A kind of method detecting complex reverse osmosis membrane desalination layer integrity and detection device thereof
Technical field
The present invention relates to reverse osmosis membrane integrity detection technical field, especially a kind of detection complex reverse osmosis membrane desalination layer
The method of integrity and detection device thereof.
Background technology
Reverse osmosis technology (Reverse Osmosis membrane, RO) is that most advanced and the most energy-conservation effective film divides
From technology.Its principle is under the effect higher than solution osmotic pressure, can not be through semipermeable membrane by these things according to other materials
Matter and water are separated.Due to the membrane aperture of reverse osmosis membrane the least (only about 10A), therefore, it is possible to effectively remove in water
Dissolved salts, colloid, microorganism, Organic substance etc. (clearance is up to 97%-98%).Reverse osmosis is in current high purity water equipment
Most widely used a kind of desalting technology, it separate to as if solution in ion range and molecular weight reach hundreds of organic
Thing.
Reverse osmosis membrane is a kind of high-performance separation membrane material, the most progressively replaces traditional water treatment technology, in municipal administration
The aspects such as sewage disposal, Treatment of Industrial Water, drinking water treatment, desalinization are more and more applied, and have energy-conservation, ring
The advantage such as protect, floor space is little.But current domestic reverse osmosis membrane technology more developed country falls behind, and the evaluating method of reverse osmosis membrane is relatively
Few, main detection means is the method for testing of the key propertys such as reverse osmosis membrane flux and salt rejection rate, does not has concrete UF layer, de-
The related detection devices such as salt deposit and method.
Summary of the invention
In order to solve above-mentioned technical problem present in prior art, the present invention provides a kind of detection complex reverse osmosis membrane to take off
The method of salt deposit integrity, the defect situation of reverse osmosis membrane can effectively be detected by the method, and then improves anti-
The penetrating amount of permeable membrane application and strainability, improve the final effect to sewage disposal, it is ensured that the quality of sewage disposal,
Improve water quality resource.
Further, the present invention also provides for a kind of device detecting complex reverse osmosis membrane desalination layer integrity on this basis, should
Reverse osmosis diaphragm or membrane module effectively can be carried out dyeing detection by device, it is possible to accurately by the desalination layer of reverse osmosis membrane
Defect situation detect, and can detect for different types of reverse osmosis diaphragm or membrane module so that inspection
Survey result and meet demand, it is ensured that reverse osmosis membrane is at the security performance of water treatment field and shedding quality.
It is achieved particular by techniques below scheme:
A kind of method detecting complex reverse osmosis membrane desalination layer integrity, comprises the following steps:
(1) preparation test fluid: it is 245-33000mg/l that water intaking and sodium chloride are configured to concentration, then is added thereto to Luo Dan
Bright B, and the mixing speed using mixing speed to be 300-400r/min is uniformly mixed, and control the addition of rhodamine B,
After making rhodamine B concentration in the solution be 190-210ppm, it is thus achieved that test fluid, and it is placed in test fluid case, adjusts
PH value is 7.45-7.55, stand-by;
(2) film is installed: be arranged on by film to be detected in evaluation pond so that the desalination layer of film is towards the water inlet evaluating pond
Mouthful, stand-by;
(3) pressurization dyeing: open booster pump, it is 0.39-5.55MPa that adjustable cut-off valve makes to test pressure, and controls temperature
Degree, for 24.5-25.5 DEG C, maintains under constant temperature and pressure, runs 29-31min, then open stop valve and pressure-regulating valve, adjust pressure
Pressure≤the 10psi of power table a and Pressure gauge b, is then shut off booster pump, stand-by;
(4) rinse: the test fluid in test fluid case is emitted, and be added thereto to clear water flushing test fluid case 3-4 time,
It is added thereto to clear water fuller to test fluid case, is then turned on booster pump, adjust stop valve and pressure-regulating valve so that Pressure gauge a
It is 20psi with the pressure of Pressure gauge b, and by concentrated stream gauge, controls the flow velocity >=0.45m/s of liquid, dense water to be got rid of
In time without color, stop flushing process, stand-by;
(5) evaluation is taken out: taking out diaphragm, microexamination diaphragm watch surface layer, punctation or line, then film occurs in surface layer
The desalination layer of sheet receives damage, for incomplete diaphragm;There is not punctation or line in surface layer, then diaphragm desalination layer is complete
Good lossless.
