CN105627694B - LNG gas stations BOG compresses and liquefies recovery system and method - Google Patents
LNG gas stations BOG compresses and liquefies recovery system and method Download PDFInfo
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- 238000011084 recovery Methods 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 11
- 238000007906 compression Methods 0.000 claims abstract description 63
- 230000006835 compression Effects 0.000 claims abstract description 57
- 238000009413 insulation Methods 0.000 claims description 43
- 239000007788 liquid Substances 0.000 claims description 34
- 230000001105 regulatory effect Effects 0.000 claims description 20
- 239000012071 phase Substances 0.000 claims description 18
- 238000001816 cooling Methods 0.000 claims description 9
- 238000012546 transfer Methods 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 238000004891 communication Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 48
- 238000013461 design Methods 0.000 abstract description 2
- 238000002309 gasification Methods 0.000 abstract description 2
- 239000003949 liquefied natural gas Substances 0.000 abstract 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 84
- 239000003345 natural gas Substances 0.000 description 42
- 238000005057 refrigeration Methods 0.000 description 8
- 239000002699 waste material Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 238000013022 venting Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
- F25J1/0025—Boil-off gases "BOG" from storages
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
- F25J1/0202—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0285—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
- F25J1/0288—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J5/00—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
- F25J5/002—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
本发明涉及LNG加气站中液化天然气因热损气化而产生BOG的整站回收技术领域,具体为一种LNG加气站BOG压缩液化回收系统及方法,特别是包含了再液化系统中的优化设计。采用绝热膨胀机带动一级压缩机、真空绝热三位一体换热器,其具有投资省、运行费用低、工艺流程短、设备方便撬块化等特点,非常适合在LNG加气站进行推广。
The invention relates to the technical field of whole-station recovery of BOG produced by liquefied natural gas due to heat loss gasification in LNG gas filling stations, specifically a BOG compression liquefaction recovery system and method in LNG gas filling stations, especially including the BOG in the reliquefaction system Optimized design. The adiabatic expander is used to drive the first-stage compressor and the vacuum adiabatic trinity heat exchanger. It has the characteristics of low investment, low operating cost, short process flow, and convenient prying of equipment. It is very suitable for promotion in LNG filling stations.
Description
技术领域technical field
本发明涉及LNG加气站中产生的BOG回收技术领域,具体涉及一种采用膨胀压缩一体机、真空绝热三位一体螺旋折流板列管式换热器的LNG加气站BOG压缩液化回收系统,及采用所述系统回收BOG的方法。The invention relates to the technical field of BOG recovery produced in LNG gas filling stations, in particular to a BOG compression liquefaction recovery system for LNG gas filling stations using an expansion compression integrated machine and a vacuum insulation trinity spiral baffle tube heat exchanger, and A method of recovering BOG using the system.
背景技术Background technique
随着“后石油时代”的到来,全球能源重心正在向更加高效、更加环保的天然气能源快速转移。LNG汽车作为国家清洁能源用车,近年来得到了突飞猛进的发展,同时LNG加气站也如雨后春笋般的进行了大面积的建设。目前在LNG加气站运行过程中,因储存条件苛刻、设计工艺不先进等原因,几乎所有加气站都面临着较为严重的能源浪费,其中最突出的是BOG再回收利用问题。With the advent of the "post-oil era", the global energy center is rapidly shifting to more efficient and environmentally friendly natural gas energy. As a national clean energy vehicle, LNG vehicles have developed by leaps and bounds in recent years. At the same time, LNG filling stations have also sprung up like mushrooms after a spring rain. At present, during the operation of LNG filling stations, due to harsh storage conditions and unadvanced design techniques, almost all filling stations are facing serious energy waste, the most prominent of which is the problem of BOG recycling.
在LNG加气站生产运营过程中,由于LNG槽车运输、储罐蒸发、卸车、调压、预冷、管道吸热、储罐闪蒸和泵工作外输等原因都会产生大量的BOG气体。BOG气体不仅造成加气站系统压力升高,更带来较大的安全隐患,最终这部分BOG气体不得不进行安全放散,造成巨大的能源浪费和经济损失。During the production and operation of LNG refueling stations, a large amount of BOG gas will be generated due to LNG tanker transportation, storage tank evaporation, unloading, pressure regulation, pre-cooling, pipeline heat absorption, storage tank flashing, and pump operation. BOG gas not only increases the pressure of the gas filling station system, but also brings greater safety hazards. In the end, this part of BOG gas has to be released safely, resulting in huge energy waste and economic losses.
