CN105679512B - Chip inductor and its preparation method and application - Google Patents
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
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- H01F27/30—Fastening or clamping coils, windings, or parts thereof together; Fastening or mounting coils or windings on core, casing, or other support
- H01F27/306—Fastening or mounting coils or windings on core, casing or other support
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- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
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Abstract
Description
技术领域technical field
本发明涉及电感器的制造领域,尤其涉及一种片式电感器及其制备方法和应用。The invention relates to the manufacturing field of inductors, in particular to a chip inductor and its preparation method and application.
背景技术Background technique
片式电感器是电子产业应用中最广泛的片式元器件之一,其生产工艺随着国内片式电感行业的发展也日渐成熟,为满足人们对元器件越来越高的需求,电子元器件正向小型化、高频化、大功率和低功耗等方向发展。Chip inductors are one of the most widely used chip components in the electronics industry. With the development of the domestic chip inductor industry, their production technology is becoming more and more mature. In order to meet people's increasing demand for components, electronic components Devices are developing in the direction of miniaturization, high frequency, high power and low power consumption.
然而,传统的片式电感器线圈是直接印刷在基体上,线圈印刷具有一定的厚度,使得线圈图案与基体之间存在落差,在覆盖介质层时容易造成连接处形成气泡,导致产品可靠性降低,线圈的印刷厚度受到很大的限制,使得片式电感器的额定电流较小,不能满足人们对产品性能越来越高的需求。However, the traditional chip inductor coil is directly printed on the substrate, and the coil printing has a certain thickness, so that there is a gap between the coil pattern and the substrate, and it is easy to cause bubbles to form at the connection when covering the dielectric layer, resulting in reduced product reliability. , The printing thickness of the coil is greatly limited, so that the rated current of the chip inductor is small, which cannot meet people's increasing demand for product performance.
发明内容Contents of the invention
鉴于此,有必要提供一种能够制备出额定电流较大的片式电感器的制备方法。In view of this, it is necessary to provide a preparation method capable of preparing a chip inductor with a large rated current.
此外,还提供一种片式电感器及其应用。In addition, a chip inductor and its application are also provided.
一种片式电感器的制备方法,包括如下步骤:A method for preparing a chip inductor, comprising the steps of:
提供第一铁氧体基板坯体,在所述第一铁氧体基板坯体上形成具有第一电极槽的第一铁氧体坯体层,并在所述第一电极槽内形成第一电极;A first ferrite substrate blank is provided, a first ferrite blank layer having a first electrode groove is formed on the first ferrite substrate blank, and a first ferrite substrate layer is formed in the first electrode groove. electrode;
在所述第一电极上形成电连接件;forming an electrical connection on the first electrode;
使用铁氧体浆料在所述第一铁氧体坯体层上形成介质膜坯体层,且所述介质膜坯体层遮蔽所述第一铁氧体坯体层和所述第一电极,所述电连接件穿设于所述介质膜坯体层,其中,所述第一铁氧体坯体层、所述第一电极、所述电连接件和所述介质膜坯体层共同组成电感单元;Using ferrite slurry to form a dielectric film base layer on the first ferrite base layer, and the dielectric film base layer shields the first ferrite base layer and the first electrode , the electrical connector is passed through the dielectric film base layer, wherein the first ferrite base layer, the first electrode, the electrical connector and the dielectric film base layer are in common Form the inductance unit;
在所述介质膜坯体层上形成具有第二电极槽的第二铁氧体坯体层,并在所述第二电极槽内形成第二电极,且所述第二电极与所述电连接件电连接;A second ferrite base layer with a second electrode groove is formed on the dielectric film base layer, and a second electrode is formed in the second electrode groove, and the second electrode is electrically connected to the parts electrical connection;
提供第二铁氧体基板坯体,在所述第二铁氧体坯体层上层叠所述第二铁氧体基板坯体,且所述第二铁氧体基板坯体遮蔽所述第二铁氧体坯体层和所述第二电极,得到半成品;及A second ferrite substrate blank is provided, the second ferrite substrate blank is laminated on the second ferrite substrate layer, and the second ferrite substrate blank covers the second a ferrite green body layer and said second electrode to obtain a semi-finished product; and
将所述半成品烧结,得到片式电感器。The semi-finished product is sintered to obtain a chip inductor.
在其中一个实施例中,还包括所述第一铁氧体基板坯体和所述第二铁氧体基板坯体的制备步骤:将软磁铁氧体浆料流延成型后干燥,分别形成所述第一铁氧体基板坯体和所述第二铁氧体基板坯体;In one of the embodiments, it also includes the step of preparing the first ferrite substrate body and the second ferrite substrate body: tape-casting the soft ferrite slurry and drying to form the The first ferrite substrate blank and the second ferrite substrate blank;
其中,所述软磁铁氧体浆料包括软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂,所述醋酸正丙酯与所述软磁铁氧体粉体的质量比为75~85:100,所述异丁醇与所述软磁铁氧体粉体的质量比为15~20:100。Wherein, the soft ferrite slurry includes soft ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant, and the n-propyl acetate and the soft ferrite The mass ratio of the body powder is 75-85:100, and the mass ratio of the isobutanol to the soft ferrite powder is 15-20:100.
在其中一个实施例中,使用所述铁氧体浆料在所述第一铁氧体坯体层上形成所述介质膜坯体层的步骤具体为:在所述第一铁氧体坯体层上涂覆所述铁氧体浆料,并使所述铁氧体浆料遮蔽所述第一铁氧体坯体层和所述第一电极,且使所述电连接件露出,经干燥,形成所述介质膜坯体层;In one of the embodiments, the step of using the ferrite slurry to form the dielectric film base layer on the first ferrite base layer is specifically: coating the ferrite slurry on the layer, and making the ferrite slurry cover the first ferrite green body layer and the first electrode, exposing the electrical connector, and drying , forming the dielectric film green body layer;
其中,所述铁氧体浆料包括软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂,所述醋酸正丙酯与所述软磁铁氧体粉体的质量比为75~85:100,所述异丁醇与所述软磁铁氧体粉体的质量比为15~20:100。Wherein, the ferrite slurry includes soft ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant, and the n-propyl acetate and the soft ferrite The mass ratio of the powder is 75-85:100, and the mass ratio of the isobutanol to the soft ferrite powder is 15-20:100.
在其中一个实施例中,在所述第一电极槽内形成所述第一电极的步骤具体为:在所述第一电极槽内填充银浆,经干燥后形成所述第一电极;In one of the embodiments, the step of forming the first electrode in the first electrode groove specifically includes: filling silver paste in the first electrode groove, and forming the first electrode after drying;
在所述第二电极槽内形成所述第二电极的步骤具体为:在所述第二电极槽内填充所述银浆,经干燥后形成所述第二电极。The step of forming the second electrode in the second electrode groove specifically includes: filling the silver paste in the second electrode groove, and forming the second electrode after drying.
在其中一个实施例中,在所述第一电极上形成所述电连接件的步骤具体为:在部分所述第一电极上丝网印刷银浆,经干燥,得到所述电连接件。In one embodiment, the step of forming the electrical connector on the first electrode specifically includes: screen printing silver paste on a part of the first electrode, and drying to obtain the electrical connector.
在其中一个实施例中,在所述第一铁氧体基板坯体上形成具有所述第一电极槽的所述第一铁氧体坯体层的方法为丝网印刷;在所述介质膜坯体层上形成具有所述第二电极槽的所述第二铁氧体坯体层的方法为丝网印刷。In one of the embodiments, the method of forming the first ferrite green body layer with the first electrode groove on the first ferrite substrate green body is screen printing; on the dielectric film The method for forming the second ferrite green body layer with the second electrode groove on the green body layer is screen printing.
在其中一个实施例中,在所述介质膜坯体层上形成具有所述第二电极槽的所述第二铁氧体坯体层的步骤之前,还包括多次重复制备所述第一铁氧体坯体层、所述第一电极、所述电连接件和所述介质膜坯体层的步骤,以使所述第一铁氧体基板坯体上形成多个依次层叠的所述电感单元,且相邻两个所述电感单元中,一个所述电感单元的第一铁氧体坯体层形成于另一个所述电感单元的介质膜坯体层上。In one of the embodiments, before the step of forming the second ferrite green body layer with the second electrode groove on the dielectric film green body layer, it also includes repeatedly preparing the first ferrite green body layer. Oxygen green body layer, the first electrode, the electrical connector and the dielectric film green body layer, so that a plurality of sequentially stacked inductors are formed on the first ferrite substrate green body unit, and among the two adjacent inductor units, the first ferrite base layer of one inductor unit is formed on the dielectric film base layer of the other inductor unit.
