CN105331459A - Dyed sodium percarbonate and preparation method thereof - Google Patents
Dyed sodium percarbonate and preparation method thereof Download PDFInfo
- Publication number
- CN105331459A CN105331459A CN201510935255.1A CN201510935255A CN105331459A CN 105331459 A CN105331459 A CN 105331459A CN 201510935255 A CN201510935255 A CN 201510935255A CN 105331459 A CN105331459 A CN 105331459A
- Authority
- CN
- China
- Prior art keywords
- spc
- sodium
- dyestuff
- prepared
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 title abstract 6
- 229940045872 sodium percarbonate Drugs 0.000 title abstract 6
- 239000000975 dye Substances 0.000 claims abstract description 42
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 25
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 19
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 12
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 12
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000004043 dyeing Methods 0.000 claims description 16
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 12
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 12
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 229910001385 heavy metal Inorganic materials 0.000 claims description 4
- 239000000984 vat dye Substances 0.000 claims description 4
- -1 Starso Chemical compound 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- NCGSLDXVMRCQPG-UHFFFAOYSA-K trisodium;carbonate;chloride Chemical compound [Na+].[Na+].[Na+].[Cl-].[O-]C([O-])=O NCGSLDXVMRCQPG-UHFFFAOYSA-K 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 10
- 239000012752 auxiliary agent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- ZNRSXPDDVNZGEN-UHFFFAOYSA-K trisodium;chloride;sulfate Chemical compound [Na+].[Na+].[Na+].[Cl-].[O-]S([O-])(=O)=O ZNRSXPDDVNZGEN-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention relates to sodium percarbonate used in the washing industry, in particular to dyed sodium percarbonate and a preparation method thereof. The method comprises the steps that sodium percarbonate is prepared through a common technology, dye, sodium chloride, sodium carbonate, sodium sulfate, sodium metasilicate and sodium tripolyphosphate are mixed according to the ratio, the mixture is added into an appropriate amount of water and ethyl alcohol for stirring, then the sodium percarbonate prepared through the common technology is added in, even stirring is carried out, and the mixture is dried at 20-60 DEG C to obtain the dyed sodium percarbonate. According to the technical scheme, operation is convenient, and industrial production can be achieved.
Description
Technical field
The present invention relates to a kind of washing industry SPC-D, particularly relate to the SPC-D of dyeing, the preparation method of this SPC-D.
Background technology
Current SPC-D is all white powder and particle.Along with its application in daily use chemicals industry is popularized gradually, people are no longer confined to active o content and stability to the requirement of SPC-D, and coloured to cross carbon more lovely.It is used in washing powder, oxygen bleaching powder, and product can be made more beautiful, and as added blueness, the clothes naked eyes come out look can improve value-added content of product by brilliant white more.
If need colour particles in oxygen bleaching powder in the past, can only additionally add.Such one side adds operation and cost; The dyestuff of colour ion may have an impact to the stability of hydrogen peroxide in SPC-D on the one hand, if improper use, color can change or disappear, and maybe can promote hydrogen peroxide decomposition.This all disagrees with the original meaning of adding colour particles.
Summary of the invention
The present invention provides dyeing SPC-D and preparation method thereof for the deficiencies in the prior art.Technique scheme convenient operation, can realize suitability for industrialized production.
Technical scheme provided by the invention is:
A kind of dyeing SPC-D, comprises the component of following mass ratio:
SPC-D 20 ~ 90 prepared by ordinary process,
Dyestuff 0.01 ~ 8,
Sodium-chlor 1 ~ 5,
Sodium carbonate 4 ~ 8,
Sodium sulfate 1 ~ 2,
Starso 0.5 ~ 1,
Tripoly phosphate sodium STPP 0.01 ~ 1.
Concrete, dyestuff is resistance to oxidation type dye.
Preferably, require without C=O bond, heavy metal free in described its molecular structure of resistance to oxidation type dye.
Concrete, dyestuff is any one or multiple mixing in reactive dyestuffs, substantive dyestuff, vat dyes.
