CN109504166A - A kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink and preparation method thereof - Google Patents
A kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink and preparation method thereof Download PDFInfo
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- CN109504166A CN109504166A CN201811638236.2A CN201811638236A CN109504166A CN 109504166 A CN109504166 A CN 109504166A CN 201811638236 A CN201811638236 A CN 201811638236A CN 109504166 A CN109504166 A CN 109504166A
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- Prior art keywords
- pearly
- parts
- solidified
- cigarette
- ultraviolet ray
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000010931 gold Substances 0.000 title claims abstract description 45
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 45
- 230000005855 radiation Effects 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000000975 dye Substances 0.000 claims abstract description 76
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000000843 powder Substances 0.000 claims abstract description 56
- -1 benzene ketone Chemical class 0.000 claims abstract description 48
- 239000000178 monomer Substances 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 25
- 239000003112 inhibitor Substances 0.000 claims abstract description 25
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 23
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 239000010445 mica Substances 0.000 claims abstract description 13
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 13
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical group [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 49
- 239000000203 mixture Substances 0.000 claims description 38
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- 238000006243 chemical reaction Methods 0.000 claims description 33
- 239000002904 solvent Substances 0.000 claims description 30
- NQRYJNQNLNOLGT-UHFFFAOYSA-N tetrahydropyridine hydrochloride Natural products C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 28
- QPQKUYVSJWQSDY-UHFFFAOYSA-N 4-phenyldiazenylaniline Chemical compound C1=CC(N)=CC=C1N=NC1=CC=CC=C1 QPQKUYVSJWQSDY-UHFFFAOYSA-N 0.000 claims description 26
- 229910021485 fumed silica Inorganic materials 0.000 claims description 20
- 239000000126 substance Substances 0.000 claims description 20
- 238000005086 pumping Methods 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000007689 inspection Methods 0.000 claims description 2
- 238000012797 qualification Methods 0.000 claims description 2
- 238000007639 printing Methods 0.000 abstract description 11
- 229920005749 polyurethane resin Polymers 0.000 description 27
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 27
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 20
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 18
- JMWGZSWSTCGVLX-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;2-methylprop-2-enoic acid Chemical class CC(=C)C(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O.CCC(CO)(CO)CO JMWGZSWSTCGVLX-UHFFFAOYSA-N 0.000 description 17
- 239000004408 titanium dioxide Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- 239000001294 propane Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- AJAZMOFONMJGNP-WMZOPIPTSA-N n-[(2s)-4-methyl-1-oxo-1-[[(2s)-3-oxo-4-(pyridin-2-ylsulfonylamino)butan-2-yl]amino]pentan-2-yl]-1-benzofuran-2-carboxamide Chemical compound O=C([C@H](C)NC(=O)[C@@H](NC(=O)C=1OC2=CC=CC=C2C=1)CC(C)C)CNS(=O)(=O)C1=CC=CC=N1 AJAZMOFONMJGNP-WMZOPIPTSA-N 0.000 description 6
- 201000007100 Pharyngitis Diseases 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 241000208125 Nicotiana Species 0.000 description 3
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical group [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 229910002012 Aerosil® Inorganic materials 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910017518 Cu Zn Inorganic materials 0.000 description 2
- 229910017752 Cu-Zn Inorganic materials 0.000 description 2
- 229910017943 Cu—Zn Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- LLSKXGRDUPMXLC-UHFFFAOYSA-N 1-phenylpiperidine Chemical class C1CCCCN1C1=CC=CC=C1 LLSKXGRDUPMXLC-UHFFFAOYSA-N 0.000 description 1
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- ZPUCINDJVBIVPJ-LJISPDSOSA-N cocaine Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229910001254 electrum Inorganic materials 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010940 green gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- DOTMOQHOJINYBL-UHFFFAOYSA-N molecular nitrogen;molecular oxygen Chemical compound N#N.O=O DOTMOQHOJINYBL-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 229910001112 rose gold Inorganic materials 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink, it in parts by weight include following raw material: monomer: 25-35 parts, resin: 35-45 parts, pearl powder: 15-30 parts, dyestuff: 2.5-3.5 parts, photoinitiator: 4.5-5.5 parts, polymerization inhibitor: 0.8-1.3 parts, thixotropic agent: 0.4-0.6 parts, defoaming agent: 0.2-0.4 parts, levelling agent: 0.15-0.3 parts；The pearl powder is the powder that mica sheet and titanium dioxide form；The photoinitiator is xenyl-ethylo benzene ketone.The present invention also provides a kind of preparation methods of above-mentioned pearly-lustre gold ink.Not only environment friendly and pollution-free with the gold ink of pearly-lustre obtained by technical solution of the present invention, ink stability is good, long shelf-life, and strong covering power after printing.
Description
Technical field
The present invention relates to printing technical field of ink more particularly to a kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink and
Preparation method.
