CN105968960A - Water-based anti-precipitation fluorescent ink and processing method thereof - Google Patents
Water-based anti-precipitation fluorescent ink and processing method thereof Download PDFInfo
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- CN105968960A CN105968960A CN201610383163.1A CN201610383163A CN105968960A CN 105968960 A CN105968960 A CN 105968960A CN 201610383163 A CN201610383163 A CN 201610383163A CN 105968960 A CN105968960 A CN 105968960A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 229910001868 water Inorganic materials 0.000 title claims abstract description 39
- 238000001556 precipitation Methods 0.000 title claims abstract description 17
- 238000003672 processing method Methods 0.000 title description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000012046 mixed solvent Substances 0.000 claims abstract description 13
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011575 calcium Substances 0.000 claims abstract description 11
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 11
- 239000007822 coupling agent Substances 0.000 claims abstract description 11
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 11
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 10
- 239000002562 thickening agent Substances 0.000 claims abstract description 10
- 239000003822 epoxy resin Substances 0.000 claims abstract description 8
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 24
- 239000000084 colloidal system Substances 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 15
- 239000004593 Epoxy Substances 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 13
- 230000005415 magnetization Effects 0.000 claims description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004327 boric acid Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 235000019983 sodium metaphosphate Nutrition 0.000 claims description 3
- 230000008961 swelling Effects 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 238000013329 compounding Methods 0.000 claims description 2
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical group O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 239000000017 hydrogel Substances 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229940080314 sodium bentonite Drugs 0.000 claims description 2
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- -1 ammonium phosphate Compound Chemical class 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 238000007639 printing Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the technical field of printing, in particular to a water-based anti-precipitation fluorescent ink. The water-based anti-precipitation fluorescent ink is prepared from 60-80 parts of a mixed solvent, 30-40 parts of modified epoxide resin, 6-8 parts of colloidal oil, 5-15 parts of acrylic resin, 10-20 parts of a thickener, 6-8 parts of colloidal calcium, 3-5 parts of calcium carbonate, 2-4 parts of a water-soluble dispersant, 30-40 parts of water, 15-25 parts of ethyl alcohol, 5-7 parts of ethylene glycol butyl ether, 3-5 parts of a defoaming agent, 2-4 parts of a thixotropic agent, 3-5 parts of a coupling agent and 20-30 parts of a magnetized fluorescent solution. The prepared printing ink has the advantages of being reasonable in formula, simple in preparation process, good in fluorescent property, uniform in texture, free of precipitation, significant in effect in practical use and convenient to use and popularize.
Description
Technical field
The present invention relates to printing technology, be specifically related to a kind of water base anti-precipitation fluorescent ink and processing thereof
Method.
Background technology
Notebook computer, also known as notes type, portable or kneetop computer, be that one is small-sized, be easily carried
PC, the weight of notebook computer generally weighs 1-3 kilogram, and its development trend is that volume is more and more less,
Weight is increasingly lighter, and function is from strength to strength, as Netbook, the net book being namely commonly called as, pen
Remember that this computer differs primarily in that its Portable belt with PC.
Ink is different due to its field applied, and therefore has different types of ink, notebook computer key
Dish carrying out making is being, it is necessary to it is carried out font printing, due to the required performance of fluorescence property,
When printing, ink must possess luminescent properties, and its main component is fluorescent pigment, thus produces difference
The fluorescence phenomenon of form and aspect, different color light combines and forms abnormal gay colours, and after light stops irradiating,
Luminescence phenomenon i.e. disappears, because of referred to herein as fluorescent pigment, fluorescent pigment and macromolecule resin binder, solvent
With auxiliary agent proportioning, the ground fluorescent ink for preparing, but fluorescent ink is in the application, can exist
The situation of skewness produces, and owing to fluorescent ink itself belongs to the liquid of a kind of thickness, converges in ink
Internal its granule of fluorescent material possesses certain sedimentation function, therefore in actual application, and fluoroleum
The homogenizing of ink has certain defect, therefore, causes ink in use, there is flaw, it is difficult to conform to
Ask.
Summary of the invention:
The technical problem to be solved is to provide a kind of technology simple, and fluorescence property is strong, anti-settling
Effective water base anti-precipitation fluorescent ink and processing method thereof.
