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CN106450513A - Rechargeable type wet battery - Google Patents

Rechargeable type wet battery Download PDF

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Publication number
CN106450513A
CN106450513A CN201610946292.7A CN201610946292A CN106450513A CN 106450513 A CN106450513 A CN 106450513A CN 201610946292 A CN201610946292 A CN 201610946292A CN 106450513 A CN106450513 A CN 106450513A
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CN
China
Prior art keywords
anode
wet cell
barrier film
chargeable
shell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610946292.7A
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Chinese (zh)
Inventor
董亚婵
曾繁寿
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Individual
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Individual
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Application filed by Individual filed Critical Individual
Priority to CN201610946292.7A priority Critical patent/CN106450513A/en
Publication of CN106450513A publication Critical patent/CN106450513A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/36Accumulators not provided for in groups H01M10/05-H01M10/34
    • H01M10/38Construction or manufacture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Primary Cells (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The invention provides a rechargeable type wet battery. The rechargeable type wet battery comprises an outer casing and at least one group of battery elements, wherein each group of battery elements comprises an anode, a cathode and a diaphragm which are sequentially overlapped and packaged into the outer casing; each anode and the corresponding diaphragm, and/or each cathode and the corresponding diaphragm are respectively spaced with a section of distance to form an inner cavity, and an electrolyte is injected into each inner cavity; each anode comprises an alloy layer, and the alloy layer is made from nanometer manganese dioxide. The rechargeable type wet battery provided by the embodiment of the invention has the advantages that the structure is simple, the used materials are common, the energy-saving and environment-friendly effects are realized, the service life is long, and the amount of released energy is large.

