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CN104434698B - A kind of antistatic, radiation proof hair cream and preparation method thereof - Google Patents

A kind of antistatic, radiation proof hair cream and preparation method thereof Download PDF

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CN104434698B
CN104434698B CN201410781396.8A CN201410781396A CN104434698B CN 104434698 B CN104434698 B CN 104434698B CN 201410781396 A CN201410781396 A CN 201410781396A CN 104434698 B CN104434698 B CN 104434698B
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CN104434698A (en
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孙淑萍
王凤各
侯东晓
吴玉
潘敉
李梦
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Shantou Keruo Xiyu Cosmetics Co ltd
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Wannan Medical College
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Abstract

本发明公开了一种抗静电、防辐射洗发膏及其制备方法,该洗发膏中含有以下物质:单硬脂酸甘油酯、硬脂酸、液晶型自增稠乳化剂Lipomulse LUXE、小麦胚芽油、乳木果油、荷兰乳酸钠、椰子油、阳离子瓜尔胶、冰晶形成剂AVC、生物多糖胶FUCOGEL1.5P、聚季铵盐、十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠、椰油酰胺基丙基甜菜碱CAB、烷基糖苷APG、月桂酰肌氨酸钠LS30、海藻糖、无患子提取液、薄荷提取液、乙二胺四乙酸二钠、氯化钠、柠檬酸、水溶性Ve、尼泊金乙酯/山梨酸、香精、蒸馏水。本发明制得的洗发膏具有防辐射、抗静电、养发护发、抗菌、去屑、止痒、防脱的作用。The invention discloses an antistatic and anti-radiation shampoo and a preparation method thereof. The shampoo contains the following substances: glyceryl monostearate, stearic acid, liquid crystal type self-thickening emulsifier Lipomulse LUXE, wheat Germ oil, shea butter, Dutch sodium lactate, coconut oil, cationic guar gum, ice crystal forming agent AVC, biopolysaccharide gum FUCOGEL1.5P, polyquaternium salt, sodium lauryl sulfate, fatty alcohol polyoxyethylene ether sulfate Sodium, Cocamidopropyl Betaine CAB, Alkyl Glycoside APG, Sodium Lauroyl Sarcosinate LS30, Trehalose, Sapinberry Extract, Peppermint Extract, Disodium EDTA, Sodium Chloride, Citric Acid, Water Soluble Ve, Ethyl Paraben/Sorbic Acid, Fragrance, Distilled Water. The shampoo prepared by the invention has the effects of radiation protection, antistatic, hair care, antibacterial, anti-dandruff, antipruritic and anti-hair loss.

Description

一种抗静电、防辐射洗发膏及其制备方法A kind of antistatic, anti-radiation shampoo and preparation method thereof

技术领域technical field

本发明涉及一种洗发膏及其制备方法,特别涉及一种抗静电、防辐射洗发膏及其制备方法,属日化领域。The invention relates to a shampoo and a preparation method thereof, in particular to an antistatic and anti-radiation shampoo and a preparation method thereof, belonging to the field of daily chemicals.

背景技术Background technique

随着社会的发展和人们对美的追求,人们也开始越来越注重头发的护理,因此对头发护理的需求也越来越大。近年来经济的发展,洗护发品市场不仅有了长足进步,而且还有巨大的潜在市场容量。另外对于日益强烈的紫外线,人们也逐渐认识到对于头发也是需要进行防晒的。市场上各种产品目不暇接,许多厂家、商家在利益的驱使下,为了让产品能起到最好的作用,开始在洗护发产品中添加有害于头发的化学合成物质,没有起到护发的同时,可能还会伤害头发。而且头发在高温、高寒、干燥、强风、强紫外线辐射等环境下,极易失去水分,发生破损、断裂、分叉、枯黄。With the development of society and people's pursuit of beauty, people also begin to pay more and more attention to hair care, so the demand for hair care is also increasing. With the economic development in recent years, the hair care products market has not only made great progress, but also has a huge potential market capacity. In addition, for the increasingly strong ultraviolet rays, people have gradually realized that sun protection is also required for hair. There are many kinds of products on the market. Driven by interests, many manufacturers and merchants began to add chemical synthetic substances harmful to hair in hair care products in order to make the products play the best role, which did not play a role in hair care. At the same time, it may also damage the hair. Moreover, hair is very easy to lose moisture in high temperature, high cold, dry, strong wind, strong ultraviolet radiation and other environments, and it is damaged, broken, bifurcated, and yellow.

发明内容Contents of the invention

针对上述现有技术的不足,本发明提供一种抗静电、防辐射洗发膏及其制备方法,克服了头发被晒伤、得不到护发、发生破损、断裂、分叉、枯黄的难题,并且还具有抑菌、去屑、防脱、抗静电、防辐射的效果。Aiming at the deficiencies of the above-mentioned prior art, the present invention provides an antistatic and anti-radiation shampoo and its preparation method, which overcomes the problems of sunburned hair, lack of hair care, damage, breakage, bifurcation, and yellowing , and also has antibacterial, anti-dandruff, anti-shedding, antistatic, anti-radiation effects.

为实现上述目的,本发明提供一种抗静电、防辐射洗发膏,述洗头膏中含有以下物质及其含量:In order to achieve the above object, the invention provides a kind of antistatic, anti-radiation shampoo, which contains the following substances and their contents:

作为进一步的改进,所述洗发膏中还含有金黄荷荷巴油1-5g、旱莲草提取液1-3ml。此洗发膏不仅能进一步护理头发,还具有乌发的效果。As a further improvement, the shampoo also contains 1-5g of golden jojoba oil and 1-3ml of eclipta extract. This shampoo not only further conditions the hair but also has a blackening effect.

这里可以根据不同的需求添加香精,所述的香精为青瓜香精、玫瑰香精、桂花香精、水蜜桃香精、柠檬香精、菠萝香精、茉莉香精中的一种或几种。Essence can be added here according to different requirements, and the essence is one or more of cucumber essence, rose essence, sweet-scented osmanthus essence, peach essence, lemon essence, pineapple essence, and jasmine essence.

