CA2159939C - Composition adhesive et procede correspondant - Google Patents

Composition adhesive et procede correspondant Download PDF

Info

Publication number: CA2159939C
Authority: CA; Canada
Prior art keywords: styrene; composition; elastic; modulus; weight
Prior art date: 1994-10-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA 2159939

Other languages

English (en)

Other versions

CA2159939A1 (fr

Inventor

Gianfranco Palumbo

Italo Corzani

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-10-07

Filing date

1995-10-05

Publication date

2001-05-01

1995-10-05 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

1996-04-08 Publication of CA2159939A1 publication Critical patent/CA2159939A1/fr

2001-05-01 Application granted granted Critical

2001-05-01 Publication of CA2159939C publication Critical patent/CA2159939C/fr

2015-10-05 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 269
230000001070 adhesive effect Effects 0.000 title claims description 77
239000000853 adhesive Substances 0.000 title claims description 46
238000000034 method Methods 0.000 title claims description 23
230000008569 process Effects 0.000 title claims description 16
239000011347 resin Substances 0.000 claims abstract description 106
229920005989 resin Polymers 0.000 claims abstract description 106
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 104
239000000463 material Substances 0.000 claims abstract description 52
229920001577 copolymer Polymers 0.000 claims abstract description 50
239000004831 Hot glue Substances 0.000 claims abstract description 34
239000006260 foam Substances 0.000 claims abstract description 34
230000014759 maintenance of location Effects 0.000 claims abstract description 31
VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims abstract description 27
229920001400 block copolymer Polymers 0.000 claims abstract description 25
229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 25
239000004033 plastic Substances 0.000 claims abstract description 14
229920003023 plastic Polymers 0.000 claims abstract description 14
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 12
229920006132 styrene block copolymer Polymers 0.000 claims description 37
238000005187 foaming Methods 0.000 claims description 20
125000003118 aryl group Chemical group 0.000 claims description 15
239000000126 substance Substances 0.000 claims description 13
239000007788 liquid Substances 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 claims description 10
239000004014 plasticizer Substances 0.000 claims description 9
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
238000001816 cooling Methods 0.000 claims description 6
239000011261 inert gas Substances 0.000 claims description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
239000004604 Blowing Agent Substances 0.000 claims description 4
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
239000007789 gas Substances 0.000 claims description 4
229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
239000001569 carbon dioxide Substances 0.000 claims description 2
239000002666 chemical blowing agent Substances 0.000 claims description 2
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 2
230000002745 absorbent Effects 0.000 abstract description 13
239000002250 absorbent Substances 0.000 abstract description 13
239000003292 glue Substances 0.000 abstract description 4
229920001971 elastomer Polymers 0.000 description 41
230000006399 behavior Effects 0.000 description 33
238000009472 formulation Methods 0.000 description 29
239000005060 rubber Substances 0.000 description 29
239000012943 hotmelt Substances 0.000 description 18
229920001169 thermoplastic Polymers 0.000 description 18
239000004416 thermosoftening plastic Substances 0.000 description 18
239000004820 Pressure-sensitive adhesive Substances 0.000 description 17
239000000758 substrate Substances 0.000 description 17
229920000642 polymer Polymers 0.000 description 15
239000004698 Polyethylene Substances 0.000 description 13
238000012545 processing Methods 0.000 description 13
238000001125 extrusion Methods 0.000 description 12
230000000052 comparative effect Effects 0.000 description 11
239000000806 elastomer Substances 0.000 description 11
229920003052 natural elastomer Polymers 0.000 description 11
229920001194 natural rubber Polymers 0.000 description 11
230000035882 stress Effects 0.000 description 11
238000012360 testing method Methods 0.000 description 11
244000043261 Hevea brasiliensis Species 0.000 description 10
230000000694 effects Effects 0.000 description 8
239000005062 Polybutadiene Substances 0.000 description 7
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 7
239000003963 antioxidant agent Substances 0.000 description 7
230000008901 benefit Effects 0.000 description 7
229920002857 polybutadiene Polymers 0.000 description 7
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
230000003078 antioxidant effect Effects 0.000 description 6
239000002480 mineral oil Substances 0.000 description 6
235000010446 mineral oil Nutrition 0.000 description 6
-1 poly(butadiene) Polymers 0.000 description 6
239000007787 solid Substances 0.000 description 6
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 5
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
238000010586 diagram Methods 0.000 description 5
239000000178 monomer Substances 0.000 description 5
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
238000004073 vulcanization Methods 0.000 description 5
239000013032 Hydrocarbon resin Substances 0.000 description 4
239000004793 Polystyrene Substances 0.000 description 4
239000000654 additive Substances 0.000 description 4
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 4
229920005601 base polymer Polymers 0.000 description 4
238000011161 development Methods 0.000 description 4
229920006270 hydrocarbon resin Polymers 0.000 description 4
239000000155 melt Substances 0.000 description 4
229920001195 polyisoprene Polymers 0.000 description 4
229920002223 polystyrene Polymers 0.000 description 4
