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CN104051107A - Titanium-based ferrite core material used for transformer - Google Patents

Titanium-based ferrite core material used for transformer Download PDF

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Publication number
CN104051107A
CN104051107A CN201410283346.7A CN201410283346A CN104051107A CN 104051107 A CN104051107 A CN 104051107A CN 201410283346 A CN201410283346 A CN 201410283346A CN 104051107 A CN104051107 A CN 104051107A
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China
Prior art keywords
mol
core material
ferrite core
mixed
minute
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Pending
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CN201410283346.7A
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Chinese (zh)
Inventor
李新满
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongling Sanjia Transformer Co Ltd
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Tongling Sanjia Transformer Co Ltd
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Priority to CN201410283346.7A priority Critical patent/CN104051107A/en
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  • Soft Magnetic Materials (AREA)
  • Magnetic Ceramics (AREA)
  • Compounds Of Iron (AREA)

Abstract

The invention discloses a titanium-based ferrite core material used for a transformer. The titanium-based ferrite core material comprises main materials and additives. The main materials comprise, by molar ratio, 57.3 mol to 65 mol of Fe2O3, 18.5 mol to 24 mol of manganese oxide, 12.3 mol to 15 mol of zinc oxide, 0.2 mol to 0.3 mol of lithium nitride, 0.3 mol to 0.5 mol of molybdenum trioxide and 0.01 mol to 0.02 mol of rare-earth composite magnetic powder. The additives comprise, by weight ratio of components to the ferrite core material, 60 ppm to 70 ppm of chromic oxide and 50 ppm to 60 ppm of nano carbon. The rare-earth composite magnetic powder added into the titanium-based ferrite core material is high in magnetic energy product, stable in magnetism and simple in preparing method, and the finished product has the advantages of being high in crystal boundary resistivity, low in gas hole ratio and large and even in crystal particle.

