CN109749255A - A kind of polyolefine toughener - Google Patents
A kind of polyolefine toughener Download PDFInfo
- Publication number
- CN109749255A CN109749255A CN201711086413.6A CN201711086413A CN109749255A CN 109749255 A CN109749255 A CN 109749255A CN 201711086413 A CN201711086413 A CN 201711086413A CN 109749255 A CN109749255 A CN 109749255A
- Authority
- CN
- China
- Prior art keywords
- parts
- toughener
- antioxidant
- polyolefine
- ultraviolet absorber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000012745 toughening agent Substances 0.000 title claims abstract description 30
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 17
- 229920001971 elastomer Polymers 0.000 claims abstract description 16
- 239000005060 rubber Substances 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 11
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 11
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 11
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 9
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 7
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- 235000006708 antioxidants Nutrition 0.000 claims description 9
- -1 phenyl ester Chemical class 0.000 claims description 7
- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- 150000008360 acrylonitriles Chemical class 0.000 claims description 2
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 claims description 2
- 150000003918 triazines Chemical class 0.000 claims description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims 1
- 229960004889 salicylic acid Drugs 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 231100000331 toxic Toxicity 0.000 abstract description 3
- 230000002588 toxic effect Effects 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000004698 Polyethylene Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000000034 method Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to toughener fields, and in particular to a kind of polyolefine toughener is grouped as by the group of following parts by weight: 40-50 parts of EP rubbers, 25-35 parts of pentaerythrite, 20-35 parts of pentaerythritol stearate, 2-6 parts of antiaging agent；The antiaging agent is the compound of ultraviolet absorber, antioxidant, and the mass ratio of the ultraviolet absorber and antioxidant is 1:1-1.2.Using the beneficial effects of the present invention are: the polyolefine toughener toxic side effect is small, low temperature resistant heat-resist, good impact resistance.
Description
Technical field
The invention belongs to toughener fields, and in particular to a kind of polyolefine toughener.
Background technique
Toughener, which refers to, can increase the flexible substance of adhesive film layer, and plastics are very widely used since invention,
The toughness of plastics is always people's concern, and toughener is to reduce the brittleness after plastic hardening and improve its impact strength
A kind of additive being added with elongation percentage.Toughener can be divided into rubber toughener and thermoplastic elastomer (TPE) class toughener, increase
Tough dose of general all active group, can chemically react with resin, not exclusively compatible after solidification, also want split-phase sometimes, can obtain
Comparatively ideal toughening effect is obtained, keeps heat distortion temperature constant or decline is little, common toughener is polyethylene toughener, two at present
Sad toughener, still, polyethylene toughener increase opacity, and low-temperature resistance effect is bad；Two sad toughener poison are secondary to be made
With big therefore big to human injury in process, and the toughening efficiency of the prior art is low, and poor impact toughness is easily torn.
Summary of the invention
The technical problem to be solved by the present invention is to overcome toughener toxic side effect in the prior art is big, shock resistance difference
Technical deficiency provides a kind of polyolefine toughener environmentally friendly, toughness is good.
In order to solve the above technical problems, The technical solution adopted by the invention is as follows:
A kind of polyolefine toughener, composition is by weight ratio are as follows: and 40-50 parts of EP rubbers, pentaerythrite 25-35
Part, 20-35 parts of pentaerythritol stearate, 2-6 parts of antiaging agent.
Further, the antiaging agent is the compound of ultraviolet absorber, antioxidant, the ultraviolet absorber and antioxygen
The mass ratio of agent is 1:1-1.2.
Further, the ultraviolet absorber is selected from: phenyl salicylate, group-substituted acrylonitrile, triazines and ultraviolet light are inhaled
Receive at least one of agent UV-P.
Further, the antioxidant is selected from: at least one of antioxidant 1010, anti-oxidant DLTP and antioxidant TNP.
Further, a kind of polyolefine toughener, composition is by weight ratio are as follows: and 45 parts of EP rubbers, pentaerythrite
30 parts, 25 parts of pentaerythritol stearate, 4 parts of antiaging agent.