Described pond of evaluating is that Flat Membrane evaluates pond, hollow membrane evaluates the one in pond.
Described film is the one in reverse osmosis diaphragm, reverse osmosis membrane assembly.
When described film is reverse osmosis membrane assembly, described evaluation pond is pressure vessel, and the putamina of reverse osmosis membrane assembly is
A kind of in safety glass, rustless steel, plastics makes.
Described plastics are ABS.
Another object of the present invention is to provide a kind of device detecting complex reverse osmosis membrane desalination layer integrity, including
Test fluid case, form loop with test fluid case with temperature conditioning unit by pipeline, by pipeline, test fluid case is connected with evaluating pond
Connect, and on the pipeline of this connection, be provided with Pressure gauge a and booster pump, booster pump near test fluid case end, Pressure gauge a with
Being provided with an opening between booster pump, this opening is connected with test fluid case top by pipeline, and at this opening and test fluid case
Stop valve it is provided with on pipeline;Evaluating pond and be internally provided with film deposit position, the top evaluating pond is provided with permeate outlet, should
Permeate outlet is connected with test fluid case by pipeline;Evaluating and be additionally provided with dense water out on pond, this dense water out passes through pipeline
Connect with test fluid case, and on this connecting pipeline from the beginning of evaluating pond end, be disposed with Pressure gauge b, pressure-regulating valve and
Concentrated stream gauge.
Described evaluation pond can also be used with pressure vessel and replaces.
Described film is the one in reverse osmosis diaphragm, reverse osmosis membrane assembly.
The desalination layer of described film is towards the water inlet evaluating pond.
Compared with prior art, the technique effect of the present invention is embodied in:
1 by using rhodamine B to be added in saline solution being configured to certain density dyeing liquor as dyestuff, then will dye
Color liquid is according to filtering water treatment steps by dyeing in reverse osmosis membrane desalination layer, then is rinsed after dense water colorless by clear water,
Taking-up carries out micro-judgement, punctation or lines occurs, then show existing defects, and then be the defect situation of reverse osmosis membrane
Reach the evaluation being accurately positioned so that the detection of the desalination layer of reverse osmosis membrane has been broken away from traditional penetrating amount and salt rejection rate
Detection, and specific to UF layer and the detection of desalination layer, improve the accuracy rate of detection.
2 present invention also provide for the device of a kind of detection, and rhodamine B is applied to the desalination layer of reverse osmosis membrane desalination layer detection
Defect, and then use desalination layer desalination principle to dye the defects detection of reverse osmosis membrane desalination layer, Jin Erda
To even dyeing, then pass through microexamination so that more accurate to the defects detection of reverse osmosis membrane, it is ensured that reverse osmosis membrane desalination
The layer completeness to sewage disposal, improves the quality of sewage disposal, reduces the testing cost of reverse osmosis membrane desalination layer.
Accompanying drawing explanation
Fig. 1 is the overall structure connection diagram of the detection complex reverse osmosis membrane desalination layer integrity device of the present invention.
1-test fluid case 2-booster pump 3-stop valve 4-Pressure gauge a 5-film 6-evaluates pond 7-permeate outlet 8-pressure
Power table b 9-pressure-regulating valve 10-concentrated stream gauge 11-temperature conditioning unit 12-thermometer 13-pipeline.
Detailed description of the invention
With specific embodiment, technical scheme is further limited below in conjunction with the accompanying drawings, but requirement
The scope of protection is not only limited to description.
