CN106893561A - Phase change composite material and electronic equipment - Google Patents

Abstract

The invention proposes a phase-change composite material and its preparation method and application. The phase-change composite material is used for coating on the surface of an object to be dissipated, and includes a bonding resin, a phase-change heat storage material, and the phase-change composite material used The phase transition temperature of the heat storage material is 20-70°C. The phase-change composite material of the embodiment of the present invention can be effectively used for heat dissipation of heat-generating components of electronic equipment.

Description

Phase Change Composite Materials and Electronic Devices

technical field

The invention relates to the field of materials, in particular, the invention relates to phase change composite materials and electronic equipment.

Background technique

The upgrading of electronic products is getting faster and faster, and their functions are getting stronger and stronger. However, in addition to greatly enriching the functions to meet people's increasing needs, it also brings an additional problem, that is, "hot", " Although it seems that "hot" only slightly affects the user experience, once it becomes "hot" if it is not well controlled, it will feel very bad for the user and seriously affect the user experience; and for electronic products, the long-term Working at high temperature for a long time, there may be various problems such as the battery power drops too fast, the machine crashes and restarts, and the components are aging.

Therefore, how to solve the heat generation of electronic products is an urgent problem to be solved in the development process of electronic products.

Contents of the invention

The present invention aims to solve one of the technical problems in the related art at least to a certain extent.

Therefore, in the first aspect of the present invention, the present invention proposes a phase change composite material. According to an embodiment of the present invention, the phase change composite material is used for coating on the surface of an object to dissipate heat, and includes: a bonding resin, a phase change heat storage material, and the phase change temperature of the phase change heat storage material is 20 ~70°C. According to the embodiment of the present invention, the phase change composite material can be directly coated on the surface of the object to be dissipated, and a uniform heat conduction and heat storage film is formed on the surface of the object to be dissipated, and the heat can be directly and quickly transferred to the phase change composite material, The phase change composite material gradually changes from solid to liquid when heated, and then absorbs heat from the object to be dissipated to the phase change composite material. At the same time, due to the good heat storage performance of the phase change composite material, heat slowly transfers Released, the phase change composite material changes from a liquid state to a solid state, therefore, through the phase change composite material of the embodiment of the present invention, the heat absorption is changed from a solid state to a liquid state, and the heat release is changed from a liquid state to a solid state, thereby avoiding the temperature increase caused by the increase in heat. The sharp rise of the phase change composite material completes a cycle of heat absorption and heat release, effectively absorbing the heat of the object to be dissipated, effectively realizing the heat dissipation of the object to be dissipated, and at the same time not causing heat loss due to heat absorption resulting in an excessive rise in temperature. In addition, according to the embodiment of the present invention, compared with metal backplane heat conduction, graphite heat sink heat conduction, heat conduction gel heat dissipation, and ice nest heat dissipation, the phase change composite material is applied to the heat dissipation of the object to be dissipated, and can be directly coated on the The surface of the heat-dissipating object, thereby directly contacting the object to be dissipated, and there is no air gap between the object to be dissipated, the heat can be directly transferred from the object to be dissipated to the phase-change composite material of the embodiment of the present invention, and the heat conduction efficiency is significantly improved; Heat pipe heat dissipation, the phase change composite material is applied to the heat dissipation of the object to be radiated, no container is required, and the required space is small; compared with the ice nest heat dissipation, the phase change composite material is applied to the heat dissipation of the object to be radiated, which can realize Rapid cooling of heat-dissipating objects.

