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CN105977543A - Flexible battery - Google Patents

Flexible battery Download PDF

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Publication number
CN105977543A
CN105977543A CN201610524733.4A CN201610524733A CN105977543A CN 105977543 A CN105977543 A CN 105977543A CN 201610524733 A CN201610524733 A CN 201610524733A CN 105977543 A CN105977543 A CN 105977543A
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active material
positive
negative
battery
negative electrode
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CN201610524733.4A
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杨浩田
王晓明
韦程
王志彬
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Dongguan Advanced Electronic Tech Co ltd
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Dongguan Advanced Electronic Tech Co ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

The invention provides a flexible battery which comprises a battery core formed by winding a positive electrode, a negative electrode and a diaphragm for isolating the positive electrode and the negative electrode, wherein the positive electrode comprises a positive plate which is not coated by a positive active material, the negative electrode comprises a negative plate which is not coated by a negative active material, the surface of one side, facing the negative plate, of the diaphragm is coated with the negative active material, and the surface of the other side, facing the positive plate, of the diaphragm is coated with the positive active material. According to the invention, the positive electrode active material and the negative electrode active material are coated on the diaphragm, and the diaphragm is softer than the positive plate and the negative plate, so that the battery core is easier to wind and form, the battery can be thinner and softer, and the battery is suitable for being made into a flexible battery and is suitable for being used on wearable electronic equipment; meanwhile, the situation that the positive active material and the negative active material break and fall off is avoided, so that the performance stability of the battery cell is improved, the ion passing effect in the battery cell is smoother, the resistance in the battery is reduced, and the safety of the battery is improved.

Description

柔性电池flexible battery

技术领域technical field

本发明涉及锂电池技术领域,尤其涉及一种柔软性高的柔性电池。The invention relates to the technical field of lithium batteries, in particular to a flexible battery with high flexibility.

背景技术Background technique

随着科学技术的发展,智能手机和可穿戴电子设备的厚度越做越薄,对为这些电子设备供电的电池的要求也越来越高。目前,锂电池的电芯构成一般是由涂覆有正极活性材料的正极片、涂覆有负极活性材料的负极片和隔离正负极的隔膜卷绕而成,而由于正极片和负极片相对于隔膜硬很多,正极活性材料和负极活性材料分别涂覆到正极片和负极片后,无形中增加了正极片和负极片的厚度和硬度,导致电芯不易卷绕成型,同时也增加卷绕厚度,不利于降低电池整体厚度或硬度,导致电池不能做成可弯曲的柔性电池,不适于在可穿戴的电子设备中使用;而且,当正极片或负极片卷曲时,涂覆的正极料或负极材料容易被打破脱落的情况,导致生产的电池导电性变差,造成电池报废,提高生产成本。With the development of science and technology, the thickness of smartphones and wearable electronic devices is getting thinner and thinner, and the requirements for batteries that power these electronic devices are also getting higher and higher. At present, the battery cell of a lithium battery is generally composed of a positive electrode sheet coated with a positive electrode active material, a negative electrode sheet coated with a negative electrode active material, and a separator separating the positive and negative electrodes. Because the separator is much harder, after the positive active material and the negative active material are coated on the positive and negative plates respectively, the thickness and hardness of the positive and negative plates are virtually increased, making it difficult for the battery core to be wound and formed, and it also increases the winding capacity. Thickness is not conducive to reducing the overall thickness or hardness of the battery, so that the battery cannot be made into a bendable flexible battery, which is not suitable for use in wearable electronic devices; moreover, when the positive electrode or negative electrode is curled, the coated positive electrode or The negative electrode material is easy to break and fall off, resulting in poor conductivity of the produced battery, causing the battery to be scrapped, and increasing production costs.

发明内容Contents of the invention

本发明针对现有技术存在之缺失,提供一种柔性电池,其可极大地降低电池厚度和硬度,有利于将电池做得更薄、更软,适于在可穿戴电子设备上使用。Aiming at the deficiencies in the prior art, the present invention provides a flexible battery, which can greatly reduce the thickness and hardness of the battery, which is conducive to making the battery thinner and softer, and is suitable for use on wearable electronic devices.

