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CN109963208A - An audio device with high buoyancy - Google Patents

An audio device with high buoyancy Download PDF

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Publication number
CN109963208A
CN109963208A CN201910218968.4A CN201910218968A CN109963208A CN 109963208 A CN109963208 A CN 109963208A CN 201910218968 A CN201910218968 A CN 201910218968A CN 109963208 A CN109963208 A CN 109963208A
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casing
audio device
hollow glass
buoyancy
audio
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王远昌
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Luo Yinhao
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Shenzhen Shenghong Innovation Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R1/00Details of transducers, loudspeakers or microphones
    • H04R1/02Casings; Cabinets ; Supports therefor; Mountings therein

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Signal Processing (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了音频设备技术领域中的一种具有高浮力的音频装置,包括外壳和设于外壳内的音频播放系统,外壳包括上壳体、下壳体及底座,上壳体内设有播音腔,下壳体上端与上壳体密封连接,下壳体内设有浮力腔,下壳体包括防水外壳和设于防水外壳内侧的浮力体,防水外壳的外侧涂布有疏水材料,底座的上端与下壳体密封连接,音频播放系统固定在底座上。本发明能在保证正常播放音频信息的基础上,配合使用者在意外溺水的情况下进行救生支援,整体产品结构稳定、成本低。

The invention discloses an audio device with high buoyancy in the technical field of audio equipment, comprising a casing and an audio playing system arranged in the casing. , the upper end of the lower casing is sealed with the upper casing, the lower casing is provided with a buoyancy chamber, the lower casing includes a waterproof casing and a buoyancy body arranged on the inner side of the waterproof casing, the outer side of the waterproof casing is coated with hydrophobic material, and the upper end of the base and The lower shell is sealed and connected, and the audio playback system is fixed on the base. The present invention can cooperate with the user to provide life-saving support in the case of accidental drowning on the basis of ensuring the normal playback of audio information, and the overall product structure is stable and the cost is low.

Description

一种具有高浮力的音频装置An audio device with high buoyancy

技术领域technical field

本发明涉及音频设备技术领域,具体的说,是涉及一种具有高浮力的音频装置。The invention relates to the technical field of audio equipment, in particular to an audio device with high buoyancy.

背景技术Background technique

游泳是人们喜爱的一项娱乐活动,也是一项很值得推荐的运动,在游泳的同时,全身的肌肉都可以得到运动,血液循环也会更加顺畅,对维持身体的健康有较大帮助。但是游泳溺亡的事故多有发生。据儿童安全数据显示,溺水事故和交通事故成为中小学生最大死亡杀手,溺水和交通事故死亡分别占死亡人数的43.59%和30.26%,每年近3万儿童死于溺水,其已成为学生非正常死亡的头号杀手。Swimming is a favorite recreational activity, and it is also a highly recommended exercise. While swimming, the muscles of the whole body can be exercised, and the blood circulation will be smoother, which is of great help to maintain the health of the body. But swimming drowning accidents happen more often. According to child safety data, drowning accidents and traffic accidents have become the biggest killers of primary and secondary school students. Drowning and traffic accidents account for 43.59% and 30.26% of the death toll respectively. Nearly 30,000 children die from drowning every year, which has become an abnormal death of students. the number one killer.

另外,人们在游泳过程中,常配合使用音箱进行音乐播放,现在市场上也为水上活动爱好者推出了进行音乐回放的无线音箱,能满足使用者在海滩、泳池、淋浴、冲浪、户外享受音乐。但是现在市场上的音箱外壳采用硅胶物料或其他普通塑料,其浮力仅能维持自身的浮力需求,而不能辅助使用者在溺水时进行自救,无法实现更佳的浮力需求。In addition, people often use speakers to play music during swimming. Now, wireless speakers for music playback have also been launched on the market for water sports enthusiasts, which can meet the needs of users to enjoy music at the beach, swimming pool, shower, surfing, and outdoors. . However, the current speaker shells on the market are made of silicone materials or other ordinary plastics, and their buoyancy can only maintain their own buoyancy requirements, but cannot assist users in self-rescue when drowning, and cannot achieve better buoyancy requirements.

上述缺陷,值得解决。The above shortcomings are worth solving.

发明内容SUMMARY OF THE INVENTION

为了克服现有的技术的不足,本发明提供一种具有高浮力的音频装置,本发明能在保证正常播放音频信息的基础上,配合使用者在意外溺水的情况下进行救生支援,整体产品结构稳定、成本低。In order to overcome the deficiencies of the existing technology, the present invention provides an audio device with high buoyancy. The present invention can cooperate with the user to provide life-saving support in the event of accidental drowning on the basis of ensuring the normal playback of audio information. The overall product structure Stable and low cost.

