CN104861987B - Soil improvement conditioner and its preparation method and application - Google Patents
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Abstract
本发明公开了一种中度盐碱化土壤改良调理剂及其制备方法和应用。其中,土壤改良调理剂包括:55‑60重量份的钙盐,18‑23重量份的生物质焦炭,10‑15重量份的生物质水溶液和10‑12重量份的有机化肥。该土壤改良调理剂可以快速有效地改善土壤碱化程度高、肥力低、土壤pH值高和土壤团块化等多种问题,并且该土壤改良调理剂的价格低廉,重金属含量低。The invention discloses a moderate salinization soil improvement conditioner as well as its preparation method and application. Wherein, the soil improvement conditioner includes: 55-60 parts by weight of calcium salt, 18-23 parts by weight of biomass coke, 10-15 parts by weight of biomass aqueous solution and 10-12 parts by weight of organic fertilizer. The soil improvement conditioner can quickly and effectively improve various problems such as high soil alkalization degree, low fertility, high soil pH value and soil agglomeration, and the soil improvement conditioner has low price and low heavy metal content.
Description
技术领域technical field
本发明涉及农业领域,具体地,涉及土壤改良调理剂及其制备方法和应用,更具体地,涉及土壤改良调理剂、制备土壤改良调理剂方法和改良中度盐碱化土壤的方法。The present invention relates to the field of agriculture, in particular to a soil improvement conditioner and its preparation method and application, more specifically to a soil improvement conditioner, a method for preparing the soil improvement conditioner and a method for improving moderately salinized soil.
背景技术Background technique
我国分布有大片盐碱地,盐碱化的程度正在扩大。土地盐碱化不仅仅使得我国的农业大量减产,造成了很大的损失,还由于盐碱化程度的日趋严重,使得大片土地逐渐成为了废地。改造盐碱地并提高盐碱耕地的农业生产量,是我国农业发展的重要任务之一。There are large areas of saline-alkali land distributed in our country, and the degree of salinization is expanding. The salinization of land not only causes a large amount of agricultural production reduction in our country, but also causes a lot of losses. Due to the increasingly serious degree of salinization, large areas of land have gradually become wasteland. Transforming saline-alkali land and improving the agricultural production of saline-alkali cultivated land is one of the important tasks of agricultural development in my country.
我国盐碱地改良的历史悠久,已发展出多种改良方法和技术,涉及的农艺或工程技术方法主要可分为:物理改良(如土地平整、深耕晒垡、台田改土等)、水利改良(如灌排洗研、暗管排盐等)、化学改良(如施用石膏、磷石膏、腐殖酸等)、以及生物改良(如耐盐植物种植、微生物改良等)。这些改良技术均有一定效果,也存在一定的不足。如淡水洗盐可降低土壤含盐量,但对碱度降低的效果不显著,耗水量大,易引起植作物生长必需的矿物质元素流失。生物改良普适性差,见效慢,成本相对较高。The improvement of saline-alkali land in my country has a long history, and a variety of improvement methods and technologies have been developed. The agronomic or engineering technology methods involved can be mainly divided into: physical improvement (such as land leveling, deep plowing and sunning, terrace field improvement, etc.), water conservancy improvement ( Such as irrigation and drainage, washing and research, salt drainage in hidden pipes, etc.), chemical improvement (such as application of gypsum, phosphogypsum, humic acid, etc.), and biological improvement (such as planting of salt-tolerant plants, microbial improvement, etc.). These improved technologies all have certain effects, but also have certain deficiencies. For example, washing salt with fresh water can reduce the salinity of the soil, but the effect on reducing the alkalinity is not significant, and the water consumption is large, which may easily cause the loss of mineral elements necessary for plant growth. Biological improvement has poor universality, slow effect and relatively high cost.
土壤改良剂的研究开发是化学改良技术的核心。中国专利申请CN101624523公开的“一种盐碱改良剂”,是按不同重量比由硫酸铝、硫酸亚铁铵和硫酸镁混合配制而成,制成该改良剂需要大量的化学原材料,而不是利用工业废弃物,成本较高。中国专利申请CN1377936A公开的“利用废石膏板生产盐碱土壤改良剂的方法及其产品和应用”,利用石膏中的硫酸钙置换土壤中的交换性钠,但需要将废石膏板进行加工破碎才能用来改良土壤。如果破碎后改良剂粒度大,则不利于离子置换反应,改良效果差;若要破碎后改良剂粒度很小,则要耗费大量的能量,使土壤改良的成本高到农民无法承受。专利CN201110124738.5公开的“用电厂废弃物及泥炭、风化煤资源改良盐碱土壤的组合物”利用脱硫石膏、粉煤灰等电厂废弃物和风化煤资源混合物作为改良剂,由于粉煤灰中的重金属含量较高,会引起改良后的土壤中重金属及有害微量元素超过国家标准的允许值。一些专利如CN03111936.0、CN200910117619.X等,涉及改良剂组分配方复杂。The research and development of soil conditioner is the core of chemical improvement technology. Chinese patent application CN101624523 discloses "a kind of saline-alkali improver", which is prepared by mixing aluminum sulfate, ferrous ammonium sulfate and magnesium sulfate according to different weight ratios. It needs a large amount of chemical raw materials to make the improver, instead of using Industrial waste is expensive. Chinese patent application CN1377936A discloses "Using waste gypsum board to produce saline-alkali soil improver method and its product and application", which uses calcium sulfate in gypsum to replace exchangeable sodium in soil, but waste gypsum board needs to be processed and broken to Used to improve soil. If the particle size of the improver after crushing is large, it is not conducive to the ion exchange reaction, and the improvement effect is poor; if the particle size of the improver after crushing is small, it will consume a lot of energy, making the cost of soil improvement too high for farmers to bear. Patent CN201110124738.5 discloses "composition for improving saline-alkali soil with power plant waste, peat, and weathered coal resources" using a mixture of power plant waste such as desulfurized gypsum and fly ash and weathered coal resources as a modifier. The high content of heavy metals in soil will cause the heavy metals and harmful trace elements in the improved soil to exceed the allowable value of the national standard. Some patents, such as CN03111936.0, CN200910117619.X, etc., involve complex formulations of improver components.
