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CN108183273A - A kind of charging method of the safety of lithium ion secondary battery of smart home - Google Patents

A kind of charging method of the safety of lithium ion secondary battery of smart home Download PDF

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Publication number
CN108183273A
CN108183273A CN201711432009.XA CN201711432009A CN108183273A CN 108183273 A CN108183273 A CN 108183273A CN 201711432009 A CN201711432009 A CN 201711432009A CN 108183273 A CN108183273 A CN 108183273A
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CN
China
Prior art keywords
electrode active
lithium
positive electrode
active materials
charging
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Pending
Application number
CN201711432009.XA
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Chinese (zh)
Inventor
刘雪楠
沈刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Kngli Youlan Robot Technology Co Ltd
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Beijing Kngli Youlan Robot Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201711432009.XA priority Critical patent/CN108183273A/en
Publication of CN108183273A publication Critical patent/CN108183273A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • H01M10/446Initial charging measures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4285Testing apparatus
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • H01M10/448End of discharge regulating measures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

The present invention relates to a kind of charging methods of the safety of lithium ion secondary battery of smart home, and described method includes following steps:By positive electrode active materials cobalt acid lithium and LiNi0.5Mn0.25Co0.25O2It is uniformly mixed, slurry is made together with conductive agent, binding agent and solvent;The latticed adhesive linkage of silk-screen printing on aluminium collector;Slurry obtained is coated on the collector comprising adhesive linkage, in 100 DEG C of dryings, obtains positive plate;Obtained positive plate and negative plate and electrolyte are assembled into lithium rechargeable battery;Constant-current charge is carried out to lithium rechargeable battery, at interval of the change rate of 3s detection primary voltage variations, it is judged as charge termination when dV/dt is decreased to 0.2V/h, stop the charging to battery, technical solution provided by the invention, with the even particulate dispersion of positive electrode active materials containing lithium in the particulate interspaces of the positive electrode active materials containing lithium with low voltage, so as to improve the accuracy of end point determination, so as to improve the volumetric properties of battery.