Description

A kind of titanium based ferrite core material for transformer
?
Technical field
The present invention relates generally to oxidate magnetic material and manufactures field, relates in particular to a kind of titanium based ferrite core material for transformer.
Background technology
Along with the communication technology and the digitized development of electronic product; soft magnetic ferrite and element have been proposed to new requirement; high-performance high magnetic permeability magnetic core is widely used in each type telecommunications and information stock, as the fields such as common-mode filter, pulsactor, current transformer, earth leakage protective device, insulating transformer, signal and pulse transformer are widely applied.Telecommunications industry needs FERRITE CORE to have low core loss and high magnetic permeability now, and to meet microminiaturization and the high efficiency requirement of present electric equipment, existing magnetic core is difficult to meet above-mentioned requirements;
Its magnetic energy product of the permanent magnetic material that rare earth makes can reach 150 times of carbon steel, 3~5 times of Al-Ni-Co permanent magnet material, 8~10 times of permanent-magnet ferrite, and temperature coefficient is low, magnetic stability, coercive force is up to 800 kilo-ampere/rice.Be mainly used in the magnetic system of low speed torque motor, actuating motor, transducer, magnetic bearing etc.Nd-Fe-Bo permanent magnet material is third generation rare earth permanent-magnetic material, and its remanent magnetism, coercive force and maximum magnetic energy product are higher than the former, non-friable, has good mechanical performance, and alloy density is low, is conducive to lightness, slimming, the small-sized and subminaturization of magnetic element.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, and a kind of titanium based ferrite core material for transformer is provided.
The present invention is achieved by the following technical solutions:
A kind of titanium based ferrite core material for transformer, it comprises major ingredient and additive, and described major ingredient comprises according to mol ratio: the molybdenum trioxide of the zinc oxide of the Fe2O3 of 57.3-65 mol, the manganese oxide of 18.5-24 mol, 12.3-15 mol, the lithium nitride of 0.2-0.3mol, 0.3-0.5 mol, the rare earth compounded magnetic conductive powder of 0.01-0.02 mol; Additive comprises according to the weight ratio meter that accounts for described ferrite magnetic core material: the chrome green of 60-70ppm, the nano-sized carbon of 50-60ppm;
The preparation of described rare earth compounded magnetic conductive powder comprises the following steps:
The preparation of premixed liquid:
Described premixed liquid is made up of the raw material of following weight parts: tetradecyl alchohol oleate 1-2, N-sodium lauroyl sarcosine 1-2, titanium dioxide 90-100, silane coupler KH560 0.5-1, dolomol 2-4, water 200-300;
Dolomol is mixed with tetradecyl alchohol oleate, and at 60-70 DEG C, heating mixes 2-4 minute, adds titanium dioxide, stirs;
Silane coupler KH560 is added to the water, adds N-sodium lauroyl sarcosine, stir;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 600-1000 rev/min of dispersed with stirring 10-20 minute, obtains premixed liquid;
The trimethylolpropane that is 1-2:5-7:100 by mass ratio, stearic acid, neodymia mix, at 58-65 DEG C, be uniformly mixed 30-40 minute, adding concentration is the acetic acid of 10-20%, 70-100 rev/min of dispersed with stirring 4-6 minute, add ammonium fluoride, be uniformly mixed 20-30 minute, add premixed liquid, 400-500 rev/min of dispersed with stirring 1-2 hour, dry 20-30 minute at 80-100 DEG C, send into sintering furnace, sintering 4-6 hour at 300-350 DEG C, obtains described rare earth compounded magnetic conductive powder;
The mol ratio of described neodymia, acetic acid, ammonium fluoride is 2-3:6-7:1-2;
Described titanium dioxide and the mass ratio of neodymia are 10-20:1.
For a preparation method for the titanium based ferrite core material of transformer, comprise the following steps:
(1) above-mentioned major ingredient is sent into blending tank, 2500-3000 rev/min is stirred mixed 2-4 hour, sends into grinding pot, and being ground to fineness is 50-70 μ m, adds the water of major ingredient weight 25-30%, the polyvinylpyrrolidone of 2-3%, and high-speed stirred is mixed, and obtains slurries;
(2) additive is sent into grinding pot, add the lithium carbonate of weight of additive 1-2%, the sodium phosphate trimer of 1-2%, being ground to fineness is 60-100 μ m;
(3) above-mentioned each raw material after treatment is mixed, stir, spraying is dry, is pressed into base, and sintering obtains the described titanium based ferrite core material for transformer.
Advantage of the present invention is:
The rare earth compounded magnetic conductive powder magnetic energy product that ferrite magnetic core material of the present invention adds is high, magnetic stability, and preparation method is simple, and it is high that finished product has grain boundary resistance rate, and the porosity is low, mechanical performance is strong, and crystal grain is feature greatly and uniformly.
Embodiment
Embodiment 1
A kind of titanium based ferrite core material for transformer, it is characterized in that it comprises major ingredient and additive, described major ingredient comprises according to mol ratio: the molybdenum trioxide of the zinc oxide of the Fe2O3 of 57.3 mol, the manganese oxide of 18.5mol, 15 mol, the lithium nitride of 0.3mol, 0.5 mol, the rare earth compounded magnetic conductive powder of 0.02 mol; Additive comprises according to the weight ratio meter that accounts for described ferrite magnetic core material: the chrome green of 70ppm, the nano-sized carbon of 60ppm;
The preparation of described rare earth compounded magnetic conductive powder comprises the following steps:
The preparation of premixed liquid:
Described premixed liquid is made up of the raw material of following weight parts: tetradecyl alchohol oleate 2, N-sodium lauroyl sarcosine 2, titanium dioxide 100, silane coupler KH560 0.5, dolomol 2, water 300;
Dolomol is mixed with tetradecyl alchohol oleate, and at 70 DEG C, heating mixes 2 minutes, adds titanium dioxide, stirs;
Silane coupler KH560 is added to the water, adds N-sodium lauroyl sarcosine, stir;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 1000 revs/min of dispersed with stirring 20 minutes, obtain premixed liquid;
The trimethylolpropane that is 1:5:100 by mass ratio, stearic acid, neodymia mix, at 65 DEG C, be uniformly mixed 40 minutes, adding concentration is the acetic acid of 10-20%, 100 revs/min of dispersed with stirring 6 minutes, add ammonium fluoride, be uniformly mixed 30 minutes, add premixed liquid, 500 revs/min of dispersed with stirring 2 hours, at 100 DEG C, be dried 30 minutes, send into sintering furnace, sintering 4 hours, obtains described rare earth compounded magnetic conductive powder at 350 DEG C;
The mol ratio of described neodymia, acetic acid, ammonium fluoride is 3:6:1;
Described titanium dioxide and the mass ratio of neodymia are 20:1.
For a preparation method for the titanium based ferrite core material of transformer, comprise the following steps:
(1) above-mentioned major ingredient is sent into blending tank, 3000 revs/min are stirred mixed 4 hours, send into grinding pot, and being ground to fineness is 70 μ m, adds the water of major ingredient weight 30%, 2% polyvinylpyrrolidone, and high-speed stirred is mixed, and obtains slurries;
(2) additive is sent into grinding pot, add the lithium carbonate of weight of additive 1%, 2% sodium phosphate trimer, being ground to fineness is 100 μ m;
(3) above-mentioned each raw material after treatment is mixed, stir, spraying is dry, is pressed into base, and sintering obtains the described titanium based ferrite core material for transformer.
Through detection, the basic mechanical design feature index that the product of above-described embodiment 1 gained reaches:
The initial permeability of magnetic core of the present invention is greater than 2700 μ i;
Maximum magnetic flux core loss (100Kc, 200mT) unit: KW/m 3: 417 (100 ± 2 DEG C);
Curie temperature is higher than 240 DEG C.