因此,目前的土壤改良剂有待于进一步研究。Therefore, the current soil conditioner needs to be further studied.
发明内容Contents of the invention
本发明旨在至少解决现有技术中存在的技术问题之一。为此,本发明的一个目的在于提出一种生物改良普适性好,见效快,价格低廉,并且重金属含量低的土壤改良剂,该土壤改良剂适于盐碱化土壤的改良,尤其适用于中度盐碱化土壤的改良。The present invention aims to solve at least one of the technical problems existing in the prior art. For this reason, an object of the present invention is to propose a kind of soil improver with good universality of biological improvement, quick effect, low price, and low heavy metal content, which is suitable for the improvement of saline-alkali soil, especially for Improvement of moderately salinized soils.
根据本发明的一个方面,本发明提供了一种土壤改良调理剂。根据本发明的实施例,该土壤改良调理剂包括:55-60重量份的钙盐,18-23重量份的生物质焦炭,10-15重量份的生物质水溶液和10-12重量份的有机化肥。According to one aspect of the present invention, the present invention provides a soil improvement conditioner. According to an embodiment of the present invention, the soil improvement conditioner includes: 55-60 parts by weight of calcium salt, 18-23 parts by weight of biomass coke, 10-15 parts by weight of biomass aqueous solution and 10-12 parts by weight of organic fertilizer.
根据本发明的实施例,本发明的土壤改良调理剂可以快速有效地改善土壤的碱化程度高、肥力低、土壤pH值高和土壤团块化等多种问题。并且该土壤改良调理剂的价格低廉,有机物含量高,重金属含量低。According to the embodiments of the present invention, the soil improvement conditioner of the present invention can quickly and effectively improve various problems such as high degree of alkalization of the soil, low fertility, high soil pH value and soil agglomeration. Moreover, the price of the soil improving conditioner is low, the content of organic matter is high, and the content of heavy metals is low.
根据本发明的另一方面,本发明提供了一种制备土壤改良调理剂的方法。根据本发明的实施例,该方法包括:将生物质有机物与钙盐进行混合,以便得到第一混合物;将所述第一混合物进行热处理,以便得到热处理固态产物和热处理液态产物,其中,所述热处理固态产物包含:生物质焦炭和的所述钙盐;将所述热处理液态产物进行静置分层并分离水相,所述水相构成所述生物质水溶液;向所述热处理固态产物中加入有机化肥,进行第一搅拌处理,以便得到第二混合物;以及向所述第二混合物中加入所述生物质水溶液,进行第二搅拌处理,以便得到所述土壤改良调理剂。According to another aspect of the present invention, the present invention provides a method for preparing a soil improvement conditioner. According to an embodiment of the present invention, the method includes: mixing biomass organic matter and calcium salt to obtain a first mixture; and heat-treating the first mixture to obtain a heat-treated solid product and a heat-treated liquid product, wherein the The heat-treated solid product includes: biomass coke and the calcium salt; the heat-treated liquid product is subjected to static layering and the water phase is separated, and the water phase constitutes the biomass aqueous solution; organic fertilizer, performing a first stirring treatment to obtain a second mixture; and adding the biomass aqueous solution to the second mixture, performing a second stirring treatment, so as to obtain the soil improvement conditioner.
根据本发明的实施例,利用本发明的方法,将钙盐和与生物质有机物混合后直接进行热处理,无需对生物质有机物和钙盐进行破碎预处理,简化了生产工艺,还可以提高焦炭的产率,并且,钙盐加热释放水,冷凝回收后,收取得到的热处理液态产物的产率也提高。同时,本发明的方法生产工艺简单,生产成本低,制备得到的土壤改良调理剂的有机物含量高,重金属含量低,能快速、有效地增强土壤肥力。According to the embodiment of the present invention, using the method of the present invention, the calcium salt and the biomass organic matter are mixed and then heat-treated directly, without crushing and pretreatment of the biomass organic matter and calcium salt, which simplifies the production process and can also improve the coke. Moreover, the calcium salt is heated to release water, and after condensation and recovery, the yield of the heat-treated liquid product obtained by charging is also improved. At the same time, the method of the invention has simple production process and low production cost, and the prepared soil improvement conditioner has high organic content and low heavy metal content, and can quickly and effectively enhance soil fertility.
根据本发明的再一方面,本发明提供了一种改良中度盐碱化土壤的方法。根据本发明的实施例,该方法对所述中度盐碱化土壤施用前述土壤改良调理剂。According to yet another aspect of the present invention, the present invention provides a method for improving moderately salinized soil. According to an embodiment of the present invention, the method applies the aforementioned soil improvement conditioner to the moderately salinized soil.
根据本发明的实施例,利用本发明的土壤改良调理剂可以快速有效地对中度盐碱化土壤进行改良,该土壤改良调理剂可以有效降低土壤的碱化度,增强土壤的肥力,降低土壤的pH值,并改善土壤的团粒结构。According to the embodiments of the present invention, moderate salinization soil can be improved quickly and effectively by using the soil improvement conditioner of the present invention. The soil improvement conditioner can effectively reduce the alkalinity of the soil, enhance the fertility of the soil, reduce the pH value, and improve the aggregate structure of the soil.
本发明的附加方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本发明的实践了解到。Additional aspects and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention.
附图说明Description of drawings
本发明的上述和/或附加的方面和优点从结合下面附图对实施例的描述中将变得明显和容易理解,其中:The above and/or additional aspects and advantages of the present invention will become apparent and comprehensible from the description of the embodiments in conjunction with the following drawings, wherein:
图1显示了根据本发明一个实施例的制备土壤改良调理剂的流程图。Fig. 1 shows a flow chart of preparing a soil improvement conditioner according to one embodiment of the present invention.
