CN104276908A - Safe environment-friendly novel pyrotechnic composition - Google Patents
Safe environment-friendly novel pyrotechnic composition Download PDFInfo
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- CN104276908A CN104276908A CN201310287319.2A CN201310287319A CN104276908A CN 104276908 A CN104276908 A CN 104276908A CN 201310287319 A CN201310287319 A CN 201310287319A CN 104276908 A CN104276908 A CN 104276908A
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- powder
- medicament
- gunpowder
- environmental protection
- tinting material
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- 239000000203 mixture Substances 0.000 title abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000007800 oxidant agent Substances 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims description 32
- 239000003814 drug Substances 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 17
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 12
- 229920000742 Cotton Polymers 0.000 claims description 12
- 230000007613 environmental effect Effects 0.000 claims description 12
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical group [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 claims description 12
- 241000208125 Nicotiana Species 0.000 claims description 9
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 9
- 239000003721 gunpowder Substances 0.000 claims description 9
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 238000005034 decoration Methods 0.000 claims description 7
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- 229910001864 baryta Inorganic materials 0.000 claims description 6
- 229960004643 cupric oxide Drugs 0.000 claims description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 5
- 239000011324 bead Substances 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims description 5
- 229940039790 sodium oxalate Drugs 0.000 claims description 5
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229920001800 Shellac Polymers 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims description 3
- 239000012636 effector Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims description 3
- 229920003987 resole Polymers 0.000 claims description 3
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims description 3
- 229940113147 shellac Drugs 0.000 claims description 3
- 235000013874 shellac Nutrition 0.000 claims description 3
- 239000004208 shellac Substances 0.000 claims description 3
- 239000001828 Gelatine Substances 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- JOSWYUNQBRPBDN-UHFFFAOYSA-P ammonium dichromate Chemical compound [NH4+].[NH4+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O JOSWYUNQBRPBDN-UHFFFAOYSA-P 0.000 claims description 2
- 229940116318 copper carbonate Drugs 0.000 claims description 2
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229920001206 natural gum Polymers 0.000 claims description 2
- 239000012286 potassium permanganate Substances 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 150000002910 rare earth metals Chemical class 0.000 claims description 2
- 229940009188 silver Drugs 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 230000035945 sensitivity Effects 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000004040 coloring Methods 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 2
- 239000000020 Nitrocellulose Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 238000013112 stability test Methods 0.000 description 4
- 230000000087 stabilizing effect Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 2
- 241000205585 Aquilegia canadensis Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000907663 Siproeta stelenes Species 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229940045511 barium chloride Drugs 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- OOULUYZFLXDWDQ-UHFFFAOYSA-L barium perchlorate Chemical compound [Ba+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O OOULUYZFLXDWDQ-UHFFFAOYSA-L 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- AQMRBJNRFUQADD-UHFFFAOYSA-N copper(I) sulfide Chemical compound [S-2].[Cu+].[Cu+] AQMRBJNRFUQADD-UHFFFAOYSA-N 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- -1 sodium aluminum fluoride Chemical compound 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- KQAGKTURZUKUCH-UHFFFAOYSA-L strontium oxalate Chemical compound [Sr+2].[O-]C(=O)C([O-])=O KQAGKTURZUKUCH-UHFFFAOYSA-L 0.000 description 1
- 159000000008 strontium salts Chemical class 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
A safe environment-friendly novel pyrotechnic composition is used as a powdery colorful flower-forming spray composition, and comprises the compositions in parts by weight: 20-50 parts of a high-energy oxidizing agent, 30-60 parts of nitrocellulose, 1-15 parts of a colouring agent, 1-15 parts of a combustible effect agent, 1-10 parts of an adhesive, and 1-10 parts of a stabilizing agent. A preparation technology for the novel pyrotechnic composition is simple, the pyrotechnic composition prepared by employing the above formula is relatively low in friction sensitivity and impact sensitivity, far higher in chemical stability and safety than those of other pyrotechnic compositions, slightly smoky and environment-friendly after being combusted, and is widely applicable to various pyrotechnic composition products.
Description
Technical field
The present invention relates to the manufacturing technology of firework medicament composition in firework product.
Background technology
Pyrotechnic composition in firework product is a kind of mixture of complexity, wherein the physico-chemical property of most of composition is very unstable, slow or violent change can be there is under certain ambient conditions, light then reduce the firework display effect of product, heavy then cause combustion explosion accident, therefore, when strengthening safety and environmental protection requirement in the whole world to firework product, the security of the pyrotechnic composition of firework product seriously constrains the development of industry.
Summary of the invention
Technical problem to be solved by this invention is: provide a kind of safety, environmental protection, pyrotechnic composition composition that stability is high.