本发明技术方案如下所述:The technical scheme of the present invention is as follows:

一种具有高浮力的音频装置,包括外壳和设于所述外壳内的音频播放系统,其特征在于,所述外壳包括:An audio device with high buoyancy, comprising a casing and an audio playback system arranged in the casing, wherein the casing comprises:

上壳体,所述上壳体内设有播音腔;an upper casing, wherein a broadcasting cavity is arranged in the upper casing;

下壳体,所述下壳体上端与所述上壳体密封连接,所述下壳体内设有浮力腔,所述下壳体包括防水外壳和设于所述防水外壳内侧的浮力体,所述防水外壳的外侧涂布有疏水材料;A lower casing, the upper end of the lower casing is sealed with the upper casing, a buoyancy cavity is arranged in the lower casing, and the lower casing includes a waterproof casing and a buoyancy body arranged on the inner side of the waterproof casing. The outer side of the waterproof shell is coated with a hydrophobic material;

底座,所述底座的上端与所述下壳体密封连接,所述音频播放系统固定在所述底座上。A base, the upper end of the base is sealed with the lower shell, and the audio playback system is fixed on the base.

根据上述方案的本发明,其特征在于,所述防水外壳的底部设有固定孔,所述浮力体的底部穿过所述固定孔后与所述防水外壳扣合连接。The present invention according to the above solution is characterized in that the bottom of the waterproof casing is provided with a fixing hole, and the bottom of the buoyant body passes through the fixing hole and is then fastened and connected to the waterproof casing.

进一步的,所述浮力体的底部外侧套有密封垫,密封螺栓穿过所述密封垫与所述浮力体固定连接。Further, a sealing gasket is sleeved on the outer side of the bottom of the buoyancy body, and a sealing bolt passes through the sealing gasket and is fixedly connected to the buoyancy body.

根据上述方案的本发明,其特征在于,所述音频播放系统包括控制器、电池模块及至少一个扬声器,所述控制器分别与所述电池模块、所述扬声器电连接;所述控制器和所述电池模块设于所述浮力腔内,所述扬声器设于所述播音腔内。The present invention according to the above solution is characterized in that the audio playback system includes a controller, a battery module and at least one speaker, the controller is electrically connected to the battery module and the speaker respectively; The battery module is arranged in the buoyancy cavity, and the speaker is arranged in the broadcasting cavity.

根据上述方案的本发明,其特征在于,所述上壳体的顶部设有太阳能电源板,所述太阳能电源板为所述电池模块供电。The present invention according to the above solution is characterized in that a solar power panel is provided on the top of the upper casing, and the solar power panel supplies power to the battery module.

根据上述方案的本发明,其特征在于,所述外壳的外侧固定有安全带。The present invention according to the above aspect is characterized in that a safety belt is fixed on the outer side of the outer casing.

根据上述方案的本发明,其特征在于,所述疏水材料通过粘结剂涂覆在所述防水外壳的表面。The present invention according to the above aspect is characterized in that, the hydrophobic material is coated on the surface of the waterproof casing by an adhesive.

进一步的,所述粘结剂为树脂。Further, the binder is resin.

根据上述方案的本发明,其特征在于,在所述疏水材料制备的过程中,先制备纳米SiO2溶胶;后以氨丙基三乙氧基硅烷与γ-二乙烯三胺丙基甲基二甲氧基硅烷作为纳米SiO2溶胶的团聚剂,构建微纳米的粗糙结构;采用十六烷基三甲氧基硅烷进行颗粒疏水改性;通过粘结剂进行粘结,制备得到疏水性能良好的超疏水复合材料。The present invention according to the above scheme is characterized in that, in the process of preparing the hydrophobic material, nano-SiO 2 sol is prepared first; Methoxysilane is used as agglomeration agent of nano-SiO 2 sol to build micro-nano rough structure; hexadecyltrimethoxysilane is used for particle hydrophobic modification; bonded by binder, super-hydrophobicity with good hydrophobicity is prepared. Hydrophobic composite.

进一步的,以正硅酸乙酯为原料,通过溶胶-凝胶法制备得到所述纳米SiO2溶胶。Further, using ethyl orthosilicate as a raw material, the nano-SiO 2 sol is prepared by a sol-gel method.

根据上述方案的本发明,其特征在于,所述浮力体以环氧树脂和空心玻璃微珠为原料制备而成,且所述环氧树脂占原料的质量比为2-10%,所述空心玻璃微珠占原料的质量比为90-98%。The present invention according to the above scheme is characterized in that the buoyant body is prepared by using epoxy resin and hollow glass microspheres as raw materials, and the mass ratio of the epoxy resin to the raw materials is 2-10%. The mass ratio of glass beads to raw materials is 90-98%.

根据上述方案的本发明,其特征在于,在制备所述浮力体的过程中,具体包括以下步骤:The present invention according to the above scheme is characterized in that, in the process of preparing the buoyant body, the following steps are specifically included:

(1)首先对空心玻璃微珠进行筛选和表面处理;(1) First, the hollow glass beads are screened and surface treated;

(2)将处理后的空心玻璃微珠分次加入到改性UPR中,并在真空状态下进行搅拌;(2) Add the treated hollow glass microspheres to the modified UPR in stages, and stir in a vacuum state;

(3)先后加入助固化剂和固化剂,并进行真空搅拌;(3) Add co-curing agent and curing agent successively, and conduct vacuum stirring;

(4)将搅拌后的混合物浇注于模具中,并将模具置于一定温度中固化;(4) Pour the stirred mixture into a mold, and place the mold at a certain temperature to solidify;

(5)将固化后的半成品进行高温熟化;(5) Curing the cured semi-finished products at high temperature;

(6)冷却后脱模,并经过后处理得到高强度的浮力体。(6) Demoulding after cooling, and post-processing to obtain a high-strength buoyant body.

