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CN107747042A - A kind of high reaming steel of the economical great surface quality of 690MPa levels and preparation method thereof - Google Patents

A kind of high reaming steel of the economical great surface quality of 690MPa levels and preparation method thereof Download PDF

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CN107747042A
CN107747042A CN201711080428.1A CN201711080428A CN107747042A CN 107747042 A CN107747042 A CN 107747042A CN 201711080428 A CN201711080428 A CN 201711080428A CN 107747042 A CN107747042 A CN 107747042A
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steel
surface quality
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690mpa
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汪创伟
李正荣
崔凯禹
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Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium

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  • Engineering & Computer Science (AREA)
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  • Physics & Mathematics (AREA)
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  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

本发明公开了一种690MPa级经济型高表面质量高扩孔钢及其制备方法,属于钢铁冶金和压延技术领域。690MPa级经济型高表面质量高扩孔钢,按重量百分比计,其化学成分为[C]、[Si]、[Mn]、[P]、[S]、[Alt]、[Ca]、[N]和[O],其余为Fe及不可避免的杂质。其制备方法包括以下步骤:冶炼工序→连铸工序→加热工序→粗轧工序→热卷箱工序→精轧工序→层流冷却工艺→卷取→缓慢冷却→酸洗工序→卷取包装。本发明通过对高扩孔钢化学成分及制备方法的控制,使高扩孔钢具有高表面质量、成本低、性能优异的特点,能够满足汽车底盘及复杂冲压件用钢的需求。

The invention discloses a 690MPa grade economical steel with high surface quality and high hole expansion and a preparation method thereof, belonging to the technical fields of iron and steel metallurgy and rolling. 690MPa grade economical high surface quality high hole reaming steel, by weight percentage, its chemical composition is [C], [Si], [Mn], [P], [S], [Alt], [Ca], [ N] and [O], the rest are Fe and unavoidable impurities. The preparation method comprises the following steps: smelting process→continuous casting process→heating process→rough rolling process→hot coil box process→finish rolling process→laminar flow cooling process→coiling→slow cooling→pickling process→coiling and packaging. The invention controls the chemical composition and preparation method of the high-hole-expanding steel, so that the high-hole-expanding steel has the characteristics of high surface quality, low cost and excellent performance, and can meet the requirements of steel for automobile chassis and complex stamping parts.

Description

一种690MPa级经济型高表面质量高扩孔钢及其制备方法A kind of 690MPa grade economical high surface quality high hole reaming steel and its preparation method

技术领域technical field

本发明属于钢铁冶金和压延技术领域,具体涉及一种690MPa级经济型高表面质量高扩孔钢及其制备方法。The invention belongs to the technical field of iron and steel metallurgy and rolling, and in particular relates to a 690MPa economical steel with high surface quality and high hole expansion and a preparation method thereof.

背景技术Background technique

为了汽车轻量化、降低油耗和改善整车安全性等,近年来许多新钢种的研发计划主要集中在开发具有良好成形性能的先进高强度钢(Advanced High Strength Steel,简称AHSS)。AHSS钢的种类很多,如铁素体/马氏体双相(Ferrite/Martensite Dual Phase,简称FMDP)钢、铁素体/贝氏体双相(Ferrite/Bainite Dual Phase,简称FBDP)钢、相变诱导塑性(Transformation Induced Plasticity,简称TRIP)钢、孪晶诱导塑性(TwinningInduced Plasicity,简称TWIP)钢、复相(Complex Phase,简称CP)钢、马氏体(Martensite,简称M)钢、淬火配分(Quenching andParitioning,简称Q&P)钢和热成形(Hot Formed,简称HF)钢等。In order to reduce the weight of automobiles, reduce fuel consumption, and improve vehicle safety, etc., many new steel research and development plans in recent years have mainly focused on the development of Advanced High Strength Steel (AHSS) with good formability. There are many types of AHSS steels, such as ferrite/martensite dual phase (Ferrite/Martensite Dual Phase, FMDP for short) steel, ferrite/bainite dual phase (Ferrite/Bainite Dual Phase, FBDP for short) steel, phase Transformation Induced Plasticity (TRIP) steel, Twinning Induced Plasicity (TWIP) steel, Complex Phase (CP) steel, Martensite (M) steel, quenching partition (Quenching and Paritioning, referred to as Q&P) steel and hot formed (Hot Formed, referred to as HF) steel.

AHSS钢的强化方式除了固溶、晶粒细化、析出等强化方式外,还有相变强化,这是普通高强钢所不具备的,是AHSS钢的主要强化方式之一。与普通高强度钢相比,AHSS钢成形性好、能量吸收率高、防撞凹性能好、烘烤硬化性能、屈服强度、加工硬化率高以及疲劳性能良好等优点,在汽车行业中越来越显示出其良好的应用情景。In addition to strengthening methods such as solid solution, grain refinement, and precipitation, the strengthening methods of AHSS steel also have phase transformation strengthening, which is not available in ordinary high-strength steels, and is one of the main strengthening methods of AHSS steel. Compared with ordinary high-strength steel, AHSS steel has the advantages of good formability, high energy absorption rate, good anti-collision performance, bake hardening performance, yield strength, high work hardening rate and good fatigue performance, etc., and is becoming more and more popular in the automotive industry. Shows its good application scenarios.

热轧高强度钢板用于制作汽车底盘、车轮等汽车行走部件,是实现车体减重的重要的有效途径之一。汽车底盘部件不外露,对钢板表面质量要求虽不甚严格,但由于其形状复杂,主要的成形包括:拉伸翻边、弯曲、扩孔和电火花成形等,这些成形方式对钢板的成形性,尤其是延伸凸缘性能要求较高。Hot-rolled high-strength steel plates are used to make automobile chassis, wheels and other automobile running parts, which is one of the important and effective ways to reduce the weight of the car body. Automobile chassis parts are not exposed, although the requirements for the surface quality of the steel plate are not very strict, but due to its complex shape, the main forming includes: stretch flanging, bending, reaming and EDM, etc. These forming methods have a great impact on the formability of the steel plate , especially the extended flange performance requirements are higher.

传统的FMDP钢在成形复杂汽车部件时(如:汽车底盘、车轮轮辋和轮辐等),存在变形能力差异很大的两相(F+M)界面,在成形过程中易在开孔部位开裂,延伸凸缘成形性能不够好,特别在闪光焊接后,易在热影响区(HAZ)发生马氏体回火软化,同时疲劳强度低,故无法满足成形需求。When traditional FMDP steels are used to form complex automobile parts (such as automobile chassis, wheel rims, and spokes, etc.), there are two-phase (F+M) interfaces with great differences in deformation ability, which are easy to crack at the opening parts during the forming process. The formability of the extended flange is not good enough, especially after flash welding, it is easy to temper and soften the martensite in the heat-affected zone (HAZ), and the fatigue strength is low at the same time, so it cannot meet the forming requirements.