To achieve these goals, the invention provides following technical scheme:
A kind of safety, environmental protection, Novel tobacco gunpowder, when using as powder color spraying decoration medicament, its component and ratio of weight and number are: high energy oxidizer 20-50 part, soluble cotton 30-60 part, tinting material 1-15 part, flammable effector agent 1-15 part, tackiness agent 1-10 part, stablizer 1-10 part;
When using as powder color flare medicament, its component and ratio of weight and number are: high energy oxidizer 20-55 part, soluble cotton 30-60 part, tinting material 2-15 part, tackiness agent 1-10 part, stablizer 1-10 part;
When using as colorful bright bead granulation medicament, its component and ratio of weight and number are: high energy oxidizer 20-50 part, soluble cotton 30-55 part, tinting material 1-10 part, tackiness agent 1-10 part, stablizer 1-10 part;
When using as colored powder column forming agents, its component and ratio of weight and number are: high energy oxidizer 20-50 part, soluble cotton 30-55 part, tinting material 2-15 part, tackiness agent 1-10 part, stablizer 1-10 part.
Described high energy oxidizer is any one in ammoniumper chlorate, potassium perchlorate, potassium permanganate, ammonium dichromate.
Described soluble cotton is single original washing powder or double-basis powder.Single original washing powder/double-basis powder adopts retired single base/double-base propellant directly broken and makes, single original washing powder/double-basis powder take soluble cotton as main energetic component, its energy compared with low, ablation is little, single, double original washing powder is used for pyrotechnic composition mainly as reductive agent, be all gaseous product because of what generate after the reaction of itself and other medicament, be used to can make during firework display, to produce micro-cigarette or smokeless after pyrotechnic composition uses.
Described tinting material when using as powder color spraying decoration medicament powdery and colored flare medicament is strontium nitrate, one of Strontium carbonate powder, nitrate of baryta, barium carbonate, Sodium Silicofluoride, sodium oxalate, cupric oxide, copper carbonate;
Tinting material when using as colorful bright bead granulation medicament and colored powder column forming agents is strontium nitrate, one of Strontium carbonate powder, nitrate of baryta, barium carbonate, Sodium Silicofluoride, sodium oxalate, cupric oxide, silver, titanium, magnesium, aluminium, iron.
Described tackiness agent is one of starch, glutinous rice, gelatine, resol, natural gum, shellac.
Described stablizer is the order of department.
The medicament production starting material of fireworks and firecrackers have: the material of oxygenant, reductive agent, tackiness agent, tinting material and other special effects.
The oxygenant that fireworks and firecrackers medicament is conventional has: saltpetre, nitrate of baryta, strontium nitrate, cupric oxide, potassium perchlorate, ammoniumper chlorate etc.The reductive agent that fireworks and firecrackers medicament is conventional has: charcoal, sulphur, aluminium powder, aluminium-magnesium alloy powder, titanium valve etc.Tackiness agent conventional in fireworks medicament has: resol, shellac, paste, dextrin etc.
The tinting material of fireworks medicament has: sodium salt is yellow coloring thing, as sodium aluminum fluoride, Sodium Fluoride, Sodium Silicofluoride, sodium bicarbonate, sodium oxalate, borax etc.; Strontium salt is red colored thing, as Strontium carbonate powder, strontium oxalate, strontium nitrate, Strontium Sulphate etc.Barium salt is green coloring thing, as nitrate of baryta, barium carbonate, barium oxide, bariumchloride, barium perchlorate etc.Mantoquita is blue-colored thing, as cupric oxide, ventilation breather (malachite), cuprous sulfide, metallic copper etc.Each material is all flame tinting materials well-known in the art above, uses the realization all not affecting the object of the invention in component ratio of the present invention by known manner.
Wounded in the battle effect agent: as metal-powders such as silver powder, magnesium powder, titanium valve, zirconium powder, iron powder, rare earth metals.
The order of department is stearic another name, i.e. octadecanoic acid, and molecular formula C18H36O2, has good oilness and good light, heat stabilization, be widely used in the purposes such as industrial stablizer, promoting agent, promotor, water-resisting agent, whipping agent, emulsifying agent.Nitro-cotton in pyrotechnic composition composition has high flammability and explosivity, and the physico-chemical property of other compositions is also unstable, in pyrotechnic composition, add stearic acid, can promote the consistency of each composition of pyrotechnic composition, improves the unstable of pyrotechnic composition.
Remarkable advantage of the present invention is: preparation technology is simple, its friction sensitivity of pyrotechnic composition adopting above-mentioned formula to prepare and impact sensitivity lower, chemical stability and security are far above other pyrotechnic compositions, and micro-cigarette environmental protection after burning; All kinds of pyrotechnics product can be widely used in.
