CN109825150A - A kind of macromolecule environmental-protection agent and preparation method thereof for equipment surface spraying - Google Patents
A kind of macromolecule environmental-protection agent and preparation method thereof for equipment surface spraying Download PDFInfo
- Publication number
- CN109825150A CN109825150A CN201910057637.7A CN201910057637A CN109825150A CN 109825150 A CN109825150 A CN 109825150A CN 201910057637 A CN201910057637 A CN 201910057637A CN 109825150 A CN109825150 A CN 109825150A
- Authority
- CN
- China
- Prior art keywords
- parts
- macromolecule
- agent
- equipment surface
- friendly materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The invention discloses a kind of macromolecule environment-friendly materials equipment list protective agents for equipment surface spraying, it includes each component raw material of following parts by weight: 5-30 parts of macromolecule emulsion wax, 30-80 parts of resin emulsion, 3-10 parts of emulsifier, 3-10 parts of film forming agent, 0.5-3 parts of quick dry agent, 0-1 parts of modified silicon oil and distillation appropriate amount of water.The invention also discloses a kind of preparation methods of macromolecule environment-friendly materials protective agent for equipment surface spraying.After protective agent spraying of the invention thoroughly parches, surface is smooth, does not touch with one's hand, and non-scale, water-fast flushing is low temperature resistant, and good toughness rub resistance etc..The corrosive mediums such as water, sour gas are isolated fabulous, play antirust, the effects of waterproof, acid rain preventing corrosion.
Description
Technical field
The present invention relates to machine-building or assembling casing external form, in particular to a kind of macromolecules for equipment surface spraying
Environment-friendly materials protective agent and preparation method thereof.
Background technique
In today of rapid economic development, large scale equipment manufacturing industry flourishes.But equipment without in use, by
It in installation, causes equipment localized metallic exposed, the corrosion of generation is contacted with air and containing substances such as soda acids, is caused
Equipment surface has rusty stains, and has seriously affected equipment external form quality.For example agricultural equipment, tractor, extraordinary cultivation harvester etc.,
All there is corrosion in motor vehicle equipment, pump casing, simple and mechanical, amusement facility, motor sailboat etc..This product is suitable for protection
Equipment external form quality, prevents the corrosion of equipment surface.
Summary of the invention
The purpose of the present invention is causing equipment localized metallic exposed in equipment assembling, with air and containing objects such as soda acids
Matter contacts and corrodes, a kind of macromolecule environment-friendly materials equipment surface protective agent for equipment surface spraying provided.
A kind of macromolecule environment-friendly materials equipment surface protective agent for equipment surface spraying, it includes following parts by weight
Each component raw material: 5-30 parts of macromolecule emulsion wax, 30-80 parts of resin emulsion, 3-10 parts of emulsifier, 3-10 parts of film forming agent, quick-drying
0.5-3 parts of agent, 0-1 parts of modified silicon oil and distillation appropriate amount of water.
The macromolecule emulsion wax is that the cream for accounting for its quality 3%-10% is added after macromolecule wax to be heated to 80-90 DEG C of temperature
Agent, stirs 60-90min, and mixing speed 250-350r/min makes it become emulsion state, obtains macromolecule emulsion wax；Institute
Macromolecule wax is stated as any one in polyethylene wax, No. 80 microwaxes, No. 85 microwaxes.
The resin emulsion is emulsion acrylic resin.
The emulsifier be octadecylamine, milky white spirit, sapn, in tween any one or more is compound.
The film forming agent is PVP-K30, PVP-K90, acrylic amine copolymer DC-79, polyvinyl alcohol (PVA), 12 carbon
Any one or more in alcohol ester is compound.
The modified silicon oil is 204 water soluble polyether modified silicon oils.
The quick dry agent is water-based zinc stearate.
