CN108947670A - High-energy phosphoryl compound fertilizer and application thereof - Google Patents
High-energy phosphoryl compound fertilizer and application thereof Download PDFInfo
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Abstract
本发明公开了一种高能磷酰肥料,它包括高能磷酰化合物,所述的高能磷酰化合物为6‑磷酸果糖、6‑磷酸葡萄糖、果糖‑2,6‑二磷酸、果糖‑1,6‑二磷酸、磷酸肌酸、FAD、NADH、NADPH中的任意一种或几种的组合。与现有技术相比,本发明适用于所有植物的浸种、拌种、叶面喷施、灌根、冲施、喷灌、滴灌等方式使用;无毒、无激素、无残留,能平衡调节植物生长发育,促进植物光合作用和新陈代谢;可延迟植物衰老,提高品质,增加产量;具有一定的抗旱、抗寒和抗病作用;多次施用可减少化肥施用量10~40%;作物增产5~60%。The invention discloses a high-energy phosphoryl fertilizer, which comprises a high-energy phosphoryl compound, and the high-energy phosphoryl compound is fructose-6-phosphate, glucose-6-phosphate, fructose-2,6-diphosphate, fructose-1,6 ‑ Any one or a combination of diphosphate, creatine phosphate, FAD, NADH, NADPH. Compared with the prior art, the present invention is applicable to all plants for seed soaking, seed dressing, foliar spraying, root irrigation, flushing, sprinkler irrigation, drip irrigation, etc.; it is non-toxic, hormone-free, and residue-free, and can balance and regulate plants. Growth and development, promote plant photosynthesis and metabolism; delay plant aging, improve quality, increase yield; have certain drought resistance, cold resistance and disease resistance; multiple applications can reduce the amount of chemical fertilizers by 10-40%; increase crop yield by 5-40% 60%.
Description
技术领域technical field
本发明属于农业肥料技术领域,具体涉及一种高能磷酰化合物肥料及其应用。The invention belongs to the technical field of agricultural fertilizers, and in particular relates to a high-energy phosphoryl compound fertilizer and its application.
背景技术Background technique
大力发展种植业、林业,促进作物增产,保持青山绿水,保护环境,是我国长期关注的重大问题。然而,随着农林业的发展,过量大量施用化学肥料、大量施用农药等现象日益严重。目前,农业用的肥料主要以含氮、磷、钾为主的大量元素肥料、含氨基酸、腐殖酸、黄腐酸等并符合单一或多种微量元素混合的水溶肥料。作物使用后可以起到补充相应元素的作用,对作用有一定的增产效果。但是,少有直接补充能量,并调节作物系统抗性的肥料。Vigorously developing planting and forestry, increasing crop production, maintaining green mountains and green waters, and protecting the environment are major issues of long-term concern in our country. However, with the development of agriculture and forestry, excessive application of chemical fertilizers and pesticides are becoming more and more serious. At present, the fertilizers used in agriculture are mainly macronutrient fertilizers containing nitrogen, phosphorus, and potassium, and water-soluble fertilizers containing amino acids, humic acid, fulvic acid, etc., which are single or mixed with multiple trace elements. After the crops are used, they can supplement the corresponding elements, and have a certain effect on increasing production. However, there are few fertilizers that directly supplement energy and regulate the resistance of crop systems.
酵母是一些单细胞真菌,能将糖发酵成酒精和二氧化碳,分布于整个自然界,是一种典型的兼性厌氧微生物,在有氧和无氧条件下都能够存活,是一种天然发酵剂。酵母转化物中富含多肽、氨基酸、寡聚核苷酸、呈味核苷酸、核苷酸、6-磷酸果糖、果糖-1,6-二磷酸、三磷酸腺苷、二磷酸腺苷、B族维生素、辅因子及微量元素。是一种优良的天然调味料,在食品行业中具有广泛的用途。也是最为理想的生物培养基原料和发酵工业中的主要原料。Yeast is a single-celled fungus that can ferment sugar into alcohol and carbon dioxide. It is distributed throughout nature and is a typical facultative anaerobic microorganism that can survive under both aerobic and anaerobic conditions. It is a natural leavening agent . Yeast transformant is rich in polypeptides, amino acids, oligonucleotides, flavor nucleotides, nucleotides, fructose 6-phosphate, fructose-1,6-diphosphate, adenosine triphosphate, adenosine diphosphate, B vitamins , cofactors and trace elements. It is an excellent natural seasoning and has a wide range of uses in the food industry. It is also the most ideal biological medium raw material and the main raw material in the fermentation industry.
高绪娜等报道了酵母培养物高活性菌株的分离及发酵条件优化(中国饲料 2017第1期 P13-17,27 1004-3314)。金晓琳等综述了酵母培养物在动物生产中的研究与应用(饲料研究 2017 第16期 P7-10 1002-2813)。孙红梅等报道了酵母培养物对牦牛瘤胃发酵及甲烷产量的影响(江苏农业科学 2015 第43卷 第3期 P177-182 1002-1302)。田书会等研究了酵母培养物对夏季生长育肥猪肠道菌群结构和发酵能力的影响(南京农业大学学报2013 第36卷 第4期 1000-2030)。唐海翠等报道了高精料条件下酵母培养物对山羊瘤胃发酵特性的影响(粮食与饲料工业 2006 第9期 P37-38,411003-6202)。周雪飞等研究了不同添加剂量的酵母培养物对绵羊瘤胃发酵的影响(中国畜牧杂志 2015 第51卷 第21期 P49-53 0258-7033)。专利CN105147584A公开了一种含中药成分的酵母转化物及其制备方法和应用。专利CN103910547A公开了一种食用菌培养基及其制备方法和食用菌培养方法。专利CN102178038A公开了一种发酵型高赖氨酸高蛋白饲料的制备方法。Gao Xuna et al. reported the isolation of highly active yeast culture strains and the optimization of fermentation conditions (China Feed 2017 Issue 1 P13-17, 27 1004-3314). Jin Xiaolin and others reviewed the research and application of yeast culture in animal production (Feed Research 2017 No. 16 P7-10 1002-2813). Sun Hongmei et al reported the effect of yeast culture on yak rumen fermentation and methane production (Jiangsu Agricultural Science 2015 Volume 43 Issue 3 P177-182 1002-1302). Tian Shuhui et al. studied the effect of yeast culture on the intestinal flora structure and fermentation ability of growing and finishing pigs in summer (Journal of Nanjing Agricultural University 2013 Volume 36 Issue 4 1000-2030). Tang Haicui et al. reported the effect of yeast culture on the rumen fermentation characteristics of goats under the condition of high concentrate feed (Grain and Feed Industry 2006 No. 9 P37-38, 411003-6202). Zhou Xuefei et al. studied the effect of different dosages of yeast culture on sheep rumen fermentation (Chinese Journal of Animal Husbandry 2015 Volume 51 Issue 21 P49-53 0258-7033). Patent CN105147584A discloses a yeast transformant containing traditional Chinese medicine ingredients and its preparation method and application. Patent CN103910547A discloses an edible fungus culture medium and its preparation method and edible fungus cultivation method. Patent CN102178038A discloses a method for preparing a fermented high-lysine high-protein feed.
