CN108878689B - A substrate and its preparation method, and a display device - Google Patents
A substrate and its preparation method, and a display device Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及显示技术领域,尤其涉及一种基板及其制备方法、显示装置。The present invention relates to the field of display technology, and in particular, to a substrate, a preparation method thereof, and a display device.
背景技术Background technique
有机电致发光器件(Organic Electro-luminescent Display,简称OLED)因具有自发光、发光效率高、工作电压低、轻薄、可柔性化及制程工艺简单等诸多优点,在显示、照明等领域得到广泛的应用。Organic Electro-luminescent Display (OLED) has many advantages such as self-luminescence, high luminous efficiency, low operating voltage, lightness, flexibility, and simple manufacturing process. It has been widely used in display, lighting and other fields. application.
目前OLED器件中发光层的成膜方式有两种,一种是蒸镀制程,这种方式适合于小尺寸OLED器件的生产;另一种是溶液制程,溶液制程包括旋涂、喷墨打印或丝网印刷等方式。利用溶液制程成膜的方式由于具有成本低、产能高、适用于大尺寸OLED器件的生产等优点,而被广泛用于OLED器件的生产过程中。At present, there are two ways to form the light-emitting layer in OLED devices, one is the evaporation process, which is suitable for the production of small-sized OLED devices; the other is the solution process, which includes spin coating, inkjet printing or screen printing, etc. The method of film formation using the solution process is widely used in the production process of OLED devices due to its advantages of low cost, high productivity, and suitability for the production of large-sized OLED devices.
现有的像素界定层(Pixel Definition Layer,简称PDL)由挡墙构成,如图1所示,沿靠近衬底基板10到远离衬底基板10的方向,挡墙的宽度逐渐减小,即像素界定层20垂直于衬底基板10的截面为正梯形状。由于形成像素界定层20的材料具有亲附性(像素界定层20的材料包括光刻胶和亲性材料),当在像素界定层20的开口区域中通过溶液制程如喷墨打印(Ink-Jet Printing,简称IJP)形成发光功能层(Electroluminescent,简称EL)30,且墨水中包括亲性材料时,墨水在干燥过程中会沿像素界定层20的侧壁攀爬,因此使得在像素界定层20的开口区域中形成的发光功能层30中间薄、边缘厚,即发光功能层30的厚度不均匀,从而影响OLED器件的出光效果,导致OLED器件亮度均一性较差,进而影响了OLED器件的寿命。The existing pixel definition layer (Pixel Definition Layer, PDL for short) is composed of retaining walls. As shown in FIG. 1 , the width of the retaining walls gradually decreases along the direction from close to the
发明内容SUMMARY OF THE INVENTION
本发明的实施例提供一种基板及其制备方法、显示装置,可解决在现有像素界定层的开口区域形成的发光功能层厚度不均匀的问题。Embodiments of the present invention provide a substrate, a method for manufacturing the same, and a display device, which can solve the problem of uneven thickness of the light-emitting functional layer formed in the opening area of the existing pixel definition layer.
为达到上述目的,本发明的实施例采用如下技术方案:To achieve the above object, the embodiments of the present invention adopt the following technical solutions:
第一方面,提供一种基板的制备方法,包括:在衬底基板上形成像素界定层薄膜;其中,所述像素界定层薄膜的材料包括光刻胶和掺杂在所述光刻胶中的亲性材料、弹性材料及辅助颗粒;所述辅助颗粒用于在分解时释放出气体,所述弹性材料用于在所述辅助颗粒释放出气体时使所述像素界定层薄膜膨胀;所述亲性材料、所述光刻胶以及所述弹性材料的分子量均大于所述辅助颗粒的分子量;对所述像素界定层薄膜进行加热,使所述辅助颗粒向远离所述衬底基板的方向移动;对所述像素界定层薄膜进行处理形成像素界定层,并使所述辅助颗粒分解释放出气体。In a first aspect, a method for preparing a substrate is provided, comprising: forming a pixel definition layer film on a base substrate; wherein, the material of the pixel definition layer film includes photoresist and a material doped in the photoresist. a hydrophilic material, an elastic material and auxiliary particles; the auxiliary particles are used to release gas when decomposing, and the elastic material is used to expand the pixel definition layer film when the auxiliary particles release gas; the affinity The molecular weights of the elastic material, the photoresist and the elastic material are all larger than the molecular weight of the auxiliary particles; heating the pixel definition layer film to make the auxiliary particles move in a direction away from the base substrate; The pixel definition layer film is processed to form a pixel definition layer, and the auxiliary particles are decomposed to release gas.