Background technique
For metallic ink because its gloss is dazzling, the metal-like presented on printed matter is unusual, is constantly applied in recent years
Onto cigarette-brand packaging product, so that these products are more unique on the market, more pleasing.Pearly-lustre gold is used for solvent-based ink at present
Or water-based ink is transferred on paper by intaglio printing and flexible version printing.Due to " HJ 371-2018 environmental labelling product skill
Art requires gravure ink and flexo ink " it is come into effect on October 1st, 2018, VOCs content is limited to 5% hereinafter, since then
Solvent type pearly-lustre Jin Moyin is unsatisfactory for environmental requirement and starts to be eliminated.And water-soluble pearlescent ink is because practical application is few, generally speaking not
It is very mature.It is accordingly used in the solidified by ultraviolet ray radiation pearly-lustre Jin Moyin of silk-screen printing and belongs to environment-friendly ink without solvent, it will be at
For the Novel tobacco printing ink with bright prospects.
One, technical problem to be solved:
The safety and sanitation index of solidified by ultraviolet ray radiation pearly-lustre gold ink；
The stability of solidified by ultraviolet ray radiation pearly-lustre gold ink；
The covering power of solidified by ultraviolet ray radiation pearly-lustre gold ink；
Two, reason of problems:
1, the safety and sanitation index request of cigarette-brand ink is high, and common ink is because residual containing benzene,toluene,xylene, acetone, solvent
Stay higher, the photoinitiator containing disabling even if printing effect is good can not be used for pharyngitis granule.The effect that cigarette-brand has not required nothing more than
Fruit more requires to have to comply with " YQ69-2015 tobacco shred and box packaging paper safety and health request ", therefore to the ink of printing cigarette-brand
It is required that higher.
2, bronze material used in existing ultraviolet curing gold ink is Cu-Zn alloy powder, and essence is exactly copper, zinc powder, easily oxygen
Change, cause entire shelf life of products short, at present mostly the shelf-life at 1-2 months, after 2 months will gelatinization, become waste product.
Summary of the invention
The purpose of the present invention is to provide a kind of environmentally friendly and good stability cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink.
It is another object of the present invention to provide a kind of preparation methods of above-mentioned pearly-lustre gold ink.
In order to solve the above technical problems, the present invention provides a kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink, by weight
Number includes following raw material:
Monomer: 25-35 parts
Resin: 35-45 parts
Pearl powder: 15-30 parts
Dyestuff: 2.5-3.5 parts
Photoinitiator: 4.5-5.5 parts
Polymerization inhibitor: 0.8-1.3 parts
Thixotropic agent: 0.4-0.6 parts
Defoaming agent: 0.2-0.4 parts
Levelling agent: 0.15-0.3 parts；
The pearl powder is the powder that mica sheet and titanium dioxide form；
The photoinitiator is xenyl-ethylo benzene ketone.
Preferably, the monomer is the mixture of trifunctional group acrylate and monofunctional acrylates' ester.
Preferably, the fineness of the pearl powder is 20-40um.
Preferably, the ingredient of the dyestuff: the blend mixture of C.I. solvent red 122 and C.I. solvent yellow 82.
Preferably, the polymerization inhibitor is NO free radical piperidine alcohols.
Preferably, the thixotropic agent is fumed silica.
Preferably, the defoaming agent is modified polyorganosiloxane.
Preferably, the levelling agent is polysiloxane-copolyether.
The present invention also provides the above-mentioned cigarette-brand preparation methods of solidified by ultraviolet ray radiation pearly-lustre gold ink, including following step
It is rapid:
A, monomer is added in reaction kettle with photoinitiator and is mixed, temperature: 80 ± 2 DEG C of revolving speeds: 600-800 revs/min, when
Between: 30-50 minutes, stirring to photoinitiator was completely dissolved；
B, resin, polymerization inhibitor, defoaming agent, levelling agent, thixotropic agent are added into reaction kettle, temperature: 80 ± 2 DEG C of revolving speeds:
It 600-800 revs/min, the time: 10-20 minutes, stirs evenly；
C, 90 DEG C are heated to, vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, take out the nuisance evaporated in mixture
Matter, time: 10 minutes；
D, vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
E, pearl powder is added into a mixing bowl, revolving speed: 400-600 revs/min, the time: 20-40 minutes, stirs evenly；
F, dyestuff is added into a mixing bowl, mixes colours, revolving speed: 400-600 revs/min, the time: 20-40 minutes, stirring was equal
It is even；
G, inspection is sampled, strainer filtering is used after qualified, is packaged.
Preferably, it is filtered after qualification with 150 mesh filter screens in step G.
It is had the following beneficial effects: with technical solution of the present invention
1, the safety and sanitation index of solidified by ultraviolet ray radiation pearly-lustre gold ink, the generation of harmful substance derive from two aspects,
One is the harmful substance dissociated in ink, and one is that ink photochemical reaction occurs after receiving ultraviolet radiation is cracked to form
Harmful substance.For free harmful substance, technique is generated by improving, in process of production by heating and vacuumizing skill
Art is driven away.For the harmful substance being cracked to form, most of ink can all react in UV curing process and crack life
At one or more of benzene,toluene,xylene, acetone harmful substance, cause safety and sanitation index that pharyngitis granule oil is not achieved
The safety and sanitation index of ink can not be applied to pharyngitis granule, crack life in ink even if upper machine adaptive and printing effect are fine
It is exactly that photoinitiator active bond after absorbing ultraviolet energy is broken at the main reason for harmful substance, phenyl on branch,
The fracture of the groups such as tolyl, and these harmful substances are generated, by experiment, the light that will largely generate these harmful substances draws
It sends out agent to reject, selects a small amount of photoinitiator generated or do not generate harmful substance.Meet ink by two above step
" YQ69-2015 tobacco shred and box packaging paper safety and health request ".
