CN107828532A - A kind of hyperconcetration milky biology enzyme liquid detergent and preparation method thereof - Google Patents
A kind of hyperconcetration milky biology enzyme liquid detergent and preparation method thereof Download PDFInfo
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- CN107828532A CN107828532A CN201711091760.8A CN201711091760A CN107828532A CN 107828532 A CN107828532 A CN 107828532A CN 201711091760 A CN201711091760 A CN 201711091760A CN 107828532 A CN107828532 A CN 107828532A
- Authority
- CN
- China
- Prior art keywords
- milky
- hyperconcetration
- liquid detergent
- alcohol
- biology enzyme
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007788 liquid Substances 0.000 title claims abstract description 88
- 108090000790 Enzymes Proteins 0.000 title claims abstract description 70
- 102000004190 Enzymes Human genes 0.000 title claims abstract description 70
- 239000003599 detergent Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 35
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003605 opacifier Substances 0.000 claims abstract description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 13
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 12
- 239000001509 sodium citrate Substances 0.000 claims abstract description 11
- 230000008859 change Effects 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- 229940075643 oleth-3 Drugs 0.000 claims abstract description 10
- KGULFLCOPRYBEV-KTKRTIGZSA-N 2-[2-[2-[(z)-octadec-9-enoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCOCCOCCO KGULFLCOPRYBEV-KTKRTIGZSA-N 0.000 claims abstract description 9
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 8
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims abstract description 7
- -1 Propane diols Chemical class 0.000 claims abstract description 7
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims abstract description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001294 propane Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims description 42
- 238000003756 stirring Methods 0.000 claims description 27
- 235000011083 sodium citrates Nutrition 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 150000002170 ethers Chemical class 0.000 claims description 8
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 3
- 108010020132 microbial serine proteinases Proteins 0.000 claims description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 2
- 108091005804 Peptidases Proteins 0.000 claims description 2
- 239000004365 Protease Substances 0.000 claims description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- BQODPTQLXVVEJG-UHFFFAOYSA-N [O].C=C Chemical compound [O].C=C BQODPTQLXVVEJG-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000005233 alkylalcohol group Chemical group 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 238000009472 formulation Methods 0.000 abstract description 6
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 abstract description 3
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002932 luster Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000002085 irritant Substances 0.000 description 2
- 231100000021 irritant Toxicity 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005494 tarnishing Methods 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 208000034874 Product colour issue Diseases 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000003841 chloride salts Chemical group 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2089—Ether acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of hyperconcetration milky biology enzyme liquid detergent and preparation method thereof, it includes each raw material components of following percentage by weight：Deionized water 35 60%；Sodium sulfate of polyethenoxy ether of fatty alcohol 10 20%；The sulfosuccinic acid esterdiol 3 10% of oleth 3；Isomery AEO 10 25%；Branched chain isomer alcohol alkoxylates 5 20%；Cocomethylammonium MEA 0 3%；Propane diols 1 4%；Sodium citrate 0 3%：Opacifier 0.2 0.6%；Salt 0 3%；Citric acid solution 0 1%；Methylisothiazolinone 0.1 0.15%；Essence 0.2 0.5%；Liquid bio enzyme 0.1 1%.Inventive formulation system produces hyperconcetration milky biological enzyme liquid liquid detergent, is keeping product while is not influenceing to further increase the content more than 30% of active matter on the basis of product milky appearance is not easy to change, is greatly enhancing its detergency.
Description
Technical field
The present invention relates to daily chemical product technical field, more particularly to a kind of hyperconcetration milky biology enzyme liquid detergent and
Its preparation method.
Background technology
The personalized direction developing direction of liquid detergent mainly includes super concentrated liquid liquid detergent and biological enzyme liquid liquid detergent.
Super concentrated liquid liquid detergent has the advantages that strong detergency, dosage are few, easy to use, environmentally friendly, and biological enzyme liquid liquid detergent has
There is the features such as few ultralow excitant of superstrong pollution-removing power, dosage, easy to use, strong applicability.Existing some laundry liquids production
The situation that product are combined in enrichment and extensively in two sides of addition enzyme preparation also occurs, and can reach its corresponding requirements.