优选的,对所述像素界定层薄膜进行处理形成像素界定层,并使所述辅助颗粒分解释放出气体,具体包括:对所述像素界定层薄膜进行曝光、显影形成像素界定层;对所述像素界定层中的所述辅助颗粒进行分解处理,以使所述辅助颗粒分解释放出气体;或者,对所述像素界定层薄膜进行曝光、显影形成像素界定层,并使所述辅助颗粒分解释放出气体。Preferably, the pixel-defining layer film is processed to form a pixel-defining layer, and the auxiliary particles are decomposed to release gas, which specifically includes: exposing and developing the pixel-defining layer film to form a pixel-defining layer; The auxiliary particles in the pixel-defining layer are decomposed, so that the auxiliary particles are decomposed to release gas; or, the pixel-defining layer film is exposed and developed to form a pixel-defining layer, and the auxiliary particles are decomposed Gas is released.
进一步优选的,对所述像素界定层中的所述辅助颗粒进行分解处理,以使所述辅助颗粒分解释放出气体,具体包括:对所述像素界定层中的所述辅助颗粒进行加热处理或光照处理使所述辅助颗粒分解释放出气体。Further preferably, decomposing the auxiliary particles in the pixel-defining layer to decompose the auxiliary particles to release gas, specifically comprising: heating the auxiliary particles in the pixel-defining layer or The light treatment decomposes the auxiliary particles to release gas.
优选的,所述像素界定层包括开口区域和用于界定所述开口区域的像素界定区域;对所述像素界定层薄膜进行处理形成像素界定层之后,所述制备方法还包括:在所述像素界定层的开口区域形成发光功能层。Preferably, the pixel-defining layer includes an opening area and a pixel-defining area for defining the opening area; after the pixel-defining layer film is processed to form a pixel-defining layer, the preparation method further includes: in the pixel The opening area of the defining layer forms a light-emitting functional layer.
进一步优选的,在所述像素界定层的开口区域形成发光功能层,包括:利用喷墨打印法在所述像素界定层的开口区域打印包含发光功能层材料的墨水。Further preferably, forming the light-emitting functional layer in the opening area of the pixel defining layer includes: printing ink containing the material of the light-emitting functional layer in the opening area of the pixel defining layer by using an inkjet printing method.
优选的,所述辅助颗粒为偶氮化合物颗粒。Preferably, the auxiliary particles are azo compound particles.
优选的,所述弹性材料包括热塑性聚酯弹性体、热塑性聚氨酯弹性体或热塑性三元乙丙动态硫化弹性体中的至少一种。Preferably, the elastic material includes at least one of thermoplastic polyester elastomer, thermoplastic polyurethane elastomer or thermoplastic EPDM dynamic vulcanization elastomer.
优选的,所述亲性材料包括聚酰亚胺、双酚A聚碳酸酯、主链中含有烷基的聚合物以及主链中含有环状刚性结构的聚合物中的至少一种。Preferably, the affinity material includes at least one of polyimide, bisphenol A polycarbonate, a polymer containing an alkyl group in the main chain, and a polymer containing a cyclic rigid structure in the main chain.
第二方面,提供一种基板,所述基板采用上述的制备方法制备形成。In a second aspect, a substrate is provided, and the substrate is prepared and formed by the above-mentioned preparation method.
第三方面,提供一种显示装置,包括上述的基板。In a third aspect, a display device is provided, including the above-mentioned substrate.
