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CN105922084B - A kind of fine grinding technology to coating for metal surfaces - Google Patents

A kind of fine grinding technology to coating for metal surfaces Download PDF

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Publication number
CN105922084B
CN105922084B CN201610541664.8A CN201610541664A CN105922084B CN 105922084 B CN105922084 B CN 105922084B CN 201610541664 A CN201610541664 A CN 201610541664A CN 105922084 B CN105922084 B CN 105922084B
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fine grinding
workpiece
weight
coating
parts
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CN105922084A (en
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牛海侠
潘秀琴
吕雪
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Anhui Sanlian University
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Anhui Sanlian University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B1/00Processes of grinding or polishing; Use of auxiliary equipment in connection with such processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/34Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
    • B24D3/346Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties utilised during polishing, or grinding operation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/14Anti-slip materials; Abrasives
    • C09K3/1454Abrasive powders, suspensions and pastes for polishing

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

This case discloses a kind of fine grinding technology to coating for metal surfaces, including:Workpiece to be ground is washed;Workpiece is placed at 60 80 DEG C and cured 0.5 1 hours;Workpiece is placed in ultraviolet environments 0.5 1 hours;Workpiece is placed in fine grinding fluid, and refined using mill;Wherein, include in fine grinding fluid:The parts by weight of water 1000;The parts by weight of citric acid 45 50;The parts by weight of sodium hypophosphite 25 30;The parts by weight of nitric acid 24;The parts by weight of benzene sulfonic acid sodium salt 15 20;The parts by weight of prodan 35 and the parts by weight of polyethylene glycol 45;The combination for having calcium oxide particle and barium carbonate particle is comprised at least in the abrasive particle of disc surface.This case is coordinated fine grinding fluid and special mill that brand-new design goes out, can realize and be refined in a manner of soft in coating surface, so that coating obtains more high-quality flat appearance degree and brightness by the improvement to existing fine grinding technology.

Description

一种对金属表面涂层的精磨工艺A Fine Grinding Process for Metal Surface Coating

技术领域technical field

本发明涉及一种打磨工艺,具体涉及一种对金属表面涂层的精磨工艺。The invention relates to a grinding process, in particular to a fine grinding process for metal surface coating.

背景技术Background technique

对金属表面的打磨工艺由来已久,但一般都是对单一材质的表面进行打磨,而打磨的要求一般也只要符合平整度或光亮度等要求即可,不要考虑待打磨工件的表面涂层的厚度等问题,因此,这种打磨方式相对比较简单,且易于控制。但如果要对金属表面镀有的精密型涂层打磨时,就要考虑打磨本身是否会给这种精密涂层带来性能上的影响,例如对一些抗氧化或耐酸碱涂层打磨时,由于在镀层时的工艺水平参差不齐,导致厚度不一,或局部产生细纹等影响,易导致在打磨时,使涂层破裂或磨穿。并且,有些涂层本身并不需要太深度地打磨,只需对表面的浅层存在的裂纹或凹坑进行磨平即可。因此,现有技术中的打磨方式对于这种“娇贵”的涂层来说有些“粗暴”,在施工时不易控制。The grinding process of metal surfaces has a long history, but generally the surface of a single material is polished, and the grinding requirements generally only need to meet the requirements of flatness or brightness, and do not consider the surface coating of the workpiece to be polished. Therefore, this grinding method is relatively simple and easy to control. However, if you want to polish the precision coating on the metal surface, you must consider whether the grinding itself will affect the performance of this precision coating. For example, when grinding some anti-oxidation or acid and alkali resistant coatings, Due to the uneven process level of the coating, resulting in uneven thickness, or local fine lines and other effects, it is easy to cause the coating to break or wear through during polishing. Moreover, some coatings themselves do not need to be polished too deeply, and only need to smooth the cracks or pits existing in the shallow layer of the surface. Therefore, the grinding method in the prior art is somewhat "rough" for this "delicate" coating, and is difficult to control during construction.

发明内容Contents of the invention

针对现有技术的不足之处,本发明的目的在于提供一种对金属表面涂层的精磨工艺,该工艺能够以温和的方式对微米级的致密型涂层进行有效精磨,以使涂层获得更加优质的外观平整度或光亮度。Aiming at the deficiencies in the prior art, the purpose of the present invention is to provide a fine grinding process for metal surface coatings, which can effectively grind micron-sized dense coatings in a mild manner, so that the coating layer for better appearance flatness or brilliance.