Embodiment
embodiment 1: when pyrotechnic composition of the present invention uses as powder color spraying decoration medicament, each component carries out pulverizing by each component formulated according to the form below and portion rate, screen, Homogeneous phase mixing, then mealy medicine is prepared into, medicament is used for spraying honeysuckle flower or golden flower in red, blue, green, yellow, purple assorted fireworks after spraying decoration product is seted off, get pyrotechnic composition 20 grams to detect through experiment, its impact sensitivity is about 40%, friction sensitivity is about 5%, 12 meters of fall down tests are without burning or blast, rate of moisture absorption≤0.8%, 75 DEG C of stability test results are " stabilizing ".
embodiment 2:when pyrotechnic composition of the present invention uses as powder color flare medicament, each component carries out pulverizing by each component formulated according to the form below and portion rate, screen, Homogeneous phase mixing, then mealy medicine is prepared into, medicament is used for firework product and sets off rear in red, blue, green, yellow, purple assorted flare, get pyrotechnic composition 20 grams to detect through experiment, its impact sensitivity is about 40%, friction sensitivity is about 5%, 12 meters of fall down tests are without burning or blast, rate of moisture absorption≤0.8%, 75 DEG C of stability test results are " stabilizing ".
embodiment 3:when pyrotechnic composition of the present invention uses as colorful bright bead granulation medicament, each component carries out pulverizing by each component formulated according to the form below and portion rate, screen, Homogeneous phase mixing, then be prepared into medicament, be a granulated into red, blue, green, yellow, purple, the bright pearl of silver color, oven dry, get pearl brightening drug 20 grams to detect through experiment, its impact sensitivity is about 40%, and friction sensitivity is about 5%, and 12 meters of fall down tests are without burning or blast, rate of moisture absorption≤0.8%, 75 DEG C of stability test results are " stabilizing ".
embodiment 4:when pyrotechnic composition of the present invention uses as colored powder column forming agents, each component carries out pulverizing by each component formulated according to the form below and portion rate, screen, Homogeneous phase mixing, then red, blue, green, yellow, purple, silver color powder column is prepared into, get it filled 20 grams and detect through experiment, its impact sensitivity is about 40%, and friction sensitivity is about 5%, and 12 meters of fall down tests are without burning or blast, rate of moisture absorption≤0.8%, 75 DEG C of stability test results are " stabilizing ".
Claims (7)
1. safety, environmental protection, a Novel tobacco gunpowder, is characterized in that,
When using as powder color spraying decoration medicament, its component and ratio of weight and number are: high energy oxidizer 20-50 part, soluble cotton 30-60 part, tinting material 1-15 part, effector agent 1-15 part, tackiness agent 1-10 part, stablizer 1-10 part;
When using as powder color flare medicament, its component and ratio of weight and number are: high energy oxidizer 20-55 part, soluble cotton 30-60 part, tinting material 2-15 part, tackiness agent 1-10 part, stablizer 1-10 part;
When using as colorful bright bead granulation medicament, its component and ratio of weight and number are: high energy oxidizer 20-50 part, soluble cotton 30-55 part, tinting material 1-10 part, tackiness agent 1-10 part, stablizer 1-10 part;
When using as colored powder column forming agents, its component and ratio of weight and number are: high energy oxidizer 20-50 part, soluble cotton 30-55 part, tinting material 2-15 part, tackiness agent 1-10 part, stablizer 1-10 part.
2. a kind of safety according to claim 1, environmental protection, Novel tobacco gunpowder, is characterized in that, described high energy oxidizer is any one in ammoniumper chlorate, potassium perchlorate, potassium permanganate, ammonium dichromate.
3. a kind of safety according to claim 1, environmental protection, Novel tobacco gunpowder, is characterized in that, described soluble cotton is single original washing powder or double-basis powder.
4. a kind of safety according to claim 1, environmental protection, Novel tobacco gunpowder, is characterized in that,
Described tinting material when using as powder color spraying decoration medicament powdery and colored flare medicament is strontium nitrate, one of Strontium carbonate powder, nitrate of baryta, barium carbonate, Sodium Silicofluoride, sodium oxalate, cupric oxide, copper carbonate;
Described tinting material when using as colorful bright bead granulation medicament and colored powder column forming agents is strontium nitrate, one of Strontium carbonate powder, nitrate of baryta, barium carbonate, Sodium Silicofluoride, sodium oxalate, cupric oxide, silver, titanium, magnesium, aluminium, iron.
5. a kind of safety according to claim 1, environmental protection, Novel tobacco gunpowder, is characterized in that, effector agent when using for powder color spraying decoration medicament is titanium, one of iron, zirconium, rare earth metal.
