CN109090127A - A kind of composition pesticide containing fluorine thiophene worm sulfone and thiodicarb - Google Patents
A kind of composition pesticide containing fluorine thiophene worm sulfone and thiodicarb Download PDFInfo
- Publication number
- CN109090127A CN109090127A CN201811016007.7A CN201811016007A CN109090127A CN 109090127 A CN109090127 A CN 109090127A CN 201811016007 A CN201811016007 A CN 201811016007A CN 109090127 A CN109090127 A CN 109090127A
- Authority
- CN
- China
- Prior art keywords
- thiodicarb
- fluorine thiophene
- worm sulfone
- pyridine amide
- composition pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 title claims abstract description 113
- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 239000000575 pesticide Substances 0.000 title claims abstract description 24
- 150000003457 sulfones Chemical class 0.000 title claims description 36
- OYVABZRZDZPVQD-UHFFFAOYSA-N [F].C=1C=CSC=1 Chemical compound [F].C=1C=CSC=1 OYVABZRZDZPVQD-UHFFFAOYSA-N 0.000 title claims description 31
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 11
- 230000001069 nematicidal effect Effects 0.000 claims abstract 2
- -1 PH regulator Substances 0.000 claims description 18
- 239000000375 suspending agent Substances 0.000 claims description 18
- 239000003921 oil Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000004563 wettable powder Substances 0.000 claims description 11
- 239000000839 emulsion Substances 0.000 claims description 9
- 239000004530 micro-emulsion Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000004562 water dispersible granule Substances 0.000 claims description 8
- 239000002689 soil Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 241000255777 Lepidoptera Species 0.000 claims description 4
- 239000002552 dosage form Substances 0.000 claims description 3
- 239000002917 insecticide Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 230000008635 plant growth Effects 0.000 claims description 3
- 239000002671 adjuvant Substances 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 239000003337 fertilizer Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 239000003595 mist Substances 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 241000244206 Nematoda Species 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 13
- 230000002195 synergetic effect Effects 0.000 abstract description 11
- 241000243785 Meloidogyne javanica Species 0.000 abstract description 9
- 239000005645 nematicide Substances 0.000 abstract description 6
- 244000068988 Glycine max Species 0.000 abstract description 4
- 235000010469 Glycine max Nutrition 0.000 abstract description 4
- 240000008042 Zea mays Species 0.000 abstract description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 4
- 235000005822 corn Nutrition 0.000 abstract description 4
- 230000012010 growth Effects 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 244000299507 Gossypium hirsutum Species 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- 241000498254 Heterodera glycines Species 0.000 abstract 1
- 240000008790 Musa x paradisiaca Species 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 235000021015 bananas Nutrition 0.000 abstract 1
- 235000013399 edible fruits Nutrition 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- IBBMAWULFFBRKK-UHFFFAOYSA-N picolinamide Chemical compound NC(=O)C1=CC=CC=N1 IBBMAWULFFBRKK-UHFFFAOYSA-N 0.000 description 72
- 238000002156 mixing Methods 0.000 description 22
- 239000003814 drug Substances 0.000 description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
- 235000019198 oils Nutrition 0.000 description 12
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 description 8
- 241000244203 Caenorhabditis elegans Species 0.000 description 6
- 206010011732 Cyst Diseases 0.000 description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 208000031513 cyst Diseases 0.000 description 6
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- 230000002265 prevention Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 210000000481 breast Anatomy 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 229930192474 thiophene Natural products 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 230000012447 hatching Effects 0.000 description 4
- 102000002322 Egg Proteins Human genes 0.000 description 3
- 108010000912 Egg Proteins Proteins 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 230000002147 killing effect Effects 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 230000010534 mechanism of action Effects 0.000 description 3
- 230000003151 ovacidal effect Effects 0.000 description 3
- 210000004681 ovum Anatomy 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- XXKHDSGLCLCFSC-UHFFFAOYSA-N 2,3-diphenylphenol Chemical compound C=1C=CC=CC=1C=1C(O)=CC=CC=1C1=CC=CC=C1 XXKHDSGLCLCFSC-UHFFFAOYSA-N 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003071 parasitic effect Effects 0.000 description 2