本发明的技术方案概述如下:Technical scheme of the present invention is summarized as follows:

一种对金属表面涂层的精磨工艺,其包括以下步骤:A kind of finishing process to metal surface coating, it comprises the following steps:

步骤1)将待精磨的工件进行水洗;Step 1) washing the workpiece to be finely ground;

步骤2)将工件置于60-80℃下熟化0.5-1小时;Step 2) aging the workpiece at 60-80°C for 0.5-1 hour;

步骤3)将工件置于紫外环境中0.5-1小时;Step 3) placing the workpiece in an ultraviolet environment for 0.5-1 hour;

步骤4)将工件置于精磨液中,并采用磨盘进行精磨;Step 4) placing the workpiece in the fine grinding fluid, and using a grinding disc to carry out fine grinding;

其中,所述精磨液中包括有以下重量份的材料:Wherein, the following materials by weight are included in the refined grinding liquid:

所述磨盘表面的磨粒中至少包括有氧化钙颗粒和碳酸钡颗粒的组合。The abrasive grains on the surface of the grinding disc at least include a combination of calcium oxide particles and barium carbonate particles.

优选的是,所述的对金属表面涂层的精磨工艺,其中,所述氧化钙颗粒与碳酸钡颗粒的重量比为1∶(1.3-1.4)。Preferably, in the fine grinding process for metal surface coating, the weight ratio of the calcium oxide particles to the barium carbonate particles is 1: (1.3-1.4).

优选的是,所述的对金属表面涂层的精磨工艺,其中,所述磨盘的转速为400-500r/min。Preferably, in the fine grinding process for metal surface coating, the rotational speed of the grinding disc is 400-500r/min.

优选的是,所述的对金属表面涂层的精磨工艺,其中,所述氧化钙颗粒和碳酸钡颗粒的粒径为100-200μm。Preferably, in the fine grinding process for metal surface coating, the particle diameters of the calcium oxide particles and barium carbonate particles are 100-200 μm.

优选的是,所述的对金属表面涂层的精磨工艺,其中,所述磨盘对工件表面的压力为90-120N。Preferably, in the fine grinding process for metal surface coating, the pressure of the grinding disc on the workpiece surface is 90-120N.

本发明的有益效果是:本案通过对现有精磨工艺的改进,配合全新设计出的精磨液和特制磨盘,能够实现以柔和的方式在涂层表面进行精磨,以使涂层获得更加优质的外观平整度和光亮度。The beneficial effects of the present invention are: through the improvement of the existing fine grinding process in this case, combined with the newly designed fine grinding fluid and special grinding disc, it can realize fine grinding on the surface of the coating in a soft way, so that the coating can be more High-quality appearance flatness and brightness.

具体实施方式detailed description

下面结合实施例对本发明做进一步的详细说明,以令本领域技术人员参照说明书文字能够据以实施。The present invention will be further described in detail below in conjunction with the embodiments, so that those skilled in the art can implement it with reference to the description.

本案提出一实施例的对金属表面涂层的精磨工艺,其包括以下步骤:This case proposes an embodiment of the fine grinding process to the metal surface coating, which includes the following steps:

步骤1)将待精磨的工件进行水洗,以使工件表面的涂层被水浸润;由于不同的涂层有着不同的吸水性,因此,这里的水洗未必是要求水必须渗透进涂层内部,即便对于斥水性的涂层来说,水洗的步骤也是有意义的,因为,水分子可能会嵌入在涂层表面的裂缝或凹坑中,这有利于步骤2)在加热熟化时,能够产生有效的应力。Step 1) wash the workpiece to be finely ground, so that the coating on the surface of the workpiece is soaked by water; because different coatings have different water absorption properties, the washing here does not necessarily require water to penetrate into the coating. Even for water-repellent coatings, the step of washing with water is also meaningful, because water molecules may be embedded in cracks or pits on the surface of the coating, which is beneficial to step 2) during heating and curing, which can produce effective of stress.

步骤2)将工件置于60-80℃下熟化0.5-1小时,通过加热的方式使工件表面的涂层产生应力;这样做的目的是使潜伏在涂层内部的微小应力得到增强,通过这种“加速”的方式,使得本来需要较长时间才能由应力的释放而显现出的涂层缺陷提前显现,从而利于对这种缺陷进行精磨处理。Step 2) Place the workpiece at 60-80°C for 0.5-1 hour to mature, and heat the coating on the surface of the workpiece to generate stress; This method of "acceleration" makes the coating defects that would have taken a long time to appear due to the release of stress to appear in advance, thus facilitating the fine grinding treatment of such defects.

步骤3)将工件置于紫外环境中0.5-1小时,以尽可能地逼出工件涂层最外层表面的微小裂缝;该步骤与步骤2)类似,是通过加速老化的方式使得涂层表面较为脆弱的地方提前暴露出来,也是利于对这些缺陷处进行精磨处理。Step 3) Place the workpiece in an ultraviolet environment for 0.5-1 hour to force out the tiny cracks on the outermost surface of the workpiece coating as much as possible; this step is similar to step 2), which makes the coating surface The more fragile places are exposed in advance, which is also conducive to the fine grinding of these defects.

