CN104928082A - Preparing method for composite type gentle and moistening soap base - Google Patents
Preparing method for composite type gentle and moistening soap base Download PDFInfo
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- CN104928082A CN104928082A CN201510340825.2A CN201510340825A CN104928082A CN 104928082 A CN104928082 A CN 104928082A CN 201510340825 A CN201510340825 A CN 201510340825A CN 104928082 A CN104928082 A CN 104928082A
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- 239000000344 soap Substances 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title abstract description 13
- 239000002131 composite material Substances 0.000 title abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 45
- 238000007127 saponification reaction Methods 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229930006000 Sucrose Natural products 0.000 claims abstract description 14
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 7
- 239000000194 fatty acid Substances 0.000 claims abstract description 7
- 229930195729 fatty acid Natural products 0.000 claims abstract description 7
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims description 22
- 150000002632 lipids Chemical class 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 239000013543 active substance Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 13
- 239000005720 sucrose Substances 0.000 claims description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 239000003921 oil Substances 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 235000013311 vegetables Nutrition 0.000 claims description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 3
- 239000005639 Lauric acid Substances 0.000 claims description 3
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 3
- 230000007062 hydrolysis Effects 0.000 claims description 3
- 238000006460 hydrolysis reaction Methods 0.000 claims description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000003346 palm kernel oil Substances 0.000 claims description 3
- 235000019865 palm kernel oil Nutrition 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- 239000000811 xylitol Substances 0.000 claims description 3
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 3
- 235000010447 xylitol Nutrition 0.000 claims description 3
- 229960002675 xylitol Drugs 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 23
- 239000002699 waste material Substances 0.000 abstract description 7
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- 238000004090 dissolution Methods 0.000 abstract 1
- 239000002085 irritant Substances 0.000 abstract 1
- 231100000021 irritant Toxicity 0.000 abstract 1
- 239000008213 purified water Substances 0.000 abstract 1
- 229960004793 sucrose Drugs 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 235000019633 pungent taste Nutrition 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- 241000237502 Ostreidae Species 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000020636 oyster Nutrition 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention provides a preparing method for a composite type gentle and moistening soap base. The preparing method for the composite type gentle and moistening soap base comprises the steps that saponification reaction is carried out on fatty acid with the proportion ranging from 8% to 30%, polyhydric alcohol with the proportion ranging from 20% to 52%, cane sugar with the proportion ranging from 8% to 27.5%, purified water with the proportion ranging from 3% to 22%, a surface active agent with the proportion ranging from 1% to 18% through sodium hydroxide with the proportion ranging from 3% to 7.5%. The method has the advantages that repeated dissolution can be achieved, the utilization rate can be increased, polyhydric alcohol moisture components are added in the production process, the skin irritant of the soap is lowered, and the moisture degree on the skin is improved. Wastes are not produced in the producing process, big-scaled devices and middle-scaled devices are not needed, a producing device is simple, and minimum conditions and factory mass production conditions exist. In addition, the repeated utilization rate of the soap base is high, redissolution can be carried out on the soap with the mass production due to the inaccurate statistical quantity during producing, the soap with other types can be manufactured, and the resource wastes cannot be caused.
Description
Technical field
The present invention relates to the technical field of soap, refer more particularly to the preparation method that a kind of compound gentleness moistens soap base.
Background technology
Traditional perfumed soap (representative has comfortable good perfumed soap, vertical white perfumed soap etc.) mainly manufactures raw material: soap base (perfumed soap hereafter mentioned makes raw material and all refers to soap base) can only rely on heavy-duty machines equipment vegetables oil or animal oil, recovery wet goods by following sodium hydroxide to carry out and saponification reaction obtain soap base, water and glycerine, extrude shaping after soap base is carried out vacuum-drying and become neat soap, byproduct glycerine and effluent part, the method is relatively traditional, there is certain waste water to produce, the place of certain area need be possessed and buy expensive equipment and technician.
If this soap base occurs that in production link mishandle will cause this batch all to be scrapped, cauldron can not be thrown back for regenerative ratio, cause the waste of resource.
This soap base has taken out the glycerin components with moisturizing effect in production final tache, residue major part is fatty dry soda soap, if wash for the production of middle and high ends such as the clean facial soaps of makeup and protect product and non-optimal, pungency is large, alkalescence (pH value) is high, and cleaning capacity easily allows by force people do not feel like oneself.
The traditional perfumed soap adopting this soap base to make also needs the using area of corresponding big-and-middle-sized equipment and certain area, machine energy consumption is large, conflict with energy-saving and emission-reduction, production process is many, from feeding intake → be uniformly mixed → grinding chips → extrude shaping → punching press printing → final product, is also not suitable for little Wei enterprise that current government encourage develops and electric commercial business industry.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, providing the preparation method that a kind of compound gentleness moistens soap base.