- 230000003285 pharmacodynamic effect Effects 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241001489135 Globodera pallida Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241000243784 Meloidogyne arenaria Species 0.000 description 1
- 241000611260 Meloidogyne chitwoodi Species 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000332477 Scutellonema bradys Species 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- OIPILFWXSMYKGL-UHFFFAOYSA-N acetylcholine Chemical compound CC(=O)OCC[N+](C)(C)C OIPILFWXSMYKGL-UHFFFAOYSA-N 0.000 description 1
- 229960004373 acetylcholine Drugs 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002329 esterase inhibitor Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 231100001224 moderate toxicity Toxicity 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 230000001537 neural effect Effects 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000004783 oxidative metabolism Effects 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
- KKDONKAYVYTWGY-UHFFFAOYSA-M sodium;2-(methylamino)ethanesulfonate Chemical compound [Na+].CNCCS([O-])(=O)=O KKDONKAYVYTWGY-UHFFFAOYSA-M 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明涉及一种杀线虫组合物，所述杀线虫组合物成分包括氟噻虫砜与硫双威及常用助剂，氟噻虫砜与硫双威的重量份数比为30:1‑1:30，优选为1:10‑10:1，氟噻虫砜与硫双威以一定的比例复配后对鳞翅目类害虫及线虫有明显的的协同增效作用，适用于防治大豆爪哇根结线虫、大豆孢囊线虫、玉米根结线虫、棉花南方根结线虫等，并可广泛应用于蔬菜，香蕉，果树，药材等作物的害虫防治，本发明的农药组合物防治效果好，利于作物生长，值得推广。The invention relates to a nematocidal composition, the nematicide composition comprises fluthiazol, thiodicarb and common auxiliary agents, and the weight ratio of fluthiazol and thiodicarb is 30:1-1 :30, preferably 1:10-10:1, fluthiazol and thiodicarb compounded in a certain ratio have obvious synergistic effect on lepidopteran pests and nematodes, and are suitable for preventing and controlling soybean Java root-knot nematode, soybean cyst nematode, corn root-knot nematode, cotton incognita, etc., and can be widely used in the pest control of crops such as vegetables, bananas, fruit trees, and medicinal materials. The pesticide composition of the present invention has a good control effect and is beneficial to Crop growth is worth promoting.
Description
Technical field
The invention belongs to technical field of pesticide compounding, and in particular to be a kind of agriculture comprising fluorine thiophene worm sulfone and thiodicarb
Drug composition and its application.
Background technique
Plant nematode is important one of phytopathy original, has concealment, more host's property, intractable and easily propagates
The features such as.Its population growth is rapid, prevention and treatment is difficult, causes sternly to China's grain, vegetables, industrial crops Isoquant and economic benefit
Ghost image is rung.Its main host plants crop includes soybean, potato, cotton, corn, tomato, carrot and beet etc..Nematode is endangered at present
Evil is on the rise, and constitutes a serious threat to production estimation.The whole world every year the crop failure as caused by eelworm harm up to 14%,
Cause economic loss 80,000,000,000~1,00000000000 dollar.Crop failure caused by China is encroached on because of nematode every year is up to 12%, and list is by line
Soybean annual output caused by worm loses between 5%~80%.Parasitic nematode destroys plant root, easily causes disease fungus after infecting
Infection aggravates the infringement of bacterium, fungi and virus, destroys plant growth, reduces crop yield and quality.
The fluorine thiophene worm sulfone mechanism of action is unique, has the function of compared with Organophosphorus and carbamate pesticides class nematicide different
Mechanism, the former has irreversible killing effect to nematode, and the latter can only play temporary control.The medicament has touching to nematode
The effect of killing, activity is reduced after nematode contact, and then is benumbed, and stops feeding, infection ability decline, egg production capacity after 1 h of exposure
It can reduce, institute's spawning and hatching rate decline, the larva hatched can not survive for a long time, finally irreversible to be killed.Fluorine thiophene worm
Sulfone not only has good control efficiency to various plants parasitic nematode, also has original killing living to serious root-knot nematode is endangered
Property.Studies have shown that the medicament can effectively prevent javanese root knot nematode, north south side root-knot nematode, thorn nematode, G.pallida,
The infringement of the pests on plants root system such as Meloidogyne chitwoodi, corn lesion nematode, peanut root-knot nematode.As with interior suction
Property non-fumigating nematicide, it can also be used to prevention and treatment harm agricultural and garden crop nematode.As non-stifling property nematicide
Application is simple, and easily by soil absorption, the time that other nematicides enter soil is about 5 days, and this product only needs 12 hours.It should
Medicament cannot maintain entire Growing season to the preventive effect of nematode, but energy cover crop is until established root system.
