CN108839395B - Toothed plate reinforced composite plate and production process thereof - Google Patents
Toothed plate reinforced composite plate and production process thereof Download PDFInfo
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- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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Abstract
本发明公开了一种齿板增强型复合板材及其生产工艺,包括芯材和金属齿板,所述芯材的上、下面通过金属齿板增强,芯材为热塑性高分子材料,芯材的结构为空心结构;所述金属齿板上设有销钉和热塑性高分子材料的凸起花纹;所述金属齿板开口形状可以是圆形、方形、椭圆或其它多变形。本发明具有附着性好、改善原地承载力、铺设方便、可循环使用、残破后可回收再造、成本低、使用安全等优点。
The invention discloses a tooth plate-reinforced composite plate and its production process, which includes a core material and a metal tooth plate. The upper and lower sides of the core material are reinforced by metal tooth plates. The core material is a thermoplastic polymer material. The structure is a hollow structure; the metal tooth plate is provided with pins and raised patterns of thermoplastic polymer material; the opening shape of the metal tooth plate can be circular, square, elliptical or other multiple deformations. The invention has the advantages of good adhesion, improved in-situ bearing capacity, convenient laying, recyclability, recycling after being broken, low cost, safe use, etc.
Description
技术领域Technical field
本发明的技术领域为复合材料,具体为一种齿板增强型复合板材及其生产工艺,应用于交通、建筑等领域。The technical field of the present invention is composite materials, specifically a tooth plate-reinforced composite plate and its production process, which are used in transportation, construction and other fields.
背景技术Background technique
传统板材多采用单层钢板,虽然其具有较好刚度,承载能力好,易于加工,但是仍存在一下不足。Traditional plates mostly use single-layer steel plates. Although they have good stiffness, good load-bearing capacity and are easy to process, they still have some shortcomings.
1.钢板较重,铺设和移动较为困难,费时费力,而且运输、叠放也不方便,成本较高。1. Steel plates are heavy, difficult to lay and move, time-consuming and labor-intensive, inconvenient to transport and stack, and costly.
2.在遇到如车辆或外力冲击时容易出现不可自然复位的凹痕,易变形,使用寿命短。2. When encountering impacts such as vehicles or external forces, it is easy to have dents that cannot be reset naturally, are easily deformed, and have a short service life.
3.由于钢板表面较光滑,摩擦系数小,因此在实际应用中,如在松软砂土、淤泥等土上使用时,其与地基的抓着力小,不利于车辆或行人行走。3. Since the surface of the steel plate is smooth and the friction coefficient is small, in practical applications, such as when used on soft sand, silt, etc., its grip with the foundation is small, which is not conducive to vehicles or pedestrians walking.
4.现有纯的高分子塑料强度低、刚度不足和耐冲击性不好。4. Existing pure polymer plastics have low strength, insufficient stiffness and poor impact resistance.
发明内容Contents of the invention
本发明的目的在于克服现有纯的高分子塑料强度低、刚度不足和耐冲击性不好等问题,提供一种齿板增强型复合板材及其生产工艺,具有附着性好、改善原地承载力、铺设方便、可循环使用、残破后可回收再造、成本低、使用安全等优点。The purpose of the present invention is to overcome the problems of existing pure polymer plastics such as low strength, insufficient stiffness and poor impact resistance, and provide a tooth plate reinforced composite plate and its production process, which have good adhesion and improved in-situ load bearing. It has the advantages of strength, easy laying, recyclability, recyclability after damage, low cost, and safe use.
本发明采用的技术方案为:一种齿板增强型复合板材,包括芯材和金属齿板,所述芯材的上、下面通过金属齿板增强,芯材为热塑性高分子材料,芯材的结构为空心结构;所述金属齿板上设有销钉和热塑性高分子材料的凸起花纹;The technical solution adopted by the present invention is: a tooth plate-reinforced composite plate, which includes a core material and a metal tooth plate. The upper and lower sides of the core material are reinforced by metal tooth plates. The core material is a thermoplastic polymer material. The structure is a hollow structure; the metal tooth plate is provided with pins and raised patterns of thermoplastic polymer material;
所述金属齿板开口形状可以是圆形、方形、椭圆或其它多变形。所述的齿板开口形状可使在压制过程中,溢出的热塑性高分子材料形成不同形状的凸起花纹。The opening shape of the metal tooth plate may be circular, square, elliptical or other multiple deformations. The opening shape of the tooth plate enables the overflowing thermoplastic polymer material to form convex patterns of different shapes during the pressing process.