FBDP钢也称延伸凸缘(Stretch-Flangeable,简称SF)钢或高扩孔(High Hole-Expansion,简称HHE)钢,当贝氏体含量为10%~20%时,其具有非常良好的成形性能,尤其是延伸凸缘性能。相对于HSLA(高强度低合金钢,High Strength LowAlloy Steel)和FMDP钢,FBDP钢的主要优点是提高了剪切边延展性,兼顾强度和延伸性的矛盾与平衡,并且其焊接、疲劳以及扩孔性能良好,具有一般材料不可比拟的优点;FBDP钢在闪光焊接后热影响区的硬度高于基体金属,随后加工时不会出现软化现象,同时该钢板具有良好的轻度-疲劳性能配合,与同等强度级别的HSLA钢相比,FBDP钢应变硬化指数(n值)和总延伸率较高,故FBDP钢更适合于冲压类似汽车底盘等要求较高,且延伸性能良好的部件。FBDP steel is also called Stretch-Flangeable (SF for short) steel or High Hole-Expansion (HHE for short) steel. When the bainite content is 10% to 20%, it has very good formability. performance, especially extended flange performance. Compared with HSLA (High Strength Low Alloy Steel) and FMDP steel, the main advantage of FBDP steel is that it improves the shear edge ductility, taking into account the contradiction and balance of strength and ductility, and its welding, fatigue and expansion Pore performance is good, which has incomparable advantages of general materials; the hardness of FBDP steel in the heat-affected zone after flash welding is higher than that of the base metal, and there will be no softening phenomenon during subsequent processing. At the same time, the steel plate has good light-fatigue performance. Compared with HSLA steel of the same strength level, FBDP steel has higher strain hardening index (n value) and total elongation, so FBDP steel is more suitable for stamping parts with high requirements and good elongation performance, such as automobile chassis.

20世纪90年代,美国、日本等相继开发了440~780MPa级高扩孔性能的热轧FB钢板,其扩孔率为70%~131%,主要应用于成形性,尤其是翻边性能要求良好的汽车底盘、车轮等部件,由于其含有较多贵重合金元素Cr、Nb、Ti、V和Mo等,虽然在冷速较低的条件下可以获得铁素体/贝氏体双相组织,但其成本较高。In the 1990s, the United States and Japan successively developed hot-rolled FB steel plates with high hole expansion performance of 440-780MPa. The hole expansion rate is 70% to 131%. It is mainly used in formability, especially good flanging performance. Automobile chassis, wheels and other parts, because they contain more precious alloy elements Cr, Nb, Ti, V and Mo, etc., although the ferrite/bainite dual phase structure can be obtained under the condition of low cooling rate, but Its cost is higher.

发明内容Contents of the invention

本发明所要解决的技术问题是提供一种690MPa级经济型高表面质量高扩孔钢,该经济型高表面质量高扩孔钢不含Cr、Nb、Ti、V和Mo等贵重合金元素,同时具有良好的扩孔性能、成形性能、显微组织性能、冲压性能、各向同性等优点。The technical problem to be solved by the present invention is to provide a 690MPa economical steel with high surface quality and high hole expansion, which does not contain precious alloy elements such as Cr, Nb, Ti, V and Mo, and at the same time It has the advantages of good hole expansion performance, formability, microstructure performance, stamping performance, isotropy and so on.

本发明解决上述技术问题所采用的技术方案是提供一种690MPa级经济型高表面质量高扩孔钢,按重量百分比计,其化学成分为:[C]:0.055%~0.095%,[Si]:0.85%~1.50%,[Mn]:1.30%~1.80%,[P]:0.010%~0.020%,[S]:≤0.003%,[Alt]:0.010%~0.050%,[Ca]:0.0010%~0.0050%,[N]:≤0.0050%,[O]:≤0.0040%,其余为Fe及不可避免的杂质,且[C]×[Mn]×104≤0.15,{[P]+10×[S]}×102≤0.04,[Ca]/[S]≥0.3。The technical solution adopted by the present invention to solve the above-mentioned technical problems is to provide a 690MPa-level economical high-surface-quality high-hole reaming steel, and its chemical composition is: [C]: 0.055% to 0.095%, [Si] : 0.85%~1.50%, [Mn]: 1.30%~1.80%, [P]: 0.010%~0.020%, [S]: ≤0.003%, [Alt]: 0.010%~0.050%, [Ca]: 0.0010 %~0.0050%, [N]: ≤0.0050%, [O]: ≤0.0040%, the rest is Fe and unavoidable impurities, and [C]×[Mn]×10 4 ≤0.15, {[P]+10 ×[S]}×10 2 ≤0.04, [Ca]/[S]≥0.3.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢中,所述690MPa级经济型高表面质量高扩孔钢的厚度规格为1.4~6.0mm。Wherein, in the above-mentioned 690MPa grade economical high surface quality high hole reaming steel, the thickness specification of the 690MPa grade economical high surface quality high hole reaming steel is 1.4-6.0mm.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢中,所述690MPa级经济型高表面质量高扩孔钢的显微组织结构由铁素体和贝氏体组成。Wherein, in the above-mentioned 690MPa grade economical high surface quality high hole reaming steel, the microstructure of the 690MPa grade economical high surface quality high hole reaming steel is composed of ferrite and bainite.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的屈服强度(Rel(或Pp0.2))为450~550MPa,抗拉强度(Rm)为≥690MPa,扩孔率(λ)为≥75%,断后延伸率(A80)为≥19%,180°冷弯试验D=0a合格;其中,拉伸试样的平行段标距L0=80mm,平行段宽度b=20mm;冷弯试验中D为弯心直径,a为钢带厚度。Among them, the yield strength (R el (or P p0.2 )) of the above-mentioned 690MPa grade economical high surface quality and high hole expansion steel is 450-550MPa, the tensile strength (R m ) is ≥690MPa, and the hole expansion rate (λ) is ≥75%, the elongation after break (A 80 ) is ≥19%, and the 180° cold bending test D=0a is qualified; wherein, the parallel section gauge length L 0 of the tensile sample = 80mm, and the parallel section width b =20mm; in the cold bending test, D is the diameter of the bending center, and a is the thickness of the steel strip.

