CN106256346A - A kind of transparent type Vitamin E acetate dry powder and preparation method thereof - Google Patents
A kind of transparent type Vitamin E acetate dry powder and preparation method thereof Download PDFInfo
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- CN106256346A CN106256346A CN201510331044.7A CN201510331044A CN106256346A CN 106256346 A CN106256346 A CN 106256346A CN 201510331044 A CN201510331044 A CN 201510331044A CN 106256346 A CN106256346 A CN 106256346A
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- 239000000843 powder Substances 0.000 title claims abstract description 49
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 title claims abstract description 36
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229940042585 tocopherol acetate Drugs 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title abstract description 17
- 239000006185 dispersion Substances 0.000 claims abstract description 27
- 239000007788 liquid Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 235000013361 beverage Nutrition 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 11
- 235000015203 fruit juice Nutrition 0.000 claims abstract description 8
- 235000013616 tea Nutrition 0.000 claims abstract description 8
- 235000020535 bottled fortified water Nutrition 0.000 claims abstract description 7
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 7
- 235000015110 jellies Nutrition 0.000 claims abstract description 7
- 239000008274 jelly Substances 0.000 claims abstract description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000011496 sports drink Nutrition 0.000 claims abstract description 6
- 239000001692 EU approved anti-caking agent Substances 0.000 claims abstract description 5
- 239000008346 aqueous phase Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 12
- 239000012071 phase Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 11
- 229930006000 Sucrose Natural products 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 230000001804 emulsifying effect Effects 0.000 claims description 8
- 239000005720 sucrose Substances 0.000 claims description 8
- 125000005456 glyceride group Chemical group 0.000 claims description 7
- 241000196324 Embryophyta Species 0.000 claims description 6
- 108010010803 Gelatin Proteins 0.000 claims description 6
- 229920002774 Maltodextrin Polymers 0.000 claims description 6
- 239000005913 Maltodextrin Substances 0.000 claims description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 6
- 229920000159 gelatin Polymers 0.000 claims description 6
- 239000008273 gelatin Substances 0.000 claims description 6
- 235000019322 gelatine Nutrition 0.000 claims description 6
- 235000011852 gelatine desserts Nutrition 0.000 claims description 6
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 6
- 229940035034 maltodextrin Drugs 0.000 claims description 6
- 229920000881 Modified starch Polymers 0.000 claims description 5
- 239000004368 Modified starch Substances 0.000 claims description 5
- 235000019426 modified starch Nutrition 0.000 claims description 5
- -1 sucrose Fatty acid ester Chemical class 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 4
- 235000010489 acacia gum Nutrition 0.000 claims description 3
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 3
- 235000019359 magnesium stearate Nutrition 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- 229920000136 polysorbate Polymers 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- UVGUPMLLGBCFEJ-SWTLDUCYSA-N sucrose acetate isobutyrate Chemical compound CC(C)C(=O)O[C@H]1[C@H](OC(=O)C(C)C)[C@@H](COC(=O)C(C)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(=O)C(C)C)[C@@H](OC(=O)C(C)C)[C@H](OC(=O)C(C)C)[C@@H](COC(C)=O)O1 UVGUPMLLGBCFEJ-SWTLDUCYSA-N 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 229910003978 SiClx Inorganic materials 0.000 claims 1
- 239000008041 oiling agent Substances 0.000 claims 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 28
- 239000000243 solution Substances 0.000 description 23
- 239000000047 product Substances 0.000 description 15
- 239000003921 oil Substances 0.000 description 14
- 229930003427 Vitamin E Natural products 0.000 description 12
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 12
- 229940046009 vitamin E Drugs 0.000 description 12
- 239000011709 vitamin E Substances 0.000 description 12
- 235000019165 vitamin E Nutrition 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 7
- 238000001694 spray drying Methods 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000005352 clarification Methods 0.000 description 5
- 239000003595 mist Substances 0.000 description 5