因此,即使在现有技术中研究或提出了用于酵母提取物的制备工艺和在应用方案;但经检索,含高能磷酰化合物的肥料及其在农业上的应用,还未见报道。Therefore, even if the preparation process and application scheme for yeast extract are studied or proposed in the prior art; however, after searching, there is no report on the fertilizer containing high-energy phosphoryl compounds and its application in agriculture.
发明内容Contents of the invention
本发明要解决的技术问题是提供一种高能磷酰化合物肥料及其应用,以解决现有技术存在的效果不佳等问题。The technical problem to be solved by the present invention is to provide a high-energy phosphoryl compound fertilizer and its application, so as to solve the problems of poor effect in the prior art.
为解决上述技术问题,本发明采用的技术方案如下:In order to solve the problems of the technologies described above, the technical scheme adopted in the present invention is as follows:
一种高能磷酰化合物肥料,它包括高能磷酰化合物;其中,所述的高能磷酰化合物为如下的三种情况之一:A high-energy phosphoryl compound fertilizer, which includes a high-energy phosphoryl compound; wherein, the high-energy phosphoryl compound is one of the following three situations:
(1)6-磷酸果糖或其盐、6-磷酸葡萄糖或其盐、果糖-1,6-二磷酸或其盐、磷酸肌酸或其盐、FAD或其盐、NADH或其盐和NADPH或其盐中的任意一种;(1) Fructose-6-phosphate or a salt thereof, glucose-6-phosphate or a salt thereof, fructose-1,6-bisphosphate or a salt thereof, creatine phosphate or a salt thereof, FAD or a salt thereof, NADH or a salt thereof, and NADPH or any of its salts;
(2)6-磷酸果糖或其盐、6-磷酸葡萄糖或其盐、果糖-1,6-二磷酸或其盐、磷酸肌酸或其盐、FAD或其盐、NADH或其盐和NADPH或其盐中任意两种的组合;(2) Fructose-6-phosphate or a salt thereof, glucose-6-phosphate or a salt thereof, fructose-1,6-bisphosphate or a salt thereof, creatine phosphate or a salt thereof, FAD or a salt thereof, NADH or a salt thereof, and NADPH or A combination of any two of its salts;
(3)6-磷酸果糖或其盐、6-磷酸葡萄糖或其盐、果糖-1,6-二磷酸或其盐、磷酸肌酸或其盐、FAD或其盐、NADH或其盐和NADPH或其盐的组合。(3) Fructose-6-phosphate or a salt thereof, glucose-6-phosphate or a salt thereof, fructose-1,6-diphosphate or a salt thereof, creatine phosphate or a salt thereof, FAD or a salt thereof, NADH or a salt thereof, and NADPH or its combination of salts.
其中,6-磷酸果糖或其盐、6-磷酸葡萄糖或其盐和果糖-1,6-二磷酸或其盐的结构式如下:Wherein, the structural formulas of fructose-6-phosphate or its salt, glucose-6-phosphate or its salt and fructose-1,6-diphosphate or its salt are as follows:
其中,上述结构式中,R1和R2各自独立的取自氢、金属阳离子、有机阳离子和阳离子氨基酸;Wherein, in the above structural formula , R1 and R2 are independently selected from hydrogen, metal cations, organic cations and cationic amino acids;
其中,in,
所述的金属阳离子为钾、钠、镁、钙、锌、钛、钒、锰、铁、钴、镍、铜、锌和镧或金属阳离子;The metal cations are potassium, sodium, magnesium, calcium, zinc, titanium, vanadium, manganese, iron, cobalt, nickel, copper, zinc and lanthanum or metal cations;
所述的有机阳离子为基于胺的阳离子、基于低聚胺的阳离子、基于聚胺的阳离子或基于氨基酸的阳离子,优选聚乙烯亚胺的阳离子;The organic cations are amine-based cations, oligoamine-based cations, polyamine-based cations or amino acid-based cations, preferably polyethyleneimine cations;
所述的阳离子氨基酸为赖氨酸的阳离子或精氨酸的阳离子。The cationic amino acid is the cation of lysine or the cation of arginine.
情况(1)中,当高能磷酰化合物为6-磷酸果糖或其盐时,水溶性肥料中还包括多肽0.05~20%、氨基酸0.03~20%、寡聚核苷酸1.5~20%、核苷酸0.005~20%、脱氧核苷酸0.005~20%、二磷酸腺苷0.05~2%、B族维生素0.05~5%、辅因子0.05~2%、中量元素0.05~10%和微量元素0.05~10%。In case (1), when the high-energy phosphoryl compound is fructose-6-phosphate or its salt, the water-soluble fertilizer also includes 0.05-20% of polypeptide, 0.03-20% of amino acid, 1.5-20% of oligonucleotide, nuclear Nucleic acid 0.005-20%, deoxynucleotide 0.005-20%, adenosine diphosphate 0.05-2%, B vitamins 0.05-5%, cofactor 0.05-2%, medium element 0.05-10% and trace element 0.05-10%.
