CN104342253B - Anti-oxidative knitting machine oil composition and application thereof - Google Patents
Anti-oxidative knitting machine oil composition and application thereof Download PDFInfo
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- CN104342253B CN104342253B CN201410494815.XA CN201410494815A CN104342253B CN 104342253 B CN104342253 B CN 104342253B CN 201410494815 A CN201410494815 A CN 201410494815A CN 104342253 B CN104342253 B CN 104342253B
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- phosphorous acid
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- phosphite
- knitting machine
- machine oil
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- 238000009940 knitting Methods 0.000 title claims abstract description 52
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 32
- 239000010721 machine oil Substances 0.000 title claims abstract description 32
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 16
- 239000002199 base oil Substances 0.000 claims abstract description 10
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 9
- 238000005461 lubrication Methods 0.000 claims abstract description 9
- 150000008301 phosphite esters Chemical class 0.000 claims abstract description 8
- 239000013556 antirust agent Substances 0.000 claims abstract description 5
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 9
- 239000012964 benzotriazole Substances 0.000 claims description 8
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 6
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 6
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims description 4
- -1 toluene Ester Chemical class 0.000 claims description 4
- XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 claims description 4
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- FACLLCPRCNZXNS-UHFFFAOYSA-N C(CCCCCCC)OP(OCCCCCCCCCCCCCCCCCC)O Chemical compound C(CCCCCCC)OP(OCCCCCCCCCCCCCCCCCC)O FACLLCPRCNZXNS-UHFFFAOYSA-N 0.000 claims description 3
- RAADJDWNEAXLBL-UHFFFAOYSA-N 1,2-di(nonyl)naphthalene Chemical compound C1=CC=CC2=C(CCCCCCCCC)C(CCCCCCCCC)=CC=C21 RAADJDWNEAXLBL-UHFFFAOYSA-N 0.000 claims description 2
- VMRWSLJQNIBPAN-UHFFFAOYSA-N C(CCCCCCCCCCC)(=O)OCC(OC(CCCCCCCCCCC)=O)COC(CCCCCCCCCCC)=O.P(O)(O)O Chemical compound C(CCCCCCCCCCC)(=O)OCC(OC(CCCCCCCCCCC)=O)COC(CCCCCCCCCCC)=O.P(O)(O)O VMRWSLJQNIBPAN-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 241000158728 Meliaceae Species 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 2
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 claims 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- 239000010705 motor oil Substances 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- FEVFLQDDNUQKRY-UHFFFAOYSA-N tris(4-methylphenyl) phosphite Chemical compound C1=CC(C)=CC=C1OP(OC=1C=CC(C)=CC=1)OC1=CC=C(C)C=C1 FEVFLQDDNUQKRY-UHFFFAOYSA-N 0.000 claims 1
- 239000003921 oil Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 6
- 230000003026 anti-oxygenic effect Effects 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 239000012965 benzophenone Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 231100000241 scar Toxicity 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical group OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical class CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- ZIGHXUZOOZUUGF-UHFFFAOYSA-N dodecane phosphorous acid Chemical compound P(O)(O)O.CCCCCCCCCCCC ZIGHXUZOOZUUGF-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000003613 toluenes Chemical class 0.000 description 1
Landscapes
- Knitting Machines (AREA)
- Lubricants (AREA)
Abstract
The present invention relates to a kind of anti-oxidative knitting machine oil composition and application thereof, mainly solves the problems, such as that the prior art is not provided simultaneously with the wear-resistant property strengthened and inoxidizability there are knitting machine oil composition.The present invention is made of following component by using being counted with parts by weight：A) 0.2~1 part of phosphite ester extreme pressure anti-wear additives；B) 0.1~1 part of antioxidant；C) 0.05~0.2 part of antirust agent；D) technical solution of 98~99.5 parts of base oils preferably solves the problems, such as this, the lubrication available for seamless knitting equipment.
Description
Technical field
The present invention relates to a kind of anti-oxidative knitting machine oil composition and application thereof.
