CN109576044B - Furfural extract oil emulsion composition, furfural extract oil emulsion product, and preparation method and application of furfural extract oil emulsion product - Google Patents
Furfural extract oil emulsion composition, furfural extract oil emulsion product, and preparation method and application of furfural extract oil emulsion product Download PDFInfo
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- CN109576044B CN109576044B CN201710900252.3A CN201710900252A CN109576044B CN 109576044 B CN109576044 B CN 109576044B CN 201710900252 A CN201710900252 A CN 201710900252A CN 109576044 B CN109576044 B CN 109576044B
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- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 title claims abstract description 158
- 239000000203 mixture Substances 0.000 title claims abstract description 90
- 239000000839 emulsion Substances 0.000 title claims abstract description 35
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title abstract description 16
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 33
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 32
- 239000002184 metal Substances 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 8
- 239000002173 cutting fluid Substances 0.000 claims abstract description 8
- 238000004512 die casting Methods 0.000 claims abstract description 8
- 238000005096 rolling process Methods 0.000 claims abstract description 8
- 239000010959 steel Substances 0.000 claims abstract description 8
- 239000003921 oil Substances 0.000 claims description 88
- 238000003756 stirring Methods 0.000 claims description 43
- 238000010438 heat treatment Methods 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 17
- 239000007864 aqueous solution Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- -1 sorbitan ester Chemical class 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 7
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 4
- 239000006082 mold release agent Substances 0.000 claims description 4
- 239000003208 petroleum Substances 0.000 claims description 4
- 239000001587 sorbitan monostearate Substances 0.000 claims description 4
- 235000011076 sorbitan monostearate Nutrition 0.000 claims description 4
- 229940035048 sorbitan monostearate Drugs 0.000 claims description 4
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004147 Sorbitan trioleate Substances 0.000 claims description 3
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 238000007710 freezing Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000001593 sorbitan monooleate Substances 0.000 claims description 3
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 3
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 3
- 235000019337 sorbitan trioleate Nutrition 0.000 claims description 3
- 229960000391 sorbitan trioleate Drugs 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 6
- 239000011707 mineral Substances 0.000 claims 6
- 239000003002 pH adjusting agent Substances 0.000 claims 5
- 108010053481 Antifreeze Proteins Proteins 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 2
- 230000002528 anti-freeze Effects 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 18
- 239000004094 surface-active agent Substances 0.000 abstract description 13
- 230000001804 emulsifying effect Effects 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 42
- 238000004945 emulsification Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- 239000002006 petroleum coke Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000004939 coking Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 230000004913 activation Effects 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000002619 bicyclic group Chemical group 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000015784 hyperosmotic salinity response Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/02—Well-defined aliphatic compounds
- C10M2203/0206—Well-defined aliphatic compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/02—Well-defined aliphatic compounds
- C10M2203/022—Well-defined aliphatic compounds saturated
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/104—Aromatic fractions
- C10M2203/1045—Aromatic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/24—Emulsion properties
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/36—Release agents or mold release agents
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Colloid Chemistry (AREA)
Abstract
The invention provides a furfural extract oil emulsified composition, a furfural extract oil emulsified product, and a preparation method and application of the product. The emulsified composition comprises the following components in parts by weight: 20-60 parts of furfural extract oil; 0.2-8 parts of a nonionic surfactant; 0.02-3 parts of an anionic surfactant; and 40-80 parts of water. The emulsified product formed by the emulsified composition with the composition has stable performance and low production cost, can be directly used or used by introducing a functional agent, and is suitable for being used as a building release agent, a metal die casting release agent, a metal cutting fluid, a steel rolling emulsion and the like, so that the additional value of the furfural extract oil is improved, and the application environment of the furfural extract oil is expanded. The molecules of the nonionic surfactant and the anionic surfactant have hydrophilic and oleophilic groups, so that the surfactant can obviously reduce the surface tension, and can play a good emulsifying role when being mixed with the furfural extract.
Description
Technical Field
The invention relates to the field of emulsification, in particular to a furfural extract oil emulsified composition, a furfural extract oil emulsified product, a preparation method and an application of the product.