Thiodicarb be moderate toxicity amino-acid ester insecticides, to fish, bird safety, no slow poisoning, without carcinogenic, teratogenesis,
Mutagenesis, to crop safety.There is special efficacy to lepidoptera pest, and have ovicidal action, to cotten aphid, leafhopper, thrips and mite class
In vain, it can also be used to prevent and treat coleoptera, Diptera and Hymenoptera pest.Thiodicarb is mainly stomach poison function, almost without tagging
Effect has stronger selectivity, the residual period is very short in the soil without stifling and systemic action.Its mechanism of action is neural resistance
Hinder effect, i.e., hinders activating again for transmitter in nerve fibre to lead to pest by acetylcholine esterase inhibition activity
It is poisoned to death.Can ovicidal, can also kill larva and certain adults.Ovicidal activity is high, and show three aspects: 1. medical fluid connects
Unhatched ovum is touched, the hatching of ovum can be prevented or is made is i.e. dead before larvae development to 2 ages after hatching；2. being produced in 3 days after application
Ovum cannot hatch or cannot complete children phase development；It can effectively kill when 3. going out shell after egg hatching because chewing egg membrane and just incubate
Larva.Due to introducing thioether bond in the structure of thiodicarb, to using oxidative metabolism as the resistant insect product of detoxication mechanisms
System also has higher insecticidal activity.Desinsection is rapid, but the residual period is short, can only generally maintain 45 days.
An important component of the thiodicarb as pesticide has good inhibition to make crops Lepidoptera class pest
With residual life in the soil is short, environmentally friendly；And fluorine thiophene worm sulfone is as a kind of novel nematicide, it is suitable for thiodicarb
There is the good mechanism of action with the control of nematode of crop.Therefore the present invention passes through to thiodicarb and fluorine thiophene worm sulfone mixture formula
Further investigation, discovery is by thiodicarb and fluorine thiophene worm sulfone mixture, within a certain range of mixing ratios, to crops lepidoptera pest
And the prevention and treatment of nematode has apparent synergistic function, is decreased compared to single dose using environmental pollution, and the scope of application
Wider, the raising of healthy growth and yield for crops has obvious effect, after further research, complete the present invention.
Summary of the invention
The purpose of the present invention is to provide the synergistic pesticide combinations that a kind of effective component is thiodicarb and fluorine thiophene worm sulfone
Object provides a kind of suitable mode use, safe and efficient for the prevention and treatment of crop pest and nematode.
In order to achieve the above objectives, the present invention adopts the following technical scheme: a kind of composition pesticide, it is characterised in that its work
Property ingredient include at least fluorine thiophene worm sulfone and thiodicarb, wherein the weight fraction ratio of fluorine thiophene worm sulfone and thiodicarb be 30:1-1:30, it is excellent
It is selected as 1:10-10:1.
Further, the mass percentage of composition shared by active constituent is 1%- in composition pesticide of the invention
70%, preferably 10%-35%.
Further, composition pesticide of the invention also includes other insecticides adjuvants, as dispersing agent, wetting agent, disintegrating agent,
One kind or combinations thereof object in antifreezing agent, thickener, defoaming agent, emulsifier, solvent, PH regulator, filler or water.
Further, the dosage form of composition pesticide of the invention be missible oil, wettable powder, water dispersible granules, suspending agent,
It is aqueous emulsion, microemulsion, any in dispersible oil-suspending agent.
Further, composition pesticide method of application of the invention be sprayed, pouring root, spread fertilizer over the fields, ditch spread, cave are applied, can also
Pass through the region such as soil or seed treatment etc. for being applied to plant growth.
Compared with prior art, composition pesticide of the invention has the beneficial effect that
(1) present invention is compared with single dose, and the composition is prevented and treated and handled to each class pest and nematode from multiple mechanism, one
Determine the use scope for having widened pesticide in degree, is conducive to the insecticidal properties for enhancing pesticide；
(2) two kinds of effective component synergistic effects of the present invention, reduce Pesticide use amount, reduce control cost；
(3) present invention is to crop nonhazardous, and environmentally friendly, safety increases compared with single dose.