Embodiment 1
As it is shown in figure 1, a kind of method detecting complex reverse osmosis membrane desalination layer integrity, comprise the following steps:
(1) preparation test fluid: it is 245-33000mg/l that water intaking and sodium chloride are configured to concentration, then is added thereto to Luo Dan
Bright B, and the mixing speed using mixing speed to be 350r/min is uniformly mixed, and control the addition of rhodamine B so that
After rhodamine B concentration in the solution is 200ppm, it is thus achieved that test fluid, and being placed in test fluid case 1, adjusting pH value is
7.45-7.55, stand-by;
(2) film is installed: be arranged on by film 5 to be detected in evaluation pond 6 so that the desalination layer of film is towards evaluating entering of pond 6
The mouth of a river, stand-by;
(3) pressurization dyeing: open booster pump 2, it is 0.39-5.55MPa that adjustable cut-off valve 3 makes to test pressure, and controls
Temperature is 24.5-25.5 DEG C, maintains under constant temperature and pressure, runs 30min, then open stop valve 3 and pressure-regulating valve 9, adjusts
Pressure≤the 10psi of Pressure gauge a4 and Pressure gauge b8, is then shut off booster pump 2, stand-by;
(4) rinse: the test fluid in test fluid case 1 is emitted, and be added thereto to clear water flushing test fluid case 4 times,
It is added thereto to clear water fuller to test fluid case 1, is then turned on booster pump 2, adjust stop valve 3 and pressure-regulating valve 9 so that pressure
The pressure of table a4 and Pressure gauge b8 is 20psi, and by concentrated stream gauge 10, controls the flow velocity >=0.45m/s of liquid, wait to get rid of
Dense water without color time, stop flushing process, stand-by;
(5) evaluation is taken out: taking out diaphragm, microexamination diaphragm watch surface layer, punctation or line, then film occurs in surface layer
The desalination layer of sheet receives damage, for incomplete diaphragm;There is not punctation or line in surface layer, then diaphragm desalination layer is complete
Good lossless.
Described evaluation pond is that hollow membrane evaluates pond.
Described film 5 is reverse osmosis membrane assembly.
When described film 5 is reverse osmosis membrane assembly, described evaluation pond 6 is pressure vessel, the putamina of reverse osmosis membrane assembly
For rustless steel.
Concrete test fluid for different reverse osmosis membrane types, the concentration of test fluid, the pH value of test fluid, test time
Temperature, the flow velocity that shows of test pressure, concentrated stream gauge be shown in table 1 below:
Table 1:
Embodiment 2
As it is shown in figure 1, a kind of method detecting complex reverse osmosis membrane desalination layer integrity, comprise the following steps:
(1) preparation test fluid: it is 245-33000mg/l that water intaking and sodium chloride are configured to concentration, then is added thereto to Luo Dan
Bright B, and the mixing speed using mixing speed to be 400r/min is uniformly mixed, and control the addition of rhodamine B so that
After rhodamine B concentration in the solution is 210ppm, it is thus achieved that test fluid, and being placed in test fluid case 1, adjusting pH value is
7.45-7.55, stand-by;
(2) film is installed: be arranged on by film 5 to be detected in evaluation pond 6 so that the desalination layer of film is towards evaluating entering of pond 6
The mouth of a river, stand-by;
(3) pressurization dyeing: open booster pump 2, it is 0.39-5.55MPa that adjustable cut-off valve 3 makes to test pressure, and controls
Temperature is 24.5-25.5 DEG C, maintains under constant temperature and pressure, runs 31min, then open stop valve 3 and pressure-regulating valve 9, adjusts
Pressure≤the 10psi of Pressure gauge a4 and Pressure gauge b8, is then shut off booster pump 2, stand-by;
(4) rinse: the test fluid in test fluid case 1 is emitted, and be added thereto to clear water flushing test fluid case 4 times,
It is added thereto to clear water fuller to test fluid case 1, is then turned on booster pump 2, adjust stop valve 3 and pressure-regulating valve 9 so that pressure
The pressure of table a4 and Pressure gauge b8 is 20psi, and by concentrated stream gauge 10, controls the flow velocity >=0.45m/s of liquid, wait to get rid of
Dense water without color time, stop flushing process, stand-by;
(5) evaluation is taken out: taking out diaphragm, microexamination diaphragm watch surface layer, punctation or line, then film occurs in surface layer
The desalination layer of sheet receives damage, for incomplete diaphragm;There is not punctation or line in surface layer, then diaphragm desalination layer is complete
Good lossless.
Described evaluation pond is that hollow membrane evaluates pond.
Described film 5 is reverse osmosis membrane assembly.
When described film 5 is reverse osmosis membrane assembly, described evaluation pond 6 is pressure vessel, the putamina of reverse osmosis membrane assembly
For ABS.