In a second aspect of the invention, the invention proposes an electronic device. According to an embodiment of the present invention, the electronic device includes: a housing; and at least one of a processor or a battery, the processor or the battery is arranged in the housing; wherein, the surface of the processor or the battery Coated with a phase change composite as previously described. As mentioned above, the phase change composite material of the embodiment of the present invention can be directly coated on the surface of the object to be dissipated, such as the surface of the electronic device processor or battery, between the object to be dissipated and the phase change composite material of the embodiment of the present invention Without an air gap, heat can be directly transferred from the object to be dissipated to the phase change composite material of the embodiment of the present invention, and the heat conduction efficiency is high. At the same time, because the phase change composite material of the embodiment of the present invention has the advantage of good heat storage performance, it can The heat absorption is changed from solid to liquid, and the heat release is changed from liquid to solid, which can avoid the sharp rise of temperature caused by the increase of heat. Therefore, according to an embodiment of the present invention, the processor or battery of the electronic device of the embodiment of the present invention is coated with the phase change composite material of the embodiment of the present invention, and the processor or battery can work at a substantially constant temperature, avoiding The electronic equipment works for a long time and produces heat, which causes the battery power of the equipment to drop too fast, crashes and restarts, and the problems of component aging. Therefore, the electronic equipment in the embodiment of the present invention has the advantage of long service life.

detailed description

Embodiments of the present invention are described in detail below. The embodiments described below are exemplary and are intended to explain the present invention, but should not be construed as limiting the present invention.

phase change composite

In the first aspect of the present invention, the present invention proposes a phase change composite material. According to an embodiment of the present invention, the phase-change composite material of the embodiment of the present invention is used for coating on the surface of an object to be dissipated heat, and includes: an adhesive resin, a phase-change heat storage material, and a phase-change heat storage material used The change temperature is 20-70°C. According to an embodiment of the present invention, the above heat dissipation object may be a processor or a battery of an electronic device. According to an embodiment of the present invention, the phase change composite material can be directly coated on the surface of an object to be dissipated, such as a processor or a battery of an electronic device, to form a uniform heat conduction and heat storage film on the surface of the object to be dissipated, and the heat can be directly The phase change composite material is quickly transferred to the phase change composite material, and the phase change composite material gradually changes from solid to liquid state when heated, and then absorbs heat from the object to be dissipated to the phase change composite material. At the same time, because the phase change composite material has good heat storage performance, Heat is slowly released from the phase-change composite material, and the phase-change composite material changes from a liquid state to a solid state. Therefore, through the phase-change composite material of the embodiment of the present invention, the heat absorption is changed from solid state to liquid state, and the heat release is changed from liquid state to solid state. Avoiding the sharp increase in temperature caused by the increase in heat, the state change of the phase change composite material completes a cycle of heat absorption and heat release, effectively absorbing the heat of the object to be dissipated, and effectively realizing the heat dissipation of the object to be dissipated. It will not cause excessive temperature rise due to heat absorption. In addition, according to the embodiment of the present invention, compared with metal backplane heat conduction, graphite heat sink heat conduction, heat conduction gel heat dissipation, and ice nest heat dissipation, the phase change composite material is applied to the heat dissipation of the object to be dissipated, and can be directly coated on the The surface of the heat-dissipating object, thereby directly contacting the object to be dissipated, and there is no air gap between the object to be dissipated, the heat can be directly transferred from the object to be dissipated to the phase-change composite material of the embodiment of the present invention, and the heat conduction efficiency is significantly improved; Heat pipe heat dissipation, the phase change composite material is applied to the heat dissipation of the object to be radiated, no container is required, and the required space is small; compared with the ice nest heat dissipation, the phase change composite material is applied to the heat dissipation of the object to be radiated, which can realize Rapid cooling of heat-dissipating objects.

In addition, according to the embodiments of the present invention, the inventors have found through a large number of screening experiments that the content of the binder resin is 10-50 parts by weight, and the content of the phase-change heat storage material is 25-70 parts by weight. The supporting effect can be better matched with the phase change performance of the endothermic/exothermic phase change of the phase change heat storage material, thus, the film forming effect of the phase change composite material of the embodiment of the present invention is significantly improved, which is more beneficial to the present invention The phase-change composite material of the embodiment is directly coated on the surface of the object to be dissipated, and the heat conduction and heat storage performances are further improved.