A kind of preparation method of the macromolecule environment-friendly materials equipment surface protective agent for equipment surface spraying, including it is following
Step: being packed into reconciliation kettle for the macromolecule emulsion wax and resin emulsion of above-mentioned parts by weight, and opening to stir and heat makes to reconcile in kettle
Temperature reaches 40-50 DEG C, and the emulsifier of above-mentioned parts by weight is then added and stirs 1-1.5h, then adds the film forming of above-mentioned parts by weight
Agent, quick dry agent, modified silicon oil and distilled water, continue to stir 1-2h, then stop heating wait reconcile after temperature in the kettle is down to room temperature
Discharging, obtains the high polymer elastic environment-friendly materials equipment surface protective agent.
The mixing speed for reconciling kettle is controlled in 300-1000r/min.
Advantages of the present invention: this product is widely used in device fabrication: such as speed reducer, machining equipment, the installing of agricultural machinery group
Standby, lorry assembles equipment, low temperature low-speed running equipment, haulage equipment, amusement facility, the appearance of sports equipment etc. exposure device
Protection etc., service life 1 year or more.After protective agent spraying thoroughly parches, surface is smooth, does not touch with one's hand, non-scale, water-fast punching
It washes, it is low temperature resistant, and good toughness rub resistance etc..It is fabulous to the isolation of the corrosive mediums such as sour gas, play antirust, waterproof, acid-proof
The effects of rain corrodes.
Detailed description of the invention
Fig. 1 is influence schematic diagram of the auxiliary agent A to coated film；
Fig. 2 is influence schematic diagram of the auxiliary agent B to spray-coating surface quick-drying；
Fig. 3 is influence schematic diagram of the auxiliary agent C to viscosity.
Specific embodiment
It is a kind of for equipment surface spraying macromolecule environment-friendly materials equipment surface protective agent, it is characterised in that it include with
The each component raw material of lower parts by weight: 5-30 parts of macromolecule emulsion wax, 30-80 parts of resin emulsion, 3-10 parts of emulsifier, film forming agent 3-
10 parts, 0.5-3 parts of quick dry agent, 0-1 parts of modified silicon oil and distillation appropriate amount of water.
The macromolecule emulsion wax is that the cream for accounting for its quality 3%-10% is added after macromolecule wax to be heated to 80-90 DEG C of temperature
Agent, stirs 60-90min, and mixing speed 250-350r/min makes it become emulsion state, obtains macromolecule emulsion wax；Institute
Macromolecule wax is stated as any one in polyethylene wax, No. 80 microwaxes, No. 85 microwaxes.
The resin emulsion is emulsion acrylic resin.
The emulsifier be octadecylamine, milky white spirit, sapn, in tween any one or more is compound.
The film forming agent is PVP-K30, PVP-K90, acrylic amine copolymer DC-79, polyvinyl alcohol (PVA), 12 carbon
Any one or more in alcohol ester is compound.
The modified silicon oil is 204 water soluble polyether modified silicon oils.
The quick dry agent is water-based zinc stearate.
A kind of preparation method of the macromolecule environment-friendly materials equipment surface protective agent for equipment surface spraying, including it is following
Step: being packed into reconciliation kettle for the macromolecule emulsion wax and resin emulsion of above-mentioned parts by weight, and opening to stir and heat makes to reconcile in kettle
Temperature reaches 40-50 DEG C, and the emulsifier of above-mentioned parts by weight is then added and stirs 1-1.5h, then adds the film forming of above-mentioned parts by weight
Agent, quick dry agent, modified silicon oil and distilled water, continue to stir 1-2h, then stop heating wait reconcile after temperature in the kettle is down to room temperature
Discharging, obtains the high polymer elastic environment-friendly materials equipment surface protective agent.
The mixing speed for reconciling kettle is controlled in 300-1000r/min.
<embodiment 1>
A kind of macromolecule environment-friendly materials equipment surface protective agent for equipment surface spraying, it includes each group of following parts by weight
Divide raw material: 8 parts of macromolecule wax, 27.5 parts of propenoic acid resin series, emulsifier tween+sapn+milky white spirit add up to 5 parts, film forming agent
Polyvinyl alcohol (PVA) and Lauryl Alcohol rouge is 4 parts total, 0.1 part of quick dry agent, 0.1 part of water-soluble silicon oil and 55 parts of pure water.