所述芯材的空心结构可以为蜂窝形状、圆球形状、圆柱状,以及其它的多边形柱状结构。The hollow structure of the core material can be honeycomb shape, spherical shape, cylindrical shape, and other polygonal columnar structures.
作为优选,所述热塑性高分子材料为高分子聚乙烯、高分子聚丙烯。Preferably, the thermoplastic polymer material is polymer polyethylene or polymer polypropylene.
作为优选,所述金属齿板由钢板、铝板或其它金属板材冲压而成,在冲压的过程中,齿钉一次成型。Preferably, the metal tooth plate is stamped from a steel plate, an aluminum plate or other metal plates, and during the stamping process, the tooth nails are formed at one time.
上述一种齿板增强型复合板材的生产工艺,包括以下步骤:The production process of the above-mentioned tooth plate reinforced composite plate includes the following steps:
1)首先进行单板芯子加工:单板芯子加工是通过加热模具将热塑性高分子材料加热至半熔融状态后,在热塑性高分子材料表面铺上带销钉的金属齿板,并由加热模具压制一次成型;为提高金属齿板和热塑性高分子材料之间的粘结力,在金属齿板和热塑性高分子材料之间涂抹界面剂以提高两者间的界面相容性,增强整体粘结力;1) First perform veneer core processing: veneer core processing is to heat the thermoplastic polymer material to a semi-molten state through a heating mold, then lay a metal tooth plate with pins on the surface of the thermoplastic polymer material, and heat the mold by heating the mold. Press molding in one step; in order to improve the bonding force between the metal tooth plate and the thermoplastic polymer material, an interface agent is applied between the metal tooth plate and the thermoplastic polymer material to improve the interface compatibility between the two and enhance the overall bonding. force;
2)然后进行双板拼合:双板拼合分为两种方式:2) Then join the double boards together: There are two ways to join the double boards:
第一种方式是在单板芯子加工完成的基础上,通过加热板将单板芯子粘结面加热至半熔融状态后,再使用平板压机将两块单板沿芯子面正法线方向压制粘结,其中,在加热板加热单板芯子时,首先将加热板放置两块单板芯子中间位置,待芯子被加热至半熔融状态时,将加热板沿单方向从芯子之间迅速抽离,之后使用平板压机挤压单板,最后通过压实、冷却凝固工艺,去除平板压机,获得复合板材本体成品。The first method is to use a heating plate to heat the bonding surface of the veneer core to a semi-molten state after the veneer core is processed, and then use a flat plate press to press the two veneers along the normal line of the core surface. Directional press bonding. When the heating plate heats the veneer core, first place the heating plate in the middle of the two veneer cores. When the core is heated to a semi-molten state, move the heating plate from the core in one direction. The veneers are quickly separated, and then a flat plate press is used to extrude the veneer. Finally, through the compaction, cooling and solidification process, the flat press is removed to obtain the finished composite plate body.
第二种方式是在单板芯子加工完成的基础上,通过加热板将单板芯子粘结面加热至半熔融状态后,再使用滚轮压机将两块单板沿芯子面正法线方向压制粘结,其中,在加热板加热单板芯子时,首先将加热板放置两块单板芯子中间位置,待芯子被加热至半熔融状态时,将加热板沿单方向从芯子之间迅速抽离,之后使用滚轮压机挤压单板,最后通过压实、冷却凝固工艺,获得复合板材本体成品。The second method is to use a heating plate to heat the bonding surface of the veneer core to a semi-molten state after the veneer core is processed, and then use a roller press to press the two veneers along the normal line of the core surface. Directional press bonding. When the heating plate heats the veneer core, first place the heating plate in the middle of the two veneer cores. When the core is heated to a semi-molten state, move the heating plate from the core in one direction. The veneers are quickly separated, and then a roller press is used to extrude the veneer. Finally, through compaction, cooling and solidification processes, the finished composite plate body is obtained.
所述的金属齿板由钢板、铝板或其它金属板材冲压而成,齿板开口形状可以是圆形、方形、椭圆或其它多变形,在冲压的过程中,齿钉一次成型。The metal tooth plate is stamped from steel plate, aluminum plate or other metal plates. The opening shape of the tooth plate can be round, square, oval or other multiple deformations. During the stamping process, the tooth nails are formed at one time.
作为优选,所述界面剂包括环氧树脂胶、聚氨酯(PU)胶、氨基树脂胶、酚醛树脂胶、丙烯酸树脂胶、聚酰亚胺胶、脲醛树脂胶等高分子胶。Preferably, the interface agent includes polymer glues such as epoxy resin glue, polyurethane (PU) glue, amino resin glue, phenolic resin glue, acrylic resin glue, polyimide glue, and urea-formaldehyde resin glue.