Background
The furfural extract oil is a byproduct in the process of producing the lubricating oil base oil by a positive sequence process or a reverse sequence process, namely, a non-ideal component which is removed when the lubricating oil base oil is refined by taking furfural as a solvent contains a large amount of monocyclic, bicyclic or polycyclic aromatic hydrocarbons, and in addition, a part of saturated alkane and a small amount of colloid and asphaltene. The total aromatic hydrocarbon content of furfural extract oil of a smoothing petrochemical company exceeds 70 percent, and belongs to typical high aromatic hydrocarbon oil, the furfural extract oil is all used as a coking raw material at present, the furfural extract oil is an ideal raw material for producing petroleum coke by a coking device of a petroleum refinery, but the petroleum coke production needs complex reaction processes such as high-temperature cracking, polymerization and the like, the operation conditions are harsh, wherein the outlet temperature of a heating furnace is 495-505 ℃, and the production cost is high; the petroleum coke is mainly used for preparing carbon products and used as fuel, and has low additional value; moreover, petroleum coke pollutes the environment, and particularly, petroleum coke with high sulfur content has certain influence on the quality of the atmospheric environment. Therefore, the current application of the furfural extract oil does not realize efficient reutilization, and the potential high added value of the furfural extract oil is not discovered.
The furfural extract oil has complex composition and structure and is not easy to emulsify. At present, no relevant emulsification technical documents are reported, and oil product processing manufacturers are not precedent for developing new products with high added value of furfural extraction oil by directly utilizing emulsification technology.
Disclosure of Invention
The invention mainly aims to provide a furfural extract oil emulsified composition, a furfural extract oil emulsified product, a preparation method and application of the product, and aims to solve the problem that furfural extract oil cannot be effectively reused in the prior art.
In order to achieve the above object, according to one aspect of the present invention, there is provided a furfural extract oil emulsion composition comprising, in parts by weight: 20-60 parts of furfural extract oil; 0.2-8 parts of a nonionic surfactant; 0.02-3 parts of an anionic surfactant; and 40-80 parts of water.
Further, the nonionic surfactant comprises 1.2-6 parts by weight of sorbitan ester and 0.2-2 parts by weight of polyoxyethylene type nonionic surfactant.
Further, the polyoxyethylene type nonionic surfactant is selected from any one or more of alkylphenol ethoxylates; the sorbitan ester is selected from one or more of sorbitan monostearate, sorbitan monooleate and sorbitan trioleate.
Further, the weight ratio of the nonionic surfactant to the anionic surfactant is 2: 1-4: 1; preferably, the anionic surfactant is selected from any one or more of dodecyl sulfonates.
Further, the emulsion composition further comprises 0.001-3 parts by weight of a pH value regulator, wherein the pH value regulator is an organic amine, and preferably the organic amine is one or more selected from organic amine monoethanolamine, diethanolamine, triethanolamine and 3-propanolamine.
Furthermore, the emulsion composition further comprises 0.001-5 parts by weight of an anti-freezing auxiliary agent, wherein the anti-freezing auxiliary agent is any one or more of ethanol, ethylene glycol and propylene glycol.
Furthermore, the emulsion composition also comprises 0.001-3 parts by weight of solvent oil, wherein the solvent oil is aliphatic hydrocarbon solvent oil, and is preferably 90# petroleum ether, 120# solvent oil or 200# solvent oil.
According to another aspect of the invention, a preparation method of a furfural extract oil emulsified product is provided, and the furfural extract oil emulsified product is prepared by adopting any one of the emulsified compositions as a raw material.
Further, the preparation method comprises the following steps: step S1, mixing the nonionic surfactant of the emulsified composition with the furfural extract oil to form a mixture; and step S2, mixing the aqueous solution of the anionic surfactant at the temperature of 70-90 ℃ with the mixture to form an emulsified product.
Further, the step S1 includes: adding a nonionic surfactant of the emulsified composition to the furfural extract oil to obtain a first premix; heating the first premix to a first temperature at a first stirring speed to obtain a first preheated object, wherein the first temperature is 60-70 ℃, and the first stirring speed is 400-600 revolutions per minute; stirring at a first stirring speed for 10-20 min at a first temperature to obtain a first primary mixture; and heating the first primary mixture to a second temperature at the first stirring speed to obtain a mixture, wherein the second temperature is 70-90 ℃.
Further, the step S2 includes: adding an anionic surfactant to water to obtain a second premix; heating the second premix to a third temperature at a second stirring speed to obtain a second preheated object, wherein the third temperature is 60-70 ℃; stirring at the third temperature for 10-20 min at the second stirring speed at the constant temperature to obtain a second primary mixture; heating the second primary mixture to a fourth temperature at a second stirring speed to obtain an aqueous solution of an anionic surfactant, wherein the fourth temperature is 70-90 ℃; and adding the aqueous solution into the mixture, and stirring at a rotating speed of 200-1000 rpm for 20-80 min to obtain an emulsified product.