情况(1)中,当高能磷酰化合物为6-磷酸葡萄糖或其盐时,肥料中还包括多肽0.05~20%、氨基酸0.03~20%、寡聚核苷酸1.5~20%、核苷酸0.005~20%、脱氧核苷酸0.005~20%、三磷酸腺苷0.05~2%、B族维生素0.05~5%、中量元素0.05~10%和微量元素0.05~10%。In case (1), when the high-energy phosphoryl compound is glucose-6-phosphate or its salt, the fertilizer also includes 0.05-20% of polypeptide, 0.03-20% of amino acid, 1.5-20% of oligonucleotide, nucleotide 0.005-20%, deoxynucleotide 0.005-20%, adenosine triphosphate 0.05-2%, B vitamins 0.05-5%, medium elements 0.05-10% and trace elements 0.05-10%.
情况(1)中,当高能磷酰化合物为果糖-1,6-二磷酸或其盐时,肥料中还包括多肽0.05~20%、氨基酸0.03~20%、寡聚核苷酸1.5~20%、核苷酸0.005~20%、脱氧核苷酸0.005~20%、磷酸腺苷0.05~2%、中量元素0.05~10%和微量元素0.05~10%。In case (1), when the high-energy phosphoryl compound is fructose-1,6-diphosphate or its salt, the fertilizer also includes 0.05-20% of polypeptide, 0.03-20% of amino acid, and 1.5-20% of oligonucleotide , 0.005-20% of nucleotides, 0.005-20% of deoxynucleotides, 0.05-2% of adenosine phosphate, 0.05-10% of medium elements and 0.05-10% of trace elements.
情况(1)中,当高能磷酰化合物为磷酸肌酸或其盐时,肥料中还包括多肽0.05~20%、氨基酸0.03~20%、寡聚核苷酸1.5~20%、核苷酸0.005~20%、脱氧核苷酸0.005~20%、磷酸腺苷0.05~2%、中量元素0.05~10%和微量元素0.05~10%。In case (1), when the high-energy phosphoryl compound is creatine phosphate or its salt, the fertilizer also includes 0.05-20% of polypeptide, 0.03-20% of amino acid, 1.5-20% of oligonucleotide, and 0.005% of nucleotide ~20%, deoxynucleotide 0.005~20%, adenosine phosphate 0.05~2%, medium element 0.05~10% and trace element 0.05~10%.
情况(1)中,当高能磷酰化合物为FAD或其盐、NADH或其盐和NADPH或其盐时,肥料中还包括多肽0.05~40%、氨基酸0.03~40%、寡聚核苷酸1.5~15%、核苷酸0.005~10%、脱氧核苷酸0.005~10%、磷酸腺苷0.05~2%、中量元素0.05~30%和微量元素0.05~30%。In case (1), when the high-energy phosphoryl compound is FAD or its salt, NADH or its salt, and NADPH or its salt, the fertilizer also includes 0.05-40% of polypeptide, 0.03-40% of amino acid, 1.5% of oligonucleotide ~15%, nucleotide 0.005~10%, deoxynucleotide 0.005~10%, adenosine phosphate 0.05~2%, medium element 0.05~30% and trace element 0.05~30%.
情况(2)中,当高能磷酰化合物为6-磷酸果糖或其盐和6-磷酸葡萄糖或其盐时,6-磷酸果糖或其盐和6-磷酸葡萄糖或其盐的质量比为0.5~20∶1;当高能磷酰化合物为6-磷酸果糖或其盐和果糖-1,6-二磷酸或其盐时,6-磷酸果糖或其盐和果糖-1,6-二磷酸或其盐的质量比为0.5~20∶1;当高能磷酰化合物为6-磷酸葡萄糖或其盐和果糖-1,6-二磷酸或其盐时,6-磷酸葡萄糖或其盐和果糖-1,6-二磷酸或其盐的质量比为0.5~20∶1;当高能磷酰化合物为6-磷酸果糖或其盐和磷酸肌酸或其盐时,6-磷酸果糖或其盐和磷酸肌酸或其盐的质量比为0.1~40∶1;当高能磷酰化合物为6-磷酸果糖或其盐和FAD或其盐时,6-磷酸果糖或其盐和FAD或其盐的质量比为0.1~40∶1;当高能磷酰化合物为6-磷酸果糖或其盐和NADH或其盐时,6-磷酸果糖或其盐和NADH或其盐的质量比为0.1~40∶1;当高能磷酰化合物为6-磷酸果糖或其盐和NADPH或其盐时,6-磷酸果糖或其盐和NADPH或其盐的质量比为0.1~40∶1。In case (2), when the high-energy phosphoryl compound is 6-phosphate fructose or its salt and 6-phosphate glucose or its salt, the mass ratio of 6-phosphate fructose or its salt to 6-phosphate glucose or its salt is 0.5~ 20:1; when the high-energy phosphoryl compound is fructose-6-phosphate or its salt and fructose-1,6-diphosphate or its salt, fructose-6-phosphate or its salt and fructose-1,6-diphosphate or its salt The mass ratio is 0.5 to 20:1; when the high-energy phosphoryl compound is 6-phosphate glucose or its salt and fructose-1,6-diphosphate or its salt, 6-phosphate glucose or its salt and fructose-1,6 - The mass ratio of diphosphoric acid or its salt is 0.5 to 20:1; when the high-energy phosphoryl compound is 6-phosphofructose or its salt and phosphocreatine or its salt, The mass ratio of its salt is 0.1~40:1; when the high-energy phosphoryl compound is 6-phosphate fructose or its salt and FAD or its salt, the mass ratio of 6-phosphate fructose or its salt to FAD or its salt is 0.1~ 40:1; when the high-energy phosphoryl compound is 6-phosphate fructose or its salt and NADH or its salt, the mass ratio of 6-phosphate fructose or its salt to NADH or its salt is 0.1 to 40:1; when the high-energy phosphoryl When the compound is fructose-6-phosphate or its salt and NADPH or its salt, the mass ratio of fructose-6-phosphate or its salt to NADPH or its salt is 0.1-40:1.