Specifically, according to the embodiment of the present invention, the phase change heat storage material used can be selected from at least one of paraffins, alcohols and fatty acids, and the phase transition temperature of paraffins, alcohols and fatty acids is between 20°C and 70°C Among them, paraffin, alcohols, and fatty acids have good heat absorption and heat release functions between 20 and 70 °C, and can more effectively realize heat dissipation of the object to be cooled through heat absorption and heat release cycles without causing a sudden rise in temperature .

According to some embodiments of the present invention, the used binding resin may be selected from at least one of thermosetting resin and thermoplastic resin, wherein the thermoplastic resin includes hydrophilic thermoplastic resin and lipophilic thermoplastic resin. The type of the thermosetting resin is not particularly limited. According to an embodiment of the present invention, the thermosetting resin may be selected from at least one of epoxy resin, alkyd resin, polyurethane resin, and polyester resin. According to some other embodiments of the present invention, when the bonding resin adopts thermosetting plastic resin, the phase change composite material of the embodiments of the present invention may further include a curing agent. According to the embodiments of the present invention, the curing agent is selected from polyamide, at least one of polyisocyanates. In addition, according to the embodiment of the present invention, the type of thermoplastic resin used is not particularly limited. According to the embodiment of the present invention, the thermoplastic resin can be selected from but not limited to thermoplastic acrylic resin, thermoplastic polyurethane resin, polycarbonate, methacrylic acid At least one of ester, polyethylene, cellulose, chlorinated rubber, perchlorethylene, and novolak resin. According to an embodiment of the present invention, when the bonding resin adopts the hydrophilic thermoplastic resin in the thermoplastic resin, the phase change composite material of the embodiment of the present invention may further include a film-forming aid. According to other embodiments of the present invention, the At least one of alcohol ester dodeca, ethylene glycol butyl ether, diethylene glycol butyl ether, dipropylene glycol butyl ether, and propylene glycol butyl ether is used as the film-forming aid. The inventors found that, due to the high water content of the hydrophilic thermoplastic resin, it is not conducive to film formation, and film-forming aids such as alcohol ester twelve can significantly promote the film formation of the hydrophilic thermoplastic resin, which is more beneficial to the embodiment of the present invention. The advanced phase change composite material is directly coated on the surface of the object to be dissipated.

In addition, according to an embodiment of the present invention, the phase change composite material of the embodiment of the present invention may further include: 0.1-5 parts by weight of a tackifier, and the inventors found that 0.1-5 parts by weight of a tackifier can enable the implementation of the present invention The viscosity of the phase-change composite material of the embodiment of the present invention is improved, which is beneficial to achieve the construction viscosity, is more conducive to the film-forming of the phase-change composite material of the embodiment of the present invention, and is more convenient to directly coat the phase-change composite material of the embodiment of the present invention on the The surface of a heat-dissipating object.

At the same time, according to some other embodiments of the present invention, the inventors also surprisingly found that the phase change composite material of the embodiments of the present invention may further include: 5-60 parts by weight of diluent, the inventors found that 5-60 parts by weight The diluent will also be more conducive to the construction of the phase change composite material of the embodiment of the present invention, that is, spraying, printing or brushing. Specifically, the type of diluent is not particularly limited. According to an embodiment of the present invention, the diluent may be selected from but not limited to acetone, methyl ethyl ketone, cyclohexanone, benzene, toluene, xylene, n-butanol, styrene, At least one of deionized water, the phase change composite material of the embodiment of the present invention adopts the above-mentioned diluent, and its construction is more convenient. By spraying, printing or brushing, the phase change composite material of the embodiment of the present invention is more convenient to be directly coated on The surface of the object to be cooled.