具体实施方式Detailed ways
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。Embodiments of the present invention are described in detail below, examples of which are shown in the drawings, wherein the same or similar reference numerals designate the same or similar elements or elements having the same or similar functions throughout. The embodiments described below by referring to the figures are exemplary only for explaining the present invention and should not be construed as limiting the present invention.
土壤改良调理剂Soil Improvement Conditioner
根据本发明的一个方面,本发明提供了一种土壤改良调理剂。根据本发明的实施例,该土壤改良调理剂包括:55-60重量份的钙盐,18-23重量份的生物质焦炭,10-15重量份的生物质水溶液和10-12重量份的有机化肥。According to one aspect of the present invention, the present invention provides a soil improvement conditioner. According to an embodiment of the present invention, the soil improvement conditioner includes: 55-60 parts by weight of calcium salt, 18-23 parts by weight of biomass coke, 10-15 parts by weight of biomass aqueous solution and 10-12 parts by weight of organic fertilizer.
根据本发明的实施例,本发明钙盐中的钙离子(Ca2+)可以与土壤胶体上的可代换性钠离子进行离子交换,使钠离子从土壤胶体进入土壤溶液后随灌溉水下渗或经由排水渠排走,从而,降低土壤的碱化度,改善土壤的团粒结构。根据本发明的实施例,本发明的生物质焦炭,是多孔的富碳聚合物,略呈碱性,可以吸附和固定土壤里的盐分离子和水分,保持土壤湿度,为土壤微生物繁殖提供场所,同时在一定程度上阻断毛细通道,降低土壤颗粒盐份,改善土壤结构和盐碱土颗粒团聚特性。根据本发明的实施例,生物质水溶液中含有大量乙酸、丙酸、丙酮等,可以提高土壤的有机质含量,结合有机菌肥,增加土壤肥力,为作物生长提供营养成份,并且可以降低碱土的pH值,改善土壤的碱化情况。由此,本发明的土壤改良调理剂可以针对土壤的多种问题进行改良,该土壤改良剂可以有效降低土壤的碱化度,增强土壤的肥力,降低土壤的pH值,改善土壤的团粒结构。并且该土壤改良调理剂的价格低廉,有机物含量高,重金属含量低,能快速、有效地增强土壤肥力。According to an embodiment of the present invention, the calcium ion (Ca 2+ ) in the calcium salt of the present invention can carry out ion exchange with the substitutable sodium ion on the soil colloid, so that the sodium ion enters the soil solution from the soil colloid and then goes under the irrigation water. Seepage or discharge through drainage channels, thereby reducing the alkalinity of the soil and improving the aggregate structure of the soil. According to an embodiment of the present invention, the biomass coke of the present invention is a porous carbon-rich polymer, which is slightly alkaline, can absorb and fix salt ions and water in the soil, maintain soil moisture, and provide a place for soil microorganisms to reproduce. At the same time, it blocks the capillary channel to a certain extent, reduces the salinity of soil particles, and improves the soil structure and the aggregation characteristics of saline-alkali soil particles. According to the embodiments of the present invention, the biomass aqueous solution contains a large amount of acetic acid, propionic acid, acetone, etc., which can increase the organic matter content of the soil, combine with organic bacterial fertilizer, increase soil fertility, provide nutrients for crop growth, and reduce the pH of alkaline soil value to improve the alkalization of the soil. Therefore, the soil improving conditioner of the present invention can improve various problems of the soil, and the soil improving agent can effectively reduce the alkalization degree of the soil, enhance the fertility of the soil, reduce the pH value of the soil, and improve the aggregate structure of the soil. Moreover, the soil improvement conditioner has low price, high organic matter content and low heavy metal content, and can quickly and effectively enhance soil fertility.
根据本发明的具体实施例,生物质焦炭和生物质水溶液是通过以下步骤得到的:将生物质有机物与钙盐进行混合,得到第一混合物;将该第一混合物进行热处理,得到热处理固态产物和热处理液态产物,其中,热处理固态产物包含:生物质焦炭和钙盐;将热处理液态产物进行静置分层并分离水相,该水相构成生物质水溶液。发明人惊奇地发现,将钙盐和与生物质有机物混合后直接进行热处理,生物质有机物热处理生成小体积的焦炭,从而,省略了对生物质有机物进行破碎预处理的过程,简化了生产工艺,还可以提高焦炭的产率,并且,钙盐加热释放水,冷凝回收后,收取得到的生物质水溶液产率也提高。According to a specific embodiment of the present invention, biomass coke and biomass aqueous solution are obtained through the following steps: mixing biomass organic matter with calcium salt to obtain a first mixture; subjecting the first mixture to heat treatment to obtain a heat-treated solid product and The heat-treated liquid product, wherein the heat-treated solid product includes: biomass coke and calcium salt; the heat-treated liquid product is subjected to static layering and the water phase is separated, and the water phase constitutes an aqueous solution of biomass. The inventor surprisingly found that after mixing the calcium salt and the biomass organic matter, heat treatment is performed directly, and the heat treatment of the biomass organic matter generates small-volume coke, thereby omitting the process of crushing the biomass organic matter and simplifying the production process. It can also increase the yield of coke, and the calcium salt is heated to release water, and after condensation and recovery, the yield of the biomass aqueous solution obtained by charging is also improved.
其中,需要说明的是,钙盐在热处理过程中会出现脱水,在本发明中,脱水后的钙盐和未经脱水处理的钙盐均可用于本发明的土壤改良调理剂,对土壤改良调理剂的成份无影响,并且对土壤的改良效果也无影响。Wherein, it should be noted that calcium salts will be dehydrated in the heat treatment process. In the present invention, calcium salts after dehydration and calcium salts without dehydration treatment can be used in the soil improvement conditioner of the present invention, which can improve the condition of soil. The composition of the agent has no effect, and it has no effect on the improvement effect of the soil.