本发明还提供了上述690MPa级经济型高表面质量高扩孔钢的制备方法,包括以下步骤:冶炼工序→连铸工序→加热工序→粗轧工序→热卷箱工序→精轧工序→层流冷却工艺→卷取→缓慢冷却→酸洗工序→卷取包装。The present invention also provides a preparation method for the above-mentioned 690MPa-level economical high-surface-quality high-hole reaming steel, comprising the following steps: smelting process→continuous casting process→heating process→rough rolling process→hot coil box process→finish rolling process→laminar flow Cooling process → coiling → slow cooling → pickling process → coiling and packaging.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述冶炼工序中按照690MPa级经济型高表面质量高扩孔钢的相应化学成分进行冶炼;采用LF脱硫处理,控制S含量。Among them, in the above-mentioned preparation method of 690MPa economical high surface quality high hole reaming steel, the smelting process is carried out according to the corresponding chemical composition of 690MPa economical high surface quality high reaming steel; LF desulfurization treatment is adopted , to control the S content.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述连铸工序中,采用低过热度浇铸,过热度控制在20~25℃,采用倒角结晶器,连铸成板坯。Wherein, in the preparation method of 690MPa grade economical high surface quality and high hole reaming steel mentioned above, in the continuous casting process, casting with low superheat is adopted, the superheat is controlled at 20-25°C, and a chamfering crystallizer is used. Continuous casting into slabs.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述加热工序中连铸板坯出炉温度为1200±30℃。Wherein, in the above-mentioned preparation method of 690MPa grade economical steel with high surface quality and high hole expansion, the continuous casting slab temperature in the heating process is 1200±30°C.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述粗轧工序中进行除鳞,除鳞水压力≥20MPa,除磷喷嘴角度为40~50°。Wherein, in the above-mentioned preparation method of 690MPa grade economical high surface quality and high hole reaming steel, descaling is carried out in the rough rolling process, the descaling water pressure is ≥20MPa, and the phosphorus removal nozzle angle is 40-50°.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述热卷箱工序中进行除鳞,除鳞水压力≥20MPa,除磷喷嘴角度为40~50°。Wherein, in the above-mentioned preparation method of 690MPa grade economical high surface quality high hole reaming steel, descaling is carried out in the hot coil box process, the descaling water pressure is ≥ 20MPa, and the phosphorus removal nozzle angle is 40-50°.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述精轧工序中进行除鳞,除鳞水压力≥20MPa,除磷喷嘴角度为40~50°。Wherein, in the above-mentioned preparation method of 690MPa grade economical high surface quality high hole reaming steel, descaling is carried out in the finishing rolling process, the descaling water pressure is ≥ 20MPa, and the phosphorus removal nozzle angle is 40-50°.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,经粗轧工序得中间坯,进入热卷箱,卷取破鳞,采用除鳞水除鳞,除鳞水压力≥20MPa,除磷喷嘴角度为40~50°。Among them, in the preparation method of the above-mentioned 690MPa grade economical high surface quality and high hole reaming steel, the intermediate billet is obtained through the rough rolling process, enters the hot coil box, coils and breaks the scale, and uses the descaling water to descale, and the descaling water The pressure is ≥20MPa, and the angle of the dephosphorization nozzle is 40-50°.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述粗轧工序中粗轧出口的中间坯厚度为40±3mm。Wherein, in the above-mentioned preparation method of 690MPa grade economical high surface quality and high hole expansion steel, the thickness of the intermediate billet at the rough rolling exit in the rough rolling process is 40±3mm.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述精轧工序中精轧入口温度为1080±40℃,终轧温度为820~880℃,精轧出口厚度为1~6mm。Wherein, in the above-mentioned preparation method of 690MPa grade economical high-surface-quality high-hole reaming steel, the finishing rolling entrance temperature in the finishing rolling process is 1080±40°C, the finish rolling temperature is 820-880°C, and the finish rolling exit The thickness is 1-6mm.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述层流冷却工艺中采用双段冷却方式,以不低于26℃/s的冷却速度快速冷却650~700℃,然后空冷7~12s,随后以不低于18℃/s的冷却速度快速冷却至400~470℃;所述卷取的卷取温度为400~470℃;所述缓慢冷却为卷取后缓慢冷却至280~350℃,再自然冷却至40℃以下。Among them, in the preparation method of 690MPa economical high surface quality and high hole reaming steel described above, the laminar flow cooling process adopts a double-stage cooling method to rapidly cool 650~ 700°C, then air-cooled for 7-12s, and then rapidly cooled to 400-470°C at a cooling rate not lower than 18°C/s; the coiling temperature of the coiling is 400-470°C; the slow cooling is coiling Then slowly cool to 280-350°C, and then naturally cool to below 40°C.

其中,上述所述的690MPa级经济型高表面质量高扩孔钢的制备方法中,所述酸洗工序中拉矫延伸率为0.8~1.8%,酸洗槽HCl酸液温度为55~85℃,酸洗槽游离酸HCl浓度为50~160g/L,酸洗槽Fe2+浓度为50~140g/L,酸洗速度为60~120m/min,漂洗槽温度为50±10℃,烘干机组稳定为85±5℃。Wherein, in the above-mentioned preparation method of 690MPa grade economical high surface quality and high hole reaming steel, the tensile elongation rate in the pickling process is 0.8-1.8%, and the temperature of the HCl acid solution in the pickling tank is 55-85°C , the concentration of free acid HCl in the pickling tank is 50-160g/L, the concentration of Fe 2+ in the pickling tank is 50-140g/L, the pickling speed is 60-120m/min, the temperature of the rinsing tank is 50±10°C, and the drying The unit is stable at 85±5°C.

本发明的有益效果是:The beneficial effects of the present invention are:

本发明690MPa级经济型高表面质量高扩孔钢采用“低C+Si+Mn”合金化处理技术,不添加Cr、Nb、Ti、V和Mo等贵重合金元素,显著降低了钢质的合金成本,从材质方面实现了经济型;本发明经济型高表面质量高扩孔钢制备成本低、工艺简单,其屈服强度(Rel(或Pp0.2))为450~550MPa,抗拉强度(Rm)为≥690MPa,扩孔率(λ)为≥75%,断后延伸率(A80)为≥19%,180°冷弯试验D=0a合格;具有良好的扩孔性能、成形性能、显微组织性能、冲压性能、各向同性等优点,满足汽车底盘及复杂冲压件用钢的需求。The 690MPa grade economical high surface quality and high reaming steel of the present invention adopts the "low C + Si + Mn" alloying treatment technology, does not add precious alloy elements such as Cr, Nb, Ti, V and Mo, and significantly reduces the alloying properties of the steel. Cost, realized economical type from the aspect of material; The preparation cost of the economical type high surface quality high reaming steel of the present invention is low, and process is simple, and its yield strength (R el (or P p0.2 )) is 450~550MPa, and tensile strength (R m ) ≥ 690MPa, hole expansion rate (λ) ≥ 75%, elongation after fracture (A 80 ) ≥ 19%, 180° cold bending test D = 0a qualified; has good hole expansion performance and formability , microstructure performance, stamping performance, isotropy and other advantages, to meet the needs of steel for automobile chassis and complex stamping parts.

本发明通过控制钢的化学成分及其制备方法,得到了一种690MPa级经济型高表面质量高扩孔钢:设计合理的化学成分范围,采用热机械控制工艺(Thermo MechanicalControl Process,简称TMCP)工艺技术和控轧控冷技术,配以合理的快速冷却速率和卷取温度区间采用,一方面可有效细化铁素体晶粒,另一方面可获得比例适中、形态及分布理想的贝氏体组织,实现钢带铁素体和贝氏体的显微组织结构,工艺控制简单、易生产,无需后续热处理工序,缩短生产工序,节约了工序成本;通过化学成分设计、冶炼工序钢质的夹杂物有效控制、连铸工序倒角结晶器的使用和低过热度浇铸,获得高品质的铸坯;热轧工序采用控制除鳞次数和除鳞水压力,以及酸洗工序破鳞工艺和酸洗工艺,获得高表面质量的产品。The present invention obtains a 690MPa-level economical high-surface-quality high-reaming steel by controlling the chemical composition of the steel and its preparation method: a reasonable chemical composition range is designed, and a thermomechanical control process (Thermo Mechanical Control Process, TMCP for short) process is adopted Technology and controlled rolling and controlled cooling technology, combined with reasonable rapid cooling rate and coiling temperature range, can effectively refine ferrite grains on the one hand, and obtain bainite with moderate proportion, ideal shape and distribution on the other hand microstructure of steel strip ferrite and bainite, the process control is simple, easy to produce, no subsequent heat treatment process is required, the production process is shortened, and the process cost is saved; through the design of chemical composition and the inclusion of steel in the smelting process Effective control of material, the use of chamfering crystallizers in the continuous casting process and low superheat casting to obtain high-quality slabs; the hot rolling process adopts the control of descaling times and descaling water pressure, as well as the descaling process and pickling in the pickling process process to obtain products of high surface quality.