发明内容Contents of the invention
本专利旨在提供一种在LNG加气站中采用膨胀压缩一体机、真空绝热三位一体螺旋折流板列管式换热器的BOG优化压缩液化回收装置,解决目前LNG加气站的安全隐患和BOG气体放空处理造成的环境污染、资源浪费。This patent aims to provide a BOG optimized compression liquefaction recovery device using an expansion and compression integrated machine and a vacuum insulation trinity spiral baffle tube heat exchanger in an LNG filling station, so as to solve the safety hazards and problems of the current LNG filling station. Environmental pollution and resource waste caused by BOG gas venting.
为实现上述技术目的,本发明采用以下的技术方案:For realizing above-mentioned technical purpose, the present invention adopts following technical scheme:
LNG加气站BOG压缩液化回收系统,包括用于储存LNG液体的LNG储罐和用于收集加气站管道内BOG气体的BOG缓冲罐;LNG储罐和所述BOG缓冲罐分别通过管道与真空绝热三位一体换热器的一级换热区相连通;所述真空绝热三位一体换热器的一级换热区与绝热膨胀压缩一体机的压缩机相连通,所述绝热膨胀压缩一体机的压缩机通过一级空温式换热器与二级压缩机相连通,所述二级压缩机通过二级空温式换热器与真空绝热三位一体换热器的一级换热区相连通;所述真空绝热三位一体换热器的三级换热区与绝热膨胀压缩一体机的绝热膨胀机相连通;所述绝热膨胀压缩一体机的绝热膨胀机连接气液分离器,所述气液分离器的气相口通过管道和调节阀与所述真空绝热三位一体换热器的二级换热区相连通,所述气液分离器的液相口连接低温泵,所述低温泵与所述真空绝热三位一体换热器的三级换热区及所述LNG储罐相连通。The BOG compression liquefaction recovery system of the LNG gas filling station includes an LNG storage tank for storing LNG liquid and a BOG buffer tank for collecting BOG gas in the pipeline of the gas filling station; the LNG storage tank and the BOG buffer tank are connected through the pipeline and vacuum respectively The primary heat exchange area of the adiabatic trinity heat exchanger is connected; the primary heat exchange area of the vacuum adiabatic trinity heat exchanger is connected with the compressor of the adiabatic expansion compression integrated machine, and the compressor of the adiabatic expansion compression integrated machine The secondary compressor is connected to the secondary compressor through the primary air-temperature heat exchanger, and the secondary compressor is connected to the primary heat exchange area of the vacuum insulation trinity heat exchanger through the secondary air-thermal heat exchanger; The three-stage heat exchange area of the vacuum insulation trinity heat exchanger is connected with the adiabatic expander of the adiabatic expansion and compression integrated machine; the adiabatic expander of the adiabatic expansion and compression integrated machine is connected to the gas-liquid separator, and the gas phase of the gas-liquid separator The port is connected to the secondary heat exchange area of the vacuum insulation trinity heat exchanger through a pipeline and a regulating valve, and the liquid phase port of the gas-liquid separator is connected to a cryopump, and the cryopump exchanges heat with the vacuum insulation trinity The tertiary heat exchange area of the device is connected with the LNG storage tank.
作为优选,所述真空绝热三位一体换热器将三个管式换热器集成在一个真空壳内,壳内采用螺旋折流板提高换热效率,部分管路集成在壳内,使设备小型化,投资省,配管简单,工艺简化。当然,也可以采用其他形式的三个换热器集成于一个真空壳内,部分管路集成在壳内。As a preference, the vacuum insulation trinity heat exchanger integrates three tubular heat exchangers into one vacuum shell, and spiral baffles are used in the shell to improve heat exchange efficiency, and part of the pipelines are integrated in the shell to make the equipment miniaturized , low investment, simple piping, simplified process. Of course, other forms of three heat exchangers can also be integrated in one vacuum shell, and part of the pipelines are integrated in the shell.
作为优选,所述膨胀压缩一体机利用绝热膨胀机进行制冷的同时带动压缩机,对富热后的BOG进行一级压缩,制冷效率高,设备小,投资省,工艺简化,节能降耗。Preferably, the expansion-compression integrated machine utilizes an adiabatic expander to perform refrigeration while driving the compressor to perform one-stage compression on the heat-enriched BOG, which has high refrigeration efficiency, small equipment, low investment, simplified process, and energy saving and consumption reduction.
作为优选,所述BOG压缩液化回收系统采用DCS对BOG回收压缩液化撬进行控制,通过调节阀分别与压力变送器、温度变送器和液位变送器相连锁,安全可靠,操作简单。As a preference, the BOG compression liquefaction recovery system uses DCS to control the BOG recovery compression liquefaction skid, and is respectively linked with the pressure transmitter, temperature transmitter and liquid level transmitter through the regulating valve, which is safe, reliable and easy to operate.
