CN105928934A - Anti-lightening power distribution cabinet based on gasochromic gas sensor - Google Patents
Anti-lightening power distribution cabinet based on gasochromic gas sensor Download PDFInfo
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- CN105928934A CN105928934A CN201610256646.5A CN201610256646A CN105928934A CN 105928934 A CN105928934 A CN 105928934A CN 201610256646 A CN201610256646 A CN 201610256646A CN 105928934 A CN105928934 A CN 105928934A
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- gas
- discoloration
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- 238000009826 distribution Methods 0.000 title claims abstract description 38
- 239000007789 gas Substances 0.000 claims abstract description 154
- 238000010438 heat treatment Methods 0.000 claims abstract description 39
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910001930 tungsten oxide Inorganic materials 0.000 claims abstract description 32
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 19
- 239000001257 hydrogen Substances 0.000 claims abstract description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000001514 detection method Methods 0.000 claims abstract description 8
- 230000000007 visual effect Effects 0.000 claims abstract description 8
- 238000002845 discoloration Methods 0.000 claims description 107
- 239000010408 film Substances 0.000 claims description 90
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 80
- 239000000758 substrate Substances 0.000 claims description 77
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 63
- 239000008367 deionised water Substances 0.000 claims description 37
- 229910021641 deionized water Inorganic materials 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 30
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 28
- 239000000243 solution Substances 0.000 claims description 28
- 239000010409 thin film Substances 0.000 claims description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 26
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 238000004528 spin coating Methods 0.000 claims description 20
- 239000002070 nanowire Substances 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 16
- 238000004544 sputter deposition Methods 0.000 claims description 15
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 14
- 238000003916 acid precipitation Methods 0.000 claims description 14
- 239000000084 colloidal system Substances 0.000 claims description 14
- 239000003292 glue Substances 0.000 claims description 14
- 239000010937 tungsten Substances 0.000 claims description 14
- 229910052721 tungsten Inorganic materials 0.000 claims description 14
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 13
- 230000000694 effects Effects 0.000 claims description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 8
- 238000011161 development Methods 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 229910000831 Steel Inorganic materials 0.000 claims description 7
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 7
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000001548 drop coating Methods 0.000 claims description 7
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 238000001259 photo etching Methods 0.000 claims description 7
- 229920002120 photoresistant polymer Polymers 0.000 claims description 7
- 238000007747 plating Methods 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 239000010959 steel Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000004148 unit process Methods 0.000 claims description 7
- 238000001291 vacuum drying Methods 0.000 claims description 7
- 239000004575 stone Substances 0.000 claims 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000002086 nanomaterial Substances 0.000 abstract 1
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten(VI) oxide Inorganic materials O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 106
- 238000012360 testing method Methods 0.000 description 35
- 230000004044 response Effects 0.000 description 30
- 238000002834 transmittance Methods 0.000 description 26
- 230000008859 change Effects 0.000 description 21
- 230000035945 sensitivity Effects 0.000 description 19
- 238000004140 cleaning Methods 0.000 description 12
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 230000001276 controlling effect Effects 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 7
- 239000003471 mutagenic agent Substances 0.000 description 7
- 231100000707 mutagenic chemical Toxicity 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 238000001755 magnetron sputter deposition Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000010422 painting Methods 0.000 description 6
- 230000001105 regulatory effect Effects 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000003708 ampul Substances 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 238000007689 inspection Methods 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- 238000012800 visualization Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 231100001261 hazardous Toxicity 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- GTZCNONABJSHNM-UHFFFAOYSA-N 5,10,15,20-tetraphenyl-21,23-dihydroporphyrin zinc Chemical class [Zn].c1cc2nc1c(-c1ccccc1)c1ccc([nH]1)c(-c1ccccc1)c1ccc(n1)c(-c1ccccc1)c1ccc([nH]1)c2-c1ccccc1 GTZCNONABJSHNM-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- -1 oxonium ion Chemical class 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000005036 potential barrier Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02B—BOARDS, SUBSTATIONS OR SWITCHING ARRANGEMENTS FOR THE SUPPLY OR DISTRIBUTION OF ELECTRIC POWER
- H02B1/00—Frameworks, boards, panels, desks, casings; Details of substations or switching arrangements
- H02B1/015—Boards, panels, desks; Parts thereof or accessories therefor
- H02B1/04—Mounting thereon of switches or of other devices in general, the switch or device having, or being without, casing
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02B—BOARDS, SUBSTATIONS OR SWITCHING ARRANGEMENTS FOR THE SUPPLY OR DISTRIBUTION OF ELECTRIC POWER
- H02B1/00—Frameworks, boards, panels, desks, casings; Details of substations or switching arrangements
- H02B1/26—Casings; Parts thereof or accessories therefor
- H02B1/30—Cabinet-type casings; Parts thereof or accessories therefor
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plasma & Fusion (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Abstract
The invention relates to an anti-lightening power distribution cabinet based on a gasochromic gas sensor. The gasochromic gas sensor is installed on the outer surface of the anti-lightening power distribution cabinet and comprises a sensitive unit, a heating unit and a data reading unit, wherein the heating unit and the data reading unit are connected with a tungsten oxide gas-sensitive film of the sensitive unit, the heating unit is used as a heating source for the tungsten oxide gas-sensitive film in operation, and the sensitive unit is of a double-layer structure with a hollow-structure central part. The anti-lightening power distribution cabinet is based on the gas-sensitive property and gasochromic property of a WO3 nano-material, can realize visual detection of leaked hydrogen and has the advantages of convenience in usage and easiness in operation.
Description
Technical field
The application relates to power distribution cabinet field, is specifically related to a kind of based on gas-discoloration gas sensor anti-
Thunder power distribution cabinet.
Background technology
Power distribution cabinet is the final stage device of a distribution system, is divided into dynamic power distribution cabinet and light distribution cabinet, is
The general designation of Motor Control.Power distribution cabinet uses relatively decentralized in duty ratio, the occasion that loop is more.
Lightning protection power distribution cabinet is the one of power distribution cabinet, in addition to having power distribution cabinet general property, has lightning protection concurrently
Effect.Owing to lightning protection power distribution cabinet application is relatively big, when working environment residing for it is that laboratory etc. is deposited
When having the hazardous gas environment such as hydrogen, the existence of hazardous gas can produce certain potential safety hazard to it.
Summary of the invention
For overcoming problem present in correlation technique, the application provides a kind of and passes based on gas-discoloration gas
The lightning protection power distribution cabinet of sensor.
