TH 35 (for example , ROOT PRO® of myControl Ltd., Israel), T. harzianum T-39 (for example, TRICHODEX® and TRICHODERMA 2000® of mycontrol Ltd., Israel and Makhteshim Ltd., Israel), T harzianum and T. viride (for example, TRICHOPEL from Agrimm Technologies Ltd, NZ), T harzianum ICC012 and T viride ICC080 (eg REMEDIER® WP from Isagro Ricerca, Italy), T polysporum and T. harzianum (eg BINAB® from BINAB Bio-Innovation AB , Sweden), T stromaticum (for example, TRICOVAB® by CEPLAC, Brazil), T virens GL-21 (also called Gliocladium virens) (for example, SOILGARD® by Certis LLC, USA), T viride (for example, TRIECO® from EcoSense Labs. (India) Pvt. Ltd., Indien, BIO-Cure® F from T. Stanes & Co. Ltd., India), T viride TV1 (for example, T viride TV1 from Agribiotec srl, Italy) and Ulocladium oudemansii HRU3 (by example, BOTRY-ZEN® by Botry-Zen Ltd, NZ).

[023] Bacillus amyloliquefaciens AP-136 (NRRL B-50614), B. amyloliquefaciens AP-188 (NRRL B-50615), B. amyloliquefaciens AP-218 (NRRL B-50618), B. amyloliquefaciens AP-219 (NRRL B -50619), B. amyloliquefaciens AP-295 (NRRL B-50620), B. japonicum SEMIA 5079 (for example, Gelfix 5 or Adhere 60 from Nitral Urbana Laoboratories, Brazil, a BASF company), B. japonicum SEMIA 5080 (by example, GELFIX 5 or ADHERE 60 from Nitral Urbana Laoboratories, Brazil, a BASF company), B. mojavensis AP-209 (NRRL B-50616), B. solisalsi AP-217 (NRRL B-50617), INR- strain 7 from B. pumilus (also called BU-F22 (NRRL B-50153) and BU-F33 (NRRL B-50185)), B. simplex ABU 288 (NRRL B-50340) and B. amyloliquefaciens subsp. plantarum MBI600 (NRRL B-50595) were mentioned in patent application US 20120149571, WO 2012/079073. Beauveria bassiana DSM 12256 is known from US200020031495. Bradyrhizobium japonicum USDA is known from US patent 7,262,151. Sphaerodes mycoparasitica IDAC 301008-01 (IDAC = Canada International Depositary Authority) is known from the document WO 2011/022809. NRRL numbers refer to the deposit numbers of strains deposited with the United States Department of Agriculture.

[024] Bacillus amyloliquefaciens subsp. plantarum MBI600 having accession number NRRL B-50595 is deposited with the United States Department of Agriculture on November 10, 2011 under the strain name Bacillus subtilis 1430. It has also been deposited with The National Collections of Industrial and Marine Beach Bacteria Ltd (NCIB), Torry Research Station, PO Box 31, 135 Abbey Road, Aberdeen, AB9 8DG, Scotland under accession number 1237, on December 22, 1986. Bacillus amyloliquefaciens MBI600 is known as rice seed promoter plant growth from Int. J. Microbiol. Res. ISSN 0975-5276, 3 (2) (2011), 120-130 and, for example, further described in US 2012/0149571 A1. This MBI600 strain is commercially available as a liquid formulation product Integral® (Becker-Underwood Inc., USA). Recently, the MBI 600 strain was reclassified as Bacillus amyloliquefaciens subsp. plantarum based on polyphasic tests that combine classic microbiological methods that depend on a mixture of traditional tools (such as culture-based methods) and molecular tools (such as genotyping and fatty acid analysis). Thus, Bacillus subtilis MBI600 (MBI or 600 or MBI-600) is identical to Bacillus amyloliquefaciens subsp. plantarum MBI600, formerly Bacillus subtilis MBI600.

[025] Metarhizium anisopliae IMI33 is commercially available from Becker Underwood as a Green Guard product. M. anisopliae var Acridium cepa IMI 330189 (NRRL-50758) is commercially available from Becker Underwood as a Green Muscle product.

[026] Bacillus subtilis cepa FB17 was originally isolated from beets in North America (Sistem Appl. Microbiol 27 (2004) 372-379). This strain of Bacillus subtilis promotes plant health (US 2010/0260735 A1; WO 2011/109395 A2). B. subtilis FB17 was also deposited with American Type Culture Collection (ATCC), Manassas, VA, USA, under accession number PTA-11857 on April 26, 2011. Bacillus subtilis strain FB17 can also be referred to as UD1022 or UD10- 22.

[027] Bacillus amyloliquefaciens AP-136 (NRRL B-50614 and B-50330), B. amyloliquefaciens AP-188 (NRRL B-50615 and B-50331), B. amyloliquefaciens AP-218 (NRRL B-50618), B amyloliquefaciens AP-219 (NRRL B-50619 and B-50332), B. amyloliquefaciens AP-295 (NRRL B-50620 and B-50333), B. amyloliquefaciens subsp. plantarum MBI600 (NRRL B-50595), B. mojavensis AP-209 (NRRL No. B-50616), B. pumilus INR-7 (also referred to as BU-F22 (NRRL B-50153) and BU-F33 (NRRL B -50185)), B. simplex ABU 288 (NRRL B-50340), B. solisalsi AP-217 (NRRL B-50617) are known from US 8,445,255.

[028] Jasmine acid or salts (jasmonates) or derivatives include, without limitation, potassium jasmonate, sodium jasmonate, lithium jasmonate, ammonium jasmonate, dimethylammonium jasmonate, isopropylammonium jasmonate, diolammonium jasmonate, diethyl ether, ethanol jasmonic acid methyl, jasmonic acid amide, jasmonic acid methylamide, jasmonic acid-L-amino acid (amide-linked) conjugates (for example, conjugated with L-isoleucine, L-valine, L-leucine or L-phenylalanine) , 12-oxo-phytodienic acid, coronatin, coronafacoyl-L-serine, coronafacoyl-L-threonine, 1-oxo-indanoyl-isoleucine methyl esters, 1-oxo-indanoyl-leucine methyl esters, coronalon methyl ester of the acid ( 2 - [(6-ethyl-1-oxo-indan-4-carbonyl) -amino] -3-methyl-pentanoic), linoleic acid or its derivatives and cis-jasmine, or combinations of any of the above.

[029] Humatos are humic and fulvic acids extracted from a form of lignite coal and clay, known as leonardite. Humic acids are organic acids that occur in humus and other organically derived materials such as peat and certain soft coals. They have been shown to increase the effectiveness of fertilizer in absorbing phosphate and micronutrients by plants, as well as assist in the development of the plant's root system.