<embodiment 2>
A kind of macromolecule environment-friendly materials equipment surface protective agent for equipment surface spraying, it includes each group of following parts by weight
Divide raw material: 10 parts of macromolecule wax, 25.5 parts of propenoic acid resin series, emulsifier tween and sapn add up to 4.5 parts, film forming agent PVP-
K30 and acrylic amine copolymer DC-79 is 4 parts total, 0.2 part of quick dry agent, 0.1 part of water-soluble silicon oil and 56 parts of pure water.
<embodiment 3>
A kind of macromolecule environment-friendly materials equipment surface protective agent for equipment surface spraying, it includes each group of following parts by weight
Divide raw material: 10 parts of macromolecule wax lotion, 75 parts of propenoic acid resin series lotion, film forming agent PVP-K30 and Lauryl Alcohol rouge total 5
Part, 0.2 part of quick dry agent, 0.1 part of water-soluble silicon oil and 10 parts of pure water.
<embodiment 4>
A kind of macromolecule environment-friendly materials equipment surface protective agent for equipment surface spraying, it includes each group of following parts by weight
Divide raw material: 10 parts of macromolecule wax lotion, 78 parts of propenoic acid resin series lotion, film forming agent PVP-K30 and Lauryl Alcohol rouge are total
7 parts, 0.2 part of quick dry agent, 0.1 part of water-soluble silicon oil and 5 parts of pure water.
<experimental test data>
Using the product of embodiment 1-4 as test product, its main indicator is tested.
Product main indicator
* pH value detects: solution being prepared to 10% aqueous solution, is soaked and is developed the color with standard PH test paper.
After metal surface is sprayed protection sealing wax by *, after natural drying, soak at room temperature is in 15% salt water, storage 30
It as passes through without the scar area that gets rusty or get rusty no more than 1%.
Annex -1
Sealing wax is protected to spray measuring method
Main contents: our law regulation measurement protection sealing wax spraying effect, the coating film forming of protection sealing wax when range estimation sprays
Whether uniformly, whether there is or not trickling, the case where drying time and surface smoothness.
Equipment and material:
The pitch-dark steel plate of 1mm thickness 2m2: one piece；
Portable spray gun: one；
500ml: one；
Tap water: 5Kg；
The sample of blending send analysis, while doing spray test and quick-drying into film test.
It takes sample about 100ml, places in spray gun tank, closed good, on the steel plate by sample even application, area has 0.2 flat
Square rice or so.
Observation:
It whether uniform forms a film, whether there is or not hang flow phenomenon.
Spray time is recorded, the speed (time) (generally at 10~120 minutes) of quick-drying is investigated,
Parching property (estimates no thaw melting point), touches wiping with hand, and surface is smooth, and hard, non-scale is preferred.
By multiple recipe determination, above-described embodiment passes through laboratory simulation experiment, and embodiment 1,2,3,4 formula is equal
Meet the requirements, from spraying effect, to film low-temperature resistance, heat-resisting ability,
Test data:
Protective agent (film) main adsorption capacity is fine, and emphasis has done emphasis to weatherability (season of summer and winter) from use process and examined
Consider, main toughness, high temperature resistant, low temperature capability and the Fast curing (meeting pipelining) etc. for showing film.
Investigate influence to coated film by auxiliary agent A of emulsifier, be specifically shown in Fig. 1, from Fig. 1 curvilinear trend can be seen that with
Coalescing agent A additional amount increase, the tensile elongation of coated film increases, and elasticity is obviously improved.Illustrate to add auxiliary agent A, coating is tough
Property improves.
The influence to spray-coating surface quick-drying is investigated by auxiliary agent B of film forming agent, figure -2 is seen, can be seen that and help from Fig. 2 curvilinear trend
- 2 additional amount of agent increases, and quick-drying time change is little, while influencing viscosity and cost.
It investigates by auxiliary agent C of quick dry agent to viscosity influence, sees figure -3, can be seen that from Fig. 3 tracing pattern with auxiliary agent C
Additional amount increase, the decline of the viscosity of protective agent, viscosity film destructible less than normal is imperfect, and viscosity is excessive to be unfavorable for spraying.