本发明的实施例提供一种基板及其制备方法、显示装置,在衬底基板上制备像素界定层时,由于像素界定层薄膜的材料中除包括光刻胶和亲性材料外,还包括辅助颗粒和弹性材料,在对像素界定层薄膜加热后,像素界定层薄膜中的辅助颗粒会向远离衬底基板的方向移动,这样沿靠近衬底基板到远离衬底基板的方向,辅助颗粒的分布密度逐渐增加,因此当对像素界定层薄膜进行处理,并使辅助颗粒释放出气体时,由于沿靠近衬底基板到远离衬底基板的方向,辅助颗粒的分布密度逐渐增加,因而沿靠近衬底基板到远离衬底基板的方向,辅助颗粒分解释放出的气体的量逐渐增加,因此像素界定层的膨胀程度逐渐越大,这样一来,当像素界定层由挡墙构成时,沿靠近衬底基板到远离衬底基板的方向,挡墙的宽度逐渐增加(即形成的像素界定层垂直于衬底基板的截面为倒梯形状)。基于此,当在像素界定层的开口区域形成发光功能层时,由于沿靠近衬底基板到远离衬底基板的方向,挡墙的宽度逐渐增加,因而挡墙的侧壁会对发光功能层材料施加朝向衬底基板的应力,这样一来在利用溶液制程形成发光功能层时,便防止了发光功能层的材料在干燥过程中沿挡墙的侧壁攀爬,从而使得形成的发光功能层厚度均一。当该基板应用于OLED器件中时确保了OLED器件的发光均一性,提高了OLED器件的寿命。Embodiments of the present invention provide a substrate, a method for preparing the same, and a display device. When a pixel defining layer is prepared on the base substrate, since the material of the pixel defining layer film includes not only photoresist and affinity material, but also auxiliary particles and elastic material, after heating the pixel definition layer film, the auxiliary particles in the pixel definition layer film will move away from the base substrate, so that the distribution density of auxiliary particles in the direction from close to the base substrate to away from the base substrate Gradually increase, so when the pixel definition layer film is processed and the auxiliary particles are released gas, the distribution density of auxiliary particles gradually increases in the direction from approaching the base substrate to the direction away from the base In the direction away from the base substrate, the amount of gas released by the decomposition of the auxiliary particles gradually increases, so the expansion degree of the pixel defining layer gradually increases. In the direction away from the base substrate, the width of the retaining wall gradually increases (ie, the cross-section of the formed pixel defining layer perpendicular to the base substrate is an inverted trapezoid). Based on this, when the light-emitting functional layer is formed in the opening area of the pixel definition layer, since the width of the retaining wall gradually increases in the direction from close to the base substrate to the direction away from the base substrate, the sidewall of the retaining wall will affect the material of the light-emitting functional layer. Apply stress toward the base substrate, so that when the light-emitting functional layer is formed by the solution process, the material of the light-emitting functional layer is prevented from climbing along the sidewall of the retaining wall during the drying process, so that the thickness of the formed light-emitting functional layer is reduced. uniform. When the substrate is used in an OLED device, the uniformity of light emission of the OLED device is ensured, and the lifespan of the OLED device is improved.
附图说明Description of drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to explain the embodiments of the present invention or the technical solutions in the prior art more clearly, the following briefly introduces the accompanying drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are only These are some embodiments of the present invention. For those of ordinary skill in the art, other drawings can also be obtained according to these drawings without creative efforts.
图1为现有技术提供的一种在衬底基板上形成像素界定层的结构示意图;1 is a schematic structural diagram of forming a pixel definition layer on a base substrate provided by the prior art;
图2为本发明实施例提供的一种基板的制备方法的流程示意图;FIG. 2 is a schematic flowchart of a method for preparing a substrate according to an embodiment of the present invention;
图3为本发明实施例提供的一种在衬底基板上形成像素界定层薄膜的结构示意图一;3 is a schematic structural diagram 1 of forming a pixel definition layer film on a base substrate according to an embodiment of the present invention;
图4为本发明实施例提供的一种在衬底基板上形成像素界定层薄膜的结构示意图二;FIG. 4 is a second structural schematic diagram of forming a pixel definition layer film on a base substrate according to an embodiment of the present invention;
图5为本发明实施例提供的一种基板的结构示意图一;FIG. 5 is a schematic structural diagram 1 of a substrate according to an embodiment of the present invention;
图6为本发明实施例提供的一种基板的结构示意图二;FIG. 6 is a second structural schematic diagram of a substrate provided by an embodiment of the present invention;
图7(a)为本发明实施例提供的一种在衬底基板上形成像素界定层的结构示意图一;FIG. 7( a ) is a schematic structural diagram 1 of forming a pixel defining layer on a base substrate according to an embodiment of the present invention;
图7(b)为本发明实施例提供的一种在衬底基板上形成像素界定层的结构示意图二。FIG. 7( b ) is a second structural schematic diagram of forming a pixel defining layer on a base substrate according to an embodiment of the present invention.
附图标记:Reference number:
10-衬底基板;20-像素界定层;30-发光功能层;40-像素界定层薄膜;50-辅助颗粒;60-TFT驱动电路;70-平坦层;80-电极层;801-子电极。10-substrate; 20-pixel defining layer; 30-light-emitting functional layer; 40-pixel defining layer film; 50-auxiliary particles; 60-TFT driving circuit; 70-flat layer; 80-electrode layer; 801-sub-electrode .