附图说明Description of drawings

图1为本发明实施例1实验组2的酸洗成品金相组织;Fig. 1 is the pickling finished metallographic structure of the experimental group 2 of embodiment 1 of the present invention;

图2为本发明实施例1实验组5的酸洗成品金相组织。Fig. 2 is the metallographic structure of the pickling finished product of the experimental group 5 of Example 1 of the present invention.

具体实施方式Detailed ways

具体的,一种抗拉强度为690MPa级经济型高表面质量高扩孔钢,按重量百分比计,其化学成分为:[C]:0.055%~0.095%,[Si]:0.85%~1.50%,[Mn]:1.30%~1.80%,[P]:0.010%~0.020%,[S]:≤0.003%,[Alt]:0.010%~0.050%,[Ca]:0.0010%~0.0050%,[N]:≤0.0050%,[O]:≤0.0040%,其余为Fe及不可避免的杂质,且[C]×[Mn]×104≤0.15,{[P]+10×[S]}×102≤0.04,[Ca]/[S]≥0.3。Specifically, an economical high-surface-quality high-hole reaming steel with a tensile strength of 690 MPa, its chemical composition is: [C]: 0.055% to 0.095%, [Si]: 0.85% to 1.50% by weight percentage , [Mn]: 1.30% to 1.80%, [P]: 0.010% to 0.020%, [S]: ≤0.003%, [Alt]: 0.010% to 0.050%, [Ca]: 0.0010% to 0.0050%, [ N]: ≤0.0050%, [O]: ≤0.0040%, the rest is Fe and unavoidable impurities, and [C]×[Mn]×10 4 ≤0.15, {[P]+10×[S]}× 10 2 ≤0.04, [Ca]/[S]≥0.3.

本发明690MPa级经济型高表面质量高扩孔钢中必须具备一定含量的C,以便促进碳化物强化相的形成,进而保证钢带的强度级别;研究发现C含量过高时,析出的碳化物颗粒增大,不利于钢板扩孔性能;C含量过低时,强度达不到设计要求;本发明将C含量控制在0.055%~0.095%。The 690MPa grade economical high surface quality and high hole reaming steel of the present invention must have a certain content of C, so as to promote the formation of carbide strengthening phase, and then ensure the strength level of the steel strip; it is found that when the C content is too high, the precipitated carbide The increase of particles is not conducive to the hole expansion performance of the steel plate; when the C content is too low, the strength cannot meet the design requirements; the present invention controls the C content at 0.055% to 0.095%.

Si在钢中具有固溶强化作用,可同时提高钢带的强度和延伸率,改善钢带的成形性能,本发明控制Si含量为0.85%~1.50%;然而,Si含量较高时,钢带表面易产生Fe2SiO4红锈,在酸洗时不易祛除,为提高钢带表面质量,本发明设计了适合该钢种的除鳞方式和酸洗工艺。Si has solid solution strengthening effect in steel, can improve the strength and elongation of steel strip simultaneously, improve the formability of steel strip, the present invention controls Si content to be 0.85%~1.50%; However, when Si content is higher, steel strip The surface is easy to produce Fe 2 SiO 4 red rust, which is difficult to remove during pickling. In order to improve the surface quality of the steel strip, the present invention designs a descaling method and pickling process suitable for this steel type.

Mn属于固溶强化元素,根据本发明钢种的强度要求,当Mn含量过低时,强度将达不到设计要求;Mn含量过高,将增加珠光体的比例,且高Mn时极易导致铸坯Mn成分偏析,这是导致钢带出现带状组织的主要原因之一,而带状组织将会使钢带的扩孔性能急剧下降,因此,本发明控制Mn含量为1.30%~1.80%;同时,对碳锰钢而言,C和Mn的交互作用,对珠光体组织的形成和分布有一定的影响,二者含量过高时,[C]×[Mn]乘积增大,易产生珠光体粗大和带状组织,故本发明对C、Mn含量的匹配提出了控制要求,即[C]×[Mn]≤0.15。Mn belongs to the solid solution strengthening element. According to the strength requirements of the steel grade of the present invention, when the Mn content is too low, the strength will not meet the design requirements; if the Mn content is too high, the proportion of pearlite will be increased, and it is very easy to cause The segregation of the Mn composition of the slab is one of the main reasons for the banded structure of the steel strip, and the banded structure will sharply reduce the hole expansion performance of the steel strip. Therefore, the present invention controls the Mn content to 1.30% to 1.80%. ; At the same time, for carbon-manganese steel, the interaction between C and Mn has a certain influence on the formation and distribution of pearlite structure. The pearlite is coarse and banded, so the present invention puts forward control requirements for the matching of C and Mn contents, that is, [C]×[Mn]≤0.15.

P作为强化铁素体元素最强的元素,具有很强的固溶强化作用和冷作硬化作用,作为合金元素使用时,能提高其强度和钢带的耐大气腐蚀性能,但含量过高时,钢带的冷冲压性能将急剧下降,同时,会出现连铸板坯成分偏析,引起组织不均匀,增加回火脆性,显著降低钢带的塑性和韧性,从而使钢带在冷加工时出现“冷脆”现象而脆裂;此外,P在碳锰钢中属杂质元素,故其含量也不宜过高,通常含量不应大于0.030%~0.040%。本发明为了充分利用P的固溶强化作用,减小钢带力学性能波动,同时尽量降低P的作用,控制P含量为0.010%~0.020%。P, as the strongest ferrite strengthening element, has strong solid solution strengthening and cold hardening effects. When used as an alloying element, it can improve its strength and the atmospheric corrosion resistance of the steel strip, but when the content is too high , the cold stamping performance of the steel strip will drop sharply. At the same time, the composition of the continuous casting slab will segregate, causing uneven structure, increasing temper brittleness, and significantly reducing the plasticity and toughness of the steel strip, so that the steel strip will appear during cold working. In addition, P is an impurity element in carbon-manganese steel, so its content should not be too high, usually the content should not exceed 0.030% to 0.040%. In order to make full use of the solid solution strengthening effect of P, reduce the fluctuation of the mechanical properties of the steel strip, and at the same time reduce the effect of P as much as possible, the content of P is controlled to be 0.010%-0.020%.