First aspect according to the embodiment of the present application, it is provided that a kind of based on gas-discoloration gas sensor
Lightning protection power distribution cabinet, described lightning protection power distribution cabinet outer surface is provided with gas-discoloration gas sensor, described gas
Mutagens color gas sensor is based on WO3Gas sensitive and WO3Gas-discoloration material；Described gas mutagens
Color gas sensor includes sensing unit, heating unit and data-reading unit；Described heating unit and
Data-reading unit is connected with the tungsten oxide air-sensitive film of sensing unit；Described heating unit is as oxidation
The heating source during work of tungsten air-sensitive film；Data-reading unit processes the electrical conductivity of tungsten oxide air-sensitive film
Variable signal is to show the concentration value of object gas；Described sensing unit is the double-deck knot of hollow structure
Structure, forms double-deck A face structure and B face structure is staggered relatively, distance 500 μm, A face
The periphery of structure and the handing-over of B face structure uses colloid to seal；Described A face include quartz glass substrate,
Interdigital electrode layer and WO3Air-sensitive film layer, WO3Air-sensitive film layer is doping SnO2WO3Thin
Film, it is possible to achieve to NO2The detection of gas, described B face includes quartz glass substrate and WO3Gas
Mutagens chromatograph, WO3Gas-discoloration layer is WO3Nano wire film doping ZnTPP-2-NO2, utilize
Gas-discoloration principle can realize the Visual retrieval to hydrogen；It is additionally provided with 2 in the structure of described B face
The individual air-vent penetrated for object gas.In A face, described SnO2Granularity less than 40nm,
Described WO3Air-sensitive film layer thickness is 700nm；In B face, described WO3Nanowire length about 2
μm, diameter about 60nm.
Second aspect according to the embodiment of the present application, it is provided that a kind of based on gas-discoloration gas sensor
The preparation method of lightning protection power distribution cabinet, it is preferable that the sensing unit of described gas-discoloration gas sensor
Making comprises the following steps:
S1, preparation A face structure, including following enforcement step: (1) takes certain size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water ultrasonic cleaning 20min；(2)
Spin coating one layer photoetching glue in quartz glass substrate, thickness 1 μm, under interdigital electrode mask covers
Exposure 6s, cleans with deionized water after being then passed through development 50s, uses magnetically controlled sputter method plating one
Cr film thick for layer 300nm, as interdigital electrode layer, then removes photoresist；(3) by quartz glass
Glass substrate is put in magnetic control sputtering device, is evacuated to 5 × 10-4Below Pa, is passed through Ar and O2Mixing
Gas, regulates Ar:O2Ratio is 5:1, and operating pressure is 2.4Pa, is purity 99.96% at target
Metal W target magnetic control sputtering 28min, target is the metal tin target magnetron sputtering 2min of purity 98%,
Obtain the SnO that adulterates2WO3Thin film, i.e. WO3Air-sensitive film layer；
S2, preparation B face structure, including following enforcement step: (1) takes same size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water, NaOH aqueous solution, go from
Sub-water ultrasonic cleaning, the time is 20min；(2) take 20g sodium tungstate to be dissolved in 200ml water,
Add excess concentrated hydrochloric acid obtain active tungstic acid precipitation, is filtered, then with deionized water cleaning until
Can't detect chloride ion, then active tungstic acid precipitation is dissolved in hydrogen peroxide, prepares colloidal sol, spin coating
In quartz glass substrate, 350 DEG C process 1h and obtain Seed Layer, and thickness is 20nm；(3) tungsten is taken
Acid sodium powder 4.12g is dissolved in 60ml deionized water, and regulating its pH with 3M HCl solution is 2.0,
Be subsequently adding 2.1g (0.3M) ammonium sulfate as controlling agent, quartz glass substrate is lain in from
In sub-water, after stirring 1 hour, pour in rustless steel hydrothermal reaction kettle, be heated to 150 DEG C in an oven
Keep 10h, then take out quartz glass substrate and spend ionized water cleaning；(4) chloroform is selected
For solvent, take 3.8g ZnTPP-2-NO2It is configured to the solution of 5.0mg/ml, supersound process 20min,
Make solution uniform, by dripping glue mode by made solution drop coating at quartz glass substrate surface, set rotation
Painting speed is 3400rpm, and spin-coating time is 70s, finally by quartz glass substrate at vacuum drying oven
In be dried 12h at 60 DEG C, obtain the ZnTPP-2-NO that adulterates2WO3Nano wire film, i.e. WO3
Gas-discoloration layer；
S3, assembling: by staggered relatively to the A face completed, B face structure, distance 500 μm, A
The periphery of face structure and the handing-over of B face structure uses colloid to seal, and obtains described gas-discoloration gas sensing
The sensing unit of device.
The technical scheme that embodiments herein provides includes following beneficial effect:
1. configuration aspects, creative employing double membrane structure, the air-sensitive combining tungsten oxide material is special
Property and gas-discoloration characteristic, increase the range of application of device；
2. tungsten oxide air-sensitive film passes through magnetically controlled sputter method system based on Film-mode resistor sensor, thin film
Make, by controlling partial pressure of oxygen and doped stannum oxide in manufacturing process so that thin film is to NO2Selectivity
All it is greatly improved with sensitivity；
3. tungsten oxide gas chromism film is tungsten oxide nano doping tetraphenylporphyrin zinc derivative
(ZnTPP-2-NO2) material, this dopant material, as catalyst, substantially increases tungsten oxide nanometer
Line is to H2Reactivity, improve sensitivity, and achieve " smell-seeing " to hydrogen and measure.
Aspect and advantage that the application adds will part be given in the following description, and part will be from following
Description in become obvious, or recognized by the practice of the application.It should be appreciated that above
It is only exemplary and explanatory that general description and details hereinafter describe, and can not limit the application.
Accompanying drawing explanation
Accompanying drawing herein is merged in description and constitutes the part of this specification, it is shown that meet this
Inventive embodiment, and for explaining the principle of the present invention together with description.
Fig. 1 is the schematic diagram of sensing unit in the gas-discoloration gas sensor that the present invention uses.
Fig. 2 is the flow chart preparing the sensing unit in Fig. 1.
Wherein: 1-quartz glass substrate, 2-interdigital electrode layer, 3-WO3Air-sensitive film layer, 4-hollow
Structure, 5-WO3Gas-discoloration layer.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Below
Description when relating to accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents identical or phase
As key element.Embodiment described in following exemplary embodiment does not represent and present invention phase one
The all embodiments caused.On the contrary, they only with as appended claims describes in detail, this
The example of the consistent apparatus and method of some aspects of invention.
Following disclosure provides many different embodiments or example for realizing the difference of the application
Structure.In order to simplify disclosure herein, hereinafter parts and setting to specific examples are described.
Certainly, they are the most merely illustrative, and are not intended to limit the application.Additionally, the application is permissible
Repeat reference numerals and/or letter in different examples.This repetition is to simplify and clearly mesh
, itself it is more than the relation between various embodiment being discussed and/or arranging.Additionally, the application
The various specific technique provided and the example of material, but those of ordinary skill in the art can anticipate
Know the applicability to other techniques and/or the use of other materials.It addition, described below first is special
Levy Second Eigenvalue " on " structure can include what the first and second features were formed as directly contacting
Embodiment, it is also possible to include the embodiment that other feature is formed between the first and second features, this
Sample the first and second feature is not likely to be directly contact.
In the description of the present application, it should be noted that unless otherwise prescribed and limit, term " peace
Dress ", should be interpreted broadly " being connected ", " connection ", for example, it may be mechanical connection or electrically connect, also
Can be the connection of two element internals, can be to be joined directly together, it is also possible to indirect by intermediary
It is connected, for the ordinary skill in the art, above-mentioned term can be understood as the case may be
Concrete meaning.