Specific embodiment
Below in conjunction with specific preferred embodiment, the invention will be further described, but not thereby limiting the invention
Protection scope.
After the pestsides synthesis of different cultivars, it is usually expressed as three types: summation action, synergistic effect and antagonism.
But it is specially which kind of effect is unpredictable, only just can know that by largely test.Compound synergic is the important of integrated control
Means.
The composition pesticide of fluorine-containing thiophene worm sulfone and thiodicarb of the invention using fluorine thiophene worm sulfone and thiodicarb as effective component, press by the two
According to certain proportion combination, there is apparent synergistic effect to corn root-knot nematode and soy bean cyst roundworm；Rather than two kinds of drugs
Simple adduction, specifically using co-toxicity carry out indoor bioassay.
By indoor toxicity test, the co-toxicity coefficient (CTC) after two kinds of medicaments compound by a certain percentage is defined, CTC < 80 are
Antagonism, 80≤CTC≤120 are summation action, and CTC >=120 are synergistic effect, on this basis, then carry out field trial.
The The Toxicity Determination result of 1 fluorine thiophene worm sulfone of table and thiodicarb and combinations thereof to root-knot nematode (2 instar larvae)
As shown in Table 1, fluorine thiophene worm sulfone and thiodicarb to the LC50 of root-knot nematode (2 instar larvae) be respectively 4.56mg/L and
13.92mg/L.At 30: 1 to 1: 30, co-toxicity coefficient CTC is all larger than 120 for fluorine thiophene worm sulfone and thiodicarb quality proportioning, illustrates fluorine
Both thiophene worm sulfone and the thiodicarb mixture in 30: 1 to 1: 30 ranges show synergistic effect, and especially the two is total to 6: 1
Malicious coefficient is 247.28, and synergistic effect is the most obvious.
The The Toxicity Determination result of 2 fluorine thiophene worm sulfone of table and thiodicarb and combinations thereof to cyst roundworm (2 instar larvae)
As shown in Table 2, fluorine thiophene worm sulfone and thiodicarb are respectively 3.89mg/L and 10.50mg/L to the LC50 of cyst roundworm.Fluorine thiophene
At 30: 1 to 1: 30, co-toxicity coefficient CTC is all larger than 120, illustrates both fluorine thiophene worm sulfone and thiodicarb for worm sulfone and thiodicarb proportion
Mixture shows synergistic effect in 30: 1 to 1: 30 ranges, and especially the two increases in 2: 1, co-toxicity coefficient 219.78
Effect effect is the most obvious.
The present invention is elaborated below by field trial embodiment, the percentage in embodiment is weight percent
Than, but the present invention is not limited thereto.
Embodiment 1:55% trifluoro miaow pyridine amide thiodicarb wettable powder
Trifluoro miaow pyridine amide 10%, thiodicarb 45%, lignosulfonates 7%, lauryl sodium sulfate 5%, talcum powder complement to
100%, air-flow crushing is carried out after mixing, 55% trifluoro miaow pyridine amide thiodicarb wettable powder is made.
Embodiment 2:60% trifluoro miaow pyridine amide thiodicarb wettable powder
Trifluoro miaow pyridine amide 55%, thiodicarb 5%, alkyltaurate 5%, calcium dodecyl benzene sulfonate 10%, white carbon black complement to
100%, air-flow crushing is carried out after mixing, 60% trifluoro miaow pyridine amide thiodicarb wettable powder is made.
Embodiment 3:26% trifluoro miaow pyridine amide thiodicarb wettable powder
Trifluoro miaow pyridine amide 6%, thiodicarb 20%, fatty acid amide N~N-methyltaurine sodium salt 3%, Nekal BX 8%, diatomite
100% is complemented to, carries out air-flow crushing after mixing, 26% trifluoro miaow pyridine amide thiodicarb wettable powder is made.