But the physicochemical characteristics that unstability and its color due to enzyme preparation is deeper so that with the addition of the hyperconcetration of enzyme preparation
The detergency of biological enzyme liquid liquid detergent is gradually reduced in placement, while the color of enzyme preparation is deeper, mostly brown color, addition
The hyperconcetration biological enzyme liquid liquid detergent color change at initial stage of enzyme preparation is little, but the enzyme preparation to be failed in long-term place is got over
Come more, the influence to product colour can be increasingly severe, so as to influence the appearance luster of product.To cover color and luster change to production
The influence of product outward appearance, commercially available hyperconcetration biological enzyme liquid liquid detergent are to cover product discoloration by adding uranidin, become mostly
The shortcomings that yellow.In the market also occur non-concentrated type can Anti- tarnishing milky biological enzyme liquid liquid detergent, if common milky white
Colour biological enzyme laundry liquid continues to increase active matter content, particularly largely uses common alcohol AEO, table
Face activating agent is combined to reach and micella can be formed after finite concentration destroys stable system.In order to reach, not influence product milky white
Colored appearance, at the same improve Product Activity thing content to high concentration and do not cause product system formed this three effects of micella, it is necessary to
It is preferred that the colourless special surfactant formulatory milky biological enzyme liquid liquid detergent for being not easy to form micella, being concentrated through, production
Product need further to optimize.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of hyperconcetration milky biology enzyme liquid detergent and preparation method thereof,
Reach for existing milky biological enzyme liquid liquid detergent can be formed after finite concentration micella destroy stable system can not be real
The technical problem of existing hyperconcetration.
In order to solve the above-mentioned technical problem, the thinking of technical solution of the present invention is：By improving milky biological enzyme liquid
The content of surfactant in liquid detergent, reach concentration and require, and increase the content of laundry liquid surfactant simultaneously
Strengthen the compatibility of enzyme preparation and system, so as to further improve the detergency stability of super concentrated liquid liquid detergent.It is in addition, logical
The change of reduction system raw material color and luster and enzyme preparation are crossed because of influence of the failure discoloration to product appearance, ensures biological enzyme liquid liquid detergent
Milky aesthetic appearance still can be kept after hyperconcetration is reached.
Specifically, the invention provides a kind of hyperconcetration milky biological enzyme liquid liquid detergent, it includes following weight hundred
Divide each raw material components of ratio：
Deionized water 35-60%；
Sodium sulfate of polyethenoxy ether of fatty alcohol 10-20%；
The sulfosuccinate disodium of oleth -3 3-10%；
Isomery AEO 10-25%；
Branched chain isomer alcohol alkoxylates 5-20%；
Cocomethylammonium MEA 0-3%；
Propane diols 1-4%；
Sodium citrate 0-3%：
Opacifier 0.2-0.6%；
Salt 0-3%；
Citric acid solution 0-1%；
Methylisothiazolinone 0.1-0.15%；
Essence 0.2-0.5%；
Liquid bio enzyme 0.1-1%.
Further, the concentration of the sodium sulfate of polyethenoxy ether of fatty alcohol is 70%.
Further, the isomery AEO is C13 isomeric alcohol polyethenoxy ethers, the C13 isomeries alcohol
APEO includes C13 alcohol APEO 6EO, C13 alcohol APEOs 9EO one of which or two kinds of mixtures.
Further, the branched chain isomer alcohol alkoxylates include C8-10 branched chain isomer alcohol alkoxylates 9EO or
One of which or two kinds of mixtures in C8-10 branched chain isomer alcohol alkoxylates 6EO.
Further, active matter content >=80% of the cocomethylammonium MEA.
Further, the opacifier is polyacrylate, glycol distearate class compound or polymer breast
Liquid.
Further, the essence is any one in ethers, alcohols and saturated hydrocarbons essence or a variety of mixtures.Or
Person selects other essence not easy to change.
Further, the liquid bio enzyme is that SAVINASE ULTRA 16XL match the superpower stable type liquid protease of prestige
Or other light biology enzymes.
Alternatively, the salt is sodium chloride.
Alternatively, the concentration of the citric acid solution is 10%.