情况(2)中,当高能磷酰化合物为6-磷酸果糖或其盐和6-磷酸葡萄糖或其盐时,水溶性肥料中还包括多肽0.05~20%、氨基酸0.03~20%、寡聚核苷酸1.5~20%、核苷酸0.005~20%、脱氧核苷酸0.005~20%、二磷酸腺苷0.05~2%、B族维生素0.05~5%、辅因子0.05~2%、中量元素0.05~10%和微量元素0.05~10%。In case (2), when the high-energy phosphoryl compound is 6-phosphate fructose or its salt and 6-phosphate glucose or its salt, the water-soluble fertilizer also includes 0.05-20% of polypeptide, 0.03-20% of amino acid, oligomeric nucleus Nucleic acid 1.5-20%, nucleotide 0.005-20%, deoxynucleotide 0.005-20%, adenosine diphosphate 0.05-2%, B vitamins 0.05-5%, cofactor 0.05-2%, moderate amount 0.05-10% of elements and 0.05-10% of trace elements.
情况(2)中,当高能磷酰化合物为6-磷酸果糖或其盐和果糖-1,6-二磷酸或其盐时,水溶性肥料中还包括多肽0.05~20%、氨基酸0.03~20%、寡聚核苷酸1.5~20%、核苷酸0.005~20%、脱氧核苷酸0.005~20%、环磷腺苷0.05~2%、B族维生素0.05~5%、辅因子0.05~2%、中量元素0.05~10%和微量元素0.05~10%。In case (2), when the high-energy phosphoryl compound is fructose-6-phosphate or its salt and fructose-1,6-diphosphate or its salt, the water-soluble fertilizer also includes 0.05-20% of polypeptide and 0.03-20% of amino acid , oligonucleotide 1.5-20%, nucleotide 0.005-20%, deoxynucleotide 0.005-20%, cyclic adenosine monophosphate 0.05-2%, B vitamins 0.05-5%, cofactor 0.05-2 %, 0.05-10% of medium elements and 0.05-10% of trace elements.
情况(2)中,当高能磷酰化合物为6-磷酸葡萄糖或其盐和果糖-1,6-二磷酸或其盐时,水溶性肥料中还包括多肽0.05~20%、氨基酸0.03~20%、寡聚核苷酸1.5~20%、核苷酸0.005~20%、脱氧核苷酸0.005~20%、二丁酰环磷腺苷0.05~2%、B族维生素0.05~5%、辅因子0.05~2%、中量元素0.05~10%和微量元素0.05~10%。In case (2), when the high-energy phosphoryl compound is 6-phosphate glucose or its salt and fructose-1,6-diphosphate or its salt, the water-soluble fertilizer also includes 0.05-20% of polypeptide and 0.03-20% of amino acid , oligonucleotide 1.5-20%, nucleotide 0.005-20%, deoxynucleotide 0.005-20%, dibutyrylcyclic adenosine monophosphate 0.05-2%, B vitamins 0.05-5%, cofactor 0.05- 2%, 0.05-10% of medium elements and 0.05-10% of trace elements.
情况(2)中,当高能磷酰化合物为磷酸肌酸或其盐、FAD或其盐、NADH或其盐和NADPH或其盐时,水溶性肥料中还包括多肽0.05~20%、氨基酸0.03~20%、寡聚核苷酸1.5~20%、核苷酸0.005~20%、脱氧核苷酸0.005~20%、二丁酰环磷腺苷0.05~2%、B族维生素0.05~5%、辅因子0.05~2%、中量元素0.05~10%和微量元素0.05~10%。In case (2), when the high-energy phosphoryl compound is creatine phosphate or its salt, FAD or its salt, NADH or its salt, and NADPH or its salt, the water-soluble fertilizer also includes 0.05-20% of polypeptide, 0.03-20% of amino acid 20%, oligonucleotide 1.5-20%, nucleotide 0.005-20%, deoxynucleotide 0.005-20%, dibutyryl cycloadenosine 0.05-2%, B vitamins 0.05-5%, cofactor 0.05-2%, medium element 0.05-10% and trace element 0.05-10%.
情况(3)中,情况(3)中,6-磷酸果糖或其盐、6-磷酸葡萄糖或其盐、果糖-1,6-二磷酸或其盐、磷酸肌酸或其盐、FAD或其盐、NADH或其盐、NADPH或其盐的质量比为0.5-40∶0.5-40∶1∶0.01-20∶0.5-40∶0.5-40∶0.5-40。In case (3), in case (3), 6-phosphofructose or its salt, 6-phosphate glucose or its salt, fructose-1,6-diphosphate or its salt, phosphocreatine or its salt, FAD or its The mass ratio of salt, NADH or its salt, NADPH or its salt is 0.5-40:0.5-40:1:0.01-20:0.5-40:0.5-40:0.5-40.
情况(3)中,肥料中还包括多肽0.05~20%、氨基酸0.03~20%、寡聚核苷酸1.5~20%、核苷酸0.005~20%、脱氧核苷酸0.005~20%、B族维生素0.05~5%、辅因子0.05~2%、中量元素0.05~10%和微量元素0.05~10%。In case (3), the fertilizer also includes 0.05-20% of polypeptide, 0.03-20% of amino acid, 1.5-20% of oligonucleotide, 0.005-20% of nucleotide, 0.005-20% of deoxynucleotide, B 0.05-5% of group vitamins, 0.05-2% of cofactors, 0.05-10% of medium elements and 0.05-10% of trace elements.
上述肥料在农作物的种植中的应用也在本发明的保护范围之内。The application of the above-mentioned fertilizers in the cultivation of crops is also within the protection scope of the present invention.
其中,上述肥料可单独使用,也可与大量元素配合使用。Among them, the above-mentioned fertilizers can be used alone or in combination with a large number of elements.
其中,上述肥料可单独用于病虫害防治使用,也可与病虫害防治的药物配合使用。Wherein, the above-mentioned fertilizers can be used alone for pest control, and can also be used in combination with drugs for pest control.
其中,上述肥料和大量元素配合使用时,质量比为0.005~300∶1。Wherein, when the above-mentioned fertilizers are used in combination with macroelements, the mass ratio is 0.005-300:1.
其中,上述肥料可单独使用,也可与腐殖酸或黄腐酸等配合使用。Among them, the above-mentioned fertilizers can be used alone or in combination with humic acid or fulvic acid.