Background technology
Seamless knitted product is high-grade knitted product popular in recent years, it is using dedicated shaping knitting equipment-seamless
Knitting machine carries out disposable shaping production.Nowadays, seamless knitting technique has been achieved for being greatly improved, and more and more maturely should
Various aspects for garment industry.Compared with traditional knitting mode of production, jointless technique has that technological process is short, labour
It is vertical that cost is low, one-pass molding reduces wastage of material, the flexible change of product good integrity, organization can weave three-dimensional (3D)
The advantages of body tissue.But its degree of automation is high, the speed of service is high, temperature rise is fast, the increased wear of knitting needle and syringe, because
This modern knitting equipment especially requirement for proposing higher of seamless knitter to knitting machine oil.Footwear machine is seamless knitter
One kind, due to process velocity is fast,
More demanding to oil product lubricity and antioxygenic property, finished product need not generally clean, therefore to the cleaning of oil product
Property is without particular/special requirement.
Patent CN 101235336A《High abrasion-resisting easy-cleaning knitting machine oil composition》Disclose one kind and be suitable for disk pin
The knitting machine oil of the equipment lubrications such as loom, footwear machine and inner wear machine, base oil content 70-95%, wear scar diameter 0.43-
0.62mm.Patent CN 1995302A《Emulsifiable oil for knitting》One kind is disclosed to be used as lubrication for weaving, weaving process, resist
Electrostatic, antirust and the fluid composition of cooling, wear scar diameter 0.44mm.Therefore, the wear scar diameter of knitting machine oil is reduced, is improved
Its antioxygenic property will further expand its application.Patent《Knitting machine oil》CN 102071091A disclose it is a kind of it is best in quality,
Easy cleaning, high lubricating effect, the knitting machine oil of long shelf-life, base oil content 40%-60%, but its lubricity is not investigated
Energy.Document《The performance characteristic of Sh series of high speed knitting oils and its use》, Liu Jinlin, petroleum refining, 1991,9:57-58；Text
Offer《The development of ZJ loom special lubes》, Yang Xuanhua etc., cotton textile technology, 1994,22 (8)：489-491；Document《HZ is advanced
The development of knitting machine oil》Open peaceful etc., lubricating oil, 2004,19 (1)：62-64；Document《The development of knitting oil》, Yin Hongbo, profit
Lubricating oil, 2002,17 (5)：The undisclosed additive titles therein of 41-43, and the mill spot and antioxygenic property of oil product are not investigated.
Document《The development of temperature stability knitting machine oil》, Jiang Yuhua etc., Tianjin Polytechnic University's journal, 2009,2 (1)：57-59, basis
Oily additive amount is 80-90%, does not grind spot to it and evaluates.
In conclusion it there is no the knitting machine for the water white transparency for being provided simultaneously with the wear-resistant property strengthened and inoxidizability in open source literature
Oil product.
The content of the invention
The first technical problem to be solved by the present invention is that the prior art is not provided simultaneously with resisting there are knitting machine oil composition
A kind of the problem of mill property strengthened and inoxidizability, there is provided new knitting machine oil composition.Said composition appearance colorless is transparent, has
The characteristics of wear resistence, good in oxidation resistance, while good cooling effect is provided for equipment, ensure that processing is smoothed out.The present invention
The two of technical problem to be solved are to provide a kind of use with solving one of technical problem corresponding knitting machine oil composition
On the way.
To solve one of above-mentioned technical problem, the technical solution adopted by the present invention is as follows：A kind of anti-oxidative knitting machine oil
Composition, is counted with parts by weight and is made of following component：
A) 0.2~1 part of phosphite ester extreme pressure anti-wear additives；
B) 0.1~1 part of antioxidant；
C) 0.05~0.2 part of antirust agent；
D) 98~99.5 parts of base oils；
Wherein, the phosphite ester extreme pressure anti-wear additives are selected from triphenyl phosphite, three certain herbaceous plants with big flowers ester of phosphorous acid, phosphorous acid three to first
Phenyl ester, phosphorous acid trilaurin, phosphorous acid three (tridecyl) ester, phosphorous acid two (18) alkenyl esters, phosphorous acid dodecane
At least one of base monooctyl ester, phosphorous acid octadecyl monooctyl ester or tributyl phosphite；
The antioxidant is selected from benzophenone kind antioxidant, benzotriazole kind antioxidant, amine antioxidants or phenols antioxygen
At least one of agent；
The antirust agent is selected from least one of alkaline dinonyl naphthalene sulfonate barium or middle base number calcium mahogany sulfonate；
The base oil is selected from least one of II class hydrogenation mineral oil or III class hydrogenation mineral oil.
In above-mentioned technical proposal, it is preferable that the phosphite ester extreme pressure anti-wear additives are selected from phosphite ester triphenylmethyl methacrylate, phosphorous acid
Three pairs of toluene esters, three certain herbaceous plants with big flowers ester of phosphite ester, phosphorous acid three (tridecyl) ester, phosphorous acid two (18) alkenyl esters, phosphorous acid ten
At least one of eight alkyl monooctyl esters or tributyl phosphite.