Another aspect of the present invention, in order to prepare above-mentioned hyperconcetration milky biology enzyme liquid detergent, present invention also offers
A kind of hyperconcetration milky biology enzyme laundry liquid and preparation method thereof, the described method comprises the following steps：
S101, prepare recipe ingredient：Deionized water 35-60%；Sodium sulfate of polyethenoxy ether of fatty alcohol 10-20%；Oleyl alcohol
The sulfosuccinate disodium of polyethers -3 3-10%；Isomery AEO 10-25%；Branched chain isomer alcohol alkoxylates
5-20%；Cocomethylammonium MEA 0-3%；Propane diols 1-4%；Sodium citrate 0-3%：Opacifier 0.2-0.6%；Salt 0-
3%；Citric acid solution 0-1%；Methylisothiazolinone 0.1-0.15%；Essence 0.2-0.5%；Liquid bio enzyme 0.1-1%；
S102, at room temperature, by weight than being added for 35-60% deionized water in batch mixing a mixing bowl, 30 DEG C are heated to,
Oleth -3 sulfo group of the weight than the sodium sulfate of polyethenoxy ether of fatty alcohol for 10-20%, 3-10% is added after starting stirring
Succinate disodium, stirring is to being uniformly dissolved；
10-25%C13 isomeric alcohol polyethenoxy ethers are slowly sequentially added in S103, batch mixing a mixing bowl in step s 102
And 5-20% branched chain isomer alcohol alkoxylates surfactants, and stir to being uniformly dissolved；
0-3% cocomethylammoniums MEA, 1- are slowly sequentially added in S104, batch mixing a mixing bowl in step s 103
4% propane diols, 0-3% sodium citrates, stirring is to being uniformly dissolved；
0.2-0.6% opacifiers are slowly added in S105, the batch mixing a mixing bowl in step S104, stirring is equal to dissolving
It is even；
Weight is slowly added in S106, the batch mixing a mixing bowl in step S105 than adjusting viscosity to pre- for 0-3% salt
If scope；
0-1% citric acid solutions, regulation pH value to 5.5- are slowly added in S107, batch mixing a mixing bowl in step s 106
Between 7.0；
The first that percentage by weight is 0.1-0.15% is successively slowly added in S108, batch mixing a mixing bowl in step s 107
The essence of base OIT and 0.2-0.5%, stirring is to being uniformly dissolved；
0.1-1% liquid bio enzyme is added in S109, the stirring in step S108, is stopped after continuing stirring 30 minutes
Stirring；
S110, standing are filling after 2 hours.
Inventive formulation system principal surfactant raw material uses the raw material of low irritant, and non-ionic surface active
Agent and cloudy surface-active contents ratio are more than 2:1, be advantageous to the stable holding of biology enzyme；Primary raw material and biology enzyme ratio in formula
Compared with stable matching, such as propane diols, C13 isomery alcohol AEO, C8-10 branched chain isomer alcohol alkoxylates.Match somebody with somebody
The proportion of surfactant forms Superconcentrated washing liquid more than 30% in cube system；Own in formula system in addition to biology enzyme
Raw material is colourless or light, transparent or white (opacifier plays milky white effect), and liquid bio enzyme is the raw material of yellow, but
Addition is less, and within the shelf-life of 2 years, the browning factors being induced by it are influenceed less, in tolerance interval on whole system
It is interior.
In addition, preservative and essence are also easy to cause milky hyperconcetration milky biological enzyme liquid liquid detergent to become
Color, this formula cook preservative using the methylisothiazolinone of not chloride ion-containing, and itself is almost colourless, due to it is not chloride from
Son, excitant very little；Essence is Anti- tarnishing, colourless essence, is both not easy to cause system to change colour, so whole system is more steady
It is fixed, it can effectively keep milky underwear washing to occur within the shelf-life without obvious metachromatism, so as to preferably ensure that
Product quality.
The beneficial effect of technical solution of the present invention：
Hyperconcetration milky biological enzyme liquid liquid detergent provided in an embodiment of the present invention and preparation method thereof, due to being formulated
System with the addition of superpower stable type liquid bio enzyme so that it can reach to the detergency of albumen soiled cotton and sebum soiled cotton commonly washes
2~4 times of clothing liquid, so as to ensure that this hyperconcetration milky biological enzyme liquid liquid detergent protide spot common to clothing
Clean effect.By selecting the raw material of mild low-stimulation, the material system of low irritant is low to skin irritation, to biology enzyme
The excitant of preparation is relatively low；System raw material will have good compatibility and compatibility with biological enzyme formulation, be unlikely to brokenly
The activity of bad biological enzyme formulation；Raw material true qualities used can not be too deep, preferably water white transparency or simply white, not influence to produce
Product milky appearance.