6. a kind of safety according to claim 1, environmental protection, Novel tobacco gunpowder, is characterized in that, described tackiness agent is starch, gelatine, resol, natural gum, shellac.
7. a kind of safety according to claim 1, environmental protection, Novel tobacco gunpowder, is characterized in that, described stablizer is the order of department.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310287319.2A CN104276908A (en) | 2013-07-10 | 2013-07-10 | Safe environment-friendly novel pyrotechnic composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310287319.2A CN104276908A (en) | 2013-07-10 | 2013-07-10 | Safe environment-friendly novel pyrotechnic composition |
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| Publication Number | Publication Date |
|---|---|
| CN104276908A true CN104276908A (en) | 2015-01-14 |
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| CN201310287319.2A Pending CN104276908A (en) | 2013-07-10 | 2013-07-10 | Safe environment-friendly novel pyrotechnic composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104860787A (en) * | 2015-04-08 | 2015-08-26 | 江西省万载县金峰花炮有限公司 | Safe and environment-friendly slight-smoke colored spraying fireworks |
| CN106495971A (en) * | 2016-10-13 | 2017-03-15 | 湖南荣晖实业有限公司 | Luxuriant medicine is opened without sulfur |
| CN107827685A (en) * | 2017-11-14 | 2018-03-23 | 舒辉 | Micro- cigarette combination of effects fireworks |
| CN108218647A (en) * | 2017-11-15 | 2018-06-29 | 梁日 | A kind of environment-friendly type fireworks and firecrackers formula |
| CN108299135A (en) * | 2018-01-29 | 2018-07-20 | 泸州北方化学工业有限公司 | A kind of smokelessly cold light firework medicament without ammonia odor |
| CN108911933A (en) * | 2018-08-30 | 2018-11-30 | 浏阳象形精品烟花出口制造有限公司 | A kind of colloid gunpowder of high nitrogen type solvent flashing |
| CN109020762A (en) * | 2018-08-30 | 2018-12-18 | 浏阳象形精品烟花出口制造有限公司 | A kind of rapid catalyst for cold light firework gunpowder |
| CN109704893A (en) * | 2017-10-26 | 2019-05-03 | 湖南省醴陵市创客中小企业服务中心有限公司 | A kind of unreal star medicine of firework |
| CN109721446A (en) * | 2019-03-17 | 2019-05-07 | 程爱宝 | A kind of micro- pyrotechnic composition complex composition and its application |
| CN110950726A (en) * | 2019-12-20 | 2020-04-03 | 江西吉润花炮新材料科技有限公司 | Smokeless and sulfur-free firework bomb lift-off agent and preparation method thereof |
| CN110963868A (en) * | 2019-12-20 | 2020-04-07 | 江西吉润花炮新材料科技有限公司 | High-explosive-sound firecracker medicament |
| CN111018638A (en) * | 2019-12-05 | 2020-04-17 | 江西吉润花炮新材料科技有限公司 | Waterproof smokeless and sulfur-free firing cable and preparation method thereof |
| CN111440039A (en) * | 2020-05-27 | 2020-07-24 | 湖南坤普科技有限公司 | Novel indoor and outdoor cold firework formula and preparation process thereof |
| CN111533630A (en) * | 2020-06-16 | 2020-08-14 | 湖南坤普科技有限公司 | Micro-smoke cooling firework containing light beads and sounders |
| CN111875457A (en) * | 2020-07-15 | 2020-11-03 | 北京理工大学 | Color agent for fireworks and firecrackers and preparation method thereof |
| CN113135811A (en) * | 2020-01-17 | 2021-07-20 | 浏阳象形精品烟花出口制造有限公司 | Effective medicament for disintegrating micro-smoke firework powder |
| CN113582794A (en) * | 2021-08-27 | 2021-11-02 | 陈昊彬 | Pyrotechnic composition for liquid carbon dioxide blasting and production method thereof |
| CN113698260A (en) * | 2021-02-09 | 2021-11-26 | 北京理工大学 | Low-cost combustion improver-based safe and environment-friendly firework propellant |
| CN113912465A (en) * | 2021-10-14 | 2022-01-11 | 长沙士象消防科技有限公司 | Moisture-proof and waterproof thermosensitive wire and preparation method thereof |
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| CN111440039A (en) * | 2020-05-27 | 2020-07-24 | 湖南坤普科技有限公司 | Novel indoor and outdoor cold firework formula and preparation process thereof |
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| CN111875457A (en) * | 2020-07-15 | 2020-11-03 | 北京理工大学 | Color agent for fireworks and firecrackers and preparation method thereof |
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