In above-mentioned technical proposal, it is preferable that the benzophenone kind antioxidant is selected from 2,4-DihydroxyBenzophenone, 2- hydroxyls
Base -4- oxy-octyl benzophenones or ESCALOL 567.
In above-mentioned technical proposal, it is preferable that the benzotriazole kind antioxidant is selected from 2- (2'- hydroxyl -5'- aminomethyl phenyls)
Benzotriazole, 2- (2'- hydroxyl -5'- t-octyls phenyl) benzotriazole, 6- (2- benzotriazole base) tertiary fourths of 4- tertiary pentyls -6'-
Base -4'- methyl -22'- methylene diphenol.
In above-mentioned technical proposal, it is preferable that the phenolic antioxidant is selected from 2,6-di-tert-butyl p-cresol, 4,4'- methylenes
Base double (2,6- di-tert-butylphenols), Irganox L135 phenol or Vanlube BHC phenol.
In above-mentioned technical proposal, it is preferable that the antioxidant is selected from benzophenone kind antioxidant, benzotriazole kind antioxidant
Or at least one of phenolic antioxidant.
In above-mentioned technical proposal, it is preferable that the component is colourless or light.
In above-mentioned technical proposal, it is preferable that the composition appearance is colourless transparent liquid.
To solve the two of above-mentioned technical problem, the technical solution adopted by the present invention is as follows：The anti-oxidative knitting machine oil
Composition is used for the lubrication of seamless knitting equipment.
In above-mentioned technical proposal, it is preferable that the seamless knitting equipment is footwear machine.
In above-mentioned technical proposal, component, parts by weight and the preferred scope of the anti-oxidative knitting machine oil composition
It is identical with solving the technical solution that one of technical problem taken.
The preparation method of anti-oxidative knitting machine oil composition of the present invention is as follows：Base oil is added in blending kettle, is heated up
To 55~65 DEG C, open stirring, sequentially add extreme pressure anti-wear additives and antioxidant, when stirring 1~5 is small, both the knitting machine oil
Product.
The present invention carries out compatibility by preferred extreme pressure anti-wear additives and antioxidant, and selects the hydrogenation base of colourless high viscosity index (HVI)
Plinth oil, obtains anti-oxidative knitting machine oil composition.The present invention makes full use of the extreme-pressure anti-wear and auxiliary of phosphorous acid esters material
Antioxidation and antioxidant act synergistically, and improve the antioxygenic property of oil product, and preferable pole is obtained under smaller additive amount
The characteristics of pressing wear resistence, inoxidizability and photostability, and assigning oil product water white transparency, wear scar diameter reaches 0.30mm, meets
The lubricating requirement of footwear machine equipment, achieves preferable technique effect.
In the present invention, light durability test method is that sample is placed in the colourless tool plug vial of 25mL and carries out nature
Light illumination experiment.The change of oil product color after a certain period of time is placed in observation, is turned to be yellow or is precipitated as and is unqualified.
Below by embodiment, the invention will be further elaborated.
Embodiment
【Embodiment 1~8】
Anti-oxidative knitting machine oil each component and its content are shown in Table 1.
【Embodiment 9】
Will【Embodiment 1~8】Anti-oxidative knitting machine oil carry out appearance, viscosity, mill spot, oxidation stability, illumination it is steady
Qualitative evaluation, the results are shown in Table 2.
【Comparative example 1】
Using only base oil as knitting machine oil, carry out appearance, viscosity, mill spot, oxidation stability, light durability comment
Valency, the results are shown in Table 2.
【Comparative example 2】
According to document CN101235336《High abrasion-resisting easy-cleaning knitting machine oil composition》1 disclosure system of embodiment
Standby composition, (70 parts of 5cst, 17 parts of polyisobutene, RL-33 parts, 1 part of octanoic acid, 3 parts of oleic acid, 0.5 part of 45%KOH, AEO-71
Part, AEO-33 parts, 201 parts, T5010.5 parts of TWEEN) and carry out appearance, viscosity, grind spot, oxidation stability, light durability
Evaluation, the results are shown in Table 2.
Table 1
Table 2
As shown in Table 2, easy cleaning rust-proof type knitting machine oil of the present invention has the excellent spy of water white transparency, antioxygenic property
Point.
