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CN107541798B - Device for eliminating electrostatic influence in electrospinning direct writing - Google Patents

Device for eliminating electrostatic influence in electrospinning direct writing Download PDF

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CN107541798B
CN107541798B CN201710962826.XA CN201710962826A CN107541798B CN 107541798 B CN107541798 B CN 107541798B CN 201710962826 A CN201710962826 A CN 201710962826A CN 107541798 B CN107541798 B CN 107541798B
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ion wind
motion platform
dimensional motion
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nozzle
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CN107541798A (en
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李好义
雷文龙
李轶
丁玉梅
张莉彦
谭晶
杨卫民
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Beijing University of Chemical Technology
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Abstract

本发明涉及一种用于电纺直写可消除静电影响的装置,属于静电纺丝的领域。主要包括主流道、三维运动平台、点胶喷头、离子风喷头、塑料软管、离子发生器、加热器和控制器。主流道外壁上端通过轴承和弹簧卡扣支撑有定制的齿轮盘,定制的齿轮盘通过同步电机、同步带转动,离子风喷头在旋转键、连接器、齿条、定制的齿轮盘、同步带和同步电机的调节下向纺丝路径的前端喷射离子风。本发明一种用于电纺直写可消除静电影响的装置,通过离子风来中和纤维上的电荷,从而减少或消除静电排斥的影响;通过喷头结构和控制器使得离子风朝着喷头相对运动斜前方的喷射,不影响静电纺丝的工艺。所以使用此装置,可以在不增加变量的情况下减少静电排斥实现精准定位。

Figure 201710962826

The invention relates to a device for electrospinning direct writing that can eliminate the influence of static electricity, and belongs to the field of electrospinning. It mainly includes main channel, three-dimensional motion platform, dispensing nozzle, ion wind nozzle, plastic hose, ion generator, heater and controller. The upper end of the outer wall of the main channel supports a customized gear plate through bearings and spring buckles. The customized gear plate is rotated by a synchronous motor and a synchronous belt. Under the adjustment of the synchronous motor, the ion wind is sprayed to the front end of the spinning path. The invention is a device for electrospinning direct writing that can eliminate the influence of static electricity. The ion wind is used to neutralize the charge on the fiber, thereby reducing or eliminating the influence of electrostatic repulsion; the structure of the nozzle and the controller make the ion wind face the nozzle. The jet that moves obliquely ahead does not affect the electrospinning process. Therefore, using this device, electrostatic repulsion can be reduced to achieve precise positioning without increasing variables.

Figure 201710962826

Description

一种用于电纺直写可消除静电影响的装置A device for electrospinning direct writing that can eliminate the influence of static electricity

技术领域technical field

本发明涉及一种用于电纺直写可消除静电影响的装置,属于静电纺丝的领域。The invention relates to a device for electrospinning direct writing capable of eliminating the influence of static electricity, which belongs to the field of electrospinning.

背景技术Background technique

近年来,随着科学技术的不断发展和研究的深入,微纳技术逐渐深入到日常生活的方方面面,二维(2D)纳米结构(如纳米纤维毡、纳米线、纳米带等)得益于其具有的小尺寸效应、表面或界面效应、超顺磁性等独特性质,在众多领域产生了广泛的应用。与2D结构的微纳米纤维相比,三维微纳米结构由于其在厚度上有明显提升,受到了学者们的广泛关注。In recent years, with the continuous development of science and technology and the deepening of research, micro-nano technology has gradually penetrated into all aspects of daily life. Two-dimensional (2D) nanostructures (such as nanofiber mats, nanowires, nanobelts, etc.) It has unique properties such as small size effect, surface or interface effect, superparamagnetism, etc., and has a wide range of applications in many fields. Compared with 2D micro-nanofibers, three-dimensional micro-nanostructures have attracted extensive attention from scholars due to their significantly improved thickness.

