CN106768345B - Method based on surface plasma direct measurement vertically polarized light polarization state - Google Patents
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Abstract
本发明涉及一种基于表面等离子体直接测量纵向偏振光偏振态的方法,金属纳米颗粒受到光激发时,其产生的表面等离子体的分布由激发光的偏振态决定。基于这个现象,设计了探测基片,通过观察曝光后探测基片记录层上的图案来判断激发光的偏振态。实现了对纵向偏振光的纵向偏振态的直接测量,这是目前其他偏振测量方法无法实现的;测量方法简单有效,容易实施。
The invention relates to a method for directly measuring the polarization state of longitudinally polarized light based on surface plasmons. When metal nanoparticles are excited by light, the distribution of surface plasmons generated by the metal nanoparticles is determined by the polarization state of the excitation light. Based on this phenomenon, a detection substrate is designed, and the polarization state of the excitation light can be judged by observing the pattern on the recording layer of the detection substrate after exposure. The direct measurement of the longitudinal polarization state of the longitudinally polarized light is realized, which cannot be realized by other current polarization measurement methods; the measurement method is simple, effective and easy to implement.
Description
技术领域technical field
本发明涉及一种光学测量技术,特别涉及一种基于表面等离子体直接测量纵向偏振光偏振态的方法。The invention relates to an optical measurement technology, in particular to a method for directly measuring the polarization state of longitudinally polarized light based on surface plasmons.
背景技术Background technique
光的偏振状态是光的重要属性之一,是在光的应用与研究过程中必须考虑的参数,因此测量光的偏振态尤为重要。对于常见的横向偏振光,也就是偏振方向与传播方向垂直的光,通过旋转偏振片可以很容易的确定光的偏振方向。但是对于纵向偏振光,也就是偏振方向与光的传播方向相同的光,偏振片的旋转对光的透射没有影响,因而无法检测偏振态。The polarization state of light is one of the important properties of light, and it is a parameter that must be considered in the application and research of light. Therefore, it is particularly important to measure the polarization state of light. For common transversely polarized light, that is, light whose polarization direction is perpendicular to the propagation direction, the polarization direction of the light can be easily determined by rotating the polarizer. But for longitudinally polarized light, that is, light whose polarization direction is the same as the direction of light propagation, the rotation of the polarizer has no effect on the transmission of light, so the polarization state cannot be detected.
目前对纵向偏振光偏振态测量有一些间接的方法:例如使用光刻胶测量光在垂直传播方向平面上的强度分布,使用二次谐波的强度分布,以及利用偶极子散射的方法,这种方法需要精确放置纳米颗粒并使用复杂的重构运算。但是所有这些方法测量的纵向偏振光都带有比纵向分量更强的横向偏振分量,而这些方法是通过对横向电场分布的测量来推断出纵向分量电场的分布。At present, there are some indirect methods for measuring the polarization state of longitudinally polarized light: for example, using photoresist to measure the intensity distribution of light on the plane perpendicular to the direction of propagation, using the intensity distribution of the second harmonic, and the method of using dipole scattering. This method requires precise placement of nanoparticles and the use of complex reconstruction algorithms. However, the longitudinally polarized light measured by all these methods has a stronger transverse polarization component than the longitudinal component, and these methods infer the distribution of the longitudinal component electric field through the measurement of the transverse electric field distribution.
发明内容Contents of the invention
本发明是针对现有技术无法测量纵向偏振光偏振态的问题,提出了一种基于表面等离子体直接测量纵向偏振光偏振态的方法,此方法简单易行,解决了目前无法直接测量纵向偏振光偏振态的难题。The present invention aims at the problem that the prior art cannot measure the polarization state of longitudinally polarized light, and proposes a method for directly measuring the polarization state of longitudinally polarized light based on surface plasmons. The state of polarization conundrum.