The technical problem to be solved realizes by the following technical solutions:
A kind of water base anti-precipitation fluorescent ink, it is characterised in that be made up of the raw material of following components:
Mixed solvent 60-80 part, modified epoxy 30-40 part, colloid oil 6-8 part, acrylic resin 5-15
Part, thickening agent 10-20 part, colloid calcium 6-8 part, calcium carbonate 3-5 part, aqueous dispersion 2-4 part, water 30-40
Part, ethanol 15-25 part, butyl glycol ether 5-7 part, defoamer 3-5 part, thixotropic agent 2-4 part, coupling agent
3-5 part, magnetization fluorescent solutions 20-30 part.
The preferred ingredient of each raw material is: mixed solvent 70 parts, modified epoxy 35 parts, colloid oil 7 parts,
Acrylic resin 10 parts, thickening agent 15 parts, colloid calcium 7 parts, calcium carbonate 4 parts, aqueous dispersion 3 parts, water
35 parts, ethanol 20 parts, butyl glycol ether 6 parts, defoamer 4 parts, thixotropic agent 3 parts, coupling agent 4 parts, magnetic
Change fluorescent solutions 25 parts.
Described mixed solvent formic acid, oleic acid, glycerol carry out compounding making according to the amount of 1:2:1.
Described thickening agent is sodium bentonite or Silica hydrogel.
Aqueous dispersion compounds according to the mass ratio of 15:2:1 by using water, ammonium sulfate, ammonium phosphate
Make.
Described modified epoxy is made up of the raw material of following component: epoxy resin 80 parts, Polymeric sodium metaphosphate.
1 part, 26 parts of water, boric acid 2 parts, potassium hydroxide 12 parts, Borax 3, organobentonite 30 parts；
Its preparation method is: put into by epoxy resin in the molten device of stirring, Polymeric sodium metaphosphate. is joined container
In, stirring mixing, add 15 parts of water to stirring molten device, stir 3 minutes, stand swelling dispersion 50
Minute, then by 3 parts of boric acid, water, put in stirring container, stir, stand 25 minutes, then
Potassium hydroxide, Borax and remaining 8 parts of water are put into wherein, stirs, stand 45 minutes, add
After organobentonite, urge dry, can be prepared by modified epoxy.
Described magnetization fluorescent solutions preparation method is: take a diameter of 8um-70um fluorescent particles, by fluorescence
Particle is put in agitator tank, adds the clear water of total amount 4 times, and high-speed stirred obtains suspension liquid, then takes glimmering
The Magnet stone powder of light particle total amount 12% is added thereto again, after continuing stirring 20-30min, the most available
Magnetization fluorescent solutions.
It is another object of the present invention to prepare the method for water base anti-settling electrically conductive ink in the present invention, its feature exists
In, comprise the following steps:
1) colloid oil, acrylic resin, colloid calcium and the calcium carbonate in raw material is put in grinding pot carry out
Being milled to internal particle fineness is 10-30um, obtains suspension fluid, standby；
2) by the mixed solvent in raw material, modified epoxy, water, ethanol, butyl glycol ether and magnetization
Fluorescent solutions all adds in stirred tank, and high-speed stirred is also heated to 60-80 DEG C, after stirring 1-2h, and fall
Temperature is to 25-35 DEG C；
3) aqueous dispersion in raw material, defoamer, thixotropic agent and coupling agent are added stirring in step 2
Mix in still, after being again stirred 20-30min, take out, put in the grinding pot in step 1, again
After stirring 30min, the most available.
In the present invention, by the modification to epoxy resin so that epoxy resin has possessed more homogenizing
Bond properties, the merging of magnetization fluorescent solutions inner magnet iron powder and fluorescent material simultaneously, promote each grain
Possess the power repelled mutually and attract each other between son, promote liquid internal particle normally to fix, thus
Possesses non-setting effect.
The invention have the benefit that printing-ink prepared by the present invention, its formula is reasonable, preparation technology
Simply, fluorescence property is good, homogeneous, will not produce precipitation, and in actual use, effect is notable,
It is easy to promote and use.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from
Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
Weigh mixed solvent 60kg, modified epoxy 30kg, colloid oil 6kg, acrylic resin 5kg,
Thickening agent 10kg, colloid calcium 6kg, calcium carbonate 3kg, aqueous dispersion 2kg, water 30kg, ethanol 15kg,
Butyl glycol ether 5kg, defoamer 3kg, thixotropic agent 2kg, coupling agent 3kg, magnetization fluorescent solutions 20kg.