Present invention also offers a kind of preparation method of the SPC-D that dyes, SPC-D is prepared into through ordinary process, again dyestuff is mixed according to aforementioned proportion with sodium-chlor, sodium carbonate, sodium sulfate, Starso, tripoly phosphate sodium STPP, and be blended in suitable quantity of water and alcohol and stir, and then add SPC-D prepared by ordinary process, stir, dry at 20-60 DEG C.Wherein alcohol is for dissolving dye, and water is for dissolving other auxiliary agents.The quantity of alcohol and water is can dissolving dye and other auxiliary agents be advisable completely.
Starso, tripoly phosphate sodium STPP can chelating calcium ions and magnesium ions, increase the stability of system; Sodium carbonate and SPC-D compatibleness better, are beneficial to abundant combination; Sodium-chlor, sodium sulfate, can be cost-saving as common stopping composition.
The present invention has following technique effect:
1, the SPC-D stability after dyeing strengthens, can not because of hydrogen peroxide oxidation variable color in use procedure.
2, not containing heavy metal in the dyestuff in SPC-D, the decomposition of hydrogen peroxide can not be promoted, the result of use of SPC-D can be kept.
3, the SPC-D after dyeing, such as blue, fabric can be made after using to look more brilliant white.
Embodiment
specific embodiment 1
A kind of dyeing SPC-D, comprises the component of following mass ratio:
SPC-D 20 prepared by ordinary process,
Dyestuff 0.01,
Sodium-chlor 1,
Sodium carbonate 4,
Sodium sulfate 1,
Starso 0.5,
Tripoly phosphate sodium STPP 0.01.
Dye paste has multiple choices, and dye paste can select resistance to oxidation type dye, requires without C=O bond, heavy metal free in resistance to oxidation type dye molecular structure.Dye paste also can be any one or multiple mixing in reactive dyestuffs, substantive dyestuff, vat dyes.
The obtained SPC-D of ordinary process preparation, again dyestuff is mixed according to aforementioned proportion with sodium-chlor, sodium carbonate, sodium sulfate, Starso, tripoly phosphate sodium STPP, and be blended in suitable quantity of water and alcohol and stir, join SPC-D prepared by ordinary process, stir, dry at 20-60 DEG C dyeing SPC-D.Wherein alcohol is for dissolving dye, and water is for dissolving other auxiliary agents.The quantity of alcohol and water is can dissolving dye and other auxiliary agents be advisable completely.
Selected reactive dyestuffs generate covalent linkage with the starch reaction that can dye in SPC-D, and in SPC-D sodium carbonate effect under fixation.
Selected substantive dyestuff and the Starch formation hydrogen bond that can dye in SPC-D, and in SPC-D sodium carbonate effect under fixation.
Selected vat dyes reacts with the hydrogen peroxide that can dye in SPC-D and generates solid dye particles, anchors in SPC-D.
specific embodiment 2
With specific embodiment 1 unlike:
A kind of dyeing SPC-D, comprises the component of following mass ratio:
SPC-D 30 prepared by ordinary process,
Dyestuff 2,
Sodium-chlor 2,
Sodium carbonate 5,
Sodium sulfate 1.3,
Starso 0.6,
Tripoly phosphate sodium STPP 0.21.
specific embodiment 3
With specific embodiment 1 unlike:
A kind of dyeing SPC-D, comprises the component of following mass ratio:
SPC-D 50 prepared by ordinary process,
Dyestuff 4,
Sodium-chlor 3,
Sodium carbonate 6,
Sodium sulfate 1.5,
Starso 0.7,
Tripoly phosphate sodium STPP 0.33.
specific embodiment 4
With specific embodiment 1 unlike:
A kind of dyeing SPC-D, comprises the component of following mass ratio:
SPC-D 70 prepared by ordinary process,
Dyestuff 5,
Sodium-chlor 3.5,
Sodium carbonate 6,
Sodium sulfate 1.6,
Starso 0.8,
Tripoly phosphate sodium STPP 0.4.
specific embodiment 5
With specific embodiment 1 unlike:
A kind of dyeing SPC-D, comprises the component of following mass ratio:
SPC-D 81 prepared by ordinary process,
Dyestuff 7,
Sodium-chlor 4,
Sodium carbonate 7,
Sodium sulfate 1.8,
Starso 0.9,
Tripoly phosphate sodium STPP 0.7.
specific embodiment 6
With specific embodiment 1 unlike:
A kind of dyeing SPC-D, comprises the component of following mass ratio:
SPC-D 90 prepared by ordinary process,
Dyestuff 8,
Sodium-chlor 5,
Sodium carbonate 8,
Sodium sulfate 2,
Starso 1,
Tripoly phosphate sodium STPP 1.