S是钢中的杂质元素,在钢中易形成MnS,钢中的硫化物数量和形态直接影响钢带的扩孔性能,特别是条状硫化物夹杂在变形过程中易产生裂纹,故在设计化学成分时必须降低S含量,本发明控制S含量为≤0.003%,且要求[P]+10×[S]≤0.04。S is an impurity element in steel, and it is easy to form MnS in steel. The quantity and form of sulfide in steel directly affect the hole expansion performance of steel strip, especially strip-shaped sulfide inclusions are prone to cracks during deformation, so in the design The S content must be reduced during the chemical composition, and the present invention controls the S content to be ≤0.003%, and requires [P]+10×[S]≤0.04.

Al元素作为钢中优良的脱氧元素,可减少钢中的氧化物夹杂,提高钢质纯净度,从而提高钢带的成形性能,脱氧后绝大部分的Al2O3作为氧化物保护渣上浮至钢液上层,从而降低钢中的氧含量,剩余的单质Al溶入钢中,称之为酸溶铝(Als),同时,极少的Al2O3也会滞留在钢中形成Al2O3夹杂物,降低钢带的成形性能,单质Al和Al2O3的含量总和称为总铝(Alt),故本发明为使钢中必须含有一定量的Als,同时降低Al2O3夹杂物含量,Alt含量不易过高,本发明经济型高表面质量高扩孔钢中控制Alt为0.010%~0.050%。As an excellent deoxidizing element in steel, Al element can reduce oxide inclusions in steel, improve steel purity, and thus improve the formability of steel strip. After deoxidation, most of Al 2 O 3 floats up to The upper layer of molten steel reduces the oxygen content in the steel, and the remaining elemental Al dissolves into the steel, which is called acid-soluble aluminum (Als). At the same time, very little Al 2 O 3 will also remain in the steel to form Al 2 O 3 inclusions, reducing the formability of the steel strip, the sum of the contents of elemental Al and Al 2 O 3 is called total aluminum (Alt), so the present invention must contain a certain amount of Als in the steel, and at the same time reduce the inclusion of Al 2 O 3 The Alt content is not easy to be too high, and the Alt is controlled to be 0.010% to 0.050% in the economical high surface quality high hole reaming steel of the present invention.

Ca作为改性钢中硫化物类、氧化物类和硅酸盐类等夹杂的重要元素,可改变这些夹杂物的形状和组成,促块状、进链状和条状硫化物转变成球状,从而提高钢带的塑性和韧性,进而提高钢带的耐疲劳性能;此外,发明人在实践中发现:Ca可改善钢带的各向异性,促进钢带的等向性能,随着[Ca]/[S]的升高,钢带的等向性能呈上升趋势;当[Ca]/[S]=0.2时,钢带横向和纵向的冲击韧性值之比为0.85;当[Ca]/[S]≥0.3时,钢带横向和纵向的冲击韧性值之比接近于1,因此本发明控制Ca含量为0.0010%~0.0050%,且要求[Ca]/[S]≥0.3。Ca, as an important element of inclusions such as sulfides, oxides and silicates in modified steel, can change the shape and composition of these inclusions, and promote the transformation of massive, chain-like and strip-like sulfides into spherical shapes. Thereby improving the plasticity and toughness of the steel strip, and then improving the fatigue resistance of the steel strip; in addition, the inventor finds in practice: Ca can improve the anisotropy of the steel strip, promote the isotropic performance of the steel strip, with [Ca] As /[S] increases, the isotropic performance of the steel strip shows an upward trend; when [Ca]/[S]=0.2, the ratio of the transverse and longitudinal impact toughness values of the steel strip is 0.85; when [Ca]/[ When S]≥0.3, the ratio of impact toughness values in the transverse direction and longitudinal direction of the steel strip is close to 1, so the present invention controls the Ca content to be 0.0010%-0.0050%, and requires [Ca]/[S]≥0.3.

N可与合金元素结合生产非金属夹杂,降低了合金元素的作用,被视为有害元素,因此本发明控制N含量为≤0.0050%;钢带中残存的氧,或扩散到钢带表面的氧,均易使晶界氧化物形成脆性的氧化物夹层,在随后的变形加工时引起晶间裂纹,从而导致工件开裂,故钢带中的氧含量应尽量低,本发明控制O含量为≤0.0040%。N can be combined with alloying elements to produce non-metallic inclusions, which reduces the effect of alloying elements and is regarded as a harmful element. Therefore, the present invention controls the N content to be ≤0.0050%; the residual oxygen in the steel strip, or the oxygen diffused to the surface of the steel strip , are easy to make grain boundary oxides form brittle oxide interlayers, causing intergranular cracks during subsequent deformation processing, thereby causing cracks in the workpiece, so the oxygen content in the steel strip should be as low as possible. The present invention controls the O content to be ≤0.0040 %.

本发明690MPa级经济型高表面质量高扩孔钢一方面采用“低C+Si+Mn”合金化处理技术,不添加Cr、Nb、Ti、V和Mo等贵重合金元素,显著降低了钢质的合金成本,从材质方面实现了经济型;另一方面,本发明经济型高表面质量高扩孔钢的屈服强度(Rel(或Pp0.2))为450~550MPa,抗拉强度(Rm)为≥690MPa,扩孔率(λ)为≥75%,断后延伸率(A80)为≥19%,180°冷弯试验D=0a合格;具有良好的扩孔性能、成形性能、显微组织性能、冲压性能、各向同性等优点,满足汽车底盘及复杂冲压件用钢的需求。The 690MPa grade economical high surface quality and high hole reaming steel of the present invention adopts the "low C + Si + Mn" alloying treatment technology on the one hand, does not add precious alloy elements such as Cr, Nb, Ti, V and Mo, and significantly reduces the steel quality. The cost of the alloy realizes economy from the aspect of material; on the other hand, the yield strength (R el (or P p0.2 )) of the economical high surface quality high hole expansion steel of the present invention is 450~550MPa, and the tensile strength ( R m ) is ≥690MPa, hole expansion rate (λ) is ≥75%, elongation after fracture (A 80 ) is ≥19%, and 180° cold bending test D=0a is qualified; it has good hole expansion performance, formability, Microstructure performance, stamping performance, isotropy and other advantages meet the needs of steel for automobile chassis and complex stamping parts.

其中,上述所述的抗拉强度为690MPa级经济型高表面质量高扩孔钢中,所述经济型高表面质量高扩孔钢的厚度规格为1.4~6.0mm。Wherein, among the above-mentioned economical high surface quality high hole reaming steels with a tensile strength of 690 MPa, the thickness specification of the economical high surface quality high hole reaming steels is 1.4-6.0 mm.

本发明还提供了上述抗拉强度为690MPa级经济型高表面质量高扩孔钢的制备方法,包括以下步骤:冶炼与连铸工序→加热工序→粗轧工序→热卷箱工序→精轧工序→层流冷却工艺→酸洗工序→卷取包装。The present invention also provides a preparation method for the above-mentioned economical high-surface-quality high-hole reaming steel with a tensile strength of 690 MPa, which includes the following steps: smelting and continuous casting process→heating process→rough rolling process→hot coil box process→finish rolling process → Laminar cooling process → Pickling process → Coiling and packaging.

