CN108935496A - Long-acting mould-proof bacteria remover and preparation method thereof - Google Patents
Long-acting mould-proof bacteria remover and preparation method thereof Download PDFInfo
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- CN108935496A CN108935496A CN201810712674.2A CN201810712674A CN108935496A CN 108935496 A CN108935496 A CN 108935496A CN 201810712674 A CN201810712674 A CN 201810712674A CN 108935496 A CN108935496 A CN 108935496A
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- mould
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- 241000894006 Bacteria Species 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims description 17
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 239000003112 inhibitor Substances 0.000 claims abstract description 12
- 239000002562 thickening agent Substances 0.000 claims abstract description 10
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 6
- 239000000417 fungicide Substances 0.000 claims abstract description 6
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 24
- -1 iodopropynyl butyl Chemical group 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 20
- 150000002148 esters Chemical class 0.000 claims description 15
- NMJJFJNHVMGPGM-UHFFFAOYSA-N n-butylmethanoate Natural products CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
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- 239000002253 acid Substances 0.000 claims description 7
- 229920006037 cross link polymer Polymers 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 5
- XJMWHXZUIGHOBA-UHFFFAOYSA-N azane;propanoic acid Chemical compound N.CCC(O)=O XJMWHXZUIGHOBA-UHFFFAOYSA-N 0.000 claims description 5
- 125000002346 iodo group Chemical group I* 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 150000007530 organic bases Chemical group 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
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- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- FIDHUEJNXPLJNN-UHFFFAOYSA-N [ClH]=C Chemical compound [ClH]=C FIDHUEJNXPLJNN-UHFFFAOYSA-N 0.000 claims description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 229960001927 cetylpyridinium chloride Drugs 0.000 claims description 3
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 239000003002 pH adjusting agent Substances 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- ZXPLGLMEXWSLCX-UHFFFAOYSA-N 2-chloro-3,5-dimethylphenol Chemical compound CC1=CC(C)=C(Cl)C(O)=C1 ZXPLGLMEXWSLCX-UHFFFAOYSA-N 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 claims 1
- 229960000228 cetalkonium chloride Drugs 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229940031098 ethanolamine Drugs 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229950008882 polysorbate Drugs 0.000 claims 1
- 229920000136 polysorbate Polymers 0.000 claims 1
- 229940032912 zephiran Drugs 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 238000003556 assay Methods 0.000 description 5
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- 238000004806 packaging method and process Methods 0.000 description 5
- 239000008234 soft water Substances 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 4
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical group [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 4
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- 230000000694 effects Effects 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
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- 239000002781 deodorant agent Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 2
- 235000004443 Ricinus communis Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
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- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000011169 microbiological contamination Methods 0.000 description 2
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 2
- 239000008159 sesame oil Substances 0.000 description 2
- 235000011803 sesame oil Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
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- 239000000126 substance Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- WMSLPDVKMJABST-UHFFFAOYSA-N 4-iodobut-2-ynoic acid Chemical compound OC(=O)C#CCI WMSLPDVKMJABST-UHFFFAOYSA-N 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 208000019693 Lung disease Diseases 0.000 description 1
- 206010027146 Melanoderma Diseases 0.000 description 1
- CBSOFSBFHDQRLV-UHFFFAOYSA-N N-methylbenzylamine hydrochloride Chemical compound [Cl-].C[NH2+]CC1=CC=CC=C1 CBSOFSBFHDQRLV-UHFFFAOYSA-N 0.000 description 1
- 206010028813 Nausea Diseases 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 208000036071 Rhinorrhea Diseases 0.000 description 1
- 206010039101 Rhinorrhoea Diseases 0.000 description 1
- 241000235342 Saccharomycetes Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- OPCRGEVPIBLWAY-QNRZBPGKSA-N ethyl (2E,4Z)-deca-2,4-dienoate Chemical compound CCCCC\C=C/C=C/C(=O)OCC OPCRGEVPIBLWAY-QNRZBPGKSA-N 0.000 description 1
- 125000005909 ethyl alcohol group Chemical group 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 230000008693 nausea Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 206010041232 sneezing Diseases 0.000 description 1
- XNRNJIIJLOFJEK-UHFFFAOYSA-N sodium;1-oxidopyridine-2-thione Chemical compound [Na+].[O-]N1C=CC=CC1=S XNRNJIIJLOFJEK-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of long-acting mould-proof bacteria removers, include the raw material of following weight percent: mould inhibitor 0.1-2%；Thickener 0.2-2%；Fungicide 0.005-5%；Solvent 5-50%；Surfactant 0.1-5%；Auxiliary agent 0-1%；Water 40-90%.The long-acting mould-proof bacteria remover can continue mould proof 90 days or more, and there is height to sprawl adhesion, and it is mould proof to be suitable for household.
