CN107892638A - A kind of gas producing medicinal - Google Patents
A kind of gas producing medicinal Download PDFInfo
- Publication number
- CN107892638A CN107892638A CN201710308215.3A CN201710308215A CN107892638A CN 107892638 A CN107892638 A CN 107892638A CN 201710308215 A CN201710308215 A CN 201710308215A CN 107892638 A CN107892638 A CN 107892638A
- Authority
- CN
- China
- Prior art keywords
- gas
- producing medicinal
- azodicarbonamide
- gas producing
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000019399 azodicarbonamide Nutrition 0.000 claims abstract description 16
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 14
- 239000011591 potassium Substances 0.000 claims abstract description 14
- 239000004156 Azodicarbonamide Substances 0.000 claims abstract description 11
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims abstract description 11
- 239000007800 oxidant agent Substances 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 abstract description 30
- 238000002485 combustion reaction Methods 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000000567 combustion gas Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 230000035945 sensitivity Effects 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 8
- 230000007613 environmental effect Effects 0.000 description 5
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical class [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical group [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001540 azides Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
- C06D5/06—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B29/00—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
- C06B29/02—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Air Bags (AREA)
Abstract
The present invention relates to a kind of gas producing medicinal, the gas producing medicinal includes potassium hyperchlorate and azodicarbonamide.Its mass percent component：Potassium hyperchlorate：40%~60%；Azodicarbonamide：40%~60%.Gas producing medicinal of the present invention has the characteristics that gas production is big, combustion temperature is low, gas componant is clean；It is cheap and raw material are easy to obtain, production process safety.The method have the benefit that：（1）Gas production is big：More than 600L/kg（Standard state）.（2）Safety and stability：Sensitivity is low.（3）Cost is low：Azodicarbonamide source is wide, cheap.（4）Combustion gas is cleaned：Main component is H2、CO2、N2、H2O etc..It can be widely applied to civilian and military domain.
Description
Technical field
The present invention relates to a kind of gas producing medicinal, more particularly to a kind of gas production is big, combustion temperature is low, safe and reliable, inexpensive, combustion
The gas producing medicinal of gas cleaning.
Background technology
Gas-forming agent is mainly by fuel agent, oxidant and additive composition.Additive generally comprises catalyst, bonding
Agent, cooling agent, burning ratemodifier etc., can be by gas generator, and rapid burning discharges a large amount of gases, for externally doing work or filling
Gas buffers.Gas-forming agent is widely used in military and civil area.The former is such as the rail control engine energy, landing cushion gasbag
Source of the gas etc.；The latter such as civil aviaton meets an urgent need slide source of the gas, Mae West source of the gas, unmanned plane buffering landing air bag, underwater salvage air bag
Deng.
At present, gas-forming agent is broadly divided into nitrine class and non-nitrine class gas-forming agent.In nitrine class gas-forming agent
Azide is fuel agent, wherein Alkali-Metal Na NO3The most used, oxidant typically uses metal oxide Fe2O3、MnO2
Deng.Composition of Sodium Azide Gas Generant tool ignition temperature is low（About 1500K）, a large amount of nontoxic nitrogen, burning speed are produced after burning
Spend the advantage such as relatively fast and free from the influence of the external environment.But azide is easily production after toxic articles, with oxidant reaction
Raw stimulating component, residue is not easy to filter after burning；The danger such as blast during use be present.Therefore function admirable is developed,
Safe and reliable non-nitrine class gas-forming agent is imperative.
The content of the invention
In view of the shortcomings of the prior art, object of the present invention is to provide gas production is big, combustion temperature is low, safe and reliable, low
Cost, the gas producing medicinal of combustion gas cleaning.
Technical scheme includes potassium hyperchlorate and azodicarbonamide, its mass percent component：
Potassium hyperchlorate：40%~60%
Azodicarbonamide：40%~60%.
Preferred mass percentage component of the present invention：
Potassium hyperchlorate：43%~47%
Azodicarbonamide：53%~57%.
Potassium hyperchlorate of the present invention is oxidant, and granularity is no more than 150um.
Azodicarbonamide of the present invention is reducing agent, and granularity is no more than 20um.
Compared with prior art, gas producing medicinal of the present invention has the characteristics that gas production is big, combustion temperature is low, gas componant is clean；
It is cheap and raw material are easy to obtain, production process safety, it can be widely applied to civilian and military domain.The present invention's has
Benefit has the technical effect that：
（1）Gas production is big：More than 600L/kg（Standard state）.
（2）Safety and stability：Sensitivity is low.
（3）Cost is low：Azodicarbonamide source is wide, cheap.