在冶炼工序中,应按照以下化学成分范围进行冶炼,其化学成分重量百分比如下,[C]:0.055%~0.095%,[Si]:0.85%~1.50%,[Mn]:1.30%~1.80%,[P]:0.010%~0.020%,[S]:≤0.003%,[Alt]:0.010%~0.050%,[Ca]:0.0010%~0.0050%,[N]:≤0.0050%,[O]:≤0.0040%,其余为Fe及不可避免的杂质,且[C]×[Mn]×104≤0.15,{[P]+10×[S]}×102≤0.04,[Ca]/[S]≥0.3。In the smelting process, smelting should be carried out according to the following chemical composition range, and the weight percentage of the chemical composition is as follows, [C]: 0.055% ~ 0.095%, [Si]: 0.85% ~ 1.50%, [Mn]: 1.30% ~ 1.80% , [P]: 0.010% to 0.020%, [S]: ≤0.003%, [Alt]: 0.010% to 0.050%, [Ca]: 0.0010% to 0.0050%, [N]: ≤0.0050%, [O] : ≤0.0040%, the rest is Fe and unavoidable impurities, and [C]×[Mn]×10 4 ≤0.15, {[P]+10×[S]}×10 2 ≤0.04, [Ca]/[ S]≥0.3.

针对本发明设计的经济型高表面质量高扩孔钢的化学成分,发明人对其制备方法中各工艺操作及参数进行大量尝试。Aiming at the chemical composition of the economical, high-surface-quality, and high-hole reaming steel designed by the present invention, the inventors made a lot of attempts on various process operations and parameters in its preparation method.

本发明在冶炼工序中采用LF脱硫处理,成品[S]≤0.003%,保证了S含量足够低;连铸过程中采用低过热度浇铸,过热度控制在20~25℃,可降低铸坯心部成分偏析,同时采用倒角结晶器,可极大降低铸坯角部出现裂纹的风险,避免后续起皮。The invention adopts LF desulfurization treatment in the smelting process, and the finished product [S]≤0.003%, which ensures that the S content is low enough; in the continuous casting process, low superheat casting is adopted, and the superheat is controlled at 20-25°C, which can reduce the core of the slab. Partial component segregation and the use of chamfering molds can greatly reduce the risk of cracks at the corners of the slab and avoid subsequent peeling.

在加热工序中,控制连铸板坯出炉温度为1200±30℃。In the heating process, the continuous casting slab temperature is controlled to be 1200±30°C.

在粗轧工序和精轧工序中进行除鳞,包括:在粗轧工序中,要求全程除鳞,除鳞水压力≥20Mpa,除磷喷嘴角度为40~50°;经粗轧工序获得中间坯,进入热卷箱工序中,中间坯卷取破鳞,要求全程采用除鳞水除鳞,除鳞水压力≥20MPa,除磷喷嘴角度为40~50°;然后进入精轧工序,钢带出在精轧出口处进行除鳞,除鳞水压力≥20MPa,除磷喷嘴角度为40~50°。Descaling is carried out in the rough rolling process and the finishing rolling process, including: in the rough rolling process, the whole process of descaling is required, the descaling water pressure is ≥ 20Mpa, and the angle of the dephosphorization nozzle is 40-50°; the intermediate billet is obtained through the rough rolling process , enter the hot coil box process, the intermediate billet is coiled and descaled, and it is required to use descaling water to descale the whole process. Descaling is carried out at the exit of the finish rolling, the pressure of the descaling water is ≥20MPa, and the angle of the dephosphorization nozzle is 40-50°.

此外,本发明还控制粗轧出口的中间坯厚度为40±3mm;精轧工序中,精轧入口温度为1080±40℃,终轧温度为820~880℃,精轧出口厚度为1~6mm。In addition, the present invention also controls the thickness of the intermediate slab at the rough rolling exit to be 40±3mm; in the finish rolling process, the finish rolling inlet temperature is 1080±40°C, the finish rolling temperature is 820~880°C, and the finish rolling exit thickness is 1~6mm .

在层流冷却工艺中,精轧后钢带采用层流冷却工艺中采用双段冷却方式,以不低于26℃/s的冷却速度快速冷却650~700℃,然后空冷7~12s,随后以不低于18℃/s的冷却速度快速冷却至400~470℃,在该温度段卷取成卷,卷曲后堆垛缓慢冷却至280~350℃,然后自然冷却至40℃以下;配以合理的快速冷却速率和卷取温度区间采用,一方面可有效细化铁素体晶粒,另一方面可获得比例适中、形态及分布理想的贝氏体组织,实现钢带铁素体和贝氏体的显微组织结构,工艺控制简单、易生产,无需后续热处理工序,缩短生产工序,节约了工序成本。In the laminar cooling process, the steel strip after finishing rolling adopts a double-stage cooling method, and the cooling rate is not lower than 26 ° C / s to rapidly cool 650 ~ 700 ° C, then air cooling for 7 ~ 12 s, and then Rapid cooling to 400-470°C at a cooling rate of not less than 18°C/s, coiling into rolls at this temperature range, and slowly cooling to 280-350°C for stacking after coiling, and then naturally cooling to below 40°C; The rapid cooling rate and the coiling temperature range are used. On the one hand, it can effectively refine the ferrite grains, and on the other hand, it can obtain a bainite structure with a moderate proportion, ideal shape and distribution, and realize the ferrite and bainite structure of the steel strip. The microstructure of the body, the process control is simple, easy to produce, no subsequent heat treatment process is required, the production process is shortened, and the process cost is saved.

在酸洗工序中,40℃以下的热轧钢带经过喷丸除鳞机组和拉矫破鳞机组促使氧化铁皮破碎,再经浅槽紊流式酸洗机组进行酸洗、漂洗、挤干、烘干;本发明控制拉矫延伸率为0.8~1.8%,酸洗槽酸液温度为55~85℃,酸洗槽游离酸浓度为50~160g/L,酸洗槽Fe2+浓度为50~140g/L,酸洗速度为60~120m/min,漂洗槽温度为50±10℃,烘干机组稳定为85±5℃。In the pickling process, the hot-rolled steel strip below 40 °C passes through the shot peening descaling unit and the tension leveling descaling unit to break the oxide scale, and then pickling, rinsing, squeezing and drying through the shallow groove turbulent pickling unit. Drying; the present invention controls the elongation rate of tension and straightening to 0.8~1.8%, the temperature of the acid solution in the pickling tank is 55~85°C, the concentration of free acid in the pickling tank is 50~160g/L, and the Fe concentration in the pickling tank is 50 ~140g/L, the pickling speed is 60~120m/min, the temperature of the rinsing tank is 50±10℃, and the drying unit is stable at 85±5℃.