一种片式电感器,包括第一铁氧体基板、第一铁氧体层、第一电极、介质膜层、第二铁氧体层、第二电极、电连接件及第二铁氧体基板,其中,所述第一铁氧体层、所述介质膜层、所述第二铁氧体层和所述第二铁氧体基板依次层叠于所述第一铁氧体基板上;所述第一铁氧体层上开设有第一电极槽,所述第一电极收容于所述第一电极槽中;所述第二铁氧体层上开设有第二电极槽,所述第二电极收容于所述第二电极槽中;所述电连接件穿设于所述介质膜层,且所述电连接件电连接所述第一电极和所述第二电极;所述介质膜层的材料为铁氧体,所述第一铁氧体层、所述第一电极、所述介质膜层和所述电连接件共同组成电感单元。A chip inductor, comprising a first ferrite substrate, a first ferrite layer, a first electrode, a dielectric film layer, a second ferrite layer, a second electrode, an electrical connector and a second ferrite A substrate, wherein the first ferrite layer, the dielectric film layer, the second ferrite layer and the second ferrite substrate are sequentially stacked on the first ferrite substrate; A first electrode slot is opened on the first ferrite layer, and the first electrode is accommodated in the first electrode slot; a second electrode slot is opened on the second ferrite layer, and the second electrode slot is opened on the second ferrite layer. The electrodes are accommodated in the second electrode groove; the electrical connectors are penetrated through the dielectric film layer, and the electrical connectors are electrically connected to the first electrode and the second electrode; the dielectric film layer The material is ferrite, and the first ferrite layer, the first electrode, the dielectric film layer and the electrical connector together form an inductor unit.
在其中一个实施例中,所述电感单元为多个,且多个所述电感单元依次层叠于所述第一铁氧体基板上,相邻两个所述电感单元中,一个所述电感单元的第一铁氧体层层叠于另一个所述电感单元的介质膜层上,且一个所述电感单元的电连接件与另一个所述电感单元的第一电极电连接,所述第二铁氧体层层叠于离所述第一铁氧体基板最远的所述电感单元的介质膜层上。In one of the embodiments, there are a plurality of inductance units, and the plurality of inductance units are sequentially stacked on the first ferrite substrate, and among two adjacent inductance units, one of the inductance units The first ferrite layer of the inductance unit is stacked on the dielectric film layer of the other inductance unit, and the electrical connector of one inductance unit is electrically connected with the first electrode of the other inductance unit, and the second ferrite The oxide layer is stacked on the dielectric film layer of the inductor unit farthest from the first ferrite substrate.
上述片式电感器在电子产品中的应用。Application of the above-mentioned chip inductors in electronic products.
上述片式电感器的制备方法操作简单,易于工业化生产,且上述片式电感器的制备方法通过将电极填入到电极槽中,使得介质膜坯体层与第一铁氧体坯体层、第二铁氧体坯体层的连接处平整,避免了气泡的形成,且电极填入电极槽的方式能够有效地增加电极的厚度,降低电极的直流电阻,提高了片式电感器的额定电流和可靠性。The preparation method of the above-mentioned chip inductor is simple to operate and easy to industrialized production, and the preparation method of the above-mentioned chip inductor is filled in the electrode groove by filling the electrode, so that the dielectric film green body layer and the first ferrite green body layer, The connection of the second ferrite body layer is flat, avoiding the formation of air bubbles, and the way the electrodes are filled into the electrode slots can effectively increase the thickness of the electrodes, reduce the DC resistance of the electrodes, and increase the rated current of the chip inductor and reliability.
附图说明Description of drawings
图1为一实施方式的片式电感器的制备方法流程图;Fig. 1 is a flow chart of the preparation method of the chip inductor of an embodiment;
图2为图1所示的片式电感器的制备方法制备得到的半成品的分解图;Fig. 2 is the exploded view of the semi-finished product prepared by the preparation method of the chip inductor shown in Fig. 1;
图3为一实施方式的片式电感器的分解图。FIG. 3 is an exploded view of a chip inductor according to one embodiment.
具体实施方式detailed description
为了便于理解本发明,下面将参照相关附图对本发明进行更全面的描述。附图中给出了本发明的较佳的实施例。但是,本发明可以以许多不同的形式来实现,并不限于本文所描述的实施例。相反地,提供这些实施例的目的是使对本发明的公开内容的理解更加透彻全面。In order to facilitate the understanding of the present invention, the present invention will be described more fully below with reference to the associated drawings. Preferred embodiments of the invention are shown in the accompanying drawings. However, the present invention can be embodied in many different forms and is not limited to the embodiments described herein. On the contrary, these embodiments are provided to make the understanding of the disclosure of the present invention more thorough and comprehensive.
除非另有定义,本文所使用的所有的技术和科学术语与属于本发明的技术领域的技术人员通常理解的含义相同。本文中在本发明的说明书中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本发明。Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the technical field of the invention. The terms used herein in the description of the present invention are for the purpose of describing specific embodiments only, and are not intended to limit the present invention.
如图1所示,一实施方式的片式电感器的制备方法,包括如下步骤:As shown in Figure 1, the preparation method of the chip inductor of an embodiment comprises the following steps:
步骤S110:提供第一铁氧体基板坯体,在第一铁氧体基板坯体上形成具有第一电极槽的第一铁氧体坯体层,并在第一电极槽内形成第一电极。Step S110: providing a first ferrite substrate blank, forming a first ferrite blank layer with a first electrode groove on the first ferrite substrate blank, and forming a first electrode in the first electrode groove .
其中,第一铁氧体基板坯体的制备步骤为:将软磁铁氧体浆料流延成型后干燥,形成第一铁氧体基板坯体。Wherein, the preparation step of the first ferrite substrate body is: tape-casting the soft magnetic ferrite slurry and then drying to form the first ferrite substrate body.
其中,软磁铁氧体浆料包括软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂。Wherein, the soft ferrite slurry includes soft ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant.
其中,软磁铁氧体粉体为是以Fe2O3为主成分的亚铁磁性氧化物,可采用粉末冶金方法生产。将软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂制备成软磁铁氧体浆料之前,先将软磁铁氧体粉体于100~150℃干燥6~12小时。Among them, the soft magnetic ferrite powder is a ferrimagnetic oxide mainly composed of Fe 2 O 3 , which can be produced by powder metallurgy. Before preparing soft magnetic ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant into soft ferrite slurry, first put the soft ferrite powder at 100-150°C Dry for 6-12 hours.
醋酸正丙酯与软磁铁氧体粉体的质量比为75~85:100。异丁醇与软磁铁氧体粉体的质量比为15~20:100。The mass ratio of n-propyl acetate to soft magnetic ferrite powder is 75-85:100. The mass ratio of isobutanol to soft magnetic ferrite powder is 15-20:100.
增塑剂与软磁铁氧体粉体的质量比为1.5~2.5:100;增塑剂可以为本领域常用的增塑剂,优选的,增塑剂为邻苯二甲酸二辛酯。例如,型号为DOP的邻苯二甲酸二辛酯增塑剂。The mass ratio of the plasticizer to the soft magnetic ferrite powder is 1.5-2.5:100; the plasticizer can be a commonly used plasticizer in this field, preferably, the plasticizer is dioctyl phthalate. For example, dioctyl phthalate plasticizer under the model number DOP.
粘结剂可以为本领域常用的粘结剂,优选的,粘结剂为聚甲基丙烯酸甲酯树脂。在本实施例中,粘结剂为型号为B44和A21的聚甲基丙烯酸甲酯树脂的混合物、或者为型号为B44的聚甲基丙烯酸甲酯树脂。当粘结剂为型号为B44的聚甲基丙烯酸甲酯树脂时,粘结剂与软磁铁氧体粉体的质量比为20~25:100;当粘结剂为型号为B44和A21的聚甲基丙烯酸甲酯树脂的混合物时,粘结剂与软磁铁氧体粉体的质量比为1~1.5:100。The binder may be a commonly used binder in the field, preferably, the binder is polymethyl methacrylate resin. In this embodiment, the binder is a mixture of polymethyl methacrylate resins of type B44 and A21, or a polymethyl methacrylate resin of type B44. When the binder is polymethyl methacrylate resin of model B44, the mass ratio of binder to soft ferrite powder is 20-25:100; when the binder is polymethyl methacrylate resin of model B44 and A21 For the mixture of methyl methacrylate resin, the mass ratio of binder to soft ferrite powder is 1-1.5:100.
分散剂与软磁铁氧体粉体的质量比为1~1.5:100。分散剂可以为本领域常用的分散剂,优选的,分散剂为聚乙二醇辛基苯基醚。例如,型号为X-100的聚乙二醇辛基苯基醚分散剂。The mass ratio of the dispersant to the soft magnetic ferrite powder is 1-1.5:100. The dispersant can be a dispersant commonly used in the art, preferably, the dispersant is polyethylene glycol octylphenyl ether. For example, polyethylene glycol octyl phenyl ether dispersant type X-100.
其中,软磁铁氧体浆料也可以为青岛浩普公司的生产的LSF-11型号的大功率铁氧体浆料。Wherein, the soft magnetic ferrite slurry may also be LSF-11 type high-power ferrite slurry produced by Qingdao Haopu Company.