Further, the emulsified composition also comprises a pH value regulator, an optional antifreezing aid and an optional solvent oil, and the preparation method also comprises the process of adding the pH value regulator, the optional antifreezing aid and the optional solvent oil into the mixed substances after mixing the aqueous solution of the anionic surfactant at the temperature of 70-90 ℃ with the mixture.
According to another aspect of the invention, a furfural extract oil emulsified product is provided, and the emulsified product is prepared by adopting any one of the preparation methods.
According to another aspect of the invention, the application of the furfural extract oil emulsion product comprises the application of the furfural extract oil emulsion product in building release agents, metal die-casting release agents, metal cutting fluids or steel rolling emulsion.
By applying the technical scheme of the invention, the emulsified product formed by the emulsified composition with the composition has stable performance and low production cost, can be directly used or used by introducing a functional agent, and is suitable for being used as a building release agent, a metal die-casting release agent, a metal cutting fluid, a steel rolling emulsified liquid and the like, so that the added value of the furfural extract oil is improved, and the application environment of the furfural extract oil is expanded. The nonionic surfactant and the anionic surfactant have hydrophilic and lipophilic groups in molecules, are surfactants capable of remarkably reducing surface tension, can play a good emulsification role when being mixed with the furfural extract oil, and are matched for use, so that the emulsification role of the furfural extract oil can be further improved.
Detailed Description
It should be noted that the embodiments and features of the embodiments in the present application may be combined with each other without conflict. The present invention will be described in detail with reference to examples.
As analyzed by the background art, the furfural extract oil adopted in the prior art is basically used as a coking raw material, so that the added value is not exploited, and the waste of useful substances is caused. However, in the prior art, no report about an emulsification technology of furfural extract oil exists at present, so that after the composition of the furfural extract oil and the performance requirements of the emulsified product are analyzed, a formula of the emulsified product with the furfural extract oil as a matrix is obtained on the basis of a large number of tests, and a furfural extract oil emulsified composition, a furfural extract oil emulsified product, and a preparation method and an application of the product are provided on the basis of the formula.
The emulsified composition of the furfural extract oil comprises, by weight, 20-60 parts of furfural extract oil; 0.2-8 parts of a nonionic surfactant; 0.02-3 parts of an anionic surfactant; and 40-80 parts of water.
The emulsified product formed by the emulsified composition with the composition has stable performance and low production cost, can be directly used or used by introducing a functional agent, and is suitable for being used as a building release agent, a metal die-casting release agent, a metal cutting fluid, a steel rolling emulsion and the like, so that the added value of the furfural extract oil is improved, and the application environment of the furfural extract oil is expanded. The nonionic surfactant and the anionic surfactant have hydrophilic and lipophilic groups in molecules, are surfactants capable of remarkably reducing surface tension, can play a good emulsification role when being mixed with the furfural extract oil, and are matched for use, so that the emulsification role of the furfural extract oil can be further improved.
In a preferred embodiment of the present application, the nonionic surfactant includes 1.2 to 6 parts by weight of sorbitan ester and 0.2 to 2 parts by weight of polyoxyethylene type nonionic surfactant. The polyoxyethylene nonionic surfactant contains lipophilic alkyl in molecules, particularly lipophilic groups containing a plurality of ether bonds, has good hydrophilicity, and is easy to extract furfural oil to disperse into water; the sorbitan contains ester formed by organic matters with a plurality of hydroxyl groups and higher fatty acid, contains long-chain fatty acid with strong lipophilicity or long-chain fatty alcohol lipophilic group and hydroxyl lipophilic group with weak hydrophilicity, and the hydroxyl hydrophilicity is weak, so that the furfural extract oil is easy to emulsify. The two types of nonionic surfactants complement and cooperate in hydrophilicity and lipophilicity, and are more stable than emulsions formed by other surfactants.
Further, it is preferable that the above polyoxyethylene type nonionic surfactant is selected from any one or more of alkylphenol ethoxylates; the sorbitan ester is selected from one or more of sorbitan monostearate, sorbitan monooleate and sorbitan trioleate. The cost of the nonionic surface activity is relatively low, and the surface activity effect is better. The alkylphenol ethoxylates mentioned above include various types of specific products known in the art, such as OP-10, NP-7 and APE-12.