传统的三维微纳结构制备方法主要有模压成型法、激光微技术、光刻法和3D打印技术。3D打印作为一种增材制造技术逐渐受到人们的关注。但是传统3D打印在加工宏观器件时存在打印速度慢、消耗材料多、材料兼容性差等缺点,无法满足微纳制造的发展要求。而基于电液动力学原理的电纺直写技术工艺简单,材料兼容性好,高效,无污染,可制备微纳米尺度的纤维结构,在三维微纳米结构制造上展现出良好的应用前景。The traditional three-dimensional micro-nano structure preparation methods mainly include compression molding, laser microtechnology, photolithography and 3D printing technology. 3D printing has gradually attracted people's attention as an additive manufacturing technology. However, traditional 3D printing has shortcomings such as slow printing speed, high material consumption, and poor material compatibility when processing macroscopic devices, which cannot meet the development requirements of micro-nano manufacturing. The electrospinning direct writing technology based on the principle of electrohydraulic dynamics has simple process, good material compatibility, high efficiency, and no pollution. It can prepare micro-nano-scale fiber structures, and shows a good application prospect in the manufacture of three-dimensional micro-nano structures.

虽然这种新型的生产工艺,可以实现三维的微纳结构。但是在工艺过程中,存在着无法忽略的问题,静电排斥现象。因为整个过程是电场控制,在电纺过程中纤维会在电场力的作用下拉伸,纤维上会附带电荷。因此,在纤维沉积的过程中会产生静电排斥,从而降低了打印的精度。Although this new type of production process can realize three-dimensional micro-nano structure. However, in the process, there is a problem that cannot be ignored, the phenomenon of electrostatic repulsion. Because the whole process is controlled by the electric field, the fiber will be stretched under the action of the electric field force during the electrospinning process, and the fiber will be charged. Therefore, electrostatic repulsion occurs during fiber deposition, which reduces the printing accuracy.

发明内容Contents of the invention

针对存在静电排斥的问题,本发明提出了一种新型的三维直写纺丝装置,喷头连接离子发生器可在电纺过程中实现对纤维的静电消除,从而减少在打印过程中静电的影响。Aiming at the problem of electrostatic repulsion, the present invention proposes a new type of three-dimensional direct-writing spinning device. The nozzle is connected to the ion generator to realize the static elimination of the fiber during the electrospinning process, thereby reducing the influence of static electricity during the printing process.

实现上述目的的技术方案是:一种用于电纺直写可消除静电影响的装置,主要包括主流道、加热器、三维运动平台、点胶喷头、离子风喷头、塑料软管、离子发生器、静电发生器和电极板。主流道位于三维运动平台的上方,主流道固定在框架上,主流道的最下端是点胶喷头,主流道的外壁包覆有加热器;点胶喷头与静电发生器的接地端相连,电机板位于三维运动平台的工作台下端,电机板与三维运动平台的工作台绝缘,电极板与点胶喷头之间形成的静电场使得点胶喷头喷出的丝落在三维运动平台的工作台上完成直写;离子风喷头安装在主流道旁边,离子风喷头通过塑料软管与离子发生器连接,离子风喷头向三维运动平台上喷射离子风,以消除在三维运动平台上聚集的静电电荷。The technical solution to achieve the above purpose is: a device for electrospinning direct writing that can eliminate the influence of static electricity, mainly including a main flow channel, a heater, a three-dimensional motion platform, a dispensing nozzle, an ion wind nozzle, a plastic hose, and an ion generator , electrostatic generator and electrode plate. The main channel is located above the three-dimensional motion platform, and the main channel is fixed on the frame. The lower end of the main channel is a dispensing nozzle, and the outer wall of the main channel is covered with a heater; Located at the lower end of the worktable of the three-dimensional motion platform, the motor board is insulated from the workbench of the three-dimensional motion platform, and the electrostatic field formed between the electrode plate and the dispensing nozzle makes the filaments ejected from the dispensing nozzle fall on the workbench of the three-dimensional motion platform to complete Direct writing; the ion wind nozzle is installed next to the main channel, and the ion wind nozzle is connected to the ion generator through a plastic hose. The ion wind nozzle sprays ion wind on the three-dimensional motion platform to eliminate the electrostatic charge accumulated on the three-dimensional motion platform.

本发明一种用于电纺直写可消除静电影响的装置,主流道外壁上端通过轴承和弹簧卡扣支撑有定制的齿轮盘,定制的齿轮盘通过同步电机、同步带转动,定制的齿轮盘上固定有齿条,在齿条上安装有连接器,连接器连接有离子风喷头、旋转键,离子发生器通过塑料管连接到离子风喷头,离子风喷头在旋转键、连接器、齿条、定制的齿轮盘、同步带和同步电机的调节下向纺丝路径的前端喷射离子风。The invention is a device for electrospinning direct writing that can eliminate the influence of static electricity. The upper end of the main channel outer wall is supported by a bearing and a spring buckle with a customized gear plate. The customized gear plate is rotated by a synchronous motor and a synchronous belt. The customized gear plate is A rack is fixed on the rack, and a connector is installed on the rack. The connector is connected with an ion wind nozzle and a rotary key. The ion generator is connected to the ion wind nozzle through a plastic tube. , Customized gear disc, synchronous belt and synchronous motor are adjusted to spray ion wind to the front end of the spinning path.