Protective agent is sprayed on steel plate and steel plate oil paint surface, is stored 1000 hours in -18 DEG C of situations, there is no de-
Phenomena such as mould, slight crack or peeling fall off.The steel plate sample of spraying is placed in baking oven and does heatproof test, as temperature constantly rises
Height is to have slightly touch with one's hand phenomenon, very 90 DEG C of steady temperature when oven temperature reaches 60 DEG C, 4 hours, still touches with one's hand, but do not melt
Phenomenon, adsorptivity are extremely strong.
By above-mentioned test, determines embodiment 3,4 formulas, spray on automobile assembly line, sprayed on the spot in Various Seasonal
Vehicle frame surface is applied, spraying is best, and requirement of actual working condition is fully achieved in effect.Spray the more uniform (hand spray of thickness.Workpiece surface
It is uneven whole), the quick-drying time is fine to equipment protection antirust ability in 5-40 minutes.
Claims (9)
1. a kind of macromolecule environment-friendly materials protective agent for equipment surface spraying, it is characterised in that it includes following parts by weight
Each component raw material: 5-30 parts of macromolecule emulsion wax, 30-80 parts of resin emulsion, 3-10 parts of emulsifier, 3-10 parts of film forming agent, quick-drying
0.5-3 parts of agent, 0-1 parts of modified silicon oil and distillation appropriate amount of water.
2. a kind of macromolecule environment-friendly materials protective agent for equipment surface spraying according to claim 1, feature exist
The emulsifier for accounting for its quality 3%-10% is added after being that macromolecule wax is heated to 80-90 DEG C of temperature in the macromolecule emulsion wax,
60-90min is stirred, mixing speed 250-350r/min makes it become emulsion state, obtains macromolecule emulsion wax；The height
Molecular wax is polyethylene wax, No. 80 microwaxes, any one in No. 85 microwaxes.
3. a kind of macromolecule environment-friendly materials protective agent for equipment surface spraying according to claim 1, feature exist
In the resin emulsion be emulsion acrylic resin.
4. -2 described in any item a kind of macromolecule environment-friendly materials protective agents for equipment surface spraying according to claim 1,
It is characterized in that the emulsifier be octadecylamine, milky white spirit, sapn, in tween any one or more is compound.
5. a kind of macromolecule environment-friendly materials protective agent for equipment surface spraying according to claim 1, feature exist
In the film forming agent be PVP-K30, PVP-K90, acrylic amine copolymer DC-79, polyvinyl alcohol (PVA), in Lauryl Alcohol rouge
Any one or more is compound.
6. a kind of macromolecule environment-friendly materials protective agent for equipment surface spraying according to claim 1, feature exist
In the modified silicon oil be 204 water soluble polyether modified silicon oils.
7. a kind of macromolecule environment-friendly materials protective agent for equipment surface spraying according to claim 1, feature exist
In the quick dry agent be water-based zinc stearate.
8. a kind of preparation side of macromolecule environment-friendly materials protective agent for equipment surface spraying according to claim 1
Method, it is characterised in that the following steps are included: the macromolecule emulsion wax and resin emulsion of above-mentioned parts by weight are packed into reconciliation kettle, open
Stirring and heating makes reconciliation temperature in the kettle reach 40-50 DEG C, and the emulsifier of above-mentioned parts by weight is then added and stirs 1-1.5h, then
Film forming agent, quick dry agent, modified silicon oil and the distilled water for adding above-mentioned parts by weight continue to stir 1-2h, then stop heating wait adjust
It discharges after being down to room temperature with temperature in the kettle, obtains the high polymer elastic environment-friendly materials equipment surface protective agent.