为实现上述目的,本发明采用如下之技术方案:To achieve the above object, the present invention adopts the following technical solutions:

一种柔性电池,包括由正极、负极和隔离正负极的隔膜卷绕而成的电芯,所述正极包括未被正极活性材料涂覆的正极片,所述负极包括未被负极活性材料涂覆的负极片,所述隔膜朝向负极片的一侧表面涂覆有负极活性材料,朝向正极片的另一侧表面涂覆有正极活性材料。A flexible battery, comprising an electric core wound by a positive electrode, a negative electrode and a separator separating the positive and negative electrodes, the positive electrode includes a positive electrode sheet not coated with a positive active material, and the negative electrode includes a positive electrode sheet not coated with a negative active material A coated negative electrode sheet, the surface of the separator facing the negative electrode sheet is coated with a negative electrode active material, and the surface of the other side facing the positive electrode sheet is coated with a positive electrode active material.

作为一种优选方案,所述正极活性材料的涂覆厚度为50-500μm,涂覆面密度为20-400g/m2;所述负极活性材料的涂覆厚度为50-500μm,涂覆面密度为20-400g/m2As a preferred solution, the coating thickness of the positive electrode active material is 50-500 μm, and the coating surface density is 20-400 g/m 2 ; the coating thickness of the negative electrode active material is 50-500 μm, and the coating surface density is 20 -400g/m 2 .

作为一种优选方案,所述正极片与隔膜之间设有正极粘结层,所述负极片与隔膜之间设有负极粘结层。As a preferred solution, a positive electrode bonding layer is provided between the positive electrode sheet and the separator, and a negative electrode bonding layer is provided between the negative electrode sheet and the separator.

作为一种优选方案,所述正极片为铝箔。As a preferred solution, the positive electrode sheet is aluminum foil.

作为一种优选方案,所述负极片为铜箔。As a preferred solution, the negative electrode sheet is copper foil.

作为一种优选方案,所述正极活性材料为钴酸锂。As a preferred solution, the positive electrode active material is lithium cobaltate.

作为一种优选方案,所述负极活性材料为石墨。As a preferred solution, the negative electrode active material is graphite.

本发明与现有技术相比具有明显的优点和有益效果,具体而言,通过将正极活性材料和负极活性材料均涂覆于隔膜上,隔膜比正极片及负极片更加柔软,使电芯更容易卷绕成型,有利于将电池做得更薄、更软,适于做成柔性电池,适于在可穿戴电子设备上使用;同时,通过将正极活性材料和负极活性材料均涂覆于隔膜上,避免了正极片和负极片弯曲时正极活性材料和负极活性材料打破脱落的情况,从而提高了电芯性能的稳定性,提高了电池质量;而且将正极活性材料和负极活性材料涂覆于隔膜上可使得电芯内的离子通过效果更加流畅,降低了电池内部的电阻,降低了电池在充放电过程中的放热量,提高了电池的安全性;另外,通过将正极活性材料和负极活性材料均涂覆于隔膜上,使得负极片与隔膜更加容易粘结固定,提高了电池结构的稳定性,增加了电池寿命。Compared with the prior art, the present invention has obvious advantages and beneficial effects. Specifically, by coating both the positive electrode active material and the negative electrode active material on the diaphragm, the diaphragm is softer than the positive electrode sheet and the negative electrode sheet, making the cell more flexible. It is easy to wind and shape, which is conducive to making the battery thinner and softer, suitable for making flexible batteries, suitable for use in wearable electronic devices; at the same time, by coating both positive and negative active materials on the separator On the one hand, it avoids the situation that the positive electrode active material and the negative electrode active material break off when the positive electrode sheet and the negative electrode sheet are bent, thereby improving the stability of the performance of the cell and improving the quality of the battery; and coating the positive electrode active material and the negative electrode active material on the The diaphragm can make the ions in the cell pass more smoothly, reduce the internal resistance of the battery, reduce the heat release of the battery during charging and discharging, and improve the safety of the battery; in addition, by combining the positive active material and negative active material The materials are all coated on the diaphragm, which makes it easier to bond and fix the negative electrode sheet and the diaphragm, improves the stability of the battery structure, and increases the battery life.

为更清楚地阐述本发明的结构特征、技术手段及其所达到的具体目的和功能,下面结合附图与具体实施例来对本发明作进一步详细说明:In order to more clearly illustrate the structural features, technical means and the specific objectives and functions achieved by the present invention, the present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments:

附图说明Description of drawings

图1是本发明之实施例的电芯截面示意图。FIG. 1 is a schematic cross-sectional view of an electric core according to an embodiment of the present invention.