所述抗静电、防辐射洗发膏制备方法,包括如下步骤:Described antistatic, anti-radiation shampoo preparation method, comprises the steps:

步骤一:称取0.1-1g冰晶形成剂AVC,溶于30-100ml的水中,搅拌均匀,静置2-3h,待其自然溶胀溶解,得凝胶A;Step 1: Weigh 0.1-1g of ice crystal forming agent AVC, dissolve in 30-100ml of water, stir evenly, let it stand for 2-3h, and wait for its natural swelling and dissolution to obtain gel A;

步骤二:称取阳离子瓜尔胶1-2g,溶于30-100ml的水中,搅拌均匀,于70-90℃水浴中继续搅拌至溶解,常温下冷却30min,得调理剂B;Step 2: Weigh 1-2g of cationic guar gum, dissolve it in 30-100ml of water, stir evenly, continue stirring in a water bath at 70-90°C until dissolved, and cool at room temperature for 30 minutes to obtain conditioner B;

步骤三:称取小麦胚芽油2-10g、乳木果油1-5g、椰子油1-5g、硬脂酸0.1-1g、液晶型自增稠乳化剂Lipomulse LUXE 2-3g置于烧杯中,水浴70-90℃加热,为油相;Step 3: Weigh 2-10g of wheat germ oil, 1-5g of shea butter, 1-5g of coconut oil, 0.1-1g of stearic acid, and 2-3g of liquid crystal self-thickening emulsifier Lipomulse LUXE into a beaker, Heating in a water bath at 70-90°C is the oil phase;

步骤四:称取蒸馏水10-25g,水浴70-90℃加热,为水相;Step 4: Weigh 10-25g of distilled water and heat in a water bath at 70-90°C to form the water phase;

步骤五:等油相已澄清透明,水相、油相达到相同温度的情况下,将水相呈细流状加入油相中,边加边搅拌,形成乳剂基质C;Step 5: When the oil phase is clear and transparent, and the water phase and the oil phase have reached the same temperature, add the water phase into the oil phase in a thin stream, and stir while adding to form an emulsion matrix C;

步骤六:称取蒸馏水10-30g,加入脂肪醇聚氧乙烯醚硫酸钠1-5g、荷兰乳酸钠2-10g、椰油酰胺基丙基甜菜碱CAB 1-5g、烷基糖苷APG 1-5g、月桂酰肌氨酸钠LS301-5g、水溶性Ve 0.1-1g、海藻糖1-2g、聚季铵盐1-5g、生物多糖胶FUCOGEL 1.5P 1-5g、十二烷基硫酸钠0.1-3g、氯化钠0.1-3g,搅拌溶解,得溶液D;Step 6: Weigh 10-30g of distilled water, add 1-5g of fatty alcohol polyoxyethylene ether sodium sulfate, 2-10g of Dutch lactate sodium, 1-5g of cocamidopropyl betaine CAB, 1-5g of alkyl glycoside APG, Sodium lauroyl sarcosinate LS301-5g, water-soluble Ve 0.1-1g, trehalose 1-2g, polyquaternium salt 1-5g, biopolysaccharide gum FUCOGEL 1.5P 1-5g, sodium lauryl sulfate 0.1-3g 1. Sodium chloride 0.1-3g, stirred and dissolved to obtain solution D;

步骤七:向乳剂基质C中加入无患子提取液1-5g、薄荷提取液1-5g,搅拌混合均匀,再加入凝胶A、调理剂B、溶液D,搅拌混合均匀;Step 7: Add 1-5g of Sapindus chinensis extract and 1-5g of peppermint extract to emulsion base C, stir and mix evenly, then add gel A, conditioning agent B, solution D, stir and mix evenly;

步骤八:称取乙二胺四乙酸二钠0.01-0.05g、尼泊金乙酯或山梨酸0.1-0.3g、加入蒸馏水5-18ml,加热使其溶解,加入步骤七体系中,再加入香精0.05-0.3ml,用20%柠檬酸溶液0.1-3ml,调节pH值为6.5-7.5后,搅拌10-15min,混合均匀,即得抗静电、防辐射洗发膏。Step 8: Weigh 0.01-0.05g of disodium edetate, 0.1-0.3g of ethylparaben or sorbic acid, add 5-18ml of distilled water, heat to dissolve, add to the system of step 7, and then add flavor 0.05-0.3ml, use 0.1-3ml of 20% citric acid solution, adjust the pH value to 6.5-7.5, stir for 10-15min, and mix evenly to obtain antistatic and anti-radiation shampoo.

所述的无患子提取物通过以下方法制备:取剥去内核的无患子,浸泡0.15-1h,加热至90-100℃,煎煮提取3次,第1次加6-12倍量水,提取0.5-2h,第2次加4-10倍量水,提取0.5-1.5h,第3次加3-8倍量水,提取0.5-1.5h,每次滤过,合并滤液,滤液的体积浓缩至无患子重量的3-6倍g/ml,过滤即得。The Sapindus chinensis extract is prepared by the following method: take the sapinsia chinensis peeled off the inner core, soak for 0.15-1h, heat to 90-100°C, decoct and extract 3 times, add 6-12 times the amount of water for the first time , extract 0.5-2h, add 4-10 times the amount of water for the second time, extract 0.5-1.5h, add 3-8 times the amount of water for the third time, extract 0.5-1.5h, filter each time, combine the filtrate, the filtrate The volume is concentrated to 3-6 times g/ml of the weight of Sapindus chinensis, and it is obtained by filtration.

所述的薄荷提取液通过以下方法制备:取薄荷浸泡0.5-1h,回流提取3次,第1次加10-15倍量水,提取0.5-2h,第2次加8-12倍量水,提取0.5-1.5h,第3次加6-10倍量水,提取0.5-1.5h,每次滤过,合并滤液,滤液的体积浓缩至薄荷重量的4-7倍g/ml,加液体重量1%-5%活性炭,60-100℃水浴加热搅拌,抽滤,取滤液。The mint extract is prepared by the following method: soak the mint for 0.5-1h, reflux extraction 3 times, add 10-15 times the amount of water for the first time, extract for 0.5-2h, add 8-12 times the amount of water for the second time, Extract for 0.5-1.5h, add 6-10 times the amount of water for the third time, extract for 0.5-1.5h, filter each time, combine the filtrate, the volume of the filtrate is concentrated to 4-7 times the weight of mint g/ml, add the liquid weight 1%-5% activated carbon, heated and stirred in a water bath at 60-100°C, filtered with suction, and the filtrate was taken.

