CN107225818A - A kind of ceramic-metal composites mix multilayer material - Google Patents
A kind of ceramic-metal composites mix multilayer material Download PDFInfo
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- CN107225818A CN107225818A CN201710604195.4A CN201710604195A CN107225818A CN 107225818 A CN107225818 A CN 107225818A CN 201710604195 A CN201710604195 A CN 201710604195A CN 107225818 A CN107225818 A CN 107225818A
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- 239000000463 material Substances 0.000 title claims abstract description 53
- 239000002905 metal composite material Substances 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 title abstract 2
- 230000004313 glare Effects 0.000 claims abstract description 25
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- 239000011204 carbon fibre-reinforced silicon carbide Substances 0.000 claims abstract description 17
- 239000000956 alloy Substances 0.000 claims abstract description 6
- 238000010276 construction Methods 0.000 claims abstract description 5
- 239000002131 composite material Substances 0.000 abstract description 8
- 239000000919 ceramic Substances 0.000 abstract description 6
- 239000007769 metal material Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 5
- 230000035945 sensitivity Effects 0.000 abstract description 3
- HPNSNYBUADCFDR-UHFFFAOYSA-N chromafenozide Chemical compound CC1=CC(C)=CC(C(=O)N(NC(=O)C=2C(=C3CCCOC3=CC=2)C)C(C)(C)C)=C1 HPNSNYBUADCFDR-UHFFFAOYSA-N 0.000 abstract description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical class [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000000626 liquid-phase infiltration Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000943 NiAl Inorganic materials 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000002498 deadly effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/043—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/08—Interconnection of layers by mechanical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/041—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
Mix multilayer material the invention discloses a kind of ceramic-metal composites, be made up of C/SiC materials, sheet metal and Glare laminates, its structure is laminated construction, is from top to bottom followed successively by C/SiC materials, sheet metal and Glare laminates.Described C/SiC material thicknesses are 1 4mm.Described sheet metal can be one kind in Mo, Nb or Ti metal and its alloy material, and thickness is 0.3 0.5mm.Described Glare laminate thickness is 2 5mm.The material passes through method hot-forming at high temperature, the advantage of set ceramic matric composite, metal material and Glare plates so that the Fracture of Material is significantly improved, and notch sensitivity is greatly lowered, and substantially increases the intensity and toughness of material.
Description
Technical field
The present invention relates to a kind of multilayer material, more particularly to a kind of ceramic-metal-composite mixes multilayer material.
Background technology
Current C/SiC composites can fire-resistant oxidation resistant, its high-temperature behavior is very excellent, in aircraft engine, stops
Hull, the field such as structure stress part is had a wide range of applications, and big yet with silicon carbide ceramics fragility, easy fragmentation is limited significantly
It uses scope.Even if by carbon fiber-reinforced, its toughness can reach level of alloy, but be due to the breach of carbofrax material
Sensitiveness is big, and the critical defective of fracture is too low, and about 10-3The mm order of magnitude, it is critical well below metal and its alloy defect
Value（About 1mm grades）, this deadly defect but greatly limit its widely apply.And refractory metal intensity is high, toughness is high, its
The critical defective of fracture is far above silicon carbide ceramics, due to the spy of metallic bond between the long-range order and atom of metallic atom
Property, make it have certain plasticity.The characteristic of the existing metallic plate of Glare laminates, there is glass fibre again." bridge joint " mechanism
Make it have excellent fatigue resistance；The presence of glass fibre makes its notch strength keep higher level；The moisture-resistant of metallic plate
Performance makes Glare laminates have good moisture-resistant hot property；Glass layer has excellent corrosion resistance.If by C/SiC materials
Material, Mo sheet metals and Glare laminates are hot-forming at high temperature, prepare a kind of C/SiC-Mo metals-Glare composite woods
Material mixes multilayer material, and the material made possesses excellent mechanical property, combines traditional fibre composite and metal material
And the characteristics of Glare laminates, the deficiency of homogenous material is compensate for, and not only with high specific stiffness and specific strength, excellent fatigue
Performance and damage tolerance performance, toughness and machinability also with metal material will significantly improve the obdurability of material, greatly
The notch sensitivity of big reduction material, becomes the ideal chose of aerospace flight vehicle structure material requested.
All the time, metal phase enhancing ceramic material is due to its excellent performance, and respective advantage and disadvantage are complementary, are always to grind
Study carefully focus.Document " Al2O3-Ni3The Study on Mechanical Properties of-Al composites, Zhang Ping Rong, Shen Jianxing, the such as Wang Jiefeng China pottery
Porcelain, 2000,30 (4):5-7 " describes a kind of nickel alumin(i)um alloy enhancing alumina ceramic material, the side that the material passes through powder metallurgy
Method is made, with pure Al2O3Ceramic phase ratio, the composite still maintains higher fracture toughness until 1000 DEG C.Brilliant rosy clouds et al.
The NiAl/TiC and Ni of high TiC contents are prepared for using spontaneous melt infiltration method3- Al/TiC composites, make the fracture of material
Toughness is greatly increased.It can be seen that this kind of material is made up by respective advantage or part compensate for mutual shortcoming, with excellent
Different performance.But such material void is difficult to be completely eliminated, if the mechanics of material certainly will be influenceed by adding excessive sintering aid
Performance, the material prepared especially by spontaneous melt infiltration method, structure is uneven, and there is indelible stomata, greatly
The big fracture toughness for reducing material.