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
本发明实施例提供一种基板的制备方法,如图2所示,包括:An embodiment of the present invention provides a method for preparing a substrate, as shown in FIG. 2 , including:
S100、如图3所示,在衬底基板10上形成像素界定层薄膜40;其中,像素界定层薄膜40的材料包括光刻胶和掺杂在光刻胶中的亲性材料、弹性材料及辅助颗粒50;辅助颗粒50用于在分解时释放出气体,弹性材料用于在辅助颗粒50释放出气体时使像素界定层薄膜40膨胀;亲性材料、光刻胶以及弹性材料的分子量均大于辅助颗粒50的分子量。S100 , as shown in FIG. 3 , a pixel
需要说明的是,第一,对于衬底基板10的材料不进行限定。示例的,衬底基板10的材料可以是氮化硅(SiNx)、氧化硅(SiOx)或氮氧化硅(SiOxNy)中的至少一种。It should be noted that, first, the material of the
第二,对于如何在衬底基板10上形成像素界定层薄膜40不进行限定,例如,可以利用旋涂或喷涂等在衬底基板10上形成像素界定层薄膜40。Second, how to form the pixel
第三,对于辅助颗粒50的材料不进行限定,以能在分解时释放出气体为准。此外,对于如何使辅助颗粒50分解不进行限定,辅助颗粒50可以在加热时分解释放出气体,此时辅助颗粒50为热分解材料,辅助颗粒50的材料例如可以为偶氮化合物,其中,偶氮化合物的结构通式为R-N=N-R′,R为可以为烃基或碱金属,烃基具体可以为脂烃基、酰基、磺酰基等有机基团,此外在辅助颗粒50热分解不影响像素界定层薄膜40其它成分的情况下,辅助颗粒50的材料还可以选用叠氮化合物;辅助颗粒50也可以在光照时分解释放出气体,此时辅助颗粒50为光分解材料,辅助颗粒50的材料例如可以为邻叠氮萘醌类化合物。Third, the material of the
在此基础上,对于辅助颗粒50释放出的气体类型不进行限定,为了避免辅助颗粒50释放出的气体与基板上的膜层反应,影响基板上膜层的性能,因而本发明优选辅助颗粒50分解释放出氮气(N2)、氩气(Ar)或一氧化碳(CO)等性能较稳定的气体。进一步优选的,由于氮气性能稳定,不易与其它材料反应,因而本发明实施例辅助颗粒50分解释放出氮气。On this basis, the type of gas released by the
对于弹性材料的具体材料不进行限定,由于弹性材料在辅助颗粒50释放出气体时可以使像素界定层薄膜40膨胀,因而弹性材料应选用高弹性材料。示例的,弹性材料可以包括热塑性聚酯弹性体、热塑性聚氨酯弹性体(Thermoplastic polyyrethane,简称TPU)或热塑性三元乙丙动态硫化弹性体(Thermoplastic Vulcanizate,简称TPV)中的至少一种。其中,热塑性聚酯弹性体(TPEE),又称聚酯橡胶,是一类含有PBT(聚对苯二甲酸丁二醇酯)聚酯硬段和脂肪族聚酯或聚醚软段的线型嵌段共聚物。The specific material of the elastic material is not limited. Since the elastic material can expand the pixel
对于光刻胶的材料不进行限定,例如可以包括聚酰亚胺(Polyimide,简称PI)。此外,光刻胶可以正性光刻胶,也可以是负性光刻胶。The material of the photoresist is not limited, for example, it can include polyimide (Polyimide, PI for short). In addition, the photoresist can be either positive photoresist or negative photoresist.
此处,亲性材料可以为亲水性材料或亲油性材料。亲性材料为刚性聚合物,对于亲性材料的具体材料不进行限定,示例的,亲性材料可以包括聚酰亚胺、双酚A聚碳酸酯、主链中含有烷基的聚合物以及主链中含有环状刚性结构的聚合物中的至少一种。其中,主链中含有烷基的聚合物例如可以是聚丙烯酸、聚丙烯酞胺、聚乙烯醇、聚氨酷、聚酞胺等高分子及其衍生物。此外,需要说明的是,由于聚酰亚胺既可以作为光刻胶的材料,又可以作为亲性材料,因而光刻胶的材料和亲性材料可以都选用聚酰亚胺,当光刻胶的材料和亲性材料都选用聚酰亚胺时,在聚酰亚胺中加入弹性材料及辅助颗粒50即可。Here, the hydrophilic material may be a hydrophilic material or a lipophilic material. The affinity material is a rigid polymer, and the specific material of the affinity material is not limited. For example, the affinity material may include polyimide, bisphenol A polycarbonate, a polymer containing an alkyl group in the main chain, and a main At least one of the polymers containing a cyclic rigid structure in the chain. Among them, the polymer containing