Embodiment 4:18% trifluoro miaow pyridine amide thiodicarb water-dispersible granules
Trifluoro miaow pyridine amide 10%, thiodicarb 8%, alkyl phenol polyoxyethylene ether sulfate 10%, sodium alkyl benzene sulfonate 5%, mosanom
1%, precipitated calcium carbonate is supplied to 100%, and 18% trifluoro miaow pyridine amide thiodicarb water-dispersible granules are made in mixing granulation.
Embodiment 5:42% trifluoro miaow pyridine amide thiodicarb water dispersible granules
Trifluoro miaow pyridine amide 20%, thiodicarb 22%, polyoxyethylene polyoxypropylene block copolymer 8%, polyoxyethylene tri-styryl benzene
Based phosphates 8%, ammonium sulfate 2%, diatomite are supplied to 100%, and 42% trifluoro miaow pyridine amide thiodicarb moisture is made in mixing granulation
Dissipate property granula.
Embodiment 6:31% trifluoro miaow pyridine amide thiodicarb water dispersible granules
Trifluoro miaow pyridine amide 30%, thiodicarb 1%, alkyl phenol polyoxyethylene ether 2%, spaonin powder 3%, urea 3%, attapulgite are supplied
To 100%, 31% trifluoro miaow pyridine amide thiodicarb water-dispersible granules made from mixing granulation.
Embodiment 7:20% trifluoro miaow pyridine amide thiodicarb suspending agent
Trifluoro miaow pyridine amide 2%, thiodicarb 18%, calcium dodecyl benzene sulfonate 4%, fatty alcohol polyoxyethylene ether 6%, methylol are fine
Dimension element 1%, urea 1%, silicone 0.5%, water are supplied to 100%, and 20% trifluoro miaow pyridine amide thiodicarb suspending agent is made after mixing.
Embodiment 8:8% trifluoro miaow pyridine amide thiodicarb suspending agent
Trifluoro miaow pyridine amide 4%, sodium alkyl benzene sulfonate 8%, lignosulfonates 2%, xanthan gum 1%, glycerol 2%, has thiodicarb 4%
Machine silicone oil 1%, water are supplied to 100%, and 8% trifluoro miaow pyridine amide thiodicarb suspending agent is made after mixing.
Embodiment 9:30% trifluoro miaow pyridine amide thiodicarb suspending agent
Trifluoro miaow pyridine amide 10%, thiodicarb 20%, polyoxyethylene tristyrene phenyl phosphate 10%, alkyltaurate 10%,
Gum arabic 0.5%, isopropanol 2%, the fatty alcohols of C8~10 compound 0.1%, water are supplied to 100%, and 30% is made after mixing
Trifluoro miaow pyridine amide thiodicarb suspending agent.
Embodiment 10:10% trifluoro miaow pyridine amide thiodicarb aqueous emulsion
Trifluoro miaow pyridine amide 1%, thiodicarb 9%, alkylbenzene naphthalene sulfonate 8%, aluminium-magnesium silicate 0.1%, propylene glycol 1%, polyoxyethylene are sweet
Oily ether 0.5%, solvent naphtha 5%, water are supplied to 100%, and 10% trifluoro miaow pyridine amide thiodicarb aqueous emulsion is made after mixing.
Embodiment 11:28% trifluoro miaow pyridine amide thiodicarb aqueous emulsion
Trifluoro miaow pyridine amide 8%, thiodicarb 20%, alkyl phenol polyoxyethylene ether phosphate 7%, hydroxymethyl cellulose 0.5%, poly- second
Glycol 2%, silicone oil 1%, ethyl acetate 10%, water are supplied to 100%, 28% trifluoro miaow pyridine amide thiodicarb water obtained after mixing
Floating agent.
Embodiment 12:50% trifluoro miaow pyridine amide thiodicarb aqueous emulsion
Trifluoro miaow pyridine amide 15%, thiodicarb 35%, diphenyl phenol polyethenoxy polyethenoxy ether 5%, xanthan gum 0.8%, propylene glycol
2%, the fatty alcohols of C8~10 compound 0.1%, ethyl acetate 10%, water are supplied to 100%, and 50% trifluoro miaow pyridine acyl is made after mixing
Amine thiodicarb aqueous emulsion.