Description

A kind of charging method of the safety of lithium ion secondary battery of smart home
Technical field
The present invention relates to electronic component fields, and in particular to a kind of safety of lithium ion secondary battery of smart home Charging method.
Background technology
Smart home (English:Smart home, home automation) it is using house as platform, utilize comprehensive wiring Technology, network communication technology, security precautions technology, automatic control technology, audio frequency and video technology are by the related facility collection of home life Into building the management systems of efficient housing facilities and family's schedule affairs, promote house security, convenience, comfort, skill Art, and realize the living environment of environmental protection and energy saving.
Many smart homes need to provide power supply for it using energy-storage battery, lithium ion battery as novel energy storage cell, There is energy density height, memory-less effect is ideal smart home power supply.But the charging of lithium ion battery is safe An always critical problem, excessive charging can lead to catching fire and exploding for battery, bring very serious consequence.Lithium from Sub- battery overcharge a part the reason is that because charge termination be difficult to detect caused by.
Invention content
The present invention provides a kind of charging method of the safety of lithium ion secondary battery of smart home, and the purpose is to the present invention Purpose be to improve the charging method of the safety of lithium ion secondary battery for smart home, to overcome existing above-mentioned lack It falls into.
The purpose of the present invention is what is realized using following technical proposals:
The present invention provides a kind of charging method of the safety of lithium ion secondary battery of smart home, it is improved in that institute The method of stating includes:
(1)By positive electrode active materials cobalt acid lithium and LiNi0.5Mn0.25Co0.25O2It is uniformly mixed, with conductive agent, binding agent and solvent Slurry is made together;
(2)The latticed adhesive linkage of silk-screen printing on aluminium collector;
(3)By step(1)Slurry obtained is coated on the collector comprising adhesive linkage, with 100 DEG C of dryings, obtains positive plate;
(4)By step(3)Obtained positive plate is assembled into lithium rechargeable battery with negative plate and electrolyte;
(5)Constant-current charge is carried out to lithium rechargeable battery, constant-current charge is divided into 3 stages, and the 1st stage charging current is 5C, Charging time is 9min, and the 2nd stage charging current is 1C, and charging time 9min, the 3rd stage charging current is 0.1C, is charged To charge termination;
(6)In step(5)The 3rd stage, at interval of 3s detection primary voltage variations change rate dV/dt, dV/dt from gradual Increase becomes being gradually reduced again, is judged as charge termination when dV/dt is decreased to 0.2V/h, stops the charging to battery.
Preferably, the positive electrode active materials cobalt acid lithium and LiNi0.5Mn0.25Co0.25O2It is uniformly mixed, with conductive agent, viscous Slurry is made in knot agent and solvent together, and method includes:
The LiNi of total positive electrode active materials quality 2% will be accounted for0.5Mn0.25Co0.25O2, 94% positive electrode active materials, 3% conduction Agent, 3% binding agent are mixed, and are fabricated to slurry;
Wherein, LiNi0.5Mn0.25Co0.25O2Average grain diameter for 200nm, the average grain diameter of cobalt acid lithium is 1000nm;
Preferably, the latticed adhesive linkage of silk-screen printing, the method on aluminium collector include:
24% of layer material coated area for afflux bulk area will be bonded, adhesive linkage includes binding agent PVDF and nano-silver powder, receives Rice silver powder accounts for the 45% of adhesive linkage quality;
Preferably, described to carry out constant-current charge to lithium rechargeable battery, constant-current charge is divided into 3 stages, and method includes:
1st stage charging current is 5C, charging time 9min;
2nd stage charging current is 1C, charging time 9min;
3rd stage charging current is 0.1C, charges to charge termination., it is improved in that including:
Beneficial effects of the present invention:
The present invention uses two different positive electrode active materials, with the progress of charging, is initially formed low-voltage positive-active material Material, can quickly be increased to high-voltage anode active material, then voltage is steady in low-voltage positive electrode active materials latter stage of charging voltage Be scheduled on high-voltage anode active material, so as to avoid a kind of positive electrode active materials charge end up when cell voltage drastically On the other hand raising is coordinated using voltage change ratio detection means so that and dV/dt becomes being gradually reduced again from gradual increase, from And it is judged as charge termination when dV/dt is decreased to predetermined threshold, charge termination can be preferably detected, prevents excessively filling for battery Electricity, also, by way of the above-mentioned judgement charge termination of voltage change ratio, having as charge termination detection agent can be reduced The usage amount of the electrode active material of high voltage.So as to improve the accuracy of end point determination, and it is close with higher accumulation Degree improves the volumetric properties of battery.
Description of the drawings
Fig. 1 is a kind of flow chart of the charging method of the safety of lithium ion secondary battery of smart home of the present invention.
Specific embodiment
It elaborates below in conjunction with the accompanying drawings to the specific embodiment of the present invention.
Purpose, technical scheme and advantage to make the embodiment of the present invention are clearer, below in conjunction with the embodiment of the present invention In attached drawing, the technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is Part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art The all other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
Embodiment one:
The present invention uses two different positive electrode active materials, matches with the progress and voltage change ratio detection means of charging It closes so that dV/dt becomes being gradually reduced again from gradual increase, so as to be judged as charging eventually when dV/dt is decreased to predetermined threshold Point can preferably detect charge termination, prevent overcharging for battery, also, charge by the above-mentioned judgement of voltage change ratio The mode of terminal can guarantee quick charge, and be avoided that the big charging current of latter stage of charging causes the drastically liter of cell voltage It is high.The security performance of battery is improved, latticed coating method can reduce the usage amount of binding agent and reduce resistance simultaneously, including Following steps:
(1)By positive electrode active materials cobalt acid lithium and LiNi0.6Mn0.2Co0.2O2It is uniformly mixed, with conductive agent, binding agent and solvent one It rises and slurry, wherein LiNi is made0.6Mn0.2Co0.2O2Account for the 1.5% of total positive electrode active materials quality, positive electrode active materials, conduction Agent, binding agent percentage be respectively:94%th, 3%, 3%;LiNi0.6Mn0.2Co0.2O2Average grain diameter for 150nm, cobalt acid lithium Average grain diameter be 800nm.
(2)The latticed adhesive linkage of silk-screen printing on aluminium collector, bonding layer material coated area are afflux bulk area 22%, adhesive linkage includes binding agent PVDF and nano-silver powder, and nano-silver powder accounts for the 45% of adhesive linkage quality;
(3)By step(1)Slurry obtained is coated on the collector comprising adhesive linkage, in 100 DEG C of dryings, obtains positive plate;
(4)By step(3)Obtained positive plate is assembled into lithium rechargeable battery with negative plate and electrolyte;
(5)Constant-current charge is carried out to lithium rechargeable battery, constant-current charge is divided into 3 stages, and the 1st stage charging current is 5C, Charging time is 9min, and the 2nd stage charging current is 1C, and charging time 9min, the 3rd stage charging current is 0.1C, is charged To charge termination;
(6)In step(5)The 3rd stage, at interval of 3s detection primary voltage variations change rate dV/dt, dV/dt from gradual Increase becomes being gradually reduced again, is judged as charge termination when dV/dt is decreased to 0.2V/h, stops the charging to battery.
Embodiment two:A kind of charging method of the safety of lithium ion secondary battery of smart home, includes the following steps:
(1)By positive electrode active materials cobalt acid lithium and LiNi0.5Mn0.25Co0.25O2It is uniformly mixed, with conductive agent, binding agent and solvent Slurry, wherein LiNi are made together0.5Mn0.25Co0.25O2Account for the 2% of total positive electrode active materials quality, positive electrode active materials, conduction Agent, binding agent percentage be respectively:94%th, 3%, 3%;LiNi0.5Mn0.25Co0.25O2Average grain diameter for 200nm, cobalt acid The average grain diameter of lithium is 1000nm.
(2)The latticed adhesive linkage of silk-screen printing on aluminium collector, bonding layer material coated area are afflux bulk area 24%, adhesive linkage includes binding agent PVDF and nano-silver powder, and nano-silver powder accounts for the 45% of adhesive linkage quality;
(3)By step(1)Slurry obtained is coated on the collector comprising adhesive linkage, in 100 DEG C of dryings, obtains positive plate;
(4)By step(3)Obtained positive plate is assembled into lithium rechargeable battery with negative plate and electrolyte;
(5)Constant-current charge is carried out to lithium rechargeable battery, constant-current charge is divided into 3 stages, and the 1st stage charging current is 5C, Charging time is 9min, and the 2nd stage charging current is 1C, and charging time 9min, the 3rd stage charging current is 0.1C, is charged To charge termination;
(6)In step(5)The 3rd stage, at interval of 3s detection primary voltage variations change rate dV/dt, dV/dt from gradual Increase becomes being gradually reduced again, is judged as charge termination when dV/dt is decreased to 0.2V/h, stops the charging to battery.Ability Technical staff in domain is it should be appreciated that embodiments herein can be provided as method, system or computer program product.Therefore, originally Apply for the form of the embodiment in terms of complete hardware embodiment, complete software embodiment can be used or combine software and hardware.And And the computer-usable storage medium for wherein including computer usable program code in one or more can be used in the application (Including but not limited to magnetic disk storage, CD-ROM, optical memory etc.)The form of the computer program product of upper implementation.
The application is with reference to method, the equipment according to the embodiment of the present application(System)And the flow of computer program product Figure and/or block diagram describe.It should be understood that it can be realized by computer program instructions every first-class in flowchart and/or the block diagram The combination of flow and/or box in journey and/or box and flowchart and/or the block diagram.These computer programs can be provided The processor of all-purpose computer, special purpose computer, Embedded Processor or other programmable data processing devices is instructed to produce A raw machine so that the instruction performed by computer or the processor of other programmable data processing devices is generated for real The device of function specified in present one flow of flow chart or one box of multiple flows and/or block diagram or multiple boxes.
These computer program instructions, which may also be stored in, can guide computer or other programmable data processing devices with spy Determine in the computer-readable memory that mode works so that the instruction generation being stored in the computer-readable memory includes referring to Enable the manufacture of device, the command device realize in one flow of flow chart or multiple flows and/or one box of block diagram or The function of being specified in multiple boxes.
These computer program instructions can be also loaded into computer or other programmable data processing devices so that counted Series of operation steps are performed on calculation machine or other programmable devices to generate computer implemented processing, so as in computer or The instruction offer performed on other programmable devices is used to implement in one flow of flow chart or multiple flows and/or block diagram one The step of function of being specified in a box or multiple boxes.
Finally it should be noted that:The above embodiments are merely illustrative of the technical scheme of the present invention and are not intended to be limiting thereof, to the greatest extent Pipe is described in detail the present invention with reference to above-described embodiment, those of ordinary skills in the art should understand that:Still The specific embodiment of the present invention can be modified or replaced equivalently, and without departing from any of spirit and scope of the invention Modification or equivalent replacement should all cover within the claims of the present invention.