Description
Technical field
The present invention relates to daily chemical product fields, more particularly to long-acting mould-proof bacteria remover and preparation method thereof.
Background technique
As the microorganisms such as mould and bacterium, saccharomycete, it is distributed widely in the biosphere of the earth, growth and breeding are very
Rapidly, metabolism is very vigorous, and is easy variation and adapts to environment, so under appropriate conditions will be in various objects
It grows and breeds on product.The growth of mould is that we live common phenomenon at home, especially regional in south China, annual
Plum rain season and " going back to Nan Tian " time, moist environment are even more the breeding ground that mould breeds.Common phenomenon are as follows: wall occurs mould
Become, furniture blackspot etc. occurs in growing between apparent mould, sanitation of bath-room.
Influence of the growth of mould to human health is even more that cannot ignore.The spore of mould with air flowing
And disperse everywhere, the malaise symptoms such as asthma and headache, dizziness, nausea, rhinorrhea, sneezing can be caused, it is serious also to cause
Respiratory system failure and initiation Pulmonary Diseases.There are many method for preventing article from going mouldy, and it is micro- to can control temperature, humidity, oxygen etc.
The environmental condition that biology is depended on for existence, or physical factor and chemical bactericide are used to kill microorganism or inhibit microorganism
Growing environment etc..Chinese patent CN103651449A discloses a kind of long-acting mould-proof deodorant and preparation method thereof, patent
Design use iodopropynyl butyl formate and parachlorometaxylenol for mould inhibitor, using propylene glycol, polypropylene glycol and
Polyethylene glycol is solubilisation aids, prepares liquid spray type long-acting mould-proof deodorant.But iodopropynyl butyl formate
Additive amount is up to 3%-8%, and the long-acting mould-proof deodorant low-temperature stability of preparation is poor.And liquid sprays mold proof product cannot be compared with
The position at good covering household dead angle.In addition it in spraying process, is also easy to that human body is caused to suck, there are security risks；It is Chinese special
Sharp CN 107549185A discloses a kind of leather fungicide and preparation method thereof, from the point of view of the formula of patent disclosure, uses third
Ring azoles, three kinds of active constituents of sodium pyrithione and iodopropynyl butyl carbamate, heterogeneity have antibacterial activity group, phase
It is had obvious synergistic function between mutually, improves the antibacterial spectrality of mould inhibitor.CN105885203A discloses a kind of solid
Film class mold proof product, it is lower in the application value of household wall and furniture surface.
Summary of the invention
Based on this, the present invention provides a kind of long-acting mould-proof bacteria remover and preparation method thereof.
The specific technical proposal is:
A kind of long-acting mould-proof bacteria remover, includes the raw material of following weight percent:
The mould inhibitor is selected from iodopropynyl butyl formate, the chloro- 3,5-dimethylphenol of 2,4- bis- and didecyl
One or more of methyl polyoxyethanyl propionic acid ammonium；
The thickener be selected from acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer, hydroxyethyl cellulose,
One or more of carboxymethyl cellulose and modified magnesium aluminium silicate.
The long-acting mould-proof bacteria remover includes the raw material of following weight percent in one of the embodiments:
The thickener is selected from acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters crosslinking in one of the embodiments,
Polymer.
The mould inhibitor is selected from iodopropynyl butyl formate in one of the embodiments,.
The fungicide is selected from dodecyl benzyl dimethyl ammonium chloride, cetyl two in one of the embodiments,
Methylbenzyl ammonium chloride one or more of gathers own methylene hydrochloride and Cetylpyridinium Chloride.