The purpose that the present invention uses EP rubbers is: EP rubbers is with ethylene, propylene for main raw material monomer, using having
Organic metal catalyst, amorphous rubber made of being copolymerized under solution state.The content of usual propylene is about 40-60% or so,
The content of Third monomer is about 2-5%, 250,000 or more average molecular weight, and wider distribution.Due to the third of introducing in EP rubbers
Alkene destroys original polyethylene crystallization with unformed arrangement, thus becomes the irregular noncrystalline rubber of copolymerization, while retaining again
Certain characteristics of polyethylene.EP rubbers is substantially a kind of high-molecular compound of saturation, and intramolecular does not have polarity substitution
Base, chain link are submissiveer.Its ozone resistants, weatherability, resistance to ag(e)ing be in general purpose rubber it is best, electrical insulating property,
Chemical-resistant and impact resistance are all preferable.
Using the beneficial effects of the present invention are: the polyolefine toughener toxic side effect is small, low temperature resistant heat-resist, shock resistance
Property is good.
Specific embodiment
Below with reference to embodiment, the invention will be further described.
Embodiment 1
A kind of polyolefine toughener, composition is by weight ratio are as follows: and 40 parts of EP rubbers, 25 parts of pentaerythrite, season penta
20 parts of tetrol stearate, 2 parts of antiaging agent.
Embodiment 2
A kind of polyolefine toughener, composition is by weight ratio are as follows: and 45 parts of EP rubbers, 30 parts of pentaerythrite, season penta
25 parts of tetrol stearate, 4 parts of antiaging agent.
The present embodiment is preferred forms.
Embodiment 3
A kind of polyolefine toughener, composition is by weight ratio are as follows: and 50 parts of EP rubbers, 35 parts of pentaerythrite, season penta
35 parts of tetrol stearate, 6 parts of antiaging agent.
Claims (5)
1. a kind of polyolefine toughener, it is characterised in that be grouped as by the group of following parts by weight: 40-50 parts of EP rubbers, season penta
25-35 parts of tetrol, 20-35 parts of pentaerythritol stearate, 2-6 parts of antiaging agent.
2. a kind of polyolefine toughener according to claim 1, it is characterised in that the antiaging agent be ultraviolet absorber,
The mass ratio of the compound of antioxidant, the ultraviolet absorber and antioxidant is 1:1-1.2.
3. a kind of polyolefine toughener according to claim 2, it is characterised in that the ultraviolet absorber is selected from: salicylic acid
At least one of phenyl ester, group-substituted acrylonitrile, triazines and Ultraviolet Absorber UV-P.
4. a kind of polyolefine toughener according to claim 2, it is characterised in that the antioxidant is selected from: antioxidant
1010, at least one of anti-oxidant DLTP and antioxidant TNP.
5. a kind of polyolefine toughener according to claim 1, it is characterised in that be grouped as by the group of following parts by weight: second
Third 45 parts of rubber, 30 parts of pentaerythrite, 25 parts of pentaerythritol stearate, 4 parts of antiaging agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711086413.6A CN109749255A (en) | 2017-11-07 | 2017-11-07 | A kind of polyolefine toughener |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711086413.6A CN109749255A (en) | 2017-11-07 | 2017-11-07 | A kind of polyolefine toughener |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109749255A true CN109749255A (en) | 2019-05-14 |
Family
ID=66400120
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711086413.6A Withdrawn CN109749255A (en) | 2017-11-07 | 2017-11-07 | A kind of polyolefine toughener |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109749255A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110168425A1 (en) * | 2010-01-08 | 2011-07-14 | Ahmed Ali Basfar | Clean flame retardant compositions with carbon nano tube for enhancing mechanical properties for insulation of wire and cable |
| CN102234397A (en) * | 2011-05-10 | 2011-11-09 | 深圳市兴迪塑胶有限公司 | Polypropylene composition for indoor communication cabinet |
| CN104877240A (en) * | 2015-06-12 | 2015-09-02 | 刘洋 | Polyolefin toughening agent |
-
2017
- 2017-11-07 CN CN201711086413.6A patent/CN109749255A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110168425A1 (en) * | 2010-01-08 | 2011-07-14 | Ahmed Ali Basfar | Clean flame retardant compositions with carbon nano tube for enhancing mechanical properties for insulation of wire and cable |
| CN102234397A (en) * | 2011-05-10 | 2011-11-09 | 深圳市兴迪塑胶有限公司 | Polypropylene composition for indoor communication cabinet |
| CN104877240A (en) * | 2015-06-12 | 2015-09-02 | 刘洋 | Polyolefin toughening agent |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190514 |