- CBHOWTTXCQAOID-UHFFFAOYSA-L sodium ethane formaldehyde mercury(2+) molecular iodine 2-sulfidobenzoate Chemical compound [Na+].[Hg++].C[CH2-].II.C=O.[O-]C(=O)c1ccccc1[S-] CBHOWTTXCQAOID-UHFFFAOYSA-L 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 229930003799 tocopherol Natural products 0.000 description 5
- 229960001295 tocopherol Drugs 0.000 description 5
- 239000011732 tocopherol Substances 0.000 description 5
- 235000010384 tocopherol Nutrition 0.000 description 5
- 229940088594 vitamin Drugs 0.000 description 5
- 229930003231 vitamin Natural products 0.000 description 5
- 235000013343 vitamin Nutrition 0.000 description 5
- 239000011782 vitamin Substances 0.000 description 5
- 150000003722 vitamin derivatives Chemical class 0.000 description 5
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003094 microcapsule Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000002242 deionisation method Methods 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229920001661 Chitosan Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 235000021466 carotenoid Nutrition 0.000 description 2
- 150000001747 carotenoids Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- 206010003591 Ataxia Diseases 0.000 description 1
- 201000001320 Atherosclerosis Diseases 0.000 description 1
- 201000003883 Cystic fibrosis Diseases 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000371 Esterases Proteins 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 208000007536 Thrombosis Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 235000021185 dessert Nutrition 0.000 description 1
- 235000015872 dietary supplement Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 210000000232 gallbladder Anatomy 0.000 description 1
- 210000004392 genitalia Anatomy 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- DKXULEFCEORBJK-UHFFFAOYSA-N magnesium;octadecanoic acid Chemical compound [Mg].CCCCCCCCCCCCCCCCCC(O)=O DKXULEFCEORBJK-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000007170 pathology Effects 0.000 description 1
- 235000011185 polyoxyethylene (40) stearate Nutrition 0.000 description 1
- 239000001194 polyoxyethylene (40) stearate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229940083466 soybean lecithin Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Non-Alcoholic Beverages (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Medicinal Preparation (AREA)
Abstract
The present invention relates to a kind of transparent type Vitamin E acetate dry powder and preparation method thereof, described dry powder includes vitamin E acetate 1～20 weight %, wall material 20～80 weight %, emulsifying agent 5～30 weight %, anticaking agents 0.5～2 weight %.The dry powder of the present invention can be dispersed in water, and the transparent shape of dispersion liquid formed after dispersion, can apply to fortified water, tea beverage, instant beverage, sports drink, fruit juice, fruit jelly, soda pop, drinks etc. in the high beverage of transparency requirement and product, expand the range of application of Vitamin E acetate.
Description
Technical field
The present invention relates to a kind of transparent type dry powder, particularly relate to a kind of transparent type vitamin
The preparation method of E acetate dry powder.
Background technology
Vitamin E, also known as tocopherol, is a kind of fatty antioxidant, is the one of needed by human
Plant nutritional labeling, there is normal function and the homergy of muscle maintaining genitals, people
Internal have antioxidation, elimination free radical, the effect of protection cell membrane, prevents bad cholesterol
LDL aoxidizes and prevents to be formed the blood clot of blocking tremulous pulse.The E that is deficient in vitamin can cause tremulous pulse
The diseases such as atherosclerosis, ataxia, gallbladder cystic fibrosis.Along with threpsology grinds with pathology
That studies carefully gos deep into, and the more New function of vitamin E is constantly found and obtain research to confirm.People
The most increasing to the demand of vitamin E, its effect the most increasingly by the weight of people
Depending on.The most extensively it is applied in health product, food additive, medicine and cosmetics.
Free tocopherol extremely unstable, in conditions such as oxygen, free radical, light and heat, metals
The most oxidized, free tocopherol is esterified, its activity antioxidant groups by with acid
In conjunction with being protected, under esterase in intestinal, the effect of hydrolytic enzyme, again discharge free
Tocopherol, play antioxidation.The esterified form of tocopherol has acetate and succinate,
Relative to vitamin E, its stability is higher, can be used for supplementary, health product and food
In additive.