an alkyl group in the main chain can be, for example, polymers such as polyacrylic acid, polyacrylamide, polyvinyl alcohol, polyurethane, and polyamide, and derivatives thereof. In addition, it should be noted that since polyimide can be used as both a photoresist material and an affinity material, both the photoresist material and the affinity material can be selected from polyimide. When polyimide is selected as the material and the affinity material, the elastic material and
基于上述,本发明实施提供的像素界定层薄膜40的材料包括但不限于光刻胶和掺杂在光刻胶中的亲性材料、弹性材料和辅助颗粒50外,还可以包括其它材料如溶剂。Based on the above, the materials of the pixel defining
S101、如图4所示,对像素界定层薄膜40进行加热,使辅助颗粒50向远离衬底基板10的方向移动。S101 , as shown in FIG. 4 , heating the pixel
其中,由于辅助颗粒50的分子量小于像素界定层薄膜40的材料中光刻胶、弹性材料以及亲性材料的分子量,因而当对像素界定层薄膜加热时,辅助颗粒50会向远离衬底基板10的方向运动,这样一来,如图4所示,沿靠近衬底基板10到远离衬底基板10的方向(如图4中箭头所示),辅助颗粒50的分布密度逐渐增加。Wherein, since the molecular weight of the
此处,当辅助颗粒50的材料为热分解材料,由于在对像素界定层薄膜40进行加热的过程中,辅助颗粒50要向远离衬底基板10的方向移动,因而辅助颗粒50不能分解,因此选取的对像素界定层薄膜40加热的温度应小于辅助颗粒50的热分解温度。本发明实施例优选的,对像素界定层薄膜40进行加热的加热温度为30~40℃。Here, when the material of the
S102、如图5所示,对像素界定层薄膜40进行处理形成像素界定层20,并使辅助颗粒50分解释放出气体。S102 , as shown in FIG. 5 , the pixel
此处,在对像素界定层薄膜40进行处理时,可以在形成像素界定层20的同时,使辅助颗粒50分解释放出气体;也可以先形成像素界定层20,再使辅助颗粒50分解释放出气体,对此不进行限定。Here, when the pixel defining
需要说明的是,由于沿靠近衬底基板10到远离衬底基板10的方向,辅助颗粒50的分布密度逐渐增加,因而沿靠近衬底基板10到远离衬底基板10的方向,辅助颗粒50释放出的气体的量逐渐增加,而像素界定层薄膜40中的弹性材料在辅助颗粒50释放出气体时可以使像素界定层薄膜40膨胀,辅助颗粒50释放出的气体的量越多,像素界定层薄膜40膨胀程度越大,因而沿靠近衬底基板10到远离衬底基板10的方向,像素界定层20的膨胀程度越大。基于此,当像素界定层20由挡墙构成时,沿靠近衬底基板10到远离衬底基板10的方向,挡墙的宽度逐渐增加,即像素界定层20垂直于衬底基板10的截面为倒梯形状。It should be noted that, since the distribution density of the
本发明实施例提供一种基板的制备方法,在衬底基板10上制备像素界定层20时,由于像素界定层薄膜40的材料中除包括光刻胶和亲性材料外,还包括辅助颗粒50和弹性材料,在对像素界定层薄膜40加热后,像素界定层薄膜40中的辅助颗粒50会向远离衬底基板10的方向移动,这样沿靠近衬底基板10到远离衬底基板10的方向,辅助颗粒50的分布密度逐渐增加,因此当对像素界定层薄膜40进行处理,并使辅助颗粒50释放出气体时,由于沿靠近衬底基板10到远离衬底基板10的方向,辅助颗粒50的分布密度逐渐增加,因而沿靠近衬底基板10到远离衬底基板10的方向,辅助颗粒50分解释放出的气体的量逐渐增加,因此像素界定层20的膨胀程度逐渐越大,这样一来,当像素界定层20由挡墙构成时,沿靠近衬底基板10到远离衬底基板10的方向,挡墙的宽度逐渐增加(即形成的像素界定层20垂直于衬底基板10的截面为倒梯形状)。基于此,当在像素界定层20的开口区域形成发光功能层30时,由于沿靠近衬底基板10到远离衬底基板10的方向,挡墙的宽度逐渐增加,因而挡墙的侧壁会对发光功能层30材料施加朝向衬底基板10的应力(如图5中箭头所示),这样一来在利用溶液制程形成发光功能层30时,便防止了发光功能层30的材料在干燥过程中沿挡墙的侧壁攀爬,从而使得形成的发光功能层30厚度均一。当该基板应用于OLED器件中时确保了OLED器件的发光均一性,提高了OLED器件的寿命。An embodiment of the present invention provides a method for manufacturing a substrate. When the