Modern society, along with economic and industry development, mankind's consumption to various natural resourcess
Being continuously increased, owing to pursuing the shortcoming of economic goal and environmental consciousness, the pollution problem of environment is the tightest
Weight.Meanwhile, show gas aspect, in productive life discharge various inflammable, explosive, have
The leakage of gas in poisonous gas and environment, pollution are also that people's property safety is big with the one of personal safety
Threaten.Therefore, gas sensor technology is one of important topic of current research.Gas sensor is
A kind of can change and the device effectively monitored or device by perception surrounding target gas levels,
It is based on physical principle or chemical reaction etc., the type of gas sensor mainly has semiconductor gas
Dependent sensor, electrochemical gas sensor, catalytic combustion type gas sensor, optical profile type gas sensing
Device etc..WO3It is a kind of preferably controllable color change material, can realize visible ray and near-infrared radiation saturating
Cross continuously adjusting of rate.Amorphous WO from Deb reported first in 19693The electrochromism effect of thin film
Since Ying, find the performance such as its gas-discoloration, photochromic, thermochromism successively, meanwhile, as
Transition metal oxide, Tungstic anhydride. is to some gas, such as NO2、NO、NH3、H2、H2S etc.
All show sensitivity characteristic；Compared with electrochromic device, WO3Gas-discoloration device has system structure
Simply, the advantage such as relative inexpensiveness, therefore its gas-discoloration characteristic is combined with gas-sensitive property,
Great significance to gas sensing optics type senser element.
The operation principle of the gas sensor used in the application is: gas sensor is sensing technology
One important branch.Gas sensor can be divided into dissimilar according to structure and material etc., wherein,
The sensitive prime material that Metal Oxide Gas Sensors is used is broad stopband N-shaped metal-oxide half
Conductor, it all shows good sensitivity characteristic to multiple gases.
The sensitive mechanism of metal oxide semiconductor gas sensor is: sensitive material is made into as thin
Films etc. are beneficial to contact the structure of air, under heating state, when it is exposed in air, and sensitive material
The total surface of material is to adsorb a certain amount of oxonium ion, forms surface potential barrier and space charge layer, can make
The sheet electron concentration of sensitive material declines, and then electrical conductivity declines；When object gas is reproducibility gas
(such as CO, H during body2), this reducibility gas can adsorb on sensitive material surface, and with surface
Oxygen reacts, and makes sheet electron concentration increase, and electrical conductivity rises therewith；When object gas is oxidation
(such as NO during property gas2), the absorption on sensitive material surface of this oxidizing gas further increases
The adsorbance of oxygen so that the electrical conductivity of sensitive material declines further；I.e. the concentration of object gas with
The electrical conductivity of sensitive material has dependency, thus, by measure sensitive material electrical conductivity change thus
Measure the concentration of object gas.
After gas-discoloration refers to that material arrives some gas, because the reversible chemical reaction occurred makes
Material produces the colour developing effect that the light to wavelengths characteristic absorbs, and the absorption spectrum of material can change,
Macro manifestations is the change of material color.Specific to WO3After contact hydrogen, it can with hydrogen generation
Back reaction, can form tungsten bronze structure (HxWO4), owing to this structure is blue, show as WO3
The color of thin film can be blue by original transparent color, again because the change of thin film color can make it saturating
The light intensity crossed changes, i.e. the light transmittance of thin film changes, therefore can be by measuring thin film
The concentration of determination of light transmittance hydrogen.
The application is based on WO3The gas-discoloration character of material and air-sensitive character, will by double membrane structure
It combines；On the one hand, WO3Air-sensitive film can measure NO in the case of external power supply and heating2
Concentration, on the other hand, can not heat with not powered etc. have particular/special requirement in the environment of, WO3Air-sensitive
Thin-film material shows limitation, now can pass through WO3Gas chromism film is to H2Detect.
Embodiment 1:
There is provided a kind of lightning protection power distribution cabinet based on gas-discoloration gas sensor, outside described lightning protection power distribution cabinet
Surface is provided with gas-discoloration gas sensor, and described gas-discoloration gas sensor is based on WO3Gas
Quick material and WO3Gas-discoloration material；Described gas-discoloration gas sensor include sensing unit,
Heating unit and data-reading unit；The oxygen of described heating unit and data-reading unit and sensing unit
Change tungsten air-sensitive film to connect；Heating source when described heating unit works as tungsten oxide air-sensitive film；
Data-reading unit processes the conductivity variations signal of tungsten oxide air-sensitive film with display object gas
Concentration value.
Fig. 1 is the schematic diagram of sensing unit in the gas-discoloration gas sensor that the present invention uses.Reference
Fig. 1, this sensing unit is the double-decker of hollow structure, forms double-deck A face structure and B
Face structure is staggered relatively, distance 500 μm, and the periphery of A face structure and the handing-over of B face structure uses colloid
Seal；Described A face includes quartz glass substrate, interdigital electrode layer and WO3Air-sensitive film layer, WO3
Air-sensitive film layer is doping SnO2WO3Thin film, it is possible to achieve to NO2The detection of gas, described
B face includes quartz glass substrate and WO3Gas-discoloration layer, WO3Gas-discoloration layer is WO3Nanometer
Line film doping ZnTPP-2-NO2, utilize gas-discoloration principle can realize the inspection of the visualization to hydrogen
Survey；2 it are additionally provided with for air-vent that object gas penetrates in the structure of described B face.In A face,
Described SnO2Granularity less than 40nm, described WO3Air-sensitive film layer thickness is 700nm；B
In face, described WO3Nanowire length about 2 μm, diameter about 60nm；
Fig. 2 is according to the flow chart preparing sensing unit shown in an exemplary embodiment, such as Fig. 2 institute
Show, comprise the following steps:
S1, preparation A face structure, including following enforcement step: (1) takes certain size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water ultrasonic cleaning 20min；(2)
Spin coating one layer photoetching glue in quartz glass substrate, thickness 1 μm, under interdigital electrode mask covers
Exposure 6s, cleans with deionized water after being then passed through development 50s, uses magnetically controlled sputter method plating one
Cr film thick for layer 300nm, as interdigital electrode layer, then removes photoresist；(3) by quartz glass
Glass substrate is put in magnetic control sputtering device, is evacuated to 5 × 10-4Below Pa, is passed through Ar and O2Mixing
Gas, regulates Ar:O2Ratio is 5:1, and operating pressure is 2.4Pa, is purity 99.96% at target
Metal W target magnetic control sputtering 28min, target is the metal tin target magnetron sputtering 2min of purity 98%,
Obtain the SnO that adulterates2WO3Thin film, i.e. WO3Air-sensitive film layer；
S2, preparation B face structure, including following enforcement step: (1) takes same size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water, NaOH aqueous solution, go from
Sub-water ultrasonic cleaning, the time is 20min；(2) take 20g sodium tungstate to be dissolved in 200ml water,
Add excess concentrated hydrochloric acid obtain active tungstic acid precipitation, is filtered, then with deionized water cleaning until
Can't detect chloride ion, then active tungstic acid precipitation is dissolved in hydrogen peroxide, prepares colloidal sol, spin coating
In quartz glass substrate, 350 DEG C process 1h and obtain Seed Layer, and thickness is 20nm；(3) tungsten is taken
Acid sodium powder 4.12g is dissolved in 60ml deionized water, and regulating its pH with 3M HCl solution is 2.0,
Be subsequently adding 2.1g (0.3M) ammonium sulfate as controlling agent, quartz glass substrate is lain in from
In sub-water, after stirring 1 hour, pour in rustless steel hydrothermal reaction kettle, be heated to 150 DEG C in an oven
Keep 10h, then take out quartz glass substrate and spend ionized water cleaning；(4) chloroform is selected
For solvent, take 3.8g ZnTPP-2-NO2It is configured to the solution of 5.0mg/ml, supersound process 20min,
Make solution uniform, by dripping glue mode by made solution drop coating at quartz glass substrate surface, set rotation
Painting speed is 3400rpm, and spin-coating time is 70s, finally by quartz glass substrate at vacuum drying oven
In be dried 12h at 60 DEG C, obtain the ZnTPP-2-NO that adulterates2WO3Nano wire film, i.e. WO3
Gas-discoloration layer；
S3, assembling: by staggered relatively to the A face completed, B face structure, distance 500 μm, A
The periphery of face structure and the handing-over of B face structure uses colloid to seal, and obtains described gas-discoloration gas sensing
The sensing unit of device.