所述步骤步骤三中还加入有1-5重量份的金黄荷荷巴油。In the third step of the step, 1-5 parts by weight of golden jojoba oil is also added.

所述步骤七中还加入有1-5重量份的旱莲草提取液。所述的旱莲草提取液通过以下方法制备:取旱莲草,回流提取2次,第1次加10-18倍水量,提取0.5-1.5h,第2次用10-12倍水量,提取0.5-1.5h,每次用3层纱布滤过,合并滤液,加热浓缩至旱莲草重量的2-10倍g/ml,过滤即得。In the step seven, 1-5 parts by weight of Eclipta chinensis extract is also added. The described Eclipta extract is prepared by the following method: take Eclipta, reflux and extract twice, add 10-18 times the amount of water for the first time, extract for 0.5-1.5h, and use 10-12 times the amount of water for the second time, extract 0.5-1.5h, filter with 3 layers of gauze each time, combine the filtrates, heat and concentrate to 2-10 times the weight of Eclipta chinensis g/ml, and filter to obtain.

本发明中的各种成分如下:Various compositions among the present invention are as follows:

无患子也叫洗手果。其果皮中含无患子皂苷等三萜皂苷。《本草纲目》中记载:无患子果实蕴含天然净菌素。自古以来是中华民族传统的天然洗护珍果。它具有不伤人体,不污染水源之特性。无患子也具有抑菌、去屑、防脱的作用。Soapberry is also called washing fruit. Its peel contains triterpene saponins such as Sapindus sapinsin. It is recorded in "Compendium of Materia Medica": the fruit of Sapindus chinensis contains natural clementin. Since ancient times, it has been the traditional natural care and precious fruit of the Chinese nation. It has the characteristics of not hurting the human body and not polluting water sources. Sapindus also has the functions of antibacterial, anti-dandruff and anti-shedding.

旱莲草有滋补肝肾,乌须固齿,凉血止血的功效。捣汁涂眉发,能促进毛发生长,内服有乌发、黑发功效。《滇南本草》载,墨旱莲“固齿,乌发,洗九种痔疮”。《本草纲目》指出,墨旱莲“乌须发,益肾阴”。旱莲草治须发早白、眉髭脱落。Eclipta has the effects of nourishing the liver and kidney, strengthening the teeth with black whiskers, cooling blood and stopping bleeding. Pounding the juice and applying it on the eyebrows and hair can promote hair growth, and it can be used orally to have black hair and black hair. "Southern Yunnan Materia Medica" contains that Eclipta "fixes teeth, black hair, and washes nine kinds of hemorrhoids". "Compendium of Materia Medica" pointed out that Eclipta "black beard and hair, benefit kidney and yin". Eclipta can cure premature graying of beard and hair, and fall off of eyebrows and mustaches.

薄荷含有挥发油、薄荷精以及单宁等物质,有助于抚平愤怒、沮丧等负面情绪,是消除疲劳、缓解压力、平心静气的心灵补药。薄荷有清凉的感觉,可抗菌、抑菌,止痒。Peppermint contains substances such as volatile oil, mint essence, and tannins, which help to soothe negative emotions such as anger and depression. It is a spiritual tonic for eliminating fatigue, relieving stress, and calming the mind. Peppermint has a cool feeling, antibacterial, antibacterial, antipruritic.

小麦胚芽油富含各种营养,易被人体吸收,具有抑制自由基,抗氧化、延缓机体衰老、保护细胞膜、促进皮肤新陈代谢,提高人体免疫力、增强防癌、抗癌及促进血液循环作用,还有保湿、使皮肤润泽,护肤美容、保持青春、令女性肌肤变得柔润而富有弹性等作用。对滋润干燥发质、养护头皮极有帮助,适合各种肤质,对干癣、湿疹有一定效果,亦具有防晒功能,可用于身体、头发的防晒。Wheat germ oil is rich in various nutrients and is easily absorbed by the human body. It has the functions of inhibiting free radicals, anti-oxidation, delaying the aging of the body, protecting cell membranes, promoting skin metabolism, improving human immunity, enhancing anti-cancer, anti-cancer and promoting blood circulation. It also has the functions of moisturizing, moisturizing the skin, skin care and beauty, maintaining youth, and making women's skin soft and elastic. It is very helpful for moisturizing dry hair and maintaining the scalp. It is suitable for all skin types and has certain effects on psoriasis and eczema. It also has sun protection function and can be used for sun protection of body and hair.

金黄荷荷巴油有良好的渗透性,分子排列和人的油脂非常类似,是稳定性极高、延展性特佳的基础油,可以改善粗糙的发质,是头发用油的最佳选择,可防止头发晒伤、柔软头发,有助于头发乌黑、预防分叉。荷荷巴油另一个特性是其亲水性,对皮肤有调节水分的功能,是一种很完美的护肤与护发的天然保养成分。Golden jojoba oil has good permeability, and its molecular arrangement is very similar to human oil. It is a base oil with high stability and excellent ductility. It can improve rough hair and is the best choice for hair oil. It can prevent hair sunburn, soften hair, help black hair and prevent split ends. Another feature of jojoba oil is its hydrophilicity, which has the function of regulating moisture to the skin. It is a perfect natural maintenance ingredient for skin care and hair care.

阳离子瓜尔胶能对护发产品提供优良的调理性能,有良好的发泡、稳泡、抗静电作用,降低头发的干、湿梳阻力,改善头发的湿梳性和干梳性,使头发长期保持光泽、柔软,富有弹性。它能吸附于毛杆,形成单分子吸附膜,使头发柔软,富有光泽及弹性,并阻止产生静电,梳理十分方便,是一种生产透明日化产品的理想调理剂。Cationic guar gum can provide excellent conditioning properties for hair care products, have good foaming, foam stabilization, and antistatic effects, reduce the resistance of dry and wet combing of hair, improve the wet combing and dry combing properties of hair, and make hair Maintain luster, softness and elasticity for a long time. It can be adsorbed on the hair shaft to form a monomolecular adsorption film, which makes the hair soft, shiny and elastic, prevents static electricity, and is very convenient for combing. It is an ideal conditioner for the production of transparent daily chemical products.