作为优选,LNG槽车的气相部分通过管道与所述BOG缓冲罐上部的管道相连通,管道上分别设置止回阀。所述BOG压缩液化回收系统不仅对LNG储罐内的BOG进行回收,而且对LNG槽车和管线内的BOG气体均可进行回收,杜绝了加气站内的能源浪费。Preferably, the gas phase part of the LNG tanker communicates with the pipeline on the upper part of the BOG buffer tank through pipelines, and check valves are respectively arranged on the pipelines. The BOG compression liquefaction recovery system not only recovers the BOG in the LNG storage tank, but also recovers the BOG gas in the LNG tanker and the pipeline, which prevents energy waste in the gas filling station.
作为优选,所述一级压缩机和二级压缩机采用一级空温式换热器和二级空温式换热器进行级间冷凝,从而提供BOG气体液化所需冷能。Preferably, the first-stage compressor and the second-stage compressor use a first-stage air-to-air heat exchanger and a second-stage air-to-air heat exchanger to perform interstage condensation, thereby providing cold energy required for liquefaction of BOG gas.
作为优选,所述真空绝热三位一体换热器包括外壳和内胆,所述外壳和内胆之间形成真空真空壳,所述真空绝热三位一体换热器的若干换热管集成设置于所述内胆内部而形成所述一级换热区、二级换热区及三级换热区,各换热区管式换热器采用螺旋折流板提高传热效率。Preferably, the vacuum insulation trinity heat exchanger includes an outer shell and an inner tank, a vacuum shell is formed between the outer shell and the inner tank, and several heat exchange tubes of the vacuum thermal insulation trinity heat exchanger are integrally arranged in the inner tank The first heat exchange area, the second heat exchange area and the third heat exchange area are formed inside, and the tubular heat exchangers in each heat exchange area use spiral baffles to improve heat transfer efficiency.
作为进一步优选,所述真空绝热三位一体换热器的一级换热区与二级换热区之间、二级换热区与三级换热区之间的管程分别通过管程连接腔相连通;所述真空绝热三位一体换热器的一级换热区与二级换热区之间、二级换热区与三级换热区之间的壳程分别通过壳程连接管相连通。As a further preference, the tubes between the primary heat exchange area and the secondary heat exchange area, and between the secondary heat exchange area and the tertiary heat exchange area of the vacuum-insulated trinity heat exchanger are respectively connected through tube-side connecting chambers The shell side between the primary heat exchange area and the secondary heat exchange area, and the shell side between the secondary heat exchange area and the tertiary heat exchange area of the vacuum insulation trinity heat exchanger are respectively connected through shell side connecting pipes.
本发明的另一目的在于提供采用以上所述系统回收BOG的方法,包括如下步骤:Another object of the present invention is to provide a method for reclaiming BOG using the system described above, comprising the steps of:
S1.将LNG加气站的管线BOG收集至缓冲罐内,并在缓冲罐的气相出口安装调节阀,卸车装置的气相也通过此调节阀连接压缩回收撬;LNG储罐的气相出口安装调节阀和压缩回收撬相连;待储罐内的压力超过规定的要求,DCS将连锁启动压缩回收撬,对LNG储罐内BOG气体进行回收,将LNG储罐压力降低到规定的值后DCS将停止压缩回收;BOG缓冲罐压力达到一定值时,DCS将连锁启动压缩回收撬,压力降低到规定的压力后,压缩回收装置将自动停止;LNG槽车卸车完成后,通过BOG回收撬将槽车内NG充分回收。回收的BOG气体通过分别调压后送入液化回收装置的真空绝热三位一体换热器进行一级换热,充分回收BOG气体的冷能;S1. Collect the pipeline BOG of the LNG filling station into the buffer tank, and install a regulating valve at the gas phase outlet of the buffer tank. The gas phase of the unloading device is also connected to the compression recovery skid through this regulating valve; the gas phase outlet of the LNG storage tank is installed with a regulating valve It is connected with the compression recovery skid; when the pressure in the storage tank exceeds the specified requirements, the DCS will start the compression recovery skid in chains to recover the BOG gas in the LNG storage tank, and the DCS will stop the compression after the pressure of the LNG storage tank is reduced to the specified value Recovery; when the pressure of the BOG buffer tank reaches a certain value, the DCS will start the compression recovery skid in chains. After the pressure drops to the specified pressure, the compression recovery device will automatically stop; fully recycled. The recovered BOG gas is sent to the vacuum insulated trinity heat exchanger of the liquefaction recovery device for primary heat exchange after the pressure is adjusted separately, so as to fully recover the cold energy of the BOG gas;