其中,上述肥料呈固体、液体、半固体、凝胶、乳液、溶液、混悬液、胶束、纳米颗粒、微粒或薄膜的形式,可用于所有植物的浸种、拌种、叶面喷施、灌根、冲施、喷灌或滴灌方式使用。它是无毒、无激素、无残留,能平衡调节植物生长发育,促进植物光合作用和新陈代谢;可延迟植物衰老,提高品质,增加产量;具有一定的抗旱、抗寒和抗病作用。Among them, the above-mentioned fertilizers are in the form of solid, liquid, semi-solid, gel, emulsion, solution, suspension, micelles, nanoparticles, microparticles or films, and can be used for soaking, seed dressing, foliar spraying, Root irrigation, flushing, sprinkler irrigation or drip irrigation. It is non-toxic, hormone-free, and residue-free. It can balance and regulate plant growth and development, promote plant photosynthesis and metabolism; it can delay plant aging, improve quality, and increase yield; it has certain effects of drought resistance, cold resistance and disease resistance.
有益效果:Beneficial effect:
与现有技术相比,本发明具有如下优势:Compared with the prior art, the present invention has the following advantages:
本发明肥料的一次喷施用量为每亩植物2~400克,稀释50~20000倍后可用于植物种子的浸种或拌种,在幼苗期、快速生长期、花期、果实膨大期或收获前期叶面喷施、灌根、冲施、喷灌、滴灌等3~6次。适用于所有植物的浸种、拌种、叶面喷施、灌根、冲施、喷灌、滴灌等方式使用;无毒、无激素、无残留,能平衡调节植物生长发育,促进植物光合作用和新陈代谢;可延迟植物衰老,提高品质,增加产量;具有一定的抗旱、抗寒和抗病作用;多次施用可减少化肥施用量10~40%;作物增产5~60%;可广泛用于粮、油、棉、蔬菜、果树、烟草、茶叶、中药材、花卉、林木等植物。它可配合腐殖酸、黄腐酸等可进一步促进植物生长、提供营养、改善和提高品质。The one-time spraying dosage of the fertilizer of the present invention is 2 to 400 grams per mu of plant, and can be used for soaking or seed dressing of plant seeds after being diluted 50 to 20,000 times. Surface spraying, root irrigation, flushing, sprinkler irrigation, drip irrigation, etc. 3 to 6 times. It is suitable for soaking, seed dressing, foliar spraying, root irrigation, flushing, spray irrigation, drip irrigation, etc. of all plants; it is non-toxic, hormone-free, and residue-free, and can balance and regulate plant growth and development, and promote plant photosynthesis and metabolism. It can delay plant aging, improve quality, and increase yield; it has certain effects of drought resistance, cold resistance and disease resistance; multiple applications can reduce the amount of chemical fertilizers by 10-40%; crop yields can increase by 5-60%; it can be widely used in grain, Oil, cotton, vegetables, fruit trees, tobacco, tea, Chinese herbal medicines, flowers, trees and other plants. It can be combined with humic acid, fulvic acid, etc. to further promote plant growth, provide nutrition, improve and improve quality.
具体实施方式Detailed ways
根据下述实施例,可以更好地理解本发明。然而,本领域的技术人员容易理解,实施例所描述的内容仅用于说明本发明,而不应当也不会限制权利要求书中所详细描述的本发明。The present invention can be better understood from the following examples. However, those skilled in the art can easily understand that the content described in the embodiments is only for illustrating the present invention, and should not and will not limit the present invention described in the claims.
实施例1:取6-磷酸果糖5克,硝酸钾1克,粉碎,混合均匀,即得肥料。Embodiment 1: Get 5 grams of fructose-6-phosphate, 1 gram of potassium nitrate, pulverize, mix evenly, obtain fertilizer.
实施例2:取6-磷酸果糖10克,磷酸二氢钾180克,粉碎,混合均匀,即得肥料。Embodiment 2: Get 10 grams of 6-fructose phosphate, 180 grams of potassium dihydrogen phosphate, pulverize, mix evenly, obtain fertilizer.
实施例3:取6-磷酸果糖50克,粉碎,即得肥料。Embodiment 3: Get 50 grams of fructose 6-phosphate, pulverize, obtain fertilizer.
实施例4:取6-磷酸果糖钾盐15克,氯化钙2克,粉碎,混合均匀,即得肥料。Embodiment 4: Get 15 grams of 6-fructose phosphate potassium salt, 2 grams of calcium chloride, pulverize, mix evenly, obtain fertilizer.
实施例5:取6-磷酸果糖钾盐40克,粉碎,即得肥料。Embodiment 5: Take 40 grams of 6-fructose phosphate potassium salt and pulverize it to obtain fertilizer.
实施例6:取6-磷酸果糖钾盐40克,果糖-1,6-二磷酸锌盐5克,硫酸亚铁5克,粉碎,混合均匀,即得肥料。Embodiment 6: Take 40 grams of fructose-6-phosphate potassium salt, 5 grams of fructose-1,6-diphosphate zinc salt, and 5 grams of ferrous sulfate, grind them, and mix them uniformly to obtain fertilizer.
实施例7:取6-磷酸果糖钾盐40克,硫酸亚铁5克,粉碎,混合均匀,即得肥料。Embodiment 7: Get 40 grams of 6-fructose phosphate potassium salt, 5 grams of ferrous sulfate, pulverize, mix evenly, obtain fertilizer.
实施例8:取6-磷酸果糖钠盐20克,果糖-1,6-二磷酸钾盐20克,粉碎,混合均匀,即得肥料。Example 8: Take 20 grams of fructose-6-phosphate sodium salt and 20 grams of fructose-1,6-diphosphate potassium salt, pulverize them and mix them uniformly to obtain fertilizer.
实施例9:取6-磷酸葡萄糖镁盐280克,聚谷氨酸5克,粉碎,混合均匀,即得肥料。Embodiment 9: Take 280 grams of magnesium 6-phosphate glucose and 5 grams of polyglutamic acid, pulverize them, and mix them uniformly to obtain fertilizer.
实施例10:取6-磷酸葡萄糖钙盐50克,聚谷氨酸5克,粉碎,混合均匀,即得肥料。Embodiment 10: Take 50 grams of 6-glucose phosphate calcium salt and 5 grams of polyglutamic acid, pulverize them, and mix them uniformly to obtain fertilizer.