2, the stability of solidified by ultraviolet ray radiation pearly-lustre gold ink, bronze material used in existing ultraviolet curing gold ink are
Cu-Zn alloy powder, essence is exactly copper, zinc powder, is easily aoxidized, and causes entire shelf life of products short, at present mostly the shelf-life at 1-2 months,
After 2 months will gelatinization, become waste product.The present invention does not have to copper zinc powder, but uses pearl powder, and kernel is low optical refractive index
Mica, be wrapped in outer layer is the metal oxide of high refractive index, such as titanium dioxide or iron oxide, itself has been oxidation
Object extends the shelf-life so the stability of product is strong.
3, the covering power of solidified by ultraviolet ray radiation pearly-lustre gold ink, for pearl powder because its pearly-lustre is more saturating, simple uses pearl powder,
For printing effect is compared to relatively common gold ink, covering power is inadequate, and the present invention is added with centainly again on the basis of adding pearl powder
The transparent yellow of ratio, transparent red dye, so that the covering power of pearly-lustre gold ink reaches requirement, it, will not since dyestuff is transparent compared with toner
Block the flickering of pearly-lustre；Therefore the dyestuff that the present invention selects compensates for the deficiency of pearly-lustre.
Specific embodiment
Below in conjunction with specific embodiment, technical scheme in the embodiment of the invention is clearly and completely described.
The embodiment of the present invention is as shown in table 1 below
Table 1
Specifically,
Embodiment 1
The embodiment of the invention provides a kind of cigarette-brands with solidified by ultraviolet ray radiation pearly-lustre gold ink, the original including following parts by weight
Material: 10% monomer A, 20% monomer B, 40% resin, 20% pearl powder, 1.5% dyestuff A, 1.5% dyestuff B, 5% photoinitiator,
1% polymerization inhibitor, 0.5% thixotropic agent, 0.3% defoaming agent, 0.2% levelling agent.
Wherein, monomer A is tetrahydrofurfuryl acrylate, and monomer B is 3 (ethyoxyl) trimethylolpropane trimethacrylates；
Resin is polyurethane resin；Pearl powder is the mixture of mica and titanium dioxide；Dyestuff A is C.I. solvent red 122, and dyestuff B is
C.I. solvent yellow 82, photoinitiator are xenyl-ethylo benzene ketone；Polymerization inhibitor is NO free radical piperidine alcohols；Thixotropic agent is
Fumed silica；Defoaming agent is modified polyorganosiloxane；Levelling agent is polysiloxane-copolyether.
A kind of preparation method of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink in the present embodiment, including walk as follows
It is rapid:
(1) following raw material: 10% tetrahydrofurfuryl acrylate, 20% 3 (ethyoxyl) three hydroxyls are weighed by weight
Propane tri, 40% polyurethane resin, 20% pearl powder, 1.5% 122 dyestuff of C.I. solvent red,
1.5% 82 dyestuff of C.I. solvent yellow, 5% xenyl-ethylo benzene ketone, 1% NO free radical piperidine alcohols, 0.5%
Fumed silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether；
(2) by 10% tetrahydrofurfuryl acrylate, 20% 3 (ethyoxyl) trimethylolpropane trimethacrylates with
5% xenyl-ethylo benzene ketone is added in reaction kettle and mixes, and 80 DEG C of temperature, 600 revs/min of revolving speed, the time: 30 minutes；
(3) 40% polyurethane resin, 1% NO free radical piperidine alcohols, 0.5% gas phase two are added into reaction kettle
Silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether, 80 DEG C of temperature, revolving speed: 600 revs/min,
Time: 20 minutes；
(4) vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, is taken out the harmful substance evaporated in mixture, time 10
Minute；
(5) vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
(6) 20% pearl powder is added into a mixing bowl, revolving speed: 400 revs/min, mixing time: 20 minutes；
(7) 1.5% 122 dyestuff of C.I. solvent red is added into a mixing bowl, 1.5% 82 dyestuff of C.I. solvent yellow turns
Speed: 400 revs/min, mixing time: 20 minutes；
(8) it is filtered, is packaged with 150 mesh filter screens.
Embodiment 2
The embodiment of the invention provides a kind of cigarette-brands with solidified by ultraviolet ray radiation pearly-lustre gold ink, the original including following parts by weight
Material: 15% monomer A, 15% monomer B, 40% resin, 20% pearl powder, 1.5% dyestuff A, 1.5% dyestuff B, 5% photoinitiator,
1% polymerization inhibitor, 0.51% thixotropic agent, 0.3% defoaming agent, 0.2% levelling agent.
