CN104946011B - Method for preparing quick-dry ink - Google Patents
Method for preparing quick-dry ink Download PDFInfo
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- CN104946011B CN104946011B CN201510455344.6A CN201510455344A CN104946011B CN 104946011 B CN104946011 B CN 104946011B CN 201510455344 A CN201510455344 A CN 201510455344A CN 104946011 B CN104946011 B CN 104946011B
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- 238000000034 method Methods 0.000 title claims abstract description 6
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 10
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- -1 diacetone acrylamides Chemical class 0.000 claims description 6
- 150000002576 ketones Chemical class 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 230000000844 anti-bacterial effect Effects 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- 239000003085 diluting agent Substances 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 229920005610 lignin Polymers 0.000 claims description 5
- 239000010445 mica Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical class OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropyl acetate Chemical class CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 3
- MTJGVAJYTOXFJH-UHFFFAOYSA-N 3-aminonaphthalene-1,5-disulfonic acid Chemical compound C1=CC=C(S(O)(=O)=O)C2=CC(N)=CC(S(O)(=O)=O)=C21 MTJGVAJYTOXFJH-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 8
- 238000012546 transfer Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000013456 study Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a method for preparing quick-dry ink. The ink adopts acrylic resin which is prepared according to a specific process and can improve the drying rate of the ink, besides, keto-aldehyde resin and waterborne polyurethane resin are also added, so that the drying rate of the ink is further increased.
Description
Technical field
The present invention relates to a kind of preparation method of rapid-curing cutback ink.
Background of invention
Water color ink is with water as solvent or the ink of disperse medium, is mainly made up of binder, pigment and auxiliary agent etc..
With various paint, the development of coating, research and the application of water color ink have also obtained very big development.Although water color ink has
There is environmental protection, free from environmental pollution, the advantages of being harmful to human health, but as which is emerging ink, many performance studys are also
It is immature, many problems are remained in actual applications, so as to hinder its development to a certain extent.Due to aqueouss oil
, mainly with water as solvent, the boiling point of water is higher than the boiling point of common organic solvents for ink, thus when being dried, water color ink is dried
Time is longer than the drying time of solvent type ink.The speed of drying property directly affects the height of cost.It is dried too slowly, prolongs
The time of long production, can also increase cost.Water color ink rate of drying is excessively slow, causes print speed printing speed to reduce, extends manufacture cycle,
Cause ink when being transferred on printable fabric, ink is also dried completely, and dot gain is easily caused when of the same colour under chromatography,
Level is difficult to enrich.
The content of the invention
For solve ink the problems referred to above, the present invention employ in ink special process preparation be conducive to improve ink
The acrylic resin of dry rate, while also added ketone resin and waterborne polyurethane resin, further increases ink
Dry rate.
For achieving the above object, present invention employs following technical scheme：
A kind of preparation method of rapid-curing cutback ink, comprises the steps：
A) following component is weighed in terms of parts by weight：20 parts of ketone resins, 10 parts of waterborne polyurethane resins, 10 parts of acrylic acid
Resin, 40 parts of distilled water, 1 part of levelling agent, 1 part of defoamer, 0.5 part of antibacterial, 1.3 parts of diluent, in adding agitator, with
The speed of 350 turns/min, is sufficiently stirred for dispersion 30 minutes, treats each component mix homogeneously, and mixed liquor is obtained；
B) 50 parts of pigment are weighed in terms of parts by weight, 10 parts of silicon dioxide powders, 3 parts of mica powders, 10 parts of alumina powders are mixed
Close uniform, then feed the mixture into step 1）In obtained mixed liquor, add 3 weight portions lignin sulfonic acid, blender with
The speed of 400 turns/min is stirred 1 hour, then ground machine is fully ground, and is filtrated to get ink composite；
Described acrylic resin is adopted and is obtained with the following method：
In terms of parts by weight, 20 parts of ethanol are taken, 20 parts of propanol, 15 parts of isopropyl acetates add reactor after mix homogeneously
In, with the ramp of about 5-10 DEG C/min to 80 DEG C, 30min is incubated, 20 parts of ethyl acrylate, 10 parts of first are then sequentially added
Base acrylic acid, 15 parts of 2-(Acryloyloxy)ethanols, 2 parts of diacetone acrylamides, 1 part of azo diisopropyl imidazoline hydrochloride, stirring mixing are equal
Even, isothermal reaction 5 hours is cooled to 30 DEG C, and Deca 1.5ml strong aqua ammonia is stirred for 30min, obtains acrylic resin.