The hyperconcetration milky biological enzyme liquid liquid detergent of the present invention, product is neutral gentle, non-stimulated, lossless to fabric
Wound, soluble in water, Low-foam and easily crosses water, easy to use, can also improve stability under the premise of dirt-removing power is improved, ensure that
Discoloration does not occur within the shelf-life.
Embodiment
The embodiment of the present invention is described further below.Herein it should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but does not form limitation of the invention.In addition, invention described below
As long as involved technical characteristic does not form conflict can and is mutually combined each other in each embodiment.
The invention provides a kind of hyperconcetration milky biology enzyme liquid detergent, and it includes each raw material of following percentage by weight
Component：Deionized water 35-60%；Sodium sulfate of polyethenoxy ether of fatty alcohol 10-20%；The sulfosuccinate disodium of oleth -3
3-10%；Isomery AEO 10-25%；Branched chain isomer alcohol alkoxylates 5-20%；Cocomethylammonium monoethanol
Amine 0-3%；Propane diols 1-4%；Sodium citrate 0-3%：Opacifier 0.2-0.6%；Salt 0-3%；Citric acid solution 0-1%；First
Base OIT 0.1-0.15%；Essence 0.2-0.5%；Liquid bio enzyme 0.1-1%.
Illustrated below by taking four embodiments as an example, the gross mass of wherein component is defined by 100g.
Embodiment one
Mixed configuration is carried out according to the component and ratio of table one.
Embodiment two
Mixed configuration is carried out according to the component and ratio of table one.
Embodiment three
Mixed configuration is carried out according to the component and ratio of table one.
Example IV
Mixed configuration is carried out according to the component and ratio of table one.
Table one
A kind of reference specification that each component uses in above-described embodiment is as follows：
Sodium sulfate of polyethenoxy ether of fatty alcohol, manufacturer：Praise space in Zhejiang；Specification：70 types；
The sulfosuccinate disodium of oleth -3, manufacturer：Zhong Shan sections are beautiful, specification：30 types；
C13 isomeric alcohol polyethenoxy ethers, manufacturer：France's match Bick；Model：1309L；
Branched chain isomer alcohol alkoxylates, manufacturer：LG-DOW；Model：CA-90；
Cocomethylammonium MEA, manufacturer：Zhong Shan sections are beautiful, specification：80 types
Propane diols, manufacturer：LG-DOW；Specification：Pharmaceutical grade；
Sodium citrate, manufacturer：Ying Xuan；Specification：Cosmetics-stage：
Opacifier, manufacturer：BASF；Model：OP301；
Salt, manufacturer：Hunan weighing apparatus salinization；Specification：Technical grade
Citric acid, manufacturer：Ying Xuan；Specification：Cosmetics-stage
Methylisothiazolinone, manufacturer：Moisten river in Shanghai；Model：1212；
Essence, manufacturer：Engrave health, specification in Guangdong：Daily chemical essence；
Liquid bio enzyme, manufacturer：Novi's letter, specification：SAVINASE ULTRA 16XL.
The preparation method of above-mentioned hyperconcetration milky biology enzyme liquid detergent is carried out as follows, is with embodiment one
Example illustrates, and the method for its excess-three embodiment does not repeat as embodiment one.