其中,将软磁铁氧体浆料流延成型后的干燥步骤为:75℃干燥3.5分钟。Wherein, the drying step after tape-casting the soft ferrite slurry is: drying at 75° C. for 3.5 minutes.
具体的,第一铁氧体基板坯体的厚度为100~300微米。Specifically, the thickness of the first ferrite substrate blank is 100-300 microns.
其中,在第一铁氧体基板坯体上形成具有第一电极槽的第一铁氧体坯体层的方法为丝网印刷。形成第一铁氧体坯体层使用的浆料为可塑性铁氧体浆料。例如,银辉电子材料公司的生产的H-T型号的可塑性铁氧体浆料。Wherein, the method of forming the first ferrite body layer with the first electrode groove on the first ferrite substrate body is screen printing. The slurry used to form the first ferrite green body layer is plastic ferrite slurry. For example, the plastic ferrite slurry of H-T type produced by Yinhui Electronic Materials Co., Ltd.
其中,第一铁氧体坯体层的厚度为40~60微米。Wherein, the thickness of the first ferrite body layer is 40-60 microns.
其中,在第一电极槽内形成第一电极的步骤具体为:在第一电极槽内填充银浆,经干燥后形成第一电极。如,银浆可以为东荣公司生产的SP19L型号的银浆。Wherein, the step of forming the first electrode in the first electrode groove specifically includes: filling the first electrode groove with silver paste, and forming the first electrode after drying. For example, the silver paste can be the silver paste of SP19L type produced by Dongrong Company.
其中,在第一电极槽内填充银浆后的干燥步骤为:70℃干燥3.5分钟。Wherein, the drying step after filling the silver paste in the first electrode tank is: drying at 70° C. for 3.5 minutes.
步骤S120:在第一电极上形成电连接件。Step S120: forming an electrical connection on the first electrode.
其中,在第一电极上形成电连接件的步骤具体为:在部分第一电极上丝网印刷银浆,经干燥,得到电连接件。例如,银浆可以为东荣公司生产的SP19L型号的银浆。Wherein, the step of forming the electrical connector on the first electrode specifically includes: screen printing silver paste on a part of the first electrode, and drying to obtain the electrical connector. For example, the silver paste can be the silver paste of SP19L type produced by Dongrong Company.
其中,在部分第一电极上丝网印刷银浆的干燥步骤为:70℃干燥3.5分钟。Wherein, the drying step of screen printing silver paste on part of the first electrodes is: drying at 70° C. for 3.5 minutes.
步骤S130:使用铁氧体浆料在第一铁氧体坯体层上形成介质膜坯体层,且介质膜坯体层遮蔽第一铁氧体坯体层和第一电极,电连接件穿设于介质膜坯体层,其中,第一铁氧体坯体层、第一电极、电连接件及介质膜坯体层共同组成电感单元。Step S130: using ferrite slurry to form a dielectric film base layer on the first ferrite base layer, and the dielectric film base layer shields the first ferrite base layer and the first electrode, and the electrical connector passes through It is arranged on the dielectric film base layer, wherein the first ferrite base layer, the first electrode, the electrical connector and the dielectric film base layer jointly form an inductor unit.
其中,使用铁氧体浆料在第一铁氧体坯体层上形成介质膜坯体层的步骤具体为:在第一铁氧体坯体层上涂覆铁氧体浆料,并使铁氧体浆料遮蔽第一铁氧体坯体层和第一电极,且使电连接件露出,经干燥,形成介质膜坯体层。Wherein, the step of using the ferrite slurry to form the dielectric film green body layer on the first ferrite green body layer is as follows: coating the ferrite slurry on the first ferrite green body layer, and making the iron The oxide slurry shields the first ferrite body layer and the first electrode, and exposes the electrical connector, and is dried to form a dielectric film body layer.
其中,铁氧体浆料包括软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂。Wherein, the ferrite slurry includes soft magnetic ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant.
其中,软磁铁氧体粉体为是以Fe2O3为主成分的亚铁磁性氧化物,可采用粉末冶金方法生产。将软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂制备成软磁铁氧体浆料之前,先将软磁铁氧体粉体于100~150℃干燥6~12小时。Among them, the soft magnetic ferrite powder is a ferrimagnetic oxide mainly composed of Fe 2 O 3 , which can be produced by powder metallurgy. Before preparing soft magnetic ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant into soft ferrite slurry, first put the soft ferrite powder at 100-150°C Dry for 6-12 hours.
醋酸正丙酯与软磁铁氧体粉体的质量比为75~85:100。异丁醇与软磁铁氧体粉体的质量比为15~20:100。The mass ratio of n-propyl acetate to soft magnetic ferrite powder is 75-85:100. The mass ratio of isobutanol to soft magnetic ferrite powder is 15-20:100.
增塑剂与软磁铁氧体粉体的质量比为1.5~2.5:100;增塑剂可以为本领域常用的增塑剂,优选的,增塑剂为邻苯二甲酸二辛酯。例如,型号为DOP的邻苯二甲酸二辛酯增塑剂。The mass ratio of the plasticizer to the soft magnetic ferrite powder is 1.5-2.5:100; the plasticizer can be a commonly used plasticizer in this field, preferably, the plasticizer is dioctyl phthalate. For example, dioctyl phthalate plasticizer under the model number DOP.
粘结剂可以为本领域常用的粘结剂,优选的,粘结剂为聚甲基丙烯酸甲酯树脂。在本实施例中,粘结剂为型号为B44和A21的聚甲基丙烯酸甲酯树脂的混合物、或者为型号为B44的聚甲基丙烯酸甲酯树脂。当粘结剂为型号为B44的聚甲基丙烯酸甲酯树脂时,粘结剂与软磁铁氧体粉体的质量比为20~25:100;当粘结剂为型号为B44和A21的聚甲基丙烯酸甲酯树脂的混合物时,粘结剂与软磁铁氧体粉体的质量比为1~1.5:100。The binder may be a commonly used binder in the field, preferably, the binder is polymethyl methacrylate resin. In this embodiment, the binder is a mixture of polymethyl methacrylate resins of type B44 and A21, or a polymethyl methacrylate resin of type B44. When the binder is polymethyl methacrylate resin of model B44, the mass ratio of binder to soft ferrite powder is 20-25:100; when the binder is polymethyl methacrylate resin of model B44 and A21 For the mixture of methyl methacrylate resin, the mass ratio of binder to soft ferrite powder is 1-1.5:100.
分散剂与软磁铁氧体粉体的质量比为1~1.5:100。分散剂可以为本领域常用的分散剂,优选的,分散剂为聚乙二醇辛基苯基醚。例如,型号为X-100的聚乙二醇辛基苯基醚分散剂。The mass ratio of the dispersant to the soft magnetic ferrite powder is 1-1.5:100. The dispersant may be a dispersant commonly used in the art, preferably, the dispersant is polyethylene glycol octylphenyl ether. For example, polyethylene glycol octyl phenyl ether dispersant type X-100.
在本实施例中,制备介质膜坯体层使用的铁氧体浆料与制备第一铁氧体坯体层使用的软磁铁氧体浆料的组成相同。例如,制备介质膜坯体层使用的铁氧体浆料也可以为青岛浩普公司的生产的LSF-11型号的大功率铁氧体浆料。In this embodiment, the composition of the ferrite slurry used to prepare the dielectric film green body layer is the same as that of the soft ferrite slurry used to prepare the first ferrite green body layer. For example, the ferrite slurry used for preparing the dielectric film green body layer may also be the LSF-11 type high-power ferrite slurry produced by Qingdao Haopu Company.
其中,介质膜坯体层的厚度为30~50微米。Wherein, the thickness of the dielectric film base layer is 30-50 microns.
步骤S140:在介质膜坯体层上形成具有第二电极槽的第二铁氧体坯体层,并在第二电极槽内形成第二电极,且第二电极与电连接件电连接。Step S140 : forming a second ferrite green layer with a second electrode groove on the dielectric film green layer, and forming a second electrode in the second electrode groove, and the second electrode is electrically connected to the electrical connector.
其中,在介质膜坯体层上形成具有第二电极槽的第二铁氧体坯体层的方法为丝网印刷。形成第二铁氧体坯体层使用的浆料为可塑性铁氧体浆料。例如,银辉电子材料公司的生产的H-T型号的可塑性铁氧体浆料。Wherein, the method of forming the second ferrite green body layer with the second electrode groove on the dielectric film green body layer is screen printing. The slurry used to form the second ferrite green body layer is plastic ferrite slurry. For example, the plastic ferrite slurry of H-T type produced by Yinhui Electronic Materials Co., Ltd.
其中,第二铁氧体坯体层的厚度为40~60微米。Wherein, the thickness of the second ferrite green body layer is 40-60 microns.
其中,在第二电极槽内形成第二电极的步骤具体为:在第二电极槽内填充银浆,经干燥后形成第二电极。例如,银浆可以为东荣公司生产的SP19L型号的银浆。Wherein, the step of forming the second electrode in the second electrode groove is specifically: filling silver paste in the second electrode groove, and forming the second electrode after drying. For example, the silver paste can be the silver paste of SP19L type produced by Dongrong Company.