About the device in above-described embodiment, the concrete mode that wherein modules performs to operate exists
About the embodiment of the method has been described in detail, explanation will be not set forth in detail herein.
Data test:
In A face, air-sensitive test completes on Testing system of gas-sensor built, is put into by the device made
In quartz ampoule, heating unit heats makes the operating temperature of sensing unit be 120 DEG C, after stable, logical
Enter by air and finite concentration NO2The mixed gas of configuration, keeps 30min, is again passed through pure air,
Record WO3The resistance value of air-sensitive film layer, respectively R (NO2) and R (air), define air-sensitive
Sensitivity is: S=R (NO2)/R (air), response time is defined as being passed through resistance after test gas
Change to the time required for the 80% of maximum changes in resistance.Test finds, this tungsten oxide air-sensitive film
NO in 8ppm concentration2Gas medium sensitivity is 36；Best-case Response Time is 14s；Through 100
Secondary testing fatigue, electrical response value drops to original 86%.WO3Air-sensitive film shows well
Sensitivity, response time and repeatability.
In B face, use spectrophotometer to variable concentrations H2WO in atmosphere3Gas-discoloration layer is carried out
Light transmittance is tested, and defines T0For not leading to H2Time sample light transmittance, T is for being passed through finite concentration H2
Time sample light transmittance, relative light transmission:, be passed through H2When concentration is 5000ppm, the most thoroughly
Light rate with wavelength change, minimum 4%, be 59.7% to the maximum, and through about 10min, relatively
Light transmittance tends towards stability, it is seen that be passed through with tested gas, and tungsten oxide gas-discoloration layer light transmittance declines,
Showing as thin film color and transparent become blue from original, response time is short, shows good gas mutagens
Color performance.
Test finds, this lightning protection power distribution cabinet is provided with gas-discoloration gas sensor, utilizes gas-discoloration
Principle can realize the Visual retrieval to hydrogen, and response time is short, highly sensitive, variable color model
Enclose bigger, it is achieved that beyond thought effect, there is certain actual application value.
Embodiment 2:
There is provided a kind of lightning protection power distribution cabinet based on gas-discoloration gas sensor, outside described lightning protection power distribution cabinet
Surface is provided with gas-discoloration gas sensor, and described gas-discoloration gas sensor is based on WO3Gas
Quick material and WO3Gas-discoloration material；Described gas-discoloration gas sensor include sensing unit,
Heating unit and data-reading unit；The oxygen of described heating unit and data-reading unit and sensing unit
Change tungsten air-sensitive film to connect；Heating source when described heating unit works as tungsten oxide air-sensitive film；
Data-reading unit processes the conductivity variations signal of tungsten oxide air-sensitive film with display object gas
Concentration value.
Fig. 1 is the schematic diagram of sensing unit in the gas-discoloration gas sensor that the present invention uses.Reference
Fig. 1, this sensing unit is the double-decker of hollow structure, forms double-deck A face structure and B
Face structure is staggered relatively, distance 500 μm, and the periphery of A face structure and the handing-over of B face structure uses colloid
Seal；Described A face includes quartz glass substrate, interdigital electrode layer and WO3Air-sensitive film layer, WO3
Air-sensitive film layer is doping SnO2WO3Thin film, it is possible to achieve to NO2The detection of gas, described
B face includes quartz glass substrate and WO3Gas-discoloration layer, WO3Gas-discoloration layer is WO3Nanometer
Line film doping ZnTPP-2-NO2, utilize gas-discoloration principle can realize the inspection of the visualization to hydrogen
Survey；2 it are additionally provided with for air-vent that object gas penetrates in the structure of described B face.In A face,
Described SnO2Granularity less than 42nm, described WO3Air-sensitive film layer thickness is 700nm；B
In face, described WO3Nanowire length about 2 μm, diameter about 60nm；
Fig. 2 is according to the flow chart preparing sensing unit shown in an exemplary embodiment, such as Fig. 2 institute
Show, comprise the following steps:
S1, preparation A face structure, including following enforcement step: (1) takes certain size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water ultrasonic cleaning 20min；(2)
Spin coating one layer photoetching glue in quartz glass substrate, thickness 1 μm, under interdigital electrode mask covers
Exposure 6s, cleans with deionized water after being then passed through development 50s, uses magnetically controlled sputter method plating one
Cr film thick for layer 300nm, as interdigital electrode layer, then removes photoresist；(3) by quartz glass
Glass substrate is put in magnetic control sputtering device, is evacuated to 5 × 10-4Below Pa, is passed through Ar and O2Mixing
Gas, regulates Ar:O2Ratio is 5:1, and operating pressure is 2.4Pa, is purity 99.96% at target
Metal W target magnetic control sputtering 28min, target is the metal tin target magnetron sputtering 2min of purity 98%,
Obtain the SnO that adulterates2WO3Thin film, i.e. WO3Air-sensitive film layer；
S2, preparation B face structure, including following enforcement step: (1) takes same size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water, NaOH aqueous solution, go from
Sub-water ultrasonic cleaning, the time is 20min；(2) take 20g sodium tungstate to be dissolved in 200ml water,
Add excess concentrated hydrochloric acid obtain active tungstic acid precipitation, is filtered, then with deionized water cleaning until
Can't detect chloride ion, then active tungstic acid precipitation is dissolved in hydrogen peroxide, prepares colloidal sol, spin coating
In quartz glass substrate, 350 DEG C process 1h and obtain Seed Layer, and thickness is 20nm；(3) tungsten is taken
Acid sodium powder 4.12g is dissolved in 60ml deionized water, and regulating its pH with 3M HCl solution is 2.0,
Be subsequently adding 2.1g (0.3M) ammonium sulfate as controlling agent, quartz glass substrate is lain in from
In sub-water, after stirring 1 hour, pour in rustless steel hydrothermal reaction kettle, be heated to 150 DEG C in an oven
Keep 10h, then take out quartz glass substrate and spend ionized water cleaning；(4) chloroform is selected
For solvent, take 3.8g ZnTPP-2-NO2It is configured to the solution of 5.0mg/ml, supersound process 20min,
Make solution uniform, by dripping glue mode by made solution drop coating at quartz glass substrate surface, set rotation
Painting speed is 3400rpm, and spin-coating time is 70s, finally by quartz glass substrate at vacuum drying oven
In be dried 12h at 60 DEG C, obtain the ZnTPP-2-NO that adulterates2WO3Nano wire film, i.e. WO3
Gas-discoloration layer；
S3, assembling: by staggered relatively to the A face completed, B face structure, distance 500 μm, A
The periphery of face structure and the handing-over of B face structure uses colloid to seal, and obtains described gas-discoloration gas sensing
The sensing unit of device.
