CN109322040A - A kind of graphene radiation resistant fiber fabric - Google Patents
A kind of graphene radiation resistant fiber fabric Download PDFInfo
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- CN109322040A CN109322040A CN201811318857.2A CN201811318857A CN109322040A CN 109322040 A CN109322040 A CN 109322040A CN 201811318857 A CN201811318857 A CN 201811318857A CN 109322040 A CN109322040 A CN 109322040A
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- 239000000835 fiber Substances 0.000 title claims abstract description 45
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 29
- 239000004744 fabric Substances 0.000 title claims abstract description 22
- 230000005855 radiation Effects 0.000 title claims abstract description 18
- 239000002134 carbon nanofiber Substances 0.000 claims abstract description 20
- 229920000767 polyaniline Polymers 0.000 claims abstract description 20
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000126 substance Substances 0.000 claims abstract description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 4
- 238000009987 spinning Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005030 aluminium foil Substances 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 2
- 238000010041 electrostatic spinning Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000012286 potassium permanganate Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000008859 change Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 206010028980 Neoplasm Diseases 0.000 description 2
- -1 alkenyl carbon nano-fiber Chemical compound 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 201000011510 cancer Diseases 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 230000005672 electromagnetic field Effects 0.000 description 2
- 230000005670 electromagnetic radiation Effects 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 206010000234 Abortion spontaneous Diseases 0.000 description 1
- 208000000044 Amnesia Diseases 0.000 description 1
- 208000031091 Amnestic disease Diseases 0.000 description 1
- 208000012639 Balance disease Diseases 0.000 description 1
- 201000004569 Blindness Diseases 0.000 description 1
- 208000003174 Brain Neoplasms Diseases 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- 208000002177 Cataract Diseases 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 208000007443 Neurasthenia Diseases 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 206010047571 Visual impairment Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000006986 amnesia Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000004596 appetite loss Effects 0.000 description 1
- 206010003549 asthenia Diseases 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- VNWKTOKETHGBQD-YPZZEJLDSA-N carbane Chemical compound [10CH4] VNWKTOKETHGBQD-YPZZEJLDSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000000887 face Anatomy 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 125000000879 imine group Chemical group 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 235000021266 loss of appetite Nutrition 0.000 description 1
- 208000019017 loss of appetite Diseases 0.000 description 1
- 210000002751 lymph Anatomy 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000005906 menstruation Effects 0.000 description 1
- 208000015994 miscarriage Diseases 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 208000000995 spontaneous abortion Diseases 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 208000029257 vision disease Diseases 0.000 description 1
- 230000004393 visual impairment Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0035—Protective fabrics
- D03D1/0058—Electromagnetic radiation resistant
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/12—Carbon; Pitch
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Artificial Filaments (AREA)
- Inorganic Fibers (AREA)
Abstract
The invention discloses a kind of radiation resistant fiber fabrics, the polyaniline fiber of its graphene-based carbon nano-fiber and 5-10% containing 15-30% by volume, the graphene-based carbon nano-fiber, polyaniline fiber and plant fiber or chemical fibre twill is blended obtains the radiation-proof fabric fiber.Radiation resistant fiber fabric of the present invention realizes comfortable and easy to wear and shielding property balance, and simple and easy in fabrication processes.
Description
Technical field
The invention belongs to textile material technical field more particularly to a kind of radiation resistant fiber fabrics.