步骤4)将工件置于精磨液中,并采用磨盘进行精磨;Step 4) placing the workpiece in the fine grinding fluid, and using a grinding disc to carry out fine grinding;

其中,精磨液中包括有以下重量份的材料:Wherein, the refining fluid includes the following materials by weight:

磨盘表面的磨粒中至少包括有氧化钙颗粒和碳酸钡颗粒的组合。The abrasive grains on the surface of the grinding disc at least include a combination of calcium oxide particles and barium carbonate particles.

精磨液和磨盘是一个有机整体,因为精磨液是针对磨盘的组分而特别定制的,两者相互配合才能获得最佳的精磨效果。本案的设计原理是使磨盘在精磨液中一边对工件打磨一边被精磨液所溶解,以这种方式来实现用较为温和的力道对一些“娇贵”的涂层进行精磨,以防止过大的打磨力道将涂层破坏。采用氧化钙颗粒和碳酸钡颗粒的组合是因为在酸性条件下,氧化钙的溶解速度比氧化钡略快,而要使两者保持几乎相同的溶解速度,就需要采用钡的碳酸盐形式,即碳酸钡,碳酸盐的溶解速度快于氧化物,在磨盘的表面碳酸钡先反应生成氧化钡,随后氧化钡和氧化钙共同作用于工件表面,随着打磨的进行,氧化钡和氧化钙又逐渐被精磨液溶解。而之所以在众多金属氧化物和碳酸盐中选择氧化钙和碳酸钡,是因为它们在弱酸性条件下的溶解速度适中,并且,氧化钙和碳酸钡的硬度也十分适中,这即能保证磨盘对涂层能够起到实质有效的打磨,又能保证这种打磨力度不过分强烈。The fine grinding liquid and the grinding disc are an organic whole, because the fine grinding liquid is specially customized for the components of the grinding disc, and the two cooperate with each other to obtain the best fine grinding effect. The design principle of this case is to make the grinding disc dissolve the workpiece while grinding the workpiece in the fine grinding liquid. In this way, some "delicate" coatings can be finely ground with a relatively gentle force to prevent excessive grinding. Heavy grinding force will destroy the coating. The combination of calcium oxide particles and barium carbonate particles is used because calcium oxide dissolves slightly faster than barium oxide under acidic conditions, and to maintain almost the same dissolution rate of the two requires the use of the carbonate form of barium, That is, barium carbonate, the dissolution rate of carbonate is faster than that of oxide, on the surface of the grinding disc, barium carbonate first reacts to form barium oxide, then barium oxide and calcium oxide work together on the surface of the workpiece, as the grinding progresses, barium oxide and calcium oxide It is gradually dissolved by the fine grinding liquid. The reason why calcium oxide and barium carbonate are selected among many metal oxides and carbonates is that they have a moderate dissolution rate under weakly acidic conditions, and the hardness of calcium oxide and barium carbonate is also very moderate, which can ensure The grinding disc can effectively polish the coating, and can ensure that the grinding force is not too strong.

在精磨液中,硝酸主要起到酸的溶解作用;柠檬酸和次磷酸钠主要用于控制精磨液的酸性,它具有一定的缓冲能力,以保护涂层免被强酸所侵害;苯磺酸钠在酸性条件下可以起到导热剂的作用,它可以提高精磨液的导热速度,以防止磨盘打磨而造成精磨液温度过高;氟硅酸钠和聚乙二醇的组合使用主要用于调节精磨液的粘稠度,并在一定程度上增加精磨液的润滑度,以保证磨盘在打磨时,不会对涂层造成不可修复的损伤,同时,氟硅酸钠和聚乙二醇的组合还具有一定的消泡作用,以减少磨盘在精磨液中旋转时的液体溅射量。精磨液作为一个整体,其中每个成分的添加量都应受到限制,若超出优选的范围,将导致其与磨盘的配合偏离最优效果。In the fine grinding liquid, nitric acid is mainly used to dissolve the acid; citric acid and sodium hypophosphite are mainly used to control the acidity of the fine grinding liquid, which has a certain buffer capacity to protect the coating from strong acid damage; benzenesulfon Sodium phosphate can play the role of heat conduction agent under acidic conditions, it can increase the heat conduction speed of the fine grinding liquid, so as to prevent the grinding disc from grinding and cause the temperature of the fine grinding liquid to be too high; the combination of sodium fluorosilicate and polyethylene glycol is mainly used It is used to adjust the viscosity of the fine grinding fluid and increase the lubricity of the fine grinding fluid to a certain extent, so as to ensure that the coating will not be irreparably damaged when the grinding disc is polished. At the same time, sodium fluorosilicate and poly The combination of ethylene glycol also has a certain defoaming effect to reduce the amount of liquid splashed when the disc rotates in the refining liquid. As a whole, the addition amount of each component should be limited in the refining liquid, if it exceeds the preferred range, it will lead to deviation from the optimal effect of its cooperation with the grinding disc.