[030] According to an embodiment of the inventive mixtures, the at least one biopesticide II is selected from groups L1) to L6):
L1) microbial pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activity: Ampelomyces quisqualis M-10, Aspergillus flavus NRRL 21882, Aureobasidium pullulans DSM 14940, A. pullulans DSM 14941, Bacillus amyloliquefaciens AP-136 (NRRL BRL -50614), B. amyloliquefaciens AP-188 (NRRL B-50615), B. amyloliquefaciens AP-218 (NRRL B-50618), B. amyloliquefaciens AP-219 (NRRL B-50619), B. amyloliquefaciens AP-295 ( NRRL B -50620), B. amyloliquefaciens IT-45 (CNCM I-3800, NCBI 1091041), B. amyloliquefaciens subsp. plantarum MBI600 (NRRL B-50595), B. mojavensis AP-209 (NRRL No. B-50616), B. pumilus INR-7 (also referred to as BU-F22 (NRRL B-50153) and BU-F33 (NRRL B -50185)), B. pumilus KFP9F, B. pumilus QST 2808 (NRRL B 30087), B. pumilus GHA 181, B. simplex ABU 288 (NRRL B-50340), B. solisalsi AP-217 (NRRL B- 50617 ), B. subtilis CX-9060, B. subtilis GB03, B. subtilis GB07, B. subtilis QST-713 (NRRL B-21661), B. subtilis var. amyloliquefaciens FZB23, B. subtilis var. amyloliquefaciens D747, Candida oleophila I-82, C. oleophila O, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans CON / M / 91-08, Cryphonectria parasitica, Cryptococcus albidus, Fusarium oxysporum, Clonostachys rosea f. catenulata J1446 (also called Gliocladium catenulatum), Gliocladium roseum 321U, Metschnikowia fructicola, Microdochium dimerum, Paenibacillus polymyxa PKB1 (ATCC n ° 202127), Pantoea agglomerans c91, Phlebiopsis gigantea, PseudoCycosa, Pysema Streptomyces lvdicus WYEC 108, S. violaceusniger XL-2, S. violaceusniger YCED-9, Talaromyces flavus V117b, Trichoderma asperellum T34, T. asperellum SKT-1, T. atroviride LC52, T. fertile JM41R, T. gamsii, T. harmatum TH 382, T. harzianum TH-35, T. harzianum T-22, T. harzianum T-39 ,; mixture of T. harzianum ICC012 and T. viride ICC080; mixture of T. polysporum and T. harzianum; T. stromaticum, T. virens (also named Gliocladium virens) GL-21, T. virens G41, T. viride TV1, Typhula phacorrhiza 94671, Ulocladium oudema, U. oudemansii HRU3, Verticillium dahlia, zucchini yellow mosaic virus (strain non-virulent);
L2) biochemical pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activity: chitosan (hydrolysis), laminarin, Menhaden fish oil, natamycin, Plum pox virus cover protein, Reynoutria sachlinensis extract, salicylic acid, tea tree oil;
L3) microbial pesticides with insecticidal, acaricidal, molluscicidal and / or nematicidal activity: Agrobacterium radiobacter K1026, A radiobacter K84, Bacillus firmus I-1582, B. thurin-giensis ssp. israelensis SUM-6218, B. t. ssp. galleriae SDS-502, B. t. ssp. kurstaki SB4, Beauveria bassiana GHA, B. bassiana H123, B. bassiana DSM 12256, B. bassiana PPRI 5339, Burkholderia sp. A396, Chromobacterium subtsugae PRAA4-1T, isolated from Cydia pomonella granulose virus V22, Isaria fumosorosea Apopka-97, Lecanicillium longisporum KV42, L. longisporum KV71, L. muscarium (formerly Verticillium lecanii), Metarhizium anisopliae FI5 FI-1045, M. anisopliae F52, M. anisopliae ICIPE 69, M. anisopliae var. acridum IMI 330189, Paecilomyces fumosoroseus FE 9901, P. lilacinus DSM 15169, P. lilacinus BCP2, Paenibacillus poppiliae Dutky-1940 (NRRL B-2309 = ATCC 14706), P. poppiliae KLN 3, P. poppiliae Dutky 1, Pasteuria spp. Ph3, P. nishizawae PN-1, P. reneformis Pr-3, P. usagae, Pseudomonas fluorescens CL 145A, Steinernema carpocapsae, S. feltiae, S. kraussei L137, Streptomces galbus;
L4) biochemical pesticides with insecticidal, acaricidal, molluscicidal, pheromone and / or nematicidal activity: L-carvone, citral, (E, Z) -7,9-dodecadien-1-yl acetate, ethyl format, (E decadenoate) , Z) -2,4-ethyl (pear ester), (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulil senecioate, 2-methyl 1-butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, (E, Z) -2,13-octadecadien-1-ol, (E, Z) -3,13 -octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E, Z, Z) acetate -3,8,11-tetradecatrienyl acetate (Z, E ) -9,12-tetradecadien-1-yl, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecen-1-ol, black wattle extract, grapefruit seed and pulp extract, Chenopodium ambrosiodae extract, Catnip oil, Neem oil, Quillay extract, Tagetes oil;
L5) microbial pesticides with plant stress reducing activity, plant growth regulator, plant growth promoter and / or yield promoter: Azospirillum amazonense BR 11140 (SpY2T), A. brasilense AZ39, A. brasilense XOH, A. brasilense BR 11005 (Sp245), A. brasilense BR 11002, A. lipoferum BR 11646 (Sp31), A. irakense, A. halopraeferens, Bradyrhizobium sp. PNL01, B. sp. (Arachis) CB1015, B. sp. (Arachis) USDA 3446, B. sp. (Arachis) SEMIA 6144, B. sp. (Arachis) SEMIA 6462, B. sp. (Arachis) SEMIA 6464, B. sp. (Vigna), B. elkanii SEMIA 587, B. elkanii SEMIA 5019, B. elkanii U-1301, B. elkanii U-1302, B. elkanii USDA 74, B. elkanii USDA 76, B. elkanii USDA 94, B. elkanii USDA 3254, B. japonicum 532c, B. japonicum CPAC 15, B. japonicum E-109, B. japonicum G49, B. japonicum TA-11, B. japonicum USDA 3, B. japonicum USDA 31, B. japonicum USDA 76, B. japonicum USDA 110, B. japonicum USDA 121, B. japonicum USDA 123, B. japonicum USDA 136, B. japonicum SEMIA 566, B. japonicum SEMIA 5079, B. japonicum SEMIA 5080, B. liaoningense, B. Lupini LL13, B. Lupini WU425, B. Lupini WSM471, B. Lupini WSM4024, Glomus intraradices RTI-801, Mesorhizobium sp. WSM1271, M. sp. WSM1497, M. ciceri CC1192, M. huakii, M. loti CC829, M. loti SU343, Paenibacillus alvei NAS6G6, Penicillium bilaiae, Rhizobium leguminosarum bv. phaseolii, R. l. trifolii, R. l. bv. viciae SU303, R. l. bv. viciae WSM1455, Sinorhizobium meliloti MSDJ0848 (INRA, France);
L6) biochemical pesticides with plant stress reducing activity, regulating plant growth and / or promoting plant yield: abscisic acid, aluminum silicate (kaolin), 3 decen-2-one, homobrassinlide, humatos, methyl jasmonate , cis-jasmine, lysophosphatidyl ethanlamine, polymeric polyhydroxy acid, salicylic acid, Ascophyllum nodosum extract (Norwegian kelp, brown kelp) and Ecklonia maxima extract (kelp).

[031] It is preferred that the mixtures comprise as component 4) fungicidal compounds that are independently of each other, selected from groups A), B), C), D), E), F), G), H ), I), J), K) and L).

[032] According to another embodiment of the invention, the mixtures comprise, as compound IV (component 4), a herbicidal compound that is selected from the group N), in particular glyphosate.

[033] According to another embodiment, the mixtures comprise, as compound IV (component 4), an insecticidal compound that is selected from the group O).

[034] Preference is also given to mixtures which comprise, as compound IV (component 4), at least one active substance selected from group A) and, in particular, selected from dimoxystrobin, cresoxime-methyl, orisastrobin, picoxystrobin , pyraclostrobin; famoxadone, phenamidone; benzovindiflupyr, bixafen, fluopiram, isopyrazam, penflufen, pentiopirad, silkxane; ametoctradin, cyazofamide, phentin salts, such as fentin acetate.

[035] Preference is also given to mixtures comprising, as compound IV (component 4), at least one active substance selected from group B) and in particular selected from cyproconazole, diphenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafolol , metconazole, miclobutanil, penconazole, propiconazole, protioconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, fenarimol, triforin; dodemorf, fenpropimorf, tridemorf, fenpropidin, spiroxamine; fenexamide.