Description

A kind of chargeable wet cell
Technical field
The present invention be with regard to battery technology, specifically with regard to a kind of chargeable wet cell.
Background technology
What the world today was with fastest developing speed does not cross digital information and the big technology of clean energy resource two.The birth of fuel cell, be exactly Best illustration.But one-time investment is too big, and the construction period is oversize.Therefore, researching and developing a kind of environmental protection and being easy to circulation makes Battery, is problem demanding prompt solution at present.
Content of the invention
The main purpose of the embodiment of the present invention is to provide a kind of chargeable wet cell, to reduce battery consumption to environment Pollution.
To achieve these goals, the embodiment of the present invention provides a kind of chargeable wet cell, and described wet cell includes: Shell and least one set cell device, wherein, the cell device includes:Anode, negative electrode and barrier film, wherein, the anode, every Film, negative electrode are sequentially overlapped, and are packaged in described shell, also, between the anode and barrier film, and/or negative electrode and barrier film it Between be spaced a distance, to form inner chamber, the inner chamber is in order to inject electrolyte;Described anode includes an alloy-layer, described The material of alloy-layer includes:Nano-manganese dioxide.
In one embodiment, above-mentioned anode also includes:Copper foil layer, copper wire stratum reticulare, the copper foil layer, copper wire stratum reticulare and conjunction Layer gold is sequentially overlapped, and fits together between adjacent two layers.
In one embodiment, above-mentioned anode also includes:Copper Foil stratum reticulare, the Copper Foil stratum reticulare and alloy-layer are sequentially overlapped, Fit together each other.
In one embodiment, the both ends open of above-mentioned shell, when the wet cell is dipped in electrolyte, the electricity Solution liquid is entered in the inner chamber by the opening.
In one embodiment, above-mentioned shell also includes:Two closures, after injecting the electrolyte into the inner chamber, pass through It is open described in the seal cap sealing.
In one embodiment, above-mentioned shell is enclosed construction, to be respectively arranged with inlet on the housing and go out liquid Mouthful, by the inlet and liquid outlet, adjust the capacity of the electrolyte for entering the inner chamber.
In one embodiment, when being all spaced a distance and negative electrode and barrier film between the anode and barrier film, institute The distance between anode and barrier film are stated less than the distance between the anode and barrier film.
In one embodiment, the material of above-mentioned negative electrode is zinc.
The beneficial effect of the embodiment of the present invention is, simple structure, common with material, energy-conserving and environment-protective, long service life, release Energy is big.
Description of the drawings
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, embodiment will be described below Needed for accompanying drawing to be used be briefly described, it should be apparent that, drawings in the following description be only the present invention some Embodiment, for those of ordinary skill in the art, without having to pay creative labor, can also be according to these Accompanying drawing obtains other accompanying drawings.
Figure 1A is the structural representation of the wet cell according to the embodiment of the present invention;
Figure 1B is the profile () according to the wet cell of the embodiment of the present invention along hatching line A-A ';
Fig. 1 C is the top view of the wet cell according to the embodiment of the present invention;
Fig. 2 is the profile (two) according to the wet cell of the embodiment of the present invention along hatching line A-A ';
Fig. 3 is the structural representation of the wet cell according to another embodiment of the present invention;
Fig. 4 is the top view of the wet cell according to another embodiment of the present invention;
Fig. 5 A is the structural representation of the anode 1 according to the embodiment of the present invention;
Fig. 5 B is the structural representation of the anode 1 according to another embodiment of the present invention;
Fig. 6 is the structural representation of the negative electrode 2 according to the embodiment of the present invention;;
Fig. 7 A is the structural representation of the wet cell according to another embodiment of the present invention;
Fig. 7 B is the top view of the wet cell according to another embodiment of the present invention;
The top view of Fig. 7 C wet cell according to another embodiment of the present invention;
Fig. 8 is the battery performance test curve chart of the wet cell according to the embodiment of the present invention.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation is described, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.It is based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made Embodiment, belongs to the scope of protection of the invention.
The embodiment of the present invention provides a kind of chargeable wet cell.Below in conjunction with accompanying drawing, the present invention is described in detail.
As illustrated in figures ia and ib, the wet cell of the embodiment of the present invention mainly includes:Shell 3 and cell device, wherein, should Cell device includes:Anode 1, negative electrode 2 and barrier film 5.
In above-mentioned cell device, its anode 1, barrier film 5, negative electrode 2 are sequentially overlapped, and are packaged in the shell 3, also, should Barrier film 5 is fitted with anode 1, is spaced a distance (as shown in Figure 1B) between barrier film 5 and negative electrode 2;Or, the barrier film 5 with cloudy Pole 2 fits, and is spaced a distance between anode 1 and barrier film 5;Or, be all spaced between anode 1, barrier film 5, negative electrode 2 one section away from From;The inner chamber for defining the wet cell spaced apart, the inner chamber is in order to inject electrolyte.
Also, in embodiments of the present invention, above-mentioned anode 1 includes an alloy-layer 11, the material of the alloy-layer 11 includes: Nano-manganese dioxide.It is that it is possible to make wet cell stable working using the advantage of nano-manganese dioxide, prevents electric current, voltage from going out Now fluctuate, in order to avoid polarization occurs in anode material, but also the resistance that cation is moved in the battery can be reduced.
In actual applications, above-mentioned negative electrode 2 can be made with metallic zinc.It is suitable for doing the cathode material of water battery, both at home and abroad All using magnesium metal and magnesium alloy, this is because magnesium elements are on earth compared with horn of plenty.And the outer electronic structure of magnesium elements For 3S2.In acid, alkali, two electronics are easily lost in the medium such as water, and shows active chemical property, its standard electrode EMF Higher, can reach more than -2.3V.But negative electrode being done with magnesium there is also some shortcomings:
1. magnesium is in water battery, and with the increase of discharge current and the prolongation of discharge time, its rate of dissolution can also increase Plus, reduce the service life of battery;
2. magnesium is in discharge process, and also one side effect, is exactly to be piled into Mg (OH) between electrodes2Dirt Mud, hinders the electro-ionic exchange between two electrodes.Therefore, the life-span of water battery also just terminates.Although some benefits can be taken Rescue measure, but limited success, and cost increases, manufacture difficulty is also increased.
For these reasons, in embodiments of the present invention, be using zinc as cathode material.Although negative electrode is done with zinc, its Output voltage only has 1V or so, and zinc also has side reaction generation, but as long as taking some simple measure, you can mitigate or keep away Exempt from Zn (OH) occur2.In this way, the life-span of water battery can be not only extended, can be more to make water battery charge repeatedly to carry For advantage.