根据本发明的具体实施例,生物质有机物为选自锯末、木屑和农作物秸秆的至少一种,其中,农作物秸秆可以是玉米秸秆、小麦秸秆、水稻秸秆等农业生产的废弃物。由此,利用锯末、木屑和农作物秸秆等生产废弃物做为土壤改良调理剂的原料,可以对生产的废物利用,并且,土壤改良调理剂的成本低。According to a specific embodiment of the present invention, the biomass organic matter is at least one selected from sawdust, wood chips, and crop straw, wherein the crop straw can be agricultural waste such as corn straw, wheat straw, and rice straw. Thus, production waste such as sawdust, sawdust, and crop stalks can be used as raw materials for the soil improvement conditioner, and the production waste can be utilized, and the cost of the soil improvement conditioner is low.
根据本发明的一些实施例,钙盐为脱硫石膏。其中,需要说明的是,脱硫石膏是燃煤电厂石灰石-石膏法烟气湿法脱硫工艺的副产物,有效成分CaSO4.2H2O在脱硫石膏中的含量为60-92%。脱硫石膏中的钙离子(Ca2+)可以与土壤胶体上的可代换性钠离子进行交换,使钠离子从土壤胶体进入土壤溶液后随灌溉水下渗或经由排水渠排走,降低土壤的碱化度,并改善土壤的团粒结构。According to some embodiments of the present invention, the calcium salt is desulfurized gypsum. Among them, it should be noted that desulfurization gypsum is a by-product of limestone-gypsum flue gas wet desulfurization process in coal-fired power plants, and the content of active ingredient CaSO4.2H 2 O in desulfurization gypsum is 60-92%. Calcium ions (Ca 2+ ) in desulfurized gypsum can be exchanged with replaceable sodium ions on the soil colloid, so that the sodium ions enter the soil solution from the soil colloid and then infiltrate with irrigation water or drain away through drainage channels, reducing soil Alkalinity, and improve the aggregate structure of the soil.
根据本发明的一些实施例,生物质有机物与钙盐的重量比不受特别的限制,可以根据土壤的问题调整比例,例如,土壤的的碱化问题严重,可以提高钙盐的比例,土壤的盐份高,土壤团块严重,则可以提供生物质有机物的比例,优选地,生物质有机物与钙盐的重量比为0.6-1.4:1。由此,按该比例混合制备的土壤改良调理剂可以有效的降低土壤碱化程度,改善土壤结构和土壤颗粒团聚情况。According to some embodiments of the present invention, the weight ratio of biomass organic matter to calcium salt is not particularly limited, and the ratio can be adjusted according to the problem of the soil. For example, the alkalinization problem of the soil is serious, and the ratio of calcium salt can be increased. If the salinity is high and the soil lumps are serious, the ratio of biomass organic matter can be provided. Preferably, the weight ratio of biomass organic matter to calcium salt is 0.6-1.4:1. Therefore, the soil improvement conditioner prepared by mixing in this proportion can effectively reduce the degree of soil alkalization and improve the soil structure and the aggregation of soil particles.
根据本发明的具体实施例,钙盐的粒径为至多50微米。由此,钙盐与土壤的接触面积大,促进钙离子与土壤中的可代换性钠离子进行离子置换反应,对土壤的改良效果好。According to a particular embodiment of the invention, the particle size of the calcium salt is at most 50 microns. Therefore, the contact area between the calcium salt and the soil is large, and the ion exchange reaction between the calcium ion and the replaceable sodium ion in the soil is promoted, and the improvement effect on the soil is good.
根据本发明的具体实施例,热处理为烘焙、干馏或热解。由此,热处理获得的焦炭和热处理液态产物的产率高,热处理效果好。According to a specific embodiment of the present invention, the heat treatment is baking, dry distillation or pyrolysis. Thus, the coke obtained by the heat treatment and the heat treatment liquid product have a high yield, and the heat treatment effect is good.
根据本发明的具体实施例,热处理在温度为280-500℃,惰性气氛的条件下进行的,其中,惰性气氛为烟气或惰性气体。由此,热处理得到的产物不易被氧化,且焦炭和热处理液态产物的产率高,热处理效果好。According to a specific embodiment of the present invention, the heat treatment is carried out at a temperature of 280-500° C. under an inert atmosphere, wherein the inert atmosphere is flue gas or inert gas. Therefore, the product obtained by heat treatment is not easy to be oxidized, and the yield of coke and liquid product of heat treatment is high, and the effect of heat treatment is good.
根据本发明的具体实施例,生物质水溶液的pH值小于7,可直接降低碱土的pH值。并且,生物质水溶液还可以含有大量乙酸、丙酸、丙酮等,土壤改良调理剂的有机质含量高,结合有机菌肥,有利于增加土壤肥力,为作物生长提供营养成份。According to a specific embodiment of the present invention, the pH value of the biomass aqueous solution is less than 7, which can directly reduce the pH value of the alkaline earth. Moreover, the biomass aqueous solution can also contain a large amount of acetic acid, propionic acid, acetone, etc., and the soil improvement conditioner has a high content of organic matter. Combined with organic bacterial fertilizer, it is beneficial to increase soil fertility and provide nutrients for crop growth.
根据本发明的一些实施例,有机化肥为益生菌群发酵化肥,即向市售的有机化肥中加入益生菌群进行发酵,获得的化肥。由此,该有机化肥中含有大量益生菌群发酵产物,有机化肥的肥力高。According to some embodiments of the present invention, the organic fertilizer is a fertilizer fermented with probiotic flora, that is, a fertilizer obtained by adding probiotic flora to commercially available organic fertilizers for fermentation. Therefore, the organic fertilizer contains a large amount of fermentation products of probiotic flora, and the organic fertilizer has high fertility.