Background technique
Human body is constantly in certain energy electromagnetic wave radiation environment, when its frequency is more than 105Hz or more just to people
Body is harmful.The output power of wave electromagnetic radiation source is bigger, and radiation intensity is bigger, and wavelength is shorter, and frequency is higher, and distance is closer, connects
Touch the time it is longer, environment temperature is higher, and humidity is bigger, and air does not circulate, then environmental pollution degree is bigger, and women and
Children are more serious by endangering.Electromagnetic wave can upset the natural physiological law of human body, lead to organism balance disorder, cause headache, head
The neurasthenia symptoms such as dizzy, insomnia, amnesia；Make one out of strength, loss of appetite, irritable；Models of Human Thermal Regulation can also be made to lose
It adjusts, causes increased heart rate, blood pressure are raised and lowered, have difficulty in breathing, oligoleukocythemia；Generation to cardiovascular disease and deteriorate
Impetus.Furthermore electromagnetic wave can cause visual impairment.When intensity is the electromagnetic wave irradiation eyes of 100mw/cm2, can make
Oedema occurs for crystal, can develop into cataract, result even in blindness.When the electromagnetic wave that intensity is 5mw/cm2-10mw/cm2 shines
When penetrating human body, though the dermal sensation of people is unobvious, fertility and heredity may be influenced.Women is under Electromagnetic Field, menstruation week
Phase substantially change, and can cause pregnant woman's miscarriage and gene defect, the children being chronically under the action of strong electromagnetic wave, cancer
Disease incidence is 2~5 times higher than the children under low electromagnetic wave, and electromagnetic wave is also one of the inducement of leukaemia, lymph cancer, brain tumor.
Anti-electromagnetic radiation is to inhibit electromagnetic interference using the methods of electromagnetic shielding, usually utilizes conductive or magnetic conductive material
By electromagnetic radiation be limited in it is a certain as defined in range, be divided into electric field shielding, magnetic field shielding, electromagnetic-field-shielded by its principle.No matter
Which kind of shielding is essentially all research electromagnetic field the problem of how various specific local spaces distribute.It is wanted in practical application
Different screen methods is selected according to the difference of field source.
Exposure suit is exactly generally to use specific fabric using electromagnetic shielding and clothes made of ELECTROMAGNETIC REFLECTION principle
Or coating is realized.But in its technological means used, there are chemical contamination or metallic pollution, some radiation-proof effects for some
Generally.
Summary of the invention
It is an object of the invention to propose a kind of radiation resistant fiber fabric, enable to comfortable and easy to wear and shielding property
Balance, and it is simple and easy in fabrication processes.
To achieve this purpose, the present invention adopts the following technical scheme:
A kind of graphene radiation resistant fiber fabric, by volume graphene-based carbon nano-fiber and 5- containing 15-35%
10% polyaniline fiber, the graphene-based carbon nano-fiber, polyaniline fiber and plant fiber or chemical fibre twill are mixed
Spinning obtains the radiation-proof fabric fiber.
Preferably, in the radiation resistant fiber fabric, the content of graphene-based carbon nano-fiber is 20-30%.Work as graphite
When alkenyl carbon nano-fiber content is within the scope of this, snugness of fit and shielding property balance the most.
Preferably, the preparation method of the graphene-based carbon nano-fiber, comprising:
(1) by the crystalline flake graphite of 2-5 parts by weight, the concentrated sulfuric acid of 300-500 parts by weight and the phosphoric acid mixing of 30-60 parts by weight are equal
It is even, it is slowly added to the potassium permanganate of 15-20 parts by weight, is stirred 9-18 hours at 45-55 DEG C；
(2) at 0-5 DEG C, the deionized water of 300-500 parts by weight and the 10- of 20-50 parts by weight are added into mixture
The hydrogen peroxide of 30wt% concentration, and stir 5-10 minutes；
(3) it separates and successively uses deionized water, the hydrochloric acid of 10-30wt% concentration and dehydrated alcohol washed product, be dried in vacuo
To graphene oxide；
(4) graphene oxide of 0.01-0.1 parts by weight is added in the n,N-Dimethylformamide of 5-20 parts by weight, is surpassed
Sound, which is dispersed to, to be completely dispersed；
(5) while agitating, the polyacrylonitrile of 0.5-1.5 parts by weight is added, is heated to 40-50 DEG C and continues to stir, until
Polyacrylonitrile is completely dissolved, and obtains mixed liquor；
(6) by the mixed liquor electrostatic spinning, using aluminium foil as receiving screen, spinning film is obtained；
(7) it pre-oxidizes at 250-300 DEG C in the strong film-air, is then carbonized at 750-850 DEG C in protective atmosphere
30-120 minutes, obtain the graphene-based carbon nano-fiber.