本发明的技术方案为:一种基于表面等离子体直接测量纵向偏振光偏振态的方法,具体包括如下步骤:The technical solution of the present invention is: a method for directly measuring the polarization state of longitudinally polarized light based on surface plasmons, specifically comprising the following steps:
1)制作探测基片,探测基片包括玻璃基片、附在玻璃基本上的与玻璃基片面积相同的200纳米厚的铬薄膜记录层,以及在记录层上的金属纳米颗粒;1) Make a detection substrate, which includes a glass substrate, a 200nm-thick chromium thin film recording layer attached to the glass base with the same area as the glass substrate, and metal nanoparticles on the recording layer;
2)在待测光束的光路上依次放置可调光功率衰减器和曝光快门,在光路的末端,也就是测量光偏振状态的位置放置探测基片,带测光垂直入射到记录层;2) Place an adjustable optical power attenuator and an exposure shutter in sequence on the optical path of the beam to be measured, and place a detection substrate at the end of the optical path, that is, the position where the polarization state of the light is measured, with the light incident perpendicularly to the recording layer;
3)通过可调光功率衰减器调节光功率至符合测量要求的范围内;3) Adjust the optical power to the range that meets the measurement requirements through the adjustable optical power attenuator;
4)调节曝光快门的曝光时间,待测光束经过可调光功率衰减器和曝光快门,然后垂直入射到探测基片上,进行一次曝光;4) Adjust the exposure time of the exposure shutter, the light beam to be measured passes through the adjustable optical power attenuator and the exposure shutter, and then is vertically incident on the detection substrate for one exposure;
5)使用扫描电子显微镜对探测基片在曝光过程中被照射的区域进行观察,纪录此区域内记录层上金属纳米颗粒所处位置及其附近的表面形貌;5) Use a scanning electron microscope to observe the irradiated area of the detection substrate during the exposure process, and record the location of the metal nanoparticles on the recording layer in this area and the surface morphology near it;
6)通过计算模拟,得到探测基片上记录层上金属纳米颗粒所处位置附近的电场分布图,然后将步骤5)中得到的表面形貌与模拟结果进行对比,确定待测光束的偏振状态。6) Obtain the electric field distribution near the position of the metal nanoparticles on the recording layer on the detection substrate through calculation and simulation, and then compare the surface morphology obtained in step 5) with the simulation results to determine the polarization state of the beam to be measured.
所述记录层上的金属纳米颗粒的尺寸为被测光束波长的1/3左右。The size of the metal nanoparticles on the recording layer is about 1/3 of the wavelength of the measured light beam.
本发明的有益效果在于:本发明基于表面等离子体直接测量纵向偏振光偏振态的方法,实现了对纵向偏振光的纵向偏振态的直接测量,这是目前其他偏振测量方法无法实现的;测量方法简单有效,容易实施。The beneficial effect of the present invention is that: the method for directly measuring the polarization state of longitudinally polarized light based on surface plasmons in the present invention realizes the direct measurement of the longitudinal polarization state of longitudinally polarized light, which cannot be realized by other current polarization measurement methods; the measurement method Simple and effective, easy to implement.
附图说明Description of drawings
图1为本发明表面等离子体直接测量纵向偏振光偏振态装置结构示意图;Fig. 1 is a schematic structural view of a device for directly measuring the polarization state of longitudinally polarized light by surface plasmons of the present invention;
图2为本发明中探测基片的结构示意图;Fig. 2 is the structural representation of detection substrate among the present invention;
图3为计算模拟得到的线偏振光激发下金属纳米颗粒附近的电场分布图;Fig. 3 is the electric field distribution diagram near the metal nanoparticles excited by the linearly polarized light obtained by calculation and simulation;
图4为本发明使用本发明的方法,在线偏振光激发下,经曝光后,由扫描电子显微镜观测到的在金属纳米颗粒位置的记录层表面形貌图;Fig. 4 is the method of the present invention using the present invention, under the excitation of linear polarized light, after exposure, the surface topography of the recording layer at the position of the metal nanoparticles observed by the scanning electron microscope;
图5为计算模拟得到的纵向偏振光激发下金属纳米颗粒附近的电场分布图;Fig. 5 is the electric field distribution diagram near the metal nanoparticles excited by longitudinally polarized light obtained by calculation and simulation;
图6为本发明使用本发明的方法,在纵向偏振光激发下,经曝光后,由扫描电子显微镜观测到的在金属纳米颗粒位置的记录层表面形貌图。FIG. 6 is a surface topography diagram of the recording layer at the position of the metal nanoparticles observed by scanning electron microscopy after exposure under the excitation of longitudinally polarized light by using the method of the present invention.