根据本发明的具体实施例,益生菌群为选自嗜盐碱杆菌、乳酸菌、醋酸菌、酵母菌和光合菌的至少之一。由此,益生菌群的发酵效果好,有机化肥中含有大量有益的发酵产物,有机化肥的肥力高。According to a specific embodiment of the present invention, the probiotic group is at least one selected from halophilic bacteria, lactic acid bacteria, acetic acid bacteria, yeast and photosynthetic bacteria. Therefore, the fermentation effect of the probiotic group is good, the organic fertilizer contains a large amount of beneficial fermentation products, and the organic fertilizer has high fertility.
制备土壤改良调理剂的方法Method for preparing soil improvement conditioner
根据本发明的另一方面,本发明提供了一种制备土壤改良调理剂的方法。参考图1,对制备土壤改良调理剂的方法进行详细说明。According to another aspect of the present invention, the present invention provides a method for preparing a soil improvement conditioner. Referring to Fig. 1, the method for preparing the soil improvement conditioner is described in detail.
S100:混合S100: Hybrid
根据本发明的实施例,将生物质有机物与钙盐进行混合,得到第一混合物。由此,将生物质有机物和钙盐混合均匀,促进热解反应的进行,有利于提供焦炭和生物质水溶液的产率。According to an embodiment of the present invention, the biomass organic matter and the calcium salt are mixed to obtain the first mixture. Thus, the biomass organic matter and the calcium salt are evenly mixed, the pyrolysis reaction is promoted, and the yield of coke and biomass aqueous solution is improved.
根据本发明的具体实施例,生物质有机物为选自锯末、木屑和农作物秸秆的至少一种,其中,农作物秸秆可以是玉米秸秆、小麦秸秆、水稻秸秆等农业生产的废弃物。由此,利用锯末、木屑和农作物秸秆等生产废弃物做为土壤改良调理剂的原料,可以对生产的废物进行利用,并且,土壤改良调理剂的成本低。According to a specific embodiment of the present invention, the biomass organic matter is at least one selected from sawdust, wood chips, and crop straw, wherein the crop straw can be agricultural waste such as corn straw, wheat straw, and rice straw. Thus, production waste such as sawdust, sawdust, and crop stalks can be used as raw materials for the soil improvement conditioner, and the produced waste can be utilized, and the cost of the soil improvement conditioner is low.
根据本发明的一些实施例,钙盐为脱硫石膏。其中,需要说明的是,脱硫石膏是燃煤电厂石灰石-石膏法烟气湿法脱硫工艺的副产物,有效成分CaSO4·2H2O在脱硫石膏中的含量为60-92%。脱硫石膏中的钙离子(Ca2+)可以与土壤胶体上的可代换性钠离子进行交换,使钠离子从土壤胶体进入土壤溶液后随灌溉水下渗或经由排水渠排走,降低土壤的碱化度,并改善土壤的团粒结构状况。According to some embodiments of the present invention, the calcium salt is desulfurized gypsum. Among them, it should be noted that desulfurization gypsum is a by-product of limestone-gypsum flue gas wet desulfurization process in coal-fired power plants, and the content of active ingredient CaSO 4 ·2H 2 O in desulfurization gypsum is 60-92%. Calcium ions (Ca 2+ ) in desulfurized gypsum can be exchanged with replaceable sodium ions on the soil colloid, so that the sodium ions enter the soil solution from the soil colloid and then infiltrate with irrigation water or drain away through drainage channels, reducing soil Alkalinity, and improve the aggregate structure of the soil.
根据本发明的一些实施例,生物质有机物与钙盐的重量比不受特别的限制,可以根据土壤的问题调整比例,例如,土壤的的碱化问题严重,可以提高钙盐的比例,土壤的盐份高,土壤团块严重,则可以提供生物质有机物的比例,优选地,生物质有机物与钙盐的重量比为0.6-1.4:1。由此,按该比例混合制备的土壤改良调理剂可以有效的降低土壤碱化程度,改善土壤结构和土壤颗粒团聚情况。According to some embodiments of the present invention, the weight ratio of biomass organic matter to calcium salt is not particularly limited, and the ratio can be adjusted according to the problem of the soil. For example, the alkalinization problem of the soil is serious, and the ratio of calcium salt can be increased. If the salinity is high and the soil lumps are serious, the ratio of biomass organic matter can be provided. Preferably, the weight ratio of biomass organic matter to calcium salt is 0.6-1.4:1. Therefore, the soil improvement conditioner prepared by mixing in this proportion can effectively reduce the degree of soil alkalization and improve the soil structure and the aggregation of soil particles.
S200:热处理S200: heat treatment
将第一混合物进行热处理,得到热处理固态产物和热处理液态产物,其中,该热处理固态产物包含:生物质焦炭和钙盐。发明人惊奇地发现,将第一混合物进行热处理,生物质有机物生成小体积的焦炭,从而,省略了对生物质有机物和钙盐进行破碎预处理的过程,简化了生产工艺,还可以提高焦炭的产率,并且,钙盐加热释放水,冷凝回收后,收取得到的热处理液态产物的产率也提高了。The first mixture is heat-treated to obtain a heat-treated solid product and a heat-treated liquid product, wherein the heat-treated solid product includes: biomass coke and calcium salt. The inventors have surprisingly found that the first mixture is subjected to heat treatment, and the biomass organic matter generates small-volume coke, thereby omitting the process of crushing and pretreating the biomass organic matter and calcium salt, simplifying the production process, and improving the quality of the coke. Productivity, and, calcium salt heating releases water, after condensation recovery, the productive rate of the heat-treated liquid product that collects obtains has also improved.
其中,需要说明的是,钙盐在热处理过程中会出现脱水,在本发明中,脱水后的钙盐和未经脱水处理的钙盐均可用于本发明的土壤改良调理剂,对土壤改良调理剂的成份无影响,并且对土壤的改良效果也无影响。Wherein, it should be noted that calcium salts will be dehydrated in the heat treatment process. In the present invention, calcium salts after dehydration and calcium salts without dehydration treatment can be used in the soil improvement conditioner of the present invention, which can improve the condition of soil. The composition of the agent has no effect, and it has no effect on the improvement effect of the soil.