附图标识说明:Explanation of the accompanying drawings:

1、负极片, 2、隔膜, 3、正极片,1. Negative plate, 2. Diaphragm, 3. Positive plate,

4、负极活性材料, 5、正极活性材料。4. Negative active material, 5. Positive active material.

具体实施方式detailed description

如图1所示,一种柔性电池,包括由正极、负极和隔离正负极的隔膜2卷绕而成的电芯,所述正极包括未被正极活性材料涂覆的正极片3,所述负极包括未被负极活性材料涂覆的负极片1,所述隔膜2朝向负极片1的一侧表面涂覆有负极活性材料4,朝向正极片3的另一侧表面涂覆有正极活性材料5。所述正极活性材料5的涂覆厚度为50-500μm,涂覆面密度为20-400g/m2;所述负极活性材料4的涂覆厚度为50-500μm,涂覆面密度为20-400g/m2。所述正极片3与隔膜2之间设有正极粘结层,所述负极片1与隔膜2之间设有负极粘结层。As shown in Fig. 1, a kind of flexible battery comprises the electric core that is wound by positive electrode, negative electrode and separator 2 separating positive and negative electrodes, and described positive electrode includes the positive electrode sheet 3 that is not coated with positive electrode active material, and described The negative pole includes a negative electrode sheet 1 that is not coated with the negative electrode active material, the surface of the separator 2 facing the negative electrode sheet 1 is coated with the negative electrode active material 4, and the surface of the other side facing the positive electrode sheet 3 is coated with the positive electrode active material 5 . The coating thickness of the positive electrode active material 5 is 50-500 μm, and the coating surface density is 20-400 g/m 2 ; the coating thickness of the negative electrode active material 4 is 50-500 μm, and the coating surface density is 20-400 g/m 2 . A positive electrode bonding layer is provided between the positive electrode sheet 3 and the separator 2 , and a negative electrode bonding layer is provided between the negative electrode sheet 1 and the separator 2 .

本发明中,所述正极片3为铝箔,所述负极片1为铜箔,所述正极活性材料5为钴酸锂,所述负极活性材料4为石墨。In the present invention, the positive electrode sheet 3 is aluminum foil, the negative electrode sheet 1 is copper foil, the positive electrode active material 5 is lithium cobaltate, and the negative electrode active material 4 is graphite.

综上所述,本发明通过将正极活性材料和负极活性材料均涂覆于隔膜上,隔膜比正极片及负极片更加柔软,使电芯更容易卷绕成型,有利于将电池做得更薄、更软,适于做成柔性电池,适于在可穿戴电子设备上使用;同时,通过将正极活性材料和负极活性材料均涂覆于隔膜上,避免了正极片和负极片弯曲时正极活性材料和负极活性材料打破脱落的情况,从而提高了电芯性能的稳定性,提高了电池质量;而且将正极活性材料和负极活性材料涂覆于隔膜上可使得电芯内的离子通过效果更加流畅,降低了电池内部的电阻,降低了电池在充放电过程中的放热量,提高了电池的安全性;另外,通过将正极活性材料和负极活性材料均涂覆于隔膜上,使得负极片与隔膜更加容易粘结固定,提高了电池结构的稳定性,增加了电池寿命。In summary, the present invention coats both the positive electrode active material and the negative electrode active material on the separator, and the separator is softer than the positive electrode sheet and the negative electrode sheet, so that the battery core is easier to be wound and formed, which is conducive to making the battery thinner , softer, suitable for making flexible batteries, and suitable for use on wearable electronic devices; at the same time, by coating both the positive active material and the negative active material on the separator, the positive electrode activity when the positive electrode sheet and the negative electrode sheet are bent is avoided. Materials and negative active materials break the shedding situation, thereby improving the stability of battery performance and improving battery quality; and coating the positive active material and negative active material on the separator can make the ions in the battery pass through more smoothly , which reduces the internal resistance of the battery, reduces the heat release of the battery during charging and discharging, and improves the safety of the battery; in addition, by coating both the positive electrode active material and the negative electrode active material on the separator, the negative electrode sheet and the separator It is easier to bond and fix, which improves the stability of the battery structure and increases the battery life.