The solvent is selected from ethyl alcohol, propylene glycol, glycerine, propylene glycol monomethyl ether and dipropyl two in one of the embodiments,
One of alcohol methyl ether is a variety of.
The surfactant is selected from fatty alcohol polyoxyethylene ether, rilanit special, poly- mountain in one of the embodiments,
One or more of pear ester and sorbitan fatty acid ester.
The auxiliary agent includes pH adjusting agent in one of the embodiments, and the pH adjusting agent is selected from organic base.
The organic base is selected from triethanolamine or monoethanolamine in one of the embodiments,.
The present invention also provides the preparation methods of above-mentioned long-acting mould-proof bacteria remover, comprising the following steps:
The thickener and surfactant are added in the water, stirring obtains component A to dissolving；
The mould inhibitor is added in the solvent, stirs to being completely dissolved, adds the fungicide, stirs, obtains B group
Point；
The B component is added into the component A, is stirred evenly, be added auxiliary agent, obtain thickened mixt to get.
The pH value of the thickened mixt is 7.5-9.0 in one of the embodiments,.
Compared with prior art, the invention has the following advantages:
For the present invention by joined specific thickener into specific mould-proof bacteria-removing system, the advantage of generation is as follows:
(1) after particular thickener being added, iodopropynyl formic acid fourth can be reduced under the premise of not influencing drug effect
The additive amount of the mould inhibitors such as ester makes to be not easy to be precipitated under its low temperature, the stability of raising mould-proof bacteria-removing system, and sustainable mould proof 90
More than it, achieve the purpose that play drug effect for a long time.
(2) after particular thickener being added, mildewproof bacteria remover is in gel, there is height to sprawl adhesion, in the mould proof mistake of household
Cheng Zhong is preferably attached to household surface, and can easily cover blank area, and mould proof contact is more abundant, solves household dead angle
It is difficult to the problem covered.
(3) present invention using the antibacterial activity group of heterogeneity by being made specific mould inhibitor and bactericide compounded
With, can kill or inhibit fungus growth and kill and inhibit bacterial growth, have apparent synergistic effect, improve it is antibacterial
Spectrality.On the basis of long-acting mould-proof, 99.9% is up to the killing rate of household common bacteria, solves existing mould inhibitor sterilization
Effect technical problem on the weak side.
Specific embodiment
It to facilitate the understanding of the present invention, below will be to invention is more fully described.The present invention can be with many not
With form realize, however it is not limited to embodiment described herein.On the contrary, purpose of providing these embodiments is makes to this
Disclosure of the invention content understanding is more thorough and comprehensive.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein "and/or" includes one or more phases
Any and all combinations of the listed item of pass.
Long-acting mould-proof bacteria remover and preparation method thereof of the invention is made below in conjunction with specific embodiment further details of
Explanation.
Raw material used in following specific embodiments can derive from commercially available unless otherwise noted.
Didecyl methyl polyoxyethanyl propionic acid ammonium CAS No.94667-33-1.
Embodiment 1-3
According to raw material each in table 1 and its content, prepare the long-acting mould-proof bacteria remover of embodiment 1-3, it is specific the preparation method comprises the following steps:
In container A, first acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer is added in soft water,
It stirs evenly, sufficiently dissolves.Rilanit special and essence are added, stirring is allowed to dissolve, and obtains component A.
In another container B, iodopropynyl butyl formate, propylene glycol and ethyl alcohol are stirred evenly, make iodo third
Alkynylamino butyl formate is completely dissolved, and dodecyl benzyl dimethyl ammonium chloride is added, and stirring and dissolving obtains B component.
Solution in container B is added into A, is stirred sufficiently at transparent and homogeneous liquid.Monoethanolamine is added, adjusts pH value
It is 8, thickens mixed system.Sample detection, carried out after the assay was approved it is filling, packaging to get.
The raw material and content of the long-acting mould-proof bacteria remover of 1 embodiment 1-3 of table
Embodiment 4-6
According to raw material each in table 2 and its content, prepare the long-acting mould-proof bacteria remover of embodiment 4-6, it is specific the preparation method comprises the following steps:
In container A, first acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer is added in soft water,
It stirs evenly, sufficiently dissolves.Rilanit special and essence are added, stirring is allowed to dissolve, and obtains component A.