实施例11:取6-磷酸葡萄糖钙盐100克,果糖-1,6-二磷酸镁盐20克,聚天冬氨酸5克,复合氨基酸10克,粉碎,混合均匀,即得肥料。Example 11: Take 100 grams of calcium salt of glucose 6-phosphate, 20 grams of magnesium fructose-1,6-diphosphate, 5 grams of polyaspartic acid, and 10 grams of compound amino acids, pulverize them, and mix them uniformly to obtain fertilizer.
实施例12:取6-磷酸葡萄糖钙盐370克,果糖-1,6-二磷酸镁盐20克,聚天冬氨酸5克,高能磷酰化合物1克,粉碎,混合均匀,即得肥料。Example 12: Take 370 grams of 6-glucose phosphate calcium salt, 20 grams of fructose-1,6-diphosphate magnesium salt, 5 grams of polyaspartic acid, and 1 gram of high-energy phosphoryl compound, pulverize and mix uniformly to obtain fertilizer .
实施例13:取6-磷酸葡萄糖锌盐5克,聚天冬氨酸5克,复合氨基酸10克,粉碎,混合均匀,即得肥料。Example 13: Take 5 grams of 6-glucose phosphate zinc salt, 5 grams of polyaspartic acid, and 10 grams of compound amino acids, pulverize them, and mix them uniformly to obtain fertilizer.
实施例14:取果糖-1,6-二磷酸锌盐30克,B族维生素3克,葡萄糖30克,粉碎,混合均匀,即得肥料。Example 14: Take 30 grams of fructose-1,6-diphosphate zinc salt, 3 grams of B vitamins, and 30 grams of glucose, grind them, and mix them uniformly to obtain a fertilizer.
实施例15:取果糖-1,6-二磷酸锌盐90克,B族维生素3克,粉碎,混合均匀,即得肥料。Example 15: Take 90 grams of fructose-1,6-diphosphate zinc salt and 3 grams of B vitamins, pulverize them, and mix them uniformly to obtain fertilizer.
实施例16:取果糖-1,6-二磷酸锌盐5克,果糖-1,6-二磷酸镁盐5克,葡萄糖10克,粉碎,混合均匀,即得肥料。Example 16: Take 5 grams of fructose-1,6-diphosphate zinc salt, 5 grams of fructose-1,6-diphosphate magnesium salt, and 10 grams of glucose, grind them, and mix them uniformly to obtain fertilizer.
实施例17:取果糖-1,6-二磷酸锌盐30克,果糖-1,6-二磷酸镁盐20克,葡萄糖5克,粉碎,混合均匀,即得肥料。Example 17: Take 30 grams of fructose-1,6-diphosphate zinc salt, 20 grams of fructose-1,6-diphosphate magnesium salt, and 5 grams of glucose, grind them, and mix them uniformly to obtain fertilizer.
实施例18:取果糖-1,6-二磷酸锌盐90克,果糖-1,6-二磷酸钙盐15克,B族维生素1克,粉碎,混合均匀,即得肥料。Example 18: Take 90 grams of fructose-1,6-diphosphate zinc salt, 15 grams of fructose-1,6-diphosphate calcium salt, and 1 gram of B vitamins, pulverize them and mix them uniformly to obtain fertilizer.
实施例19:取果糖-1,6-二磷酸钛盐10克,磷酸二氢钾100克,聚谷氨酸2克,B族维生素1克,粉碎,混合均匀,即得肥料。Example 19: Take 10 grams of fructose-1,6-diphosphate titanium salt, 100 grams of potassium dihydrogen phosphate, 2 grams of polyglutamic acid, and 1 gram of B vitamins, pulverize and mix evenly to obtain fertilizer.
实施例20:取磷酸肌酸15克,磷酸二氢钾100克,聚谷氨酸5克,B族维生素1克,粉碎,混合均匀,即得肥料。Example 20: Take 15 grams of creatine phosphate, 100 grams of potassium dihydrogen phosphate, 5 grams of polyglutamic acid, and 1 gram of B vitamins, pulverize them, and mix them uniformly to obtain fertilizer.
实施例21:取磷酸肌酸锰盐10克,磷酸二氢钾100克,聚谷氨酸15克,氨基酸40克,B族维生素1克,粉碎,混合均匀,即得肥料。Example 21: Take 10 grams of creatine phosphate manganese salt, 100 grams of potassium dihydrogen phosphate, 15 grams of polyglutamic acid, 40 grams of amino acids, and 1 gram of B vitamins, pulverize them, and mix them uniformly to obtain fertilizer.
实施例22:取6-磷酸葡萄糖铁盐5克,果糖-1,6-二磷酸钙盐5克,葡萄糖20克,粉碎,混合均匀,即得肥料。Example 22: Take 5 grams of glucose-6-phosphate iron salt, 5 grams of fructose-1,6-diphosphate calcium salt, and 20 grams of glucose, grind them, and mix them uniformly to obtain a fertilizer.
实施例23:取果糖-1,6-二磷酸铁盐15克,果糖-1,6-二磷酸锌盐5克,葡萄糖20克,粉碎,混合均匀,即得肥料。Example 23: Take 15 grams of fructose-1,6-diphosphate iron salt, 5 grams of fructose-1,6-diphosphate zinc salt, and 20 grams of glucose, pulverize and mix evenly to obtain fertilizer.
实施例24:取果糖-1,6-二磷酸铁盐30克,果糖-1,6-二磷酸铜盐5克,葡萄糖20克,粉碎,混合均匀,即得肥料。Example 24: Take 30 grams of fructose-1,6-diphosphate iron salt, 5 grams of fructose-1,6-diphosphate copper salt, and 20 grams of glucose, grind them, and mix them uniformly to obtain fertilizer.
实施例25:取果糖-1,6-二磷酸钴盐1克,果糖-1,6-二磷酸锌盐5克,葡萄糖20克,粉碎,混合均匀,即得肥料。Example 25: Take 1 gram of fructose-1,6-diphosphate cobalt salt, 5 grams of fructose-1,6-diphosphate zinc salt, and 20 grams of glucose, pulverize and mix evenly to obtain fertilizer.
实施例26:取果糖-1,6-二磷酸镍盐20克,果糖-1,6-二磷酸锌盐5克,酵母转化物1克,粉碎,混合均匀,即得肥料。Example 26: Take 20 grams of fructose-1,6-diphosphate nickel salt, 5 grams of fructose-1,6-diphosphate zinc salt, and 1 gram of yeast transformant, pulverize and mix evenly to obtain fertilizer.