Embodiment 2
Weigh mixed solvent 80kg, modified epoxy 40kg, colloid oil 8kg, acrylic resin 15kg,
Thickening agent 20kg, colloid calcium 8kg, calcium carbonate 5kg, aqueous dispersion 4kg, water 40kg, ethanol 25kg,
Butyl glycol ether 7kg, defoamer 5kg, thixotropic agent 4kg, coupling agent 5kg, magnetization fluorescent solutions 30kg.
Embodiment 3
Weigh mixed solvent 70kg, modified epoxy 35kg, colloid oil 7kg, acrylic resin 10kg,
Thickening agent 15kg, colloid calcium 7kg, calcium carbonate 4kg, aqueous dispersion 3kg, water 35kg, ethanol 20kg,
Butyl glycol ether 6kg, defoamer 4kg, thixotropic agent 3kg, coupling agent 4kg, magnetization fluorescent solutions 25kg.
Preparation embodiment 1, embodiment 2 or embodiment 3 method:
1) colloid oil, acrylic resin, colloid calcium and the calcium carbonate in raw material is put in grinding pot carry out
Being milled to internal particle fineness is 10-30um, obtains suspension fluid, standby；
2) by the mixed solvent in raw material, modified epoxy, water, ethanol, butyl glycol ether and magnetization
Fluorescent solutions all adds in stirred tank, and high-speed stirred is also heated to 60-80 DEG C, after stirring 1-2h, and fall
Temperature is to 25-35 DEG C；
3) aqueous dispersion in raw material, defoamer, thixotropic agent and coupling agent are added stirring in step 2
Mix in still, after being again stirred 20-30min, take out, put in the grinding pot in step 1, again
After stirring 30min, the most available.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession
Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation
The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention,
The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model
In enclosing.Claimed scope is defined by appending claims and equivalent thereof.
Claims (8)
1. a water base anti-precipitation fluorescent ink, it is characterised in that by the raw material of following components
Make:
Mixed solvent 60-80 part, modified epoxy 30-40 part, colloid oil 6-8 part, third
Olefin(e) acid resin 5-15 part, thickening agent 10-20 part, colloid calcium 6-8 part, calcium carbonate 3-5 part,
Aqueous dispersion 2-4 part, water 30-40 part, ethanol 15-25 part, butyl glycol ether 5-7 part,
Defoamer 3-5 part, thixotropic agent 2-4 part, coupling agent 3-5 part, magnetization fluorescent solutions 20-30
Part.
The water base anti-precipitation fluorescent ink of one the most according to claim 1, it is characterised in that:
The preferred ingredient of each raw material is: mixed solvent 70 parts, modified epoxy 35 parts, colloid oil 7
Part, acrylic resin 10 parts, thickening agent 15 parts, colloid calcium 7 parts, calcium carbonate 4 parts, aqueous are divided
Powder 3 parts, 35 parts of water, ethanol 20 parts, butyl glycol ether 6 parts, defoamer 4 parts, thixotropic agent 3
Part, coupling agent 4 parts, magnetization fluorescent solutions 25 parts.
The water base anti-precipitation fluorescent ink of one the most according to claim 1, it is characterised in that:
Described mixed solvent formic acid, oleic acid, glycerol carry out compounding making according to the amount of 1:2:1.
The water base anti-precipitation fluorescent ink of one the most according to claim 1, it is characterised in that:
Described thickening agent is sodium bentonite or Silica hydrogel.
The water base anti-precipitation fluorescent ink of one the most according to claim 1, it is characterised in that:
Aqueous dispersion is carried out according to the mass ratio of 15:2:1 by using water, ammonium sulfate, ammonium phosphate
Compound and make.
The water base anti-precipitation fluorescent ink of one the most according to claim 1, it is characterised in that:
Described modified epoxy is made up of the raw material of following component: epoxy resin 80 parts, inclined phosphorus
Acid 1 part of sodium, 26 parts of water, boric acid 2 parts, potassium hydroxide 12 parts, Borax 3, organic swelling
30 parts of soil；
Its preparation method is: is put into by epoxy resin in the molten device of stirring, is added by Polymeric sodium metaphosphate.