海藻糖具有优异、安全的保湿能力和生物大分子活性的特性。头发在高温、高寒、干燥、强风、强紫外线辐射等环境下,极易失去水分,发生破损、断裂、分叉、枯黄。海藻糖在这种情况下能够在头发表层形成一层特殊的保护膜,保持头皮原有营养和水分,保护发丝纤维及毛鳞片免遭脱水的伤害,帮助秀发保持天然的结构,因此它是一种高效的保湿剂,并且提供不受气候潜在伤害的保护作用。海藻糖还具有将外来的热量辐射出去的功能,从而保护头发不致受损。海藻糖能抑制由于脂肪酸降解而导致的挥发性醛类的产生,能抑制由此而引起的异味。海藻糖具有很好的防辐射、抗静电效果。Trehalose has the characteristics of excellent and safe moisturizing ability and biomacromolecular activity. In high temperature, high cold, dry, strong wind, strong ultraviolet radiation and other environments, hair is very easy to lose moisture, breakage, breakage, bifurcation, and yellowing. In this case, trehalose can form a special protective film on the surface of the hair, maintain the original nutrition and moisture of the scalp, protect the hair fibers and cuticles from dehydration, and help the hair maintain its natural structure, so it Is a highly effective moisturizer and provides protection against potential damage from the weather. Trehalose also has the function of radiating external heat to protect hair from damage. Trehalose can inhibit the production of volatile aldehydes due to the degradation of fatty acids, and can inhibit the resulting odor. Trehalose has good anti-radiation and antistatic effects.

有益效果:本发明所制成的洗发膏具有很好的防辐射、抗静电、养发护发的功效、清爽、舒适、芳香,同时也具有抗菌抑菌的作用,还具有去屑、止痒、防脱的作用。阳离子瓜尔胶有良好的发泡稳泡作用,抗静电作用,改善头发的湿梳性和干梳性,使头发长期保持光泽、柔软,富有弹性。处方中成分相辅相成,使得该洗头膏有较好的保湿效果,可全面滋养头发,修复受损毛发,补充毛囊所需营养,促进毛囊细胞新陈代谢,使头发由内到外得到全面调理,令头发一梳到底,如丝绸般光滑柔亮,富有弹性。Beneficial effects: the shampoo made by the present invention has good effects of anti-radiation, antistatic, hair care and hair care, refreshing, comfortable, and fragrant, and also has antibacterial and antibacterial effects, and also has anti-dandruff, anti-dandruff, and anti-bacterial effects. Itching, anti-off effect. Cationic guar gum has good foam stabilizing effect, antistatic effect, improves wet combing and dry combing properties of hair, and keeps hair shiny, soft and elastic for a long time. The ingredients in the prescription complement each other, so that the shampoo has a good moisturizing effect, can fully nourish the hair, repair damaged hair, supplement the nutrients needed by the hair follicles, promote the metabolism of the hair follicle cells, and make the hair fully conditioned from the inside to the outside. Once combed to the end, it is as smooth, soft and elastic as silk.

具体实施方式detailed description

下面结合实施例对本发明做进一步的描述。The present invention will be further described below in conjunction with the examples.

本发明的金黄荷荷巴油、小麦胚芽油、椰子油为市售。Golden jojoba oil, wheat germ oil and coconut oil of the present invention are commercially available.

实施例1Example 1

本实施例抗静电、防辐射洗发膏通过如下步骤制得:The present embodiment antistatic, anti-radiation shampoo is made through the following steps:

步骤一:称取0.5g冰晶形成剂AVC,溶于100ml的水中,搅拌均匀,静置2h,待其自然溶胀溶解,得凝胶A;Step 1: Weigh 0.5g of ice crystal forming agent AVC, dissolve in 100ml of water, stir evenly, let stand for 2 hours, wait for its natural swelling and dissolution to obtain gel A;

步骤二:称取阳离子瓜尔胶2g,溶于100ml的水中,搅拌均匀,于80℃水浴中继续搅拌至溶解,常温下冷却30min,得调理剂B;Step 2: Weigh 2 g of cationic guar gum, dissolve it in 100 ml of water, stir evenly, continue stirring in a water bath at 80°C until dissolved, and cool at room temperature for 30 minutes to obtain conditioner B;

步骤三:称取小麦胚芽油2g、乳木果油1.5g、椰子油1g、硬脂酸0.5g、液晶型自增稠乳化剂Lipomulse LUXE 2g置于烧杯中,水浴80℃加热,为油相;Step 3: Weigh 2g of wheat germ oil, 1.5g of shea butter, 1g of coconut oil, 0.5g of stearic acid, and 2g of liquid crystal self-thickening emulsifier Lipomulse LUXE, put them in a beaker, and heat in a water bath at 80°C to form the oil phase ;

步骤四:称取蒸馏水15g,水浴85℃加热,为水相;Step 4: Weigh 15g of distilled water and heat in a water bath at 85°C to form the water phase;

步骤五:等油相已澄清透明,水相、油相达到相同温度的情况下,将水相呈细流状加入油相中,边加边搅拌,形成乳剂基质C;Step 5: When the oil phase is clear and transparent, and the water phase and the oil phase have reached the same temperature, add the water phase into the oil phase in a thin stream, and stir while adding to form an emulsion matrix C;

步骤六:称取蒸馏水10g,加入脂肪醇聚氧乙烯醚硫酸钠3g、荷兰乳酸钠3g、椰油酰胺基丙基甜菜碱CAB 2g、烷基糖苷APG 3g、月桂酰肌氨酸钠LS30 2g、水溶性Ve 0.8g、海藻糖1.5g、聚季铵盐2g、生物多糖胶FUCOGEL 1.5P 1.5gg、十二烷基硫酸钠0.3g、氯化钠0.5g,搅拌溶解,得溶液D;Step 6: Weigh 10g of distilled water, add 3g of sodium fatty alcohol polyoxyethylene ether sulfate, 3g of Dutch lactate, 2g of cocamidopropyl betaine CAB, 3g of alkyl glycoside APG, 2g of sodium lauroyl sarcosinate LS30, water soluble Add 0.8g of Ve, 1.5g of trehalose, 2g of polyquaternium, FUCOGEL 1.5P 1.5gg of biopolysaccharide, 0.3g of sodium lauryl sulfate, and 0.5g of sodium chloride, stir and dissolve to obtain solution D;

步骤七:向乳剂基质C中加入无患子提取液2g、薄荷提取液1.5g,搅拌混合均匀,再加入凝胶A、调理剂B、溶液D,搅拌混合均匀;Step 7: Add 2 g of Sapindus chinensis extract and 1.5 g of peppermint extract to emulsion base C, stir and mix evenly, then add gel A, conditioner B, solution D, stir and mix evenly;