进一步的,在所述步骤(1)中,将所述空心玻璃微珠进行抗压筛选,后放入配置好的硅烷偶联剂溶液中进行表面处理。Further, in the step (1), the hollow glass microspheres are subjected to compression screening, and then put into the prepared silane coupling agent solution for surface treatment.

更进一步的,所述硅烷偶联剂溶液占所述空心玻璃微珠质量的0.5-1.5%。Further, the silane coupling agent solution accounts for 0.5-1.5% of the mass of the hollow glass microspheres.

更进一步的,所述硅烷偶联剂溶液由硅烷、醇及水混合而成,其中硅烷、醇及水所占质量百分百分别为20%、72%、8%。Further, the silane coupling agent solution is formed by mixing silane, alcohol and water, wherein the mass percentages of silane, alcohol and water are 20%, 72% and 8% respectively.

更进一步的,所述醇包括乙醇、甲醇及异丙醇。Further, the alcohol includes ethanol, methanol and isopropanol.

进一步的,在所述步骤(3)中,所述助固化剂为环烷酸钴促进剂,所述固化剂为过氧化甲乙酮固化剂。Further, in the step (3), the co-curing agent is a cobalt naphthenate accelerator, and the curing agent is a methyl ethyl ketone peroxide curing agent.

根据上述方案的本发明,其有益效果在于,本发明通过涂覆疏水材料,使得防水外壳能够充分实现疏水功能,使表面具有极强的疏水、憎水、防水效果;本发明在防水外壳内锁何止浮力体,能够提供更高的浮力,在保证音频装置本身的浮力情况下,为使用者提供辅助浮力,辅助其进行溺水自救,提供了更高的安全保障;本发明整体结构紧凑、稳定,不易损坏,同时能够充分降低原料成本。According to the present invention according to the above scheme, the beneficial effect of the present invention is that, by coating the hydrophobic material, the waterproof casing can fully realize the hydrophobic function, so that the surface has extremely strong hydrophobic, hydrophobic and waterproof effects; the present invention is locked in the waterproof casing. More than a buoyant body, it can provide higher buoyancy, and under the condition of ensuring the buoyancy of the audio device itself, it can provide auxiliary buoyancy for users to assist them in drowning self-rescue, and provide a higher safety guarantee; the overall structure of the present invention is compact and stable, It is not easy to be damaged, and can fully reduce the cost of raw materials.

附图说明Description of drawings

图1为本发明的结构示意图。FIG. 1 is a schematic structural diagram of the present invention.

图2为图1中Ⅰ部分的放大图。FIG. 2 is an enlarged view of part I in FIG. 1 .

图3为发明中制备浮力体的流程图。Fig. 3 is a flow chart of preparing a buoyant body in the invention.

在图中,11、防水外壳;12、浮力体;13、上壳体;14、底座;20、密封螺栓;21、密封垫;31、浮力腔;32、播音腔;41、控制器;42、电池模块;43、扬声器;44、太阳能电源板。In the figure, 11, waterproof casing; 12, buoyant body; 13, upper casing; 14, base; 20, sealing bolt; 21, gasket; 31, buoyancy chamber; 32, broadcasting chamber; 41, controller; 42 , battery module; 43, speaker; 44, solar power panel.

具体实施方式Detailed ways

下面结合附图以及实施方式对本发明进行进一步的描述:The present invention will be further described below in conjunction with the accompanying drawings and embodiments:

如图1所示,一种具有高浮力的音频装置,包括外壳和设于外壳内的音频播放系统,音频播放系统包括控制器41、电池模块42及至少一个扬声器43,控制器41分别与电池模块42、扬声器43电连接。As shown in FIG. 1, an audio device with high buoyancy includes a housing and an audio playback system arranged in the housing. The audio playback system includes a controller 41, a battery module 42 and at least one speaker 43. The controller 41 is connected to the battery respectively. The module 42 and the speaker 43 are electrically connected.

外壳包括上壳体13、下壳体及底座14,其中,上壳体内设有播音腔32,扬声器43设于播音腔35内;下壳体上端与上壳体13密封连接,下壳体内设有浮力腔31,控制器41和电池模块42设于浮力腔31内,下壳体包括防水外壳11和设于防水外壳11内侧的浮力体12;底座14的上端与下壳体密封连接,音频播放系统固定在底座14上。The outer shell includes an upper shell 13, a lower shell and a base 14, wherein the upper shell is provided with a broadcasting cavity 32, and the speaker 43 is arranged in the broadcasting cavity 35; the upper end of the lower shell is sealed with the upper shell 13, and the lower shell is provided with There is a buoyancy chamber 31, the controller 41 and the battery module 42 are arranged in the buoyancy chamber 31, the lower casing includes a waterproof casing 11 and a buoyancy body 12 arranged inside the waterproof casing 11; the upper end of the base 14 is sealed with the lower casing. The playback system is fixed on the base 14 .

控制器41内设有存储单元、音频处理单元及电源控制单元,音频处理单元分别与扬声器、存储单元及电源控制单元连接,电源控制单元与电池模块连接。在控制器内部,音频信号的具体处理过程可采用现有常用的处理方式,其并非本发明的改进部分,故此不再详细描述。The controller 41 is provided with a storage unit, an audio processing unit and a power supply control unit. The audio processing unit is respectively connected with the speaker, the storage unit and the power supply control unit, and the power supply control unit is connected with the battery module. Inside the controller, the specific processing process of the audio signal can adopt the existing common processing method, which is not an improved part of the present invention, so it will not be described in detail.