本发明一种用于电纺直写可消除静电影响的装置,主流道固定不动,三维运动平台移动,加热器给主流道及点胶喷头加热。定制的齿轮盘套在主流道上间隙配合可旋转,由深沟球轴承和弹簧卡扣来固定其移动方向,同步电机通过同步带与其连接并控制其转动。齿条可以有两个,其中一个齿条与定制的齿轮盘焊接在一起,连接器可在此齿条上移动,控制离子风喷头与主流道的距离;另一个齿条安装在连接器内,控制离子风喷头距离三维运动平台的距离。离子风喷头可在齿条的移动来进行位置调节,由旋转键进行角度调节。离子喷头通过塑料软管和离子发生器连接。The invention is a device for electrospinning direct writing that can eliminate the influence of static electricity. The main channel is fixed, the three-dimensional motion platform moves, and the heater heats the main channel and the glue dispensing nozzle. The customized gear disc sleeve is rotatable with a clearance fit on the main channel, and its moving direction is fixed by deep groove ball bearings and spring buckles. The synchronous motor is connected to it through a synchronous belt and controls its rotation. There can be two racks, one of which is welded with a custom-made gear plate, and the connector can move on this rack to control the distance between the ion wind nozzle and the main channel; the other rack is installed in the connector, Control the distance between the ion wind nozzle and the three-dimensional motion platform. The position of the ion wind nozzle can be adjusted by the movement of the rack, and the angle can be adjusted by the rotation key. The ion spray head is connected with the ion generator through a plastic hose.

本发明是一种用于电纺直写可消除静电影响的装置,在工作的时候,加热器负责对主流道和点胶喷头进行加热,物料在主流道中熔融塑化,通过主流道中的柱塞对熔融物料进行挤出。The invention is a device for electrospinning direct writing that can eliminate the influence of static electricity. When working, the heater is responsible for heating the main channel and the dispensing nozzle. The material is melted and plasticized in the main channel, and passes through the plunger in the main channel. The molten material is extruded.

本发明一种用于电纺直写可消除静电影响的装置,在三维运动平台进行运动时,控制器会根据平台的X、Y方向的移动速度,计算出X、Y的合成速度方向向量的反方向,控制电机带动定制齿轮转动,使得离子出风口总是朝着运动前进的方向。The invention is a device for electrospinning direct writing that can eliminate the influence of static electricity. When the three-dimensional motion platform is moving, the controller will calculate the synthetic speed direction vector of X and Y according to the moving speed of the platform in the X and Y directions. In the opposite direction, the control motor drives the customized gear to rotate, so that the ion air outlet is always in the direction of motion.

本发明一种用于电纺直写可消除静电影响的装置,通过齿条和旋转键来调整离子出风口的位置和角度,保证在电纺过程中离子风是以斜向前的角度运动,从而使得前面的已有纤维电荷中和,保证后面的电纺纤维过程不受静电影响。在整个过程中不影响工艺参数,保证电纺过程正常运行。The invention is a device for electrospinning direct writing that can eliminate the influence of static electricity. The position and angle of the ion air outlet are adjusted through the rack and the rotation key to ensure that the ion wind moves at an oblique forward angle during the electrospinning process. Therefore, the charges of the existing fibers in the front are neutralized to ensure that the subsequent electrospun fiber process is not affected by static electricity. The process parameters are not affected during the whole process, ensuring the normal operation of the electrospinning process.

本发明一种用于电纺直写可消除静电影响的装置,为防止因离子风喷头在拐点移动速度过快而导致离子风不能及时地消除静电的影响,则当离子风喷头移动的路径转角超过120°时,开启在定制的齿轮盘上附加的离子风喷头的开关,直至原离子风喷头正常地指向纺丝移动方向,两个离子风喷头指向通样的方向时,关闭附加的离子风喷头。The present invention is a device for electrospinning direct writing that can eliminate the influence of static electricity. When it exceeds 120°, turn on the switch of the additional ion wind nozzle on the customized gear plate until the original ion wind nozzle normally points to the direction of spinning movement, and when the two ion wind nozzles point to the direction of the sample, turn off the additional ion wind nozzle nozzle.

