CA2233429A1 - Polycarbonate/graft polymer moulding compositions with reduced deposit formation - Google Patents
Polycarbonate/graft polymer moulding compositions with reduced deposit formationInfo
- Publication number
- CA2233429A1 CA2233429A1 CA002233429A CA2233429A CA2233429A1 CA 2233429 A1 CA2233429 A1 CA 2233429A1 CA 002233429 A CA002233429 A CA 002233429A CA 2233429 A CA2233429 A CA 2233429A CA 2233429 A1 CA2233429 A1 CA 2233429A1
- Authority
- CA
- Canada
- Prior art keywords
- weight
- parts
- moulding compositions
- graft polymer
- polycarbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 238000000465 moulding Methods 0.000 title abstract 5
- 229920000578 graft copolymer Polymers 0.000 title abstract 3
- 229920000515 polycarbonate Polymers 0.000 title abstract 3
- 239000004417 polycarbonate Substances 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 abstract 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 2
- 229920001169 thermoplastic Polymers 0.000 abstract 2
- 239000004416 thermosoftening plastic Substances 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000002216 antistatic agent Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 238000001746 injection moulding Methods 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 229920001897 terpolymer Polymers 0.000 abstract 1
- 239000004415 thermoplastic moulding composition Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
- B29C45/0055—Shaping
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Thermoplastic polycarbonate/graft polymer moulding compositions containing A) 5 to 95 parts by weight of an aromatic polycarbonate, B) 1 to 50 parts by weight of at least one thermoplastic homopolymer, copolymer or terpolymer of styrene, .alpha.- methylstyrene, acrylonitrile, N-substituted. maleimide or mixtures thereof, C) 1 to 50 parts by weight of at least one graft polymer of C.1) 5 to 90 parts by weight of styrene, .alpha.- methylstyrene, acrylonitrile, N-substituted. maleimide or mixtures thereof, on C.2) 95 to 10 parts by weight of a rubber with a glass transition temperature <= 0°C and D) 1 to 25 parts by weight (per 100 parts by weight A+B+C) of at least one additive selected from flame retardants, lubricants, antistatic agent, mould release agents or mixtures thereof, characterised in that the component B) is produced by bulk, solution or suspension polymerisation and has an oligomer content <= 1 wt.%, component C) is produced by emulsion polymerisation and the total oligomer content of the moulding compositions is <= 0.6 wt.%. The thermoplastic moulding compositions may be used for the production of mouldings by injection moulding and for high-gloss mouldings.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19713508.0 | 1997-04-01 | ||
| DE19713508A DE19713508A1 (en) | 1997-04-01 | 1997-04-01 | Polycarbonate / graft polymer molding compounds with reduced deposit formation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2233429A1 true CA2233429A1 (en) | 1998-10-01 |
| CA2233429C CA2233429C (en) | 2007-08-14 |
Family
ID=7825170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002233429A Expired - Fee Related CA2233429C (en) | 1997-04-01 | 1998-03-27 | Polycarbonate/graft polymer moulding compositions with reduced deposit formation |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0869149B1 (en) |
| JP (1) | JPH10279789A (en) |
| KR (1) | KR100548849B1 (en) |
| CN (1) | CN1124318C (en) |
| AR (1) | AR012215A1 (en) |
| AU (1) | AU729595B2 (en) |
| BR (1) | BR9800990A (en) |
| CA (1) | CA2233429C (en) |
| DE (2) | DE19713508A1 (en) |
| ES (1) | ES2201356T3 (en) |
| TW (1) | TW473511B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10138364B2 (en) | 2014-01-28 | 2018-11-27 | Ineos Styrolution Group Gmbh | Thermoplastic molding compounds with optimized flowability-toughness ratio |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2329639B (en) * | 1997-09-25 | 2002-02-20 | Samyang Corp | Flame retardant resin composition |
| DE19925049C5 (en) * | 1999-06-01 | 2005-12-22 | Hella Kgaa Hueck & Co. | Plastic disc of motor vehicle headlights or motor vehicle lights and method for their production |
| DE19941823A1 (en) * | 1999-09-02 | 2001-03-08 | Bayer Ag | Flame retardant polycarbonate blends |