基于上述,需要说明的是,在衬底基板10上形成像素界定层薄膜40之前,如图6所示,还可以先在衬底基板10上形成TFT(Thin Film Transistor,薄膜晶体管)驱动电路60,在TFT驱动电路60上形成平坦层70,平坦层70覆盖TFT驱动电路60,再在平坦层70形成电极层80,电极层80包括多个相互独立的子电极801,子电极801通过平坦层70上的过孔与TFT驱动电路60连接,每个子电极801位于像素界定层20的一个开口区域。此处,对于平坦层70的厚度不进行限定,优选的,平坦层70的厚度为1~10μm。此外,对于如何形成电极层80不进行限定,示例的,可以现在平坦层70上溅射一层导电薄膜,再通过对导电薄膜进行曝光、显影及刻蚀形成多个子电极801。子电极801的材料例如可以为ITO(Indium Tin Oxide,氧化铟锡)等透明材料。Based on the above, it should be noted that, before forming the pixel defining
优选的,步骤S102包括:Preferably, step S102 includes:
S200、对像素界定层薄膜40进行曝光、显影形成像素界定层20。S200 , exposing and developing the pixel defining
需要说明的是,当像素界定层薄膜40中的光刻胶材料为正性光刻胶时,正性光刻胶曝光的位置显影后溶解,未曝光的位置显影后保留,由于最终形成的像素界定层20没有受到光照,因而无论辅助颗粒50的材料是光分解材料,还是热分解材料,在制备基板时,可以先实施步骤S101,如图4所示,再实施步骤S200,此时得到的像素界定层20如图7(a)所示,即先使像素界定层薄膜40中的辅助颗粒50移动后,沿靠近衬底基板10到远离衬底基板10的方向,辅助颗粒50的分布密度逐渐增加,再对像素界定层薄膜40曝光显影形成像素界定层20;也可以先实施步骤S200,此时得到的像素界定层20如图7(b)所示,再实施步骤S101,得到如图7(a)所示的像素界定层,即先对像素界定层薄膜40曝光显影形成像素界定层20,再使像素界定层20中的辅助颗粒50移动后,沿靠近衬底基板10到远离衬底基板10的方向,辅助颗粒50的分布密度逐渐增加。It should be noted that, when the photoresist material in the pixel defining
当像素界定层薄膜40中的光刻胶材料为负性光刻胶时,负性光刻胶未曝光的位置显影后溶解,曝光的位置显影后保留,由于曝光的位置光刻胶会发生固化反应,这样一来,辅助颗粒50在加热时会不易移动,因而本发明实施例,当光刻胶为负性光刻胶时,在制备基板时,先实施步骤S101,再实施步骤S200。When the photoresist material in the pixel defining
此处,对像素界定层薄膜40进行曝光、显影形成像素界定层20后,此时如图7(a)和图7(b)所示,若像素界定层20由挡墙构成,则沿靠近衬底基板10到远离衬底基板10的方向,挡墙的宽度相同,即像素界定层20垂直于衬底基板10的截面为矩形。Here, after the pixel
S201、对像素界定层20中的辅助颗粒50进行分解处理,以使辅助颗粒50分解释放出气体。S201 , decomposing the
此处,对于分解处理不进行限定,以能使辅助颗粒50分解释放出气体为准。具体的,分解处理可以是加热处理,也可以是光照处理。当辅助颗粒50的材料为热分解材料时,对像素界定层20中的辅助颗粒50进行加热处理,以使辅助颗粒50分解释放出气体,此时加热处理的加热温度可以根据辅助颗粒50的热分解温度进行相应选择;当辅助颗粒50的材料为光分解材料时,对像素界定层20中的辅助颗粒50进行光照处理,以使辅助颗粒50分解释放出气体。此处,对像素界定层20中的辅助颗粒50进行光照处理时,选取的光与辅助颗粒50有关,示例的,若辅助颗粒50在紫外光照射下可以分解释放出气体,则光照处理选择紫外光;若辅助颗粒50在可见光照射下可以分解释放出气体,则光照处理选择可见光。Here, the decomposition treatment is not limited, as long as the
当像素界定层薄膜40中的光刻胶材料为负性光刻胶,负性光刻胶曝光的位置显影后保留,若像素界定层薄膜40中的辅助颗粒50为光分解材料,且能在可见光例如黄光下分解释放出气体,则步骤S102包括:When the photoresist material in the pixel
S300、对像素界定层薄膜40进行曝光、显影形成像素界定层20,并使辅助颗粒50分解释放出气体。S300 , exposing and developing the pixel defining
由于像素界定层薄膜40中的光刻胶材料为负性光刻胶,负性光刻胶曝光的位置显影后保留,在对负性光刻胶曝光时,辅助颗粒50在可见光的照射会分解释放出气体,因而在形成像素界定层20的同时,辅助颗粒50会分解释放出气体,因此可以无需再对辅助颗粒50进行分解处理。Since the photoresist material in the pixel defining
优选的,像素界定层20包括开口区域和用于界定开口区域的像素界定区域。Preferably, the
对像素界定层薄膜40进行处理形成像素界定层20之后,上述制备方法还包括:在像素界定层20的开口区域形成发光功能层30。After the pixel-defining
其中,发光功能层30除包括发光层外,还可以包括空穴注入层、空穴传输层、电子传输层以及电子注入层中的至少一种。The light-emitting
此外,对于发光层的材料不进行限定,可以是有机发光层;也可以是量子点发光层。In addition, the material of the light-emitting layer is not limited, and it may be an organic light-emitting layer or a quantum dot light-emitting layer.