S2.在真空绝热三位一体换热器中,低温BOG气体与常温的压缩NG进行一级换热,使BOG气体温度升至20℃左右,变成NG,将其冷能全部由压缩后NG气体回收;S2. In the vacuum adiabatic trinity heat exchanger, the low-temperature BOG gas and the compressed NG at room temperature perform a heat exchange, so that the temperature of the BOG gas rises to about 20°C and becomes NG, and all its cold energy is recovered by the compressed NG gas ;
S3.然后将NG送入第一级压缩机增压,一级压缩机利用绝热膨胀制冷机的机械能带动,绝热膨胀机和一级压缩机整合在一个机座上,不仅投资省,节省占地面积,并且制冷效率提高70%,节电40%。压缩后的NG送入第二级压缩机,压缩至10MPa,两级压缩采用级间冷凝,使压缩后的NG气体温度控制在30℃左右,然后将压缩NG送至真空绝热三位一体换热器进行降温;S3. Then send NG to the first-stage compressor for boosting. The first-stage compressor is driven by the mechanical energy of the adiabatic expansion refrigerator. The adiabatic expander and the first-stage compressor are integrated on one machine base, which not only saves investment but also saves space area, and the cooling efficiency is increased by 70%, and the electricity is saved by 40%. The compressed NG is sent to the second-stage compressor and compressed to 10MPa. The two-stage compression adopts inter-stage condensation to control the temperature of the compressed NG gas at about 30°C, and then sends the compressed NG to the vacuum insulation trinity heat exchanger for further processing. cool down;
S4.压缩NG在真空绝热三位一体换热器中分别与低温回收BOG、气液分离器后NG及气液分离器中部分LNG进行三级换热,使压缩NG气体温度降至-110℃左右;然后将NG送入绝热膨胀机,使NG压力降至400KPa,由于NG绝热做功温度降至约-160℃;大部分NG被液化。S4. The compressed NG performs three-stage heat exchange with the low-temperature recovered BOG, NG after the gas-liquid separator, and part of the LNG in the gas-liquid separator respectively in the vacuum adiabatic trinity heat exchanger, so that the temperature of the compressed NG gas drops to about -110°C; Then the NG is sent to the adiabatic expander, so that the pressure of NG drops to 400KPa, and the temperature of NG drops to about -160°C due to the adiabatic work of NG; most of the NG is liquefied.
S5.将气液混合物送入气液分离器,实现气液分离;气态低温NG通过调节阀调压后送至真空绝热三位一体换热器二级换热,LNG一部分泵送至LNG储罐,另一部分送至真空绝热三位一体换热器第三级与压缩NG换热;在三级换热器内LNG温度升至-120℃而气化成低温NG,出三级换热器的低温NG通过一体化换热器内壳程连接管与气液分离器低温NG一起进入真空绝热三位一体换热器二级换热,换热结束后进入一级换热器与回收BOG一起对压缩NG气体进行冷却;压缩NG从一级换热器被冷却后分别从级间管程腔进入二级换热器,从二级冷却后又进入三级换热器进入冷却;真空绝热三位一体换热器内折流板为螺旋板,提高换热效率30%。S5. Send the gas-liquid mixture into the gas-liquid separator to realize gas-liquid separation; the gaseous low-temperature NG is sent to the vacuum insulation trinity heat exchanger for secondary heat exchange after the pressure is adjusted by the regulating valve, and part of the LNG is pumped to the LNG storage tank. Part of it is sent to the third stage of the vacuum insulation trinity heat exchanger to exchange heat with compressed NG; in the third stage heat exchanger, the temperature of LNG rises to -120°C and is gasified into low temperature NG, and the low temperature NG exiting the third stage heat exchanger passes through the integration The inner shell-side connecting pipe of the heat exchanger and the low-temperature NG of the gas-liquid separator enter the secondary heat exchange of the vacuum adiabatic trinity heat exchanger, and after the heat exchange, enter the primary heat exchanger to cool the compressed NG gas together with the recovered BOG; compression After being cooled in the primary heat exchanger, NG enters the secondary heat exchanger from the interstage tube-side cavity, and enters the tertiary heat exchanger after secondary cooling; the baffle plate in the vacuum insulation trinity heat exchanger is Spiral plate, improve heat exchange efficiency by 30%.