Document " Chinese patent of Application No. 201410056071.3 " discloses a kind of preparation shaping of Glare components
Method, Glare laminates are replaced by the aluminium alloy sheet thick 0.3-0.5 mm glass fibre prepreg thick with 0.2-0.3mm
Lamination is formed, and its density is low and with prominent tension-pressure fatigue behaviour and higher nick break performance, its excellent property
Energy, stable preparation technology and significant cost advantage, the extensive use in Aero-Space.But simple Glare laminates its
High temperature resistant, anti-oxidant and intensity hardness performance is not outstanding, is easily oxidized at high temperature, flexible when by load, from
And limit it and use field.And a kind of material for combining traditional fibre composite and metallic character, will have wider
Wealthy application prospect.
The content of the invention
The purpose of the present invention is intended to overcome the defect of prior art there is provided a kind of hardness high tenacity is good, being capable of high temperature resistant
Oxidation resistant ceramic-metal-composite mixes multilayer material.
To realize that the technical scheme that the purpose of the present invention is used is：A kind of ceramic-metal-composite mixes multilayer material
Material, it is characterised in that be made up of C/SiC materials, sheet metal and Glare laminates, its structure be laminated construction, from top to bottom according to
Secondary is C/SiC materials, sheet metal and Glare laminates.Described C/SiC material thicknesses are 1-4mm.Described sheet metal can
For one kind in Mo, Nb or Ti metal and its alloy material, thickness is 0.3-0.5mm.Described Glare laminate thickness is 2-
5mm。
Beneficial effects of the present invention：（1）The material gathers ceramic base composite wood by method hot-forming at high temperature
The advantage of material, metal material and Glare plates so that the Fracture of Material is significantly improved, and notch sensitivity is greatly lowered, significantly
Improve the intensity and toughness of material；（2）The material preparation process is simple, reliably, and application easy to spread.
Brief description of the drawings
Fig. 1 is the sectional view that a kind of ceramic-metal-composite mixes multilayer material：
10 be C/SiC ceramic matric composites；20 be sheet metal；30 be Glare plates.
Embodiment
With reference to specific embodiment, the present invention is furture elucidated, it should be understood that these embodiments are merely to illustrate the present invention
Rather than limitation the scope of the present invention, after the present invention has been read, various equivalences of the those skilled in the art to the present invention
The modification of form falls within the application appended claims and limited.
Embodiment one
A kind of ceramic-metal-composite mixes multilayer material, it is characterised in that by C/SiC materials, sheet metal and Glare
Laminate is constituted, and its structure is laminated construction, is from top to bottom followed successively by C/SiC materials, sheet metal and Glare laminates.Described
C/SiC material thicknesses are 2mm.Described sheet metal is Mo metal materials, and thickness is 0.4mm.Described Glare laminate thickness
For 3mm.
Embodiment two
A kind of ceramic-metal-composite mixes multilayer material, it is characterised in that by C/SiC materials, sheet metal and Glare
Laminate is constituted, and its structure is laminated construction, is from top to bottom followed successively by C/SiC materials, sheet metal and Glare laminates.Described
C/SiC material thicknesses are 3mm.Described sheet metal is Ti metal materials, and thickness is 0.3mm.Described Glare laminate thickness
For 4mm.
Claims (1)
1. a kind of ceramic-metal-composite mixes multilayer material, it is characterised in that by C/SiC materials, sheet metal and
Glare laminates are constituted, and its structure is laminated construction, is from top to bottom followed successively by C/SiC materials, sheet metal and Glare laminates, C/
SiC material thickness is 1-4mm, and sheet metal can be any of Mo, Nb, Ti metal and its alloy material, and thickness is 0.3-
0.5mm, Glare laminate thickness are 2-5mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710604195.4A CN107225818A (en) | 2017-07-24 | 2017-07-24 | A kind of ceramic-metal composites mix multilayer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710604195.4A CN107225818A (en) | 2017-07-24 | 2017-07-24 | A kind of ceramic-metal composites mix multilayer material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107225818A true CN107225818A (en) | 2017-10-03 |
Family
ID=59956367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710604195.4A Pending CN107225818A (en) | 2017-07-24 | 2017-07-24 | A kind of ceramic-metal composites mix multilayer material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107225818A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114086090A (en) * | 2021-11-12 | 2022-02-25 | 吉林大学 | Continuous SiC fiber reinforced refractory metal matrix composite based on nano multilayer structure and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020164485A1 (en) * | 2001-02-26 | 2002-11-07 | Martin Laura Lee | Structural modified epoxy adhesive compositions |
| CN1623770A (en) * | 2004-12-17 | 2005-06-08 | 清华大学 | Metal/ceramic layered composite protective plate |
| CN103727357A (en) * | 2013-09-11 | 2014-04-16 | 太仓派欧技术咨询服务有限公司 | Ultrathin high-temperature-resistant thermal insulation material structure |
-
2017
- 2017-07-24 CN CN201710604195.4A patent/CN107225818A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020164485A1 (en) * | 2001-02-26 | 2002-11-07 | Martin Laura Lee | Structural modified epoxy adhesive compositions |
| CN1623770A (en) * | 2004-12-17 | 2005-06-08 | 清华大学 | Metal/ceramic layered composite protective plate |
| CN103727357A (en) * | 2013-09-11 | 2014-04-16 | 太仓派欧技术咨询服务有限公司 | Ultrathin high-temperature-resistant thermal insulation material structure |
Non-Patent Citations (2)
| Title |
|---|
| 亚伯 斯海维: "《结构与材料的疲劳（第2版）》", 31 January 2014, 航空工业出版社 * |
| 朱和国等: "《复合材料原理》", 31 July 2013, 国防工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114086090A (en) * | 2021-11-12 | 2022-02-25 | 吉林大学 | Continuous SiC fiber reinforced refractory metal matrix composite based on nano multilayer structure and preparation method and application thereof |
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Application publication date: 20171003 |
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