在此基础上,对于采用何种工艺在像素界定层20的开口区域形成发光功能层30不进行限定,示例的,可以采用丝网印刷工艺或喷墨打印工艺在像素界定层20的开口区域形成发光功能层30。On this basis, there is no limitation on which process is used to form the light-emitting
需要说明的是,当对像素界定层薄膜40进行处理形成像素界定层20包括步骤S200以及步骤S201时,可以在步骤S200之后,步骤S201之前,在像素界定层20的开口区域形成发光功能层30;也可以在步骤S201之后,在像素界定层20的开口区域形成发光功能层30。由于先形成发光功能层30,再对像素界定层20中的辅助颗粒50进行分解处理,以使辅助颗粒50分解释放出气体,这样一来,一方面,辅助颗粒50分解释放出气体使像素界定层20膨胀的过程,可以更好地抑制发光功能层30的材料沿像素界定层20的侧壁攀爬;另一方面当对辅助颗粒50的分解处理为加热处理时,可以在对辅助颗粒50进行加热处理以使辅助颗粒50分解释放出气体的同时,对发光功能层30进行烘烤,简化了基板的制作工艺,因而本发明实施例优选的,在步骤S200之后,步骤S201之前,在像素界定层20的开口区域形成发光功能层30。在此基础上,在步骤S200之后,步骤S201之前,在像素界定层20的开口区域形成发光功能层30时,在对辅助颗粒50进行热分解处理时,可以根据辅助颗粒50的热分解温度和发光功能层30的材料选择合适的加热处理的加热温度。此外,加热处理可以是常压加热,也可以是低压加热。It should be noted that, when the processing of the pixel defining
进一步优选的,在像素界定层20的开口区域形成发光功能层30,包括:利用喷墨打印法在像素界定层20的开口区域打印包含发光功能层材料的墨水。Further preferably, forming the light-emitting
由于喷墨打印法相对于其它溶液制程如丝网印刷具有精度高、节省材料等优点,因而本发明实施例优选利用喷墨打印法在像素界定层20的开口区域打印包含发光功能层材料的墨水,以形成发光功能层30。Since the inkjet printing method has the advantages of high precision and material saving compared with other solution processes such as screen printing, the embodiment of the present invention preferably uses the inkjet printing method to print the ink containing the material of the light-emitting functional layer in the opening area of the
本发明实施例提供一种基板,所述基板采用上述的制备方法制备形成。An embodiment of the present invention provides a substrate, which is prepared and formed by the above-mentioned preparation method.
需要说明的是,当基板采用上述基板的制备方法制备形成时,形成的像素界定层20如图5所示,像素界定层20垂直于衬底基板10的截面为倒梯形状,即像素界定层20由挡墙构成时,沿靠近衬底基板10到远离衬底基板10的方向,挡墙的宽度逐渐增加。It should be noted that when the substrate is prepared and formed by the above-mentioned substrate preparation method, the formed
本发明实施例提供一种基板,当基板上的像素界定层20由挡墙构成时,由于沿靠近衬底基板10到远离衬底基板10的方向,挡墙的宽度逐渐增加,因而当在像素界定层20的开口区域形成发光功能层30时,挡墙的侧壁会对发光功能层30材料施加朝向衬底基板10的应力,这样一来在利用溶液制程形成发光功能层30时,便防止了发光功能层30的材料在干燥过程中沿挡墙的侧壁攀爬,从而使得形成的发光功能层30厚度均一。当该基板应用于OLED器件中时确保了OLED器件的发光均一性,提高了OLED器件的寿命。An embodiment of the present invention provides a substrate. When the
本发明实施例提供还提供一种显示装置,包括上述的基板。Embodiments of the present invention provide and further provide a display device including the above-mentioned substrate.