Furthermore, in order to promote the dissolution of the surfactant and effectively improve the salt tolerance and the hard water resistance, 2: 1-4: 1 of the nonionic surfactant and the anionic surfactant is preferably selected. In addition, experiments prove that the surface activation effect is particularly outstanding when the dodecyl sulfonate is selected as the anionic surfactant, so that the anionic surfactant is preferably selected from any one or more of the dodecyl sulfonates. The dodecyl sulfonate contains a lipophilic group (CH-), particularly has a relatively strong hydrophilic group sulfonic group, can emulsify extracted oil, and is beneficial to improving the performance of the surfactant when being compounded with the selected nonionic surfactant. In addition, in order to prevent corrosion of the furfural extract oil emulsion to metal products, the emulsion composition preferably further comprises 0.001-3 parts by weight of a pH regulator, wherein the pH regulator is an organic amine, and the organic amine is preferably one or more selected from monoethanolamine, diethanolamine, triethanolamine and 3-propanolamine.
In order to facilitate storage and transportation of the furfural extract oil emulsion at low temperature (0 ℃), the emulsion composition preferably further comprises 0.001-5 parts by weight of an antifreezing aid selected from any one or more of ethanol, ethylene glycol and propylene glycol.
Furthermore, in order to prevent the influence of air temperature on the viscosity of the furfural extract oil emulsion (particularly in northern areas with obvious air temperature change along with seasonal changes), the emulsion composition preferably further comprises 0.001-3 parts by weight of solvent oil, wherein the solvent oil is aliphatic hydrocarbon solvent oil, such as 90# petroleum ether, 120# solvent oil or 200# solvent oil.
In another exemplary embodiment of the present application, a method for preparing an emulsified product of furfural extract oil from any of the above emulsified compositions is provided.
The emulsified product formed by the emulsified composition with the composition has stable performance and low production cost, can be directly used or used by introducing a functional agent, and is suitable for being used as a building release agent, a metal die casting release agent, a metal cutting fluid, a steel rolling emulsion and the like.
In order to allow each component in the emulsion composition to sufficiently function, the above-mentioned production method preferably comprises: step S1, mixing the nonionic surfactant of the emulsified composition with the furfural extract oil to form a mixture; and step S2, mixing the aqueous solution of the anionic surfactant at the temperature of 70-90 ℃ with the mixture to form an emulsified product. Before water is added, the nonionic surfactant and the furfural extract oil start to be mutually dissolved under stirring along with the temperature rise until the nonionic surfactant and the furfural extract oil are integrated, and when the nonionic surfactant and the furfural extract oil are mixed with the aqueous solution of the anionic surfactant, the added surfactant has a real effect, namely, the lipophilic group of the surfactant is connected with the furfural extract oil, and the hydrophilic group is connected with water to form an emulsion. The substances are mixed according to the method, so that the activation effect of each surfactant can be fully exerted, and a uniform emulsified product is formed.
In a preferred embodiment of the present application, the step S1 includes: adding a nonionic surfactant of the emulsified composition to the furfural extract oil to obtain a first premix; heating the first premix to a first temperature at a first stirring speed to obtain a first preheated object, wherein the first temperature is 60-70 ℃, and the first stirring speed is 400-600 revolutions per minute; stirring at a first stirring speed for 10-20 min at a first temperature to obtain a first primary mixture; and heating the first primary mixture to a second temperature at the first stirring speed to obtain a mixture, wherein the second temperature is 70-90 ℃. By adopting the step-by-step heating mode, the respective emulsifying performance in the composite surfactant is exerted to the optimal state, the particle size distribution of the emulsion is uniform, and the emulsifying system tends to be more stable.
In another preferred embodiment of the present application, the step S2 includes: adding an anionic surfactant to water to obtain a second premix; heating the second premix to a third temperature at a second stirring speed to obtain a second preheated object, wherein the third temperature is 60-70 ℃; stirring at the third temperature for 10-20 min at the second stirring speed at the constant temperature to obtain a second primary mixture; heating the second primary mixture to a fourth temperature at a second stirring speed to obtain an aqueous solution of an anionic surfactant, wherein the fourth temperature is 70-90 ℃; and adding the aqueous solution into the mixture, and stirring at a rotating speed of 200-1000 rpm for 20-80 min to obtain an emulsified product.