Method for preparing phase change composite material

For the convenience of understanding, the method that can be used to prepare the above-mentioned phase change composite material is described below. . According to an embodiment of the present invention, the method includes: mixing a binder resin and a phase-change heat storage material, so as to obtain a phase-change composite material. Specifically, according to an embodiment of the present invention, the method for preparing a phase-change composite material in the embodiment of the present invention further includes adding a binder resin, a phase-change heat storage material, a tackifier, a diluent and/or a curing agent, and a film-forming assistant At least one of the agents is stirred and mixed to obtain a phase change composite material. According to the embodiments of the present invention, using the method for preparing phase-change composite materials in the embodiments of the present invention, the above-mentioned phase-change composite materials can be efficiently prepared, and the binder resin, phase-change heat storage material, and tackifier used are , diluent and/or curing agent, film-forming aid are materials well known to those skilled in the art, and it is convenient to obtain materials. In addition, according to the embodiments of the present invention, the method of the embodiments of the present invention only needs to complete the mixing by stirring , the phase change composite material of the embodiment of the present invention can be obtained, and the operation is simple and convenient. At the same time, as mentioned above, the phase change composite material prepared by the preparation method of the embodiment of the present invention can be directly coated on the surface of the object to be dissipated, and a uniform heat conduction and heat storage film is formed on the surface of the object to be dissipated. There is no air gap between the heat dissipation object and the phase change composite material prepared by the method of the embodiment of the present invention, heat can be directly and quickly transferred to the phase change composite material, and the phase change composite material is gradually transformed from solid to liquid when heated, and then the heat is transferred from the The heat-dissipating object is absorbed into the phase-change composite material, and at the same time, because the obtained phase-change composite material has good heat storage performance, heat is slowly released from the phase-change composite material, and the phase-change composite material changes from liquid to solid state. Therefore, through this The phase change composite material prepared by the preparation method of the embodiment of the invention, its heat absorption changes from solid to liquid state, and its heat release changes from liquid state to solid state, which avoids the sharp rise of temperature caused by the increase of heat, and takes the advantage of the phase change composite material The state change completes a cycle of heat absorption and heat release, effectively absorbing the heat of the object to be dissipated, effectively realizing the heat dissipation of the object to be dissipated, and at the same time not causing excessive temperature rise due to heat absorption.

In addition, according to the embodiment of the present invention, the mixing in the preparation method of the embodiment of the present invention is carried out under the agitation of the high-speed disperser, and the speed of the high-speed disperser is 500-2500r/min, preferably 800r/min. Conditions, for 15 to 30 minutes. According to a specific embodiment of the present invention, other substances that do not include phase-change heat storage materials can be stirred and mixed first, and the speed of the high-speed mixer is relatively high, such as 1500r/min, and stirred for 15 minutes, and then continue to add phase-change materials. For the heat storage material, the rotating speed can be reduced at this time, such as down to 800r/min, and the stirring is continued for 15 minutes. According to the embodiments of the present invention, various substances in the phase-change composite material prepared under the above-mentioned mixing conditions can be fully mixed, and the obtained phase-change composite material has a uniform texture and further enhanced heat conduction and heat storage functions.

In addition, according to some embodiments of the present invention, the method for preparing a phase-change composite material according to the embodiment of the present invention may further include: performing ball milling on the phase-change heat storage material used in advance, and the phase-change heat storage material obtained after ball milling The diameter is less than 100 microns, preferably less than 10 microns in diameter. The inventors found that pre-milling the phase change heat storage material into particles with a diameter of less than 10 microns is beneficial to the subsequent mixing operation, and the texture uniformity of the obtained phase change composite material is further improved, and the phase change compound at different positions The heat absorption synchronization of the material is improved, and the heat dissipation function of the phase change composite material can be realized more effectively.