Claims (2)

1. the titanium based ferrite core material for transformer, it is characterized in that it comprises major ingredient and additive, described major ingredient comprises according to mol ratio: the molybdenum trioxide of the zinc oxide of the Fe2O3 of 57.3-65 mol, the manganese oxide of 18.5-24 mol, 12.3-15 mol, the lithium nitride of 0.2-0.3mol, 0.3-0.5 mol, the rare earth compounded magnetic conductive powder of 0.01-0.02 mol; Additive comprises according to the weight ratio meter that accounts for described ferrite magnetic core material: the chrome green of 60-70ppm, the nano-sized carbon of 50-60ppm;
The preparation of described rare earth compounded magnetic conductive powder comprises the following steps:
The preparation of premixed liquid:
Described premixed liquid is made up of the raw material of following weight parts: tetradecyl alchohol oleate 1-2, N-sodium lauroyl sarcosine 1-2, titanium dioxide 90-100, silane coupler KH560 0.5-1, dolomol 2-4, water 200-300;
Dolomol is mixed with tetradecyl alchohol oleate, and at 60-70 DEG C, heating mixes 2-4 minute, adds titanium dioxide, stirs;
Silane coupler KH560 is added to the water, adds N-sodium lauroyl sarcosine, stir;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 600-1000 rev/min of dispersed with stirring 10-20 minute, obtains premixed liquid;
The trimethylolpropane that is 1-2:5-7:100 by mass ratio, stearic acid, neodymia mix, at 58-65 DEG C, be uniformly mixed 30-40 minute, adding concentration is the acetic acid of 10-20%, 70-100 rev/min of dispersed with stirring 4-6 minute, add ammonium fluoride, be uniformly mixed 20-30 minute, add premixed liquid, 400-500 rev/min of dispersed with stirring 1-2 hour, dry 20-30 minute at 80-100 DEG C, send into sintering furnace, sintering 4-6 hour at 300-350 DEG C, obtains described rare earth compounded magnetic conductive powder;
The mol ratio of described neodymia, acetic acid, ammonium fluoride is 2-3:6-7:1-2;
Described titanium dioxide and the mass ratio of neodymia are 10-20:1.
2. a preparation method for the titanium based ferrite core material for transformer as claimed in claim 1, is characterized in that comprising the following steps:
(1) above-mentioned major ingredient is sent into blending tank, 2500-3000 rev/min is stirred mixed 2-4 hour, sends into grinding pot, and being ground to fineness is 50-70 μ m, adds the water of major ingredient weight 25-30%, the polyvinylpyrrolidone of 2-3%, and high-speed stirred is mixed, and obtains slurries;
(2) additive is sent into grinding pot, add the lithium carbonate of weight of additive 1-2%, the sodium phosphate trimer of 1-2%, being ground to fineness is 60-100 μ m;
(3) above-mentioned each raw material after treatment is mixed, stir, spraying is dry, is pressed into base, and sintering obtains the described titanium based ferrite core material for transformer.
CN201410283346.7A 2014-06-24 2014-06-24 Titanium-based ferrite core material used for transformer Pending CN104051107A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387048A (en) * 2014-10-16 2015-03-04 安徽德信电气有限公司 Tin-based ferrite magnetic core material for transformers
CN106915956A (en) * 2015-10-16 2017-07-04 Tdk株式会社 MnZnLi based ferrites, magnetic core and transformer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101593595A (en) * 2009-04-10 2009-12-02 临沂中瑞电子有限公司 A kind of low-temperature sintering high performance soft magnetic ferrite material and manufacture method
CN102231312A (en) * 2011-04-16 2011-11-02 江门安磁电子有限公司 Low-total harmonic distortion (THD) wideband high-permeability MnZn ferrite material and manufacturing method thereof
US20120286920A1 (en) * 2011-05-09 2012-11-15 Yajie Chen Magnetic grain boundary engineered ferrite core materials
CN102992754A (en) * 2012-11-23 2013-03-27 天长市昭田磁电科技有限公司 Preparation method of MnZn soft magnetic ferrite material with high magnetic flux density
CN103496963A (en) * 2013-09-06 2014-01-08 江门安磁电子有限公司 Ni-free MnZn ferrite magnetic core with double characteristics and manufacture method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101593595A (en) * 2009-04-10 2009-12-02 临沂中瑞电子有限公司 A kind of low-temperature sintering high performance soft magnetic ferrite material and manufacture method
CN102231312A (en) * 2011-04-16 2011-11-02 江门安磁电子有限公司 Low-total harmonic distortion (THD) wideband high-permeability MnZn ferrite material and manufacturing method thereof
US20120286920A1 (en) * 2011-05-09 2012-11-15 Yajie Chen Magnetic grain boundary engineered ferrite core materials
CN102992754A (en) * 2012-11-23 2013-03-27 天长市昭田磁电科技有限公司 Preparation method of MnZn soft magnetic ferrite material with high magnetic flux density
CN103496963A (en) * 2013-09-06 2014-01-08 江门安磁电子有限公司 Ni-free MnZn ferrite magnetic core with double characteristics and manufacture method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387048A (en) * 2014-10-16 2015-03-04 安徽德信电气有限公司 Tin-based ferrite magnetic core material for transformers
CN106915956A (en) * 2015-10-16 2017-07-04 Tdk株式会社 MnZnLi based ferrites, magnetic core and transformer

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Application publication date: 20140917