本发明热轧工序采用控制除鳞次数和除鳞水压力,以及酸洗工序破鳞工艺和酸洗工艺,在轧制表面交货时,钢带表面色泽均匀,氧化铁皮厚度在5~15μm之间,无夹杂、氧化铁皮压入、麻点、起皮、辊印和板形不良等表面缺陷;在酸洗表面交货时,除了无上述表面缺陷外,也不存在欠酸洗、过酸洗以、卷形不良等缺陷;轧制表面和酸洗表面治理均达到高级表面质量要求。The hot rolling process of the present invention adopts the control of descaling times and descaling water pressure, as well as the scale-breaking process and pickling process of the pickling process. When the rolling surface is delivered, the surface color of the steel strip is uniform, and the thickness of the oxide scale is between 5 and 15 μm. In between, there are no surface defects such as inclusions, scale pressing, pitting, peeling, roll printing, and poor plate shape; when the pickling surface is delivered, in addition to the above-mentioned surface defects, there is no under-pickling or over-aciding Defects such as washing and poor roll shape; the treatment of the rolled surface and the pickling surface all meet the high-level surface quality requirements.

通过对经济型高表面质量高扩孔钢的化学成分及其制备方法的尝试,本发明获得了一种690MPa级经济型高表面质量高扩孔钢,其显微组织由铁素体(F)和贝氏体(B)组成;屈服强度(Rel(或Pp0.2))为450~550MPa,抗拉强度(Rm)为≥690MPa,扩孔率(λ)为≥75%,断后延伸率(A80)为≥19%,180°冷弯试验D=0a合格;其中,拉伸试样的平行段标距L0=80mm,平行段宽度b=20mm;冷弯试验中D为弯心直径,a为钢带厚度;本发明经济型高表面质量高扩孔钢具有良好的扩孔性能、成形性能、显微组织性能、冲压性能、各向同性等优点,主要用于汽车底盘复杂形状零件的成形。By trying the chemical composition and preparation method of the economical high surface quality high hole expansion steel, the present invention has obtained a 690MPa economical high surface quality high hole expansion steel whose microstructure consists of ferrite (F) Composed of bainite (B); yield strength (R el (or P p0.2 )) is 450-550MPa, tensile strength (R m ) is ≥690MPa, hole expansion rate (λ) is ≥75%, after fracture The elongation (A 80 ) is ≥19%, and the 180° cold bending test D = 0a is qualified; wherein, the parallel section gauge length L 0 of the tensile sample = 80mm, and the parallel section width b = 20mm; in the cold bending test, D is The diameter of the bending center, a is the thickness of the steel strip; the economical high surface quality and high reaming steel of the present invention has the advantages of good hole reaming performance, forming performance, microstructure performance, stamping performance, isotropy, etc., and is mainly used for automobile chassis Forming of complex shaped parts.

下面通过实施例对本发明作进一步详细说明,但并不因此将本发明保护范围限制在所述的实施例范围之中。The present invention will be further described in detail through the examples below, but the protection scope of the present invention is not limited to the scope of the examples.

本发明实施例中:In the embodiment of the present invention:

1、扩孔率评价方法如下:扩孔率符号为:λ,单位为:%;在热轧或酸洗钢带取的圆饼状制样,并在中心位置开的孔,作为初始孔,标记为d1;使用顶角为60°的圆锥冲头扩张该初始孔;测定冲孔部分产生的裂纹贯通钢带厚度方向时的孔径,标记为d21. The evaluation method of the hole expansion rate is as follows: the symbol of the hole expansion rate is: λ, and the unit is: %; The circular pie sample preparation, and open in the center As the initial hole, mark it as d1; use a conical punch with a top angle of 60° to expand the initial hole; measure the hole diameter when the crack generated in the punching part penetrates the thickness direction of the steel strip, mark it as d2 ;

扩孔率(λ)计算公式:λ=[(d2-d1)÷d1]×100%;Calculation formula of hole expansion rate (λ): λ=[(d 2 -d 1 )÷d 1 ]×100%;

本发明中,λ≥100%时,方视为合格。In the present invention, when λ≥100%, it is regarded as qualified.

2、显微组织结构评价、屈服强度、抗拉强度、延伸率、扩孔率、的测定方法均按国家标准进行测定。2. Microstructural evaluation, yield strength, tensile strength, elongation, hole expansion rate, and the determination methods are all determined according to national standards.

实施例1Example 1

本实施例采用六个实验组,实验组1~6的690MPa级经济型高表面质量高扩孔钢的化学成分见表1;This embodiment adopts six experimental groups, and the chemical composition of the 690MPa grade economical high surface quality and high hole reaming steel of experimental groups 1 to 6 is shown in Table 1;

实验组1~6的690MPa级经济型高表面质量高扩孔钢由以下方法制备得到:The 690MPa grade economical steel with high surface quality and high hole reaming of experimental group 1-6 was prepared by the following method:

包括以下步骤:冶炼工序→连铸工序→加热工序→粗轧工序→热卷箱工序→精轧工序→层流冷却工艺→卷取→缓慢冷却→酸洗工序→卷取包装;各工序中工艺参数见表2和表3;It includes the following steps: smelting process → continuous casting process → heating process → rough rolling process → hot coil box process → finishing rolling process → laminar cooling process → coiling → slow cooling → pickling process → coiling and packaging; The parameters are shown in Table 2 and Table 3;

表1实施例1各实验组钢的化学成分The chemical composition of each experimental group steel of table 1 embodiment 1

在冶炼工序中,按照相应化学成分范围进行冶炼,采用LF脱硫处理,控制S含量;连铸过程中采用低过热度浇铸,过热度控制在20~25℃,采用倒角结晶器,连铸成板坯;在层流冷却工艺中,精轧后钢带采用层流冷却工艺采用双段冷却方式,以不低于26℃/s的冷却速度(即表2中层流冷却速度前)快速冷却650~700℃,然后空冷7~12s,随后以不低于18℃/s(即表2中层流冷却速度后)的冷却速度快速冷却至400~470℃,卷取成卷,堆垛缓慢冷却至280~350℃,然后自然冷却至40℃以下;In the smelting process, smelting is carried out according to the corresponding chemical composition range, and LF desulfurization treatment is used to control the S content; in the continuous casting process, low superheat casting is used, and the superheat is controlled at 20-25°C. Slab: In the laminar flow cooling process, the steel strip after finishing rolling adopts the laminar flow cooling process and adopts a double-stage cooling method, and is rapidly cooled at a cooling rate not lower than 26°C/s (that is, before the laminar cooling rate in Table 2) for 650 ~700°C, then air-cooled for 7~12s, then rapidly cooled to 400~470°C at a cooling rate not lower than 18°C/s (after the laminar cooling rate in Table 2), coiled into rolls, and stacked slowly to 280~350℃, then naturally cool to below 40℃;

本实施例中实验组1~6钢的热轧工艺见表2;The hot rolling process of experimental group 1~6 steel in this embodiment is shown in Table 2;

表2实施例1各实验组的热轧工艺The hot rolling process of each experimental group of table 2 embodiment 1

本实施例中实验组1~6钢的酸洗工艺见表3;The pickling process of experimental group 1-6 steel in this embodiment is shown in Table 3;

表3实施例1各实验组的酸洗工艺The pickling process of each experimental group of table 3 embodiment 1

本实施例中实验组1~6钢的性能见表4;The performance of experimental group 1~6 steel in this embodiment is shown in Table 4;

表4实施例1各实验组钢的性能The performance of each experimental group steel of table 4 embodiment 1