Finally should be noted that: above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit; Although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the field are to be understood that: still can modify to the specific embodiment of the present invention or carry out equivalent replacement to portion of techniques feature; And not departing from the spirit of technical solution of the present invention, it all should be encompassed in the middle of the technical scheme scope of request of the present invention protection.
Claims (5)
1. dye a SPC-D, it is characterized in that, comprise the component of following mass ratio:
SPC-D 20 ~ 90 prepared by ordinary process,
Dyestuff 0.01 ~ 8,
Sodium-chlor 1 ~ 5,
Sodium carbonate 4 ~ 8,
Sodium sulfate 1 ~ 2,
Starso 0.5 ~ 1,
Tripoly phosphate sodium STPP 0.01 ~ 1.
2. a kind of dyeing SPC-D according to claim 1, it is characterized in that, dyestuff is resistance to oxidation type dye.
3. a kind of dyeing SPC-D according to claim 2, is characterized in that, require without C=O bond, heavy metal free in described its molecular structure of resistance to oxidation type dye.
4. a kind of dyeing SPC-D according to claim 1, is characterized in that, dyestuff is any one or multiple mixing in reactive dyestuffs, substantive dyestuff, vat dyes.
5. a kind of preparation method of the SPC-D that dyes as described in claim any in claim 1-4, it is characterized in that, SPC-D is prepared into through ordinary process, again dyestuff is mixed according to aforementioned proportion with sodium-chlor, sodium carbonate, sodium sulfate, Starso, tripoly phosphate sodium STPP, and be blended in suitable quantity of water and alcohol and stir, and then add SPC-D prepared by ordinary process, stir, dry at 20-60 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510935255.1A CN105331459A (en) | 2015-12-15 | 2015-12-15 | Dyed sodium percarbonate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510935255.1A CN105331459A (en) | 2015-12-15 | 2015-12-15 | Dyed sodium percarbonate and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105331459A true CN105331459A (en) | 2016-02-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510935255.1A Pending CN105331459A (en) | 2015-12-15 | 2015-12-15 | Dyed sodium percarbonate and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105331459A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111807327A (en) * | 2020-07-22 | 2020-10-23 | 濮阳宏业环保技术研究院有限公司 | Aquaculture oxygenation agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1284991A (en) * | 1998-02-16 | 2001-02-21 | 汉高两合股份公司 | Washing and cleaning agent shaped body with bleaching agent |
| CN101061063A (en) * | 2004-12-14 | 2007-10-24 | 德古萨有限责任公司 | Compressed molded bodies containing coated sodium percarbonate particles |
| CN102660146A (en) * | 2012-04-28 | 2012-09-12 | 浙江万丰化工有限公司 | Oxidation-resistant disperse dye composition and preparation and application thereof |
| CN102918119A (en) * | 2010-05-28 | 2013-02-06 | 美利肯公司 | Color granules for granular detergents |
-
2015
- 2015-12-15 CN CN201510935255.1A patent/CN105331459A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1284991A (en) * | 1998-02-16 | 2001-02-21 | 汉高两合股份公司 | Washing and cleaning agent shaped body with bleaching agent |
| CN101061063A (en) * | 2004-12-14 | 2007-10-24 | 德古萨有限责任公司 | Compressed molded bodies containing coated sodium percarbonate particles |
| CN102918119A (en) * | 2010-05-28 | 2013-02-06 | 美利肯公司 | Color granules for granular detergents |
| CN102660146A (en) * | 2012-04-28 | 2012-09-12 | 浙江万丰化工有限公司 | Oxidation-resistant disperse dye composition and preparation and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| 周立平: "《生态纺织产品最新标准规范和技术应用及质量制手册（中卷》", 30 June 2004, 安徽文化音像出版社 * |
| 孙宝国: "《日用化工辞典》", 30 June 2002, 化学工业出版社 * |
| 李子东等: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111807327A (en) * | 2020-07-22 | 2020-10-23 | 濮阳宏业环保技术研究院有限公司 | Aquaculture oxygenation agent |
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| PB01 | Publication | ||
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Application publication date: 20160217 |