The present invention is realized by above technical scheme:
The invention provides the preparation method that a kind of compound gentleness moistens soap base, the preparation method that this compound gentleness moistens soap base is: by the pure water of the sucrose of the polyvalent alcohol of the lipid acid of 8% ~ 30% ratio, 20% ~ 52% ratio, 8% ~ 27.5% ratio, 3% ~ 22% ratio, the tensio-active agent of 1% ~ 18% ratio by carrying out saponification reaction with the sodium hydroxide of 3% ~ 7.5% ratio.
Preferably, the titanium dioxide also comprising interpolation 0.05% ~ 0.12% ratio carries out saponification reaction.
Preferably, described the pure water of the sucrose of the polyvalent alcohol of the lipid acid of 8% ~ 30% ratio, 20% ~ 52% ratio, 8% ~ 27.5% ratio, 3% ~ 22% ratio, the tensio-active agent of 1% ~ 18% ratio to be specially by carrying out saponification reaction with the sodium hydroxide of 3% ~ 7.5% ratio:
The lipid acid of 8% ~ 30% ratio is heated until dissolve completely in heating cylinder;
Add the polyvalent alcohol of 20% ~ 52% ratio fully to mix with lipid acid, and with the speed of per minute 36 turns at the uniform velocity dispersed with stirring 8 ~ 20 minutes;
The tensio-active agent adding 1% ~ 18% ratio continues stirring 5 ~ 20 minutes;
The sodium hydroxide of the pure water and 3% ~ 7.5% ratio that add 3% ~ 22% ratio continues stirring allows each composition fully carry out saponification reaction for 10 ~ 20 minutes;
Stop heating after the sucrose adding 8% ~ 27.5% ratio stirs and stir;
Leave standstill to allow for 2 ~ 10 minutes and obtain compound gentleness after the removal of foam and moisten soap base.
Preferably, described the fatty acids of 8% ~ 30% ratio to be heated until consoluet temperature controls between 70 ~ 90 degree in heating cylinder.
Preferably, described lipid acid is the higher fatty acid that vegetables oil obtains after High Temperature High Pressure continuous hydrolysis.
Preferably, described vegetables oil is plam oil, palm-kernel oil or Oleum Cocois.
Preferably, described lipid acid is lauric acid, tetradecanoic acid, palmitinic acid or stearic acid.
Preferably, described polyvalent alcohol is propylene glycol, glycerol, Xylitol or sorbyl alcohol.
The invention has the beneficial effects as follows: have repeatedly to melt and increase operation rate, production link is added with polyvalent alcohol moisturizing composition, the pungency reducing soap improves the moist degree to skin simultaneously.And do not produce waste material (byproduct), waste water, waste gas in production link, all adding materials are all fully saponified, to environment and ecological pollution-free.Adopt plurality of raw materials by accurate compound proportioning, in raw material, major part is all pharmaceutical grade or food grade materials.And in process of production, this soap base is adopted to make finished product soap without the need to big-and-middle-sized equipment, production unit is simple, minimal condition can be had to follow factory's volume production condition: minimal condition, only needs a beaker or high temperature resistant utensil, a heating installation, a mould, can complete the process making finished product soap from soap base, need not the machine knowledge of complicated specialty, without the need to excessive place, 10 square meter ~ 20 square meters just can solve place problem.Factory's volume production condition: the place of 70 square meters, a stainless steel heating cylinder, Zhang Gong's station, some moulds, 2 ~ 4 workmans can operate volume production.
In addition, this soap base repeating utilization factor is high, for the soap that the output that production causes because statistical magnitude is inaccurate is too much, can be made into the soap of other type, can not cause the waste in resource after dissolving again.
Accompanying drawing explanation
Fig. 1 is the schema that compound gentleness that the embodiment of the present invention provides moistens the preparation method of soap base.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiments provide the preparation method that a kind of compound gentleness moistens soap base, the preparation method that this compound gentleness moistens soap base is:
By the pure water of the sucrose of the polyvalent alcohol of the lipid acid of 8% ~ 30% ratio, 20% ~ 52% ratio, 8% ~ 27.5% ratio, 3% ~ 22% ratio, the tensio-active agent of 1% ~ 18% ratio by carrying out saponification reaction with the sodium hydroxide of 3% ~ 7.5% ratio.