本发明具有至少以下有益效果:采用低温BOG绝热膨胀制冷时产生的机械能带动压缩机,同时对富热后的BOG进行一级压缩,降低能耗,提高制冷效率;采用真空绝热三位一体换热器实现BOG压缩制冷液化各工段的冷能充分利用,增强传热效率,提高BOG回收的液化效率;采用DCS对BOG回收压缩液化撬进行控制,安全可靠,操作简单,利于减小LNG加气站的安全隐患,并能够实现BOG气体高效回收,从而避免BOG气体放空处理造成的环境污染和资源浪费。The present invention has at least the following beneficial effects: the mechanical energy generated during adiabatic expansion and refrigeration of low-temperature BOG is used to drive the compressor, and at the same time, one-stage compression is performed on the heat-enriched BOG to reduce energy consumption and improve refrigeration efficiency; it is realized by using a vacuum adiabatic trinity heat exchanger The cold energy of each section of BOG compression refrigeration liquefaction is fully utilized, the heat transfer efficiency is enhanced, and the liquefaction efficiency of BOG recovery is improved; DCS is used to control the BOG recovery compression liquefaction skid, which is safe, reliable, and easy to operate, which is conducive to reducing the safety of LNG filling stations Hidden dangers can be achieved, and BOG gas can be recovered efficiently, thereby avoiding environmental pollution and resource waste caused by BOG gas venting.
附图说明Description of drawings
以下附图仅旨在于对本发明做示意性说明和解释,并不限定本发明的范围。其中:The following drawings are only intended to illustrate and explain the present invention schematically, and do not limit the scope of the present invention. in:
图1是本发明实施例回收系统的结构示意图;Fig. 1 is the structural representation of the recovery system of the embodiment of the present invention;
图2是三级管式换热器的结构示意图;Fig. 2 is a structural schematic diagram of a three-stage tubular heat exchanger;
图3是图2中A处的放大结构示意图;Fig. 3 is a schematic diagram of an enlarged structure at A in Fig. 2;
图4是图2中B处的放大结构示意图。FIG. 4 is a schematic diagram of an enlarged structure at B in FIG. 2 .
图中:1-LNG储罐;11、21、81-管道;12、22、82-调节阀;13、23、83-压力变送器;2-BOG缓冲罐;3-真空绝热三位一体换热器;31-一级换热区;32-二级换热区;33-三级换热区;34-外壳;35-内胆;351-螺旋折流板;36-真空壳;37-换热管;38-壳程;381-壳程连接管;39-管程;391-管程连接腔;4-绝热膨胀压缩一体机;41-压缩机;42-绝热膨胀机;5-一级空温式换热器;6-二级空温式换热器;7-二级压缩机;8-气液分离器;9-低温泵;10-LNG槽车;101-管道;24、102-止回阀。In the figure: 1-LNG storage tank; 11, 21, 81-pipeline; 12, 22, 82-regulating valve; 13, 23, 83-pressure transmitter; 2-BOG buffer tank; 3-vacuum insulation trinity heat exchange 31-first-level heat exchange area; 32-secondary heat exchange area; 33-third-level heat exchange area; 34-outer shell; 35-inner tank; 351-spiral baffle; 36-vacuum shell; Heat pipe; 38-Shell side; 381-Shell side connecting pipe; 39-Tube side; 391-Tube side connection chamber; 4-Adiabatic expansion compressor; 41-Compressor; 42-Adiabatic expander; 5-Level 1 Air-temperature heat exchanger; 6-secondary air-temperature heat exchanger; 7-secondary compressor; 8-gas-liquid separator; 9-cryogenic pump; 10-LNG tanker; 101-pipeline; 24, 102 - Check valve.
具体实施方式detailed description
下面结合附图和实施例,进一步阐述本发明。在下面的详细描述中,只通过说明的方式描述了本发明的某些示范性实施例。毋庸置疑,本领域的技术人员可以认识到,在不偏离本发明的精神和范围的情况下,可以用各种不同的方式对所描述的实施例进行修正。因此,附图和描述在本质上是说明性的,而不是用于限制权利要求的保护范围。Below in conjunction with accompanying drawing and embodiment, further elaborate the present invention. In the following detailed description, certain exemplary embodiments of the invention are described by way of illustration only. Needless to say, those skilled in the art would realize that the described embodiments may be modified in various different ways, all without departing from the spirit and scope of the present invention. Accordingly, the drawings and description are illustrative in nature and not intended to limit the scope of the claims.