The hyperconcetration milky biology enzyme laundry liquid and preparation method thereof of embodiment one, the described method comprises the following steps：
S101, prepare recipe ingredient：Deionized water 54.7%；Sodium sulfate of polyethenoxy ether of fatty alcohol 12%；Oleth-
3 sulfosuccinate disodiums 5%；Isomery AEO 14%；Branched chain isomer alcohol alkoxylates 8%；Cocounut oil first
Base MEA 2%；Propane diols 2%；Sodium citrate 0.5%：Opacifier 0.3%；Salt 0.3%；Citric acid solution 0.1%；First
Base OIT 0.1%；Essence 0.5%；Liquid bio enzyme 0.5%；
S102, at room temperature, by weight than being added for 54.7% deionized water in batch mixing a mixing bowl, 30 DEG C are heated to,
Weight is added than the sodium sulfate of polyethenoxy ether of fatty alcohol for 12%, 5% sulfosuccinic acid of oleth -3 after starting stirring
Ester disodium, stirring is to being uniformly dissolved；
Slowly sequentially added in S103, batch mixing a mixing bowl in step s 102 14%C13 isomeric alcohol polyethenoxy ethers and
8% branched chain isomer alcohol alkoxylates surfactant, and stir to being uniformly dissolved；
2% cocomethylammonium MEA, 2% the third are slowly sequentially added in S104, batch mixing a mixing bowl in step s 103
Glycol, 0-3% sodium citrates, stirring is to being uniformly dissolved；
It is slowly added to 0.3% opacifier in S105, the batch mixing a mixing bowl in step S104, stirring is to being uniformly dissolved；
Weight is slowly added in S106, the batch mixing a mixing bowl in step S105 than adjusting viscosity to pre- for 0.3% salt
If scope；
0.1% citric acid solution, regulation pH value to 6.0 are slowly added in S107, batch mixing a mixing bowl in step s 106
Between；
It is different that the methyl that percentage by weight is 0.1% is successively slowly added in S108, batch mixing a mixing bowl in step s 107
Thiazolinone and 0.5% essence, stirring is to being uniformly dissolved；
0.1-1% liquid bio enzyme is added in S109, the stirring in step S108, is stopped after continuing stirring 30 minutes
Stirring；
S110, standing are filling after 2 hours.
The hyperconcetration milky biology enzyme liquid detergent that above-described embodiment 1-4 is obtained, utilizes detection side as shown in Table 2
Method and index carry out major parameter performance and detected.
The detection method and index of the performance parameters of table two
As a result of inventive formulation system produce hyperconcetration milky biological enzyme liquid liquid detergent, its strong detergency,
Product system is stable, and color change is small.Both ensured in the use quality of superstrong pollution-removing power again to ensure outside product in hyperconcetration product
See non-discolouring appearance requirement.Meet the inside and outside multiple quality demand of consumer.Solve such product enrichment to ask
Topic does not influence product milky appearance simultaneously.
Inventive formulation system production hyperconcetration milky biological enzyme liquid liquid detergent is employed, in holding product while not
The content more than 30% of active matter is further increased on the basis of influence product milky appearance is not easy to change, makes its detergency
Greatly enhance.
Embodiments of the present invention are explained in detail above, but the invention is not restricted to described embodiment.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall within protection scope of the present invention.
Claims (10)
1. a kind of hyperconcetration milky biology enzyme liquid detergent, it is characterised in that the liquid detergent includes following percentage by weight
Each raw material components：
Deionized water 35-60%；
Sodium sulfate of polyethenoxy ether of fatty alcohol 10-20%；
The sulfosuccinate disodium of oleth -3 3-10%；
Isomery AEO 10-25%；
Branched chain isomer alcohol alkoxylates 5-20%；
Cocomethylammonium MEA 0-3%；
Propane diols 1-4%；
Sodium citrate 0-3%：
Opacifier 0.2-0.6%；
Salt 0-3%；
Citric acid solution 0-1%；
Methylisothiazolinone 0.1-0.15%；
Essence 0.2-0.5%；
Liquid bio enzyme 0.1-1%.
A kind of 2. hyperconcetration milky biology enzyme liquid detergent according to claim 1, it is characterised in that the poly alkyl alcohol
The concentration of oxygen ethene ether sodium sulfate is 70%.
A kind of 3. hyperconcetration milky biology enzyme liquid detergent according to claim 2, it is characterised in that the isomery fat
Alcohol APEO is C13 isomeric alcohol polyethenoxy ethers, and the C13 isomeric alcohol polyethenoxy ethers include C13 alcohol APEOs
6EO, C13 alcohol APEO 9EO one of which or two kinds of mixtures.
A kind of 4. hyperconcetration milky biology enzyme liquid detergent according to claim 1, it is characterised in that the branched chain isomer
Alcohol alkoxylates are included in C8-10 branched chain isomer alcohol alkoxylates 9EO or C8-10 branched chain isomer alcohol alkoxylates 6EO
One of which or two kinds of mixtures.
A kind of 5. hyperconcetration milky biology enzyme liquid detergent according to claim 1, it is characterised in that the cocomethylammonium
Active matter content >=80% of MEA.