Wherein, monomer A is tetrahydrofurfuryl acrylate, and monomer B is 3 (ethyoxyl) trimethylolpropane trimethacrylates；
Resin is polyurethane resin；Pearl powder is the mixture of mica and titanium dioxide；Dyestuff A is C.I. solvent red 122, and dyestuff B is
C.I. solvent yellow 82, photoinitiator are xenyl-ethylo benzene ketone；Polymerization inhibitor is NO free radical piperidine alcohols；Thixotropic agent is
Fumed silica；Defoaming agent is modified polyorganosiloxane；Levelling agent is polysiloxane-copolyether.
A kind of preparation method of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink in the present embodiment, including walk as follows
It is rapid:
(1) following raw material: 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) three hydroxyls are weighed by weight
Propane tri, 40% polyurethane resin, 20% pearl powder, 1.5% 122 dyestuff of C.I. solvent red,
1.5% 82 dyestuff of C.I. solvent yellow, 5% xenyl-ethylo benzene ketone, 1% NO free radical piperidine alcohols, 0.5%
Fumed silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether；
(2) by 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) trimethylolpropane trimethacrylates with
5% xenyl-ethylo benzene ketone is added in reaction kettle and mixes, and 80 DEG C of temperature, 600 revs/min of revolving speed, the time: 30 minutes；
(3) 40% polyurethane resin, 1% NO free radical piperidine alcohols, 0.5% gas phase two are added into reaction kettle
Silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether, 80 DEG C of temperature, revolving speed: 600 revs/min,
Time: 20 minutes；
(4) vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, is taken out the harmful substance evaporated in mixture, time 10
Minute；
(5) vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
(6) 20% pearl powder is added into a mixing bowl, revolving speed: 400 revs/min, mixing time: 20 minutes；
(7) 1.5% 122 dyestuff of C.I. solvent red is added into a mixing bowl, 1.5% 82 dyestuff of C.I. solvent yellow turns
Speed: 400 revs/min, mixing time: 20 minutes；
(8) it is filtered, is packaged with 150 mesh filter screens.
Embodiment 3
The embodiment of the invention provides a kind of cigarette-brands with solidified by ultraviolet ray radiation pearly-lustre gold ink, the original including following parts by weight
Material: 20% monomer A, 10% monomer B, 40% resin, 20% pearl powder, 1.5% dyestuff A, 1.5% dyestuff B, 5% photoinitiator,
1% polymerization inhibitor, 0.51% thixotropic agent, 0.3% defoaming agent, 0.2% levelling agent.
Wherein, monomer A is tetrahydrofurfuryl acrylate, and monomer B is 3 (ethyoxyl) trimethylolpropane trimethacrylates；
Resin is polyurethane resin；Pearl powder is the mixture of mica and titanium dioxide；Dyestuff A is C.I. solvent red 122, and dyestuff B is
C.I. solvent yellow 82, photoinitiator are xenyl-ethylo benzene ketone；Polymerization inhibitor is NO free radical piperidine alcohols；Thixotropic agent is
Fumed silica；Defoaming agent is modified polyorganosiloxane；Levelling agent is polysiloxane-copolyether.
A kind of preparation method of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink in the present embodiment, including walk as follows
It is rapid:
(1) following raw material: 20% tetrahydrofurfuryl acrylate, 10% 3 (ethyoxyl) three hydroxyls are weighed by weight
Propane tri, 40% polyurethane resin, 20% pearl powder, 1.5% 122 dyestuff of C.I. solvent red,
1.5% 82 dyestuff of C.I. solvent yellow, 5% xenyl-ethylo benzene ketone, 1% NO free radical piperidine alcohols, 0.5%
Fumed silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether；
(2) by 20% tetrahydrofurfuryl acrylate, 10% 3 (ethyoxyl) trimethylolpropane trimethacrylates with
5% xenyl-ethylo benzene ketone is added in reaction kettle and mixes, and 80 DEG C of temperature, 600 revs/min of revolving speed, the time: 30 minutes；
(3) 40% polyurethane resin, 1% NO free radical piperidine alcohols, 0.5% gas phase two are added into reaction kettle
Silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether, 80 DEG C of temperature, revolving speed: 600 revs/min,
Time: 20 minutes.
(4) vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, is taken out the harmful substance evaporated in mixture, time 10
Minute；
(5) vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
(6) 20% pearl powder is added into a mixing bowl, revolving speed: 400 revs/min, mixing time: 20 minutes；
(7) 1.5% 122 dyestuff of C.I. solvent red is added into a mixing bowl, 1.5% 82 dyestuff of C.I. solvent yellow turns
Speed: 400 revs/min, mixing time: 20 minutes；
(8) it is filtered, is packaged with 150 mesh filter screens.
Embodiment 4
The embodiment of the invention provides a kind of cigarette-brands with solidified by ultraviolet ray radiation pearly-lustre gold ink, the original including following parts by weight
Material: 15% monomer A, 15% monomer B, 40% resin, 20% pearl powder, 1.0% dyestuff A, 2.0% dyestuff B, 5% photoinitiator,
1% polymerization inhibitor, 0.51% thixotropic agent, 0.3% defoaming agent, 0.2% levelling agent.