如图2所示,防水外壳11的底部设有固定孔,浮力体12的底部穿过固定孔后与防水外壳11扣合连接,浮力体12的底部外侧套有密封垫21,密封螺栓20穿过密封垫21与浮力体12固定连接。通过防水外壳11、浮力体12及底座14的密封固定,保证整个音频装置的密封效果,且增加整个产品的结构稳定性。As shown in FIG. 2 , the bottom of the waterproof casing 11 is provided with a fixing hole, the bottom of the buoyancy body 12 is connected with the waterproof casing 11 after passing through the fixing hole. The over-sealing gasket 21 is fixedly connected with the buoyancy body 12 . Through the sealing and fixing of the waterproof casing 11 , the buoyancy body 12 and the base 14 , the sealing effect of the entire audio device is ensured, and the structural stability of the entire product is increased.

防水外壳11的外侧涂布有疏水材料,疏水材料在防水外壳11外侧形成一层抗水层,其疏水角≥160°,使防水外壳11表面具有极强的疏水、憎水、防水效果。在疏水材料制备的过程中:The outer side of the waterproof casing 11 is coated with a hydrophobic material, and the hydrophobic material forms a water-resistant layer on the outer side of the waterproof casing 11, and its hydrophobic angle is ≥160°, so that the surface of the waterproof casing 11 has strong hydrophobic, hydrophobic and waterproof effects. During the preparation of hydrophobic materials:

1、先制备纳米SiO2溶胶(以正硅酸乙酯为原料,通过溶胶-凝胶法制备得到纳米SiO2溶胶);1. First prepare nano-SiO 2 sol (using ethyl orthosilicate as raw material, prepare nano-SiO 2 sol by sol-gel method);

2、后以氨丙基三乙氧基硅烷与γ-二乙烯三胺丙基甲基二甲氧基硅烷作为纳米SiO2溶胶的团聚剂,构建微纳米的粗糙结构;2. After that, aminopropyltriethoxysilane and γ-diethylenetriaminopropylmethyldimethoxysilane are used as agglomeration agents for nano-SiO 2 sol to construct a micro-nano rough structure;

3、采用十六烷基三甲氧基硅烷进行颗粒疏水改性;3. Use hexadecyltrimethoxysilane for particle hydrophobic modification;

4、以树脂为粘结剂,制备得到疏水性能良好的超疏水复合材料。4. Using resin as a binder, a superhydrophobic composite material with good hydrophobic properties was prepared.

疏水材料通过粘结剂涂覆在防水外壳的表面,粘结剂优选为树脂,提高涂层与基材之间的附着力。The hydrophobic material is coated on the surface of the waterproof casing through an adhesive, and the adhesive is preferably a resin, so as to improve the adhesion between the coating and the substrate.

浮力体以环氧树脂和空心玻璃微珠为原料制备而成,环氧树脂占原料的质量比为2-10%,空心玻璃微珠占原料的质量比为90-98%。空心玻璃微珠之间通过环氧树脂粘结在一起,帮助空心玻璃微珠相互支撑,因此环氧树脂不仅起粘接、支撑玻璃微珠的作用,而且也决定了浮力体的电性能、热性能和化学稳定性;同时,空心玻璃微珠的质量占比能最大程度上增加浮力体的浮力。The buoyant body is prepared by using epoxy resin and hollow glass microspheres as raw materials. The mass ratio of epoxy resin to raw materials is 2-10%, and the mass ratio of hollow glass microspheres to raw materials is 90-98%. The hollow glass beads are bonded together by epoxy resin, which helps the hollow glass beads to support each other. Therefore, the epoxy resin not only plays the role of bonding and supporting the glass beads, but also determines the electrical properties and thermal properties of the buoyant body. performance and chemical stability; at the same time, the mass ratio of hollow glass beads can maximize the buoyancy of the buoyant body.

本发明采用环氧树脂作为浮力体的原料之一,其具有以下特性:The present invention adopts epoxy resin as one of the raw materials of the buoyant body, and it has the following characteristics:

(1)粘结强度高、粘结面广(1) High bonding strength and wide bonding surface

环氧树脂的结构中具有羟基、醚键和活性极大的环氧基,它们使环氧树脂的分子和相邻界面产生电磁吸附或化学键,尤其是环氧基又能在固化剂作用下发生交联聚合反应生成三维网状结构的大分子,分子本身有一定的内聚力。The epoxy resin has hydroxyl, ether bonds and extremely active epoxy groups in the structure, which make the molecules of the epoxy resin and adjacent interfaces produce electromagnetic adsorption or chemical bonds, especially the epoxy groups can also occur under the action of the curing agent. The cross-linking polymerization reaction generates macromolecules with a three-dimensional network structure, and the molecules themselves have a certain cohesive force.

因此环氧树脂与绝大多数的金属和非金属都具有良好的粘接性,它与许多非金属材料(玻璃、陶瓷等)的粘接强度往往超过材料本身的强度。因此,将其作为浮力体的复合材料基体。Therefore, epoxy resin has good adhesion with most metals and non-metals, and its bonding strength with many non-metallic materials (glass, ceramics, etc.) often exceeds the strength of the material itself. Therefore, it is used as the composite matrix of the buoyant body.