150000003097 polyterpenes Chemical class 0.000 description 4
238000007711 solidification Methods 0.000 description 4
230000008023 solidification Effects 0.000 description 4
GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 4
229920004939 Cariflex™ Polymers 0.000 description 3
229920013645 Europrene Polymers 0.000 description 3
229920002633 Kraton (polymer) Polymers 0.000 description 3
229920002367 Polyisobutene Polymers 0.000 description 3
229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
238000007906 compression Methods 0.000 description 3
230000006835 compression Effects 0.000 description 3
230000001419 dependent effect Effects 0.000 description 3
230000001627 detrimental effect Effects 0.000 description 3
239000013013 elastic material Substances 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000012530 fluid Substances 0.000 description 3
XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Natural products CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 3
238000005259 measurement Methods 0.000 description 3
230000004048 modification Effects 0.000 description 3
238000012986 modification Methods 0.000 description 3
239000000049 pigment Substances 0.000 description 3
229920000573 polyethylene Polymers 0.000 description 3
230000000717 retained effect Effects 0.000 description 3
229920003051 synthetic elastomer Polymers 0.000 description 3
239000005061 synthetic rubber Substances 0.000 description 3
239000000454 talc Substances 0.000 description 3
229910052623 talc Inorganic materials 0.000 description 3
235000007586 terpenes Nutrition 0.000 description 3
KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 2
GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
206010021639 Incontinence Diseases 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
229920006272 aromatic hydrocarbon resin Polymers 0.000 description 2
239000002981 blocking agent Substances 0.000 description 2
238000007664 blowing Methods 0.000 description 2
229920005549 butyl rubber Polymers 0.000 description 2
125000003636 chemical group Chemical group 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
238000010276 construction Methods 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
230000009477 glass transition Effects 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
235000001510 limonene Nutrition 0.000 description 2
229940087305 limonene Drugs 0.000 description 2
239000012768 molten material Substances 0.000 description 2
239000003921 oil Substances 0.000 description 2
239000011343 solid material Substances 0.000 description 2
150000003440 styrenes Chemical class 0.000 description 2
238000010998 test method Methods 0.000 description 2
150000000133 (4R)-limonene derivatives Chemical class 0.000 description 1
HBKBEZURJSNABK-MWJPAGEPSA-N 2,3-dihydroxypropyl (1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical class C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(=O)OCC(O)CO HBKBEZURJSNABK-MWJPAGEPSA-N 0.000 description 1
102100023444 Centromere protein K Human genes 0.000 description 1
229920000181 Ethylene propylene rubber Polymers 0.000 description 1
244000212127 Gliricidia sepium Species 0.000 description 1
235000009664 Gliricidia sepium Nutrition 0.000 description 1
241001441571 Hiodontidae Species 0.000 description 1
101000907931 Homo sapiens Centromere protein K Proteins 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
229920005830 Polyurethane Foam Polymers 0.000 description 1
230000009471 action Effects 0.000 description 1
230000004913 activation Effects 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000006664 bond formation reaction Methods 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
230000008859 change Effects 0.000 description 1
238000004040 coloring Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
230000006735 deficit Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
229920001198 elastomeric copolymer Polymers 0.000 description 1
239000013536 elastomeric material Substances 0.000 description 1
230000006355 external stress Effects 0.000 description 1
239000013020 final formulation Substances 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
238000013012 foaming technology Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
229920003049 isoprene rubber Polymers 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000010128 melt processing Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
150000004702 methyl esters Chemical class 0.000 description 1
239000012764 mineral filler Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
230000010363 phase shift Effects 0.000 description 1
239000002530 phenolic antioxidant Substances 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
239000005011 phenolic resin Substances 0.000 description 1
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920006267 polyester film Polymers 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920006146 polyetheresteramide block copolymer Polymers 0.000 description 1
235000013824 polyphenols Nutrition 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000011496 polyurethane foam Substances 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
238000012552 review Methods 0.000 description 1
239000012056 semi-solid material Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
241000894007 species Species 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
230000008961 swelling Effects 0.000 description 1
150000003505 terpenes Chemical class 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
229920000428 triblock copolymer Polymers 0.000 description 1
239000011800 void material Substances 0.000 description 1
230000003313 weakening effect Effects 0.000 description 1

Landscapes

Adhesives Or Adhesive Processes (AREA)

CA 2159939 1994-10-07 1995-10-05 Composition adhesive et procede correspondant Expired - Lifetime CA2159939C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
ITTO94A000793		1994-10-07
IT94TO000793A IT1268621B1 (it)	1994-10-07	1994-10-07	Composizione adesiva e relativo procedimento di preparazione.