In container, stirring mixing, add 15 parts of water to stirring molten device, stir 3 minutes, quiet
Put swelling dispersion 50 minutes, then by 3 parts of boric acid, water, put in stirring container, stirring
Uniformly, stand 25 minutes, then potassium hydroxide, Borax and remaining 8 parts of water put into wherein,
Stir, stand 45 minutes, after adding organobentonite, urge dry, can be prepared by modification
Epoxy resin.
The water base anti-precipitation fluorescent ink of one the most according to claim 1, it is characterised in that:
Described magnetization fluorescent solutions preparation method is: take a diameter of 8um-70um fluorescent particles, will
Fluorescent particles is put in agitator tank, adds the clear water of total amount 4 times, and high-speed stirred obtains suspension liquid,
Then the Magnet stone powder taking fluorescent particles total amount 12% is added thereto again, continues stirring
After 20-30min, i.e. can obtain magnetizing fluorescent solutions.
8. prepare an a kind of method for water base anti-precipitation fluorescent ink in claim 1 or 2,
It is characterized in that, comprise the following steps:
1) colloid oil, acrylic resin, colloid calcium and the calcium carbonate in raw material is put into grinding pot
In carry out being milled to internal particle fineness being 10-30um, obtain suspension fluid, standby；
2) by the mixed solvent in raw material, modified epoxy, water, ethanol, butyl glycol ether
All adding in stirred tank with magnetization fluorescent solutions, high-speed stirred is also heated to 60-80 DEG C, stirs
After mixing 1-2h, it is cooled to 25-35 DEG C；
3) aqueous dispersion in raw material, defoamer, thixotropic agent and coupling agent are added step 2
In stirred tank in, after being again stirred 20-30min, take out, put in step 1
In grinding pot, after being again stirring for 30min, the most available.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610383163.1A CN105968960A (en) | 2016-05-27 | 2016-05-27 | Water-based anti-precipitation fluorescent ink and processing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610383163.1A CN105968960A (en) | 2016-05-27 | 2016-05-27 | Water-based anti-precipitation fluorescent ink and processing method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN105968960A true CN105968960A (en) | 2016-09-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610383163.1A Pending CN105968960A (en) | 2016-05-27 | 2016-05-27 | Water-based anti-precipitation fluorescent ink and processing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106433302A (en) * | 2016-09-30 | 2017-02-22 | 广州元禄信息科技有限公司 | High-luster quick-drying non-skinning ink used for printing patterns on clothes |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6666913B2 (en) * | 2000-09-05 | 2003-12-23 | Sakura Color Products Corporation | Aqueous ink composition |
| CN103694788A (en) * | 2013-11-28 | 2014-04-02 | 林国良 | Water-based foaming ink special for wallpaper intaglio printing and preparation method thereof |
| CN104031472A (en) * | 2014-06-05 | 2014-09-10 | 哈尔滨绿科科技有限公司 | Water-based electrochemical aluminum packaging composite film color layer ink |
| CN105348924A (en) * | 2015-10-29 | 2016-02-24 | 苏州市博来特油墨有限公司 | Novel aqueous conducting ink |
-
2016
- 2016-05-27 CN CN201610383163.1A patent/CN105968960A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6666913B2 (en) * | 2000-09-05 | 2003-12-23 | Sakura Color Products Corporation | Aqueous ink composition |
| CN103694788A (en) * | 2013-11-28 | 2014-04-02 | 林国良 | Water-based foaming ink special for wallpaper intaglio printing and preparation method thereof |
| CN104031472A (en) * | 2014-06-05 | 2014-09-10 | 哈尔滨绿科科技有限公司 | Water-based electrochemical aluminum packaging composite film color layer ink |
| CN105348924A (en) * | 2015-10-29 | 2016-02-24 | 苏州市博来特油墨有限公司 | Novel aqueous conducting ink |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106433302A (en) * | 2016-09-30 | 2017-02-22 | 广州元禄信息科技有限公司 | High-luster quick-drying non-skinning ink used for printing patterns on clothes |
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Application publication date: 20160928 |