其中,本发明实施例提供的显示装置可以是显示不论运动(例如,视频)还是固定(例如,静止图像)的且不论文字还是图画的图像的任何装置。更明确地说,预期所述实施例可实施在多种电子装置中或与多种电子装置关联,所述多种电子装置例如(但不限于)移动电话、无线装置、个人数据助理(PDA)、手持式或便携式计算机、GPS接收器/导航器、相机、MP4视频播放器、摄像机、游戏控制台、手表、时钟、计算器、电视监视器、平板显示器、计算机监视器、汽车显示器(例如,里程表显示器等)、导航仪、座舱控制器和/或显示器、相机视图的显示器(例如,车辆中后视相机的显示器)、电子相片、电子广告牌或指示牌、投影仪、建筑结构、包装和美学结构(例如,对于一件珠宝的图像的显示器)等。此外,本发明实施例提供的显示装置还可以是显示面板。Wherein, the display device provided by the embodiment of the present invention may be any device that displays an image regardless of motion (eg, video) or fixed (eg, still image), and regardless of text or picture. More specifically, it is contemplated that the embodiments may be implemented in or associated with a wide variety of electronic devices, such as, but not limited to, mobile phones, wireless devices, personal data assistants (PDAs) , handheld or portable computers, GPS receivers/navigators, cameras, MP4 video players, camcorders, game consoles, watches, clocks, calculators, TV monitors, flat panel monitors, computer monitors, automotive monitors (e.g., odometer displays, etc.), navigators, cockpit controls and/or displays, displays of camera views (eg, displays of rear-view cameras in vehicles), electronic photographs, electronic billboards or signs, projectors, building structures, packaging and aesthetic structures (eg, a display for an image of a piece of jewelry), etc. In addition, the display device provided by the embodiment of the present invention may also be a display panel.
此处,当基板上形成的发光功能层30包括有机发光层时,显示装置为有机电致发光显示装置;当基板上形成的发光功能层30包括量子点发光层时,显示装置为量子点发光显示装置(Quantum Dot Light Emitting Diodes,简称QLED)。Here, when the light-emitting
需要说明的是,显示装置除包括上述的基板外,还可以包括形成在基板上的封装层或封装基板。It should be noted that, in addition to the above-mentioned substrate, the display device may further include an encapsulation layer or an encapsulation substrate formed on the substrate.
本发明实施例还提供一种显示装置,显示装置包括上述的基板,显示装置中的基板具有与上述实施例提供的基板相同的结构和有益效果,由于上述实施例已经对基板的技术特征和有益效果进行了详细的描述,因而此处不再赘述。Embodiments of the present invention also provide a display device, the display device includes the above-mentioned substrate, and the substrate in the display device has the same structure and beneficial effects as the substrate provided by the above-mentioned embodiment, because the above-mentioned embodiment has already improved the technical characteristics and beneficial effects of the substrate. The effect has been described in detail, so it will not be repeated here.
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应以所述权利要求的保护范围为准。The above are only specific embodiments of the present invention, but the protection scope of the present invention is not limited thereto. Any person skilled in the art can easily think of changes or substitutions within the technical scope disclosed by the present invention. should be included within the protection scope of the present invention. Therefore, the protection scope of the present invention should be based on the protection scope of the claims.
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| CN111697024B (en) | 2019-03-11 | 2023-09-08 | 合肥鑫晟光电科技有限公司 | Display substrate and preparation method thereof |
| CN110379839B (en) | 2019-07-24 | 2021-11-02 | 京东方科技集团股份有限公司 | A display substrate, a manufacturing method of a display substrate, and a display device |
| CN110649185B (en) * | 2019-09-26 | 2022-08-09 | 合肥京东方卓印科技有限公司 | Display substrate, ink-jet printing method thereof and display device |
| CN111223901B (en) * | 2019-11-29 | 2022-07-29 | 云谷(固安)科技有限公司 | Display panel and preparation method thereof |
| CN111710706B (en) * | 2020-06-30 | 2022-11-29 | 云谷(固安)科技有限公司 | Display panel, preparation method of display panel and display device |
| CN111864090A (en) * | 2020-07-07 | 2020-10-30 | 武汉华星光电半导体显示技术有限公司 | Display panel, display panel manufacturing method and display device |
| CN112909057B (en) * | 2021-01-27 | 2024-03-15 | 京东方科技集团股份有限公司 | A display substrate, its manufacturing method and display device |
| CN112909061A (en) * | 2021-02-02 | 2021-06-04 | 武汉华星光电半导体显示技术有限公司 | Flexible display panel and preparation method thereof |
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