Claims (4)

1. a kind of charging method of the safety of lithium ion secondary battery of smart home, which is characterized in that the method includes such as Lower step:
(1)By positive electrode active materials cobalt acid lithium and LiNi0.5Mn0.25Co0.25O2It is uniformly mixed, with conductive agent, binding agent and solvent Slurry is made together;
(2)The latticed adhesive linkage of silk-screen printing on aluminium collector;
(3)By step(1)Slurry obtained is coated on the collector comprising adhesive linkage, through 100 DEG C of dryings, obtains positive plate;
(4)By step(3)Obtained positive plate is assembled into lithium rechargeable battery with negative plate and electrolyte;
(5)Constant-current charge is carried out to lithium rechargeable battery, constant-current charge is divided into 3 stages, and the 1st stage charging current is 5C, Charging time is 9min, and the 2nd stage charging current is 1C, and charging time 9min, the 3rd stage charging current is 0.1C, is charged To charge termination;
(6)In step(5)The 3rd stage, at interval of 3s detection primary voltage variations change rate dV/dt, dV/dt from gradual Increase becomes being gradually reduced again, is judged as charge termination when dV/dt is decreased to 0.2V/h, stops the charging to battery.
2. the method as described in claim 1, which is characterized in that the positive electrode active materials cobalt acid lithium and LiNi0.5Mn0.25Co0.25O2It is uniformly mixed, slurry is made together with conductive agent, binding agent and solvent, including:
The LiNi of total positive electrode active materials quality 2% will be accounted for0.5Mn0.25Co0.25O2, 94% positive electrode active materials, 3% conduction Agent, 3% binding agent are mixed, and are fabricated to slurry;
Wherein, LiNi0.5Mn0.25Co0.25O2Average grain diameter for 200nm, the average grain diameter of cobalt acid lithium is 1000nm.
3. the method as described in claim 1, which is characterized in that the latticed bonding of silk-screen printing on aluminium collector Layer, including:
24% of layer material coated area for afflux bulk area will be bonded, adhesive linkage includes binding agent PVDF and nano-silver powder, receives Rice silver powder accounts for the 45% of adhesive linkage quality.
4. as described in claim 1, which is characterized in that described that constant-current charge, constant-current charge point are carried out to lithium rechargeable battery For 3 stages, including:
1st stage charging current is 5C, charging time 9min;
2nd stage charging current is 1C, charging time 9min;
3rd stage charging current is 0.1C, charges to charge termination.
CN201711432009.XA 2017-12-26 2017-12-26 A kind of charging method of the safety of lithium ion secondary battery of smart home Pending CN108183273A (en)

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CN201711432009.XA CN108183273A (en) 2017-12-26 2017-12-26 A kind of charging method of the safety of lithium ion secondary battery of smart home

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CN201711432009.XA CN108183273A (en) 2017-12-26 2017-12-26 A kind of charging method of the safety of lithium ion secondary battery of smart home

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Cited By (1)

* Cited by examiner, † Cited by third party
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CN116493251A (en) * 2023-06-29 2023-07-28 宁德时代新能源科技股份有限公司 screening equipment

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Application publication date: 20180619