实施例27:取6-磷酸果糖铜盐10克,果糖-1,6-二磷酸铁盐15克,葡萄糖20克,粉碎,混合均匀,即得肥料。Example 27: Take 10 grams of fructose-6-phosphate copper salt, 15 grams of fructose-1,6-diphosphate iron salt, and 20 grams of glucose, grind them, and mix them uniformly to obtain a fertilizer.
实施例28:取果糖-1,6-二磷酸镧盐50克,混合均匀,即得肥料。Example 28: Take 50 grams of fructose-1,6-diphosphate lanthanum salt and mix it evenly to obtain fertilizer.
实施例29::取酵母转化物3~9种10~300克,混合均匀,即得肥料。Example 29: Take 10-300 grams of 3-9 kinds of yeast transformants and mix them evenly to obtain fertilizer.
实施例30:取酵母转化物10~20种10~300克,混合均匀,即得肥料。Embodiment 30: Take 10-20 kinds of yeast transformants, 10-300 grams, and mix them evenly to obtain fertilizer.
实施例31:取6-磷酸果糖100克,即得肥料。Example 31: Take 100 grams of fructose-6-phosphate to obtain fertilizer.
实施例32:取6-磷酸葡萄糖100克,即得肥料。Example 32: Take 100 grams of 6-phosphate glucose to obtain fertilizer.
实施例33:取1,6-二磷酸果糖100克,即得肥料。Example 33: Take 100 grams of fructose 1,6-diphosphate to obtain fertilizer.
实施例34:取6-磷酸果糖钙盐80克,6-磷酸葡萄糖镁盐20克,聚天冬氨酸5克,复合氨基酸10克,粉碎,混合均匀,即得肥料。Example 34: Take 80 grams of 6-fructose phosphate calcium salt, 20 grams of 6-glucose phosphate magnesium salt, 5 grams of polyaspartic acid, and 10 grams of compound amino acids, pulverize them and mix them uniformly to obtain fertilizer.
实施例35:取6-磷酸果糖钙盐160克,6-磷酸葡萄糖镁盐30克,,聚天冬氨酸6克,酵母转化物1克,粉碎,混合均匀,即得肥料。Example 35: Take 160 grams of fructose-6-phosphate calcium salt, 30 grams of magnesium glucose-6-phosphate salt, 6 grams of polyaspartic acid, and 1 gram of yeast transformant, pulverize and mix well to obtain fertilizer.
实施例36:马铃薯、地瓜、山芋等块茎类:幼苗期、快速生长期、现蕾期和果实膨大期叶面喷施5次,用40克实施例1所述肥料兑水40升,喷施一亩地,可增产30%。Example 36: tubers such as potatoes, sweet potatoes, and sweet potatoes: Spray 5 times on the leaves of the seedling stage, the rapid growth stage, the budding stage and the fruit expansion stage, mix 40 liters of fertilizer with 40 grams of the fertilizer described in Example 1, and spray One mu of land can increase production by 30%.
实施例37:水稻浸种,40克实施例4所述肥料兑水1.5升;幼苗期、分蘖期和灌浆期期叶面喷施5次,用40克实施例6所述肥料兑水60升,喷施一亩地,可增产60%。Embodiment 37: rice soaking, 40 grams of the fertilizer described in Example 4 was mixed with 1.5 liters of water; the seedling stage, the tillering stage and the filling stage were sprayed 5 times, and 40 grams of the fertilizer described in Example 6 was mixed with 60 liters of water, Spraying one mu of land can increase production by 60%.
实施例38:草莓:蘸根,40克实施例8所述肥料兑水6升;快速生长期和现蕾期叶面喷施5次,用40克实施例12所述肥料兑水40升,喷施一亩地,叶色明显加深,可增产10%。Embodiment 38: Strawberry: dipped in root, 40 grams of the fertilizer described in Example 8 was mixed with 6 liters of water; the leaves were sprayed 5 times during the rapid growth period and the budding stage, and 40 liters of water was mixed with 40 grams of the fertilizer described in Example 12, Spray one mu of land, the leaf color will be obviously deepened, and the yield can be increased by 10%.
实施例39:中药材:不同部位的中药材,使用方法不一,一般在苗期、初花期和盛花期各一次,用60克实施例15所述肥料兑水30~40升。Example 39: Chinese herbal medicines: different parts of Chinese herbal medicines are used in different ways, generally once at the seedling stage, early flowering stage and full flowering stage, with 60 grams of the fertilizer described in Example 15 mixed with 30-40 liters of water.
实施例40:苹果、梨、桃等,开花前、盛花期和果实膨大期叶面喷施6次,用40克实施例18所述肥料兑水30升,喷施一亩地,可增产5%~30%,水果更甜。Embodiment 40: apples, pears, peaches, etc., spray 6 times on the foliage before flowering, in full bloom and in the fruit expansion stage, mix 30 liters of water with 40 grams of the fertilizer described in Example 18, and spray one mu of land, which can increase production by 5 %~30%, the fruit is sweeter.
实施例41:苹果、梨、葡萄等,叶片生长期、开花前、盛花期、果实膨大期和转色期滴灌或冲施5次,用40克实施例21所述肥料兑水500升,一亩地,可增产8%~30%,水果更甜。Example 41: apples, pears, grapes, etc., drip irrigation or flushing 5 times during the leaf growth period, before flowering, full bloom period, fruit expansion period and color change period, with 40 grams of the fertilizer described in Example 21 mixed with 500 liters of water, one Acres of land can increase production by 8% to 30%, and the fruit is sweeter.
实施例42:油菜、小白菜、油麦菜、生菜等,移栽前、移栽成活后叶面喷施3次,用40克实施例25所述肥料兑水40升,喷施一亩地,可增产5%~50%,病虫害减轻。Embodiment 42: Rapeseed rape, Chinese cabbage, lettuce, lettuce, etc., before transplanting, after transplanting and surviving, foliage spraying 3 times, with 40 grams of fertilizer described in Example 25 mixed with 40 liters of water, spraying one mu of land, It can increase production by 5% to 50%, and reduce pests and diseases.