Embodiment 13:21% trifluoro miaow pyridine amide thiodicarb microemulsion
Trifluoro miaow pyridine amide 20%, thiodicarb 1%, solvent naphtha 10%, ethylene glycol 3%, styrenated phenol polyoxyethylene ether 3%, agriculture breast
500#2%, water are supplied to 100%, and 21% trifluoro miaow pyridine amide thiodicarb microemulsion is made after mixing.
Embodiment 14:50% trifluoro miaow pyridine amide thiodicarb microemulsion
Trifluoro miaow pyridine amide 35%, thiodicarb 15%, n,N-Dimethylformamide 15%, propylene glycol 3%, alkyl phenol polyoxyethylene ether first
Aldehyde condensate 9%, water are supplied to 100%, the 50% trifluoro miaow pyridine amide thiodicarb microemulsion made after mixing.
Embodiment 15:3% trifluoro miaow pyridine amide thiodicarb microemulsion
Trifluoro miaow pyridine amide 1%, thiodicarb 2%, solvent naphtha 8%, glycerol 2%, agriculture breast 500# 2%, castor oil ethylene oxide adduct
5%, water is supplied to 100%, the 3% trifluoro miaow pyridine amide thiodicarb microemulsion made after mixing.
Oil-suspending agent can be dispersed in embodiment 16:5% trifluoro miaow pyridine amide thiodicarb
Trifluoro miaow pyridine amide 4%, thiodicarb 1%, diphenyl phenol polyethenoxy polyformaldehyde condensation product 12%, alkyl phenol polyoxyethylene ether
Sulfate 7%, gum arabic 0.1%, polyoxyethylene glycerol ether 0.2%, methyl oleate are supplied to 100%, 5% 3 made after mixing
Oil-suspending agent can be dispersed in fluorine miaow pyridine amide thiodicarb.
Oil-suspending agent can be dispersed in embodiment 17:16% trifluoro miaow pyridine amide thiodicarb
Trifluoro miaow pyridine amide 1%, thiodicarb 15%, castor oil ethylene oxide adduct 7%, polyoxyethylene polyoxypropylene block copolymerization
Object 4%, aluminium-magnesium silicate 1%, the saturated fat acids of C10~20 compound 0.5%, vegetable oil are supplied to 100%, 16% made after mixing
Oil-suspending agent can be dispersed in trifluoro miaow pyridine amide thiodicarb.
Oil-suspending agent can be dispersed in embodiment 18:31% trifluoro miaow pyridine amide thiodicarb
Trifluoro miaow pyridine amide 30%, thiodicarb 1%, alkylbenzene naphthalene sulfonate 10%, fatty alcohol polyoxyethylene ether 10%, polyethylene pyrrole
Pyrrolidone 0.6%, organic silicone oil 0.5%, white oil are supplied to 100%, and the 31% trifluoro miaow pyridine amide thiodicarb made after mixing can divide
Dissipate oil-suspending agent.
Embodiment 19:40% trifluoro miaow pyridine amide thiodicarb missible oil
Trifluoro miaow pyridine amide 30%, thiodicarb 10%, NP-10 8%, agriculture breast 500#1%, ethyl acetate are supplied to 100%, are made after mixing
40% trifluoro miaow pyridine amide thiodicarb missible oil.
Embodiment 20:19% trifluoro miaow pyridine amide thiodicarb missible oil
Trifluoro miaow pyridine amide 18%, thiodicarb 1%, polyvinyl alcohol 6%, agriculture breast 500#3%, solvent naphtha are supplied to 100%, are made after mixing
18% trifluoro miaow pyridine amide thiodicarb missible oil.
Embodiment 21:33% trifluoro miaow pyridine amide thiodicarb missible oil
Trifluoro miaow pyridine amide 30%, thiodicarb 3%, Tween 80 12%, agriculture breast 500#2%, ethyl acetate are supplied to 100%, after mixing
33% trifluoro miaow pyridine amide thiodicarb missible oil of system.