（4）Combustion gas is cleaned：Main component is H2、CO2、N2、H2O etc..
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art's it will be clearly understood that the reality
Apply example to be only to aid in understanding the present invention, be not construed as the concrete restriction to the present invention.
Embodiment 1
Precise 40g potassium hyperchlorates and 60g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most
Freedom in minor affairs energy method calculates thermodynamic parameter of the present embodiment under 5MPa environmental pressures：The combustion temperature of this formula is 1916 K, is got angry
Measure as 746L/kg.Product component is shown in Table 1.
The product component of table 1
Embodiment 2
Precise 45g potassium hyperchlorates and 55g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most
Freedom in minor affairs energy method calculates parameter of this formula under 5MPa environmental pressures：The combustion temperature of this formula is 2150K, gas forming amount 706L/
kg.Product component is shown in Table 2.
The product component of table 2
Embodiment 3
Precise 50g potassium hyperchlorates and 50g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most
Freedom in minor affairs energy method calculates parameter of this formula under 5MPa environmental pressures：The combustion temperature of this formula is 2429K, gas forming amount 659L/
kg.Product component is shown in Table 3.
The product component of table 3
Embodiment 4
Precise 55g potassium hyperchlorates and 45g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most
Freedom in minor affairs energy method calculates parameter of this formula under 5MPa environmental pressures：The combustion temperature of this formula is 2559 K, gas forming amount 620
L/kg.Gas componant is shown in Table 4.
The product component of table 4
Embodiment 5
Precise 60g potassium hyperchlorates and 40g azodicarbonamides, are uniformly sufficiently mixed, are loaded with closed container afterwards.Using most
Freedom in minor affairs energy method calculates parameter of this formula under 5MPa environmental pressures：The combustion temperature of this formula is 2374 K, gas forming amount 598L/
Kg, gas componant are shown in Table 5.
The product component of table 5
The above embodiments are merely illustrative of the technical solutions of the present invention and unrestricted, institute within the spirit and principles of the invention
All any modification, equivalent and improvement done etc., it all should cover in the protection claimed range of the present invention.
Claims (4)
1. a kind of gas producing medicinal, it is characterised in that including following masses percentage component：
Potassium hyperchlorate：40%~60%
Azodicarbonamide：40%~60%.
2. a kind of gas producing medicinal according to claim 1, it is characterised in that including following masses percentage component：
Potassium hyperchlorate：43%~47%
Azodicarbonamide：53%~57%.
A kind of 3. gas producing medicinal according to claim 1, it is characterised in that：The potassium hyperchlorate is oxidant, and granularity is not
More than 150um.
A kind of 4. gas producing medicinal according to claim 1, it is characterised in that：The azodicarbonamide is reducing agent, grain
Degree is no more than 20um.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710308215.3A CN107892638A (en) | 2017-05-04 | 2017-05-04 | A kind of gas producing medicinal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710308215.3A CN107892638A (en) | 2017-05-04 | 2017-05-04 | A kind of gas producing medicinal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107892638A true CN107892638A (en) | 2018-04-10 |
Family
ID=61803080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710308215.3A Pending CN107892638A (en) | 2017-05-04 | 2017-05-04 | A kind of gas producing medicinal |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107892638A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125933A (en) * | 1994-02-15 | 1996-07-03 | 日本工机株式会社 | Gas generator composition, process for producing tablet therefrom, and transportation method |
| CN1266416A (en) * | 1998-04-30 | 2000-09-13 | 大赛璐化学工业株式会社 | Enhancer composition for inflator |
| CN1272102A (en) * | 1998-04-20 | 2000-11-01 | 大赛璐化学工业株式会社 | Ways to reduce NOx |
| CN101432245A (en) * | 2006-05-02 | 2009-05-13 | 日本化药株式会社 | Gas generant composition for gas actuator for activating safety device and gas generator for gas actuator using the same |
-
2017
- 2017-05-04 CN CN201710308215.3A patent/CN107892638A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125933A (en) * | 1994-02-15 | 1996-07-03 | 日本工机株式会社 | Gas generator composition, process for producing tablet therefrom, and transportation method |
| CN1272102A (en) * | 1998-04-20 | 2000-11-01 | 大赛璐化学工业株式会社 | Ways to reduce NOx |
| CN1266416A (en) * | 1998-04-30 | 2000-09-13 | 大赛璐化学工业株式会社 | Enhancer composition for inflator |
| CN101432245A (en) * | 2006-05-02 | 2009-05-13 | 日本化药株式会社 | Gas generant composition for gas actuator for activating safety device and gas generator for gas actuator using the same |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180410 |