In the above-mentioned methods, can be found out by each composition, the preparation method of the soap base provided in present method has repeatedly to melt and increases operation rate, and production link is added with in polyvalent alcohol has moisturizing composition, and the pungency reducing soap improves the moist degree to skin simultaneously.Do not produce waste material (byproduct), waste water, waste gas in production link, all adding materials are all fully saponified, to environment and ecological pollution-free.Adopt plurality of raw materials by accurate compound proportioning, in raw material, major part is all pharmaceutical grade or food grade materials.In concrete production process, this soap base is adopted to make finished product soap without the need to big-and-middle-sized equipment, minimal condition can be had to follow factory's volume production condition: minimal condition, only need a beaker or high temperature resistant utensil, a heating installation, a mould, the process making finished product soap from soap base can be completed, need not the machine knowledge of complicated specialty, without the need to excessive place, 10 square meter ~ 20 square meters just can solve place problem.Factory's volume production condition: places more than 70 square meters, a stainless steel heating cylinder, Zhang Gong's station, some moulds, 2 ~ 4 workmans can operate volume production.
In addition, this soap base repeating utilization factor is high, for the soap that the output that production causes because statistical magnitude is inaccurate is too much, can be made into the soap of other type, can not cause the waste in resource after dissolving again.
In addition, when the soap base needing preparation oyster white opaque, titanium dioxide can be added, concrete, in mentioned component, add the titanium dioxide of 0.05% ~ 0.12% ratio, after saponification reaction, form the opaque soap base of oyster white.
In order to the making method of the soap base that the detailed understanding embodiment of the present invention provides, below in conjunction with accompanying drawing 1, its production stage is described in detail.
Step 001: the lipid acid of 8% ~ 30% ratio is heated until dissolve completely in heating cylinder;
Concrete, the lipid acid that the present embodiment adopts is the higher fatty acid that vegetables oil obtains after High Temperature High Pressure continuous hydrolysis.Be specially: lauric acid, tetradecanoic acid, palmitinic acid or stearic acid.The vegetables oil adopted when preparing higher fatty acid can be plam oil, palm-kernel oil or Oleum Cocois.In addition, when heating for dissolving, temperature controls between 70 ~ 90 degree.As: the temperature arbitrarily between 70 ~ 90 degree such as 70 degree, 75 degree, 80 degree, 85 degree, 90 degree.
Step 002, add the polyvalent alcohol of 20% ~ 52% ratio and fully mix with lipid acid, and with the speed of per minute 36 turns at the uniform velocity dispersed with stirring 8 ~ 20 minutes;
In concrete whipping process, the time length can be 8 minutes, 10 minutes, 15 minutes, 20 minutes etc. arbitrarily between the time of 8 ~ 20 minutes, and fully to mix between polyvalent alcohol with lipid acid after ensureing to stir.This well-mixed standard is get the liquid of the unit volume of different positions, and in different unit liquid, the error of the ratio shared by both is in the scope of setting.
Polyvalent alcohol wherein can adopt different polyvalent alcohols, as propylene glycol, glycerol, Xylitol or sorbyl alcohol.
The tensio-active agent of step 003, interpolation 1% ~ 18% ratio continues stirring 5 ~ 20 minutes;
The sodium hydroxide of step 004, the pure water adding 3% ~ 22% ratio and 3% ~ 7.5% ratio continues stirring allows each composition fully carry out saponification reaction for 10 ~ 20 minutes;
Stop heating after step 005, the sucrose adding 8% ~ 27.5% ratio stir and stir;
Step 006, leave standstill to allow for 2 ~ 10 minutes and obtain compound gentleness after the removal of foam and moisten soap base.
In above-mentioned concrete preparation method, heterogeneity can adopt different ratios, the proportional range of each composition when preparing soap base is given in above-mentioned concrete preparation method, when specifically using, can select according to the proportional range in above-mentioned each composition, enumerate below several specifically prepare soap base time composition.
Embodiment 1
By the pure water of the sucrose of the polyvalent alcohol of the lipid acid of 8% ratio, 20% ratio, 25% ratio, 22% ratio, the tensio-active agent of 18% ratio by carrying out saponification reaction with sodium hydroxide 7%.
Embodiment 2
By the pure water of the sucrose of the polyvalent alcohol of the lipid acid of 30% ratio, 20% ratio, 22% ratio, 3% ratio, the tensio-active agent of 18% ratio by carrying out saponification reaction with sodium hydroxide 7%.
Embodiment 3
By the tensio-active agent of the pure water of the sucrose of the polyvalent alcohol of the lipid acid of 20% ratio, 30% ratio, 20% ratio, 15% ratio, 9.95% ratio, 0.05% titanium dioxide by carrying out saponification reaction with sodium hydroxide 5%.