According to the embodiment of the present invention, the phase change composite material prepared by the preparation method of the embodiment of the present invention can be directly coated on the surface of the object to be dissipated, and dried and cured at room temperature for 24 hours, so as to form a heat dissipation film on the surface of the object to be dissipated . The phase-change composite material prepared by the preparation method of the embodiment of the present invention can be directly coated on the surface of the object to be dissipated during application, and the object to be dissipated is in direct contact with the phase-change composite material of the embodiment of the present invention, there is no air gap between them, and the heat It can be directly transferred from the object to be dissipated to the phase change composite material, avoiding the problem of low heat conduction efficiency of air, and the heat conduction efficiency of the phase change composite material prepared by the preparation method of the embodiment of the present invention is significantly improved.

Application of Phase Change Composite Materials in Heat Dissipation of Electronic Equipment

In another aspect of the present invention, the present invention proposes the use of the aforementioned phase-change composite material in heat dissipation of electronic equipment. According to the embodiment of the present invention, the phase change composite material of the embodiment of the present invention can be directly coated on the surface of the electronic device to be dissipated, and a uniform heat conduction and heat storage film can be formed on the surface of the electronic device to be dissipated. There is no air gap between the phase change composite materials, heat can be directly and quickly transferred to the phase change composite material, and the phase change composite material gradually changes from solid to liquid state when heated, and then absorbs heat from the heat dissipation device of the electronic device to the phase change composite material At the same time, due to the good heat storage performance of the phase change composite material, the heat is slowly released from the phase change composite material, and the phase change composite material changes from liquid to solid state. Therefore, the phase change composite material in the embodiment of the present invention absorbs The heat is changed from solid to liquid, and the heat release is changed from liquid to solid, which can effectively avoid the sharp rise in temperature caused by the increase of heat, and complete a heat absorption and heat release cycle with the state change of the phase change composite material, thereby effectively Absorb the heat of the electronic equipment to be dissipated, effectively realize the heat dissipation of the electronic equipment to be dissipated, and at the same time, it will not cause the temperature of the electronic equipment to rise excessively due to heat absorption. Therefore, the phase change composite material of the embodiment of the present invention can be used for effective heat dissipation of electronic equipment, and has applications in heat dissipation of electronic equipment.

Electronic equipment

In another aspect of the invention, the invention proposes an electronic device. According to an embodiment of the present invention, the electronic device includes a casing; and a processor or a battery, the processor or the battery is arranged in the casing, wherein the surface of the processor or the battery is coated with the phase change composite material according to the embodiment of the present invention . The phase-change composite material of the embodiment of the present invention can be directly coated on the surface of the object to be dissipated, and has the advantages of high thermal conductivity and good heat storage performance. It can change from solid to liquid by absorbing heat, and from liquid to solid by releasing heat. , to avoid a sharp rise in temperature due to the increase in heat. Therefore, according to an embodiment of the present invention, the processor or battery of the electronic device of the embodiment of the present invention is coated with the phase change composite material of the embodiment of the present invention, and the processor or battery can work at a substantially constant temperature and can Avoiding the problems of excessive battery power drop, crash restart, and aging of components caused by heat generation caused by the electronic device working for a long time, the electronic device of the embodiment of the present invention has the significant advantage of long service life.

The solutions of the present invention will be explained below in conjunction with examples. Those skilled in the art will understand that the following examples are only for illustrating the present invention and should not be considered as limiting the scope of the present invention. If no specific technique or condition is indicated in the examples, it shall be carried out according to the technique or condition described in the literature in this field or according to the product specification. The reagents or instruments used were not indicated by the manufacturer, and they were all commercially available conventional products.

general method

In the following examples, if not explicitly stated, the phase change composite material is prepared according to the following steps:

(1) The phase-change heat storage material is ball-milled with a planetary high-energy ball mill (model DECO-SG100, Deco), and ball-milled into particles with a diameter of less than 10 microns.

(2) Prepare the phase change composite material except the phase change heat storage material into a mixed solution, stir in a high-speed disperser at a speed of 1500r/min for 15 minutes, and mix thoroughly to obtain solution X.