About the device in above-described embodiment, the concrete mode that wherein modules performs to operate exists
About the embodiment of the method has been described in detail, explanation will be not set forth in detail herein.
Data test:
In A face, air-sensitive test completes on Testing system of gas-sensor built, is put into by the device made
In quartz ampoule, heating unit heats makes the operating temperature of sensing unit be 120 DEG C, after stable, logical
Enter by air and finite concentration NO2The mixed gas of configuration, keeps 30min, is again passed through pure air,
Record WO3The resistance value of air-sensitive film layer, respectively R (NO2) and R (air), define air-sensitive
Sensitivity is: S=R (NO2)/R (air), response time is defined as being passed through resistance after test gas
Change to the time required for the 80% of maximum changes in resistance.Test finds, this tungsten oxide air-sensitive film
NO in 8ppm concentration2Gas medium sensitivity is 30；Best-case Response Time is 15s；Through 100
Secondary testing fatigue, electrical response value drops to original 86%.WO3Air-sensitive film shows well
Sensitivity, response time and repeatability.
In B face, use spectrophotometer to variable concentrations H2WO in atmosphere3Gas-discoloration layer is carried out
Light transmittance is tested, and defines T0For not leading to H2Time sample light transmittance, T is for being passed through finite concentration H2
Time sample light transmittance, relative light transmission:, be passed through H2When concentration is 5000ppm, the most thoroughly
Light rate with wavelength change, minimum 6%, be 59.7% to the maximum, and through about 10min, relatively
Light transmittance tends towards stability, it is seen that be passed through with tested gas, and tungsten oxide gas-discoloration layer light transmittance declines,
Showing as thin film color and transparent become blue from original, response time is short, shows good gas mutagens
Color performance.
Test finds, this lightning protection power distribution cabinet is provided with gas-discoloration gas sensor, utilizes gas-discoloration
Principle can realize the Visual retrieval to hydrogen, and response time is short, highly sensitive, variable color model
Enclose bigger, it is achieved that beyond thought effect, there is certain actual application value.
Embodiment 3:
There is provided a kind of lightning protection power distribution cabinet based on gas-discoloration gas sensor, outside described lightning protection power distribution cabinet
Surface is provided with gas-discoloration gas sensor, and described gas-discoloration gas sensor is based on WO3Gas
Quick material and WO3Gas-discoloration material；Described gas-discoloration gas sensor include sensing unit,
Heating unit and data-reading unit；The oxygen of described heating unit and data-reading unit and sensing unit
Change tungsten air-sensitive film to connect；Heating source when described heating unit works as tungsten oxide air-sensitive film；
Data-reading unit processes the conductivity variations signal of tungsten oxide air-sensitive film with display object gas
Concentration value.
Fig. 1 is the schematic diagram of sensing unit in the gas-discoloration gas sensor that the present invention uses.Reference
Fig. 1, this sensing unit is the double-decker of hollow structure, forms double-deck A face structure and B
Face structure is staggered relatively, distance 500 μm, and the periphery of A face structure and the handing-over of B face structure uses colloid
Seal；Described A face includes quartz glass substrate, interdigital electrode layer and WO3Air-sensitive film layer, WO3
Air-sensitive film layer is doping SnO2WO3Thin film, it is possible to achieve to NO2The detection of gas, described
B face includes quartz glass substrate and WO3Gas-discoloration layer, WO3Gas-discoloration layer is WO3Nanometer
Line film doping ZnTPP-2-NO2, utilize gas-discoloration principle can realize the inspection of the visualization to hydrogen
Survey；2 it are additionally provided with for air-vent that object gas penetrates in the structure of described B face.In A face,
Described SnO2Granularity less than 43nm, described WO3Air-sensitive film layer thickness is 700nm；B
In face, described WO3Nanowire length about 1 μm, diameter about 60nm；
Fig. 2 is according to the flow chart preparing sensing unit shown in an exemplary embodiment, such as Fig. 2 institute
Show, comprise the following steps:
S1, preparation A face structure, including following enforcement step: (1) takes certain size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water ultrasonic cleaning 20min；(2)
Spin coating one layer photoetching glue in quartz glass substrate, thickness 1 μm, under interdigital electrode mask covers
Exposure 6s, cleans with deionized water after being then passed through development 50s, uses magnetically controlled sputter method plating one
Cr film thick for layer 300nm, as interdigital electrode layer, then removes photoresist；(3) by quartz glass
Glass substrate is put in magnetic control sputtering device, is evacuated to 5 × 10-4Below Pa, is passed through Ar and O2Mixing
Gas, regulates Ar:O2Ratio is 5:1, and operating pressure is 2.4Pa, is purity 99.96% at target
Metal W target magnetic control sputtering 28min, target is the metal tin target magnetron sputtering 2min of purity 98%,
Obtain the SnO that adulterates2WO3Thin film, i.e. WO3Air-sensitive film layer；
S2, preparation B face structure, including following enforcement step: (1) takes same size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water, NaOH aqueous solution, go from
Sub-water ultrasonic cleaning, the time is 20min；(2) take 20g sodium tungstate to be dissolved in 200ml water,
Add excess concentrated hydrochloric acid obtain active tungstic acid precipitation, is filtered, then with deionized water cleaning until
Can't detect chloride ion, then active tungstic acid precipitation is dissolved in hydrogen peroxide, prepares colloidal sol, spin coating
In quartz glass substrate, 350 DEG C process 1h and obtain Seed Layer, and thickness is 20nm；(3) tungsten is taken
Acid sodium powder 4.12g is dissolved in 60ml deionized water, and regulating its pH with 3M HCl solution is 2.0,
Be subsequently adding 2.1g (0.3M) ammonium sulfate as controlling agent, quartz glass substrate is lain in from
In sub-water, after stirring 1 hour, pour in rustless steel hydrothermal reaction kettle, be heated to 150 DEG C in an oven
Keep 10h, then take out quartz glass substrate and spend ionized water cleaning；(4) chloroform is selected
For solvent, take 3.8g ZnTPP-2-NO2It is configured to the solution of 5.0mg/ml, supersound process 20min,
Make solution uniform, by dripping glue mode by made solution drop coating at quartz glass substrate surface, set rotation
Painting speed is 3400rpm, and spin-coating time is 70s, finally by quartz glass substrate at vacuum drying oven
In be dried 12h at 60 DEG C, obtain the ZnTPP-2-NO that adulterates2WO3Nano wire film, i.e. WO3
Gas-discoloration layer；
S3, assembling: by staggered relatively to the A face completed, B face structure, distance 500 μm, A
The periphery of face structure and the handing-over of B face structure uses colloid to seal, and obtains described gas-discoloration gas sensing
The sensing unit of device.