Specifically, in embodiments of the present invention, be in zinc metal mix 1%~2% Zinc oxide powder, improve electrode Electric conductivity, and make the electric current distribution of electrode uniform.
Also, organosilicon emulsion is coated in type electrode surface, so as to reduce harmful Zn (OH)2Formation.
In actual applications, operationally, its anode material is hardly consumed wet cell, only negative electrode slowly consuming, Negative electrode is changed in good time, and battery is again as excellent as before.So the life-span of wet cell is very long.
In embodiments of the present invention, above-mentioned anode 1 uses nanometer MnO2As main material, account for anode gross weight 80%~ 85%, the high conductive carbon dust of more than 8% 5,000 mesh is added, with a small amount of waterproof glue, above-mentioned material is tuned into pulpous state coating Anode is formed on Copper Foil.
Reaction equation in the wet cell of the embodiment of the present invention is represented by:
Negative pole:
Positive pole:
Total reaction equation:
Barrier film 5 is that one layer of microporous Nylon layer spins cloth, is placed between negative electrode 2 and anode 1.Its effect is to stop electronics Anode 1 being flowed in water, and to positively charged proton, then unobstructed moves towards negative electrode 2.While also functioning to reduce the internal resistance of cell Effect.
In one embodiment, above-mentioned barrier film 5 is that ionic conduction isolating membrane (is insulation to electronics, is to lead to cation Logical).With negative electrode 2 relatively far away from, and 1 relative close of anode, and on shell 3, corresponding to barrier film 5 and negative electrode 2 for the barrier film 5 The lower section of interval location opens up one first hole 31, reacts, in order to exclude negative electrode 2, the impurity for producing.Barrier film 5 is relatively close with anode 2 A bit, and in the lower section of shell one second hole 32 is opened, second hole 32 is greater than first hole 31, is passed in and out with sharp saline, as Fig. 2 institute Show.
The water battery of the application embodiment of the present invention, the charging interval is short, completes once to charge i.e. by only needing a few minutes every time Can complete.Then electric discharge can be continued again.In this way, the Reusability of the chargeable wet cell of the embodiment of the present invention is can achieve, Convenient and swift.
When being embodied as, above-mentioned electrolyte can be pure water, mineral water, soda pop, or even A Muniya (urine) water, The liquid such as Sucus Mali pumilae, Tomato juice, medicated beer, all may be used to generate electricity.In a preferred embodiment, the electrolyte be preferably sea water or Saline containing 6%~6.3%, A Muniya liquid.
It should be noted that the material of the anode 1, negative electrode 2 and barrier film 5 described in above-described embodiment is and illustrates Bright, and and be not used to limit the present invention, in actual applications, can be replaced with corresponding material with condition according to actual needs Change, the present invention is not limited thereto.
Also, only comprising a Battery pack element in the wet cell shown by Figure 1A, but in actual applications, can be according to electricity Pond electricity and the demand of battery volume, arrange two or more groups cell device, by multigroup cell device string in the wet cell Connection or offer electric power in parallel, the present invention is not limited thereto.
The advantage of the wet cell of the embodiment of the present invention is essentially consisted in:Simple structure, common with material, energy-conserving and environment-protective, using the longevity Life length, releases energy big, it is seen then that its advantage is far more than aneroid battery.
Most had a headache as wet cell is electrical leakage problems, such as the voltage of single battery be.Three series connection make With voltage is difficult to rise to 3.3V~4.2V.Therefore, in one embodiment, to the electricity in the wet cell of the embodiment of the present invention The behind of pole (negative electrode, anode) pole piece and four peripheries all coat resistant to saline solution insullac 6, as shown in Figure 3.
Also, draw in the electrode of battery case and anti-creeping groove 7 is provided with, the width of this groove 7 is that reference is international The insulating properties formula of generally acknowledged set of cells outer packageCome designed, its about >=2 millimeters of 7 width of groove.As Fig. 4 and Fig. 7 C Shown.In formula, it is 7 length of groove/cm that R is resistance/Ω, l;A is the cross-sectional area/cm of groove 72;Electricity when ρ is battery operated Solution resistivity/Ω cm.
As shown in Figure 5A, the main body of the anode 1 of the embodiment of the present invention is rectangle, mainly to include:Copper foil layer 13, copper wire stratum reticulare 12 and alloy-layer 11, wherein, copper foil layer 13, copper wire stratum reticulare 12 and alloy-layer 11 are sequentially overlapped, and are fitted in one between adjacent two layers Rise.On the copper foil layer 13, prominent contact is in order to be used as wiring.And the shape of above-mentioned anode 1 is by way of example only, can According to actual needs the shape of anode 1 is adjusted, the present invention is not limited thereto.
In another embodiment, as shown in Figure 5 B, the anode 1 mainly can be made up of Copper Foil stratum reticulare 12a and alloy-layer 11a, Wherein, Copper Foil stratum reticulare 12a and alloy-layer 11a are sequentially overlapped, and fit together each other.Prominent on Copper Foil stratum reticulare 12a Contact in order to be used as wiring.
As shown in fig. 6, the shape of the negative electrode 2 of the embodiment of the present invention is corresponding with anode 1, similarly, the shape of negative electrode 2 is only For illustrating, according to actual needs the shape of negative electrode 2 can be adjusted, the present invention is not limited thereto.
In one embodiment, as shown in Figure 1 C, above-mentioned 3 two ends of shell have opening 4, when wet cell is dipped in electrolyte When middle, electrolyte can be entered in inner chamber by opening 4, infiltrate cell device, so as to promote cell device to generate electricity.
Also, further, can also to should shell 3 arrange two can folding closure, inject the electrolyte into wet electricity After the inner chamber in pond, by the opening of the seal cap sealing shell 3.
In another embodiment, as shown in figs. 7 a and 7b, above-mentioned shell 3 can be hollow sealing structure, hollow bulb Point in order to placing above-mentioned anode 1, barrier film 5 and negative electrode 2, and form inner chamber, also, be also respectively provided with the shell 3 into Liquid mouth 31 and liquid outlet 32, by inlet 31 and liquid outlet 32, controllable enters into the capacity of the electrolyte of inner chamber, adopts this The part that 2 material of negative electrode is melted in power generation process can be taken out of by the mode at any time of kind by flowing out the electrolyte of liquid outlet 32 Inner chamber, is difficult between the two poles of the earth blocked.Therefore electric current to output, voltage ratio are more steady.
As shown in figure 8, be the result tested by the wet cell to the embodiment of the present invention, from test result as can be seen that The open-circuit voltage of single battery is in 1.5V~1.4V or so, and the size of electric current depends on the size of pole-piece area.The capacity of battery Weight depending on pole piece.Activationary time about 1 second, operating ambient temperature is from -30 DEG C~60 DEG C.Total appearance of single wet cell at present Amount is more than 6000 milliamperes/hour through field test, and internal resistance is less than 50 milliohms.
Particular embodiments described above, has been carried out to the purpose of the present invention, technical scheme and beneficial effect further in detail Describe in detail bright, the specific embodiment that the foregoing is only the present invention is should be understood that, the guarantor being not intended to limit the present invention Shield scope, all any modification, equivalent substitution and improvement that within the spirit and principles in the present invention, is done etc., should be included in this Within the protection domain of invention.