[036] Preference is also given to mixtures comprising, as compound IV (component 4), at least one active substance selected from group C) and in particular selected from metalaxyl, (metalaxyl-M) mefenoxam, ofurace.

[037] Preference is also given to mixtures comprising, as compound IV (component 4), at least one active substance selected from group D) and in particular selected from benomyl, carbendazim, thiophanate-methyl, etaboxam, fluopicolide , zoxamide, metrafenone, pyriophenone.

[038] Preference is also given to mixtures that comprise, as compound IV (component 4), at least one active substance selected from the group E) and in particular selected from cyprodinil, mepanipirim, pyrimethanil.

[039] Preference is also given to mixtures that comprise, as compound IV (component 4), at least one active substance selected from the group F) and in particular selected from iprodione, fludioxonil, vinclozolin, quinoxifene.

[040] Preference is also given to mixtures comprising, as compound IV (component 4), at least one active substance selected from the group G) and in particular selected from dimetomorf, flumorf, iprovalicarb, bentiavalicarb, mandipropamide, propamocarb .

[041] Preference is also given to mixtures that comprise, as component 4), at least one active substance selected from the group H) and in particular selected from copper acetate, copper hydroxide, copper oxychloride, sulfate copper, sulfur, mancozeb, methram, propineb, thiram, captafol, folpet, chlorothalonil, diclofluanid, dithianone.

[042] Preference is also given to mixtures which comprise, as compound IV (component 4), at least one active substance selected from group I) and in particular selected from carpropamide and phenoxanil.

[043] Preference is also given to mixtures comprising, as compound IV (component 4), at least one active substance selected from the group J) and in particular selected from acibenzolar-S-methyl, probenazole, thiadinyl, fosetyl , fosetil-aluminum, H3PO3 and their salts.

[044] Preference is also given to mixtures comprising, as compound IV (component 4), at least one active substance selected from the group K) and in particular selected from cymoxanil, proquinazide and W-methyl-2- { 1 - [(5-methyl-3-trifluoromethiMH-pyrazM-yl) -acetyl] -piperidin-4-yl} -N - [(1R) -1,2,3,4-tetrahydronaphthalen-1-yl] -4 -thiazolcarboxamide.

[045] The present invention also relates to agrochemical compositions comprising a mixture comprising, as component 4), at least one biopesticide selected from the group L), in particular at least one more fungicidal biopesticide selected from the groups L1 ) and L2), as described above, and if desired, at least one suitable helper.

[046] Preference is also given to mixtures comprising, as biopesticide IV (component 4), a biopesticide group L1), preferably selected from Bacillus amyloliquefaciens AP-136 (NRRL B-50614 and B-50330), B. amyloliquefaciens AP-188 (NRRL B-50615 and B-50331), B. amyloliquefaciens AP-218 (NRRL B-50618), B. amyloliquefaciens AP-219 (NRRL B-50619 and B-50332), B. amyloliquefaciens AP- 295 (NRRL B-50620 and B-50333), B. amyloliquefaciens IT-45 (CNCM I-3800, NCBI 1091041), B. amyloliquefaciens subsp. plantarum MBI600 (NRRL B-50595), B. mojavensis AP-209 (NRRL No. B-50616), B. pumilus INR-7 (also referred to as BU-F22 (NRRL B-50153) and BU-F33 (NRRL B -50185)), B. pumilus KFP9F, B. pumilus QST 2808 (NRRL B 30087), B. pumilus GHA 181, B. simplex ABU 288 (NRRL B-50340), B. solisalsi AP-217 (NRRL B- 50617 ), B. subtilis CX-9060, B. subtilis GB03, B. subtilis GB07, B. subtilis QST-713 (NRRL B-21661), B. subtilis var. FZB23 amyloliquefaciens, B. subtilis var. amyloliquefaciens D747, Paenibacillus alvei NAS6G6, Paenibacillus polymyxa PKB1 (ATCC No. 202127), Sphaerodes mycoparasitica IDAC 30100801 and Trichoderma fertile JM41R, even more preferably from Bacillus amyloliquefaciens AP-136 (136), (NRRL B-50615), B. amyloliquefaciens AP-218 (NRRL B-50618), B. amyloliquefaciens AP-219 (NRRL B-50619), B. amyloliquefaciens AP-295 (NRRL B-50620), B. amyloliquefaciens IT -45 (CNCM I-3800, NCBI 1091041), B. mojavensis AP-209 (NRRL No. B-50616), B. pumilus INR-7 (also referred to as BU-F22 (NRRL B-50153) and BU-F33 (NRRL B-50185)), B. pumilus QST 2808 (NRRL B-30087), B. simplex ABU 288 (NRRL B-50340), B. subtilis QST-713 (NRRL B-21661), B. subtilis MBI600 ( NRRL B-50595), Paenibacillus alvei NAS6G6, Sphaerodes mycoparasitica IDAC 301008-01 and Trichoderma fertile JM41R.

[047] Preference is also given to mixtures comprising, as biopesticide IV (component 4), a biopesticide from the L2 group), preferably selected from chitosan (hydrolyzate), methyl-jasmonate, cis-jasmine, laminarin, extract Reynoutria sachlinensis and tea tree oil.

[048] Preference is also given to mixtures comprising, as biopesticide II (component 3), a biopesticide from the L3 group), preferably selected from Agrobacterium radiobacter K1026, Bacillus firmus I-1582, Bacillus thuringiensis ssp. kurstaki SB4, Beauveria bassiana GHA, B. bassiana h123, B. bassiana DSM 12256, B. bassiana PPRI 5339, Metarhizium anisopliae var. acridum IMI 330189, M. anisopliae FI-985, M. anisopliae FI-1045, M. anisopliae F52, M. anisopliae ICIPE 69, Paecilomyces lilacinus DSM 15169, P. lilacinus BCP2, Paenibacillus poppiliae Dutky-1940 (NRRL B-2309 = ATCC 14706), P. poppiliae KLN 3 and P. poppiliae Dutky 1, even more preferably from Bacillus thuringiensis ssp. kurstaki SB4, B. bassiana DSM 12256, B. bassiana PPRI 5339, Metarhizium anisopliae var. acridum IMI 330189, M. anisopliae FI-985, M. anisopliae FI-1045, Paecilomyces lilacinus DSM 15169, P. lilacinus BCP2, Paenibacillus poppiliae Dutky-1940 (NRRL B-2309 = ATCC 14706), P. poppiliae KLN 3 and P poppiliae Dutky 1.

[049] Preference is also given to mixtures comprising, as biopesticide II (component 2), a biopesticide from the L4 group), preferably selected from methyl jasmonate, black wattle extract, seed extract and grapefruit pulp, oil of catnip, Neem oil, Quillay extract and Tagetes oil.

[050] Preference is also given to mixtures that comprise, as biopesticide IV (component 4), a biopesticide from the L5 group), preferably selected from Azospirillum amazonense BR 11140 (SpY2T), A. brasilense XOH, A. brasilense BR 11005 (Sp245), A. brasilense BR 11002, A. lipoferum BR 11646 (Sp31), A. irakense, A. halopraeferens, Bacillus amyloliquefaciens AP-136 (NRRL B-50614), Bradyrhizobium sp. (Vigna), B. japonicum USDA 3, B. japonicum USDA 31, B. japonicum USDA 76, B. japonicum USDA 110, B. japonicum USDA 121, Glomus intraradices RTI-801, Paenibacillus alvei NAS6G6, Penicillium bilaiae, Rhizobium leguminosarum bv . phaseolii, R. l. trifolii, R. l. bv. viciae and Sinorhizobium meliloti, most preferably selected from Azospirillum brasilense BR 11005 (Sp245), Bradyrhizobium sp. (Vigna), B. japonicum USDA 3, B. japonicum USDA 31, B. japonicum USDA 76, B. japonicum USDA 110, B. japonicum USDA 121, Rhizobium leguminosarum bv. phaseolii, R. l. trifolii, R. l. bv. viciae SU303, R. l. bv. viciae WSM1455 and Sinorhizobium meliloti.