根据本发明的具体实施例,钙盐的粒径为至多50微米。由此,钙盐与土壤的接触面积大,促进钙离子与土壤中的可代换性钠离子进行离子置换反应,对土壤的改良效果好。According to a particular embodiment of the invention, the particle size of the calcium salt is at most 50 microns. Therefore, the contact area between the calcium salt and the soil is large, and the ion exchange reaction between the calcium ion and the replaceable sodium ion in the soil is promoted, and the improvement effect on the soil is good.
根据本发明的具体实施例,热处理为烘焙、干馏或热解。由此,热处理获得的焦炭和生物质水溶液的产率高,热处理效果好。According to a specific embodiment of the present invention, the heat treatment is baking, dry distillation or pyrolysis. Thus, the yield of coke and biomass aqueous solution obtained by heat treatment is high, and the effect of heat treatment is good.
根据本发明的具体实施例,热处理在温度为280-500℃,惰性气氛的条件下进行的,其中,惰性气氛为烟气或惰性气体。由此,热处理得到的产物不易被氧化,且焦炭和生物质水溶液的产率高,热处理效果好。According to a specific embodiment of the present invention, the heat treatment is carried out at a temperature of 280-500° C. under an inert atmosphere, wherein the inert atmosphere is flue gas or inert gas. Therefore, the product obtained by heat treatment is not easy to be oxidized, and the yield of coke and biomass aqueous solution is high, and the effect of heat treatment is good.
S300:静置分层S300: static layering
将热处理液态产物进行静置分层并分离水相,该水相构成生物质水溶液。由此,热处理过程中的挥发性产物在冷凝回收后形成热处理液态产物,这部分热处理液态产物静置后会形成两层,一层为不溶于水的焦油,一层为含有大量水溶性有机物的水相,这一层含有水溶性有机物的水相构成了生物质水溶液。该生物质水溶液中含有大量乙酸、丙酸、丙酮等,可以提高土壤的有机质含量,结合有机菌肥,增加土壤肥力,为作物生长提供营养成份。The heat-treated liquid product is allowed to stand for stratification and the water phase is separated, and the water phase constitutes an aqueous solution of biomass. Thus, the volatile products in the heat treatment process will form heat-treated liquid products after being condensed and recovered. This part of the heat-treated liquid products will form two layers after standing still, one is water-insoluble tar, and the other is tar containing a large amount of water-soluble organic matter. Water phase, this layer of water phase containing water-soluble organic matter constitutes the biomass aqueous solution. The biomass aqueous solution contains a large amount of acetic acid, propionic acid, acetone, etc., which can increase the organic matter content of the soil, combine with organic bacterial fertilizer, increase soil fertility, and provide nutrients for crop growth.
根据本发明的具体实施例,生物质水溶液的pH值小于7,呈酸性,可直接降低碱土的pH值,改善土壤的碱化情况。According to a specific embodiment of the present invention, the pH value of the biomass aqueous solution is less than 7 and is acidic, which can directly reduce the pH value of alkaline soil and improve the alkalization of the soil.
S400:第一搅拌处理S400: first stirring treatment
向热处理固态产物中加入有机化肥,进行第一搅拌处理,得到第二混合物。由此,有机化肥中含有大量的有机物,通过加入有机化肥,增加土壤改良调理剂的肥力。The organic fertilizer is added to the heat-treated solid product, and the first stirring treatment is performed to obtain the second mixture. Therefore, the organic fertilizer contains a large amount of organic matter, and the fertility of the soil improvement conditioner can be increased by adding the organic fertilizer.
根据本发明的一些实施例,有机化肥为益生菌群发酵化肥。由此,该有机化肥中含有大量益生菌群发酵产物,有机化肥的肥力高。According to some embodiments of the present invention, the organic fertilizer is a fertilizer fermented by probiotic flora. Therefore, the organic fertilizer contains a large amount of fermentation products of probiotic flora, and the organic fertilizer has high fertility.
根据本发明的具体实施例,益生菌群为选自嗜盐碱杆菌、乳酸菌、醋酸菌、酵母菌和光合菌的至少之一。由此,益生菌群的发酵效果好,有机化肥中含有大量有益的发酵产物,有机化肥的肥力高。According to a specific embodiment of the present invention, the probiotic group is at least one selected from halophilic bacteria, lactic acid bacteria, acetic acid bacteria, yeast and photosynthetic bacteria. Therefore, the fermentation effect of the probiotic group is good, the organic fertilizer contains a large amount of beneficial fermentation products, and the organic fertilizer has high fertility.
根据本发明的实施例,热处理固态产物与有机化肥的重量比不受特别的限制,可以根据待改良的土壤进行适当调整,若土壤中盐离子含量高,则可以增加热处理固态产物的比例,若土壤的肥力差,则可以增加有机化肥的比例,优选地,热处理固态产物与有机化肥的重量比为6-8:1。由此,按该比例混合制备的土壤改良调理剂可以有效的降低土壤中的含盐量,增强土壤的肥力。According to an embodiment of the present invention, the weight ratio of the heat-treated solid product to the organic fertilizer is not particularly limited, and can be appropriately adjusted according to the soil to be improved. If the content of salt ions in the soil is high, the ratio of the heat-treated solid product can be increased. If If the fertility of the soil is poor, the proportion of the organic fertilizer can be increased. Preferably, the weight ratio of the heat-treated solid product to the organic fertilizer is 6-8:1. Therefore, the soil improvement conditioner prepared by mixing in this ratio can effectively reduce the salt content in the soil and enhance the fertility of the soil.
S500:第二搅拌处理S500: Second stirring treatment
向第二混合物中加入生物质水溶液,进行第二搅拌处理,得到土壤改良调理剂。由于生物质水溶液的加入量较小,在第一搅拌后,再将生物质水溶液加入到第二混合物中,可以将生物质水溶液和第二混合物混合的更均匀。The biomass aqueous solution is added to the second mixture, and the second stirring treatment is performed to obtain a soil improvement conditioner. Since the addition amount of the biomass aqueous solution is small, after the first stirring, the biomass aqueous solution is added to the second mixture, so that the biomass aqueous solution and the second mixture can be mixed more uniformly.