以上所述,仅是本发明的较佳实施例而已,并不用以限制本发明,故凡是依据本发明的技术实际对以上实施例所作的任何修改、等同替换、改进等,均仍属于本发明技术方案的范围内。The above are only preferred embodiments of the present invention, and are not intended to limit the present invention, so any modifications, equivalent replacements, improvements, etc. made to the above embodiments according to the technology of the present invention still belong to the present invention within the scope of the technical program.

Claims (7)

1.一种柔性电池,其特征在于:包括由正极、负极和隔离正负极的隔膜卷绕而成的电芯,所述正极包括未被正极活性材料涂覆的正极片,所述负极包括未被负极活性材料涂覆的负极片,所述隔膜朝向负极片的一侧表面涂覆有负极活性材料,朝向正极片的另一侧表面涂覆有正极活性材料。1. A kind of flexible battery, it is characterized in that: comprise the electric core that is wound by the separator of positive pole, negative pole and isolation positive and negative pole, described positive pole comprises the positive pole sheet that is not coated with positive pole active material, and described negative pole comprises For the negative electrode sheet not coated with the negative electrode active material, the surface of the separator facing the negative electrode sheet is coated with the negative electrode active material, and the surface of the other side facing the positive electrode sheet is coated with the positive electrode active material. 2.根据权利要求1所述的柔性电池,其特征在于:所述正极活性材料的涂覆厚度为50-500μm,涂覆面密度为20-400g/m2;所述负极活性材料的涂覆厚度为50-500μm,涂覆面密度为20-400g/m22. The flexible battery according to claim 1, characterized in that: the coating thickness of the positive electrode active material is 50-500 μm, and the coating surface density is 20-400 g/m 2 ; the coating thickness of the negative electrode active material is 50-500μm, coating area density 20-400g/m 2 . 3.根据权利要求2所述的柔性电池,其特征在于:所述正极片与隔膜之间设有正极粘结层,所述负极片与隔膜之间设有负极粘结层。3 . The flexible battery according to claim 2 , wherein a positive electrode bonding layer is provided between the positive electrode sheet and the separator, and a negative electrode bonding layer is provided between the negative electrode sheet and the separator. 4 . 4.根据权利要求1所述的柔性电池,其特征在于:所述正极片为铝箔。4. The flexible battery according to claim 1, wherein the positive electrode sheet is aluminum foil. 5.根据权利要求1所述的柔性电池,其特征在于:所述负极片为铜箔。5. The flexible battery according to claim 1, wherein the negative electrode sheet is copper foil. 6.根据权利要求1或2所述的柔性电池,其特征在于:所述正极活性材料为钴酸锂。6. The flexible battery according to claim 1 or 2, wherein the positive electrode active material is lithium cobalt oxide. 7.根据权利要求1或2所述的柔性电池,其特征在于:所述负极活性材料为石墨。7. The flexible battery according to claim 1 or 2, wherein the negative electrode active material is graphite.
CN201610524733.4A 2016-07-05 2016-07-05 Flexible battery Pending CN105977543A (en)

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CN109638357A (en) * 2018-11-23 2019-04-16 浙江衡远新能源科技有限公司 A kind of integrated preparation method of electrodes of lithium-ion batteries/diaphragm
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CN114243219A (en) * 2021-11-11 2022-03-25 成都市银隆新能源有限公司 A kind of multifunctional composite diaphragm and preparation method thereof

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CN109804486A (en) * 2016-10-11 2019-05-24 世倍特集团有限责任公司 Method for producing a lithium-ion galvanic cell and lithium-ion galvanic cell
CN109804486B (en) * 2016-10-11 2022-04-15 世倍特集团有限责任公司 Method for producing a lithium-ion galvanic cell and lithium-ion galvanic cell
CN106410266A (en) * 2016-10-28 2017-02-15 珠海市鹏辉电池有限公司 Ultra-thin lithium ion battery and preparation method thereof
CN108232110A (en) * 2017-02-21 2018-06-29 深圳市格瑞普电池有限公司 Laminated lithium ion battery and its pole piece
CN109638357A (en) * 2018-11-23 2019-04-16 浙江衡远新能源科技有限公司 A kind of integrated preparation method of electrodes of lithium-ion batteries/diaphragm
CN111208136A (en) * 2020-01-16 2020-05-29 东莞维科电池有限公司 Method and device for on-line checking orientation of coating diaphragm
CN114243219A (en) * 2021-11-11 2022-03-25 成都市银隆新能源有限公司 A kind of multifunctional composite diaphragm and preparation method thereof

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