For the ease of transport, convenient application, by fat-soluble Vitamin E acetate by micro-glue
Capsule technology, use the macromole such as modified starch, gelatin or arabic gum as wall material, through spraying
It is dried and is prepared as a kind of powder with certain fluidity.Presently relevant research is as follows:
Patent CN200810242671.3 proposes the preparation side of a kind of Vitamin E contained micro capsule
Method, with chitosan and maltodextrin for wall material, is compound with soybean lecithin and Tween-80
Emulsifying agent, by high-pressure emulsification and centrifugal spray drying technology, prepares the vitamin of powder
E microcapsule product.The method uses chitosan and maltodextrin to be wall material, with low cost, produces
Product can be applicable in bread, dessert, Biscuits food and the beverage the highest to transparency requirement.
Patent CN200910305454.9 proposes a kind of vitamin E powder and preparation method thereof,
It is to use microencapsulation technology that vitamin E oil embedding is made microcapsule, embeds described vitamin
The wall material of E oil is maltodextrin and gelatin.The fuel load of this product is high, is highly soluble in water, but
The highest to the transparency requirement of its aqueous solution.
Patent CN201010151522.3 proposes a kind of gravity Method and prepares nano vitamin E
The method of water dispersing powder preparation.This powder preparation can disperse rapidly in water, forms stability
The vitamin E emulsion good, transparency is high, can be applicable in the beverage higher to transparency requirement.
But this technique adds methanol, ethanol or the isopropanol solvent as vitamin E quintessence oil,
The residue problem of solvent makes product be subject to certain restrictions in application aspect.
Patent CN201380018558.6 discloses the system of the carotenoid liquid of a kind of clarification
Agent and the beverage of the clarification containing described preparation, it is proposed that " liquid preparation of clarification " refers to it
The liquid preparation deionized water dilution of invention makes the concentration of carotenoid be 10ppm, then
Initial haze≤30NTU, preferably initial haze≤25NTU, more preferably initial haze
≤ 20NTU, most preferably initial haze≤15NTU.Its turbidity does not reaches requirement.
In view of the shortcoming of above disclosure invention is with not enough, the present invention utilizes the vitamin of good stability
E acetate, as active component, selects solvent-free raw material, is divided by super-voltage micro jet nanometer
Scattered technology makes the particle diameter of emulsion more carefully, is spray-dried prepared transparent type Vitamin E acetate and does
Powder.The transparent type Vitamin E acetate dry powder of the present invention, its aqueous dispersions concentration is
120ppm, turbidity≤30NTU, the turbidity scope report that current like product is not correlated with, just
The liquid preparation of published clarification compares, and the present invention has obvious advantage, i.e. moisture
Dissipating liquid concentration high, the transparency is good.Present invention process is simple, materials safety, and the dry powder of preparation is full
The requirement to transparency such as the foot beverage etc., can apply to fortified water, tea beverage, instant beverage,
The products high to transparency requirement such as sports drink, fruit juice, fruit jelly, soda pop, drinks
In product.
Summary of the invention
The technical problem that present invention mainly solves there is provided a kind of transparent type Vitamin E acetate
The preparation method of dry powder, and dry powder dispersion transparent shape in water, can as nutrition enhancer,
It is applied to fortified water, tea beverage, instant beverage, sports drink, fruit juice, fruit jelly, carbonic acid drink
Material, drinks etc. are in the high beverage of transparency requirement and product.
A kind of transparent type Vitamin E acetate dry powder of the present invention includes vitamin E acetate 1～20
Weight %, wall material 20～80 weight %, emulsifying agent 5～30 weight %, anticaking agents 0.5～2
Weight %.
In the preferred technical solution of the present invention, described wall material is gelatin, modified starch, Arab
One or more in glue, sucrose and maltodextrin.