Test examples 1:
The pharmacodynamic test result of 3 fluorine thiophene worm sulfone of table, thiodicarb and combinations thereof prevention and treatment root-knot nematode
| Treatment agent | Effective component dosage (kg/hm2) | Prevent within 7 days after medicine It imitates (%) | Prevent within 14 days after medicine It imitates (%) | 28 days preventive effects after medicine (%) |
| 55% trifluoro miaow pyridine amide thiodicarb Wettable powder | 2 | 80.56 | 89.71 | 92.51 |
| 18% trifluoro miaow pyridine amide thiodicarb Water-dispersible granules | 2 | 84.34 | 91.58 | 91.08 |
| 20% trifluoro miaow pyridine amide thiodicarb Suspending agent | 2 | 82.28 | 91.53 | 97.32 |
| 10% trifluoro miaow pyridine amide thiodicarb Aqueous emulsion | 2 | 83.39 | 90.19 | 95.44 |
| 40% trifluoro miaow pyridine amide thiodicarb Missible oil | 2 | 88.61 | 89.13 | 93.32 |
| 480g/L fluorine thiophene worm sulfone missible oil | 2 | 68.03 | 71.88 | 73.58 |
| 75% thiodicarb wettable powder | 2 | 59.99 | 68.65 | 69.35 |
It as can be seen from Table 3, in effective component dosage is 2kg/ hm after fluorine thiophene worm sulfone and thiodicarb compounding2When, prevent and treat root
The effect of tie lines worm is above fluorine thiophene worm sulfone and thiodicarb single dose, after fluorine thiophene worm sulfone and thiodicarb complex composition its medicine 7 days it is anti-
Control effect 83.84%, 14 days control efficiency average value 90.43%, 28 days control efficiency average value 93.93%.Illustrate group of the invention
Downy mildew can be prevented and treated well by closing object, reduced dosage, reduced cost.To Target crops without bad shadow in test scope of medication
It rings.
The pharmacodynamic test result of 4 fluorine thiophene worm sulfone of table, thiodicarb and combinations thereof prevention and treatment cyst roundworm
| Treatment agent | Effective component dosage (kg/ hm2) | Prevent within 7 days after medicine It imitates (%) | Prevent within 14 days after medicine It imitates (%) | Prevent within 28 days after medicine It imitates (%) |
| 8% trifluoro miaow pyridine amide thiodicarb is outstanding Floating agent | 4 | 77.66 | 89.72 | 95.35 |
| 28% trifluoro miaow pyridine amide thiodicarb water Emulsion | 4 | 77.42 | 88.58 | 93.78 |
| 3% trifluoro miaow pyridine amide thiodicarb is micro- Emulsion | 4 | 80.55 | 90.34 | 95.94 |
| 16% trifluoro miaow pyridine amide thiodicarb can Disperse oil-suspending agent | 4 | 81.53 | 87.58 | 94.62 |
| 33% trifluoro miaow pyridine amide thiodicarb cream Oil | 4 | 82.72 | 90.44 | 95.12 |
| 480g/L fluorine thiophene worm sulfone missible oil | 4 | 70.14 | 80.53 | 88.19 |
| 75% thiodicarb wettable powder | 4 | 50.48 | 67.79 | 70.18 |
As can be seen from Table 4, different dosage forms are 4kg/hm in effective component dosage after fluorine thiophene worm sulfone and thiodicarb compound2
When, the effect for preventing and treating cyst roundworm is above fluorine thiophene worm sulfone and thiodicarb single dose.Fluorine thiophene worm sulfone and thiodicarb complex composition its
7 days control efficiency 79.98% after medicine, 14 days control efficiency average value 89.33%, 28 days control efficiency average value 94.96%.Explanation
Composition of the invention can prevent and treat cyst roundworm well, reduce dosage, reduce cost.To target in test scope of medication
Crop has no adverse effects.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation
Example.All technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It is noted that for the art
Those of ordinary skill for, improvements and modifications without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (7)
1. a kind of composition pesticide, which is characterized in that its active constituent includes at least fluorine thiophene worm sulfone and thiodicarb.
2. a kind of composition pesticide containing fluorine thiophene worm sulfone and thiodicarb according to claim 1, it is characterised in that: fluorine thiophene
The weight fraction ratio of worm sulfone and thiodicarb is 30:1-1:30.
3. a kind of composition pesticide containing fluorine thiophene worm sulfone and thiodicarb according to claim 1, it is characterised in that: fluorine thiophene
The parts by weight of worm sulfone and thiodicarb are preferably than being 1:10-10:1.