由本实施例可知,本发明经济型高表面质量高扩孔钢采用“低C+Si+Mn”合金化处理技术,不添加Cr、Nb、Ti、V和Mo等贵重合金元素,显著降低了钢质的合金成本,从材质方面实现了经济型;通过控制钢的化学成分及其制备方法,得到了一种690MPa级经济型高表面质量高扩孔钢:采用TMCP工艺技术和控轧控冷技术,配以合理的快速冷却速率和卷取温度区间采用,实现钢带铁素体和贝氏体的显微组织结构,工艺控制简单、易生产,无需后续热处理工序,缩短生产工序,节约了工序成本;通过化学成分设计、冶炼工序钢质的夹杂物有效控制、连铸工序倒角结晶器的使用和低过热度浇铸,获得高品质的铸坯;热轧工序采用控制除鳞次数和除鳞水压力,以及酸洗工序破鳞工艺和酸洗工艺,获得了高光泽度、低粗糙度、光洁度好的高表面质量的产品。It can be seen from this example that the economical high surface quality and high hole reaming steel of the present invention adopts the "low C+Si+Mn" alloying treatment technology, does not add precious alloy elements such as Cr, Nb, Ti, V and Mo, and significantly reduces the Low alloy cost, realizing economy in terms of material; by controlling the chemical composition of the steel and its preparation method, a 690MPa economical steel with high surface quality and high hole expansion is obtained: using TMCP technology and controlled rolling and controlled cooling technology , combined with a reasonable rapid cooling rate and coiling temperature range to achieve the microstructure of steel strip ferrite and bainite, the process control is simple, easy to produce, no subsequent heat treatment process is required, the production process is shortened, and the process is saved Cost; through chemical composition design, effective control of steel inclusions in the smelting process, use of chamfering crystallizers in the continuous casting process, and low superheat casting to obtain high-quality slabs; The water pressure, as well as the scale breaking process and pickling process of the pickling process, have obtained products with high gloss, low roughness, good finish and high surface quality.

本实施例所得经济型高表面质量经济型高表面质量高扩孔钢,其显微组织由铁素体(F)和贝氏体(B)组成;屈服强度(Rel(或Pp0.2))为360~450MPa,抗拉强度(Rm)为≥690MPa,扩孔率(λ)为≥85%,断后延伸率(A80)为≥22%,180°冷弯试验D=0a合格;其中,拉伸试样的平行段标距L0=80mm,平行段宽度b=20mm;冷弯试验中D为弯心直径,a为钢带厚度;具有良好的扩孔性能、成形性能、显微组织性能、冲压性能、各向同性等优点,可用于汽车底盘复杂形状零件的成形。The economical high surface quality economical high surface quality high hole reaming steel of the present embodiment gained, its microstructure is made up of ferrite (F) and bainite (B); Yield strength (R el (or P p0.2 )) is 360~450MPa, tensile strength (R m ) is ≥690MPa, hole expansion rate (λ) is ≥85%, elongation after fracture (A 80 ) is ≥22%, 180° cold bending test D=0a is qualified ; Among them, the gauge length of the parallel section of the tensile sample is L 0 =80mm, and the width of the parallel section b=20mm; in the cold bending test, D is the diameter of the bending center, and a is the thickness of the steel strip; it has good hole expansion performance, formability, Microstructural performance, stamping performance, isotropy and other advantages, it can be used for the forming of parts with complex shapes of automobile chassis.

Claims (9)

  1. The high reaming steel of the economical great surface quality of 1.690MPa levels, it is characterised in that:By weight percentage, its chemical composition For:[C]:0.055%~0.095%, [Si]:0.85%~1.50%, [Mn]:1.30%~1.80%, [P]:0.010%~ 0.020%, [S]:≤ 0.003%, [Alt]:0.010%~0.050%, [Ca]:0.0010%~0.0050%, [N]:≤ 0.0050%, [O]:≤ 0.0040%, remaining is Fe and inevitable impurity, and [C] × [Mn] × 104≤ 0.15, [P]+ 10×[S]}×102≤ 0.04, [Ca]/[S] >=0.3.
  2. 2. the high reaming steel of the economical great surface quality of 690MPa levels according to claim 1, it is characterised in that:It is described The thickness specification of the high reaming steel of the economical great surface quality of 690MPa levels is 1.4~6.0mm.
  3. 3. the high reaming steel of the economical great surface quality of 690MPa levels according to claim 1 or 2, it is characterised in that:It is described The microstructure of the high reaming steel of the economical great surface quality of 690MPa levels is made up of ferrite and bainite.
  4. 4. the high reaming steel of the economical great surface quality of 690MPa levels according to claim 1 or 2, it is characterised in that:It is described The yield strength of the high reaming steel of the economical great surface quality of 690MPa levels is 450~550MPa, and tensile strength is >=690MPa, is expanded Porosity is >=75%, and elongation after fracture is >=19%, and 180 ° of cold bending test D=0a are qualified.
  5. 5. the preparation method of the high reaming steel of the economical great surface quality of 690MPa levels described in any one of Claims 1 to 4, it is special Sign is:Comprise the following steps:Smelting procedure → continuous casting working procedure → heating process → roughing operation → Coil Box process → finish rolling Process → laminar flow cooling technology → batches → Slow cooling → pickling process → and batches packaging.
  6. 6. the preparation method of the high reaming steel of the economical great surface quality of 690MPa levels according to claim 5, its feature exist In:De-scaling, de-scaling water pressure >=20MPa, dephosphorization nozzle angle are carried out in the roughing operation, Coil Box process and finishing rolling step For 40~50 °.
  7. 7. the preparation method of the high reaming steel of the economical great surface quality of 690MPa levels according to any one of claim 5~6, It is characterized in that:The workpiece thickness that roughing exports in the roughing operation is 40 ± 3mm;Finish rolling entrance in the finishing rolling step Temperature is 1080 ± 40 DEG C, and finishing temperature is 820~880 DEG C, and finish rolling exit thickness is 1~6mm.
  8. 8. the preparation method of the high reaming steel of the economical great surface quality of 690MPa levels according to claim 5, its feature exist In:Using double section types of cooling in the laminar flow cooling technology, with the cooling velocity not less than 26 DEG C/s quickly cooling 650~ 700 DEG C, then 7~12s of air cooling, is then quickly cooled to 400~470 DEG C with the cooling velocity not less than 18 DEG C/s;The volume The coiling temperature taken is 400~470 DEG C;The Slow cooling is to slowly cool to 280~350 DEG C, then natural cooling after batching To less than 40 DEG C.
  9. 9. the preparation method of the high reaming steel of the economical great surface quality of 690MPa levels according to any one of claim 5~8, It is characterized in that:Straightening elongation percentage is 0.8~1.8% in the pickling process, and descaling bath HCl acid liquor temperatures are 55~85 DEG C, Descaling bath free acid HCl concentration is 50~160g/L, descaling bath Fe2+Concentration is 50~140g/L, and pickling speed is 60~120m/ Min, potcher temperature are 50 ± 10 DEG C, and Drying unit stabilizes to 85 ± 5 DEG C.
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