In the preferred technical solution of the present invention, described emulsifying agent is sucrose fatty acid ester, the acid of pungent certain herbaceous plants with big flowers
Glyceride, Sucrose acetoisobutyrate, tween, polyoxyethylene (40) stearate, Fructus Citri Limoniae
At least one in acid fatty glyceride, single diglyceride and span.
In the preferred technical solution of the present invention, described anticaking agents is in silicon dioxide and magnesium stearate
At least one.
Present invention also offers the preparation method bag of a kind of transparent type Vitamin E acetate dry powder
Include following steps: prepared by (1) aqueous phase: weigh wall material and emulsifying agent by proportioning, add water,
Stirring and dissolving at a temperature of 50～80 DEG C；(2) prepared by oil phase: by proportioning weigh vitamin E acetate and
Emulsifying agent, stirring and dissolving at a temperature of 70～90 DEG C；(3) step (1) and (2) are made
Standby solution carries out emulsifying, obtains a kind of finely dispersed emulsion；(4) by step (3)
The emulsion prepared carries out nano-dispersed through super-voltage micro jet nano-dispersed instrument, to prepare more
Thin emulsion；And emulsion prepared by step (4) is spray-dried by (5), obtain one
Plant the powdered substance with certain fluidity.
In the preferred technical solution of the present invention, in step (1), amount of water is wall material and emulsifying
1～3 times of agent, dissolution time be 20～60 minutes.
In the preferred technical solution of the present invention, in step (2), dissolution time is 5～10 points
Clock.
In the preferred technical solution of the present invention, in step (4), super-voltage micro jet is used to receive
Rice separating apparatus carries out nano-dispersed, and pressure is 100MPa～200MPa.
In the preferred technical solution of the present invention, in step (5), the air intake of described spray drying
Temperature 160～200 DEG C, leaving air temp 70～100 DEG C.
Additionally, invention further provides a kind of transparent type Vitamin E acetate dry powder by force
Change water, tea beverage, instant beverage, sports drink, fruit juice, fruit jelly, soda pop, function
Application on beverage, the dry powder of described transparent type Vitamin E acetate is dispersed in water,
The transparent shape of aqueous dispersions, concentration is 120ppm, turbidity≤30NTU.
Beneficial effects of the present invention is as follows: after the dispersion of existing vitamin E dry powder rehydration, its water
Dispersion liquid typically has certain turbidity, at fortified water, tea beverage, instant beverage and fruit juice etc.
Application be restricted；And the transparent type Vitamin E acetate dry powder rehydration dispersion of the present invention
After, the transparent shape of its aqueous dispersions, can be in fortified water, tea beverage, instant beverage, motion
Beverage, fruit juice, fruit jelly, soda pop, drinks etc. to the high beverage of transparency requirement and
Applying in product, range is expanded.
Relative to prior art, present invention have an advantage that 1) fatsoluble vitamin E acetic acid
Ester is prepared as the dry powder of water dispersible by microcapsule technology, it is simple to transports, conveniently use；2)
Using super-voltage micro jet nano-dispersed technology to disperse in preparation process, emulsion is thinner more
Homogeneous；3) the dry powder aqueous dispersions concentration that prepared by the present invention reaches 120ppm, turbidity≤30NTU.
The turbidity scope report that like product is not correlated with at present, with regard to the liquid preparation of published clarification
Comparing, it is high that the present invention has obvious advantage, i.e. aqueous dispersions concentration, and the transparency is good；
4), during product of the present invention can be applied not only to health product, dietary supplement, food, also may be used
Be widely used in fortified water, tea beverage, instant beverage, sports drink, fruit juice, fruit jelly,
Soda pop, drinks etc. are in the high beverage of transparency requirement and product, and range of application is more
Extensively.
Detailed description of the invention
Below in conjunction with instantiation, further illustrate the present invention, but the present invention not office
Limit is in the examples below that.