[051] Preference is also given to mixtures comprising, as biopesticide IV (component 4), a biopesticide from the L6 group), preferably selected from abscisic acid, aluminum silicate (kaolin), humatos, Ascophyllum nodosum extract ( Norwegian kelp, brown kelp) and Ecklonia maxima extract (kelp).

[052] Mixtures of the invention containing, as biopesticide IV, a microbial pesticide from groups L1), L3) and L5) can be formulated as an inoculant for a plant. The term "inoculant" means a preparation that includes a culture isolated from a microbial pesticide, and optionally a carrier, which can include a biologically acceptable medium.

[053] The mixtures and compositions according to the invention are suitable as fungicides. They are distinguished by exceptional efficacy against a broad spectrum of phytopathogenic fungi, including soil fungi, which mainly derive from the classes of Plasmodiophoromycetes, Peronosporomycetes (syn. Oomycetes), Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes and Deuteromycetes (syn. . Some are systemically effective and can be used to protect crops such as foliar fungicides, fungicides for seed treatment and soil fungicides. In addition, they are suitable for the control of harmful fungi, which occur, inter alia, in wood or plant roots.

[054] The mixtures and compositions according to the invention are particularly important for the control of a wide variety of pathogenic fungi in various cultivated plants, such as cereals, for example, wheat, rye, barley, triticale, oats or rice; beet, for example, sugar beet or fodder beet; fruits such as pomes, stone fruits and soft fruits, for example, apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries, blackberries or cassis; legumes, such as lentils, peas, alfalfa or soy; oil plants, such as rapeseed, mustard, olives, sunflowers, coconut, cocoa, castor oil, palm, peanut or soy; cucurbits, such as pumpkins, cucumbers or melons; fibrous plants, such as cotton, linen, hemp or jute; citrus fruits, such as oranges, lemons, grapefruits or mandarins; vegetables, such as spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, cucurbits or peppers; lauraceae, such as avocado, cinnamon or camphor; energy and raw material plants, such as corn, soybeans, rapeseed, sugar cane or palm oil; corn; tobacco; nuts; coffee; tea; bananas; vines (table grapes and grape juice, grape vines); hop; peat; natural rubber plants or ornamental and forest plants, such as flowers, shrubs, broadleaf or evergreen trees, for example, conifers; and plant propagation material, such as seeds, and harvest material from these plants.

[055] Preferably, inventive mixtures and compositions are used to control a large amount of fungi in field crops, such as potatoes, beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soy, rapeseed, legumes, sunflower, coffee or sugar cane; fruits; vines; ornamental plants; or vegetables, such as cucumbers, tomatoes, beans or pumpkins. Even more preferably, the mixtures and compositions of the invention are used to control a multiplicity of fungi in soy.

[056] The term "plant propagating material" should be understood as designating all the plant's producing parts, such as seeds and vegetative plant material such as cuttings and tubers (for example, potatoes), which can be used for multiplication This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, shoots and other parts of plants, including seedlings and young plants, which must be transplanted after germination or after emergence from the soil. protected before transplantation by total or partial treatment by immersion or deposition.

[057] Preferably, the treatment of plant propagation materials with the inventive combination of compound I, compound II and fluazinam as defined herein, and their compositions, respectively, is used to control a large number of fungi in cereals, such as wheat , rye, barley and oats; rice, corn, cotton and soy.

[058] The term "cultivated plants" is to be understood as including plants that have been modified by reproduction, mutagenesis or genetic engineering, including, but not limited to agricultural biotechnology products on the market or in development (cf. http: // cera -gmc.org/, see the database of GM crops there.) Genetically modified plants, whose genetic material has thus been modified through the use of recombinant DNA techniques that, under natural circumstances, cannot be easily obtained by crossing, mutating or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant. These genetic modifications include, but are not limited to, the targeted post-transitional modification of protein (s), oligo- or polypeptides, for example, by glycosylation or additions of polymers, such as prenylated, acetylated or farnesylated portions or PEG portions.

[059] The mixtures and compositions of the invention are particularly suitable for controlling the following plant diseases:

[060] Albugo spp. (white rust) in ornamental plants, vegetables (for example, A. candida) and sunflowers (for example, A. tragopogonis); Alternaria spp. (Alternaria spot) on vegetables, rapeseed (A. brassicola or brassicae), beet (A. tenuis), fruits, rice, soy, potatoes (for example, A. solani or A. alternata), tomatoes (for example, A solani or A. alternata) and wheat; Aphanomyces spp. in beets and vegetables; Ascochyta spp. in cereals and vegetables, for example, A. tritici (anthracnose) in wheat and A. hordei in barley; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.) in corn (for example, D. maydis), cereals (for example, B. sorokiniana: brown spot), rice (for example, B. oryzae) and peat; Blumeria (formerly Erysiphe) graminis (powdery mildew) in cereals (for example, wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: gray mold) in fruits and berries (for example, strawberries), vegetables (for example, lettuce, carrots, celery and cabbage), rapeseed, flowers, vines, forest plants and wheat; Bremia lactucae (downy mildew) on lettuce;