步骤S150:提供第二铁氧体基板坯体,在第二铁氧体坯体层上层叠第二铁氧体基板坯体,且第二铁氧体基板坯体遮蔽第二铁氧体坯体层和第二电极,得到半成品。Step S150: providing a second ferrite substrate body, laminating the second ferrite substrate body on the second ferrite body layer, and the second ferrite substrate body covering the second ferrite body layer and the second electrode to obtain a semi-finished product.
其中,第二铁氧体基板坯体的制备步骤为:将软磁铁氧体浆料流延成型后干燥,形成第二铁氧体基板坯体。其中,制备第二铁氧体基板坯体使用的软磁铁氧体浆料与制备第一铁氧体基板坯体使用的软磁铁氧体浆料相同。Wherein, the preparation step of the second ferrite substrate body is: tape-casting the soft magnetic ferrite slurry and then drying to form the second ferrite substrate body. Wherein, the soft ferrite slurry used to prepare the second ferrite substrate blank is the same as the soft ferrite slurry used to prepare the first ferrite substrate blank.
具体的,第二铁氧体基板坯体的厚度为100~300微米。Specifically, the thickness of the second ferrite substrate blank is 100-300 microns.
其中,图2为经上述步骤制备得到的一种具有一个电感单元的半成品200,第一铁氧体基板坯体210上依次层叠有第一铁氧体坯体层220、介质膜坯体层230、第二铁氧体坯体层240和第二铁氧体基板坯体250。其中,第一铁氧体坯体层220上形成有第一电极槽222,第一电极槽222内填充有第一电极260,第二铁氧体坯体层240上形成有第二电极槽242,第二电极槽242内填充有第二电极270。第一电极260上形成有与第一电极260电连接的电连接件280,电连接件280穿设于介质膜坯体层230,并与第二电极270电连接。Wherein, Fig. 2 is a semi-finished product 200 with an inductor unit prepared through the above steps, the first ferrite substrate blank 210 is sequentially stacked with a first ferrite blank layer 220, a dielectric film blank layer 230 , the second ferrite green body layer 240 and the second ferrite substrate green body 250 . Wherein, the first electrode groove 222 is formed on the first ferrite green body layer 220, and the first electrode groove 222 is filled with the first electrode 260, and the second electrode groove 242 is formed on the second ferrite green body layer 240. , the second electrode groove 242 is filled with the second electrode 270 . An electrical connector 280 electrically connected to the first electrode 260 is formed on the first electrode 260 . The electrical connector 280 penetrates the dielectric film body layer 230 and is electrically connected to the second electrode 270 .
进一步的,在介质膜坯体层上形成具有第二电极槽的第二铁氧体坯体层的步骤之前,还包括多次重复制备第一铁氧体坯体层、第一电极、电连接件和介质膜坯体层的步骤,以使第一铁氧体基板坯体上形成多个依次层叠的电感单元,且相邻两个电感单元中,一个电感单元的第一铁氧体坯体层形成于另一个电感单元的介质膜坯体层上,一个电感单元的电连接件与另一个电感单元的第一电极电连接,第二铁氧体坯体层层叠于离第一铁氧体基板坯体最远的电感单元的介质膜坯体层上。Further, before the step of forming the second ferrite green body layer with the second electrode groove on the dielectric film green body layer, it also includes repeatedly preparing the first ferrite green body layer, the first electrode, the electrical connection parts and dielectric film green body layers, so that a plurality of successively stacked inductor units are formed on the first ferrite substrate green body, and among two adjacent inductor units, the first ferrite green body of one inductor unit Layers are formed on the dielectric film base layer of another inductor unit, the electrical connector of one inductor unit is electrically connected to the first electrode of the other inductor unit, and the second ferrite base layer is stacked on top of the first ferrite layer. On the dielectric film blank layer of the inductor unit farthest from the substrate blank.
步骤S160:将半成品烧结,得到片式电感器。Step S160: Sintering the semi-finished product to obtain a chip inductor.
其中,烧结步骤为880℃烧结4~6小时。具体的,烧结制度为:从室温升温2小时至230℃,再升温2小时到280℃,继续升温6小时到880℃,并在880℃保温4~6小时后,自然冷却。Wherein, the sintering step is sintering at 880° C. for 4 to 6 hours. Specifically, the sintering system is as follows: from room temperature to 230°C for 2 hours, then to 280°C for 2 hours, to 880°C for 6 hours, and to keep at 880°C for 4 to 6 hours, then to cool naturally.
上述片式电感器的制备方法操作简单,易于工业化生产,且上述片式电感器的制备方法通过将电极填入到电极槽中,使得介质膜坯体层与第一铁氧体坯体层、第二铁氧体坯体层的连接处平整,避免了气泡的形成,且电极填入电极槽的方式能够有效地增加电极的厚度,降低电极的直流电阻,提高了片式电感器的额定电流和可靠性。The preparation method of the above-mentioned chip inductor is simple to operate and easy to industrialized production, and the preparation method of the above-mentioned chip inductor is filled in the electrode groove by filling the electrode, so that the dielectric film green body layer and the first ferrite green body layer, The connection of the second ferrite body layer is flat, avoiding the formation of air bubbles, and the way the electrodes are filled into the electrode slots can effectively increase the thickness of the electrodes, reduce the DC resistance of the electrodes, and increase the rated current of the chip inductor and reliability.
如图3所示,一实施方式的片式电感器300,可由上述片式电感器的制备方法制备得到。该片式电感器300包括第一铁氧体基板310、第一铁氧体层320、第一电极330、介质膜层340、第二铁氧体层350、第二电极360、电连接件370及第二铁氧体基板380。其中,第一铁氧体层320、第一电极330、介质膜层340和电连接件370共同组成电感单元。As shown in FIG. 3 , a chip inductor 300 according to an embodiment can be prepared by the above-mentioned manufacturing method of a chip inductor. The chip inductor 300 includes a first ferrite substrate 310, a first ferrite layer 320, a first electrode 330, a dielectric film layer 340, a second ferrite layer 350, a second electrode 360, and an electrical connector 370. and a second ferrite substrate 380 . Wherein, the first ferrite layer 320 , the first electrode 330 , the dielectric film layer 340 and the electrical connector 370 together form an inductor unit.
其中,第一铁氧体层320、介质膜层340、第二铁氧体层350和第二铁氧体基板380依次层叠于第一铁氧体基板310上。Wherein, the first ferrite layer 320 , the dielectric film layer 340 , the second ferrite layer 350 and the second ferrite substrate 380 are sequentially stacked on the first ferrite substrate 310 .
第一铁氧体层320上开设有第一电极槽322,第一电极330收容于第一电极槽322中。A first electrode groove 322 is opened on the first ferrite layer 320 , and the first electrode 330 is accommodated in the first electrode groove 322 .
第二铁氧体层350上开设有第二电极槽352,第二电极360收容于第二电极352槽中。A second electrode groove 352 is opened on the second ferrite layer 350 , and the second electrode 360 is received in the groove of the second electrode 352 .
电连接件370穿设于介质膜层340,且电连接件370电连接第一电极330和第二电极360。The electrical connector 370 is disposed through the dielectric film layer 340 , and the electrical connector 370 is electrically connected to the first electrode 330 and the second electrode 360 .
介质膜层340的材料为铁氧体。The material of the dielectric film layer 340 is ferrite.
进一步的,电感单元为多个,且多个电感单元依次层叠于第一铁氧体基板310上,相邻两个电感单元中,一个电感单元的第一铁氧体层320层叠于另一个电感单元的介质膜层340上,且一个电感单元的电连接件370与另一个电感单元的第一电极330电连接,第二铁氧体层350层叠于离第一铁氧体基板310最远的电感单元的介质膜层340上。Further, there are multiple inductance units, and the plurality of inductance units are stacked on the first ferrite substrate 310 in sequence. Among two adjacent inductance units, the first ferrite layer 320 of one inductance unit is stacked on the other inductor. On the dielectric film layer 340 of the unit, and the electrical connector 370 of one inductance unit is electrically connected to the first electrode 330 of the other inductance unit, and the second ferrite layer 350 is stacked on the farthest from the first ferrite substrate 310 on the dielectric film layer 340 of the inductor unit.
上述片式电感器300的第一电极330和第二电极360分别收容第一电极槽322和第二电极槽352中,使得介质膜层340与第一铁氧体层320、第二铁氧体层350的连接处平整,避免了气泡的形成,且将第一电极330和第二电极360分别收容于第一电极槽322和第二电极槽352中能够有效地增加电极的厚度,降低电极的直流电阻,提高了片式电感器300的额定电流和可靠性。The first electrode 330 and the second electrode 360 of the above-mentioned chip inductor 300 are accommodated in the first electrode groove 322 and the second electrode groove 352 respectively, so that the dielectric film layer 340 and the first ferrite layer 320, the second ferrite layer The junction of the layer 350 is flat, avoiding the formation of air bubbles, and the first electrode 330 and the second electrode 360 are accommodated in the first electrode groove 322 and the second electrode groove 352 respectively, which can effectively increase the thickness of the electrode and reduce the thickness of the electrode. The DC resistance improves the rated current and reliability of the chip inductor 300 .