本发明一种用于电纺直写可消除静电影响的装置,通过离子风来中和纤维上的电荷,从而减少或消除静电排斥的影响。除此之外通过喷头结构和控制器使得离子风朝着喷头相对运动斜前方的喷射,不影响静电纺丝的工艺。所以使用此装置,可以在不增加变量的情况下减少静电排斥实现精准定位。The invention is a device for electrospinning direct writing that can eliminate the influence of static electricity, neutralizes the charge on the fiber through ion wind, thereby reducing or eliminating the influence of static electricity repulsion. In addition, through the structure of the nozzle and the controller, the ion wind is sprayed towards the oblique front of the relative movement of the nozzle, which does not affect the electrospinning process. Therefore, using this device, it is possible to reduce electrostatic repulsion and achieve precise positioning without increasing variables.

附图说明Description of drawings

图1为本发明一种用于电纺直写可消除静电影响的装置的示意图。Fig. 1 is a schematic diagram of a device for electrospinning direct writing that can eliminate the influence of static electricity according to the present invention.

图2为本发明一种用于电纺直写可消除静电影响的装置喷头的局部放大图。Fig. 2 is a partially enlarged view of a spray head of a device for electrospinning direct writing that can eliminate the influence of static electricity according to the present invention.

图中:1-主流道、2-定制的齿轮盘、3-轴承、4-弹簧卡扣、5-加热器、6-点胶喷头、7-三维运动平台、8-离子风喷头、9-旋转键、10-塑料软管、11-连接器、12-齿条、13-离子发生器、14-同步电机、15-同步带。In the figure: 1- Main channel, 2- Customized gear plate, 3- Bearing, 4- Spring buckle, 5- Heater, 6- Dispensing nozzle, 7- Three-dimensional motion platform, 8- Ion wind nozzle, 9- Rotary key, 10-plastic hose, 11-connector, 12-rack, 13-ion generator, 14-synchronous motor, 15-synchronous belt.

具体实施方式Detailed ways

为本发明一种用于电纺直写可消除静电影响的装置,如图1和图2所示,主要包括主流道1、定制的齿轮盘2、轴承3、弹簧卡扣4、加热器5、点胶喷头6、三维运动平台7、离子风喷头8、旋转键9、塑料软管10、连接器11、齿条12、离子发生器13、同步电机14、同步带15、静电发生器和电极板。图中未画出静电发生器和电极板。主流道1位于三维运动平台7的上方,主流道1固定在框架上,主流道1的最下端是点胶喷头6,主流道1的外壁包覆有加热器5,主流道1外壁上端通过轴承3和弹簧卡扣4支撑有定制的齿轮盘2,定制的齿轮盘2通过同步电机14、同步带15转动,定制的齿轮盘2上固定有齿条12,在齿条12上安装有连接器11,连接器11连接有离子风喷头8、旋转键9,离子发生器13通过塑料管10连接到离子风喷头8,离子风喷头8在旋转键9和连接器11、齿条12、定制的齿轮盘2、同步带15和同步电机14的调节下向纺丝路径的前端喷射离子风。It is a device of the present invention that can eliminate the influence of static electricity for electrospinning direct writing, as shown in Figure 1 and Figure 2, it mainly includes a main channel 1, a customized gear plate 2, a bearing 3, a spring buckle 4, and a heater 5 , dispensing nozzle 6, three-dimensional motion platform 7, ion wind nozzle 8, rotary key 9, plastic hose 10, connector 11, rack 12, ion generator 13, synchronous motor 14, synchronous belt 15, electrostatic generator and electrode plate. The electrostatic generator and electrode plates are not shown in the figure. The main channel 1 is located above the three-dimensional motion platform 7, the main channel 1 is fixed on the frame, the lower end of the main channel 1 is a dispensing nozzle 6, the outer wall of the main channel 1 is covered with a heater 5, and the upper end of the main channel 1 outer wall passes through the bearing 3 and the spring buckle 4 are supported with a customized gear plate 2, the customized gear plate 2 is rotated by a synchronous motor 14 and a synchronous belt 15, a rack 12 is fixed on the customized gear plate 2, and a connector is installed on the rack 12 11. The connector 11 is connected with the ion wind nozzle 8 and the rotary key 9. The ion generator 13 is connected to the ion wind nozzle 8 through the plastic tube 10. Under the regulation of gear plate 2, synchronous belt 15 and synchronous motor 14, ion wind is sprayed to the front end of spinning path.