Publications (2)

Publication Number	Publication Date
CA2159939A1 CA2159939A1 (fr)	1996-04-08
CA2159939C true CA2159939C (fr)	2001-05-01

Family

ID=11412812

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2159939 Expired - Lifetime CA2159939C (fr)	1994-10-07	1995-10-05	Composition adhesive et procede correspondant

Country Status (2)

Country	Link
CA (1)	CA2159939C (fr)
IT (1)	IT1268621B1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN103146216A (zh) *	2013-03-26	2013-06-12	厦门市豪尔新材料有限公司	一种高能胶制品、制备方法及其用途
US20210290818A1 (en) *	2016-03-24	2021-09-23	Locate Therapeutics Limited	Scaffolding material, methods and uses

1994
- 1994-10-07 IT IT94TO000793A patent/IT1268621B1/it active IP Right Grant
1995
- 1995-10-05 CA CA 2159939 patent/CA2159939C/fr not_active Expired - Lifetime

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN103146216A (zh) *	2013-03-26	2013-06-12	厦门市豪尔新材料有限公司	一种高能胶制品、制备方法及其用途
CN103146216B (zh) *	2013-03-26	2015-06-17	厦门市豪尔新材料有限公司	一种高能胶制品、制备方法及其用途
US20210290818A1 (en) *	2016-03-24	2021-09-23	Locate Therapeutics Limited	Scaffolding material, methods and uses

Also Published As

Publication number	Publication date
ITTO940793A1 (it)	1996-04-07
IT1268621B1 (it)	1997-03-06
CA2159939A1 (fr)	1996-04-08
ITTO940793A0 (it)	1994-10-07

Publication	Publication Date	Title
EP0802949B1 (fr)	2003-05-02	Composition adhesive, procede et appareil de production d'une telle composition et articles absorbants comprenant ladite composition adhesive
US7847022B2 (en)	2010-12-07	Articles prepared from controlled distribution block copolymers
JP3824658B2 (ja)	2006-09-20	低粘度低適用温度ホットメルト接着剤用スチレン−イソプレン−スチレンブロックコポリマー組成物
JP2000502120A (ja)	2000-02-22	ペレット状のポリマー組成物
JPH1046128A (ja)	1998-02-17	スチレン系ブロックコポリマーを基材とするホットメルト接着剤、使い捨て非耐久消費財のための該接着剤の使用、及び該接着剤中に含まれる粘着付与樹脂
US7297741B2 (en)	2007-11-20	Pressure sensitive adhesives from high molecular weight block copolymers having a high fraction of diblock copolymer
US4650829A (en)	1987-03-17	Novel hydrocarbon resins and their use in adhesives
JP6664729B2 (ja)	2020-03-13	伸縮性ホットメルト組成物
US5210147A (en)	1993-05-11	100% Triblock hydrogenated styrene-isoprene-styrene block copolymer adhesive composition
EP1576068B1 (fr)	2007-11-28	Composition adhesive pour emballage et ruban adhesif contenant cette composition
CA2159939C (fr)	2001-05-01	Composition adhesive et procede correspondant
US7037976B2 (en)	2006-05-02	Free flowing powder
CA2159934C (fr)	2002-02-12	Composition adhesive
CA2159930C (fr)	2005-01-25	Composition adhesive et procede et appareil correspondants
JPH01174550A (ja)	1989-07-11	水添ブロック共重合体組成物
CA2159933C (fr)	2000-12-19	Article absorbant
CN116082585A (zh)	2023-05-09	一种氢化苯乙烯/丁二烯烃嵌段共聚物及其应用方法
AU732686B2 (en)	2001-04-26	Adhesive composition, method and apparatus for manufacture thereof and absorbent articles comprising said adhesive composition
JP2021046540A (ja)	2021-03-25	ホットメルト組成物
CN119137208A (zh)	2024-12-13	热熔组合物
JP2021025046A (ja)	2021-02-22	伸縮性ホットメルト組成物
CA2159937A1 (fr)	1996-04-08	Procede pour conferer de l'elasticite a des articles, en particulier des articles d'hygiene personnelle, et article produit au moyen dudit procede
JPH11198288A (ja)	1999-07-27	ポリウレタン複合成形体
WO2001096491A1 (fr)	2001-12-20	Adhesif autocollant a thermoresistance elevee et a faible viscosite complexe
JPS62250088A (ja)	1987-10-30	熱可塑性伸縮テ−プ

Legal Events

Date	Code	Title	Description
1995-10-05	EEER	Examination request
2015-12-07	MKEX	Expiry	Effective date: 20151005