上述片式电感器可广泛应用于电子产品中。其中,电子产品为笔记本电脑、智能手机、电源转换器等。The above-mentioned chip inductors can be widely used in electronic products. Among them, electronic products are notebook computers, smart phones, power converters, etc.
以下为具体实施例部分:The following is the specific embodiment part:
实施例1Example 1
本实施例的片式电感器的制备步骤如下:The preparation steps of the chip inductor of this embodiment are as follows:
(1)第一铁氧体基板坯体和第二铁氧体基板坯体的制备:将软磁铁氧体粉体于130℃干燥9小时,再将干燥后的软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂混合制备成软磁铁氧体浆料,其中,醋酸正丙酯与软磁铁氧体粉体的质量比为80:100,异丁醇与软磁铁氧体粉体的质量比为18:100,增塑剂为型号为DOP的邻苯二甲酸二辛酯,增塑剂与软磁铁氧体粉体的质量比为2:100,粘结剂为型号为B44的聚甲基丙烯酸甲酯树脂,粘结剂与软磁铁氧体粉体的质量比为20:100,分散剂为型号为X-100的聚乙二醇辛基苯基醚,分散剂与软磁铁氧体粉体的质量比为1:100。再将软磁铁氧体浆料流延成型后,经75℃干燥3.5分钟,分别形成第一铁氧体基板坯体和第二铁氧体基板坯体。第一铁氧体基板坯体的厚度为100微米,第二铁氧体基板坯体的厚度为100微米。(1) Preparation of the first ferrite substrate blank and the second ferrite substrate blank: dry the soft ferrite powder at 130°C for 9 hours, then dry the dried soft ferrite powder, acetic acid n-propyl ester, isobutanol, plasticizer, binder and dispersant are mixed to prepare soft ferrite slurry, wherein the mass ratio of n-propyl acetate to soft ferrite powder is 80:100, iso The mass ratio of butanol to soft ferrite powder is 18:100, the plasticizer is dioctyl phthalate whose model is DOP, and the mass ratio of plasticizer to soft ferrite powder is 2:100 , the binder is polymethyl methacrylate resin model B44, the mass ratio of binder to soft ferrite powder is 20:100, and the dispersant is polyethylene glycol octyl resin model X-100 The mass ratio of phenyl ether, dispersant and soft ferrite powder is 1:100. The soft magnetic ferrite slurry was tape-casted and dried at 75°C for 3.5 minutes to form a first ferrite substrate blank and a second ferrite substrate blank respectively. The thickness of the first ferrite substrate blank is 100 microns, and the thickness of the second ferrite substrate blank is 100 microns.
(2)第一铁氧体坯体层的制备:在第一铁氧体基板坯体上丝网印刷可塑性铁氧体浆料,经60℃干燥3.5分钟,形成厚度为50微米、具有第一电极槽的第一铁氧体坯体层。(2) Preparation of the first ferrite green body layer: screen-print plastic ferrite paste on the first ferrite substrate green body, and dry at 60°C for 3.5 minutes to form a layer with a thickness of 50 microns and the first The first ferrite green body layer of the electrode tank.
(3)在第一电极槽内填充银浆,经70℃干燥3.5分钟,在第一电极槽内形成第一电极。(3) Fill silver paste in the first electrode tank, and dry at 70° C. for 3.5 minutes to form the first electrode in the first electrode tank.
(4)在部分第一电极上丝网印刷银浆,经70℃干燥3.5分钟,得到电连接件。(4) Screen-print silver paste on part of the first electrodes, and dry at 70° C. for 3.5 minutes to obtain electrical connectors.
(5)将软磁铁氧体粉体于130℃干燥9小时,再将干燥后的软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂混合制备成铁氧体浆料,其中,醋酸正丙酯与软磁铁氧体粉体的质量比为80:100,异丁醇与软磁铁氧体粉体的质量比为18:100,增塑剂为型号为DOP的邻苯二甲酸二辛酯,增塑剂与软磁铁氧体粉体的质量比为2:100,粘结剂为型号为B44的聚甲基丙烯酸甲酯树脂,粘结剂与软磁铁氧体粉体的质量比为20:100,分散剂为型号为X-100的聚乙二醇辛基苯基醚,分散剂与软磁铁氧体粉体的质量比为1:100。接着,在第一铁氧体坯体层上涂覆铁氧体浆料,并使铁氧体浆料遮蔽第一铁氧体坯体层和第一电极,且使电连接件露出,经75℃干燥3.5分钟,形成介质膜坯体层,电连接件穿设于介质膜坯体层,第一铁氧体坯体层、第一电极、电连接件及介质膜坯体层共同组成电感单元。介质膜坯体层的厚度为40微米。(5) Dry the soft ferrite powder at 130°C for 9 hours, then mix the dried soft ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant to prepare Become ferrite slurry, wherein, the mass ratio of n-propyl acetate and soft ferrite powder is 80:100, the mass ratio of isobutanol and soft ferrite powder is 18:100, plasticizer is The model is dioctyl phthalate of DOP, the mass ratio of plasticizer and soft magnetic ferrite powder is 2:100, and binder is the polymethyl methacrylate resin of model B44, binder and The mass ratio of the soft ferrite powder is 20:100, the dispersant is polyethylene glycol octyl phenyl ether of model X-100, and the mass ratio of the dispersant to the soft ferrite powder is 1:100. Next, coating the ferrite slurry on the first ferrite green body layer, and making the ferrite slurry cover the first ferrite green body layer and the first electrode, and exposing the electrical connector, after 75 Dry at ℃ for 3.5 minutes to form a dielectric film green body layer. The electrical connector is pierced through the dielectric film green body layer. The first ferrite green body layer, the first electrode, the electrical connector and the dielectric film green body layer together form an inductor unit . The thickness of the dielectric film green body layer is 40 microns.
(6)在介质膜坯体层上丝网印刷可塑性铁氧体浆料,经60℃干燥3.5分钟,形成厚度为50微米、具有第二电极槽的第二铁氧体坯体层。(6) Screen-print the plastic ferrite paste on the dielectric film base layer, and dry it at 60° C. for 3.5 minutes to form a second ferrite base layer with a thickness of 50 μm and a second electrode groove.
(7)在第二电极槽内填充银浆,经70℃干燥3.5分钟,形成第二电极,且第二电极与电连接件电连接。(7) Fill silver paste in the second electrode tank, and dry at 70° C. for 3.5 minutes to form the second electrode, and the second electrode is electrically connected to the electrical connector.
(8)在第二铁氧体坯体层上层叠第二铁氧体基板坯体,且第二铁氧体基板坯体遮蔽第二铁氧体坯体层和第二电极,得到半成品。(8) A second ferrite substrate blank is stacked on the second ferrite blank layer, and the second ferrite substrate blank covers the second ferrite blank layer and the second electrode to obtain a semi-finished product.
(9)将半成品从室温升温2小时至230℃,再升温2小时到280℃,继续升温6小时到880℃,并在880℃保温5小时后,自然冷却,再经涂银、烧银、端头处理、分选编带等工序制作成片式电感器。(9) Heat the semi-finished product from room temperature to 230°C for 2 hours, then heat up to 280°C for 2 hours, continue to heat up for 6 hours to 880°C, and keep it at 880°C for 5 hours, then cool it naturally, and then apply silver, burn silver, End processing, sorting and braiding processes are used to make chip inductors.
采用HP4338B毫欧表测试本实施例的片式电感器的直流电阻;根据GJB1864A-2011测试本实施例的片式电感器的额定电流。其中,本实施例的片式电感器的直流电阻和额定电流见表1。A HP4338B milliohm meter is used to test the DC resistance of the chip inductor of this embodiment; the rated current of the chip inductor of this embodiment is tested according to GJB1864A-2011. Wherein, the DC resistance and rated current of the chip inductor in this embodiment are shown in Table 1.