9. a kind of preparation side of macromolecule environment-friendly materials protective agent for equipment surface spraying according to claim 8
Method, it is characterised in that the mixing speed for reconciling kettle is controlled in 300-1000r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910057637.7A CN109825150A (en) | 2019-01-22 | 2019-01-22 | A kind of macromolecule environmental-protection agent and preparation method thereof for equipment surface spraying |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910057637.7A CN109825150A (en) | 2019-01-22 | 2019-01-22 | A kind of macromolecule environmental-protection agent and preparation method thereof for equipment surface spraying |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109825150A true CN109825150A (en) | 2019-05-31 |
Family
ID=66861774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910057637.7A Pending CN109825150A (en) | 2019-01-22 | 2019-01-22 | A kind of macromolecule environmental-protection agent and preparation method thereof for equipment surface spraying |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109825150A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1478837A (en) * | 2003-03-14 | 2004-03-03 | 杨卫宁 | New type microemulsified paper product water resistant paint and its preparation method |
| CN103173124A (en) * | 2013-03-02 | 2013-06-26 | 富莱茵汽车部件有限公司 | Metal rustproof wax using emulsifying wax as main body and preparation method thereof |
| CN106120349A (en) * | 2016-08-01 | 2016-11-16 | 太仓中化环保化工有限公司 | A kind of environment-friendly type abietyl is without fluoro water proofing agent and preparation method thereof |
-
2019
- 2019-01-22 CN CN201910057637.7A patent/CN109825150A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1478837A (en) * | 2003-03-14 | 2004-03-03 | 杨卫宁 | New type microemulsified paper product water resistant paint and its preparation method |
| CN103173124A (en) * | 2013-03-02 | 2013-06-26 | 富莱茵汽车部件有限公司 | Metal rustproof wax using emulsifying wax as main body and preparation method thereof |
| CN106120349A (en) * | 2016-08-01 | 2016-11-16 | 太仓中化环保化工有限公司 | A kind of environment-friendly type abietyl is without fluoro water proofing agent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1153141A (en) | Vinyl acetate copolymer emulsions for paint | |
| KR840000611B1 (en) | Coating composition for protecting inner surface of tubes in heat-exchangers | |
| CN104559617B (en) | A kind of application type aqueous dual-component fluorocarbon coating and its preparation and application | |
| JP5543581B2 (en) | Water-based coating composition and coating film forming method | |
| JP2680508B2 (en) | Water-based paint for constant drying | |
| CN100413936C (en) | Nanometer modified rust-proof top-coat for metal | |
| JP2010070603A (en) | Aqueous rust-preventive coating composition | |
| CN102719126A (en) | Waterborne ultraviolet-heat double-curing polyaniline anticorrosive paint and preparation method thereof | |
| CN109825150A (en) | A kind of macromolecule environmental-protection agent and preparation method thereof for equipment surface spraying | |
| CN101914344A (en) | Non-chrome water-based organic fingerprint-resistant coating and preparation method thereof | |
| CN108588696A (en) | A kind of organic passivation agent without chromium and nickel heavy metal | |
| JP6495221B2 (en) | Sealing agent | |
| CA2151031A1 (en) | A coating composition with heat-curing film formation and its use | |
| CN105907141A (en) | Environment-friendly shop primer and preparation method thereof | |
| KR19980052464A (en) | Preparation of aqueous lubricant resin solution and steel plate surface treatment method | |
| CN106433429A (en) | Electrostatic coating which can be sprayed to form thick film and construction method thereof | |
| KR20080093786A (en) | High corrosion resistance anticorrosive coating composition for automobile steel parts | |
| CN111849289A (en) | Water-based anticorrosive paint and preparation method and application thereof | |
| KR100388895B1 (en) | Process for producing High Corrosion, Anti-Finger Printer Resin having excellent Formability and Anti-corrosion | |
| JP2670804B2 (en) | Coating composition | |
| CN103360912B (en) | A kind of metal protection coating and uses thereof and hot-dip metal plated material | |
| CN105950017B (en) | Special container bottom antirust asphalt caulk | |
| CN112795260B (en) | A kind of water-based rust conversion shielding coating and preparation method thereof | |
| CN108822646A (en) | Height adheres to the preparation method of aqueous environmental protection floor coating | |
| TWI764677B (en) | Lubricant additive for coating with oxidation resistance at high temperature and method of using same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190531 |
|
| WD01 | Invention patent application deemed withdrawn after publication |