| DE10010428A1 (en) * | 2000-03-03 | 2001-09-06 | Bayer Ag | Thermoplastic polycarbonate composition useful for making optical data-recording media, includes a hydroxylic mold release agent, a monomeric phosphorus compound and an oligomeric phosphorus compound |
| DE10027333A1 (en) * | 2000-06-02 | 2001-12-06 | Bayer Ag | Flame retardant and anti-electrostatic polycarbonate molding compounds |
| KR100372567B1 (en) * | 2000-11-13 | 2003-02-19 | 제일모직주식회사 | Permanent Anti-Static Styrene Thermoplastic Resin Composition |
| DE10255824A1 (en) * | 2002-11-29 | 2004-06-09 | Bayer Ag | Impact-modified blends |
| JP4679929B2 (en) * | 2005-02-24 | 2011-05-11 | テクノポリマー株式会社 | Infrared transparent thermoplastic resin composition and molded article using the same |
| KR100796938B1 (en) * | 2005-12-28 | 2008-01-22 | 제일모직주식회사 | Thermoplastic resin composition with low linear expansion coefficient and excellent impact resistance |
| KR100922700B1 (en) * | 2007-06-15 | 2009-10-20 | 금호석유화학 주식회사 | Low Melt Viscosity Maleimide-α-alkylstyrene Ternary Copolymer and Continuous Block Polymerization Process |
| CN101643575B (en) * | 2008-08-07 | 2011-09-28 | 比亚迪股份有限公司 | Polycarbonate composition and polycarbonate composite material formed by composition |
| CN101508835B (en) * | 2009-03-12 | 2012-08-22 | 华南理工大学 | Halogen-free flame-proof static resistant polycarbonate composition and method for producing the same |
| EP2647669A1 (en) * | 2012-04-05 | 2013-10-09 | Bayer MaterialScience AG | Impact modified polycarbonate compounds for simplified production of low temperature components with high sheen and matt component sections |
| CN104119658B (en) * | 2014-06-06 | 2016-01-13 | 宁波浙铁大风化工有限公司 | A kind of halogen-free flame-retardant PC composition and preparation method thereof |
| KR101895112B1 (en) * | 2015-12-31 | 2018-09-04 | 롯데첨단소재(주) | Rubber-modified vinyl-based graft copolymer and thermoplastic resin composition comprising the same |
| JP6270927B2 (en) * | 2016-07-08 | 2018-01-31 | 日本エイアンドエル株式会社 | Plating resin composition and plating molded product |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4068064A (en) * | 1975-12-22 | 1978-01-10 | The Dow Chemical Company | Method for preparing monovinyl aromatic monomer-acrylonitrile copolymer |
| DE2653146A1 (en) * | 1976-11-23 | 1978-05-24 | Bayer Ag | THERMOPLASTIC MOLDING COMPOUNDS |
| KR0139249B1 (en) * | 1994-09-05 | 1998-05-01 | 유현식 | Thermoplastic resin composition having flame retardancy |
-
1997
- 1997-04-01 DE DE19713508A patent/DE19713508A1/en not_active Withdrawn
-
1998
- 1998-03-17 TW TW087103875A patent/TW473511B/en not_active IP Right Cessation
- 1998-03-18 AU AU59377/98A patent/AU729595B2/en not_active Ceased
- 1998-03-19 DE DE59808568T patent/DE59808568D1/en not_active Expired - Lifetime
- 1998-03-19 EP EP98104997A patent/EP0869149B1/en not_active Expired - Lifetime
- 1998-03-19 ES ES98104997T patent/ES2201356T3/en not_active Expired - Lifetime
- 1998-03-27 CA CA002233429A patent/CA2233429C/en not_active Expired - Fee Related
- 1998-03-27 JP JP10098242A patent/JPH10279789A/en active Pending
- 1998-03-31 AR ARP980101457A patent/AR012215A1/en not_active Application Discontinuation
- 1998-03-31 KR KR1019980011257A patent/KR100548849B1/en not_active Expired - Lifetime
- 1998-04-01 BR BR9800990-7A patent/BR9800990A/en not_active Application Discontinuation
- 1998-04-01 CN CN98107003A patent/CN1124318C/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10138364B2 (en) | 2014-01-28 | 2018-11-27 | Ineos Styrolution Group Gmbh | Thermoplastic molding compounds with optimized flowability-toughness ratio |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0869149B1 (en) | 2003-06-04 |
| CN1124318C (en) | 2003-10-15 |
| EP0869149A3 (en) | 1999-09-22 |
| ES2201356T3 (en) | 2004-03-16 |
| AR012215A1 (en) | 2000-09-27 |
| CN1196364A (en) | 1998-10-21 |
| JPH10279789A (en) | 1998-10-20 |
| TW473511B (en) | 2002-01-21 |
| CA2233429C (en) | 2007-08-14 |
| AU5937798A (en) | 1998-10-08 |
| BR9800990A (en) | 1999-12-14 |
| DE19713508A1 (en) | 1998-10-08 |
| KR100548849B1 (en) | 2006-03-23 |
| KR19980080949A (en) | 1998-11-25 |
| EP0869149A2 (en) | 1998-10-07 |
| AU729595B2 (en) | 2001-02-08 |
| DE59808568D1 (en) | 2003-07-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20170327 |