Wherein, monomer A is tetrahydrofurfuryl acrylate, and monomer B is 3 (ethyoxyl) trimethylolpropane trimethacrylates；
Resin is polyurethane resin；Pearl powder is the mixture of mica and titanium dioxide；Dyestuff A is C.I. solvent red 122, and dyestuff B is
C.I. solvent yellow 82, photoinitiator are xenyl-ethylo benzene ketone；Polymerization inhibitor is NO free radical piperidine alcohols；Thixotropic agent is
Fumed silica；Defoaming agent is modified polyorganosiloxane；Levelling agent is polysiloxane-copolyether.
One of the present embodiment cigarette-brand preparation method of solidified by ultraviolet ray radiation pearly-lustre gold ink, includes the following steps:
(1) following raw material: 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) three hydroxyls are weighed by weight
Propane tri, 40% polyurethane resin, 20% pearl powder, 1.0% 122 dyestuff of C.I. solvent red,
2.0% 82 dyestuff of C.I. solvent yellow, 5% xenyl-ethylo benzene ketone, 1% NO free radical piperidine alcohols, 0.5%
Fumed silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether；
(2) by 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) trimethylolpropane trimethacrylates with
5% xenyl-ethylo benzene ketone is added in reaction kettle and mixes, and 80 DEG C of temperature, 600 revs/min of revolving speed, the time: 30 minutes；
(3) 40% polyurethane resin, 1% NO free radical piperidine alcohols, 0.5% gas phase two are added into reaction kettle
Silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether, 80 DEG C of temperature, revolving speed: 600 revs/min,
Time: 20 minutes；
(4) vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, is taken out the harmful substance evaporated in mixture, time 10
Minute；
(5) vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
(6) 20% pearl powder is added into a mixing bowl, revolving speed: 400 revs/min, mixing time: 20 minutes；
(7) 1.0% 122 dyestuff of C.I. solvent red is added into a mixing bowl, 2.0% 82 dyestuff of C.I. solvent yellow turns
Speed: 400 revs/min, mixing time: 20 minutes；
(8) it is filtered, is packaged with 150 mesh filter screens.
Embodiment 5
The embodiment of the invention provides a kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink, and the ink includes following heavy
Measure the raw material of part: 15% monomer A, 15% monomer B, 40% resin, 20% pearl powder, 2.0% dyestuff A, 1.0% dyestuff B, 5%
Photoinitiator, 1% polymerization inhibitor, 0.5% thixotropic agent, 0.3% defoaming agent, 0.2% levelling agent.
Wherein, monomer A is tetrahydrofurfuryl acrylate, and monomer B is 3 (ethyoxyl) trimethylolpropane trimethacrylates；
Resin is polyurethane resin；Pearl powder is the mixture of mica and titanium dioxide；Dyestuff A is C.I. solvent red 122, and dyestuff B is
C.I. solvent yellow 82, photoinitiator are xenyl-ethylo benzene ketone；Polymerization inhibitor is NO free radical piperidine alcohols；Thixotropic agent is
Fumed silica；Defoaming agent is modified polyorganosiloxane；Levelling agent is polysiloxane-copolyether.
One of the present embodiment cigarette-brand preparation method of solidified by ultraviolet ray radiation pearly-lustre gold ink, includes the following steps:
(1) following raw material: 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) three hydroxyls are weighed by weight
Propane tri, 40% polyurethane resin, 20% pearl powder, 2.0% 122 dyestuff of C.I. solvent red,
1.0% 82 dyestuff of C.I. solvent yellow, 5% xenyl-ethylo benzene ketone, 1% NO free radical piperidine alcohols, 0.5%
Fumed silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether；
(2) by 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) trimethylolpropane trimethacrylates with
5% xenyl-ethylo benzene ketone is added in reaction kettle and mixes, and 80 DEG C of temperature, 600 revs/min of revolving speed, the time: 30 minutes；
(3) 40% polyurethane resin, 1% NO free radical piperidine alcohols, 0.5% gas phase two are added into reaction kettle
Silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether, 80 DEG C of temperature, revolving speed: 600 revs/min,
Time: 20 minutes；
(4) vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, is taken out the harmful substance evaporated in mixture, time 10
Minute；
(5) vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
(6) 20% pearl powder is added into a mixing bowl, revolving speed: 400 revs/min, mixing time: 20 minutes；
(7) 2.0% 122 dyestuff of C.I. solvent red is added into a mixing bowl, 1.0% 82 dyestuff of C.I. solvent yellow turns
Speed: 400 revs/min, mixing time: 20 minutes；
(8) it is filtered, is packaged with 150 mesh filter screens.
Embodiment 6
The embodiment of the invention provides a kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink and preparation method thereof, the oil
Ink includes the raw material of following parts by weight: 16% monomer A, 16% monomer B, 43% resin, 15% pearl powder, 2.1% dyestuff A,
1.1% dyestuff B, 5.3% photoinitiator, 1.1% polymerization inhibitor, 0.53% thixotropic agent, 0.32% defoaming agent, 0.21% levelling agent.