本发明的主要用途为临时道路、应急通道、建筑施工铺路板。The main uses of the invention are temporary roads, emergency passages, and construction paving slabs.
有益效果:本发明在金属板直接与高分子塑料板的粘结性能不好的情况下,通过界面剂和齿钉相配合,可以有效增强粘结性能,提高整体力学性能。同时该种板材具有附着性好、质量轻、可循环利用、残破后可回收再造、成本低、使用安全等优点。Beneficial effects: When the bonding performance between the metal plate and the polymer plastic plate is not good, the invention can effectively enhance the bonding performance and improve the overall mechanical properties through the cooperation of the interface agent and the tooth nail. At the same time, this kind of board has the advantages of good adhesion, light weight, recyclability, recyclability after damage, low cost, and safe use.
附图说明Description of the drawings
图1为本发明齿板增强型复合板材结构示意图;Figure 1 is a schematic structural diagram of the tooth plate reinforced composite plate of the present invention;
图2a为单板成型工艺中初始模具及材料示意图;Figure 2a is a schematic diagram of the initial mold and materials in the veneer forming process;
图2b为单板成型工艺示意图;Figure 2b is a schematic diagram of the veneer forming process;
图2c为单板成型工艺的成型板材示意图;Figure 2c is a schematic diagram of the forming plate of the veneer forming process;
图3a为第一种双板拼合工艺示意图;Figure 3a is a schematic diagram of the first double-plate joining process;
图3b为第二种双板拼合工艺示意图;Figure 3b is a schematic diagram of the second double-plate joining process;
图3c为双板拼合工艺的成型板材示意图;Figure 3c is a schematic diagram of the forming plate of the double plate joining process;
图4a为本发明开口为多边形金属齿板示意图;Figure 4a is a schematic diagram of a polygonal metal tooth plate with openings according to the present invention;
图4b为本发明开口为长方形金属齿板示意图;Figure 4b is a schematic diagram of a rectangular metal tooth plate with an opening according to the present invention;
图4c为本发明开口为椭圆形金属齿板示意图。Figure 4c is a schematic diagram of an oval metal tooth plate with an opening according to the present invention.
具体实施方式Detailed ways
下面结合附图和具体实施方式对本发明做进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.
如图1所示,一种齿板增强型复合板材,包括芯材1和金属齿板2,所述芯材1的上、下面通过金属齿板2增强,芯材1为热塑性高分子材料,所述热塑性高分子材料为高分子聚乙烯、高分子聚丙烯。芯材1的结构为空心结构;所述金属齿板2上设有销钉3和热塑性高分子材料的凸起花纹4;As shown in Figure 1, a tooth plate-reinforced composite plate includes a core material 1 and a metal tooth plate 2. The upper and lower sides of the core material 1 are reinforced by metal tooth plates 2. The core material 1 is a thermoplastic polymer material. The thermoplastic polymer material is polymer polyethylene or polymer polypropylene. The structure of the core material 1 is a hollow structure; the metal tooth plate 2 is provided with pins 3 and raised patterns 4 of thermoplastic polymer material;
所述金属齿板2开口形状可以是圆形、方形、椭圆或其它多变形。所述的金属齿板2开口形状可使在压制过程中,溢出的热塑性高分子材料形成不同形状的凸起花纹。所述金属齿板2由钢板、铝板或其它金属板材冲压而成,在冲压的过程中,齿钉一次成型。The opening shape of the metal tooth plate 2 may be circular, square, elliptical or other multiple deformations. The opening shape of the metal tooth plate 2 enables the overflowing thermoplastic polymer material to form convex patterns of different shapes during the pressing process. The metal tooth plate 2 is stamped from a steel plate, an aluminum plate or other metal plates. During the stamping process, the tooth nails are formed at one time.
所述芯材1的空心结构可以为蜂窝形状、圆球形状、圆柱状,以及其它的多边形柱状结构。The hollow structure of the core material 1 may be in the shape of honeycomb, spherical, cylindrical, or other polygonal columnar structures.