The graphene-based carbon nanomaterial that the present invention uses, easily disperses and reduces the stacking of lamella, be conducive to function
The removing of group at high temperature, so that the conductivity and specific surface area of nanofiber are improved.
Polyaniline, one kind of high-molecular compound have special electricity, optical property, can have conduction after doped
Property and chemical property.After centainly handling, various equipment and material with specific function can be made, such as can be used as biology or
Urea enzyme sensor, electronic field emission source, the more traditional lithium electrode material of chemical sensor have more excellent in charge and discharge process
Different reversible electrode material, selective membrane material, antistatic and electromagnetic shielding material, conductive fiber, anti-corrosion material, etc.
Deng.Polyaniline is because its raw material having is easy to get, synthesis technology is simple, chemistry and environmental stability good the features such as due to have obtained extensively
Research and application.
The electroactive P electron conjugated structure in strand of polyaniline: with the expansion of P electron system in strand, P
Bonding state and P* antibonding state are respectively formed valence band and conduction band, this non-localized P electron conjugated structure is doped formed p-type and
N-type conductive state.The mechanism of doping effect of cation vacancy is generated under oxidant effect different from other conducting polymers, polyaniline
Number of electrons does not change during doping, but the Bronsted acid by adulterating decomposes and generates H+ and to anion (such as Cl-, sulphur
Acid group, phosphate radical etc.) enter main chain, extremely son and dipole delocalization are formed in conjunction with N atom in amine and imine group to entire point
In the P key of subchain, to make polyaniline that higher electric conductivity be presented.This unique mechanism of doping effect make polyaniline doping and
Dedoping completely reversibility, doping level are influenced by factors such as pH value and current potentials, and show as the corresponding change of appearance color, polyphenyl
Therefore amine also has electro-chemical activity and electrochromic property.
Above-mentioned characteristic based on polyaniline, the present invention are fine using polyaniline fiber and graphene-based carbon nano-fiber and plant
Twill is blended together for dimension/chemical fiber, solves the technical problem that graphene-based carbon nano-fiber faces when blended.
Radiation resistant fiber fabric of the present invention realizes comfortable and easy to wear and shielding property balance, and is weaving
It is simple and easy in the process.
Below with reference to embodiment, the invention will be further described.
Specific embodiment
The technical scheme of the invention is further explained by means of specific implementation.
Embodiment 1
A kind of radiation resistant fiber fabric, it is fine containing 15% graphene-based carbon nano-fiber and 5% polyaniline by volume
Dimension, the graphene-based carbon nano-fiber, polyaniline fiber and plant fiber or chemical fibre twill is blended obtains the anti-spoke
Penetrate fabric fibre.
Embodiment 2
A kind of radiation resistant fiber fabric, it is fine containing 30% graphene-based carbon nano-fiber and 10% polyaniline by volume
Dimension, the graphene-based carbon nano-fiber, polyaniline fiber and plant fiber or chemical fibre twill is blended obtains the anti-spoke
Penetrate fabric fibre.
Embodiment 3
A kind of radiation resistant fiber fabric, it is fine containing 25% graphene-based carbon nano-fiber and 8% polyaniline by volume
Dimension, the graphene-based carbon nano-fiber, polyaniline fiber and plant fiber or chemical fibre twill is blended obtains the anti-spoke
Penetrate fabric fibre.
Radiation resistant fiber fabric of the present invention realizes comfortable and easy to wear and shielding property balance, and is weaving
It is simple and easy in the process.
The above described is only a preferred embodiment of the present invention, be not intended to limit the present invention in any form, though
So the present invention has been disclosed as a preferred embodiment, and however, it is not intended to limit the invention, any technology people for being familiar with this profession
Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification
It is right according to the technical essence of the invention for the equivalent embodiment of equivalent variations, but without departing from the technical solutions of the present invention
Any simple modification, equivalent change and modification made by above embodiments, all of which are still within the scope of the technical scheme of the invention.