Claims (8)

1. a kind of chargeable wet cell, it is characterised in that described wet cell includes:Shell and least one set cell device, Wherein, the cell device includes:Anode, negative electrode and barrier film, wherein,
The anode, barrier film, negative electrode are sequentially overlapped, and are packaged in described shell, also, between the anode and barrier film and/ Or be spaced a distance between negative electrode and barrier film, to form inner chamber, the inner chamber is in order to inject electrolyte;
Described anode includes an alloy-layer, and the material of the alloy-layer includes:Nano-manganese dioxide.
2. chargeable wet cell according to claim 1, it is characterised in that described anode also includes:Copper foil layer, copper Silk screen layer, the copper foil layer, copper wire stratum reticulare and alloy-layer are sequentially overlapped, and fit together between adjacent two layers.
3. chargeable wet cell according to claim 1, it is characterised in that described anode also includes:Copper Foil stratum reticulare, The Copper Foil stratum reticulare and alloy-layer are sequentially overlapped, and fit together each other.
4. chargeable wet cell according to claim 1, it is characterised in that the both ends open of the shell, when by institute When stating wet cell and being dipped in electrolyte, the electrolyte is entered in the inner chamber by the opening.
5. chargeable wet cell according to claim 4, it is characterised in that the shell also includes:Two closures, After injecting the electrolyte into the inner chamber, by being open described in the seal cap sealing.
6. chargeable wet cell according to claim 1, it is characterised in that the shell be enclosed construction, described Inlet and liquid outlet is respectively arranged with shell, by the inlet and liquid outlet, adjusts the electrolysis for entering the inner chamber The capacity of liquid.
7. chargeable wet cell according to claim 1, it is characterised in that when between the anode and barrier film and cloudy When being all spaced a distance between pole and barrier film, the distance between the anode and barrier film are less than between the anode and barrier film Distance.
8. the chargeable wet cell according to any claim in claim 1 to 7, it is characterised in that the negative electrode Material be zinc.
CN201610946292.7A 2016-11-02 2016-11-02 Rechargeable type wet battery Pending CN106450513A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109148937A (en) * 2017-06-16 2019-01-04 北京好风光储能技术有限公司 A kind of lithium slurry battery battery core and lithium slurry battery with support water conservancy diversion cable
WO2025144285A3 (en) * 2023-12-29 2025-07-24 Untes Isitma Klima Sogutma Sanayi Ve Ticaret Anonim Sirketi A method for creating a solid model for a flooded battery