作为本案另一实施例,其中,氧化钙颗粒与碳酸钡颗粒的重量比优选为1∶(1.3-1.4)。研究表明,在该比例下,磨盘与精磨液的配合程度最好。As another embodiment of the present application, the weight ratio of calcium oxide particles to barium carbonate particles is preferably 1:(1.3-1.4). Studies have shown that at this ratio, the degree of cooperation between the grinding disc and the refining liquid is the best.

作为本案又一实施例,其中,磨盘的转速优选为400-500r/min。As yet another embodiment of the present application, wherein, the rotational speed of the grinding disc is preferably 400-500 r/min.

作为本案又一实施例,其中,氧化钙颗粒和碳酸钡颗粒的粒径优选为100-200μm。As yet another embodiment of the present application, the particle diameters of the calcium oxide particles and the barium carbonate particles are preferably 100-200 μm.

作为本案又一实施例,其中,磨盘对工件表面的压力优选为90-120N。As another embodiment of the present application, the pressure of the grinding disc on the surface of the workpiece is preferably 90-120N.

本案的精磨工艺可对涂层表面的微小裂纹或凹坑进行修复或磨平,以使涂层获得较好的平整度和表面光亮度。The fine grinding process in this case can repair or smooth the tiny cracks or pits on the surface of the coating, so that the coating can obtain better flatness and surface brightness.

尽管本发明的实施方案已公开如上,但其并不仅仅限于说明书和实施方式中所列运用,它完全可以被适用于各种适合本发明的领域,对于熟悉本领域的人员而言,可容易地实现另外的修改,因此在不背离权利要求及等同范围所限定的一般概念下,本发明并不限于特定的细节。Although the embodiment of the present invention has been disclosed as above, it is not limited to the use listed in the specification and implementation, it can be applied to various fields suitable for the present invention, and it can be easily understood by those skilled in the art Therefore, the invention is not limited to the specific details without departing from the general concept defined by the claims and their equivalents.

Claims (5)

1.一种对金属表面涂层的精磨工艺,其特征在于,包括以下步骤:1. a fine grinding process to metal surface coating, is characterized in that, comprises the following steps: 步骤1)将待精磨的工件进行水洗;Step 1) washing the workpiece to be finely ground; 步骤2)将工件置于60-80℃下熟化0.5-1小时;Step 2) aging the workpiece at 60-80°C for 0.5-1 hour; 步骤3)将工件置于紫外环境中0.5-1小时;Step 3) placing the workpiece in an ultraviolet environment for 0.5-1 hour; 步骤4)将工件置于精磨液中,并采用磨盘进行精磨;Step 4) placing the workpiece in the fine grinding fluid, and using a grinding disc to carry out fine grinding; 其中,所述精磨液中包括有以下重量份的材料:Wherein, the following materials by weight are included in the refined grinding liquid: 所述磨盘表面的磨粒中至少包括有氧化钙颗粒和碳酸钡颗粒的组合。The abrasive grains on the surface of the grinding disc at least include a combination of calcium oxide particles and barium carbonate particles. 2.根据权利要求1所述的对金属表面涂层的精磨工艺,其特征在于,所述氧化钙颗粒与碳酸钡颗粒的重量比为1∶(1.3-1.4)。2. the fine grinding process to metal surface coating according to claim 1, is characterized in that, the weight ratio of described calcium oxide particle and barium carbonate particle is 1: (1.3-1.4). 3.根据权利要求1所述的对金属表面涂层的精磨工艺,其特征在于,所述磨盘的转速为400-500r/min。3. The fine grinding process for metal surface coating according to claim 1, characterized in that, the rotating speed of the grinding disc is 400-500r/min. 4.根据权利要求1所述的对金属表面涂层的精磨工艺,其特征在于,所述氧化钙颗粒和碳酸钡颗粒的粒径为100-200μm。4. The fine grinding process for metal surface coating according to claim 1, characterized in that the particle diameters of the calcium oxide particles and barium carbonate particles are 100-200 μm. 5.根据权利要求1所述的对金属表面涂层的精磨工艺,其特征在于,所述磨盘对工件表面的压力为90-120N。5. The fine grinding process for metal surface coating according to claim 1, characterized in that, the pressure of the grinding disc on the workpiece surface is 90-120N.
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