Embodiment 1
Prepared by aqueous phase: weigh arabic gum 40g, sucrose 19.5g, polysorbas20 g, adds 150ml
Water, 70 DEG C dissolve 40 minutes, are prepared into aqueous phase solution；
Prepared by oil phase: weigh Vitamin E acetate oil 10g, pungent certain herbaceous plants with big flowers acid glyceride 10g, 85 DEG C
Dissolve 6 minutes；
The aqueous phase solution prepared and oil-phase solution are carried out emulsifying, obtains finely dispersed emulsus
Liquid；
Dispersion condition is: use the super-voltage micro jet nano-dispersed that MFIC company of the U.S. produces
Instrument M-110S, under conditions of pressure is 100MPa, carries out nano-dispersed；
It is spray-dried: the inlet temperature of spray drying is 180 DEG C, and leaving air temp is 75 DEG C, spray
Mist is dried to obtain transparent type Vitamin E acetate dry powder, adds the tristearin of dry powder weight 0.5%
Acid magnesium.
Weigh 30mg Vitamin E acetate dry powder in 25mL volumetric flask, add deionization
After water-dispersible, being settled to scale, dispersion liquid concentration is 120ppm, records its turbidity and is
26.5NTU, dispersion liquid clear appearance is transparent.
Embodiment 2
Prepared by aqueous phase: weigh modified starch 45g, maltodextrin 17g, tween 12g, adds
100ml water, 75 DEG C dissolve 50 minutes, are prepared into aqueous phase solution；
Prepared by oil phase: weigh Vitamin E acetate oil 15g, pungent certain herbaceous plants with big flowers acid glyceride 9g, 80 DEG C
Dissolve 8 minutes；
The aqueous phase solution prepared and oil-phase solution are carried out emulsifying, obtains finely dispersed emulsus
Liquid；
Dispersion condition is: use the super-voltage micro jet nano-dispersed that MFIC company of the U.S. produces
Instrument M-110S carries out nano-dispersed under conditions of pressure is 150MPa；
It is spray-dried: the inlet temperature of spray drying is 180 DEG C, and leaving air temp is 80 DEG C, spray
Mist is dried to obtain transparent type Vitamin E acetate dry powder, adds the stearic acid of dry powder weight 2%
Magnesium.
Weigh 20.0mg Vitamin E acetate dry powder in 25mL volumetric flask, add go from
After son is water-dispersible, being settled to scale, dispersion liquid concentration about 120ppm, recording its turbidity is
27.4NTU, dispersion liquid clear appearance is transparent.
Embodiment 3
Prepared by aqueous phase: weigh gelatin 20g, sucrose 44g, span 12g, adds 200ml water,
70 DEG C dissolve 60 minutes, are prepared into aqueous phase solution；
Prepared by oil phase: weigh Vitamin E acetate oil 18g, single diglyceride 5g, 80 DEG C
Dissolve 10 minutes；
The aqueous phase solution prepared and oil-phase solution are carried out emulsifying, obtains finely dispersed emulsus
Liquid；
Dispersion condition is: use the super-voltage micro jet nano-dispersed that MFIC company of the U.S. produces
Instrument M-110S carries out nano-dispersed under conditions of pressure is 135MPa；
It is spray-dried: the inlet temperature of spray drying is 185 DEG C, and leaving air temp is 75 DEG C, spray
Mist is dried to obtain transparent type Vitamin E acetate dry powder, adds the stearic acid of dry powder weight 1%
Magnesium.
Weigh 16.67mg Vitamin E acetate dry powder in 25mL volumetric flask, add go from
After son is water-dispersible, it is settled to scale, dispersion liquid concentration about 120ppm, record the turbid of aqueous solution
Degree is 24.4NTU, and dispersion liquid clear appearance is transparent.