具体实施方式Detailed ways
本发明方法基本是:金属纳米颗粒受到光激发时,其产生的表面等离子体的分布由激发光的偏振态决定。基于这个现象,设计了探测基片,通过观察曝光后探测基片记录层上的图案来判断激发光的偏振态。The basic method of the invention is: when the metal nanoparticles are excited by light, the distribution of surface plasmons generated by the metal nanoparticles is determined by the polarization state of the excitation light. Based on this phenomenon, a detection substrate is designed, and the polarization state of the excitation light can be judged by observing the pattern on the recording layer of the detection substrate after exposure.
如图1为本发明基于表面等离子体直接测量纵向偏振光偏振态装置结构示意图,待测光束经过可调光功率衰减器1和曝光快门2,然后垂直入射到探测基片3上。如图2所示探测基片的结构示意图,探测基片3包括底层玻璃基片31、在玻璃基片31上与玻璃基片31同大小面积的200纳米厚的铬薄膜形成的记录层32,以及在记录层32上的金属纳米颗粒33,探测基片3上金属纳米颗粒33的尺寸为被测光束波长的1/3左右或者更小,所述探测基片表面与待测光传播方向垂直,记录层32朝向待测光束。Figure 1 is a schematic diagram of the structure of the device for directly measuring the polarization state of longitudinally polarized light based on surface plasmons in the present invention. The light beam to be measured passes through the adjustable optical power attenuator 1 and the exposure shutter 2, and then is vertically incident on the detection substrate 3 . The structural representation of detection substrate as shown in Figure 2, detection substrate 3 comprises bottom glass substrate 31, on glass substrate 31 and the recording layer 32 that the 200 nanometer thick chromium film of the same size area of glass substrate 31 forms, And the metal nanoparticles 33 on the recording layer 32, the size of the metal nanoparticles 33 on the detection substrate 3 is about 1/3 of the wavelength of the light beam to be measured or smaller, and the surface of the detection substrate is perpendicular to the propagation direction of the light to be measured , the recording layer 32 faces the light beam to be measured.
可调光功率衰减器1用于调节光强;曝光快门2用于曝光操作,首先调节光功率衰减器1和曝光时间2,使曝光后探测基片3上的记录层产生清晰的图案,而没有因光功率过高或曝光时间过长而烧毁;然后进行一次曝光。曝光后使用扫描电子显微镜对探测基片3的记录层进行观察,纪录金属纳米颗粒33所处位置及其周围的记录层表面形貌。利用计算模拟的方法得到在不同偏振态的光激发下金属纳米颗粒附近的电场分布图。比较试验中得到的记录层表面形态图和计算模拟得到的电场分布图,从而确定待测光束在探测基片3位置的偏振状态。The adjustable optical power attenuator 1 is used to adjust the light intensity; the exposure shutter 2 is used for the exposure operation, first adjust the optical power attenuator 1 and the exposure time 2, so that the recording layer on the detection substrate 3 after exposure produces a clear pattern, and Not burned by too high light power or too long exposure time; then take one more exposure. After the exposure, the recording layer of the probe substrate 3 is observed with a scanning electron microscope, and the position of the metal nanoparticles 33 and the surface morphology of the recording layer around them are recorded. The electric field distribution near the metal nanoparticles under the excitation of different polarization states is obtained by computational simulation. The surface morphology diagram of the recording layer obtained in the test is compared with the electric field distribution diagram obtained by calculation and simulation, so as to determine the polarization state of the light beam to be measured at the position of the detection substrate 3 .