[061] Ceratocystis (syn. Ophiostoma) spp. (putrefaction or loss of vigor) in broad-leaved and evergreen trees, for example, C. ulmi (Dutch elm disease) in elm trees; Cercospora spp. (Cercospora leaf spots) on maize, rice, sugar beet (for example, C. beticola), sugar cane, vegetables, coffee, soy (for example, C. sojina or C. kikuchii) and rice; Cladosporium spp. in tomatoes (for example, C. fulvum: leaf mold) and cereals, for example, C. herbarum (black ear) in wheat; Claviceps purpurea (ergot) in cereals; Cochliobolus (anamorph: Helminthosporium de Bipolaris) spp. (leaf spots) on corn (C. carbonum), cereals (for example, C. sativus, anamorph: B. sorokiniana) and rice (for example, C. miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) on cotton (for example, C. gossypii), corn (for example, C. graminicola), soft fruits, potatoes (for example, C. coccodes: black dot), beans (for example, C. lindemuthianum) and soy (for example, C. truncatum or C gloeosporioides); Corticium spp., For example, C. sasakii (sheath burning) in rice; Corynespora cassiicola (leaf spots) in soybean and ornamental plants; Cycloconium spp., For example, C. oleaginum in olive trees; Cylindrocarpon spp. (for example, gangrene of the fruit tree or decline of the young vine, teleomorph: Nectria or Neonectria spp.) in fruit trees, vines (for example, C. liriodendri, teleomorph: Neonectria liriodendri: Black foot disease) and ornamental plants; Dematophora (teleomorph: Rosellinia) necatrix (stem and root spot) in soybean; Diaporthe spp., For example, D. phaseolorum (tipping) in soybeans; Drechslera (Syn. Helminthosporium, teleomorph: Pyrenophora) spp. in corn, cereals, such as barley (for example, D. teres, reticular spot) and wheat (for example, D. tritici-repentis: sun spot), rice and peat; Esca (perishing, apoplexy) on vines, caused by Formitiporia (syn Phellinus.) Punctata, F mediterranea, Phaeomoniella chlamydospora (formerly Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and / or Botryosphaeria obtusa; Elsinoe spp. in pomoideas (E. pyri), red fruits (E. veneta: anthracnose) and vines (E. ampelina: anthracnose); Entyloma oryzae (leaf charcoal) in rice; Epicoccum spp. (black mold) in wheat; Erysiphe spp. (powdery mildew) on beet (E. betae), vegetables (for example, E. pisi), such as cucurbits (for example, E. cichoracearum), cabbages, rapeseed (for example, E. cruciferarum); Eutypa lata (Eutypa gangrema or perishing, anamorphic: Cytosporina lata, syn Libertella blepharis) in fruit trees, vineyards and ornamental forests; Exserohilum (syn. Helminthosporium) spp. in corn (for example, E. turcicum); Fusarium (teleomorph: Gibberella) spp. (loss of vigor, root rot or stem) in various plants, such as F graminearum or F culmorum (root rot, scab or gibberellas) in cereals (for example, wheat or barley), F oxysporum in tomatoes, F solani in soy and F verticillioides in corn; Gaeumannomyces graminis (take-all) in cereals (for example, wheat or barley) and corn; Gibberella spp. in cereals (for example, G. zeae) and rice (for example, G. fujikuroi: Bakanae disease); Glomerella cingulata in vines, pome and other plants and G. gossypii in cotton; Grainstaining complex in rice; Guignardia bidwellii (black rot) on vines; Gymnosporangium spp. in plants and pink junipers, for example, G. sabinae (rust) in pears; Helminthosporium spp. (syn Drechslera, teleomorph: Cochliobolus) in corn, cereals and rice; Hemileia spp., For example, H. vastatrix (coffee leaf rust) in coffee; Isariopsis clavispora (syn. Cladosporium vitis) on vines; Macrophomina phaseolina (Syn phaseoli) (stem and root stain) in soybeans and cotton; Microdochium (Syn. Fusarium) nivale (pink snow mold) in cereals (for example, wheat or barley); Microsphaera diffusa (powdery mildew) in soybean; Monilinia spp., For example, M. laxa, M. fructicola and M. fructigena (flowering and branch rust, brown rot) in stone fruits and other rose plants; Mycosphaerella spp. in cereals, bananas, soft fruits and peanuts, such as M. graminicola (anamorph: Septoria tritici, Septoria stain) in wheat or M. fijiensis (black Sigatoka disease) in bananas; Peronospora spp. (downy mildew) on cabbage (for example, P brassicae), rapeseed (for example, P parasitic), onions (for example, P destructor), tobacco (P tabacin) and soy (for example, P manshurica); Phakopsora pachyrhizi and P meibomiae (soybean rust) in soybean culture; Phialophora spp., For example, on vines (for example, P tracheiphila and P. tetraspora) and soy (for example, P gregata: stem rot); Phoma lingam (root and stem rot) in rapeseed and cabbage and P betae (root rot, leaf spots and tipping) in beet; Phomopsis spp. in sunflowers, vines (for example, P viticola: can and leaf spot) and soy (for example stem rot: P phaseoli, teleomorph: Diaporthe phaseolorum); Physoderma maydis (brown spots) in corn; Phytophthora spp. (loss of vigor, root rot, leaves, fruits and stem) in various plants, such as peppers and cucurbits (for example, P capsici), soy (for example, P megasperma, Syn. P soye), potatoes and tomatoes ( for example, P infestans: late blight) and broadleaf trees (for example, P ramorum: sudden death of the oak); Plasmodiophora brassicae (club root) on kale, rapeseed, radish and other plants; Plasmopara spp., For example, P viticola (grape downy mildew) on vines and P halstedii on sunflowers; Podosphaera spp. (powdery mildew) in rose plants, hops, pomes and soft fruits, for example, P leucotricha in apples; Polymyxa spp., For example, in relation to cereals, such as barley and wheat (P graminis) and beet (P betae) and, therefore, transmitted viral diseases;

[062] Pseudocercosporella herpotrichoides (bed, teleomorph: Tapesia yallundae) in cereals, for example, wheat or barley; Pseudoperonospora (downy mildew) in various plants, for example, P. cubensis in cucurbits or P humili on hops; Pseudopezicula Tracheiphila (red fire disease or ‘rotbrenner’, anamorph: Phialophora) on vines; Puccinia spp. (rust) in various plants, for example, P triticin (brown or leaf rust), P striiformis (yellow stripe or rust), P hordei (dwarf rust), P graminis (stem or black rust) or P recondite (brown rust) or foliar) in cereals, such as wheat, barley or rye, and asparagus (P asparagi, for example); Pyrenophora (anamorph: Drechslera) tritici-repentis (sun spot) in wheat or P teres (reticular spot) in barley; Pyricularia spp., For example, P oryzae (teleomorph: Magnaporthe grisea, blast) in rice and P grisea in peat and cereals; Pythium spp. (tipping) in peat, rice, corn, wheat, cotton, rapeseed, sunflower, soy, beet, vegetables and various other vegetables (for example, P ultimum or P aphanidermatum); Ramularia spp., For example, R. collo-cygni (Ramularia leaf spots, physiological leaf spots) in barley and R. beticola in beet; Rhizoctonia spp. in cotton, rice, potatoes, peat, maize, rapeseed, potatoes, beets, vegetables and several other plants, for example, R. solani (stem and root rot) in soybean, R. solani (sheath burning) in rice or R. cerealis (Rhizoctonia spring rust) in wheat or barley; Rhizopus stolonifer (black mold, soft rot) in strawberries, carrots, cabbage, vines and tomatoes; Rhynchosporium secalis (scald) in barley, rye and triticale; Sarocladium oryzae and S. attenuatum (sheath rot) in rice; Sclerotinia spp. (stem rot or white mold) in vegetables and field crops, such as rapeseed, sunflowers (for example, S. sclerotiorum) and soy (for example, S. rolfsii or S. sclerotiorum); Septoria spp. in various plants, for example, S. glycines (brown spot) in soy, S. tritici (Septoria spot) in wheat and S. (syn Stagonospora) nodorum (Stagonospora spot) in cereals; Uncinula (syn Erysiphe.) Necator (powdery mildew, anamorph: Oidium tuckeri) on vines; Setospaeria spp. (leaf burning) in maize (for example, S. turcicum, syn. Helminthosporium turcicum) and peat; Sphacelotheca spp. (coal) in corn, (for example, S. reiliana: smut head), sorghum and sugar cane; Sphaerotheca fuliginea (powdery mildew) in cucurbits; Spongospora subterranea (powdery mange) in potatoes and viral diseases, thus transmissible; Stagonospora spp. in cereals, for example, S. nodorum (Stagonospora spot, teleomorph: Leptosphaeria [syn. Phaeosphaeria] nodorum) in wheat; Synchytrium endobioticum in potatoes (potato wart disease); Taphrina spp., For example, T. deformans (leaf curl disease) in peaches and T. pruni (plum pocket) in plums; Thielaviopsis spp. (black root rot) in tobacco, pome, vegetables, soy and cotton, for example, T basicola (syn. Chalara elegans); Tilletia spp. (common bowl or smelly smut) in cereals such as, for example, T. tritici (syn. T. caries, wheat bowl.) and controversial T. (dwarf bowl) in wheat; Typhula incarnata (gray snow mold) in barley or wheat; Urocystis spp., For example, U. occulta (stem smut) in rye; Uromyces spp. (rust) in vegetables, such as beans (for example, U. appendiculatus, syn. U. phaseoli) and beets (for example, U. betae); Ustilago spp. (loose smut) in cereals (for example, U. nuda and U. avaenae), corn (for example, U. maydis: corn smut) and sugar cane; Venturia spp. (scabies) in apples (for example, V. inaequalis) and pears; and Verticillium spp. (badly withered) in various vegetables, such as fruits and ornamental plants, vines, soft fruits, vegetables and field crops, for example, V. dahliae in strawberries, rapeseed, potatoes and tomatoes. Preferably, the mixtures and compositions of the invention are used to control Sclerotinia spp. (stem rot or white mold) in vegetables and field crops, such as rapeseed, sunflowers (for example, S. sclerotiorum) and soy (for example, S. rolfsii or S. sclerotiorum). More preferably, inventive mixtures and compositions are used to control Sclerotinia sclerotiorum (white mold) in vegetables and field crops, such as rapeseed, sunflower and soy; in particular, soy.