Embodiment 4:
Prepared by aqueous phase: weigh gelatin 30g, sucrose 40g, span 10g, adds 150ml water,
65 DEG C dissolve 45 minutes, are prepared into aqueous phase solution；
Prepared by oil phase: weigh Vitamin E acetate oil 10g, single diglyceride 3g, Xin Kui
Acid glyceride 5g, 80 DEG C dissolve 7 minutes；
The aqueous phase solution prepared and oil-phase solution are carried out emulsifying, obtains finely dispersed emulsus
Liquid；
Dispersion condition is: use the super-voltage micro jet nano-dispersed that MFIC company of the U.S. produces
Instrument M-110S carries out nano-dispersed under conditions of pressure is 155MPa；
It is spray-dried: the inlet temperature of spray drying is 190 DEG C, and leaving air temp is 75 DEG C, spray
Mist is dried to obtain transparent type Vitamin E acetate dry powder, adds dry powder weight 1% magnesium stearate
With 1% silicon dioxide.
Weigh 30mg Vitamin E acetate dry powder in 25mL volumetric flask, add deionization
After water-dispersible, it is settled to scale, dispersion liquid concentration about 120ppm, record the turbidity of aqueous solution
For 25.7NTU, dispersion liquid clear appearance is transparent.
Embodiment 5:
Prepared by aqueous phase: weigh modified starch 40g, sucrose 35g, span 10g, adds 140ml
Water, 65 DEG C dissolve 45 minutes, are prepared into aqueous phase solution；
Prepared by oil phase: weigh Vitamin E acetate oil 10g, single diglyceride 4g, 85 DEG C
Dissolve 6 minutes；
The aqueous phase solution prepared and oil-phase solution are carried out emulsifying, obtains finely dispersed emulsus
Liquid；
Dispersion condition is: use the super-voltage micro jet nano-dispersed that MFIC company of the U.S. produces
Instrument M-110S carries out nano-dispersed under conditions of pressure is 140MPa；
It is spray-dried: the inlet temperature of spray drying is 175 DEG C, and leaving air temp is 85 DEG C, spray
Mist is dried to obtain transparent type Vitamin E acetate dry powder, adds dry powder weight 0.2% stearic acid
Magnesium and 0.8% silicon dioxide.
Weigh 30mg Vitamin E acetate dry powder in 25mL volumetric flask, add deionization
After water-dispersible, it is settled to scale, dispersion liquid concentration about 120ppm, record the turbidity of aqueous solution
For 25.7NTU, dispersion liquid clear appearance is transparent.
Embodiment 6-9:
Embodiment 6-9 is that the condition of according to the form below 1 respectively is prepared as Vitamin E acetate dry powder,
Table 1 below (embodiment 6-9 experimental condition and result):
Table 1
It is described above the detailed description of the invention of the present invention, but common skill in the art
Art personnel are it is understood that in the case of without departing from the spirit and scope of the present invention, it is also possible to this
The detailed description of the invention of invention makees various change and replacement, and these changes and replacement all fall at this
In the range of bright claims limit.
Claims (10)
1. the dry powder of a transparent type Vitamin E acetate, it is characterised in that described dry powder
Including vitamin E acetate 1～20 weight %, wall material 20～80 weight %, emulsifying agent 5～30 weight
Amount %, anticaking agents 0.5～2 weight %.
2. dry powder as claimed in claim 1, it is characterised in that described wall material be gelatin,
One or more in modified starch, arabic gum, sucrose and maltodextrin.
3. dry powder as claimed in claim 1, it is characterised in that described emulsifying agent is sucrose
Fatty acid ester, pungent certain herbaceous plants with big flowers acid glyceride, Sucrose acetoisobutyrate, tween, polyoxyethylene (40)
At least one in stearate, citric acid fatty glyceride, single diglyceride and span.
4. dry powder as claimed in claim 1, it is characterised in that described anticaking agents is dioxy
At least one in SiClx and magnesium stearate.