在实施例中,首先使用了线偏振光,计算模拟得到的电场分布图如图3所示,图中金属颗粒所处位置41,记录层所处位置42。试验得到的记录层表面形貌入图4所示。可以看到图4中心的圆形为金属纳米颗粒所处的位置,其左右两侧的竖条纹与图3中记录层位置的两个强度最大值位置相吻合,证明被测光束的偏振状态为线偏振。然后此实施例使用了纵向偏振光,计算模拟得到的电场分布图如图5所示,图中金属颗粒所处位置51,记录层所处位置52。试验得到的记录层表面形貌入图6所示。可以看到图6只存在中心的圆形图案,其位置与图5中金属纳米颗粒正下方记录层位置的圆形强度最大值区域位置相吻合,证明被测光束的偏振状态为纵向偏振。此实例证明了本发明中提出的基于表面等离子体直接测量纵向偏振光偏振态的方法可行,有效。In the embodiment, linearly polarized light is firstly used, and the electric field distribution diagram obtained through calculation and simulation is shown in FIG. 3 , in which the metal particle is at position 41 and the recording layer is at position 42 . The surface morphology of the recording layer obtained from the test is shown in Figure 4. It can be seen that the circle in the center of Figure 4 is the position of the metal nanoparticles, and the vertical stripes on the left and right sides of it coincide with the two intensity maximum positions of the recording layer in Figure 3, which proves that the polarization state of the measured beam is linear polarization. Then this embodiment uses longitudinally polarized light, and the electric field distribution diagram obtained by calculation and simulation is shown in FIG. 5 , in which the metal particle is at position 51 and the recording layer is at position 52 . The surface morphology of the recording layer obtained from the test is shown in Figure 6. It can be seen that there is only a central circular pattern in Figure 6, and its position coincides with the position of the circular intensity maximum area at the position of the recording layer directly under the metal nanoparticles in Figure 5, which proves that the polarization state of the measured beam is longitudinal polarization. This example proves that the method for directly measuring the polarization state of longitudinally polarized light based on surface plasmons proposed in the present invention is feasible and effective.
本发明方法具体步骤如下:The concrete steps of the inventive method are as follows:
(1)如图2所示的结构制作探测基片;(1) Fabricate the detection substrate with the structure shown in Figure 2;
(2)在待测光束的光路上依次放置可调光功率衰减器和曝光快门,在光路的末端,也就是需要测量光偏振状态的位置放置探测基片;(2) Place an adjustable optical power attenuator and an exposure shutter in sequence on the optical path of the beam to be measured, and place a detection substrate at the end of the optical path, that is, where the polarization state of the light needs to be measured;
(3)通过可调光功率衰减器调节光功率至符合测量要求的范围内;(3) Adjust the optical power to the range that meets the measurement requirements through the adjustable optical power attenuator;
(4)调节曝光快门的曝光时间,进行一次曝光;(4) Adjust the exposure time of the exposure shutter for one exposure;
(5)使用扫描电子显微镜对探测基片在曝光过程中被照射的区域进行观察,纪录此区域内记录层上金属纳米颗粒所处位置及其附近的表面形貌;(5) Use a scanning electron microscope to observe the irradiated area of the detection substrate during the exposure process, and record the location of the metal nanoparticles on the recording layer in this area and the surface morphology near it;
(6)通过计算模拟,得到探测基片上记录层上金属纳米颗粒所处位置附近的电场分布图,然后将所述过程(5)中得到的表面形貌与模拟结果进行对比,确定待测光束的偏振状态。(6) Obtain the electric field distribution map near the position of the metal nanoparticles on the recording layer on the detection substrate through calculation and simulation, and then compare the surface morphology obtained in the process (5) with the simulation results to determine the beam to be measured the polarization state.
Claims (1)
- A kind of 1. method based on surface plasma direct measurement vertically polarized light polarization state, it is characterised in that specifically include Following steps:1)Make detection substrate, detection substrate include glass substrate, be attached to glass substantially with glass substrate area identical The chromium thin film recording layer of 200 nanometer thickness, and metal nanoparticle on the recording layer, metal nanoparticle on recording layer Size is 1/3 or so of tested light beam wavelength;2)Adjustable light power attenuator and exposure shutter are sequentially placed in the light path of light beam to be measured, in the end of light path, also It is that detection substrate is placed in the position for measuring light polarization state, band light-metering impinges perpendicularly on recording layer;3)In the range of adjustable light power attenuator regulating optical power to coincidence measurement requirement;4)The time for exposure of regulation exposure shutter, light beam to be measured is by adjustable light power attenuator and exposes shutter, then vertically Incide on detection substrate, carry out single exposure;5)Observed using the SEM region illuminated in exposure process to detection substrate, note down this region Metal nanoparticle present position and its neighbouring surface topography on interior recording layer;6)By calculating simulation, obtain detecting the Electric Field Distribution on substrate on recording layer near metal nanoparticle present position Figure, then by step 5)In obtained surface topography contrasted with analog result, determine the polarization state of light beam to be measured.
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