Concrete test fluid for different reverse osmosis membrane types, the concentration of test fluid, the pH value of test fluid, test time
Temperature, the flow velocity that shows of test pressure, concentrated stream gauge be shown in table 1 below:
Table 1:
Embodiment 3
As it is shown in figure 1, a kind of method detecting complex reverse osmosis membrane desalination layer integrity, comprise the following steps:
(1) preparation test fluid: it is 245-33000mg/l that water intaking and sodium chloride are configured to concentration, then is added thereto to Luo Dan
Bright B, and the mixing speed using mixing speed to be 300r/min is uniformly mixed, and control the addition of rhodamine B so that
After rhodamine B concentration in the solution is 190ppm, it is thus achieved that test fluid, and being placed in test fluid case 1, adjusting pH value is
7.45-7.55, stand-by;
(2) film is installed: be arranged on by film 5 to be detected in evaluation pond 6 so that the desalination layer of film is towards evaluating entering of pond 6
The mouth of a river, stand-by;
(3) pressurization dyeing: open booster pump 2, it is 0.39-5.55MPa that adjustable cut-off valve 3 makes to test pressure, and controls
Temperature is 24.5-25.5 DEG C, maintains under constant temperature and pressure, runs 29min, then open stop valve 3 and pressure-regulating valve 9, adjusts
Pressure≤the 10psi of Pressure gauge a4 and Pressure gauge b8, is then shut off booster pump 2, stand-by;
(4) rinse: the test fluid in test fluid case 1 is emitted, and be added thereto to clear water flushing test fluid case 3 times,
It is added thereto to clear water fuller to test fluid case 1, is then turned on booster pump 2, adjust stop valve 3 and pressure-regulating valve 9 so that pressure
The pressure of table a4 and Pressure gauge b8 is 20psi, and by concentrated stream gauge 10, controls the flow velocity >=0.45m/s of liquid, wait to get rid of
Dense water without color time, stop flushing process, stand-by;
(5) evaluation is taken out: taking out diaphragm, microexamination diaphragm watch surface layer, punctation or line, then film occurs in surface layer
The desalination layer of sheet receives damage, for incomplete diaphragm;There is not punctation or line in surface layer, then diaphragm desalination layer is complete
Good lossless.
Described evaluation pond is that Flat Membrane evaluates pond.
Described film 5 is reverse osmosis diaphragm.
Concrete test fluid for different reverse osmosis membrane types, the concentration of test fluid, the pH value of test fluid, test time
Temperature, the flow velocity that shows of test pressure, concentrated stream gauge be shown in table 1 below:
Table 1:
Embodiment 4
As it is shown in figure 1, a kind of device detecting complex reverse osmosis membrane desalination layer integrity, including test fluid case 1 and test
Liquid case 1 is formed loop by pipeline 13, is connected with evaluating pond 6 by test fluid case 1 by pipeline 13 with temperature conditioning unit 11, and
The pipeline 13 of this connection is provided with Pressure gauge a4 and booster pump 2, booster pump 2 near test fluid case 1 end, Pressure gauge a4 with
Being provided with an opening between booster pump 2, this opening is connected with test fluid case top by pipeline 13, and at this opening and test fluid case
It is provided with stop valve 3 on the pipeline 13 of 1;Evaluating pond 6 and be internally provided with film 5 deposit position, the top in evaluation pond 6 is provided with and passes through
Liquid outlet 7, this permeate outlet 7 is connected with test fluid case 1 by pipeline 13;Evaluating and be additionally provided with dense water out on pond 6, this is dense
Water out is connected with test fluid case 1 by pipeline 13, and on this connecting pipeline 13 from the beginning of evaluating pond 6 end, is disposed with
Pressure gauge b8, pressure-regulating valve 9 and concentrated stream gauge.
Described evaluation pond 6 can also be used with pressure vessel and replaces.
Described film 5 is the one in reverse osmosis diaphragm, reverse osmosis membrane assembly.
The desalination layer of described film 5 is towards the water inlet evaluating pond 6.
It is important to point out at this, above-described embodiment be only limitted to technical scheme is further elaborated and
Illustrate, be not the further restriction to technical scheme.