本发明一种用于电纺直写可消除静电影响的装置,在工作的时候,加热器5负责对主流道1及主流道1最下端的点胶喷头6进行加热,物料从放入主流道1中熔融塑化,通过主流道中的柱塞对熔融物料进行挤出。在三维运动平台7进行运动时,控制器会通过平台的X、Y方向的移动速度,计算出X、Y的合成速度方向向量的反方向,控制同步电机14通过同步带15带动定制的齿轮盘2转动,使得离子风喷头8的出风口总是朝着纺丝运动前进的方向。通过齿条12和旋转键9来调整离子出风口的角度,保证在电纺过程中离子风是以斜向前的角度运动,从而使得前面的已有纤维电荷中和,保证后面的电纺纤维不受静电影响。The invention is a device for electrospinning direct writing that can eliminate the influence of static electricity. When working, the heater 5 is responsible for heating the main channel 1 and the dispensing nozzle 6 at the lower end of the main channel 1, and the material is put into the main channel 1 Melting and plasticizing, the molten material is extruded through the plunger in the main channel. When the three-dimensional motion platform 7 is moving, the controller will calculate the opposite direction of the composite speed direction vector of X and Y through the moving speed of the platform in the X and Y directions, and control the synchronous motor 14 to drive the customized gear plate through the synchronous belt 15 2. Rotate so that the air outlet of the ion wind nozzle 8 is always in the direction that the spinning motion advances. The angle of the ion air outlet is adjusted by the rack 12 and the rotary key 9 to ensure that the ion wind moves at an oblique forward angle during the electrospinning process, so that the existing fibers in the front are neutralized to ensure that the electrospun fibers in the back Not affected by static electricity.

Claims (2)

1. An apparatus for eliminating electrostatic influence in electrospinning direct writing, characterized in that: the device mainly comprises a main runner, a heater, a three-dimensional motion platform, a dispensing nozzle, an ion wind nozzle, a plastic hose, an ion generator, an electrostatic generator and an electrode plate, wherein the main runner is positioned above the three-dimensional motion platform and is fixed on a frame, the dispensing nozzle is arranged at the bottommost end of the main runner, and the heater is coated on the outer wall of the main runner; the glue dispensing nozzle is connected with the grounding end of the electrostatic generator, the electrode plate is positioned at the lower end of the workbench of the three-dimensional motion platform, the electrode plate is insulated from the workbench of the three-dimensional motion platform, and the electrostatic field formed between the electrode plate and the glue dispensing nozzle enables wires sprayed out of the glue dispensing nozzle to fall on the workbench of the three-dimensional motion platform to finish direct writing; the ion wind spray head is arranged beside the main runner, is connected with the ion generator through a plastic hose and sprays ion wind on the three-dimensional motion platform; the upper end of the outer wall of the main runner is supported with a customized gear disc through a bearing and a spring buckle, the customized gear disc rotates through a synchronous motor and a synchronous belt, a rack is fixed on the customized gear disc, a connector is mounted on the rack, the connector is connected with an ion wind spray head and a rotary key, an ion generator is connected to the ion wind spray head through a plastic hose, and the ion wind spray head sprays ion wind to the front end of a spinning path under the adjustment of the rotary key, the connector, the rack, the customized gear disc, the synchronous belt and the synchronous motor; the two racks are arranged, one of the racks is welded with the customized gear disc, the connector can move on the rack, and the distance between the ion wind spray head and the main runner is controlled; the other rack is arranged in the connector and controls the distance between the ion wind spray head and the three-dimensional motion platform; when the three-dimensional motion platform moves, the controller calculates the opposite direction of the X, Y synthetic speed direction vector according to the X, Y direction moving speed of the platform, and controls the motor to drive the customized gear disc to rotate, so that the ion air outlet always faces the advancing direction of the spinning motion.
2. An apparatus for electrospinning direct writing capable of eliminating electrostatic influence as defined in claim 1, wherein: an additional ion wind spray head and a switch thereof are additionally arranged on the customized gear plate.
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