4. any one of -3 requiring the composition pesticide according to claim 1, which is characterized in that the nematicidal composition
In also include other insecticides adjuvants, such as kill, as dispersing agent, wetting agent, disintegrating agent, antifreezing agent, thickener, defoaming agent, emulsifier,
One kind or combinations thereof object in solvent, PH regulator, filler or water.
5. any one of -3 requiring the composition pesticide according to claim 1, which is characterized in that its dosage form be missible oil,
It is wettable powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, any in dispersible oil-suspending agent.
6. any one of -3 requiring the composition pesticide according to claim 1, which is characterized in that its method of application is spray
Mist, pouring root, spread fertilizer over the fields, ditch spread, cave are applied, can also be by the region such as soil or seed treatment etc. that are applied to plant growth.
7. any one of -6 requiring the Recompounded pesticide for preventing and treating crops Lepidoptera class pest and line according to claim 1
The purposes of worm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811016007.7A CN109090127A (en) | 2018-09-01 | 2018-09-01 | A kind of composition pesticide containing fluorine thiophene worm sulfone and thiodicarb |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811016007.7A CN109090127A (en) | 2018-09-01 | 2018-09-01 | A kind of composition pesticide containing fluorine thiophene worm sulfone and thiodicarb |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109090127A true CN109090127A (en) | 2018-12-28 |
Family
ID=64864759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811016007.7A Pending CN109090127A (en) | 2018-09-01 | 2018-09-01 | A kind of composition pesticide containing fluorine thiophene worm sulfone and thiodicarb |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109090127A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1812714A (en) * | 2003-05-02 | 2006-08-02 | 拜尔农作物科学股份公司 | Combinations of active substances based on trifluorobutenyl compounds and exhibiting nematicidal and insecticidal properties |
-
2018
- 2018-09-01 CN CN201811016007.7A patent/CN109090127A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1812714A (en) * | 2003-05-02 | 2006-08-02 | 拜尔农作物科学股份公司 | Combinations of active substances based on trifluorobutenyl compounds and exhibiting nematicidal and insecticidal properties |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105165844B (en) | A nematocidal composition containing fluthiazol | |
| CN101554170A (en) | Chlorantraniliprole and emamectin benzoate insecticidal composition | |
| CN105941451A (en) | Insecticide composition containing chromafenozide and neonicotinoid | |
| CN102805088A (en) | Insecticidal composition as well as preparation and application thereof | |
| CN101180970A (en) | Hexaflumuron carbosulfan insecticidal composition | |
| CN101836643B (en) | Pesticide preparation for controlling vegetable pests of diamondback moth and the like | |
| CN102379308A (en) | Mixed insecticidal composition containing clothianidin and application of mixed insecticidal composition | |
| CN101406195B (en) | Composition containing ethiprole and avermectin with synergistic disinsection function | |
| CN109221206A (en) | A kind of composition pesticide containing Tioxazafen and thiodicarb | |
| CN108208000A (en) | A kind of nematicidal agent composition containing imicyafos | |
| CN103947646A (en) | Insecticidal composition | |
| CN102657216A (en) | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler | |
| CN102342284A (en) | Sterilization disease-resistant composition and suspension seed coating agent thereof | |
| CN101946795A (en) | Thiamethoxam- and phoxim-containing insecticidal composition | |
| CN101790992A (en) | Disinsection composite containing clothianidin and phoxim | |
| CN109090127A (en) | A kind of composition pesticide containing fluorine thiophene worm sulfone and thiodicarb | |
| CN101433215B (en) | A kind of insecticide main agent and insecticide compounded by metarhizine and beta-cypermethrin | |
| CN109197880A (en) | A kind of composition pesticide containing trifluoro miaow pyridine amide and thiodicarb | |
| CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
| CN107996598A (en) | A kind of nematicidal composition for including iprodione | |
| CN106070260A (en) | A kind of containing avilamycin with the composition pesticide of CGA-173506 | |
| CN103371154B (en) | A pesticide composition containing fluorine-containing sulfonamide and biological sources | |
| CN1918994A (en) | Pesticides composition comprising methylamino avermectin benzoate and fipronil and uses thereof | |
| CN101897340B (en) | Disinfestation composite containing thiacloprid and carbosulfan | |
| CN100356851C (en) | Fructus cnidii thuricin complex insecticide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181228 |
|
| WD01 | Invention patent application deemed withdrawn after publication |