About the device in above-described embodiment, the concrete mode that wherein modules performs to operate exists
About the embodiment of the method has been described in detail, explanation will be not set forth in detail herein.
Data test:
In A face, air-sensitive test completes on Testing system of gas-sensor built, is put into by the device made
In quartz ampoule, heating unit heats makes the operating temperature of sensing unit be 120 DEG C, after stable, logical
Enter by air and finite concentration NO2The mixed gas of configuration, keeps 30min, is again passed through pure air,
Record WO3The resistance value of air-sensitive film layer, respectively R (NO2) and R (air), define air-sensitive
Sensitivity is: S=R (NO2)/R (air), response time is defined as being passed through resistance after test gas
Change to the time required for the 80% of maximum changes in resistance.Test finds, this tungsten oxide air-sensitive film
NO in 8ppm concentration2Gas medium sensitivity is 30；Best-case Response Time is 17s；Through 100
Secondary testing fatigue, electrical response value drops to original 84%.WO3Air-sensitive film shows well
Sensitivity, response time and repeatability.
In B face, use spectrophotometer to variable concentrations H2WO in atmosphere3Gas-discoloration layer is carried out
Light transmittance is tested, and defines T0For not leading to H2Time sample light transmittance, T is for being passed through finite concentration H2
Time sample light transmittance, relative light transmission:, be passed through H2When concentration is 5000ppm, the most thoroughly
Light rate with wavelength change, minimum 4%, be 59.7% to the maximum, and through about 16min, relatively
Light transmittance tends towards stability, it is seen that be passed through with tested gas, and tungsten oxide gas-discoloration layer light transmittance declines,
Showing as thin film color and transparent become blue from original, response time is short, shows good gas mutagens
Color performance.
Test finds, this lightning protection power distribution cabinet is provided with gas-discoloration gas sensor, utilizes gas-discoloration
Principle can realize the Visual retrieval to hydrogen, and response time is short, highly sensitive, variable color model
Enclose bigger, it is achieved that beyond thought effect, there is certain actual application value.
Embodiment 4:
There is provided a kind of lightning protection power distribution cabinet based on gas-discoloration gas sensor, outside described lightning protection power distribution cabinet
Surface is provided with gas-discoloration gas sensor, and described gas-discoloration gas sensor is based on WO3Gas
Quick material and WO3Gas-discoloration material；Described gas-discoloration gas sensor include sensing unit,
Heating unit and data-reading unit；The oxygen of described heating unit and data-reading unit and sensing unit
Change tungsten air-sensitive film to connect；Heating source when described heating unit works as tungsten oxide air-sensitive film；
Data-reading unit processes the conductivity variations signal of tungsten oxide air-sensitive film with display object gas
Concentration value.
Fig. 1 is the schematic diagram of sensing unit in the gas-discoloration gas sensor that the present invention uses.Reference
Fig. 1, this sensing unit is the double-decker of hollow structure, forms double-deck A face structure and B
Face structure is staggered relatively, distance 500 μm, and the periphery of A face structure and the handing-over of B face structure uses colloid
Seal；Described A face includes quartz glass substrate, interdigital electrode layer and WO3Air-sensitive film layer, WO3
Air-sensitive film layer is doping SnO2WO3Thin film, it is possible to achieve to NO2The detection of gas, described
B face includes quartz glass substrate and WO3Gas-discoloration layer, WO3Gas-discoloration layer is WO3Nanometer
Line film doping ZnTPP-2-NO2, utilize gas-discoloration principle can realize the inspection of the visualization to hydrogen
Survey；2 it are additionally provided with for air-vent that object gas penetrates in the structure of described B face.In A face,
Described SnO2Granularity less than 44nm, described WO3Air-sensitive film layer thickness is 700nm；B
In face, described WO3Nanowire length about 2.5 μm, diameter about 60nm；
Fig. 2 is according to the flow chart preparing sensing unit shown in an exemplary embodiment, such as Fig. 2 institute
Show, comprise the following steps:
S1, preparation A face structure, including following enforcement step: (1) takes certain size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water ultrasonic cleaning 20min；(2)
Spin coating one layer photoetching glue in quartz glass substrate, thickness 1 μm, under interdigital electrode mask covers
Exposure 6s, cleans with deionized water after being then passed through development 50s, uses magnetically controlled sputter method plating one
Cr film thick for layer 300nm, as interdigital electrode layer, then removes photoresist；(3) by quartz glass
Glass substrate is put in magnetic control sputtering device, is evacuated to 5 × 10-4Below Pa, is passed through Ar and O2Mixing
Gas, regulates Ar:O2Ratio is 5:1, and operating pressure is 2.4Pa, is purity 99.96% at target
Metal W target magnetic control sputtering 28min, target is the metal tin target magnetron sputtering 2min of purity 98%,
Obtain the SnO that adulterates2WO3Thin film, i.e. WO3Air-sensitive film layer；
S2, preparation B face structure, including following enforcement step: (1) takes same size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water, NaOH aqueous solution, go from
Sub-water ultrasonic cleaning, the time is 20min；(2) take 20g sodium tungstate to be dissolved in 200ml water,
Add excess concentrated hydrochloric acid obtain active tungstic acid precipitation, is filtered, then with deionized water cleaning until
Can't detect chloride ion, then active tungstic acid precipitation is dissolved in hydrogen peroxide, prepares colloidal sol, spin coating
In quartz glass substrate, 350 DEG C process 1h and obtain Seed Layer, and thickness is 20nm；(3) tungsten is taken
Acid sodium powder 4.12g is dissolved in 60ml deionized water, and regulating its pH with 3M HCl solution is 2.0,
Be subsequently adding 2.1g (0.3M) ammonium sulfate as controlling agent, quartz glass substrate is lain in from
In sub-water, after stirring 1 hour, pour in rustless steel hydrothermal reaction kettle, be heated to 150 DEG C in an oven
Keep 10h, then take out quartz glass substrate and spend ionized water cleaning；(4) chloroform is selected
For solvent, take 3.8g ZnTPP-2-NO2It is configured to the solution of 5.0mg/ml, supersound process 20min,
Make solution uniform, by dripping glue mode by made solution drop coating at quartz glass substrate surface, set rotation
Painting speed is 3400rpm, and spin-coating time is 70s, finally by quartz glass substrate at vacuum drying oven
In be dried 12h at 60 DEG C, obtain the ZnTPP-2-NO that adulterates2WO3Nano wire film, i.e. WO3
Gas-discoloration layer；
S3, assembling: by staggered relatively to the A face completed, B face structure, distance 500 μm, A
The periphery of face structure and the handing-over of B face structure uses colloid to seal, and obtains described gas-discoloration gas sensing
The sensing unit of device.