如图1至图4所示,LNG加气站BOG压缩液化回收系统,包括用于储存LNG液体的LNG储罐1和用于收集加气站管道内BOG气体的BOG缓冲罐2;所述LNG储罐1和所述BOG缓冲罐2气相部分分别通过管道11、21与真空绝热三位一体换热器3的一级换热区31的壳程38相连通;所述真空绝热三位一体换热器3的一级换热区31的壳程38与所述绝热膨胀压缩一体机4的压缩机41相连通,所述绝热膨胀压缩一体机4的压缩机41通过空温式换热器5与所述三级管式真空绝热三位一体换热器3的一级换热区31的管程39相连通,所述二级压缩机7通过二级空温式换热器6与真空绝热三位一体换热器3的一级换热区31相连通;所述真空绝热三位一体换热器3的三级换热区33的管程与膨胀压缩一体机4的绝热膨胀机42相连通,所述绝热膨胀压缩一体机4的绝热膨胀机42连接气液分离器8,所述气液分离器8的气相口通过管道81与所述真空绝热三位一体换热器3的二级换热区32的壳程38相连通,所述气液分离器8的液相口连接低温泵9,所述低温泵9通过调节阀和管道与所述真空绝热三位一体换热器3的三级换热区33及所述LNG储罐1相连通。As shown in Figures 1 to 4, the BOG compression liquefaction recovery system of the LNG filling station includes an LNG storage tank 1 for storing LNG liquid and a BOG buffer tank 2 for collecting BOG gas in the pipeline of the filling station; the LNG The gas phase part of the storage tank 1 and the BOG buffer tank 2 communicates with the shell side 38 of the primary heat exchange zone 31 of the vacuum insulation trinity heat exchanger 3 through pipelines 11 and 21 respectively; the vacuum insulation trinity heat exchanger 3 The shell side 38 of the primary heat exchange area 31 is connected to the compressor 41 of the adiabatic expansion and compression integrated machine 4, and the compressor 41 of the adiabatic expansion and compression integrated machine 4 is connected to the three The tube side 39 of the first-stage heat exchange zone 31 of the first-stage tube-type vacuum-insulated trinity heat exchanger 3 is connected. The first-stage heat exchange area 31 is connected; the tube side of the third-stage heat exchange area 33 of the vacuum insulation trinity heat exchanger 3 is connected with the adiabatic expander 42 of the expansion-compression integrated machine 4 , and the adiabatic expansion-compression integrated machine 4 The adiabatic expander 42 is connected to the gas-liquid separator 8, and the gas phase port of the gas-liquid separator 8 is connected to the shell side 38 of the secondary heat exchange zone 32 of the vacuum insulation trinity heat exchanger 3 through a pipeline 81, so that The liquid phase port of the gas-liquid separator 8 is connected to the cryopump 9, and the cryopump 9 is connected to the three-stage heat exchange area 33 of the vacuum insulation trinity heat exchanger 3 and the LNG storage tank 1 through a regulating valve and a pipeline Pass.
为了实现系统DCS控制,在BOG缓冲罐2的气相出口管道21安装调节阀22,LNG槽车10的气相部分通过管道101与所述BOG缓冲罐2上部的管道21相连通,LNG槽车10的BOG气相口也通过调节阀22连接压缩液化回收系统(或称压缩回收撬),所述LNG储罐1上部的气相管道11及气液分离器8上部的气相管道81上分别设置有调节阀12、82,所述调节阀12、22、82分别与压缩回收系统的温度变送器、压力变送器13、23和83连锁。待LNG储罐1、缓冲罐2内的压力达到规定值或LNG槽车10卸车完成后,DCS将控制系统自动启动压缩回收撬,对LNG储罐1、缓冲罐2和LNG槽车10内的BOG气体进行回收。为了防止气体逆向流动,所述管道101与所述BOG缓冲罐2上部的管道21上分别设置止回阀102、24。In order to realize the system DCS control, a regulating valve 22 is installed at the gas phase outlet pipeline 21 of the BOG buffer tank 2, and the gas phase part of the LNG tank car 10 communicates with the pipeline 21 on the top of the BOG buffer tank 2 through the pipeline 101, and the gas phase of the LNG tank car 10 is connected to each other through the pipeline 101. The BOG gas phase port is also connected to the compression liquefaction recovery system (or compression recovery skid) through the regulating valve 22, and the gas phase pipeline 11 on the upper part of the LNG storage tank 1 and the gas phase pipeline 81 on the upper part of the gas-liquid separator 8 are respectively provided with regulating valves 12 , 82, the regulating valves 12, 22, 82 are respectively linked with the temperature transmitter, pressure transmitter 13, 23 and 83 of the compression recovery system. After the pressure in the LNG storage tank 1 and the buffer tank 2 reaches the specified value or the unloading of the LNG tank truck 10 is completed, the DCS will automatically start the compression recovery skid by the control system. BOG gas is recovered. In order to prevent gas from flowing backward, check valves 102 and 24 are provided on the pipeline 101 and the pipeline 21 on the upper part of the BOG buffer tank 2 respectively.