Wherein, monomer A is tetrahydrofurfuryl acrylate, and the monomer B is 3 (ethyoxyl) trimethylolpropane tris acrylic acid
Ester；Resin is polyurethane resin；Pearl powder is the mixture of mica and titanium dioxide；Dyestuff A is C.I. solvent red 122, described
Dyestuff B is C.I. solvent yellow 82, and photoinitiator is xenyl-ethylo benzene ketone；Polymerization inhibitor is NO free radical piperidine alcohols；Touching
Change agent is fumed silica；Defoaming agent is modified polyorganosiloxane；Levelling agent is polysiloxane-copolyether.
One of the present embodiment cigarette-brand preparation method of solidified by ultraviolet ray radiation pearly-lustre gold ink, includes the following steps
(1) following raw material: 16% tetrahydrofurfuryl acrylate, 16% 3 (ethyoxyl) three hydroxyls are weighed by weight
Propane tri, 43% polyurethane resin, 15% pearl powder, 2.1% 122 dyestuff of C.I. solvent red,
1.1% 82 dyestuff of C.I. solvent yellow, 5.3% xenyl-ethylo benzene ketone, 1.1% NO free radical piperidine alcohols,
0.53% fumed silica, 0.32% modified polyorganosiloxane, 0.21% polysiloxane-copolyether；
(2) by 16% tetrahydrofurfuryl acrylate, 16% 3 (ethyoxyl) trimethylolpropane trimethacrylates with
5.3% xenyl-ethylo benzene ketone is added in reaction kettle and mixes, and 80 DEG C of temperature, 600 revs/min of revolving speed, the time: 30 minutes；
(3) 43% polyurethane resin, 1.1% NO free radical piperidine alcohols, 0.53% gas are added into reaction kettle
Aerosil, 0.32% modified polyorganosiloxane, 0.21% polysiloxane-copolyether, 80 DEG C of temperature, revolving speed: 600
Rev/min, the time: 20 minutes；
(4) vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, is taken out the harmful substance evaporated in mixture, time 10
Minute；
(5) vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
(6) 15% pearl powder is added into a mixing bowl, revolving speed: 400 revs/min, mixing time: 20 minutes；
(7) 2.1% 122 dyestuff of C.I. solvent red is added into a mixing bowl, 1.1% 82 dyestuff of C.I. solvent yellow turns
Speed: 400 revs/min, mixing time: 20 minutes；
(8) it is filtered, is packaged with 150 mesh filter screens；
Embodiment 7
The embodiment of the invention provides a kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink, and the ink includes following heavy
Measure the raw material of part: 14% monomer A, 14% monomer B, 38% resin, 25% pearl powder, 1.9% dyestuff A, 0.9% dyestuff B,
4.7% photoinitiator, 0.94% polymerization inhibitor, 0.47% thixotropic agent, 0.28% defoaming agent, 0.19% levelling agent.
Wherein, monomer A is tetrahydrofurfuryl acrylate, and monomer B is 3 (ethyoxyl) trimethylolpropane trimethacrylates；
Resin is polyurethane resin；Pearl powder is the mixture of mica and titanium dioxide；Dyestuff A is C.I. solvent red 122, the dyestuff
B is C.I. solvent yellow 82, and photoinitiator is xenyl-ethylo benzene ketone；Polymerization inhibitor is NO free radical piperidine alcohols；Thixotropic agent
For fumed silica；Defoaming agent is modified polyorganosiloxane；Levelling agent is polysiloxane-copolyether.
One of the present embodiment cigarette-brand preparation method of solidified by ultraviolet ray radiation pearly-lustre gold ink, includes the following steps:
(1) following raw material: 14% tetrahydrofurfuryl acrylate, 14% 3 (ethyoxyl) three hydroxyls are weighed by weight
Propane tri, 38% polyurethane resin, 25% pearl powder, 1.9% 122 dyestuff of C.I. solvent red,
0.9% 82 dyestuff of C.I. solvent yellow, 4.7% xenyl-ethylo benzene ketone, 0.94% NO free radical piperidine alcohols,
0.47% fumed silica, 0.28% modified polyorganosiloxane, 0.19% polysiloxane-copolyether；
(2) by 14% tetrahydrofurfuryl acrylate, 14% 3 (ethyoxyl) trimethylolpropane trimethacrylates with
4.7% xenyl-ethylo benzene ketone is added in reaction kettle and mixes, and 80 DEG C of temperature, 600 revs/min of revolving speed, the time: 30 minutes；
(3) 43% polyurethane resin, 0.94% NO free radical piperidine alcohols, 0.47% gas are added into reaction kettle
Aerosil, 0.28% modified polyorganosiloxane, 0.19% polysiloxane-copolyether, 80 DEG C of temperature, revolving speed: 600
Rev/min, the time: 20 minutes；
(4) vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, is taken out the harmful substance evaporated in mixture, time 10
Minute；
(5) vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
(6) 25% pearl powder is added into a mixing bowl, revolving speed: 400 revs/min, mixing time: 20 minutes；
(7) 1.9% 122 dyestuff of C.I. solvent red is added into a mixing bowl, 0.9% 82 dyestuff of C.I. solvent yellow turns
Speed: 400 revs/min, mixing time: 20 minutes；
(8) it is filtered, is packaged with 150 mesh filter screens.