实施例43:马铃薯、大豆等:幼苗期、现蕾期和果实膨大期叶面喷施6次,用40克实施例30所述肥料兑水40升,喷施一亩地,病虫害减轻。Example 43: Potatoes, soybeans, etc.: Spray 6 times on the foliage at the seedling stage, budding stage, and fruit expansion stage, mix 40 liters of water with 40 grams of the fertilizer described in Example 30, and spray one mu of land, and the damage by diseases and insect pests is alleviated.
实施例44:本发明产品与其他水溶性肥料相互配合的增产效果如表1所示。Example 44: Table 1 shows the yield-increasing effect of the product of the present invention combined with other water-soluble fertilizers.
表1Table 1
实施例45:本发明在减少使用基肥25%的情况下,可以保持作物产量,甚至增产,结果见表2。Example 45: The present invention can maintain crop yield and even increase yield while reducing the use of basal fertilizer by 25%. The results are shown in Table 2.
表2Table 2
实施例46:取6-磷酸葡萄糖钙盐5克,果糖-1,6-二磷酸钙盐5克,葡萄糖20克,粉碎,混合均匀,即得肥料。Example 46: Take 5 grams of calcium salt of glucose 6-phosphate, 5 grams of calcium salt of fructose-1,6-diphosphate, and 20 grams of glucose, grind them, and mix them uniformly to obtain a fertilizer.
实施例47:取6-磷酸葡萄糖铁盐5克,果糖-1,6-二磷酸镁盐5克,葡萄糖20克,粉碎,混合均匀,即得肥料。Example 47: Take 5 grams of glucose-6-phosphate iron salt, 5 grams of fructose-1,6-diphosphate magnesium salt, and 20 grams of glucose, grind them, and mix them uniformly to obtain a fertilizer.
实施例48:取果糖-1,6-二磷酸锌盐90克,B族维生素3克,粉碎,混合均匀,即得肥料。Example 48: Take 90 grams of fructose-1,6-diphosphate zinc salt and 3 grams of B vitamins, pulverize them, and mix them uniformly to obtain a fertilizer.
实施例49:取果糖-1,6-二磷酸铁盐90克,B族维生素3克,粉碎,混合均匀,即得肥料。Example 49: Take 90 grams of fructose-1,6-diphosphate ferric salt and 3 grams of B vitamins, pulverize them and mix them uniformly to obtain fertilizer.
实施例50:取6-磷酸葡萄糖钙盐100克,6-磷酸果糖锌盐50克,果糖-1,6-二磷酸锌盐20克,复合氨基酸10克,粉碎,混合均匀,即得肥料。Example 50: Take 100 grams of calcium salt of glucose 6-phosphate, 50 grams of zinc salt of fructose 6-phosphate, 20 grams of zinc salt of fructose-1,6-diphosphate, and 10 grams of compound amino acids, pulverize them, and mix them uniformly to obtain fertilizer.
实施例51:取6-磷酸葡萄糖钠盐100克,6-磷酸果糖钠盐50克,果糖-1,6-二磷酸镁盐20克,复合氨基酸10克,粉碎,混合均匀,即得肥料。Example 51: Take 100 grams of glucose 6-phosphate sodium salt, 50 grams of fructose 6-phosphate sodium salt, 20 grams of fructose-1,6-diphosphate magnesium salt, and 10 grams of compound amino acids, pulverize and mix well to obtain fertilizer.
实施例52:取磷酸肌酸钙盐5克,FAD钙盐5克,葡萄糖20克,粉碎,混合均匀,即得肥料。Example 52: Take 5 grams of creatine phosphate calcium salt, 5 grams of FAD calcium salt, and 20 grams of glucose, grind them, and mix them uniformly to obtain fertilizer.
实施例47:取磷酸肌酸镁盐5克,果糖-1,6-二磷酸镁盐5克,葡萄糖20克,粉碎,混合均匀,即得肥料。Example 47: Take 5 grams of creatine phosphate magnesium salt, 5 grams of fructose-1,6-diphosphate magnesium salt, and 20 grams of glucose, grind them, and mix them uniformly to obtain a fertilizer.
实施例48:取FAD锌盐90克,B族维生素3克,粉碎,混合均匀,即得肥料。Example 48: Take 90 grams of FAD zinc salt and 3 grams of B vitamins, pulverize them, and mix them uniformly to obtain a fertilizer.
实施例49:取果糖-1,6-二磷酸铁盐90克,NADH镁盐3克,粉碎,混合均匀,即得肥料。Example 49: Take 90 grams of fructose-1,6-diphosphate ferric salt and 3 grams of NADH magnesium salt, pulverize them and mix them uniformly to obtain a fertilizer.
实施例50:取NADPH钙盐100克,6-磷酸果糖锌盐50克,果糖-1,6-二磷酸锌盐20克,复合氨基酸10克,粉碎,混合均匀,即得肥料。Example 50: Take 100 grams of NADPH calcium salt, 50 grams of fructose-6-phosphate zinc salt, 20 grams of fructose-1,6-diphosphate zinc salt, and 10 grams of compound amino acids, grind them and mix them uniformly to obtain fertilizer.
实施例51:取6-磷酸葡萄糖钠盐100克,NADPH钠盐50克,果糖-1,6-二磷酸镁盐20克,复合氨基酸10克,粉碎,混合均匀,即得肥料。Example 51: Take 100 grams of glucose-6-phosphate sodium salt, 50 grams of NADPH sodium salt, 20 grams of fructose-1,6-diphosphate magnesium salt, and 10 grams of compound amino acids, grind them and mix them uniformly to obtain a fertilizer.
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| CN201980051916.0A CN112566883A (en) | 2018-08-08 | 2019-07-30 | High-energy phosphoryl compound fertilizer and application thereof |
| PCT/CN2019/098306 WO2020029831A1 (en) | 2018-08-08 | 2019-07-30 | High-energy phosphoryl compound fertilizer and application thereof |
| ZA2021/01536A ZA202101536B (en) | 2018-08-08 | 2021-03-05 | High-energy phosphoryl compound fertilizer and application thereof |
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| ZA202101536B (en) | 2021-07-28 |
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Application publication date: 20181207 |