参考图2至图4,所述真空绝热三位一体换热器3包括外壳34和内胆35,所述外壳34和所述内胆35之间形成有真空真空壳36,所述真空绝热三位一体换热器3的若干换热管37集成设置于所述内胆35内部,形成一级换热区31、二级换热区32以及三级换热区33。所述真空绝热三位一体换热器3的一级换热区31与二级换热区32之间、二级换热区32与三级换热区33之间的管程39分别通过管程连接腔391相连通;所述真空绝热三位一体换热器3的一级换热区31与二级换热区32之间、二级换热区32与三级换热区33之间的壳程38分别通过壳程连接管381相连通。另外,所述真空绝热三位一体换热器3的内胆35中布设有螺旋折流板351,利于增强真空绝热三位一体换热器的换热效果。Referring to Fig. 2 to Fig. 4, the vacuum thermal insulation trinity heat exchanger 3 includes an outer shell 34 and an inner tank 35, a vacuum shell 36 is formed between the outer shell 34 and the inner tank 35, and the vacuum thermal insulation trinity heat exchanger Several heat exchange tubes 37 of the device 3 are integrally arranged inside the inner tank 35 to form a primary heat exchange area 31 , a secondary heat exchange area 32 and a tertiary heat exchange area 33 . The tubes 39 between the primary heat exchange area 31 and the secondary heat exchange area 32 and between the secondary heat exchange area 32 and the tertiary heat exchange area 33 of the vacuum insulation trinity heat exchanger 3 are respectively connected by tubes The cavity 391 is connected; the shell side 38 between the primary heat exchange area 31 and the secondary heat exchange area 32 and between the secondary heat exchange area 32 and the tertiary heat exchange area 33 of the vacuum insulation trinity heat exchanger 3 They are respectively communicated through shell-side connecting pipes 381 . In addition, a spiral baffle 351 is disposed in the inner tank 35 of the vacuum insulation trinity heat exchanger 3, which is beneficial to enhance the heat exchange effect of the vacuum insulation trinity heat exchanger.
请再参考图1,采用以上所述系统回收BOG的方法,包括如下步骤:Please refer to Figure 1 again, the method for recycling BOG using the above-mentioned system includes the following steps:
S1.将LNG加气站管道内BOG气体收集至BOG缓冲罐2,待BOG缓冲罐2、LNG储罐1中BOG压力达到一定值时或槽车卸车完成后,将LNG储罐1、LNG槽车10和BOG缓冲罐2中的低温回收BOG通过调节阀调压至合适压力和流量后送入真空绝热三位一体换热器3的一级换热区31换热;S1. Collect the BOG gas in the pipeline of the LNG filling station to the BOG buffer tank 2. When the BOG pressure in the BOG buffer tank 2 and LNG storage tank 1 reaches a certain value or after the unloading of the tank truck is completed, the LNG storage tank 1 and the LNG tank The low-temperature recovery BOG in the car 10 and the BOG buffer tank 2 is adjusted to a suitable pressure and flow through the regulating valve, and then sent to the primary heat exchange zone 31 of the vacuum insulation trinity heat exchanger 3 for heat exchange;
S2.在真空绝热三位一体换热器3中,低温回收BOG与常温的压缩NG进行一级换热,使低温回收BOG温度升至20℃左右变成常温NG(天然气),然后常温NG送入膨胀压缩一体机4的压缩机41中进行一级压缩增压;S2. In the vacuum adiabatic trinity heat exchanger 3, the low-temperature recovered BOG performs one-stage heat exchange with the normal-temperature compressed NG, so that the temperature of the low-temperature recovered BOG rises to about 20°C to become normal-temperature NG (natural gas), and then the normal-temperature NG is sent to expand One-stage compression boosting is carried out in the compressor 41 of the compression integrated machine 4;
S3.绝热膨胀压缩一体机4的第一级压缩机41依靠绝热膨胀机42的机械能带动,对常温NG进行一级压缩增压,并用一级空温式换热器5对BOG气体进行降温至常温NG,将常温NG送入二级压缩机7进行二级压缩增压至10MPa,两级压缩采用级间空温冷凝,使压缩后的NG气体温度在30℃左右,然后将压缩NG送至真空绝热三位一体换热器3中进行冷却;S3. The first-stage compressor 41 of the adiabatic expansion and compression integrated machine 4 relies on the mechanical energy of the adiabatic expander 42 to perform one-stage compression and boosting of normal temperature NG, and uses the first-stage air-temperature heat exchanger 5 to cool the BOG gas to Normal temperature NG, send normal temperature NG to the secondary compressor 7 for secondary compression and pressurization to 10MPa. Cooling in vacuum insulated trinity heat exchanger 3;
S4.压缩NG在真空绝热三位一体换热器中分别与低温回收BOG、气液分离器NG及气液分离器中部分LNG进行三级换热,使压缩NG温度降至-110℃左右,然后将NG送入膨胀压缩一体机4的膨胀机42,使NG压力降至400KPa,NG的温度降至-160℃左右,大部分NG被液化成LNG;S4. The compressed NG performs three-stage heat exchange with the low-temperature recovered BOG, the gas-liquid separator NG and part of the LNG in the gas-liquid separator respectively in the vacuum adiabatic trinity heat exchanger, so that the temperature of the compressed NG drops to about -110°C, and then The NG is sent to the expander 42 of the expansion-compression integrated machine 4, so that the pressure of the NG drops to 400KPa, the temperature of the NG drops to about -160°C, and most of the NG is liquefied into LNG;