Embodiment 4
By the pure water of the sucrose of the polyvalent alcohol of lipid acid 40% ratio of 20% ratio, 10% ratio, 15% ratio, the tensio-active agent of 11.9% ratio, the titanium dioxide of 0.1% ratio by carrying out saponification reaction with sodium hydroxide 3%.
Embodiment 5
By the pure water of the sucrose of the polyvalent alcohol of the lipid acid of 15% ratio, 52% ratio, 26% ratio, 3% ratio, the tensio-active agent of 1% ratio by carrying out saponification reaction with sodium hydroxide 3%.
Can be found out by above-mentioned specific embodiment, the preparation method of the soap base that the present embodiment provides can select according to the proportional range of each composition provided, thus the required soap base of system.
These are only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1. a compound gentleness moistens the preparation method of soap base, it is characterized in that, by the pure water of the sucrose of the polyvalent alcohol of the lipid acid of 8% ~ 30% ratio, 20% ~ 52% ratio, 8% ~ 27.5% ratio, 3% ~ 22% ratio, the tensio-active agent of 1% ~ 18% ratio by carrying out saponification reaction with the sodium hydroxide of 3% ~ 7.5% ratio.
2. compound gentleness according to claim 1 moistens the preparation method of soap base, it is characterized in that, the titanium dioxide also comprising interpolation 0.05% ~ 0.12% ratio carries out saponification reaction.
3. compound gentleness according to claim 2 moistens the preparation method of soap base, it is characterized in that, described the pure water of the sucrose of the polyvalent alcohol of the lipid acid of 8% ~ 30% ratio, 20% ~ 52% ratio, 8% ~ 27.5% ratio, 3% ~ 22% ratio, the tensio-active agent of 1% ~ 18% ratio to be specially by carrying out saponification reaction with the sodium hydroxide of 3% ~ 7.5% ratio:
The lipid acid of 8% ~ 30% ratio is heated until dissolve completely in heating cylinder;
Add the polyvalent alcohol of 20% ~ 52% ratio fully to mix with lipid acid, and with the speed of per minute 36 turns at the uniform velocity dispersed with stirring 8 ~ 20 minutes;
The tensio-active agent adding 1% ~ 18% ratio continues stirring 5 ~ 20 minutes;
The sodium hydroxide of the pure water and 3% ~ 7.5% ratio that add 3% ~ 22% ratio continues stirring allows each composition fully carry out saponification reaction for 10 ~ 20 minutes;
Stop heating after the sucrose adding 8% ~ 27.5% ratio stirs and stir;
Leave standstill to allow for 2 ~ 10 minutes and obtain compound gentleness after the removal of foam and moisten soap base.
4. compound gentleness according to claim 3 moistens the preparation method of soap base, it is characterized in that, describedly in heating cylinder, heats the fatty acids of 8% ~ 30% ratio until consoluet temperature controls between 70 ~ 90 degree.
5. compound gentleness according to claim 1 moistens the preparation method of soap base, it is characterized in that, described lipid acid is the higher fatty acid that vegetables oil obtains after High Temperature High Pressure continuous hydrolysis.
6. compound gentleness according to claim 5 moistens the preparation method of soap base, it is characterized in that, described vegetables oil is plam oil, palm-kernel oil or Oleum Cocois.
7. compound gentleness according to claim 5 moistens the preparation method of soap base, it is characterized in that, described lipid acid is lauric acid, tetradecanoic acid, palmitinic acid or stearic acid.
8. compound gentleness according to claim 1 moistens the preparation method of soap base, it is characterized in that, described polyvalent alcohol is propylene glycol, glycerol, Xylitol or sorbyl alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510340825.2A CN104928082A (en) | 2015-06-18 | 2015-06-18 | Preparing method for composite type gentle and moistening soap base |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510340825.2A CN104928082A (en) | 2015-06-18 | 2015-06-18 | Preparing method for composite type gentle and moistening soap base |
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| CN104928082A true CN104928082A (en) | 2015-09-23 |
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| CN201510340825.2A Pending CN104928082A (en) | 2015-06-18 | 2015-06-18 | Preparing method for composite type gentle and moistening soap base |
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| CN106883959A (en) * | 2017-02-24 | 2017-06-23 | 浙江如美日化有限公司 | A kind of Chinese torreya essential oil soap |
| CN106978288A (en) * | 2017-05-05 | 2017-07-25 | 陈磊 | A kind of handmade soap containing Composition of Meteorite and preparation method thereof |
| CN109179745A (en) * | 2018-08-29 | 2019-01-11 | 杭州轩辉环境设备有限公司 | A kind for the treatment of process for the waste water producing fatty acid generation |
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