Described levelling agent is organosilicon levelling agent.
Described defoamer is BYK-016.
Beneficial effect：
1) water-dispersible acrylic's resin is contained in ink of the invention, which has good adhesive force, rate of drying
Hurry up, as one of the film-forming components of ink, the dry rate of ink film can be significantly improved.2) also make in ink of the invention
With beneficial to the ketone resin and waterborne polyurethane resin for improving dry rate, which is cooperateed with acrylic resin, is further improved
The dry rate of ink film.3）The rate of drying water color ink faster of the present invention, can significantly reduce water color ink and be dried speed
The printing quality problem that degree is brought slowly, reduces production cost, and there is actual application value pole.
Specific embodiment
The present invention will be further described with reference to embodiments, but the scope of protection of present invention is not limited to reality
Apply the scope of example expression.
Embodiment 1
The preparation of acrylic resin：
In terms of parts by weight, 20 parts of ethanol are taken, 20 parts of propanol, 15 parts of isopropyl acetates add reactor after mix homogeneously
In, with the ramp of about 5-10 DEG C/min to 80 DEG C, 30min is incubated, 20 parts of ethyl acrylate, 10 parts of first are then sequentially added
Base acrylic acid, 15 parts of 2-(Acryloyloxy)ethanols, 2 parts of diacetone acrylamides, 1 part of azo diisopropyl imidazoline hydrochloride, stirring mixing are equal
Even, isothermal reaction 5 hours is cooled to 30 DEG C, and Deca 1.5ml strong aqua ammonia is stirred for 30min, obtains acrylic resin.
The preparation of ink：
Following component is weighed in terms of parts by weight：20 parts of ketone resins, 10 parts of waterborne polyurethane resins, 10 parts of acrylic acid trees
Fat, 40 parts of distilled water, 1 part of levelling agent, 1 part of defoamer, 0.5 part of antibacterial, 1.3 parts of diluent, in adding agitator, with 350
Turn/the speed of min, be sufficiently stirred for dispersion 30 minutes, treat each component mix homogeneously, mixed liquor is obtained；
50 parts of pigment, 10 parts of silicon dioxide powders, 3 parts of mica powders, 10 parts of alumina powders, mixing are weighed in terms of parts by weight
Uniformly, then feed the mixture into step 1）In obtained mixed liquor, the lignin sulfonic acid of 3 weight portions is added, and blender is with 400
Turn/speed of min stirs 1 hour, then ground machine is fully ground, and is filtrated to get ink composite.
Comparative example 1
Following component is weighed in terms of parts by weight：25 parts of ketone resins, 15 parts of waterborne polyurethane resins, 40 parts of distilled water, 1
Part levelling agent, 1 part of defoamer, 0.5 part of antibacterial, 1.3 parts of diluent, in adding agitator, with the speed of 350 turns/min, fill
Divide dispersed with stirring 30 minutes, treat each component mix homogeneously, mixed liquor is obtained；
50 parts of pigment are weighed in terms of parts by weight, 10 parts of silicon dioxide powders, 3 parts of mica powders, 10 parts of alumina powders, mixing are equal
It is even, then feed the mixture in aforementioned obtained mixed liquor, add the lignin sulfonic acid of 3 weight portions, blender with 400 turns/
The speed of min is stirred 1 hour, then ground machine is fully ground, and is filtrated to get ink composite.
Comparative example 2
Following component is weighed in terms of parts by weight：20 parts of waterborne polyurethane resins, acrylic acid tree obtained in 20 parts of embodiments 1
Fat, 40 parts of distilled water, 1 part of levelling agent, 1 part of defoamer, 0.5 part of antibacterial, 1.3 parts of diluent, in adding agitator, with 350
Turn/the speed of min, be sufficiently stirred for dispersion 30 minutes, treat each component mix homogeneously, mixed liquor is obtained.
50 parts of pigment are weighed in terms of parts by weight, 10 parts of silicon dioxide powders, 3 parts of mica powders, 10 parts of alumina powders, mixing are equal
It is even, then feed the mixture in aforementioned obtained mixed liquor, add the lignin sulfonic acid of 3 weight portions, blender with 400 turns/
The speed of min is stirred 1 hour, then ground machine is fully ground, and is filtrated to get ink composite.