根据本发明的具体实施例,第二混合物与生物质水溶液的重量比为7-9:1。由此,土壤改良调理剂对土壤的改良效果好,可以有效降低土壤的碱化度,增强土壤的肥力,降低土壤的pH值,改善土壤的团粒结构。According to a specific embodiment of the present invention, the weight ratio of the second mixture to the aqueous biomass solution is 7-9:1. Therefore, the soil improvement conditioner has a good improvement effect on the soil, can effectively reduce the alkalization degree of the soil, enhance the fertility of the soil, reduce the pH value of the soil, and improve the aggregate structure of the soil.
改良中度盐碱化土壤的方法Methods of improving moderately salinized soil
根据本发明的再一方面,本发明提供了一种改良中度盐碱化土壤的方法。根据本发明的实施例,该方法对中度盐碱化土壤施用前述土壤改良调理剂。According to yet another aspect of the present invention, the present invention provides a method for improving moderately salinized soil. According to an embodiment of the present invention, the method applies the aforementioned soil improvement conditioner to moderately salinized soil.
根据本发明的实施例,利用本发明的土壤改良调理剂可以快速有效地对中度盐碱化土壤进行改良,该土壤改良调理剂可以有效降低土壤的碱化度,增强土壤的肥力,降低土壤的pH值,并改善土壤的团粒结构状况。According to the embodiments of the present invention, moderate salinization soil can be improved quickly and effectively by using the soil improvement conditioner of the present invention. The soil improvement conditioner can effectively reduce the alkalinity of the soil, enhance the fertility of the soil, reduce the pH value, and improve the aggregate structure of the soil.
根据本发明的一些实施例,土壤改良调理剂的施用量为2500-3500kg/亩。根据本发明的实施例,低于该施用量,土壤改良调理剂的加入量过少,钙离子不足与土壤胶体中的钠离子进行置换反应,也无法使土壤的pH值调整到合理的水平,并且,对土壤肥力的改善效果不明显。如果高于该实施量,土壤改良调理剂的加入量过多,有可以造成土壤酸化,土壤的肥力过高,不利于植物的生长。According to some embodiments of the present invention, the application rate of the soil improvement conditioner is 2500-3500 kg/mu. According to the embodiment of the present invention, if the application rate is lower than the application amount, the addition amount of the soil improvement conditioner is too small, and the calcium ion is insufficient to carry out the replacement reaction with the sodium ion in the soil colloid, and the pH value of the soil cannot be adjusted to a reasonable level. Moreover, the improvement effect on soil fertility is not obvious. If it is higher than the implementation amount, the addition amount of the soil improvement conditioner is too much, which may cause soil acidification, and the fertility of the soil is too high, which is not conducive to the growth of plants.
根据本发明的具体实施例,中度盐碱化土壤的pH值9-10.5,碱化度10-25%,含盐量<0.9%。由此,土壤改良调理剂对土壤的改良效果好,可以显著改善土壤的碱化度,增强土壤的肥力,降低土壤的pH值,并改善土壤的团粒结构。According to a specific embodiment of the present invention, the moderately salinized soil has a pH value of 9-10.5, a degree of alkalinity of 10-25%, and a salt content of <0.9%. Therefore, the soil improvement conditioner has a good improvement effect on the soil, can significantly improve the alkalization degree of the soil, enhance the fertility of the soil, reduce the pH value of the soil, and improve the aggregate structure of the soil.
下面参考具体实施例,对本发明进行说明,需要说明的是,这些实施例仅仅是说明性的,而不能理解为对本发明的限制。The present invention will be described below with reference to specific embodiments. It should be noted that these embodiments are only illustrative and should not be construed as limiting the present invention.
实施例1Example 1
利用本发明的方法,制备一种改良调理剂,具体步骤如下:Utilize the method of the present invention, prepare a kind of improved conditioning agent, concrete steps are as follows:
(1)将65g脱硫石膏与50g水稻秸秆搅拌混合,放入固定反应容器内,固定反应容器前部连接氮气罐,后部连接套管冷凝器;(1) Stir and mix 65g of desulfurized gypsum and 50g of rice stalks, put them into a fixed reaction vessel, the front of the fixed reaction vessel is connected to a nitrogen tank, and the rear is connected to a sleeve condenser;
(2)向固定反应容器持续通入少量氮气,加热固定反应容器至400℃并保持1小时,气体产物通入套管冷凝器冷凝回收液体产物;(2) Continuously feed a small amount of nitrogen into the fixed reaction vessel, heat the fixed reaction vessel to 400° C. and keep it for 1 hour, and the gas product is passed into the sleeve condenser to condense and recover the liquid product;
(3)待反应器冷却到室温后,收集固体产物,简单碾压破碎后,与10g有机菌肥搅拌混合,液体产物静置分层后,过滤得到水相产物,取10g喷洒到固体产物与有机菌肥的混合物中并搅拌均匀,得到改良调理剂,其成份为:脱硫石膏60g、生物质焦炭20g、生物质水溶液10g和有机菌肥10g。(3) After the reactor is cooled to room temperature, collect the solid product, and after simple crushing and crushing, stir and mix with 10g of organic fertilizer. The mixture of organic bacterial manure is stirred evenly to obtain an improved conditioning agent, and its ingredients are: 60 g of desulfurized gypsum, 20 g of biomass coke, 10 g of biomass aqueous solution and 10 g of organic bacterial manure.