(2)收缩率低(2) Low shrinkage

环氧树脂的固化主要是依靠环氧基的开环加成聚合,因此固化过程中不产生低分子物质;另外,环氧树脂本身具有仲羟基,再加上环氧基固化时派生的部分残留羟基,它们的氢键缔合作用使分子排列紧密,因此环氧树脂的固化收缩率是热固性树脂中最低的品种之一(一般为1-2%,如果选用适当的填料可使收缩率降至0.2%左右)。The curing of epoxy resin mainly relies on the ring-opening addition polymerization of epoxy groups, so no low molecular weight substances are produced during the curing process; in addition, epoxy resin itself has secondary hydroxyl groups, plus some residues derived from epoxy groups when curing Hydroxyl groups, their hydrogen bond associations make the molecules closely arranged, so the curing shrinkage of epoxy resins is one of the lowest among thermosetting resins (usually 1-2%, if appropriate fillers are used, the shrinkage can be reduced to 0.2% or so).

(3)稳定性好(3) Good stability

固化后的环氧树脂主链是醚键和苯环,三维交联结构致密又封闭,因此它既耐酸又耐碱,耐腐蚀性能优于酚醛树脂和聚酯树脂。在20-40℃的海水中使用24个月,材料不受破坏。The main chain of the cured epoxy resin is ether bond and benzene ring, and the three-dimensional cross-linking structure is dense and closed, so it is resistant to acid and alkali, and its corrosion resistance is better than that of phenolic resin and polyester resin. The material is not damaged when used in seawater at 20-40℃ for 24 months.

(4)优良的电绝缘性(4) Excellent electrical insulation

固化后的环氧树脂吸水率低,不再具有活性基团和游离的离子,因此具有优异的电绝缘性。The cured epoxy resin has low water absorption and no longer has active groups and free ions, so it has excellent electrical insulation.

(5)机械强度高(5) High mechanical strength

固化后的环氧树脂具有很强的内聚力,而分子结构致密,所以它的机械强度相对高于酚醛树脂和聚酯树脂。The cured epoxy resin has strong cohesion and dense molecular structure, so its mechanical strength is relatively higher than that of phenolic resin and polyester resin.

(6)良好的加工性能(6) Good processing performance

环氧树脂具有较高的灵活性,其加工工艺和制品性能具有多样性。Epoxy resin has high flexibility, and its processing technology and product properties are diverse.

本发明采用空心玻璃微珠为浮力体的原料之一,其质量对材料的性能起着决定性作用。空心玻璃微珠是一种新型的轻质非金属多功能材料,它的直径在数微米和数百微米之间,外观为灰白或灰色,松散,流动性好。其中无机空心微珠中最常用的是空心玻璃微珠。The invention adopts hollow glass microspheres as one of the raw materials of the buoyant body, and its quality plays a decisive role in the performance of the material. Hollow glass microspheres are a new type of lightweight non-metallic multi-functional material. Its diameter is between several microns and hundreds of microns, and the appearance is gray or gray, loose and good fluidity. Among them, the most commonly used inorganic hollow microbeads are hollow glass microbeads.

空心玻璃微珠呈球形,其是自然界中相同体积下表面积最小的形状,因此空心玻璃微珠具有抗压强度高、熔点高、电阻率高、热传导系数和热收缩系数小等特点。空心玻璃微珠具有以下特性:Hollow glass microspheres are spherical, which is the shape with the smallest surface area under the same volume in nature. Therefore, hollow glass microspheres have the characteristics of high compressive strength, high melting point, high resistivity, small thermal conductivity and thermal shrinkage coefficient. Hollow glass microspheres have the following properties:

(1)空心玻璃微珠密度较小,堆积密度0.1-0.3g/cm3,实际密度约为0.1-0.5 g/cm3,作为填料可以显著降低材料的密度,从而制备低密度复合材料,进而提供更高的浮力。(1) The density of hollow glass microspheres is small, the bulk density is 0.1-0.3 g/cm 3 , and the actual density is about 0.1-0.5 g/cm 3 . As a filler, the density of the material can be significantly reduced, thereby preparing low-density composite materials, and then Provides higher buoyancy.

(2)空心玻璃微珠形状光滑圆整,具有等向性,无尖锐边角,因此没有应力高度集中现象,可以有效防止应力开裂。与其它形状的填料相比,球形微珠比表面积最小。(2) The hollow glass microspheres are smooth and round in shape, isotropic, without sharp corners, so there is no high stress concentration phenomenon, which can effectively prevent stress cracking. Compared with other shaped fillers, spherical microbeads have the smallest specific surface area.

(3)由于玻璃微珠圆滑又具有相当大的抗压碎性能,故固化反应体系的粘度不会很大,对捏合机、模具成型机的磨损很小,在流道和模具内的流动性好。(3) Since the glass microspheres are smooth and have considerable crush resistance, the viscosity of the curing reaction system will not be very large, the wear on the kneader and the mold forming machine is very small, and the fluidity in the runner and the mold is small. it is good.