实施例2Example 2
本实施例的片式电感器的制备步骤如下:The preparation steps of the chip inductor of this embodiment are as follows:
(1)第一铁氧体基板坯体和第二铁氧体基板坯体的制备:将软磁铁氧体粉体于150℃干燥6小时,再将干燥后的软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂混合制备成软磁铁氧体浆料,其中,醋酸正丙酯与软磁铁氧体粉体的质量比为75:100,异丁醇与软磁铁氧体粉体的质量比为20:100,增塑剂为型号为DOP的邻苯二甲酸二辛酯,增塑剂与软磁铁氧体粉体的质量比为2.5:100,粘结剂为型号为B44的聚甲基丙烯酸甲酯树脂,粘结剂与软磁铁氧体粉体的质量比为25:100,分散剂为型号为X-100的聚乙二醇辛基苯基醚,分散剂与软磁铁氧体粉体的质量比为1.5:100。再将软磁铁氧体浆料流延成型后,经75℃干燥3.5分钟,分别形成第一铁氧体基板坯体和第二铁氧体基板坯体。第一铁氧体基板坯体的厚度在200微米,第二铁氧体基板坯体的厚度为200微米。(1) Preparation of the first ferrite substrate blank and the second ferrite substrate blank: dry the soft ferrite powder at 150°C for 6 hours, then dry the dried soft ferrite powder, acetic acid n-propyl ester, isobutanol, plasticizer, binder and dispersant are mixed to prepare soft ferrite slurry, wherein the mass ratio of n-propyl acetate to soft ferrite powder is 75:100, iso The mass ratio of butanol to soft ferrite powder is 20:100, the plasticizer is dioctyl phthalate whose model is DOP, and the mass ratio of plasticizer to soft ferrite powder is 2.5:100 , the binder is polymethyl methacrylate resin model B44, the mass ratio of binder to soft ferrite powder is 25:100, and the dispersant is polyethylene glycol octyl resin model X-100 The mass ratio of phenyl ether, dispersant and soft ferrite powder is 1.5:100. The soft magnetic ferrite slurry was tape-casted and dried at 75°C for 3.5 minutes to form a first ferrite substrate blank and a second ferrite substrate blank respectively. The thickness of the first ferrite substrate blank is 200 microns, and the thickness of the second ferrite substrate blank is 200 microns.
(2)第一铁氧体坯体层的制备:在第一铁氧体基板坯体上丝网印刷可塑性铁氧体浆料,经60℃干燥3.5分钟,形成厚度为40微米、具有第一电极槽的第一铁氧体坯体层。(2) Preparation of the first ferrite green body layer: screen-print plastic ferrite paste on the first ferrite substrate green body, and dry at 60°C for 3.5 minutes to form a layer with a thickness of 40 microns and the first The first ferrite green body layer of the electrode tank.
(3)在第一电极槽内填充银浆,经70℃干燥3.5分钟,在第一电极槽内形成第一电极。(3) Fill silver paste in the first electrode tank, and dry at 70° C. for 3.5 minutes to form the first electrode in the first electrode tank.
(4)在部分第一电极上丝网印刷银浆,经70℃干燥3.5分钟,得到电连接件。(4) Screen-print silver paste on part of the first electrodes, and dry at 70° C. for 3.5 minutes to obtain electrical connectors.
(5)将软磁铁氧体粉体于150℃干燥6小时,再将干燥后的软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂混合制备成铁氧体浆料,其中,醋酸正丙酯与软磁铁氧体粉体的质量比为75:100,异丁醇与软磁铁氧体粉体的质量比为20:100,增塑剂为型号为DOP的邻苯二甲酸二辛酯,增塑剂与软磁铁氧体粉体的质量比为2.5:100,粘结剂型号为B44的聚甲基丙烯酸甲酯树脂,粘结剂与软磁铁氧体粉体的质量比为25:100,分散剂为型号为X-100的聚乙二醇辛基苯基醚,分散剂与软磁铁氧体粉体的质量比为1.5:100。接着,在第一铁氧体坯体层上涂覆铁氧体浆料,并使铁氧体浆料遮蔽第一铁氧体坯体层和第一电极,且使电连接件露出,经75℃干燥3.5分钟,形成介质膜坯体层,电连接件穿设于介质膜坯体层,第一铁氧体坯体层、第一电极、电连接件及介质膜坯体层共同组成电感单元。介质膜坯体层的厚度为30微米。(5) Dry the soft ferrite powder at 150°C for 6 hours, then mix the dried soft ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant to prepare Become ferrite slurry, wherein, the mass ratio of n-propyl acetate and soft ferrite powder is 75:100, the mass ratio of isobutanol and soft ferrite powder is 20:100, plasticizer is The model is DOP dioctyl phthalate, the mass ratio of plasticizer to soft magnetic ferrite powder is 2.5:100, the binder model is B44 polymethyl methacrylate resin, the binder and soft ferrite powder The mass ratio of the magnetic ferrite powder is 25:100, the dispersant is polyethylene glycol octyl phenyl ether of model X-100, and the mass ratio of the dispersant to the soft magnetic ferrite powder is 1.5:100. Next, coating the ferrite slurry on the first ferrite green body layer, and making the ferrite slurry cover the first ferrite green body layer and the first electrode, and exposing the electrical connector, after 75 Dry at ℃ for 3.5 minutes to form a dielectric film green body layer. The electrical connector is pierced through the dielectric film green body layer. The first ferrite green body layer, the first electrode, the electrical connector and the dielectric film green body layer together form an inductor unit . The thickness of the dielectric film green body layer is 30 microns.
(6)在介质膜坯体层上丝网印刷可塑性铁氧体浆料,经60℃干燥3.5分钟,形成厚度为40微米、具有第二电极槽的第二铁氧体坯体层。(6) Screen-print plastic ferrite paste on the dielectric film green body layer, and dry at 60°C for 3.5 minutes to form a second ferrite green body layer with a thickness of 40 microns and a second electrode groove.
(7)在第二电极槽内填充银浆,经70℃干燥3.5分钟,形成第二电极,且第二电极与电连接件电连接。(7) Fill silver paste in the second electrode tank, and dry at 70° C. for 3.5 minutes to form the second electrode, and the second electrode is electrically connected to the electrical connector.
(8)在第二铁氧体坯体层上层叠第二铁氧体基板坯体,且第二铁氧体基板坯体遮蔽第二铁氧体坯体层和第二电极,得到半成品。(8) A second ferrite substrate blank is stacked on the second ferrite blank layer, and the second ferrite substrate blank covers the second ferrite blank layer and the second electrode to obtain a semi-finished product.
(9)将半成品从室温升温2小时至230℃,再升温2小时到280℃,继续升温6小时到880℃,并在880℃保温6小时后,自然冷却,再经涂银、烧银、端头处理、分选编带等工序制作成片式电感器。(9) Heat the semi-finished product from room temperature to 230°C for 2 hours, then raise the temperature to 280°C for 2 hours, continue to heat up for 6 hours to 880°C, and keep it at 880°C for 6 hours, then cool it naturally, and then apply silver, burn silver, End processing, sorting and braiding processes are used to make chip inductors.
采用实施例1相同的测试方法,得到本实施例的片式电感器的直流电阻和额定电流见表1。Using the same test method as in Example 1, the DC resistance and rated current of the chip inductor in this example are obtained as shown in Table 1.
实施例3Example 3
本实施例的片式电感器的制备步骤如下:The preparation steps of the chip inductor of this embodiment are as follows:
(1)第一铁氧体基板坯体和第二铁氧体基板坯体的制备:将软磁铁氧体粉体于100℃干燥12小时,再将干燥后的软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂混合制备成软磁铁氧体浆料,其中,醋酸正丙酯与软磁铁氧体粉体的质量比为85:100,异丁醇与软磁铁氧体粉体的质量比为15:100,增塑剂为型号为DOP的邻苯二甲酸二辛酯,增塑剂与软磁铁氧体粉体的质量比为1.5:100,粘结剂为型号为B44和A21的聚甲基丙烯酸甲酯树脂的混合物,粘结剂与软磁铁氧体粉体的质量比为1:100,分散剂为型号为X-100的聚乙二醇辛基苯基醚,分散剂与软磁铁氧体粉体的质量比为1:100。再将软磁铁氧体浆料经流延成型后,经75℃干燥3.5分钟,分别形成第一铁氧体基板坯体和第二铁氧体基板坯体。第一铁氧体基板坯体的厚度在300微米,第二铁氧体基板坯体的厚度为300微米。(1) Preparation of the first ferrite substrate blank and the second ferrite substrate blank: dry the soft ferrite powder at 100°C for 12 hours, then dry the dried soft ferrite powder, acetic acid N-propyl ester, isobutanol, plasticizer, binder and dispersant are mixed to prepare soft ferrite slurry, wherein the mass ratio of n-propyl acetate to soft ferrite powder is 85:100, iso The mass ratio of butanol to the soft ferrite powder is 15:100, the plasticizer is dioctyl phthalate whose model is DOP, and the mass ratio of the plasticizer to the soft ferrite powder is 1.5:100 , the binder is a mixture of polymethyl methacrylate resins of type B44 and A21, the mass ratio of binder to soft ferrite powder is 1:100, and the dispersant is polyethylene oxide of type X-100 Glycol octyl phenyl ether, the mass ratio of dispersant to soft ferrite powder is 1:100. The soft magnetic ferrite slurry was tape-casted and then dried at 75° C. for 3.5 minutes to form a first ferrite substrate blank and a second ferrite substrate blank respectively. The thickness of the first ferrite substrate blank is 300 microns, and the thickness of the second ferrite substrate blank is 300 microns.