About the device in above-described embodiment, the concrete mode that wherein modules performs to operate exists
About the embodiment of the method has been described in detail, explanation will be not set forth in detail herein.
Data test:
In A face, air-sensitive test completes on Testing system of gas-sensor built, is put into by the device made
In quartz ampoule, heating unit heats makes the operating temperature of sensing unit be 120 DEG C, after stable, logical
Enter by air and finite concentration NO2The mixed gas of configuration, keeps 30min, is again passed through pure air,
Record WO3The resistance value of air-sensitive film layer, respectively R (NO2) and R (air), define air-sensitive
Sensitivity is: S=R (NO2)/R (air), response time is defined as being passed through resistance after test gas
Change to the time required for the 80% of maximum changes in resistance.Test finds, this tungsten oxide air-sensitive film
NO in 8ppm concentration2Gas medium sensitivity is 30；Best-case Response Time is 19s；Through 100
Secondary testing fatigue, electrical response value drops to original 89%.WO3Air-sensitive film shows well
Sensitivity, response time and repeatability.
In B face, use spectrophotometer to variable concentrations H2WO in atmosphere3Gas-discoloration layer is carried out
Light transmittance is tested, and defines T0For not leading to H2Time sample light transmittance, T is for being passed through finite concentration H2
Time sample light transmittance, relative light transmission:, be passed through H2When concentration is 5000ppm, the most thoroughly
Light rate with wavelength change, minimum 4%, be 59.7% to the maximum, and through about 10min, relatively
Light transmittance tends towards stability, it is seen that be passed through with tested gas, and tungsten oxide gas-discoloration layer light transmittance declines,
Showing as thin film color and transparent become blue from original, response time is short, shows good gas mutagens
Color performance.
Test finds, this lightning protection power distribution cabinet is provided with gas-discoloration gas sensor, utilizes gas-discoloration
Principle can realize the Visual retrieval to hydrogen, and response time is short, highly sensitive, variable color model
Enclose bigger, it is achieved that beyond thought effect, there is certain actual application value.
Embodiment 5:
There is provided a kind of lightning protection power distribution cabinet based on gas-discoloration gas sensor, outside described lightning protection power distribution cabinet
Surface is provided with gas-discoloration gas sensor, and described gas-discoloration gas sensor is based on WO3Gas
Quick material and WO3Gas-discoloration material；Described gas-discoloration gas sensor include sensing unit,
Heating unit and data-reading unit；The oxygen of described heating unit and data-reading unit and sensing unit
Change tungsten air-sensitive film to connect；Heating source when described heating unit works as tungsten oxide air-sensitive film；
Data-reading unit processes the conductivity variations signal of tungsten oxide air-sensitive film with display object gas
Concentration value.
Fig. 1 is the schematic diagram of sensing unit in the gas-discoloration gas sensor that the present invention uses.Reference
Fig. 1, this sensing unit is the double-decker of hollow structure, forms double-deck A face structure and B
Face structure is staggered relatively, distance 500 μm, and the periphery of A face structure and the handing-over of B face structure uses colloid
Seal；Described A face includes quartz glass substrate, interdigital electrode layer and WO3Air-sensitive film layer, WO3
Air-sensitive film layer is doping SnO2WO3Thin film, it is possible to achieve to NO2The detection of gas, described
B face includes quartz glass substrate and WO3Gas-discoloration layer, WO3Gas-discoloration layer is WO3Nanometer
Line film doping ZnTPP-2-NO2, utilize gas-discoloration principle can realize the inspection of the visualization to hydrogen
Survey；2 it are additionally provided with for air-vent that object gas penetrates in the structure of described B face.In A face,
Described SnO2Granularity less than 45nm, described WO3Air-sensitive film layer thickness is 700nm；B
In face, described WO3Nanowire length about 2 μm, diameter about 60nm；
Fig. 2 is according to the flow chart preparing sensing unit shown in an exemplary embodiment, such as Fig. 2 institute
Show, comprise the following steps:
S1, preparation A face structure, including following enforcement step: (1) takes certain size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water ultrasonic cleaning 20min；(2)
Spin coating one layer photoetching glue in quartz glass substrate, thickness 1 μm, under interdigital electrode mask covers
Exposure 6s, cleans with deionized water after being then passed through development 50s, uses magnetically controlled sputter method plating one
Cr film thick for layer 300nm, as interdigital electrode layer, then removes photoresist；(3) by quartz glass
Glass substrate is put in magnetic control sputtering device, is evacuated to 5 × 10-4Below Pa, is passed through Ar and O2Mixing
Gas, regulates Ar:O2Ratio is 5:1, and operating pressure is 2.4Pa, is purity 99.96% at target
Metal W target magnetic control sputtering 28min, target is the metal tin target magnetron sputtering 2min of purity 98%,
Obtain the SnO that adulterates2WO3Thin film, i.e. WO3Air-sensitive film layer；
S2, preparation B face structure, including following enforcement step: (1) takes same size (4cm × 4cm)
Quartz glass substrate, sequentially pass through acetone, ethanol, deionized water, NaOH aqueous solution, go from
Sub-water ultrasonic cleaning, the time is 20min；(2) take 20g sodium tungstate to be dissolved in 200ml water,
Add excess concentrated hydrochloric acid obtain active tungstic acid precipitation, is filtered, then with deionized water cleaning until
Can't detect chloride ion, then active tungstic acid precipitation is dissolved in hydrogen peroxide, prepares colloidal sol, spin coating
In quartz glass substrate, 350 DEG C process 1h and obtain Seed Layer, and thickness is 20nm；(3) tungsten is taken
Acid sodium powder 4.12g is dissolved in 60ml deionized water, and regulating its pH with 3M HCl solution is 2.0,
Be subsequently adding 2.1g (0.3M) ammonium sulfate as controlling agent, quartz glass substrate is lain in from
In sub-water, after stirring 1 hour, pour in rustless steel hydrothermal reaction kettle, be heated to 150 DEG C in an oven
Keep 10h, then take out quartz glass substrate and spend ionized water cleaning；(4) chloroform is selected
For solvent, take 3.2g ZnTPP-2-NO2It is configured to the solution of 5.0mg/ml, supersound process 20min,
Make solution uniform, by dripping glue mode by made solution drop coating at quartz glass substrate surface, set rotation
Painting speed is 3400rpm, and spin-coating time is 70s, finally by quartz glass substrate at vacuum drying oven
In be dried 12h at 60 DEG C, obtain the ZnTPP-2-NO that adulterates2WO3Nano wire film, i.e. WO3
Gas-discoloration layer；
S3, assembling: by staggered relatively to the A face completed, B face structure, distance 500 μm, A
The periphery of face structure and the handing-over of B face structure uses colloid to seal, and obtains described gas-discoloration gas sensing
The sensing unit of device.
About the device in above-described embodiment, the concrete mode that wherein modules performs to operate exists
About the embodiment of the method has been described in detail, explanation will be not set forth in detail herein.