步骤八:称取乙二胺四乙酸二钠0.02g、尼泊金乙酯或山梨酸0.1g、加入蒸馏水8ml,加热使其溶解,加入步骤七体系中,再加入香精0.05ml,用20%柠檬酸溶液1ml,调节pH值为6.8后,搅拌10-15min,混合均匀,即得抗静电、防辐射洗发膏。这里可以根据不同的需求添加香精,所述的香精为青瓜香精、玫瑰香精、桂花香精、水蜜桃香精、柠檬香精、菠萝香精、茉莉香精中的一种或几种。Step 8: Weigh 0.02g of disodium edetate, 0.1g of ethylparaben or sorbic acid, add 8ml of distilled water, heat to dissolve, add to the system of step 7, then add 0.05ml of essence, and use 20% Take 1ml of citric acid solution, adjust the pH value to 6.8, stir for 10-15 minutes, and mix evenly to obtain an antistatic and anti-radiation shampoo. Essence can be added here according to different requirements, and the essence is one or more of cucumber essence, rose essence, sweet-scented osmanthus essence, peach essence, lemon essence, pineapple essence, and jasmine essence.

其中无患子提取物的制备:无患子剥去内核,称取40g,再浸泡1h,加热至100℃,煎煮提取3次,第1次加9倍量水,提取1.5h,第2次加9倍量水,提取1h,第3次加7倍量水,提取1h,每次滤过,合并滤液,滤液的体积浓缩至无患子重量的4倍(g/ml),过滤即得。Among them, the preparation of Sapindus chinensis extract: Peel off the inner core of Sapindus chinensis, weigh 40g, then soak for 1h, heat to 100°C, decoct and extract 3 times, add 9 times the amount of water for the first time, extract for 1.5h, the second time Add 9 times the amount of water for the first time, extract 1h, add 7 times the amount of water for the 3rd time, extract 1h, filter each time, combine the filtrate, the volume of the filtrate is concentrated to 4 times (g/ml) of the weight of Sapindus chinensis, and filter have to.

其中薄荷提取液的制备:称取薄荷30g,浸泡1h,回流提取3次,第1次加15倍量水,提取1.5h,第2次加12倍量水,提取1h,第3次加9倍量水,提取1h,每次滤过,合并滤液,滤液的体积浓缩至薄荷重量的6倍(g/ml),加液体重量3%活性炭,80℃水浴加热搅拌,抽滤,即可。The preparation of peppermint extract: Weigh 30g of mint, soak for 1h, reflux extraction for 3 times, add 15 times of water for the first time, extract for 1.5h, add 12 times of water for the second time, extract for 1h, add 9 times for the third time Double the amount of water, extract for 1 hour, filter each time, combine the filtrates, concentrate the volume of the filtrates to 6 times the weight of mint (g/ml), add 3% activated carbon by liquid weight, heat and stir in a water bath at 80°C, and filter with suction.

实施例2Example 2

本实施例与实施例1不同点在于所述步骤步骤三中还加入有1.5g的金黄荷荷巴油,所述步骤七中还加入有2g的旱莲草提取液。所述的旱莲草提取液通过以下方法制备:称取旱莲草30g,提取2次,第1次加15倍水量,提取1h,第2次用10倍水量,提取1h,每次用3层纱布滤过,合并滤液,加热浓缩至旱莲草重量的5倍(g/ml),过滤即得。The difference between this example and Example 1 is that 1.5 g of golden jojoba oil is added in step three of the step, and 2 g of Eclipta chinensis extract is also added in step seven. The described Eclipta extract is prepared by the following method: Weigh 30 g of Eclipta, extract 2 times, add 15 times of water for the first time, extract for 1 hour, use 10 times of water for the second time, extract for 1 hour, and use 3 times for each extraction. Filter with a layer of gauze, combine the filtrates, heat and concentrate to 5 times the weight of Eclipta chinensis (g/ml), and filter to obtain the product.

实施例3Example 3

本实施例抗静电、防辐射洗发膏通过如下步骤制得:The present embodiment antistatic, anti-radiation shampoo is made through the following steps:

步骤一:称取0.8冰晶形成剂AVC,溶于80ml水中,搅拌均匀,静置2h待其自然溶胀溶解;Step 1: Weigh 0.8 of the ice crystal forming agent AVC, dissolve in 80ml of water, stir evenly, and let it stand for 2 hours until it swells and dissolves naturally;

步骤二:称取阳离子瓜尔胶1g,溶于80ml水中,搅拌均匀,与80℃水中继续搅拌至溶解,常温下冷却30min,得调理剂B;Step 2: Weigh 1 g of cationic guar gum, dissolve it in 80 ml of water, stir evenly, continue stirring with 80°C water until dissolved, and cool at room temperature for 30 minutes to obtain conditioner B;

步骤三:称取小麦胚芽油4g、乳木果油3g、椰子油3g、金黄荷荷巴油1.5g、硬脂酸0.5g、液晶型自增稠乳化剂Lipomulse LUXE 3g置于烧杯中,水浴80℃加热,为油相;Step 3: Weigh 4g of wheat germ oil, 3g of shea butter, 3g of coconut oil, 1.5g of golden jojoba oil, 0.5g of stearic acid, and 3g of liquid crystal self-thickening emulsifier Lipomulse LUXE, and put them in a beaker. Heating at 80°C, it is the oil phase;

步骤四:称取蒸馏水20g,水浴80℃加热,为水相;Step 4: Weigh 20g of distilled water and heat it in a water bath at 80°C to form the water phase;

步骤五:等油相已澄清透明,水相、油相达到相同温度的情况下,将水相呈细流状加入油相中,边加边搅拌,形成乳剂基质C;Step 5: When the oil phase is clear and transparent, and the water phase and the oil phase have reached the same temperature, add the water phase into the oil phase in a thin stream, and stir while adding to form an emulsion matrix C;