S5.将绝热膨胀后的气液混合物送入气液分离器8,实现气液分离,气态低温NG通过调节阀82调压后送至真空绝热三位一体换热器3的二级换热区32换热,LNG一部分泵送至LNG储罐1,另一部分送至真空绝热三位一体换热器3的三级换热区33壳程与二三级之间(即二级换热区与三级换热区之间)管程连接腔391来的二级冷却压缩NG换热,温度升至-120℃而气化,LNG气化后通过二三级之间壳程连接管381进入二级换热区32后与从气液分离器8来的低温NG气体一起进入三级管式换热器3的二级换热区32壳程冷却压缩NG,出二级换热区32经一二级(即一级换热区与二级换热区之间)之间的壳程连接管381进入一级换热区31壳程38并与低温回收BOG一起对进入一级换热区31管程39的压缩NG气体进行第一级换热。S5. The gas-liquid mixture after adiabatic expansion is sent to the gas-liquid separator 8 to realize gas-liquid separation, and the gaseous low-temperature NG is sent to the secondary heat exchange zone 32 of the vacuum adiabatic trinity heat exchanger 3 after the pressure is adjusted by the regulating valve 82. One part of the LNG is pumped to the LNG storage tank 1, and the other part is sent to the third-stage heat exchange zone 33 of the vacuum insulated trinity heat exchanger 3 between the shell side and the second and third stages (that is, the second-stage heat exchange zone and the third-stage heat exchange The second-stage cooling compressed NG from the tube-side connection chamber 391 between the zones) is heat-exchanged, and the temperature rises to -120°C to be gasified. After gasification, the LNG enters the secondary heat-exchange zone through the shell-side connection tube 381 between the second and third stages After 32, enter the secondary heat exchange zone 32 of the three-stage tubular heat exchanger 3 together with the low-temperature NG gas from the gas-liquid separator 8 to cool and compress NG in the shell side, and go out of the secondary heat exchange zone 32 through the first and second stages (i.e. The shell side connecting pipe 381 between the primary heat exchange area and the secondary heat exchange area) enters the shell side 38 of the primary heat exchange area 31 and connects the tube side 39 of the primary heat exchange area 31 together with the low-temperature recovered BOG Compress NG gas for first stage heat exchange.
本发明采用低温BOG绝热膨胀制冷时产生的机械能带动压缩机,同时对富热后的BOG进行一级压缩,降低能耗,提高制冷效率;采用真空绝热三位一体螺旋折流板列管式换热器实现BOG压缩制冷液化各工段的冷能充分利用,增强传热效率,提高BOG回收的液化效率;采用DCS对BOG压缩回收撬进行控制,安全可靠,操作简单,利于减小LNG加气站的安全隐患,能够实现BOG气体高效回收,从而避免BOG气体放空处理造成的环境污染和资源浪费。The invention adopts the mechanical energy generated during the adiabatic expansion and refrigeration of low-temperature BOG to drive the compressor, and at the same time performs one-stage compression on the heat-enriched BOG to reduce energy consumption and improve refrigeration efficiency; a vacuum-insulated trinity spiral baffle tube-and-tube heat exchanger is adopted Realize full use of cold energy in each section of BOG compression refrigeration liquefaction, enhance heat transfer efficiency, and improve liquefaction efficiency of BOG recovery; DCS is used to control BOG compression recovery skids, which is safe, reliable, and easy to operate, which is conducive to reducing the safety of LNG filling stations Hidden dangers can realize efficient recovery of BOG gas, thereby avoiding environmental pollution and resource waste caused by BOG gas venting.
以上所述仅为本发明示意性的具体实施方式,并非用以限定本发明的范围。如真空绝热三位一体螺旋折流板列管式换热器也可以采用三级以上或其他形式多级换热器结构实现,任何本领域的技术人员,在不脱离本发明的构思和原则的前提下所作出的等同变化与修改,均应属于本发明保护的范围。The above descriptions are only illustrative specific implementations of the present invention, and are not intended to limit the scope of the present invention. For example, the three-in-one spiral baffle tube and tube heat exchanger with vacuum insulation can also be realized by adopting three or more stages or other forms of multi-stage heat exchanger structure. The equivalent changes and modifications made shall all belong to the scope of protection of the present invention.
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| US11577191B1 (en) | 2021-09-09 | 2023-02-14 | ColdStream Energy IP, LLC | Portable pressure swing adsorption method and system for fuel gas conditioning |
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