In another container B, didecyl methyl polyoxyethanyl propionic acid ammonium, propylene glycol and ethyl alcohol are stirred evenly, didecyl is made
Ylmethyl polyoxyethanyl propionic acid ammonium is completely dissolved, and addition gathers own methylene hydrochloride, and stirring and dissolving obtains B component.
Solution in container B is added into A, is stirred sufficiently at transparent and homogeneous liquid.Monoethanolamine is added, adjusts pH value
It is 8, thickens mixed system.Sample detection, carried out after the assay was approved it is filling, packaging to get.
The raw material and content of the long-acting mould-proof bacteria remover of 2 embodiment 4-6 of table
Embodiment 7-9
According to raw material each in table 3 and its content, prepare the long-acting mould-proof bacteria remover of embodiment 7-9, it is specific the preparation method comprises the following steps:
It in container A, first adds hydroxyethyl cellulose into soft water, stirs evenly, sufficiently dissolve.Add hydrogenation castor
Sesame oil and essence, stirring are allowed to dissolve, and obtain component A.
In another container B, iodopropynyl butyl formate, propylene glycol and ethyl alcohol are stirred evenly, make iodo third
Alkynylamino butyl formate is completely dissolved, and dodecyl benzyl dimethyl ammonium chloride is added, and stirring and dissolving obtains B component.
Solution in container B is added into A, is stirred to obtain the final product.Sample detection is carried out filling, packaging after the assay was approved,
To obtain the final product.
The raw material and content of the long-acting mould-proof bacteria remover of 3 embodiment 7-9 of table
Embodiment 10-12
According to raw material each in table 4 and its content, the long-acting mould-proof bacteria remover of embodiment 10-12, specific preparation method are prepared
Are as follows:
In container A, first modified magnesium aluminium silicate is added in soft water, is stirred evenly, is sufficiently dissolved.Add hydrogenation castor
Sesame oil and essence, stirring are allowed to dissolve, and obtain component A.
In another container B, iodopropynyl butyl formate, propylene glycol and ethyl alcohol are stirred evenly, make iodo third
Alkynylamino butyl formate is completely dissolved, and dodecyl benzyl dimethyl ammonium chloride is added, and stirring and dissolving obtains B component.
Solution in container B is added into A, is stirred to obtain the final product.Sample detection is carried out filling, packaging after the assay was approved,
To obtain the final product.
The raw material and content of the long-acting mould-proof bacteria remover of 4 embodiment 10-12 of table
Embodiment 13-15
According to raw material each in table 5 and its content, the long-acting mould-proof bacteria remover of embodiment 13-15, specific preparation method are prepared
Are as follows:
In container A, first acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer is added in soft water,
It stirs evenly, sufficiently dissolves.Rilanit special and essence are added, stirring is allowed to dissolve, and obtains component A.
In another container B, iodopropynyl butyl formate, propylene glycol and ethyl alcohol are stirred evenly, make iodo third
Alkynylamino butyl formate is completely dissolved, and Cetylpyridinium Chloride is added, and stirring and dissolving obtains B component.
Solution in container B is added into A, is stirred sufficiently at transparent and homogeneous liquid.Triethanolamine is added, adjusts pH value
It is 8, thickens mixed system.Sample detection, carried out after the assay was approved it is filling, packaging to get.
The raw material and content of the long-acting mould-proof bacteria remover of 5 embodiment 13-15 of table
Comparative example 1-4
According to raw material each in table 6 and its content, prepare the long-acting mould-proof bacteria remover of comparative example 1-4, specific preparation method with
Embodiment 1 is identical.
The raw material and content of the long-acting mould-proof bacteria remover of 6 comparative example 1-4 of table
Effect application test example
The long-acting mould-proof bacteria remover of embodiment 1-15 and comparative example 1-4 are tested for the property.The specific method is as follows:
1, mould proof measuring evaluation method
Using filter paper as carrier, the mould proof spraying anti-mold effect to aspergillus niger is evaluated.
1) mould proof test: carrier and pretreatment mode: carrier is filter paper, is cut into 4 × 4cm size, and 121 DEG C of high pressures are gone out
Bacterium, 50 DEG C of drying.It adds the mould proof feed liquid of 0.5g respectively on filter paper, it is stand-by to be placed in natural air drying in Biohazard Safety Equipment.