上述一种齿板增强型复合板材的生产工艺,包括以下步骤:The production process of the above-mentioned tooth plate reinforced composite plate includes the following steps:
1)如图2所示,首先进行单板芯子加工:单板芯子加工是通过加热模具5将热塑性高分子材料6加热至半熔融状态后,在热塑性高分子材料表面铺上带销钉3的金属齿板2,并由加热模具5压制一次成型;为提高金属齿板2和热塑性高分子材料6之间的粘结力,在金属齿板2和热塑性高分子材料6之间涂抹界面剂以提高两者间的界面相容性,增强整体粘结力;1) As shown in Figure 2, veneer core processing is performed first: veneer core processing is to heat the thermoplastic polymer material 6 to a semi-molten state through the heating mold 5, and then lay pins 3 on the surface of the thermoplastic polymer material. The metal tooth plate 2 is pressed and formed by the heating mold 5; in order to improve the bonding force between the metal tooth plate 2 and the thermoplastic polymer material 6, an interface agent is applied between the metal tooth plate 2 and the thermoplastic polymer material 6 To improve the interface compatibility between the two and enhance the overall bonding force;
2)然后进行双板拼合:双板拼合分为两种方式:2) Then join the double boards together: There are two ways to join the double boards:
第一种方式是在单板芯子加工完成的基础上,通过加热板7将单板芯子粘结面加热至半熔融状态后,再使用平板压机8将两块单板沿芯子面正法线方向压制粘结,其中,在加热板7加热单板芯子时,首先将加热板7放置两块单板芯子中间位置,待芯子被加热至半熔融状态时,将加热板7沿单方向从芯子之间迅速抽离,之后使用平板压机8按图3a所示方向挤压单板,最后通过压实、冷却凝固工艺,去除平板压机8,获得复合板材本体成品。The first method is to use the heating plate 7 to heat the bonding surface of the veneer core to a semi-molten state after the veneer core is processed, and then use the flat plate press 8 to press the two veneers along the core surface. Pressure bonding in the normal direction. When the heating plate 7 heats the veneer core, first place the heating plate 7 in the middle of the two veneer cores. When the core is heated to a semi-molten state, the heating plate 7 It is quickly pulled out from between the cores in one direction, and then a flat plate press 8 is used to extrude the veneer in the direction shown in Figure 3a. Finally, through the compaction, cooling and solidification process, the flat plate press 8 is removed to obtain the finished product of the composite plate body.
第二种方式是在单板芯子加工完成的基础上,通过加热板7将单板芯子粘结面加热至半熔融状态后,再使用滚轮压机9将两块单板沿芯子面正法线方向压制粘结,其中,在加热板7加热单板芯子时,首先将加热板7放置两块单板芯子中间位置,待芯子被加热至半熔融状态时,将加热板7沿单方向从芯子之间迅速抽离,之后使用滚轮压机9按图3b方式挤压单板,最后通过压实、冷却凝固工艺,获得复合板材本体成品。图3c为成型板材。The second method is to use the heating plate 7 to heat the bonding surface of the veneer core to a semi-molten state after the veneer core is processed, and then use the roller press 9 to press the two veneers along the core surface. Pressure bonding in the normal direction. When the heating plate 7 heats the veneer core, first place the heating plate 7 in the middle of the two veneer cores. When the core is heated to a semi-molten state, the heating plate 7 The veneer is quickly pulled out from between the cores in one direction, and then the roller press 9 is used to extrude the veneer as shown in Figure 3b. Finally, through the compaction, cooling and solidification process, the finished composite plate body is obtained. Figure 3c shows the formed plate.
如图4a、4b、4c所示,所述的金属齿板由钢板、铝板或其它金属板材冲压而成,齿板开口形状可以是圆形、方形、椭圆或其它多变形,在冲压的过程中,齿钉一次成型。所述界面剂包括环氧树脂胶、聚氨酯(PU)胶、氨基树脂胶、酚醛树脂胶、丙烯酸树脂胶、聚酰亚胺胶、脲醛树脂胶等高分子胶。As shown in Figures 4a, 4b, and 4c, the metal tooth plate is stamped from steel plate, aluminum plate or other metal plates. The opening shape of the tooth plate can be round, square, elliptical or other multiple deformations. During the stamping process , the tooth nail is formed at one time. The interface agent includes epoxy resin glue, polyurethane (PU) glue, amino resin glue, phenolic resin glue, acrylic resin glue, polyimide glue, urea-formaldehyde resin glue and other polymer glues.
以上结合附图对本发明的实施方式做出详细说明,但本发明不局限于所描述的实施方式。对本领域的普通技术人员而言,在本发明的原理和技术思想的范围内,对这些实施方式进行多种变化、修改、替换和变形仍落入本发明的保护范围内。The embodiments of the present invention are described in detail above with reference to the accompanying drawings, but the present invention is not limited to the described embodiments. For those of ordinary skill in the art, within the scope of the principles and technical ideas of the present invention, various changes, modifications, substitutions and deformations can be made to these embodiments and still fall within the protection scope of the present invention.
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