[063] Plant propagation materials can be treated with the mixtures and compositions of the invention, prophylactically on or before planting or transplanting.

[064] The invention also relates to agrochemical compositions comprising an auxiliary and at least one inhibitor of complex II, pyraclostrobin and fluazinam according to the invention.

[065] An agrochemical composition comprises a fungicidally effective amount of a complex II inhibitor, pyraclostrobin and fluazinam.
The term "effective amount" means an amount of the composition or mixtures according to the invention, which is sufficient to combat harmful fungi in cultivated plants or to protect materials and which does not result in substantial damage to the treated plants. this amount can vary over a wide range and depends on several factors, such as the species of fungi to be controlled, the plant or cultivated material treated, the climatic conditions and the specific mixture used.

[066] Components 1), 2) and 3) can be converted into usual types of agrochemical compositions, for example, solutions, emulsions, suspensions, dust, powders, pastes, granules, presses, capsules, and mixtures thereof. Examples of types of composition are suspensions (for example, SC, OD, FS), emulsifiable concentrates (for example, EC), emulsions (for example, EW, EO, ES, ME), capsules (for example, CS, ZC) , pastes, tablets, wettable powder or dust (for example, WP, SP, WS, DP, DS), pressed (for example, BR, TB, DT), granules (for example, WG, SG, GR, FG, GG , MG), insecticidal articles (for example, LN), as well as gel formulations for the treatment of plant propagation materials, such as seeds (for example, GF). These and other types of compositions are defined in the "Catalog of pesticide formulation types and international coding system”, Technical Monograph No. 2, 6th Ed. May 2008, CropLife International.

[067] The compositions are prepared in a known manner, as described by Mollet and Grubemann, Formulation Technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T & F Informa, London, 2005.

[068] Suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, humidifiers, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesives, thickeners, humectants, repellents, attractants, stimulants feed, compatibilizing agents, bactericides, antifreeze agents, antifoam agents, dyes, tackiness agents and binders.

[069] Suitable solvents and liquid carriers are water and organic solvents, such as medium to high boiling mineral oil fractions, for example, kerosene, diesel oil; vegetable or animal oils; aliphatic, cyclic and aromatic hydrocarbons, for example, toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, for example, ethanol, propanol, butanol, benzyl alcohol, cyclohexanol; glycols; DMSO; ketones, for example, cyclohexanone; esters, for example, lactates, carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphates; amines; amides, for example, N-methylpyrrolidone, fatty acid dimethylamides; and their mixtures.

[070] Suitable solid carriers or fillers are mineral soils, for example, silicates, silica gels, talc, kaolin, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate , magnesium oxide; polysaccharides, for example, cellulose, starch; fertilizers, for example, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, for example, cereal flour, tree bark, wood flour, nutshell flour, and mixtures thereof.

[071] Suitable surfactants are surface active compounds, such as anionic, cationic, non-ionic and amphoteric surfactants, block polymers, polyelectrolytes and their mixtures. Such surfactants can be used as an emusifier, dispersant, solubilizer, humidifier, penetration promoter, protective colloid or an adjuvant. Examples of surfactants are listed in McCutcheon’s, Vol.1: Emulsifiers & Detergents, McCutcheon’s Directories, Glen Rock, USA, 2008 (International Ed. Or North American Ed.).

[072] Suitable anionic surfactants are alkaline, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulphonates are alkylaryl sulphonates, diphenyl sulphonates, alpha-olefin sulphonates, lignin sulphonates, fatty acid sulphonates, ethoxylated alkyl phenol sulphonates, alkoxylated aryl phenyl sulphonates, condensed naphthalene sulphonates, and dodecyl sulphate sulphides alkylnaphthalenes, sulfosuccinates or sulfosuccinates. Examples of sulfates are fatty acid and oil sulfates, ethoxylated alkylphenols, alcohols, ethoxylated alcohols, or fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates.

[073] Suitable nonionic surfactants are alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters that have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and / or propylene oxide can be used for alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or alkyl polyglycosides. Examples of polymeric surfactants are vinylpyrrolidone homo- or copolymers, vinylalcohols or vinylacetate.

[074] Suitable cationic surfactants are quaternary surfactants, for example, quaternary ammonium compounds with one or two hydrophobic groups, or salts of long chain primary amines. Suitable amphoteric surfactants are alkylbetaines and imidazolines. Suitable block polymers are block polymers of type A-B or A-B-A comprising blocks of polyethylene oxide and polypropylene oxide, or of type A-B-C comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkaline salts of polyacrylic acid or comb polymers of polyacids. Examples of polyvinylamines or polyethyleneamines.

[075] Suitable adjuvants are compounds that have negligible or even no pesticidal activity in themselves, and which improve the biological performance of the mixture on the target. Examples are surfactants, mineral or vegetable oils, and other auxiliaries. Other examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T & F Informa UK, 2006, chapter 5.

[076] Suitable tackifiers are polysaccharides (eg, xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified), polycarboxylates and silicates.

[077] Suitable bactericides are derived from bronopol and isothiazolinone, such as alkyliso-thiazolinones and benzisothiazolinones.

[078] Suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerin.

[079] Suitable antifoam agents are silicones, long-chain alcohols, and salts of fatty acids.

[080] Suitable dyes (for example, red, blue or green) are pigments with low water solubility and water soluble dyes. Examples are inorganic dyes (for example, iron oxide, titanium oxide, iron hexacyanoferrate) and organic dyes (for example, alizarin-, azo- and phthalocyanine dyes).

[081] Suitable tacking agents or binders are polyvinylpyrrolidones, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.

[082] Agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75% by weight of active substances. The active substances are used in a purity of 90% to 100%, preferably from 95% to 100% (according to the NMR spectrum).

[083] Solutions for seed treatment (LS), Suspoemulsions (SE), flowable concentrates (FS), dry treatment powders (DS), water dispersible powders for treatment of slurry (WS), water soluble powders ( SS), emulsions (ES), emulsifiable concentrates (CE) and gels (GF) are usually employed for the purposes of treating plant propagation materials, especially seeds. The compositions in question provide, after dilution of two to ten times, concentrations of active substance from 0.01 to 60% by weight, preferably from 0.1 to 40%, in ready-to-use preparations. The application can be carried out before or during sowing. Methods for applying or treating fungicidal mixtures and their compositions, respectively, in plant propagation material, especially seeds, include plaster, coating, pelletizing, dusting, immersion and methods of application in furrow of propagation material. Preferably, fungicidal mixtures or their compositions, respectively, are applied to the plant's propagating material by a method such that germination is not induced, for example, by plastering, pelletizing, coating and sprinkling seeds.

[084] When used in plant protection, the amounts of active substances (the sum of all active substances in the composition, for example, components 1) to 3)) are applied, depending on the type of effect desired, usually 0.001 to 2 kg per ha, preferably from 0.005 to 2 kg per ha, more preferably from 0.05 to 0.9 kg per ha, even more preferably from 0.1 to 0.8 kg per ha, and in particular from 0 , 25 to 0.75 kg per ha.

[085] In the treatment of plant propagating materials, such as seeds, for example, by sprinkling, coating or soaking seeds, amounts of active substance from 0.1 to 1000 g, preferably from 1 to 1000 g, more preferably from 1 at 100 g and more preferably from 5 to 100 g, per 100 kg of plant propagating material (preferably seeds) are generally required.