2) preparation of microbiological contamination plate: being added 200 μ L (1-9) × 105CFU/mL black-koji mould suspension on SDA plate, applies
Cloth is uniform, for use.
3) it cultivates: filter paper sample being flattened on the SDA plate of microbiological contamination, carrier is allowed to come into full contact with culture medium.It is positive to put
Enter 28 ± 1 DEG C of cultures.
4) determine grade:
The mould proof grade criterion of table 8
2, sterilization is quantitative kills test
The Guantitative bactericidal test of mildewproof bacteria remover is tested referring to the requirement in the Ministry of Public Health " disinfection technology standard ".
Test strain is common bacteria Escherichia coli, staphylococcus aureus.Mildewproof bacteria remover is in following item to the killing rate of bacterium
Test obtains under part: test fluid concentration is stoste, action time 30min.Experimental result is shown in Table 9,10.
The evaluation of 9 anti-mold effect of table
The evaluation of 10 bactericidal effect of table
There is table 9,10 it is found that the long-acting mould-proof bacteria remover of embodiment 1-15 can effectively inhibit the growth of mildew, it is effectively anti-
The mould time can reach 90 days or more, and be up to common bacteria Escherichia coli and the golden yellow staphylococcic killing rate of Soviet Union
99.9%, also there is height to sprawl characteristic, realizes comprehensive protection to household.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of long-acting mould-proof bacteria remover, which is characterized in that include the raw material of following weight percent:
The mould inhibitor is selected from iodopropynyl butyl formate, the chloro- 3,5-dimethylphenol of 2,4- bis- and didecyl methyl
One or more of polyoxyethanyl propionic acid ammonium；
The thickener is selected from acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer, hydroxyethyl cellulose, carboxylic first
One or more of base cellulose and modified magnesium aluminium silicate.
2. long-acting mould-proof bacteria remover according to claim 1, which is characterized in that include the original of following weight percent
Material:
3. long-acting mould-proof bacteria remover according to claim 1, which is characterized in that the thickener is selected from acrylic acid (ester)
Class/C10-30 alkylol acrylamide acid esters cross-linked polymer.
4. long-acting mould-proof bacteria remover according to claim 1, which is characterized in that the mould inhibitor is selected from iodo propinyl ammonia
Base butyl formate.
5. long-acting mould-proof bacteria remover according to claim 1-4, which is characterized in that the fungicide is selected from 12
Zephiran, cetalkonium chloride gather in own methylene hydrochloride and Cetylpyridinium Chloride
It is one or more of.
6. long-acting mould-proof bacteria remover according to claim 1-4, which is characterized in that the solvent be selected from ethyl alcohol,
One of propylene glycol, glycerine, propylene glycol monomethyl ether and dipropylene glycol methyl ether are a variety of.
7. long-acting mould-proof bacteria remover according to claim 1-4, which is characterized in that the surfactant is selected from
One or more of fatty alcohol polyoxyethylene ether, rilanit special, polysorbate and sorbitan fatty acid ester.
8. long-acting mould-proof bacteria remover according to claim 1-4, which is characterized in that the auxiliary agent includes pH tune
Agent is saved, the pH adjusting agent is selected from organic base.
9. long-acting mould-proof bacteria remover according to claim 8, which is characterized in that the organic base is selected from triethanolamine or list
Ethanol amine.
10. a kind of preparation method of the described in any item long-acting mould-proof bacteria removers of claim 1-9, which is characterized in that including with
Lower step:
The thickener and surfactant are added in the water, stirring obtains component A to dissolving；
The mould inhibitor is added in the solvent, stirs to being completely dissolved, adds the fungicide, stirs, obtains B component；
The B component is added into the component A, is stirred evenly, be added auxiliary agent, obtain thickened mixt to get.
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| CN114711242A (en) * | 2022-02-14 | 2022-07-08 | 绍兴崇高新材料科技有限公司 | Novel mildew-proof material and preparation method and application thereof |
| CN115486451A (en) * | 2022-10-22 | 2022-12-20 | 广州市宝绅科技应用有限公司 | Long-acting slow-release antibacterial mildew inhibitor |
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