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GB747772A (en) * 1952-07-28 1956-04-11 Olin Mathieson Process for production of manganese metal and chlorine
EP0140312A1 (en) * 1983-10-19 1985-05-08 Rayovac Corporation Organic siliconate additive for alkaline zinc electrochemical cells
US4617242A (en) * 1983-10-19 1986-10-14 Rayovac Corporation Organic siliconate additive for alkaline zinc electrochemical cells
US5340666A (en) * 1991-03-11 1994-08-23 Battery Technologies Inc. Rechargeable alkaline manganese cell having improved capacity and improved energy density
CN1112737A (en) * 1994-03-09 1995-11-29 电池技术公司 High capacity rechargeable cell having manganese dioxide electrode
CA2297932A1 (en) * 1997-07-22 1999-02-04 Rechargeable Battery Corporation Rechargeable battery with modified manganese oxide positive electrode
CN1305235A (en) * 1994-10-21 2001-07-25 佳能株式会社 Positive electrode of charging battery and its manufacturing method
CN2445448Y (en) * 2000-08-08 2001-08-29 徐广利 Large area high discharge rate mercury-free zinc-manganese battery
US20020064710A1 (en) * 1994-05-30 2002-05-30 Soichiro Kawakami Rechargeable batteries
CN1750302A (en) * 2005-09-23 2006-03-22 王荣 Mercury-free zinc-manganese battery with internal and external anodes and manufacturing method thereof
US20060204839A1 (en) * 2004-03-18 2006-09-14 Richards Thomas C Wafer alkaline cell
CN103165918A (en) * 2013-02-06 2013-06-19 安徽省霖丰源机械制造有限公司 Zinc and manganese reserve battery and manufacture method thereof

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB747772A (en) * 1952-07-28 1956-04-11 Olin Mathieson Process for production of manganese metal and chlorine
EP0140312A1 (en) * 1983-10-19 1985-05-08 Rayovac Corporation Organic siliconate additive for alkaline zinc electrochemical cells
US4617242A (en) * 1983-10-19 1986-10-14 Rayovac Corporation Organic siliconate additive for alkaline zinc electrochemical cells
US5340666A (en) * 1991-03-11 1994-08-23 Battery Technologies Inc. Rechargeable alkaline manganese cell having improved capacity and improved energy density
CN1112737A (en) * 1994-03-09 1995-11-29 电池技术公司 High capacity rechargeable cell having manganese dioxide electrode
US20020064710A1 (en) * 1994-05-30 2002-05-30 Soichiro Kawakami Rechargeable batteries
CN1305235A (en) * 1994-10-21 2001-07-25 佳能株式会社 Positive electrode of charging battery and its manufacturing method
CA2297932A1 (en) * 1997-07-22 1999-02-04 Rechargeable Battery Corporation Rechargeable battery with modified manganese oxide positive electrode
CN2445448Y (en) * 2000-08-08 2001-08-29 徐广利 Large area high discharge rate mercury-free zinc-manganese battery
US20060204839A1 (en) * 2004-03-18 2006-09-14 Richards Thomas C Wafer alkaline cell
CN1750302A (en) * 2005-09-23 2006-03-22 王荣 Mercury-free zinc-manganese battery with internal and external anodes and manufacturing method thereof
CN103165918A (en) * 2013-02-06 2013-06-19 安徽省霖丰源机械制造有限公司 Zinc and manganese reserve battery and manufacture method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109148937A (en) * 2017-06-16 2019-01-04 北京好风光储能技术有限公司 A kind of lithium slurry battery battery core and lithium slurry battery with support water conservancy diversion cable
CN109148937B (en) * 2017-06-16 2020-08-04 北京好风光储能技术有限公司 Lithium slurry battery cell with supporting diversion cable and lithium slurry battery
WO2025144285A3 (en) * 2023-12-29 2025-07-24 Untes Isitma Klima Sogutma Sanayi Ve Ticaret Anonim Sirketi A method for creating a solid model for a flooded battery

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Effective date of abandoning: 20231229