(4)空心玻璃微珠的膨胀系数小,在树脂中分散性好,且各向同性,因此可以有效地减少制品收缩,防止因残余应变所造成的制品弯曲、翘曲变形等,有利于提高浮力体的稳定性。(4) The expansion coefficient of hollow glass microspheres is small, the dispersibility in the resin is good, and it is isotropic, so it can effectively reduce the shrinkage of the product and prevent the bending and warping of the product caused by the residual strain, which is conducive to improving the The stability of the buoyant body.

(5)空心玻璃微珠化学稳定性高,具有耐酸碱、抗辐射性能。(5) Hollow glass microspheres have high chemical stability, acid and alkali resistance and radiation resistance.

(6)堆积密度很小,作为聚合物填充材料,较其它矿物填料用量少、装载重量小,节省聚合物用量,因此可降低产品成本。(6) The bulk density is very small. As a polymer filling material, it is less used than other mineral fillers, and the loading weight is small, which saves the amount of polymer, so it can reduce the cost of the product.

另外,空心玻璃还具有一下特性:热稳定性好、阻燃、热分解温度大于1450℃、不易变形,作为聚合物填充材料,可提高聚合物的阻燃特性,可用于建筑材料和油漆行业中;电绝缘性好,可用于各种电气开关设备、仪表板、电子封装材料的填料;透明性好,可用于制造半透明制品,玻璃微珠还能吸收紫外线,提高制品的光稳定性和光反射性。In addition, hollow glass also has the following characteristics: good thermal stability, flame retardant, thermal decomposition temperature greater than 1450 ℃, not easy to deform, as a polymer filling material, it can improve the flame retardant properties of polymers, and can be used in building materials and paint industries. ; Good electrical insulation, can be used as filler for various electrical switchgear, instrument panels, electronic packaging materials; good transparency, can be used to manufacture translucent products, glass beads can also absorb ultraviolet rays, improve the light stability and light reflection of products sex.

如图3所示,在制备浮力体的过程中,具体包括以下步骤:As shown in Figure 3, in the process of preparing the buoyant body, the following steps are specifically included:

1、首先对空心玻璃微珠进行筛选和表面处理。1. First, the hollow glass beads are screened and surface treated.

将空心玻璃微珠进行抗压筛选,后放入配置好的硅烷偶联剂溶液中进行表面处理。其中,硅烷偶联剂溶液由硅烷、醇及水混合而成,其中硅烷、醇及水所占质量百分百分别为20-25%、60-75%、5-10%(优选为20%、72%、8%)。The hollow glass microspheres are subjected to compression screening, and then put into the prepared silane coupling agent solution for surface treatment. Wherein, the silane coupling agent solution is formed by mixing silane, alcohol and water, wherein the mass percentages of silane, alcohol and water are respectively 20-25%, 60-75%, 5-10% (preferably 20%) , 72%, 8%).

优选的,醇包括乙醇、甲醇及异丙醇。其中选用乙醇,形成对乙氧基硅烷;选用甲醇,形成对甲氧基硅烷;选用异丙醇,形成对不易溶于乙醇、甲醇的硅烷。Preferably, the alcohol includes ethanol, methanol and isopropanol. Among them, ethanol is selected to form p-ethoxysilane; methanol is selected to form p-methoxysilane; isopropanol is selected to form a silane that is not easily soluble in ethanol and methanol.

本实施例中,硅烷偶联剂溶液占空心玻璃微珠质量的0.5-1.5%,能够改善处理后空心玻璃微珠在环氧树脂中的分散性及粘合力,改善无机填料与环氧树脂之间的相容性,改善工艺性能和提高填充塑料(包括橡胶)的机械、电学和耐气候等性能。In this embodiment, the silane coupling agent solution accounts for 0.5-1.5% of the mass of the hollow glass beads, which can improve the dispersibility and adhesion of the treated hollow glass beads in the epoxy resin, and improve the inorganic filler and epoxy resin. Compatibility, improve process performance and improve mechanical, electrical and weather resistance of filled plastics (including rubber).

2、在环氧树脂中增加改性剂,降低固化收缩率、提高阻燃耐热性能、增强增韧、耐腐蚀等。2. Add modifier in epoxy resin to reduce curing shrinkage, improve flame retardant and heat resistance, strengthen toughening, corrosion resistance, etc.

后将处理后的空心玻璃微珠分次加入到改性UPR(即不饱和聚酯树脂)中,并在真空状态下进行搅拌。搅拌速度随体系黏度的大小调节,并控制好真空度,搅拌30 min。Afterwards, the treated hollow glass microspheres were added to the modified UPR (ie, unsaturated polyester resin) in stages, and were stirred in a vacuum state. The stirring speed was adjusted according to the viscosity of the system, and the vacuum degree was controlled, and the stirring was carried out for 30 min.

3、先加入助固化剂(优选为环烷酸钴促进剂,其用量为环氧树脂质量的1-2%),真空搅拌10 min;加入后固化剂(优选为过氧化甲乙酮固化剂,其用量为环氧树脂质量的2-4%),真空搅拌10 min。3. First add co-curing agent (preferably cobalt naphthenate accelerator, the amount of which is 1-2% of the mass of epoxy resin), and stir in vacuum for 10 min; add post-curing agent (preferably methyl ethyl ketone peroxide curing agent, its The dosage is 2-4% of the mass of epoxy resin), and vacuum stirring for 10 min.