Data test:
In A face, air-sensitive test completes on Testing system of gas-sensor built, is put into by the device made
In quartz ampoule, heating unit heats makes the operating temperature of sensing unit be 120 DEG C, after stable, logical
Enter by air and finite concentration NO2The mixed gas of configuration, keeps 30min, is again passed through pure air,
Record WO3The resistance value of air-sensitive film layer, respectively R (NO2) and R (air), define air-sensitive
Sensitivity is: S=R (NO2)/R (air), response time is defined as being passed through resistance after test gas
Change to the time required for the 80% of maximum changes in resistance.Test finds, this tungsten oxide air-sensitive film
NO in 8ppm concentration2Gas medium sensitivity is 30；Best-case Response Time is 15s；Through 100
Secondary testing fatigue, electrical response value drops to original 86%.WO3Air-sensitive film shows well
Sensitivity, response time and repeatability.
In B face, use spectrophotometer to variable concentrations H2WO in atmosphere3Gas-discoloration layer is carried out
Light transmittance is tested, and defines T0For not leading to H2Time sample light transmittance, T is for being passed through finite concentration H2
Time sample light transmittance, relative light transmission:, be passed through H2When concentration is 5000ppm, the most thoroughly
Light rate with wavelength change, minimum 7%, be 58% to the maximum, and through about 10min, the most thoroughly
Light rate tends towards stability, it is seen that be passed through with tested gas, and tungsten oxide gas-discoloration layer light transmittance declines, table
Now transparent being become blue for thin film color from original, response time is short, shows good gas-discoloration
Performance.
Test finds, this lightning protection power distribution cabinet is provided with gas-discoloration gas sensor, utilizes gas-discoloration
Principle can realize the Visual retrieval to hydrogen, and response time is short, highly sensitive, variable color model
Enclose bigger, it is achieved that beyond thought effect, there is certain actual application value.
Those skilled in the art, after considering description and putting into practice invention disclosed herein, will readily occur to
Other embodiments of the present invention.The application is intended to any modification of the present invention, purposes or fits
Answering property changes, and these modification, purposes or adaptations are followed the general principle of the present invention and wrap
Include the undocumented common knowledge in the art of the application or conventional techniques means.Description and reality
Executing example and be considered only as exemplary, true scope and spirit of the invention are referred to by claim below
Go out.
It should be appreciated that the invention is not limited in essence described above and illustrated in the accompanying drawings
Really structure, and various modifications and changes can carried out without departing from the scope.The scope of the present invention is only
Limited by appended claim.
Claims (2)
1. a lightning protection power distribution cabinet based on gas-discoloration gas sensor, it is characterised in that described
Lightning protection power distribution cabinet outer surface is provided with gas-discoloration gas sensor, described gas-discoloration gas sensor
Based on WO3Gas sensitive and WO3Gas-discoloration material；Described gas-discoloration gas sensor includes
Sensing unit, heating unit and data-reading unit；Described heating unit and data-reading unit are with quick
The tungsten oxide air-sensitive film of sense unit connects；When described heating unit works as tungsten oxide air-sensitive film
Heating source；Data-reading unit processes the conductivity variations signal of tungsten oxide air-sensitive film to show mesh
The concentration value of gas body；Described sensing unit is the double-decker of hollow structure, is formed double-deck
A face structure and B face structure are staggered relatively, distance 500 μm, A face structure and the handing-over of B face structure
Periphery use colloid seal；Described A face includes quartz glass substrate, interdigital electrode layer and WO3
Air-sensitive film layer, WO3Air-sensitive film layer is doping SnO2WO3Thin film, it is possible to achieve to NO2
The detection of gas, described B face includes quartz glass substrate and WO3Gas-discoloration layer, WO3Gas causes
Photochromic layer is WO3Nano wire film doping ZnTPP-2-NO2, utilize the gas-discoloration principle can be real
The now Visual retrieval to hydrogen；It is additionally provided with 2 in the structure of described B face to penetrate for object gas
Air-vent；In A face, described SnO2Granularity less than 40nm, described WO3Air-sensitive film
Layer thickness is 700nm；In B face, described WO3Nanowire length about 2 μm, diameter about 60nm.
2. the preparation a kind of based on gas-discoloration gas sensor lightning protection distribution described in claim 1
Cabinet, it is characterised in that wherein, the making of the sensing unit of described gas-discoloration gas sensor includes
Following steps:
S1, preparation A face structure, including following enforcement step:
(1) take the quartz glass substrate of certain size (4cm × 4cm), sequentially pass through acetone, second
Alcohol, deionized water ultrasonic cleaning 20min；
(2) spin coating one layer photoetching glue in quartz glass substrate, thickness 1 μm, cover in interdigital electrode
Masterplate exposes 6s under covering, and cleans with deionized water after being then passed through development 50s, uses magnetic control to spatter
Cr film thick for shooting method one layer of 300nm of plating, as interdigital electrode layer, then removes photoresist；
(3) quartz glass substrate is put in magnetic control sputtering device, be evacuated to 5 × 10-4Below Pa,
It is passed through Ar and O2Mixed gas, regulate Ar:O2Ratio is 5:1, and operating pressure is 2.4Pa,
Target is the metal W target magnetic control sputtering 28min of purity 99.96%, and target is the gold of purity 98%
Belong to stannum target magnetic control sputtering 2min, obtain the SnO that adulterates2WO3Thin film, i.e. WO3Air-sensitive film layer；
S2, preparation B face structure, including following enforcement step:
(1) take the quartz glass substrate of same size (4cm × 4cm), sequentially pass through acetone, second
Alcohol, deionized water, NaOH aqueous solution, deionized water ultrasonic cleaning, the time is 20min；
(2) taking 20g sodium tungstate to be dissolved in 200ml water, the concentrated hydrochloric acid adding excess obtains Porous Tungsten
Acid precipitation, is filtered, then cleans until can't detect chloride ion with deionized water, then by activity
Wolframic acid precipitation is dissolved in hydrogen peroxide, prepares colloidal sol, is spun in quartz glass substrate, at 350 DEG C
Reason 1h obtains Seed Layer, and thickness is 20nm；
(3) take sodium tungstate powder 4.12g and be dissolved in 60ml deionized water, regulate with 3M HCl solution
Its pH is 2.0, is subsequently adding 2.1g (0.3M) ammonium sulfate as controlling agent, by quartz glass substrate
The end, keeps flat in deionized water, after stirring 1 hour, pours in rustless steel hydrothermal reaction kettle, at baking oven
In be heated to 150 DEG C keep 10h, then take out quartz glass substrate spend ionized water clean；
(4) selecting chloroform is solvent, takes 3.8g ZnTPP-2-NO2It is configured to 5.0mg/ml's
Solution, supersound process 20min, make solution uniform, by dripping glue mode by made solution drop coating at stone
English glass basic surface, sets spin speed as 3400rpm, and spin-coating time is 70s, finally by stone
English substrate of glass is dried 12h in vacuum drying oven at 60 DEG C, obtain the ZnTPP-2-NO that adulterates2's
WO3Nano wire film, i.e. WO3Gas-discoloration layer；
S3, assembling: by staggered relatively to the A face completed, B face structure, distance 500 μm, A
The periphery of face structure and the handing-over of B face structure uses colloid to seal, and obtains described gas-discoloration gas sensing
The sensing unit of device.
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