[086] When used to protect stored materials or products, the amount of active substance applied depends on the type of application area and the desired effect. Amounts usually applied in the protection of materials are from 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.

[087] Various types of oils, humidifiers, adjuvants, fertilizers, or micronutrients, and other pesticides (for example, herbicides, insecticides, fungicides, growth regulators, phytotoxicity protectors, biopesticides) can be added to the active substances, or the compositions that comprise them, as a premix or, if appropriate, not until just before use (tank mix). These agents can be mixed with the compositions according to the invention in a weight ratio of 1: 100 to 100: 1, preferably from 1: 10 to 10: 1.

[088] Biopesticides are typically created by growing and concentrated naturally occurring organisms and / or their metabolites, including bacteria and other microbes, fungi, viruses, nematodes, proteins, etc. They are often considered to be important components of integrated pest management (IPM) programs.

• (1) pesticidas microbianos consistem em bactérias, fungos ou vírus (e muitas vezes incluem os metabólitos que as bactérias e os fungos produzem). Nematóides entomopatogênicos são também classificados como pesticidas microbianos, embora eles sejam multicelulares.
• (2) pesticidas bioquímicos são substâncias de ocorrência natural que controlam pragas ou proporcionam outros usos de proteção a culturas como definido abaixo, mas são relativamente não-tóxico para os mamíferos.

[089] Biopesticides are divided into two main classes, microbial and biochemical pesticides:

• (1) microbial pesticides consist of bacteria, fungi or viruses (and often include the metabolites that bacteria and fungi produce). Entomopathogenic nematodes are also classified as microbial pesticides, although they are multicellular.
• (2) biochemical pesticides are naturally occurring substances that control pests or provide other crop protection uses as defined below, but are relatively non-toxic to mammals.

[090] According to an embodiment, the individual components of the composition according to the invention, as parts of a kit, or parts of a binary or ternary mixture, can be mixed by the user himself in a spray tank or any another type of container used for applications (eg seed drums, seed pelletizing machines, backpack sprayer) and other auxiliaries can be added, if applicable. Accordingly, an embodiment of the invention is a kit for the preparation of a usable pesticidal composition, the kit comprising a) a composition comprising component 1), as defined herein and at least one auxiliary; and b) a composition comprising component 2), as defined herein and at least one auxiliary; c) a composition comprising component 3) as defined herein and at least one auxiliary; and optionally d) a composition comprising a component 4) as defined herein and at least one auxiliary.

[091] The user applies the composition according to the present invention generally from a pre-dosing device, a backpack sprayer, a spray tank, a spray plan or an irrigation system. Generally, the agrochemical composition is made with water, buffer, and / or other auxiliary agents at the desired application concentration and the spray solution ready for use or the agrochemical composition according to the invention is thus obtained. Generally, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray solution are applied per hectare of useful agricultural area.

[092] Mixtures comprising at least one compound I and at least one biochemical pesticide selected from groups L2), L4) and L6), as defined herein, can be prepared as compositions comprising, in addition to the active ingredients, at least at least one inert (auxiliary) ingredient by usual means, for example, by the means given to the compositions of compounds I. With reference to the usual ingredients of such compositions, reference is made to the explanations given for the compositions containing the compounds I.

[093] According to one embodiment, the microbial pesticides selected from groups L1), L3) and L5) cover not only pure cultures, isolated from the respective micro-organism as defined herein, but also their extract free of cells, their suspensions in a culture of total broth or as a supernatant containing the metabolite or a purified metabolite obtained from a culture of whole broth of the microorganism or strain of the microorganism.

[094] According to another embodiment, microbial pesticides selected from groups L1), L3 and L5) cover not only pure cultures, isolated from the respective micro-organism as defined herein, but also an extract free from cells or at least one of its metabolites, and / or a mutant of the respective microorganism with all its identification characteristics and also a cell-free extract or at least one metabolite of the mutant.

[095] "Whole broth culture" refers to a liquid culture containing cells and media.

[096] "Supernatant" refers to the remaining liquid broth when the cells grown in the broth are removed by centrifugation, filtration, sedimentation, or other means well known in the art.

[097] The term 'cell-free extract ”refers to an extract from vegetative cells, spores and / or the entire culture broth of a microorganism comprising cellular metabolites produced by the respective microorganism that can be obtained by methods of disruption of cells known in the art, such as solvent-based application (eg, organic solvents such as alcohols, sometimes in combination with suitable salts), temperature-based, application of shear forces, cell rupture with an ultrasonicator. The desired extract can be concentrated using conventional concentration techniques, such as drying, evaporation, centrifugation or the like. Certain washing steps using organic solvents and / or water-based media can also be applied to the crude extract, preferably before use.

[098] The term 'metabolite ”refers to any compound, substance or by-product produced by a microorganism (such as fungi and bacteria) that improves plant growth, the efficiency of using plant water, the health of planta, the appearance of planta or the population of beneficial microorganisms in the soil around the activity of the plant.

[099] The term 'mutant ”refers to a microorganism obtained by direct mutant selection, but it also includes microorganisms that have still been mutagenized or otherwise manipulated (for example, by introducing a plasmid). Accordingly, the embodiments include mutants, variants and or derivatives of the respective microorganism, both artificially induced and naturally occurring mutants. For example, mutants can be induced by subjecting the microorganism to known mutagens, such as N-methyl-nitrosoguanidine, using conventional methods.

[0100] Mixtures comprising extracts and / or metabolites free of microbial pesticide cells selected from groups L1), L3) and L5) as defined herein can be prepared in the form of compositions comprising, in addition to the active ingredients, at least one ingredient inert by usual means, for example, by the means given for the compositions of compounds I. With reference to the usual ingredients of such compositions, reference is made to the explanations given for the compositions containing the compounds I.

[0101] Mixtures comprising at least one compound I and cells, spores and / or whole broth culture from at least one microbial pesticide selected from groups L1), L3) and L5) as defined herein, can be prepared in the form of compositions comprising, in addition to the active ingredients, at least one inert (auxiliary) ingredient by customary means (see, for example, HD Burges: Formulation of Microbial Biopesticides, Springer, 1998), for example, by the means given to Compositions of compounds I. The usual suitable types of such compositions are suspensions, dust, powders, pastes, granules, presses, capsules, and mixtures thereof. Examples of types of composition are suspensions (for example, SC, OD, FS), capsules (for example, CS, ZC), pastes, lozenges, powders or wettable mists (for example, WP, SP, WS, DP, DS) , pressed (for example, BR, TB, DT), granules (for example, WG, SG, GR, FG, GG, MG), insecticidal articles (for example, LN), as well as gel formulations for the treatment of material propagation of plants, such as seeds (eg GF).

[0102] In mixtures and compositions, the compound ratios (for example, compound I / compound II / fluazinam ratio) are advantageously chosen in order to produce a synergistic effect.

[0103] The term 'synergistic effect ”should be understood as referring in particular to that defined by Colby's formula (Colby, SR," Calculating synergistic and antagonistic responses of herbicide combinations ", Weeds, 15, 20-22, pp., 1967).

[0104] The term 'synergistic effect' should also be understood as referring to that defined by the application of the Tammes method, (Tammes, PML, 'Isoboles, the graphic representation of synergism in pesticides ”, Netherl. J. Plant Pathol. 70 , 1964).

[0105] The components can be used individually or already partially or completely mixed with each other to prepare the composition according to the invention. It is also possible for them to be packaged and used as a combination, such as a kit of parts.

[0106] The fungicidal action of the compositions according to the invention can be demonstrated by the tests described below.