(2)第一铁氧体坯体层的制备:在第一铁氧体基板坯体上丝网印刷可塑性铁氧体浆料,经60℃干燥3.5分钟,形成厚度为60微米、具有第一电极槽的第一铁氧体坯体层。(2) Preparation of the first ferrite green body layer: screen-print the plastic ferrite paste on the first ferrite substrate green body, and dry at 60°C for 3.5 minutes to form a layer with a thickness of 60 microns and the first The first ferrite green body layer of the electrode tank.
(3)在第一电极槽内填充银浆,经70℃干燥3.5分钟,在第一电极槽内形成第一电极。(3) Fill silver paste in the first electrode tank, and dry at 70° C. for 3.5 minutes to form the first electrode in the first electrode tank.
(4)在部分第一电极上丝网印刷银浆,经70℃干燥3.5分钟,得到电连接件。(4) Screen-print silver paste on part of the first electrodes, and dry at 70° C. for 3.5 minutes to obtain electrical connectors.
(5)将软磁铁氧体粉体于100℃干燥12小时,再将干燥后的软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂混合制备成铁氧体浆料,其中,醋酸正丙酯与软磁铁氧体粉体的质量比为85:100,异丁醇与软磁铁氧体粉体的质量比为15:100,增塑剂为型号为DOP的邻苯二甲酸二辛酯,增塑剂与软磁铁氧体粉体的质量比为1.5:100,粘结剂为型号为B44和A21的聚甲基丙烯酸甲酯树脂的混合物,粘结剂与软磁铁氧体粉体的质量比为1:100,分散剂为型号为X-100的聚乙二醇辛基苯基醚,分散剂与软磁铁氧体粉体的质量比为1:100。接着,在第一铁氧体坯体层上涂覆铁氧体浆料,并使铁氧体浆料遮蔽第一铁氧体坯体层和第一电极,且使电连接件露出,经75℃干燥3.5分钟,形成介质膜坯体层,电连接件穿设于介质膜坯体层,第一铁氧体坯体层、第一电极、电连接件及介质膜坯体层共同组成电感单元。介质膜坯体层的厚度为50微米。(5) Dry the soft ferrite powder at 100°C for 12 hours, then mix the dried soft ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant to prepare Become ferrite slurry, wherein, the mass ratio of n-propyl acetate and soft ferrite powder is 85:100, the mass ratio of isobutanol and soft ferrite powder is 15:100, plasticizer is The model is DOP dioctyl phthalate, the mass ratio of plasticizer to soft magnetic ferrite powder is 1.5:100, and the binder is a mixture of polymethyl methacrylate resins whose models are B44 and A21. The mass ratio of the binder to the soft ferrite powder is 1:100, the dispersant is polyethylene glycol octyl phenyl ether whose model is X-100, and the mass ratio of the dispersant to the soft ferrite powder is 1:100. Next, coating the ferrite slurry on the first ferrite green body layer, and making the ferrite slurry cover the first ferrite green body layer and the first electrode, and exposing the electrical connector, after 75 Dry at ℃ for 3.5 minutes to form a dielectric film green body layer. The electrical connector is pierced through the dielectric film green body layer. The first ferrite green body layer, the first electrode, the electrical connector and the dielectric film green body layer together form an inductor unit . The thickness of the dielectric film green body layer is 50 microns.
(6)在介质膜坯体层上丝网印刷可塑性铁氧体浆料,经60℃干燥3.5分钟,形成厚度为60微米、具有第二电极槽的第二铁氧体坯体层。(6) Screen-print plastic ferrite paste on the dielectric film green body layer, and dry at 60°C for 3.5 minutes to form a second ferrite green body layer with a thickness of 60 microns and a second electrode groove.
(7)在第二电极槽内填充银浆,经70℃干燥3.5分钟,形成第二电极,且第二电极与电连接件电连接。(7) Fill silver paste in the second electrode tank, and dry at 70° C. for 3.5 minutes to form the second electrode, and the second electrode is electrically connected to the electrical connector.
(8)在第二铁氧体坯体层上层叠第二铁氧体基板坯体,且第二铁氧体基板坯体遮蔽第二铁氧体坯体层和第二电极,得到半成品。(8) A second ferrite substrate blank is stacked on the second ferrite blank layer, and the second ferrite substrate blank covers the second ferrite blank layer and the second electrode to obtain a semi-finished product.
(9)将半成品从室温升温2小时至230℃,再升温2小时到280℃,继续升温6小时到880℃,并在880℃保温4小时后,自然冷却,再经涂银、烧银、端头处理、分选编带等工序制作成片式电感器。(9) Heat the semi-finished product from room temperature to 230°C for 2 hours, then raise the temperature to 280°C for 2 hours, continue to heat up to 880°C for 6 hours, and keep it at 880°C for 4 hours, then cool it naturally, and then apply silver, burn silver, End processing, sorting and braiding processes are used to make chip inductors.
采用实施例1相同的测试方法,得到本实施例的片式电感器的直流电阻和额定电流见表1。Using the same test method as in Example 1, the DC resistance and rated current of the chip inductor in this example are obtained as shown in Table 1.
实施例4Example 4
本实施例的片式电感器的制备步骤如下:The preparation steps of the chip inductor of this embodiment are as follows:
(1)第一铁氧体基板坯体和第二铁氧体基板坯体的制备:将软磁铁氧体粉体于130℃干燥9小时,再将干燥后的软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂混合制备成软磁铁氧体浆料,其中,醋酸正丙酯与软磁铁氧体粉体的质量比为80:100,异丁醇与软磁铁氧体粉体的质量比为15:100,增塑剂为型号为DOP的邻苯二甲酸二辛酯,增塑剂与软磁铁氧体粉体的质量比为2:100,粘结剂为型号为B44和A21的聚甲基丙烯酸甲酯树脂的混合物,粘结剂与软磁铁氧体粉体的质量比为1.5:100,分散剂为型号为X-100的聚乙二醇辛基苯基醚,分散剂与软磁铁氧体粉体的质量比为1.2:100。再将软磁铁氧体浆料经流延成型后,经75℃干燥3.5分钟,分别形成第一铁氧体基板坯体和第二铁氧体基板坯体。第一铁氧体基板坯体的厚度在100微米,第二铁氧体基板坯体的厚度为100微米。(1) Preparation of the first ferrite substrate blank and the second ferrite substrate blank: dry the soft ferrite powder at 130°C for 9 hours, then dry the dried soft ferrite powder, acetic acid n-propyl ester, isobutanol, plasticizer, binder and dispersant are mixed to prepare soft ferrite slurry, wherein the mass ratio of n-propyl acetate to soft ferrite powder is 80:100, iso The mass ratio of butanol to the soft ferrite powder is 15:100, the plasticizer is dioctyl phthalate whose model is DOP, and the mass ratio of the plasticizer to the soft ferrite powder is 2:100 , the binder is a mixture of polymethyl methacrylate resins of type B44 and A21, the mass ratio of binder to soft ferrite powder is 1.5:100, and the dispersant is polyethylene oxide of type X-100 Glycol octyl phenyl ether, the mass ratio of dispersant to soft ferrite powder is 1.2:100. The soft magnetic ferrite slurry was tape-casted and then dried at 75° C. for 3.5 minutes to form a first ferrite substrate blank and a second ferrite substrate blank respectively. The thickness of the first ferrite substrate blank is 100 microns, and the thickness of the second ferrite substrate blank is 100 microns.
(2)第一铁氧体坯体层的制备:在第一铁氧体基板坯体上丝网印刷可塑性铁氧体浆料,经60℃干燥3.5分钟,形成厚度为50微米、具有第一电极槽的第一铁氧体坯体层。(2) Preparation of the first ferrite green body layer: screen-print plastic ferrite paste on the first ferrite substrate green body, and dry at 60°C for 3.5 minutes to form a layer with a thickness of 50 microns and the first The first ferrite green body layer of the electrode tank.
(3)在第一电极槽内填充银浆,经70℃干燥3.5分钟,在第一电极槽内形成第一电极。(3) Fill silver paste in the first electrode tank, and dry at 70° C. for 3.5 minutes to form the first electrode in the first electrode tank.
(4)在部分第一电极上丝网印刷银浆,经70℃干燥3.5分钟,得到电连接件。(4) Screen-print silver paste on part of the first electrodes, and dry at 70° C. for 3.5 minutes to obtain electrical connectors.