6. a kind of hyperconcetration milky biology enzyme liquid detergent according to claim 1, it is characterised in that the opacifier is
Polyacrylate, glycol distearate class compound or polymer emulsion.
7. a kind of hyperconcetration milky biology enzyme liquid detergent according to claim 1, it is characterised in that the essence is ether
Any one in class, alcohols and saturated hydrocarbons essence or a variety of mixtures.Or select other essence not easy to change.
A kind of 8. hyperconcetration milky biology enzyme liquid detergent according to claim 1, it is characterised in that the liquid bio
Enzyme is that SAVINASE ULTRA 16XL match the superpower stable type liquid protease of prestige.
9. a kind of hyperconcetration milky biology enzyme liquid detergent according to claim 1, it is characterised in that the salt is chlorination
Sodium.
The liquid and preparation method thereof 10. a kind of hyperconcetration milky biology enzyme is done washing, it is characterised in that the described method comprises the following steps：
S101, prepare recipe ingredient：Deionized water 35-60%；Sodium sulfate of polyethenoxy ether of fatty alcohol 10-20%；Oleth-
3 sulfosuccinate disodium 3-10%；Isomery AEO 10-25%；Branched chain isomer alcohol alkoxylates 5-
20%；Cocomethylammonium MEA 0-3%；Propane diols 1-4%；Sodium citrate 0-3%：Opacifier 0.2-0.6%；Salt 0-3%；
Citric acid solution 0-1%；Methylisothiazolinone 0.1-0.15%；Essence 0.2-0.5%；Liquid bio enzyme 0.1-1%；
S102, at room temperature, by weight than being added for 35-60% deionized water in batch mixing a mixing bowl, 30 DEG C are heated to, is started
Weight is added after stirring than the sodium sulfate of polyethenoxy ether of fatty alcohol for 10-20%, the 3-10% sulfosuccinic of oleth -3
Acid esters disodium, stirring is to being uniformly dissolved；
10-25%C13 isomeric alcohol polyethenoxy ethers and 5- are slowly sequentially added in S103, batch mixing a mixing bowl in step s 102
20% branched chain isomer alcohol alkoxylates surfactant, and stir to being uniformly dissolved；
0-3% cocomethylammoniums MEA, 1-4% third are slowly sequentially added in S104, batch mixing a mixing bowl in step s 103
Glycol, 0-3% sodium citrates, stirring is to being uniformly dissolved；
It is slowly added to 0.2-0.6% opacifiers in S105, the batch mixing a mixing bowl in step S104, stirring is to being uniformly dissolved；
Weight is slowly added in S106, the batch mixing a mixing bowl in step S105 than adjusting viscosity to default model for 0-3% salt
Enclose；
0-1% citric acid solutions, regulation pH value to 5.5-7.0 are slowly added in S107, batch mixing a mixing bowl in step s 106
Between；
It is different that the methyl that percentage by weight is 0.1-0.15% is successively slowly added in S108, batch mixing a mixing bowl in step s 107
The essence of thiazolinone and 0.2-0.5%, stirring is to being uniformly dissolved；
0.1-1% liquid bio enzyme is added in S109, the stirring in step S108, stops stirring after continuing stirring 30 minutes
Mix；
S110, standing are filling after 2 hours.
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Cited By (2)
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| CN108641832A (en) * | 2018-07-01 | 2018-10-12 | 田波 | A kind of enzyme color protection liquid detergent |
| CN108865510A (en) * | 2018-06-14 | 2018-11-23 | 大连洁仕清洁用品有限公司 | Laundry washes the formula and preparation method of multifunctional washing assistant in agent cleaning process by liquid |
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| JP2013503950A (en) * | 2009-09-14 | 2013-02-04 | ザ プロクター アンド ギャンブル カンパニー | Condensable liquid laundry detergent composition |
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| JP2013503950A (en) * | 2009-09-14 | 2013-02-04 | ザ プロクター アンド ギャンブル カンパニー | Condensable liquid laundry detergent composition |
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| CN108865510A (en) * | 2018-06-14 | 2018-11-23 | 大连洁仕清洁用品有限公司 | Laundry washes the formula and preparation method of multifunctional washing assistant in agent cleaning process by liquid |
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