Reference examples formula is as shown in table 2 below:
Table 2
Reference examples 1
This reference examples is the raw material including following parts by weight using common photoinitiator of the photoinitiator TPO as ink:
15% monomer A, 15% monomer B, 40% resin, 20% pearl powder, 2.0% dyestuff A, 1.0% dyestuff B, 5.0% photoinitiator,
1.0% polymerization inhibitor, 0.5% thixotropic agent, 0.3% defoaming agent, 0.2% levelling agent.
Wherein, monomer A is tetrahydrofurfuryl acrylate, and monomer B is 3 (ethyoxyl) trimethylolpropane trimethacrylates；
Resin is polyurethane resin；Pearl powder is the mixture of mica and titanium dioxide；Dyestuff A is C.I. solvent red 122, and dyestuff B is
C.I. solvent yellow 82, photoinitiator 2,4,6- trimethylbenzoy-dipheny phosphine oxide (TPO)；Polymerization inhibitor be nitrogen oxygen from
By phenylpiperidines alcohol；Thixotropic agent is fumed silica；Defoaming agent is modified polyorganosiloxane；Levelling agent is that polysiloxane-polyethers is total
Polymers.
The preparation method of this reference examples, includes the following steps
(1) following raw material: 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) three hydroxyls are weighed by weight
Propane tri, 40% polyurethane resin, 20% pearl powder, 1.2% 122 dyestuff of C.I. solvent red,
1.0% 82 dyestuff of C.I. solvent yellow, the 2 of 5.0%, 4,6- trimethylbenzoy-dipheny phosphine oxides (TPO), 1.0%
NO free radical piperidine alcohols, 0.5% fumed silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-polyethers
Copolymer；
(2) by 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) trimethylolpropane trimethacrylates with
The 2 of 5.0%, 4,6- trimethylbenzoy-dipheny phosphine oxides (TPO) are added in reaction kettle and mix, and 80 DEG C of temperature, revolving speed
600 revs/min, the time: 30 minutes；
(3) 40% polyurethane resin, 1.0% NO free radical piperidine alcohols, 0.5% gas phase are added into reaction kettle
Silica, 0.3% modified polyorganosiloxane, 0.2% polysiloxane-copolyether, 80 DEG C of temperature, revolving speed: 600 turns/
Point, the time: 20 minutes；
(4) vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, is taken out the harmful substance evaporated in mixture, time 10
Minute.
(5) vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
(6) 20% pearl powder is added into a mixing bowl, revolving speed: 400 revs/min, mixing time: 20 minutes；
(7) 2.0% 122 dyestuff of C.I. solvent red is added into a mixing bowl, 1.0% 82 dyestuff of C.I. solvent yellow turns
Speed: 400 revs/min, mixing time: 20 minutes；
(8) it is filtered, is packaged with 150 mesh filter screens.
Reference examples 2
This reference examples 2 are that dyestuff is not added, and simple uses pearly-lustre as pigment, the raw material including following parts by weight:
15% monomer A, 15% monomer B, 41% resin, 21% pearl powder, 5.15% photoinitiator, 1% polymerization inhibitor, 0.52% thixotroping
Agent, 0.31% defoaming agent, 0.21% levelling agent.
Wherein, monomer A is tetrahydrofurfuryl acrylate, and monomer B is 3 (ethyoxyl) trimethylolpropane trimethacrylates；
Resin is polyurethane resin；Pearl powder is the mixture of mica and titanium dioxide；Photoinitiator is xenyl-ethylamino benzonitrile
Ketone；Polymerization inhibitor is NO free radical piperidine alcohols；Thixotropic agent is fumed silica；Defoaming agent is modified polyorganosiloxane；Levelling agent
For polysiloxane-copolyether.
The preparation method of this reference examples ink, includes the following steps
(1) following raw material: 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) three hydroxyls are weighed by weight
Propane tri, 41% polyurethane resin, 21% pearl powder, 5.15% xenyl-ethylo benzene ketone,
1% NO free radical piperidine alcohols, 0.52% fumed silica, 0.31% modified polyorganosiloxane, 0.21% poly- silicon
Oxygen alkane-copolyether；
(2) by 15% tetrahydrofurfuryl acrylate, 15% 3 (ethyoxyl) trimethylolpropane trimethacrylates with
6.4% xenyl-ethylo benzene ketone is added in reaction kettle and mixes, and 80 DEG C of temperature, 600 revs/min of revolving speed, the time: 30 minutes；
(3) 41% polyurethane resin, 1% NO free radical piperidine alcohols, 0.52% gas phase are added into reaction kettle
Silica, 0.31% modified polyorganosiloxane, 0.21% polysiloxane-copolyether, 80 DEG C of temperature, revolving speed: 600
Rev/min, the time: 20 minutes；
(4) vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, is taken out the harmful substance evaporated in mixture, time 10
Minute；
(5) vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
(6) 21% pearl powder is added into a mixing bowl, revolving speed: 400 revs/min, mixing time: 20 minutes；
(7) it is filtered, is packaged with 150 mesh filter screens.