Speed, tack evaluation are dried to above-mentioned each ink, it is as a result as follows：
Drying property evaluation method：Each ink is printed to place 1 hour after leaflet, covering paper tape is then sticked and is applied
Pressure, paper tape is opened, and determines the printing ink transfer amount on paper tape, evaluation is divided into 3 grades：
Well：Almost without in ink transfer to paper tape；Typically：Only locally there is a small amount of ink transfer to paper tape；
Difference：There are many places and substantial amounts of ink transfer is on paper tape.
Claims (3)
1. a kind of preparation method of rapid-curing cutback ink, it is characterised in that comprise the steps：
A) following component is weighed in terms of parts by weight：20 parts of ketone resins, 10 parts of waterborne polyurethane resins, 10 parts of acrylic acid trees
Fat, 40 parts of distilled water, 1 part of levelling agent, 1 part of defoamer, 0.5 part of antibacterial, 1.3 parts of diluent, in adding agitator, with 350
Turn/the speed of min, be sufficiently stirred for dispersion 30 minutes, treat each component mix homogeneously, mixed liquor is obtained；
B) 50 parts of pigment are weighed in terms of parts by weight, 10 parts of silicon dioxide powders, 3 parts of mica powders, 10 parts of alumina powders, mixing are equal
It is even, then feed the mixture into step a）In obtained mixed liquor, the lignin sulfonic acid of 3 weight portions is added, and blender is with 400
Turn/speed of min stirs 1 hour, then ground machine is fully ground, and is filtrated to get ink composite；
Described acrylic resin is adopted and is obtained with the following method：
In terms of parts by weight, 20 parts of ethanol are taken, 20 parts of propanol, 15 parts of isopropyl acetates, in adding reactor after mix homogeneously, with
The ramp of 5-10 DEG C/min is incubated 30min, then sequentially adds 20 parts of ethyl acrylate, 10 parts of metering systems to 80 DEG C
Acid, 15 parts of 2-(Acryloyloxy)ethanols, 2 parts of diacetone acrylamides, 1 part of azo diisopropyl imidazoline hydrochloride, are uniformly mixed, constant temperature
Reaction 5 hours, is cooled to 30 DEG C, and Deca 1.5ml strong aqua ammonia is stirred for 30min, obtains acrylic resin.
2. the preparation method of ink according to claim 1, it is characterised in that：Described levelling agent is organosilicon levelling agent.
3. the preparation method of ink according to claim 1, it is characterised in that：Described defoamer is BYK-016.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510455344.6A CN104946011B (en) | 2015-07-30 | 2015-07-30 | Method for preparing quick-dry ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510455344.6A CN104946011B (en) | 2015-07-30 | 2015-07-30 | Method for preparing quick-dry ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104946011A CN104946011A (en) | 2015-09-30 |
| CN104946011B true CN104946011B (en) | 2017-04-12 |
Family
ID=54161098
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510455344.6A Expired - Fee Related CN104946011B (en) | 2015-07-30 | 2015-07-30 | Method for preparing quick-dry ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104946011B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118185372B (en) * | 2024-04-01 | 2024-09-13 | 浙江毕昇新材料有限公司 | Printing ink and printing application method thereof on decorative paper |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7947760B2 (en) * | 2004-09-21 | 2011-05-24 | Basf Corporation | Emulsion compositions for use in printing inks |
| US7470751B2 (en) * | 2004-09-21 | 2008-12-30 | Basf Corporation | Stabilized water-borne polymer compositions for use as water-based coatings |
| CN104559465B (en) * | 2013-10-24 | 2016-08-17 | 中国科学院化学研究所 | Environment-friendly type aqueous ink and preparation method thereof |
| CN103965393B (en) * | 2014-05-06 | 2016-06-01 | 江门骅弘颜料有限公司 | A kind of water-borne acrylic resin |
| CN104263076B (en) * | 2014-10-24 | 2015-12-30 | 成都普瑞斯特新材料有限公司 | Laughable red pair of PE ink of environment-friendly type and preparation method thereof |
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- 2015-07-30 CN CN201510455344.6A patent/CN104946011B/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN104946011A (en) | 2015-09-30 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Lin Jianwei Inventor before: Jin Shuanglei |
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| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170317 Address after: Along the River Industrial Zone in Guangdong province Shantou City Road 515021 No. 26 Street on the north side of Ma industrial plant building 1-3 Applicant after: Shantou Shengping Zhongxing Craft Printing Industrial Co.,Ltd. Address before: 312000 Zhejiang city of Shaoxing province Zhuji city Jiyang street Jin Jin Road No. 9 Applicant before: Jin Shuanglei |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170412 |