步骤六:称取蒸馏水15g,加入脂肪醇聚氧乙烯醚硫酸钠2g、荷兰乳酸钠4g、椰油酰胺基丙基甜菜碱CAB 3g、烷基糖苷APG 2g、月桂酰肌氨酸钠LS30 3g、水溶性Ve 0.5g、海藻糖1g、聚季铵盐3g、生物多糖胶FUCOGEL 1.5P 3g、十二烷基硫酸钠0.8g、氯化钠0.5g,搅拌溶解,得溶液D;Step 6: Weigh 15g of distilled water, add 2g of fatty alcohol polyoxyethylene ether sodium sulfate, 4g of Dutch lactate, 3g of cocamidopropyl betaine CAB, 2g of alkyl glycoside APG, 3g of sodium lauroyl sarcosinate LS30, water soluble Add 0.5g of Ve, 1g of trehalose, 3g of polyquaternium, 3g of biopolysaccharide gum FUCOGEL 1.5P, 0.8g of sodium lauryl sulfate, and 0.5g of sodium chloride, stir and dissolve to obtain solution D;

步骤七:往乳剂基质C中加入无患子提取液3g、旱莲草提取液3g、薄荷提取液3g,搅拌混合均匀,再加入凝胶A、调理剂B、溶液D,搅拌混合均匀;Step 7: Add 3g of Sapindus chinensis extract, 3g of Eclipta chinensis extract, and 3g of Peppermint extract into emulsion base C, stir and mix evenly, then add gel A, conditioning agent B, solution D, stir and mix evenly;

步骤八:称取乙二胺四乙酸二钠0.04g、尼泊金乙酯或山梨酸0.3g、加入蒸馏水15ml,加热使其溶解,加入g)体系中,再加入香精0.09ml,用20%柠檬酸溶液0.7ml,调节pH值为7后,搅拌15min,混合均匀,即得抗静电、防辐射洗发膏。这里可以根据不同的需求添加香精,所述的香精为青瓜香精、玫瑰香精、桂花香精、水蜜桃香精、柠檬香精、菠萝香精、茉莉香精中的一种或几种。Step 8: Weigh 0.04g of disodium edetate, 0.3g of ethylparaben or sorbic acid, add 15ml of distilled water, heat to dissolve, add to the g) system, then add 0.09ml of essence, and use 20% 0.7ml of citric acid solution, adjust the pH value to 7, stir for 15 minutes, and mix evenly to obtain an antistatic and anti-radiation shampoo. Essence can be added here according to different requirements, and the essence is one or more of cucumber essence, rose essence, sweet-scented osmanthus essence, peach essence, lemon essence, pineapple essence, and jasmine essence.

其中无患子提取物的制备:无患子剥去内核,称取40g,再浸泡1h,加热至100℃,煎煮提取3次,第1次加9倍量水,提取1.5h,第2次加9倍量水,提取1h,第3次加7倍量水,提取1h,每次滤过,合并滤液,滤液的体积浓缩至无患子重量的4倍(g/ml),过滤即得。Among them, the preparation of Sapindus chinensis extract: Peel off the inner core of Sapindus chinensis, weigh 40g, then soak for 1h, heat to 100°C, decoct and extract 3 times, add 9 times the amount of water for the first time, extract for 1.5h, the second time Add 9 times the amount of water for the first time, extract 1h, add 7 times the amount of water for the 3rd time, extract 1h, filter each time, combine the filtrate, the volume of the filtrate is concentrated to 4 times (g/ml) of the weight of Sapindus chinensis, and filter have to.

其中旱莲草提取液的制备:称取旱莲草50g,提取2次,第1次加15倍水量,提取1h,第2次用12倍水量,提取1h,每次用3层纱布滤过,合并滤液,加热浓缩至旱莲草重量的5倍(g/ml),过滤即得。The preparation of Eclipta chinensis extract: Weigh 50g of Eclipta chinensis, extract 2 times, add 15 times of water for the first time, extract for 1 hour, use 12 times of water for the second time, extract for 1 hour, filter with 3 layers of gauze each time , combine the filtrates, heat and concentrate to 5 times the weight of Eclipta (g/ml), and filter to obtain.

其中薄荷提取液的制备:称取薄荷30g,浸泡1h,回流提取3次,第1次加15倍量水,提取1.5h,第2次加12倍量水,提取1h,第3次加9倍量水,提取1h,每次滤过,合并滤液,滤液的体积浓缩至薄荷重量的6倍(g/ml),加液体重量3%活性炭,80℃水浴加热搅拌,抽滤,即可。The preparation of peppermint extract: Weigh 30g of mint, soak for 1h, reflux extraction for 3 times, add 15 times of water for the first time, extract for 1.5h, add 12 times of water for the second time, extract for 1h, add 9 times for the third time Double the amount of water, extract for 1 hour, filter each time, combine the filtrates, concentrate the volume of the filtrates to 6 times the weight of mint (g/ml), add 3% activated carbon by liquid weight, heat and stir in a water bath at 80°C, and filter with suction.

实施例1、2、3的理化指标及结果如下:The physicochemical index and the result of embodiment 1,2,3 are as follows:

性状:各实施例均为粘稠度适宜,泡沫丰富,凉爽舒适,稳定性好,气味芬芳,细腻均匀的乳白色洗发膏。Properties: All examples are creamy white shampoos with suitable viscosity, rich foam, cool and comfortable, good stability, fragrant smell, fine and uniform.

取各实施例所得洗发膏,用pH计测定,测得pH值为6.0-7.0之间。Get each embodiment gained shampoo cream, measure with pH meter, record pH value between 6.0-7.0.

将各洗发膏封装于透明化妆品瓶中,于4℃的冰箱冷藏一个月观察无分层现象。于55℃的恒温箱内24h,洗发膏无分层、变味等现象。Each shampoo cream was packaged in a transparent cosmetic bottle, and refrigerated in a refrigerator at 4°C for one month to observe that there was no delamination. In a constant temperature box at 55°C for 24 hours, the shampoo has no delamination and odor change.

将各洗发膏封装于具塞试管中3000r/min,离心20min,无分层现象。Each shampoo was packaged in a stoppered test tube at 3000r/min, and centrifuged for 20min, without delamination.

将实施例1、2、3所制的洗发膏置于化妆品瓶中,室温静置考察6个月,无分层现象,用后感觉无变化,气味无变化。The shampoo cream made by Examples 1, 2, and 3 is placed in a cosmetic bottle, and left standing at room temperature for 6 months, there is no delamination phenomenon, no change in feeling after use, and no change in smell.