[0107] The active compounds, separately or together, are prepared as a stock solution comprising 25 mg of active compound which is made up to 10 ml using a mixture of acetone and / or DMSO and the emulsifier Uniperol® EL (wetting agent with a emulsifying and dispersing action based on ethoxylated alkylphenols) in a solvent / emulsifier volume ratio of 99: 1. The mixture is then made up to 100 ml with water. This stock solution is diluted with the solvent / emulsifier / water mixture described to give the concentration of active compound indicated below.

[0108] The visually determined percentages of infected leaf areas are converted into efficacy in% of the untreated control.

[0109] Efficacy (E) is calculated as follows using Abbot's formula:
E = (1- α / β) · 100
α corresponds to the fungicidal infection of the treated plants in% and
β corresponds to the fungicidal infection of untreated plants (control) in%

[0110] An effectiveness of 0 means that the level of infection of the treated plants corresponds to that of the untreated control plants; an efficacy of 100 means that the treated plants have not been infected.

[0111] The expected efficiencies of combinations of active compounds in two ways were determined according to Colby's formula (Colby, SR 'Calculating synergistic and antagonistic responses of herbicide combinations ”, Weeds, 15, 20-22 pp., 1967) and compared to the observed efficiencies.
Colby's formula: E = x + y - x · y / 100
And expected effectiveness, expressed in% of untreated controls, when using the mixture of active compounds A and B in concentrations a and b
X effectiveness, expressed in% of untreated controls, when using active compound A in the concentration at
Y effectiveness, expressed in% of untreated controls, when using active compound C in concentration c.

[0112] Colby's formula can also be extended to be applied directly to mixtures in 3 ways (Colby, S.R. "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, pp. 20-22, 1967):

[0113] Colby's formula for mixtures in 3 modes:
E = x + y + z - (x · y + x · y + x · z / + y · z) / 100 - x · y · z / 10000
And expected efficacy, expressed in% of untreated controls, when using the mixture of active compounds A and B and C in concentrations a and b
X effectiveness, expressed in% of untreated controls, when using active compound A in the concentration at
y effectiveness, expressed in% of untreated controls, when using the mixture of active compound B in concentration b and active compound C in concentration c.
z efficacy, expressed in% of untreated controls, when using active compound C in concentration c.

MICROTESTS

[0114] The active compounds were formulated separately as a stock solution with a concentration of 10,000 ppm in dimethyl sulfoxide.

[0115] The product orisstrobin was used as a finished commercial formulation and diluted with water to the indicated concentration of the active compound.

[0116] The stock solutions were mixed according to the ratio, pipetted into a microtiter plate (MTP) and diluted with water to the indicated concentrations. A spore suspension of the respective pathogen was then added to the respective nutrient medium. The plates were placed in a saturated water vapor chamber at a temperature of 18 ° C. Using an absorption photometer, MTPs were measured at 405 nm 7 days after inoculation.

[0117] The measured parameters were compared with the growth of the active compound free control variant (100%) and the free blank value of active compound and fungus free to determine the relative growth in% of pathogens in the respective active compounds . These percentages were converted into efficiencies. Colby's formula for mixtures of 3 modes and 2 modes was applied as described in Weeds, 15, pp. 20-22, 1967.

EXAMPLE OF USE 1. ACTIVITY AGAINST THE PATHYGENIC AGENT PHYTOPHTHORA INFESTANS DE REQUEIMA

[0118] In this test, a spore suspension of Phytophtora infestans containing an aqueous nutrient medium based on pea juice or DDC medium was used. The results are shown here:

EXAMPLE OF USE 2. ACTIVITY AGAINST LEPTOSPHAERIA NODORUM WHICH CAUSES FOLIAR SPOTS ON WHEAT

- Boscalida + Piraclostrobina + Fluazinam

[0119] In this test, a spore suspension of Leptosphaeria nodorum was used in an aqueous bio enamel or yeast-bactopeptone-glycerin solution. The results are shown here:
- Fluxapiroxade + Piraclostrobina + Fluazinam

- Boscalide + Pyraclostrobin + Fluazinam

EXAMPLE OF USE 3. ACTIVITY AGAINST RHIZOCTONIA SOLANI THAT CAUSES STEM GANGREMA IN TOMATOES

Boscalida + Piraclostrobina + Fluazinam

[0120] In this test, a suspension of Rhizoctonia solani spores in an aqueous bio-enamel or a yeast-bacterophen-glycerin solution was used. The results are shown here:
- Fluxapiroxade + Piraclostrobina + Fluazinam

Boscalide + Pyraclostrobin + Fluazinam

EXAMPLE OF USE 4: ACTIVITY AGAINST COLLETOTRICHUM TRUNCATUM THAT CAUSES ANTHRACNOSIS IN SOY

- Boscalida + Piraclostrobina + Fluazinam

[0121] In this test, a spore suspension of Colletotrichum truncatum was then added in an aqueous isomalt or yeast-bactopeptone-glycerin solution. The results are shown here:
- Fluxapyroxade + Pyraclostrobin + Fluazinan

- Boscalide + Pyraclostrobin + Fluazinam

EXAMPLE OF USE 5: ACTIVITY AGAINST CORYNESPORA CASSIICOLA THAT CAUSES FOLIAR STAIN ON SOY

[0122] In this test, a spore suspension of Corynespora cassiicola was then added in an aqueous bio-enamel or yeast-bactopeptone-glycerin solution. The results are shown here:
- Fluxapiroxade + Piraclostrobina + Fluazinam

Claims (9)

MIXTURE, characterized by understanding how active compounds:
1) a compound I selected from fluxpyroxade or boscalide;
and
2) a compound II, selected from pyraclostrobin;
and
3) fluazinam;
wherein the weight ratio of the mixture comprising a compound (I) selected from fluxpyroxade, a compound (II) selected from pyraclostrobin and fluazinam is (1: 1: 1), (1: 4: 4), (4: 1: 1), (1: 4: 1), (1: 16: 4), (1:16:16), (16: 1: 4), (16: 1: 16) and (4 : 4: 1); or
wherein the weight ratio of the mixture comprising a compound (I) selecting from boscalide, a compound (II) selected from pyraclostrobin and fluazinam is (16: 1: 1), (4: 1: 1), (63: 4: 1), (16: 1: 4) and (63: 1: 1). MIXTURE according to claim 1, characterized in that compound I is fluxpyroxade. AGROCHEMICAL COMPOSITION, characterized by comprising an auxiliary and the mixture, as defined in any one of claims 1 to 2. SEED, characterized by being coated with the mixture, as defined in any one of claims 1 to 2, or with the composition, as defined in claim 3, in an amount of 1 g to 1000 g per 100 kg of seeds. USE OF THE MIXTURE, as defined in any one of claims 1 to 2, or of the composition, as defined in claim 3, characterized by being for combating harmful phytopathogenic fungi. USE, according to claim 5, characterized in that phytopathogenic fungi are selected from Sclerotinia spp. METHOD FOR THE CONTROL OF HARMFUL PHYTOPATHOGENIC FUNGI, characterized by understanding to treat fungi, their habitat or seeds, soil or plants to be protected from the attack of fungi with the mixture, as defined in any one of claims 1 to 2, or with the composition as defined in claim 3. METHOD, according to claim 7, characterized in that it comprises the treatment of soybean plants to be protected against fungal attack with the mixture, as defined in any one of claims 1 to 2, or with the composition, as defined in claim 3, and in which harmful phytopathogenic fungi are selected from Sclerotinia spp. METHOD, according to claim 7, characterized in that it additionally comprises the treatment of a plant, its propagation material, the place where the plant is grown or must be grown with the mixture, as defined in any one of claims 1 to 2, or with the composition, as defined in claim 3, for improving plant health.