(3) Add the phase-change heat storage material particles obtained in step (1) into the solution X, stir in a high-speed disperser at a speed of 800 r/min for 15 minutes, and mix thoroughly to obtain a phase-change composite material.

Examples 1-3

In these examples, phase-change composite materials were prepared according to the steps described in the general method, wherein, the components and amounts of the phase-change composite materials prepared in Examples 1-3 are shown in Table 1,

Table 1

The phase change composite material obtained in Examples 1-3 is directly coated on the surface of the object to be dissipated, and left at room temperature for 24 hours to dry and solidify, so as to form a heat dissipation film on the surface of the object to be dissipated.

Example 4

In Example 4, according to the steps described in the general method, a phase-change composite material was prepared, wherein, in this embodiment, the components and dosages used to prepare the phase-change composite material were the same as those used in the preparation of the phase-change composite material in Example 1. The ingredients and dosage are the same.

The phase-change composite material prepared in this embodiment is packaged in an aluminum plate with a wall thickness of 0.1 mm.

Example 5

In Example 5, according to the steps described in the general method, a phase-change composite material was prepared, wherein, in this embodiment, the components and dosages used to prepare the phase-change composite material were the same as those used in the preparation of the phase-change composite material in Example 1. The ingredients and dosage are the same.

The phase change composite material prepared in this embodiment is filled in aluminum foam with through holes.

Example 6

In this example, the fluidity test and the heat dissipation effect test were carried out on the phase change composite materials prepared in Examples 1-5 according to the following description:

(1) Liquidity test

Coating area is 25mm*25mm on metal sheet, and thickness is the phase-change composite material test block of embodiment 1～3 of 50 microns;

The phase-change composite material prepared in Example 4 is packaged in an aluminum plate with a wall thickness of 0.1 mm, wherein the phase-change composite material test sample block has a thickness of 50 microns and an area of 25mm*25mm, and is placed on a metal sheet;

The phase-change composite material prepared in Example 5 is filled in aluminum foam with a thickness of 50 microns and an area of 25mm*25mm with through holes, and placed on the metal sheet;

The above-mentioned phase-change composite material test sample block was kept at 70°C for 7 days, and the area change of the phase-change composite material before and after the test was measured. The test results are listed in Table 2.

(2) Heat dissipation effect

Make a test board with Qualcomm Snapdragon 810 processor and make it work overclocked. During production, the Qualcomm Snapdragon 810 processor was externally used for testing. The temperature is monitored by a temperature monitoring camera.

One side of the Qualcomm Snapdragon 810 processor was coated with the phase-change composite material of Examples 1-3 with a thickness of 100 microns. Start the start working button, and test the surface temperature A _meter of the processor and the surface temperature A _phase of the phase change composite material for 15 minutes. And the test results are listed in Table 2.

In embodiment 4, the phase-change composite material is packaged in an aluminum plate with a wall thickness of 0.1 mm, wherein the thickness of the phase-change composite material is 100 microns, and it is placed on the surface of the processor, and the start working button is started, and the surface temperature of the processor is tested for 15 minutes _Table A, phase change composite material surface temperature A _phase , the results are listed in Table 2.

In embodiment 5, the phase-change composite material is filled in the aluminum foam with a thickness of 100 microns with a through hole, and placed on the surface of the processor, start the start working button, and test the processor surface temperature A _meter for 15 minutes, phase-change composite material Surface temperature _Phase A, the results are listed in Table 2.

Table 2

It can be seen from Table 2 that the phase-change composite materials obtained in Examples 1-5 have no fluidity below 70°C, and can be effectively attached to the surface of objects to be dissipated (such as metal sheets, Qualcomm Snapdragon 810 processors), and the phase-change composite materials It has the characteristic of endothermic/exothermic phase change below 70°C, which makes it have good heat dissipation effect, and the surface temperature of the object to be radiated and the surface temperature of the phase change composite material will not rise too much. However, if the phase change composite material is packaged in an aluminum plate or filled in aluminum foam (as shown in Examples 4 and 5), the heat dissipation effect is not as good as that of directly coating the phase change composite material on the surface of the object to be dissipated. Therefore, the phase change composite material of the embodiment of the present invention is more suitable for direct coating on the surface of the object to be dissipated for effective heat dissipation of the object to be dissipated.