刺激性试验、过敏性实验Irritation test, allergy test

小白鼠背部剪去毛,分别涂抹按实施例1、2、3制备的洗发膏于剪去毛的部位,用少量水搓出泡沫,然后用清水洗净,和没涂部位进行比较,结果没有刺激性和过敏反应。The hair on the back of the mouse was cut off, and the shampoo cream prepared in Example 1, 2, and 3 was applied to the cut hair respectively, and foam was rubbed out with a small amount of water, then washed with clear water, and compared with the uncoated part, the result No irritation and allergic reaction.

志愿者(15-65岁,150人)用实施例1、2、3制备的洗发膏洗头,过30分钟后观察,头皮均没出现发红、发疹、起泡现象,头发也没有出现干涩、枯燥的现象,且在使用过程中发现该洗发膏质地均匀,易出泡沫,泡沫细腻,易洗净,气味芬芳,洗后感觉头发柔顺、有光泽,富有弹性。Volunteers (15-65 years old, 150 people) wash their hair with the shampoo cream prepared by embodiment 1, 2, 3, observe after 30 minutes, there is no redness, rash, and blistering phenomenon in the scalp, and there is no hair loss. Dryness and dryness appear, and during use, it is found that the shampoo has a uniform texture, is easy to produce foam, fine foam, easy to clean, and has a fragrant smell. After washing, the hair feels soft, shiny and elastic.

洗发膏综合效果考察Investigation on Comprehensive Effect of Shampoo

以下利用试用感觉来评价实施例1、2、3制造出的洗发膏的功效。采用民意调查评分法,选取150名25-65岁年龄段的人作为试用对象,任意等分成三组,分别用实施例1、2、3制备的洗发膏清洁头发。每周洗头两次,使用时间为两个月。各项使用效果总分为5分:5分为最高分,表示较好,非常满意;4分为很好;3分为可以接受;3分以下为不好,不能接受。以下为各项平均得分,结果见表1:The efficacy of the shampoos produced in Examples 1, 2, and 3 will be evaluated by using the trial feeling below. Adopt public opinion survey scoring method, select 150 people in the age group of 25-65 as trial subjects, arbitrarily divide into three groups equally, clean hair with the shampoo cream prepared in embodiment 1, 2, 3 respectively. Shampoo twice a week for two months. The total score of each use effect is 5 points: 5 points is the highest score, which means good and very satisfied; 4 points is very good; 3 points are acceptable; below 3 points are bad and unacceptable. The following is the average score of each item, and the results are shown in Table 1:

表1综合效果考察Table 1 Comprehensive effect investigation

综上所述,该洗发膏细腻柔滑,有很好滋养性、保湿性和抗静电效果,使用时感觉很清爽舒适,清洗方便,且泡沫细腻稳定。实施例2为本发明较优选的实施例。To sum up, the shampoo is delicate and smooth, with good nourishing, moisturizing and antistatic effects. It feels refreshing and comfortable when used, easy to clean, and the foam is fine and stable. Embodiment 2 is a preferred embodiment of the present invention.

对实施例2、3乌发效果测试To embodiment 2,3 black hair effect test

选取100名25-40岁年龄段的头发有焦黄情况的人作为试用对象,任意等分成两组,试验前,先通过拍照以及各自减掉少量头发做对比用。然后分别用实施例2、3制备的洗发膏清洁头发。每周洗头3次,使用时间为3个月,期间每隔一个月各自取少量头发对比观察。试验结束后,通过观察,记录实验结果可以看出两组人的头发焦黄情况均有所改善,且随着使用时间的加长,乌黑现象越明显。由此实验可以看出本洗发膏具有较好的乌黑头发的效果,长期使用头发乌黑发亮、飘逸柔顺。Select 100 people in the 25-40 age group with browned hair as the trial subjects, and randomly divide them into two groups. Before the test, take pictures and lose a small amount of hair for comparison. Then clean the hair with the shampoo cream prepared in Examples 2 and 3 respectively. Wash your hair 3 times a week and use it for 3 months. During this period, take a small amount of hair every other month for comparison and observation. After the test, by observing and recording the experimental results, it can be seen that the brown hair of the two groups of people has improved, and with the prolongation of the use time, the black phenomenon is more obvious. Can find out that this shampoo has the effect of pitch-black hair preferably from this experiment, and long-term use hair pitch-black shiny, elegant and supple.

本发明并不局限于上述实施例,在不脱离本发明精神及其实质情况下,本领域的普通技术人员可根据本发明做出各种相应改变和变形,这些相应对本发明进行的修改或者等同替换,其均应涵盖在本发明的权利要求保护的范围当中。The present invention is not limited to the above-mentioned embodiments. Without departing from the spirit and essence of the present invention, those skilled in the art can make various corresponding changes and deformations according to the present invention. These corresponding modifications or equivalents to the present invention Replacement, all of which should be included in the scope of protection of the claims of the present invention.

Claims (3)