For the safety and sanitation index and printing effect for investigating ink of the present invention, the ink of example 1-7 and reference examples 1-2 are taken,
Film is made with silk screen under the same conditions, carries out effect detection after safety and sanitation index and print, as a result as shown in table 3 below:
Table 3
Shown in table 3 as above, wherein example 1-3 of the invention, flexible with the increase of ratio shared by Monofunctional monomers
Property enhancing；For example 4,3,5 with the increase of dyestuff A content, form and aspect become partially red gold by partially green gold.Example 1- of the invention
7 compared with reference examples 1, and preferred photoinitiator can guarantee safety and sanitation qualified, without containing benzene,toluene,xylene and
Acetone.It can be widely applied on pharyngitis granule.Example 1-7 makes oil compared with reference examples 2, because being added to transparent dyestuff
Ink does not lose the flickering of pearly-lustre, and improves the required covering power of printing.
The above is a preferred embodiment of the present invention, it is noted that for those skilled in the art
For, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (10)
1. a kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink, which is characterized in that in parts by weight include following raw material:
Monomer: 25-35 parts
Resin: 35-45 parts
Pearl powder: 15-30 parts
Dyestuff: 2.5-3.5 parts
Photoinitiator: 4.5-5.5 parts
Polymerization inhibitor: 0.8-1.3 parts
Thixotropic agent: 0.4-0.6 parts
Defoaming agent: 0.2-0.4 parts
Levelling agent: 0.15-0.3 parts；
The pearl powder is the powder that mica sheet and titanium dioxide form；
The photoinitiator is xenyl-ethylo benzene ketone.
2. a kind of cigarette-brand according to claim 1 solidified by ultraviolet ray radiation pearly-lustre gold ink, it is characterised in that: the monomer
For the mixture of trifunctional group acrylate and monofunctional acrylates' ester.
3. a kind of cigarette-brand according to claim 1 solidified by ultraviolet ray radiation pearly-lustre gold ink, it is characterised in that: the pearly-lustre
The fineness of powder is 20-40um.
4. a kind of cigarette-brand according to claim 1 solidified by ultraviolet ray radiation pearly-lustre gold ink, it is characterised in that: the dyestuff
Ingredient: the blend mixture of C.I. solvent red 122 and C.I. solvent yellow 82.
5. a kind of cigarette-brand according to claim 1 solidified by ultraviolet ray radiation pearly-lustre gold ink, it is characterised in that: the polymerization inhibitor
Agent is NO free radical piperidine alcohols.
6. a kind of cigarette-brand according to claim 1 solidified by ultraviolet ray radiation pearly-lustre gold ink, it is characterised in that: the thixotroping
Agent is fumed silica.
7. a kind of cigarette-brand according to claim 1 solidified by ultraviolet ray radiation pearly-lustre gold ink, it is characterised in that: the defoaming
Agent is modified polyorganosiloxane.
8. a kind of cigarette-brand according to claim 1 solidified by ultraviolet ray radiation pearly-lustre gold ink, it is characterised in that: the levelling
Agent is polysiloxane-copolyether.
9. a kind of cigarette-brand preparation method of solidified by ultraviolet ray radiation pearly-lustre gold ink, which comprises the following steps:
A, monomer is added in reaction kettle with photoinitiator and is mixed, temperature: 80 ± 2 DEG C of revolving speeds: 600-800 revs/min, the time: 30-
50 minutes, stirring to photoinitiator was completely dissolved；
B, resin, polymerization inhibitor, defoaming agent, levelling agent, thixotropic agent, temperature: 80 ± 2 DEG C of revolving speeds: 600-800 are added into reaction kettle
Rev/min, the time: 10-20 minutes, stir evenly；
C, 90 DEG C are heated to, vacuum is opened to negative pressure, is stirred under 400 revs/min of revolving speeds, takes out the harmful substance evaporated in mixture,
Time: 10 minutes；
D, vacuum pumping pours out mixture in a mixing bowl to normal pressure from reaction kettle；
E, pearl powder is added into a mixing bowl, revolving speed: 400-600 revs/min, the time: 20-40 minutes, stirs evenly；
F, dyestuff is added into a mixing bowl, mixes colours, revolving speed: 400-600 revs/min, the time: 20-40 minutes, stirs evenly；
G, inspection is sampled, strainer filtering is used after qualified, is packaged.
10. a kind of cigarette-brand according to claim 9 preparation method of solidified by ultraviolet ray radiation pearly-lustre gold ink, feature exist
In: it is filtered after qualification with 150 mesh filter screens in step G.
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| CN110423512A (en) * | 2019-05-17 | 2019-11-08 | 劳安新材料江苏有限公司 | Aqueous golden ink of one kind and preparation method thereof |
| EP4299297A1 (en) * | 2022-06-29 | 2024-01-03 | Pegavision Corporation | Color fixing combination for contact lens, contact lens and method of manufacturing thereof |
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| EP4299297A1 (en) * | 2022-06-29 | 2024-01-03 | Pegavision Corporation | Color fixing combination for contact lens, contact lens and method of manufacturing thereof |
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