In the description of this specification, descriptions referring to the terms "one embodiment", "some embodiments", "example", "specific examples", or "some examples" mean that specific features described in connection with the embodiment or example , structure, material or characteristic is included in at least one embodiment or example of the present invention. In this specification, the schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the described specific features, structures, materials or characteristics may be combined in any suitable manner in any one or more embodiments or examples. In addition, those skilled in the art can combine and combine different embodiments or examples and features of different embodiments or examples described in this specification without conflicting with each other.

Although the embodiments of the present invention have been shown and described above, it can be understood that the above embodiments are exemplary and should not be construed as limiting the present invention, those skilled in the art can make the above-mentioned The embodiments are subject to changes, modifications, substitutions and variations.

Claims (15)

1. a kind of phase change composite material, it is characterised in that the phase change composite material is used to be coated in the surface for treating thermal dissipating object, And including：

Binding resin,

Phase-change heat-storage material, the phase transition temperature of the phase-change heat-storage material is 20~70 DEG C.

2. phase change composite material according to claim 1, it is characterised in that the content of the binding resin is 10~50 Weight portion, the content of the phase-change heat-storage material is 25~70 weight portions.

3. phase change composite material according to claim 1, it is characterised in that the phase change composite material is further wrapped Include：The tackifier of 0.1~5 weight portion.

4. phase change composite material according to claim 1, it is characterised in that the phase change composite material is further wrapped Include：The diluent of 5~60 weight portions.

5. phase change composite material according to claim 1, it is characterised in that the binding resin includes being selected from thermosetting At least one of resin, thermoplastic resin,

Wherein, the thermoplastic resin includes hydrophilic thermoplastic's resin and lipophile thermoplastic resin.

6. phase change composite material according to claim 5, it is characterised in that the thermosetting resin includes being selected from epoxy At least one of resin, alkyd resin, polyurethane resin, polyester resin.

7. phase change composite material according to claim 5, it is characterised in that the thermoplastic resin is included selected from heat Plastic propene's acid resin, TPU, makrolon, methacrylate, polyethylene, cellulose, chlorination At least one of rubber, Vinylidene Chloride, linear phenolic resin.

8. phase change composite material according to claim 5, it is characterised in that the binding resin is thermosetting resin When, the phase change composite material further includes curing agent.

9. phase change composite material according to claim 5, it is characterised in that the binding resin is thermoplastic resin, When the thermoplastic resin is hydrophilic thermoplastic's resin, the phase change composite material further includes coalescents.

10. phase change composite material according to claim 8, it is characterised in that the curing agent be selected from polyamide, At least one of polyisocyanates.

11. phase change composite materials according to claim 9, it is characterised in that the coalescents are selected from alcohol ester ten 2nd, at least one of butyl glycol ether, butyl, dipropylene, propandiol butyl ether.

12. phase change composite materials according to claim 1, it is characterised in that the phase-change heat-storage material includes being selected from At least one of paraffin class, alcohols, fatty acid.

13. phase change composite materials according to claim 4, it is characterised in that the diluent include selected from acetone, At least one of MEK, cyclohexanone, benzene,toluene,xylene, n-butanol, styrene, deionized water.

14. phase change composite materials according to claim 1, it is characterised in that the object to be radiated sets for electronics Standby processor or battery.

15. a kind of electronic equipment, it is characterised in that including：

Housing；And

At least one of processor or battery, the processor or battery are arranged in the housing,

Wherein, the surface of the processor or battery is coated with the phase change composite material described in any one of claim 1~13.