5. the method preparing dry powder as described in Claims 1 to 4 is arbitrary, its feature exists
In, said method comprising the steps of:
(1) prepared by aqueous phase: weigh wall material and emulsifying agent by proportioning, adds water, at 50～80 DEG C
At a temperature of stirring and dissolving；
(2) prepared by oil phase: weigh Vitamin E acetate oil and emulsifying agent by proportioning, 70～
Stirring and dissolving at a temperature of 90 DEG C；
(3) solution prepared by step (1) and (2) is carried out emulsifying, obtain a kind of dispersion
Uniform emulsion；
(4) emulsion that step (3) prepares is entered through super-voltage micro jet nano-dispersed instrument
Row nano-dispersed, to prepare thinner emulsion；And
(5) emulsion prepared by step (4) is spray-dried, obtains one and have necessarily
The powdered substance of mobility.
6. method as claimed in claim 5, it is characterised in that in step (1), add water
Amount is wall material and 1～3 times of emulsifying agent, dissolution time is 20～60 minutes.
7. method as claimed in claim 5, it is characterised in that in step (2), dissolve
Time is 5～10 minutes.
8. method as claimed in claim 5, it is characterised in that in step (4), use
Super-voltage micro jet nano-dispersed instrument carries out nano-dispersed, and pressure is 100MPa～200MP.
9. method as claimed in claim 5, it is characterised in that in step (5), described
Be spray-dried inlet temperature 160～200 DEG C, leaving air temp 70～100 DEG C.
10. the dry powder as described in Claims 1 to 4 is arbitrary is in fortified water, tea beverage, speed
Application on molten beverage, sports drink, fruit juice, fruit jelly, soda pop, drinks, its
Being characterised by, the dry powder of described transparent type Vitamin E acetate is dispersed in water, moisture
Dissipating the transparent shape of liquid, concentration is 120ppm, turbidity≤30NTU.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109588697A (en) * | 2017-09-30 | 2019-04-09 | 江苏正大丰海制药有限公司 | A kind of oral complete nutritional composition |
| WO2019169167A1 (en) * | 2018-03-01 | 2019-09-06 | 463Ip Partners, Llc | Microencapsulated products, clear solutions thereof, and methods of making |
| CN110313523A (en) * | 2019-07-17 | 2019-10-11 | 南江县太子洞食品有限公司 | A kind of production method of ultra micro hedgehog hydnum mushroom powder bean curd cheese |
| CN110537654A (en) * | 2019-09-20 | 2019-12-06 | 贵州山环菌草科技有限公司 | A kind of preparation method of tea tree mushroom beverage |
| RU2807066C2 (en) * | 2018-03-01 | 2023-11-09 | 463АйПи ПАРТНЕРС, ЭлЭлСи | Microencapsulated products, their clear solutions and production methods |
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| CN1197558C (en) * | 1998-06-24 | 2005-04-20 | Dsmip资产有限公司 | Vitamin powder for beverage |
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| CN1197558C (en) * | 1998-06-24 | 2005-04-20 | Dsmip资产有限公司 | Vitamin powder for beverage |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109588697A (en) * | 2017-09-30 | 2019-04-09 | 江苏正大丰海制药有限公司 | A kind of oral complete nutritional composition |
| WO2019169167A1 (en) * | 2018-03-01 | 2019-09-06 | 463Ip Partners, Llc | Microencapsulated products, clear solutions thereof, and methods of making |
| RU2807066C2 (en) * | 2018-03-01 | 2023-11-09 | 463АйПи ПАРТНЕРС, ЭлЭлСи | Microencapsulated products, their clear solutions and production methods |
| AU2019227917B2 (en) * | 2018-03-01 | 2024-08-22 | 463Ip Partners, Llc | Microencapsulated products, clear solutions thereof, and methods of making |
| CN110313523A (en) * | 2019-07-17 | 2019-10-11 | 南江县太子洞食品有限公司 | A kind of production method of ultra micro hedgehog hydnum mushroom powder bean curd cheese |
| CN110537654A (en) * | 2019-09-20 | 2019-12-06 | 贵州山环菌草科技有限公司 | A kind of preparation method of tea tree mushroom beverage |
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Application publication date: 20161228 |