Claims (5)
1. a kind of anti-oxidative knitting machine oil composition is used for the purposes of the lubrication of seamless knitting equipment, the anti-oxidative knitting
Engine oil base oil, is counted with parts by weight and is made of following component：
A) 0.2~1 part of phosphite ester extreme pressure anti-wear additives；
B) 0.1~1 part of antioxidant；
C) 0.05~0.2 part of antirust agent；
D) 98~99.5 parts of base oils；
Wherein, the phosphite ester extreme pressure anti-wear additives are selected from triphenyl phosphite, tridecyl phosphite, phosphorous acid three to toluene
Ester, phosphorous acid trilaurin, phosphorous acid three (tridecyl) ester, phosphorous acid two (18) alkenyl esters, phosphorous acid dodecyl
At least one of monooctyl ester, phosphorous acid octadecyl monooctyl ester or tributyl phosphite；
The antioxidant for Irganox L135 phenol and 2- (2'- hydroxyl -5'- aminomethyl phenyls) benzotriazole mixture, or
For Vanlube BHC phenol and 6- (the 2- benzotriazole base) 4- tertiary pentyl -6'- tert-butyl group -4'- methyl -2,2'- methylene diphenol
Mixture；
The antirust agent is selected from least one of alkaline dinonyl naphthalene sulfonate barium or middle base number calcium mahogany sulfonate；
The base oil is selected from least one of II class hydrogenation mineral oil or III class hydrogenation mineral oil.
2. anti-oxidative knitting machine oil composition is used for the purposes of the lubrication of seamless knitting equipment according to claim 1, its
Be characterized in that the phosphite ester extreme pressure anti-wear additives be selected from triphenyl phosphite, tri-p-cresyl phosphite, tridecyl phosphite,
In phosphorous acid three (tridecyl) ester, phosphorous acid two (18) alkenyl esters, phosphorous acid octadecyl monooctyl ester or tributyl phosphite
At least one.
3. anti-oxidative knitting machine oil composition is used for the purposes of the lubrication of seamless knitting equipment according to claim 1, its
It is colourless or light to be characterized in that the component.
4. anti-oxidative knitting machine oil composition is used for the purposes of the lubrication of seamless knitting equipment according to claim 1, its
It is colourless transparent liquid to be characterized in that the composition appearance.
5. anti-oxidative knitting machine oil composition is used for the purposes of the lubrication of seamless knitting equipment according to claim 1, its
It is footwear machine to be characterized in that the seamless knitting equipment.
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| CN201410494815.XA CN104342253B (en) | 2014-09-24 | 2014-09-24 | Anti-oxidative knitting machine oil composition and application thereof |
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| CN201410494815.XA CN104342253B (en) | 2014-09-24 | 2014-09-24 | Anti-oxidative knitting machine oil composition and application thereof |
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| CN104962349A (en) * | 2015-06-05 | 2015-10-07 | 广西大学 | Totally-synthetic emulsible oil composition for seamless knitting machine |
| CN114395437B (en) * | 2022-01-06 | 2022-08-30 | 江苏鑫露新材料有限公司 | Illumination-resistant anti-rust oil composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5213700A (en) * | 1991-05-20 | 1993-05-25 | Texaco Inc. | Method of lubricating a textile machine |
| CN1807565A (en) * | 2006-02-14 | 2006-07-26 | 中国石油化工股份有限公司 | Lubricant composition for computer flat-knitting machine |
| CN101065468A (en) * | 2004-09-29 | 2007-10-31 | 科聚亚公司 | Stabilized lubricant compositions |
| CN101235336A (en) * | 2008-01-24 | 2008-08-06 | 益田润石（北京）化工有限公司 | High abrasion-resisting easy-cleaning knitting machine oil composition |
-
2014
- 2014-09-24 CN CN201410494815.XA patent/CN104342253B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5213700A (en) * | 1991-05-20 | 1993-05-25 | Texaco Inc. | Method of lubricating a textile machine |
| CN101065468A (en) * | 2004-09-29 | 2007-10-31 | 科聚亚公司 | Stabilized lubricant compositions |
| CN1807565A (en) * | 2006-02-14 | 2006-07-26 | 中国石油化工股份有限公司 | Lubricant composition for computer flat-knitting machine |
| CN101235336A (en) * | 2008-01-24 | 2008-08-06 | 益田润石（北京）化工有限公司 | High abrasion-resisting easy-cleaning knitting machine oil composition |
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