利用上述的改良调理剂处理土壤,待改良土壤pH=9,碱化度15%,含盐量0.5%,改良调理剂施用量为2700kg/亩。改良后土壤pH降低至7.5左右,碱化度降至5%以下,一次施用多年持续有效,在5-8年内无需重复施用改良。Utilize above-mentioned improved conditioner to treat soil, the soil to be improved has pH=9, alkalization degree 15%, salt content 0.5%, and the application rate of improved conditioner is 2700kg/mu. After the improvement, the pH of the soil is reduced to about 7.5, and the degree of alkalization is reduced to below 5%. One application can continue to be effective for many years, and there is no need for repeated application for improvement within 5-8 years.
实施例2Example 2
利用本发明的方法,制备一种改良调理剂,具体步骤如下:Utilize the method of the present invention, prepare a kind of improved conditioning agent, concrete steps are as follows:
(1)将60g脱硫石膏与70g锯末搅拌混合,放入固定反应容器内,固定反应容器前部连接氮气罐,后部连接套管冷凝器;(1) Stir and mix 60g of desulfurized gypsum and 70g of sawdust, put them into a fixed reaction vessel, the front of the fixed reaction vessel is connected to a nitrogen tank, and the rear is connected to a sleeve condenser;
(2)向固定反应容器持续通入少量氮气,加热固定反应容器至500℃并保持1小时,气体产物通入套管冷凝器冷凝回收液体产物;(2) Continuously feed a small amount of nitrogen into the fixed reaction vessel, heat the fixed reaction vessel to 500° C. and keep it for 1 hour, and the gas product is passed into the sleeve condenser to condense and recover the liquid product;
(3)待反应器冷却到室温后,收集固体产物,并与12g有机菌肥搅拌混合,液体产物静置分层后,过滤得到水相产物,取10g喷洒到固体产物与有机菌肥混合物中并搅拌均匀,得到改良调理剂,其成份为:脱硫石膏55g、生物质焦炭23g、生物质水溶液10g和有机菌肥12g。(3) After the reactor is cooled to room temperature, collect the solid product and mix it with 12g of organic fertilizer. After the liquid product is allowed to stand and separate, filter to obtain the water phase product, and spray 10g of it into the mixture of the solid product and the organic fertilizer. and stir evenly to obtain an improved conditioner, the ingredients of which are: 55g of desulfurized gypsum, 23g of biomass coke, 10g of biomass aqueous solution and 12g of organic bacterial fertilizer.
利用上述的改良调理剂处理土壤,待改良土壤pH=10,碱化度20%,含盐量0.7%,改良调理剂施用量3200kg/亩。改良后土壤pH降低至7.5左右,碱化度降至5%以下,一次施用多年持续有效,在5-8年内无需重复施用改良。Utilize the above-mentioned improved conditioner to treat the soil, the pH of the soil to be improved is 10, the degree of alkalization is 20%, the salt content is 0.7%, and the application rate of the improved conditioner is 3200kg/mu. After the improvement, the pH of the soil is reduced to about 7.5, and the degree of alkalization is reduced to below 5%. One application can continue to be effective for many years, and there is no need for repeated application for improvement within 5-8 years.
实施例3Example 3
利用本发明的方法,制备一种改良调理剂,具体步骤如下:Utilize the method of the present invention, prepare a kind of improved conditioning agent, concrete steps are as follows:
(1)将62g脱硫石膏与55g木屑搅拌混合,放入固定反应容器内,固定反应容器前部连接氮气罐,后部连接套管冷凝器;(1) Stir and mix 62g of desulfurized gypsum and 55g of sawdust, put them into a fixed reaction vessel, the front of the fixed reaction vessel is connected to a nitrogen tank, and the rear is connected to a sleeve condenser;
(2)向固定反应容器持续通入少量氮气,加热固定反应容器至500℃并保持1小时,气体产物通入套管冷凝器冷凝回收液体产物;(2) Continuously feed a small amount of nitrogen into the fixed reaction vessel, heat the fixed reaction vessel to 500° C. and keep it for 1 hour, and the gas product is passed into the sleeve condenser to condense and recover the liquid product;
(3)待反应器冷却到室温后,收集固体产物,并与11g有机菌肥搅拌混合,液体产物静置分层后,过滤得到水相产物,取15g喷洒到固体产物与有机菌肥混合物中并搅拌均匀,得到改良调理剂,其成份为:脱硫石膏58g、生物质焦炭18g、生物质水溶液15g和有机菌肥11g。(3) After the reactor is cooled to room temperature, collect the solid product and mix it with 11g of organic fertilizer. After the liquid product is allowed to stand and separate, filter to obtain the water phase product, and spray 15g into the mixture of the solid product and the organic fertilizer. and stir evenly to obtain an improved conditioner, the composition of which is: 58g of desulfurized gypsum, 18g of biomass coke, 15g of biomass aqueous solution and 11g of organic bacterial fertilizer.
利用上述的改良调理剂处理土壤,待改良土壤pH=10,碱化度20%,含盐量0.7%,改良调理剂施用量3200kg/亩。改良后土壤pH降低至7.5左右,碱化度降至5%以下,一次施用多年持续有效,在5-8年内无需重复施用改良。Utilize the above-mentioned improved conditioner to treat the soil, the pH of the soil to be improved is 10, the degree of alkalization is 20%, the salt content is 0.7%, and the application rate of the improved conditioner is 3200kg/mu. After the improvement, the pH of the soil is reduced to about 7.5, and the degree of alkalization is reduced to below 5%. One application can continue to be effective for many years, and there is no need for repeated application for improvement within 5-8 years.
在本说明书的描述中,参考术语“一个实施例”、“一些实施例”、“示例”、“具体示例”、或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, descriptions referring to the terms "one embodiment", "some embodiments", "example", "specific examples", or "some examples" mean that specific features described in connection with the embodiment or example , structure, material or characteristic is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiment or example. Furthermore, the specific features, structures, materials or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
尽管已经示出和描述了本发明的实施例,本领域的普通技术人员可以理解:在不脱离本发明的原理和宗旨的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those skilled in the art can understand that various changes, modifications, substitutions and modifications can be made to these embodiments without departing from the principle and spirit of the present invention. The scope of the invention is defined by the claims and their equivalents.
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