4、将搅拌后的混合物浇注于模具中,并将模具置于一定温度(优选为100-105℃)中固化。4. Pour the stirred mixture into a mold, and place the mold at a certain temperature (preferably 100-105°C) to solidify.

5、将固化后的半成品进行高温熟化(熟化温度为200℃)。5. Curing the cured semi-finished products at high temperature (curing temperature is 200℃).

6、冷却后脱模,并经过后处理(即去毛刺、修剪溢出部分)得到高强度的浮力体。6. Demoulding after cooling, and post-processing (ie, deburring, trimming the overflow part) to obtain a high-strength buoyant body.

在本实施例中,上壳体的顶部设有太阳能电源板,太阳能电源板为电池模块供电,保证了音频装置能源的稳定。In this embodiment, a solar power panel is provided on the top of the upper casing, and the solar power panel supplies power to the battery module, which ensures the stability of the energy source of the audio device.

在本实施例中,外壳的外侧固定有安全带,使用者在游泳时拴上安全带,为使用者停供娱乐的同时,可为其提供足够的浮力以保障安全。In this embodiment, a safety belt is fixed on the outer side of the outer shell, and the user fastens the safety belt when swimming, so as to provide enough buoyancy for the user to ensure safety while stopping for entertainment.

应当理解的是,对本领域普通技术人员来说,可以根据上述说明加以改进或变换,而所有这些改进和变换都应属于本发明所附权利要求的保护范围。It should be understood that, for those skilled in the art, improvements or changes can be made according to the above description, and all these improvements and changes should fall within the protection scope of the appended claims of the present invention.

上面结合附图对本发明专利进行了示例性的描述,显然本发明专利的实现并不受上述方式的限制,只要采用了本发明专利的方法构思和技术方案进行的各种改进,或未经改进将本发明专利的构思和技术方案直接应用于其它场合的,均在本发明的保护范围内。The patent of the present invention has been exemplarily described above in conjunction with the accompanying drawings. Obviously, the realization of the patent of the present invention is not limited by the above methods, as long as various improvements made by the method concept and technical solutions of the patent of the present invention are adopted, or no improvement is made. It is within the protection scope of the present invention to directly apply the concept and technical solution of the patent of the present invention to other occasions.

Claims (10)