Claims (2)
1. a kind of graphene radiation resistant fiber fabric, graphene-based carbon nano-fiber and 5- containing 15-30% by volume
10% polyaniline fiber, the graphene-based carbon nano-fiber, polyaniline fiber and plant fiber or chemical fibre twill are mixed
Spinning obtains the radiation-proof fabric fiber.
2. graphene radiation resistant fiber fabric as described in claim 1, which is characterized in that the graphene-based carbon nano-fiber
Preparation method, comprising:
(1) by the crystalline flake graphite of 2-5 parts by weight, the concentrated sulfuric acid of 300-500 parts by weight and the phosphoric acid mixing of 30-60 parts by weight are equal
It is even, it is slowly added to the potassium permanganate of 15-20 parts by weight, is stirred 9-18 hours at 45-55 DEG C；
(2) at 0-5 DEG C, the deionized water of 300-500 parts by weight and the 10- of 20-50 parts by weight are added into mixture
The hydrogen peroxide of 30wt% concentration, and stir 5-10 minutes；
(3) it separates and successively uses deionized water, the hydrochloric acid of 10-30wt% concentration and dehydrated alcohol washed product, be dried in vacuo
To graphene oxide；
(4) graphene oxide of 0.01-0.1 parts by weight is added in the n,N-Dimethylformamide of 5-20 parts by weight, is surpassed
Sound, which is dispersed to, to be completely dispersed；
(5) while agitating, the polyacrylonitrile of 0.5-1.5 parts by weight is added, is heated to 40-50 DEG C and continues to stir, until
Polyacrylonitrile is completely dissolved, and obtains mixed liquor；
(6) by the mixed liquor electrostatic spinning, using aluminium foil as receiving screen, spinning film is obtained；
(7) it pre-oxidizes at 250-300 DEG C in the strong film-air, is then carbonized at 750-850 DEG C in protective atmosphere
30-120 minutes, obtain the graphene-based carbon nano-fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811318857.2A CN109322040A (en) | 2018-11-07 | 2018-11-07 | A kind of graphene radiation resistant fiber fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811318857.2A CN109322040A (en) | 2018-11-07 | 2018-11-07 | A kind of graphene radiation resistant fiber fabric |
Publications (1)
| Publication Number | Publication Date |
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| CN109322040A true CN109322040A (en) | 2019-02-12 |
Family
ID=65260958
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| CN201811318857.2A Withdrawn CN109322040A (en) | 2018-11-07 | 2018-11-07 | A kind of graphene radiation resistant fiber fabric |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114575017A (en) * | 2022-03-23 | 2022-06-03 | 陈隆梅 | Radiation-proof breathable fabric and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120077020A1 (en) * | 2009-05-26 | 2012-03-29 | Kazuo Muramatsu | Carbon material and method for producing same |
| CN106702568A (en) * | 2016-11-17 | 2017-05-24 | 无锡市长安曙光手套厂 | Graphene anti-radiation fiber fabric |
| CN108589025A (en) * | 2018-04-23 | 2018-09-28 | 中国石油大学(华东) | A kind of preparation method of graphene-carbon composite nano-fiber |
-
2018
- 2018-11-07 CN CN201811318857.2A patent/CN109322040A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120077020A1 (en) * | 2009-05-26 | 2012-03-29 | Kazuo Muramatsu | Carbon material and method for producing same |
| CN106702568A (en) * | 2016-11-17 | 2017-05-24 | 无锡市长安曙光手套厂 | Graphene anti-radiation fiber fabric |
| CN108589025A (en) * | 2018-04-23 | 2018-09-28 | 中国石油大学(华东) | A kind of preparation method of graphene-carbon composite nano-fiber |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114575017A (en) * | 2022-03-23 | 2022-06-03 | 陈隆梅 | Radiation-proof breathable fabric and preparation method thereof |
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Application publication date: 20190212 |