The solubility of anionic surfactants in water varies with temperature. When the temperature is raised to 70 ℃, the solubility of the surfactant increases dramatically, and it can only act to a greater extent when the temperature is higher than this. Therefore, firstly, the anionic surfactant is uniformly dispersed in water at 60-70 ℃, and transitional preparation is made for achieving the optimal solubility at 70-90 ℃; the dissolution is realized as soon as possible after the temperature is 70-90 ℃.
When the emulsified composition further comprises a pH value regulator, an optional antifreezing aid and an optional solvent oil, the preparation method preferably further comprises the step of determining whether to add the pH value regulator, the optional antifreezing aid and the optional solvent oil according to the measured pH value in a mixed substance after mixing the aqueous solution of the anionic surfactant at 70-90 ℃ with the mixture.
After the main components are mixed, the auxiliary agent is added, so that the influence of the auxiliary agent on the emulsification effect is avoided, and the flexibility of the property adjustment of the emulsified product is ensured.
In another exemplary embodiment of the present application, a furfural extract oil emulsified product is provided, which is prepared by any one of the above-mentioned preparation methods. The emulsified product formed by the emulsified composition with the composition has stable performance and low production cost, and can be directly used or used by introducing a functional agent.
In yet another exemplary embodiment of the present application, there is provided a use of the furfural extract oil emulsion product according to any one of the above, including use of the furfural extract oil emulsion product in construction mold release agents, metal die casting mold release agents, metal cutting fluids, or steel rolling emulsions.
The advantageous effects of the present application will be further described below with reference to examples and comparative examples.
The composition of the furfural extract oil used in the following examples is shown in table 1.
TABLE 1
The emulsified products of examples 1 to 21 were prepared as follows:
adding polyoxyethylene type nonionic surfactant and sorbitan ester surfactant in the materials into furfural extract oil to obtain a first premix; heating the first premix to a first temperature at a first stirring speed to obtain a first preheated object; stirring for a certain time at a first temperature and a first stirring speed to obtain a first primary mixture; the first primary mixture is heated to a second temperature at a first stirring speed to obtain a mixture.
Adding an anionic surfactant to water to obtain a second premix; heating the second premix to a third temperature at a second stirring speed to obtain a second preheated object; stirring for a certain time at a constant temperature at a second stirring speed at a third temperature to obtain a second primary mixture; heating the second primary mixture to a fourth temperature at a second stirring speed to obtain an aqueous solution of an anionic surfactant; and adding the aqueous solution into the mixture, and stirring for a certain time at a third stirring speed to obtain an emulsified product.
The compositions of the emulsified compositions forming the emulsified products are shown in tables 2 and 3. The temperature, stirring speed and time parameters involved in the preparation are shown in Table 4.
TABLE 2
TABLE 3
TABLE 4
Example 22
The composition of the emulsified composition was the same as in example 1 and the preparation method was as follows:
and (2) stirring NP-7 alkylphenol polyoxyethylene ether, sorbitan monostearate, furfural extract oil, sodium dodecyl sulfate and water at 80 ℃ for 90min at the speed of 1000 revolutions per minute to obtain an emulsified product.
The index detection method of the emulsified product comprises the following steps:
color: visual inspection;
solid content: measured according to the method of GBT 11175-2002;
pH value: measuring by using pH test paper;
storage stability: measured according to the method of GB 11543-89;
the results are shown in Table 5.
TABLE 5
According to the comparison of the data of the examples and the comparative examples, the emulsified products formed by the formula of the application have stable performance; meanwhile, as can be seen from the comparison between example 1 and example 18, the anionic surfactant is selected from the sulfonate type, which has the advantage of significantly improving the emulsification effect. Meanwhile, as can also be seen from comparison of example 1 with examples 19 to 22, control of the preparation method is also advantageous for improving the emulsification effect.