1.一种抗静电、防辐射洗发膏制备方法,包括如下步骤:1. a preparation method of antistatic, anti-radiation shampoo, comprising the steps of: 步骤一:称取0.1-1g冰晶形成剂AVC,溶于30-100ml的水中,搅拌均匀,静置2-3h,待其自然溶胀溶解,得凝胶A;Step 1: Weigh 0.1-1g of ice crystal forming agent AVC, dissolve in 30-100ml of water, stir evenly, let it stand for 2-3h, and wait for its natural swelling and dissolution to obtain gel A; 步骤二:称取阳离子瓜尔胶1-2g,溶于30-100ml的水中,搅拌均匀,于70-90℃水浴中继续搅拌至溶解,常温下冷却30min,得调理剂B;Step 2: Weigh 1-2g of cationic guar gum, dissolve it in 30-100ml of water, stir evenly, continue stirring in a water bath at 70-90°C until dissolved, and cool at room temperature for 30 minutes to obtain conditioner B; 步骤三:称取小麦胚芽油2-10g、乳木果油1-5g、椰子油1-5g、硬脂酸0.1-1g、液晶型自增稠乳化剂Lipomulse LUXE 2-3g置于烧杯中,水浴70-90℃加热,为油相;Step 3: Weigh 2-10g of wheat germ oil, 1-5g of shea butter, 1-5g of coconut oil, 0.1-1g of stearic acid, and 2-3g of liquid crystal self-thickening emulsifier Lipomulse LUXE into a beaker, Heating in a water bath at 70-90°C is the oil phase; 步骤四:称取蒸馏水10-25g,水浴70-90℃加热,为水相;Step 4: Weigh 10-25g of distilled water and heat in a water bath at 70-90°C to form the water phase; 步骤五:等油相已澄清透明,水相、油相达到相同温度的情况下,将水相呈细流状加入油相中,边加边搅拌,形成乳剂基质C;Step 5: When the oil phase is clear and transparent, and the water phase and the oil phase have reached the same temperature, add the water phase into the oil phase in a thin stream, and stir while adding to form an emulsion matrix C; 步骤六:称取蒸馏水10-30g,加入脂肪醇聚氧乙烯醚硫酸钠1-5g、荷兰乳酸钠2-10g、椰油酰胺基丙基甜菜碱CAB 1-5g、烷基糖苷APG 1-5g、月桂酰肌氨酸钠LS30 1-5g、水溶性Ve0.1-1g、海藻糖1-2g、聚季铵盐1-5g、生物多糖胶FUCOGEL 1.5P 1-5g、十二烷基硫酸钠0.1-3g、氯化钠0.1-3g,搅拌溶解,得溶液D;Step 6: Weigh 10-30g of distilled water, add 1-5g of fatty alcohol polyoxyethylene ether sodium sulfate, 2-10g of Dutch lactate sodium, 1-5g of cocamidopropyl betaine CAB, 1-5g of alkyl glycoside APG, Sodium lauroyl sarcosinate LS30 1-5g, water-soluble Ve0.1-1g, trehalose 1-2g, polyquaternium salt 1-5g, biopolysaccharide gum FUCOGEL 1.5P 1-5g, sodium lauryl sulfate 0.1 -3g, 0.1-3g of sodium chloride, stirred and dissolved to obtain solution D; 步骤七:向乳剂基质C中加入无患子提取液1-5g、薄荷提取液1-5g,搅拌混合均匀,再加入凝胶A、调理剂B、溶液D,搅拌混合均匀;Step 7: Add 1-5g of Sapinberry extract and 1-5g of Peppermint extract to emulsion base C, stir and mix evenly, then add gel A, conditioning agent B, solution D, stir and mix evenly; 步骤八:称取乙二胺四乙酸二钠0.01-0.05g、尼泊金乙酯或山梨酸0.1-0.3g、加入蒸馏水5-18ml,加热使其溶解,加入步骤七体系中,再加入香精0.05-0.3ml,用20%柠檬酸溶液0.1-3ml,调节pH值为6.5-7.5后,搅拌10-15min,混合均匀,即得抗静电、防辐射洗发膏;Step 8: Weigh 0.01-0.05g of disodium edetate, 0.1-0.3g of ethylparaben or sorbic acid, add 5-18ml of distilled water, heat to dissolve, add to the system of step 7, and then add flavor 0.05-0.3ml, use 0.1-3ml of 20% citric acid solution, adjust the pH value to 6.5-7.5, stir for 10-15min, and mix evenly to obtain antistatic and anti-radiation shampoo; 所述的无患子提取物通过以下方法制备:取剥去内核的无患子,浸泡0.15-1h,加热至90-100℃,煎煮提取3次,第1次加6-12倍量水,提取0.5-2h,第2次加4-10倍量水,提取0.5-1.5h,第3次加3-8倍量水,提取0.5-1.5h,每次滤过,合并滤液,滤液的体积浓缩至无患子重量的3-6倍g/ml,过滤即得;The Sapindus chinensis extract is prepared by the following method: take the sapinsia chinensis peeled off the inner core, soak for 0.15-1h, heat to 90-100°C, decoct and extract 3 times, add 6-12 times the amount of water for the first time , extract 0.5-2h, add 4-10 times the amount of water for the second time, extract 0.5-1.5h, add 3-8 times the amount of water for the third time, extract 0.5-1.5h, filter each time, combine the filtrate, the filtrate The volume is concentrated to 3-6 times g/ml of the weight of Sapindus chinensis, and it is obtained by filtration; 所述的薄荷提取液通过以下方法制备:取薄荷浸泡0.5-1h,回流提取3次,第1次加10-15倍量水,提取0.5-2h,第2次加8-12倍量水,提取0.5-1.5h,The mint extract is prepared by the following method: soak mint for 0.5-1 h, reflux extraction 3 times, add 10-15 times the amount of water for the first time, extract for 0.5-2 h, add 8-12 times the amount of water for the second time, Extract 0.5-1.5h, 第3次加6-10倍量水,提取0.5-1.5h,每次滤过,合并滤液,滤液的体积浓缩至薄荷重量的4-7倍g/ml,加液体重量1%-5%活性炭,60-100℃水浴加热搅拌,抽滤,取滤液;Add 6-10 times the amount of water for the third time, extract for 0.5-1.5 hours, filter each time, combine the filtrate, concentrate the volume of the filtrate to 4-7 times the weight of mint g/ml, add 1%-5% activated carbon by liquid weight , heated and stirred in a water bath at 60-100°C, filtered with suction, and took the filtrate; 所述步骤七中还加入有1-5g的旱莲草提取液。In the step seven, 1-5 g of Eclipta chinensis extract is also added. 2.根据权利要求1所述的抗静电、防辐射洗发膏制备方法,其特征在于:所述步骤步骤三中还加入有1-5g的金黄荷荷巴油。2. The preparation method of antistatic and anti-radiation shampoo according to claim 1, characterized in that: 1-5g of golden jojoba oil is also added in the step 3. 3.根据权利要求1所述的抗静电、防辐射洗发膏制备方法,其特征在于,所述的旱莲草提取液通过以下方法制备:取旱莲草,回流提取2次,第1次加10-18倍水量,提取0.5-1.5h,第2次用10-12倍水量,提取0.5-1.5h,每次用3层纱布滤过,合并滤液,加热浓缩至旱莲草重量的2-10倍g/ml,过滤即得。3. The antistatic and anti-radiation shampoo preparation method according to claim 1, characterized in that, the described Eclipta extract is prepared by the following method: take Eclipta, reflux extraction 2 times, the first time Add 10-18 times the amount of water, extract for 0.5-1.5 hours, use 10-12 times the amount of water for the second time, extract for 0.5-1.5 hours, filter each time with 3 layers of gauze, combine the filtrates, heat and concentrate to 2% of the weight of Eclipta -10 times g/ml, obtained by filtration.
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