(5)将软磁铁氧体粉体于130℃干燥9小时,再将干燥后的软磁铁氧体粉体、醋酸正丙酯、异丁醇、增塑剂、粘结剂和分散剂混合制备成铁氧体浆料,其中,醋酸正丙酯与软磁铁氧体粉体的质量比为80:100,异丁醇与软磁铁氧体粉体的质量比为15:100,增塑剂为型号为DOP的邻苯二甲酸二辛酯,增塑剂与软磁铁氧体粉体的质量比为2:100,粘结剂为型号为B44和A21的聚甲基丙烯酸甲酯树脂的混合物,粘结剂与软磁铁氧体粉体的质量比为1.5:100,分散剂为型号为X-100的聚乙二醇辛基苯基醚,分散剂与软磁铁氧体粉体的质量比为1.2:100。接着,在第一铁氧体坯体层上涂覆铁氧体浆料,并使铁氧体浆料遮蔽第一铁氧体坯体层和第一电极,且使电连接件露出,经75℃干燥3.5分钟,形成介质膜坯体层,电连接件穿设于介质膜坯体层,第一铁氧体坯体层、第一电极、电连接件及介质膜坯体层共同组成电感单元。介质膜坯体层的厚度为40微米。(5) Dry the soft ferrite powder at 130°C for 9 hours, then mix the dried soft ferrite powder, n-propyl acetate, isobutanol, plasticizer, binder and dispersant to prepare Become ferrite slurry, wherein, the mass ratio of n-propyl acetate and soft ferrite powder is 80:100, the mass ratio of isobutanol and soft ferrite powder is 15:100, plasticizer is The model is DOP dioctyl phthalate, the mass ratio of plasticizer to soft magnetic ferrite powder is 2:100, and the binder is a mixture of polymethyl methacrylate resins whose models are B44 and A21. The mass ratio of the binder to the soft ferrite powder is 1.5:100, the dispersant is polyethylene glycol octyl phenyl ether whose model is X-100, and the mass ratio of the dispersant to the soft ferrite powder is 1.2:100. Next, coating the ferrite slurry on the first ferrite green body layer, and making the ferrite slurry cover the first ferrite green body layer and the first electrode, and exposing the electrical connector, after 75 Dry at ℃ for 3.5 minutes to form a dielectric film green body layer. The electrical connector is pierced through the dielectric film green body layer. The first ferrite green body layer, the first electrode, the electrical connector and the dielectric film green body layer together form an inductor unit . The thickness of the dielectric film green body layer is 40 microns.
(6)在介质膜坯体层上丝网印刷可塑性铁氧体浆料,经60℃干燥3.5分钟,形成厚度为50微米、具有第二电极槽的第一铁氧体坯体层,并重复步骤(3)~(5),第一个电感单元的介质膜坯体层上形成第二个电感单元。(6) Screen-print the plastic ferrite slurry on the dielectric film green body layer, dry at 60°C for 3.5 minutes to form a first ferrite green body layer with a thickness of 50 microns and a second electrode groove, and repeat In steps (3)-(5), the second inductor unit is formed on the dielectric film base layer of the first inductor unit.
(7)在第二个电感单元的介质膜坯体层上丝网印刷可塑性铁氧体浆料,经60℃干燥3.5分钟,形成厚度为40~60微米、具有第二电极槽的第二铁氧体坯体层。(7) Screen-print plastic ferrite paste on the dielectric film base layer of the second inductance unit, and dry it at 60°C for 3.5 minutes to form a second ferrite with a thickness of 40-60 microns and a second electrode groove. Oxygen body layer.
(8)在第二电极槽内填充银浆,经70℃干燥3.5分钟,形成第二电极,且第二电极与电连接件电连接。(8) Fill the second electrode tank with silver paste, and dry at 70° C. for 3.5 minutes to form the second electrode, and the second electrode is electrically connected to the electrical connector.
(9)在第二铁氧体坯体层上层叠第二铁氧体基板坯体,且第二铁氧体基板坯体遮蔽第二铁氧体坯体层和第二电极,得到半成品。(9) Laminating the second ferrite substrate green body on the second ferrite green body layer, and the second ferrite substrate green body covers the second ferrite green body layer and the second electrode to obtain a semi-finished product.
(10)将半成品从室温升温2小时至230℃,再升温2小时到280℃,继续升温6小时到880℃,并在880℃保温5小时后,自然冷却,再经涂银、烧银、端头处理、分选编带等工序制作成片式电感器。(10) Heat the semi-finished product from room temperature to 230°C for 2 hours, then raise the temperature to 280°C for 2 hours, continue to heat up to 880°C for 6 hours, and keep it at 880°C for 5 hours, cool it naturally, and then apply silver, burn silver, End processing, sorting and braiding processes are used to make chip inductors.
采用实施例1相同的测试方法,得到本实施例的片式电感器的直流电阻和额定电流见表1。Using the same test method as in Example 1, the DC resistance and rated current of the chip inductor in this example are obtained as shown in Table 1.
对比例1Comparative example 1
对比例1的片式电感器的制备步骤如下:The preparation steps of the chip inductor of Comparative Example 1 are as follows:
采用普通铁氧体浆料(如昌平提供的SB材磁导率80)流延制备厚度100微米厚度的第一铁氧体基板和厚度为100微米的第二铁氧体基板,使用银浆在第一铁氧体基板上丝网印刷第一电极,在部分第一电极上丝网印刷电连接件;流延制备介质膜;在第二铁氧体基板上丝网印刷第二电极,在部分第二电极上丝网印刷电连接件,将想成有第一电极的第一铁氧体基板、介质膜和形成有第二电极的第二铁氧体基板层叠,得到半成品,将半成品从室温升温2小时至230℃,再升温2小时到280℃,继续升温6小时到880℃,并在880℃保温5小时后,自然冷却,再经涂银、烧银、端头处理、分选编带(均为现有成熟工艺)等工序制作成片式电感器。The first ferrite substrate with a thickness of 100 microns and the second ferrite substrate with a thickness of 100 microns are prepared by tape casting with ordinary ferrite slurry (such as the SB material magnetic permeability 80 provided by Changping), and the silver paste is used in screen-print the first electrode on the first ferrite substrate, and screen-print electrical connectors on part of the first electrode; tape-cast to prepare a dielectric film; screen-print the second electrode on the second ferrite substrate, and partially Screen printing electrical connectors on the second electrode, stacking the first ferrite substrate with the first electrode, the dielectric film and the second ferrite substrate with the second electrode to obtain a semi-finished product, the semi-finished product from room temperature Raise the temperature for 2 hours to 230°C, then raise the temperature for 2 hours to 280°C, continue to heat up for 6 hours to 880°C, and keep it at 880°C for 5 hours, then cool naturally, and then go through silver coating, silver burning, end treatment, sorting and braiding (both existing mature technology) and other processes are made into chip inductors.
采用实施例1相同的测试方法,得到对比例1的片式电感器的直流电阻和额定电流见表1。Using the same test method as in Example 1, the DC resistance and rated current of the chip inductor in Comparative Example 1 are obtained as shown in Table 1.
表1表示的是实施例1~4和对比例1的片式电感器的直流电阻和额定电流。Table 1 shows the DC resistance and rated current of the chip inductors of Examples 1-4 and Comparative Example 1.
表1Table 1
从表1中可以看出,实施例1~4的片式电感器的直流电阻最多为29mΩ,额定电流分别至少为200mA,而对比例1的片式电感器的直流电阻高达200mΩ,额定电流仅为50mA。显然,实施例1~4的片式电感器具有较低的直流电阻和较大的额定电流,提高了片式电感器的可靠性。It can be seen from Table 1 that the DC resistance of the chip inductors in Examples 1 to 4 is at most 29mΩ, and the rated current is at least 200mA, respectively, while the DC resistance of the chip inductor in Comparative Example 1 is as high as 200mΩ, and the rated current is only 200mA. 50mA. Apparently, the chip inductors in Examples 1-4 have lower DC resistance and higher rated current, which improves the reliability of the chip inductors.
以上所述实施例的各技术特征可以进行任意的组合,为使描述简洁,未对上述实施例中的各个技术特征所有可能的组合都进行描述,然而,只要这些技术特征的组合不存在矛盾,都应当认为是本说明书记载的范围。The various technical features of the above-mentioned embodiments can be combined arbitrarily. To make the description concise, all possible combinations of the various technical features in the above-mentioned embodiments are not described. However, as long as there is no contradiction in the combination of these technical features, should be considered as within the scope of this specification.
以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。The above-mentioned embodiments only express several implementation modes of the present invention, and the descriptions thereof are relatively specific and detailed, but should not be construed as limiting the patent scope of the invention. It should be noted that those skilled in the art can make several modifications and improvements without departing from the concept of the present invention, and these all belong to the protection scope of the present invention. Therefore, the protection scope of the patent for the present invention should be based on the appended claims.
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| JP2010114302A (en) * | 2008-11-07 | 2010-05-20 | Sony Corp | Inductor module and semiconductor device |
| CN101521087B (en) * | 2008-11-17 | 2012-12-05 | 深圳振华富电子有限公司 | Inductor and manufacturing method thereof |
| KR101214749B1 (en) * | 2011-04-25 | 2012-12-21 | 삼성전기주식회사 | Multi-layered power inductor |
| CN104966601A (en) * | 2014-03-26 | 2015-10-07 | 莱尔德电子材料(深圳)有限公司 | Nonmagnetic ferrite dielectric for common mode choke |
| CN204229966U (en) * | 2014-11-04 | 2015-03-25 | 深圳振华富电子有限公司 | Chip inductor |
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2016
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