1.一种具有高浮力的音频装置,包括外壳和设于所述外壳内的音频播放系统,其特征在于,所述外壳包括:1. an audio device with high buoyancy, comprising a casing and an audio playback system arranged in the casing, wherein the casing comprises: 上壳体,所述上壳体内设有播音腔;an upper casing, wherein a broadcasting cavity is arranged in the upper casing; 下壳体,所述下壳体上端与所述上壳体密封连接,所述下壳体内设有浮力腔,所述下壳体包括防水外壳和设于所述防水外壳内侧的浮力体,所述防水外壳的外侧涂布有疏水材料;A lower casing, the upper end of the lower casing is sealed with the upper casing, a buoyancy cavity is arranged in the lower casing, and the lower casing includes a waterproof casing and a buoyancy body arranged on the inner side of the waterproof casing. The outer side of the waterproof shell is coated with a hydrophobic material; 底座,所述底座的上端与所述下壳体密封连接,所述音频播放系统固定在所述底座上。A base, the upper end of the base is sealed with the lower shell, and the audio playback system is fixed on the base. 2.根据权利要求1所述的具有高浮力的音频装置,其特征在于,所述音频播放系统包括控制器、电池模块及至少一个扬声器,所述控制器分别与所述电池模块、所述扬声器电连接;所述控制器和所述电池模块设于所述浮力腔内,所述扬声器设于所述播音腔内。2 . The audio device with high buoyancy according to claim 1 , wherein the audio playback system comprises a controller, a battery module and at least one speaker, and the controller is respectively connected with the battery module and the speaker. 3 . Electrical connection; the controller and the battery module are arranged in the buoyancy cavity, and the speaker is arranged in the broadcasting cavity. 3.根据权利要求1所述的具有高浮力的音频装置,其特征在于,所述上壳体的顶部设有太阳能电源板,所述太阳能电源板为所述电池模块供电。3 . The audio device with high buoyancy according to claim 1 , wherein a solar power panel is provided on the top of the upper casing, and the solar power panel supplies power to the battery module. 4 . 4.根据权利要求1所述的具有高浮力的音频装置,其特征在于,在所述疏水材料制备的过程中,先制备纳米SiO2溶胶;后以氨丙基三乙氧基硅烷与γ-二乙烯三胺丙基甲基二甲氧基硅烷作为纳米SiO2溶胶的团聚剂,构建微纳米的粗糙结构;采用十六烷基三甲氧基硅烷进行颗粒疏水改性;通过粘结剂进行粘结,制备得到疏水性能良好的超疏水复合材料。4 . The audio device with high buoyancy according to claim 1 , wherein, in the process of preparing the hydrophobic material, nano-SiO 2 sol is prepared first; Diethylenetriaminepropylmethyldimethoxysilane was used as agglomeration agent for nano - SiO sol to build micro-nano rough structure; hexadecyltrimethoxysilane was used for particle hydrophobic modification; A superhydrophobic composite with good hydrophobicity was prepared. 5.根据权利要求1所述的具有高浮力的音频装置,其特征在于,所述浮力体以环氧树脂和空心玻璃微珠为原料制备而成,且所述环氧树脂占原料的质量比为2-10%,所述空心玻璃微珠占原料的质量比为90-98%。5 . The audio device with high buoyancy according to claim 1 , wherein the buoyant body is prepared by using epoxy resin and hollow glass microspheres as raw materials, and the epoxy resin accounts for the mass ratio of the raw materials. 6 . is 2-10%, and the mass ratio of the hollow glass microspheres to the raw material is 90-98%. 6.根据权利要求1所述的具有高浮力的音频装置,其特征在于,在制备所述浮力体的过程中,具体包括以下步骤:6. The audio device with high buoyancy according to claim 1, characterized in that, in the process of preparing the buoyant body, it specifically comprises the following steps: (1)首先对空心玻璃微珠进行筛选和表面处理;(1) First, the hollow glass beads are screened and surface treated; (2)将处理后的空心玻璃微珠分次加入到改性UPR中,并在真空状态下进行搅拌;(2) Add the treated hollow glass microspheres to the modified UPR in stages, and stir in a vacuum state; (3)先后加入助固化剂和固化剂,并进行真空搅拌;(3) Add co-curing agent and curing agent successively, and perform vacuum stirring; (4)将搅拌后的混合物浇注于模具中,并将模具置于一定温度中固化;(4) Pour the stirred mixture into a mold, and place the mold at a certain temperature to solidify; (5)将固化后的半成品进行高温熟化;(5) Curing the cured semi-finished products at high temperature; (6)冷却后脱模,并经过后处理得到高强度的浮力体。(6) Demoulding after cooling, and post-processing to obtain a high-strength buoyant body. 7.根据权利要求6所述的具有高浮力的音频装置,其特征在于,在所述步骤(1)中,将所述空心玻璃微珠进行抗压筛选,后放入配置好的硅烷偶联剂溶液中进行表面处理。7 . The audio device with high buoyancy according to claim 6 , wherein in the step (1), the hollow glass microspheres are subjected to compression screening, and then placed into the prepared silane coupling device. 8 . surface treatment in solution. 8.根据权利要求7所述的具有高浮力的音频装置,其特征在于,所述硅烷偶联剂溶液占所述空心玻璃微珠质量的0.5-1.5%。8 . The audio device with high buoyancy according to claim 7 , wherein the silane coupling agent solution accounts for 0.5-1.5% of the mass of the hollow glass beads. 9 . 9.根据权利要求7所述的具有高浮力的音频装置,其特征在于,所述硅烷偶联剂溶液由硅烷、醇及水混合而成,其中硅烷、醇及水所占质量百分百分别为20-25%、60-75%、5-10%。9 . The audio device with high buoyancy according to claim 7 , wherein the silane coupling agent solution is formed by mixing silane, alcohol and water, wherein silane, alcohol and water account for 100% by mass respectively. 10 . 20-25%, 60-75%, 5-10%. 10.根据权利要求6所述的具有高浮力的音频装置,其特征在于,在所述步骤(3)中,所述助固化剂为环烷酸钴促进剂,所述固化剂为过氧化甲乙酮固化剂。10 . The audio device with high buoyancy according to claim 6 , wherein in the step (3), the co-curing agent is a cobalt naphthenate accelerator, and the curing agent is methyl ethyl ketone peroxide 10 . Hardener.
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JPH11347258A (en) * 1998-06-04 1999-12-21 Pilot Ink Co Ltd Water play toy generating electronic sound
US20050123161A1 (en) * 1999-10-04 2005-06-09 Rany Polany System for housing an audio system in an aquatic environment
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CN101985528A (en) * 2010-11-19 2011-03-16 咸宁海威复合材料制品有限公司 Deep sea pressure-resistant workable buoyancy material and production method thereof
US20180063613A1 (en) * 2016-08-25 2018-03-01 Leon Azar Cohen Pool float with built in speakers and power source
CN109151653A (en) * 2018-08-27 2019-01-04 深圳市三诺数字科技有限公司 A kind of audio devices with water purification function
CN209462526U (en) * 2019-03-21 2019-10-01 深圳市升弘创新科技有限公司 An audio device with high buoyancy

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4489770A (en) * 1983-04-11 1984-12-25 Egon Reich Waterproof enclosure
US5369796A (en) * 1992-08-10 1994-11-29 Kung; Gregory E. Floating sound system
JPH11347258A (en) * 1998-06-04 1999-12-21 Pilot Ink Co Ltd Water play toy generating electronic sound
US20050123161A1 (en) * 1999-10-04 2005-06-09 Rany Polany System for housing an audio system in an aquatic environment
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CN101985528A (en) * 2010-11-19 2011-03-16 咸宁海威复合材料制品有限公司 Deep sea pressure-resistant workable buoyancy material and production method thereof
US20180063613A1 (en) * 2016-08-25 2018-03-01 Leon Azar Cohen Pool float with built in speakers and power source
CN109151653A (en) * 2018-08-27 2019-01-04 深圳市三诺数字科技有限公司 A kind of audio devices with water purification function
CN209462526U (en) * 2019-03-21 2019-10-01 深圳市升弘创新科技有限公司 An audio device with high buoyancy

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