From the above description, it can be seen that the above-described embodiments of the present invention achieve the following technical effects:
the emulsified product formed by the emulsified composition with the composition has stable performance and low production cost, can be directly used or used by introducing a functional agent, and is suitable for being used as a building release agent, a metal die casting release agent, a metal cutting fluid, a steel rolling emulsion and the like, so that the added value of the furfural extract oil is improved, and the application environment of the furfural extract oil is expanded. The nonionic surfactant and the anionic surfactant have hydrophilic and lipophilic groups in molecules, are surfactants capable of remarkably reducing surface tension, can play a good emulsification role when being mixed with the furfural extract oil, and are matched for use, so that the emulsification role of the furfural extract oil can be further improved.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (16)
1. A furfural extract oil emulsion composition, characterized by comprising, in parts by weight:
the nonionic surfactant comprises 1.2-6 parts of sorbitan ester and 0.2-2 parts of polyoxyethylene nonionic surfactant in parts by weight, and the anionic surfactant is any one or more selected from dodecyl sulfonate.
2. The emulsified composition as claimed in claim 1, wherein the polyoxyethylene type nonionic surfactant is selected from any one or more of alkylphenol ethoxylates; the sorbitan ester is selected from any one or more of sorbitan monostearate, sorbitan monooleate and sorbitan trioleate.
3. The emulsified composition as claimed in claim 1, wherein the weight ratio of said nonionic surfactant to said anionic surfactant is 2:1 to 4: 1.
4. The emulsified composition as set forth in claim 1, further comprising 0.001-3 parts by weight of a pH adjusting agent, wherein said pH adjusting agent is an organic amine.
5. An emulsified composition according to claim 4, wherein the organic amine is selected from any one or more of monoethanolamine, diethanolamine, triethanolamine, and 3-propanolamine.
6. The emulsified composition as claimed in claim 1, further comprising 0.001-5 parts by weight of an anti-freezing auxiliary agent selected from any one or more of ethanol, ethylene glycol and propylene glycol.
7. The emulsion composition according to claim 1, further comprising 0.001 to 3 parts by weight of a mineral spirit, wherein the mineral spirit is an aliphatic hydrocarbon mineral spirit.
8. The emulsified composition as claimed in claim 7, wherein the mineral spirit is 90# petroleum ether, 120# mineral spirit or 200# mineral spirit.
9. A method for preparing a furfural extract oil emulsified product, which is characterized in that the emulsified product is prepared by adopting the emulsified composition as claimed in any one of claims 1 to 8 as a raw material.
10. The method of manufacturing according to claim 9, comprising:
step S1, mixing the nonionic surfactant of the emulsified composition with furfural extract oil to form a mixture;
and step S2, mixing an aqueous solution of an anionic surfactant at 70-90 ℃ with the mixture to form the emulsified product.
11. The method for preparing a composite material according to claim 10, wherein the step S1 includes:
adding a nonionic surfactant of the emulsified composition to the furfural extract oil to obtain a first premix;
heating the first premix to a first temperature at a first stirring speed to obtain a first preheated object, wherein the first temperature is 60-70 ℃, and the first stirring speed is 400-600 revolutions per minute;
stirring at the first stirring speed for 10-20 min at the first temperature to obtain a first primary mixture; and
and heating the first primary mixture to a second temperature at the first stirring speed to obtain the mixture, wherein the second temperature is 70-90 ℃.
12. The method for preparing a composite material according to claim 11, wherein the step S2 includes:
adding the anionic surfactant to water to obtain a second premix;
heating the second premix to a third temperature at a second stirring speed to obtain a second preheated object, wherein the third temperature is 60-70 ℃;
stirring at the third temperature at the second stirring speed for 10-20 min to obtain a second primary mixture;
heating the second primary mixture to a fourth temperature at the second stirring speed to obtain an aqueous solution of the anionic surfactant, wherein the fourth temperature is 70-90 ℃; and
and adding the aqueous solution into the mixture, and stirring at a rotating speed of 200-1000 rpm for 20-80 min to obtain the emulsified product.
13. The method of any one of claims 10 to 12, wherein the emulsion composition further comprises a pH adjuster, and the method further comprises adding the pH adjuster to the mixed materials after mixing an aqueous solution of an anionic surfactant at 70 to 90 ℃ with the mixture.
14. The method of claim 13, wherein the emulsion composition further comprises an anti-freeze additive and/or a solvent oil, and the method further comprises adding the pH adjuster, the anti-freeze additive and/or the solvent oil to the mixed material after mixing an aqueous solution of an anionic surfactant at 70 to 90 ℃ with the mixture.
15. A furfural extract oil emulsified product, characterized in that it is produced by the production method according to any one of claims 9 to 14.
16. Use of the emulsified furfural extract oil as set forth in claim 15 in building mold release agents, metal die casting mold release agents, metal cutting fluids or steel rolling emulsions.
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