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CN109980348A - A kind of corrosion-resistant flexible wearable antenna and preparation method thereof - Google Patents

A kind of corrosion-resistant flexible wearable antenna and preparation method thereof Download PDF

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Publication number
CN109980348A
CN109980348A CN201910323050.6A CN201910323050A CN109980348A CN 109980348 A CN109980348 A CN 109980348A CN 201910323050 A CN201910323050 A CN 201910323050A CN 109980348 A CN109980348 A CN 109980348A
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layer
yarn
corrosion
resistant flexible
flexible wearable
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白耘菲
岳航宇
解柳艳
何雨欢
许福军
张昆
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Donghua University
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Donghua University
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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0088Fabrics having an electronic function
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/247Mineral
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/593Stiff materials, e.g. cane or slat
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D25/00Woven fabrics not otherwise provided for
    • D03D25/005Three-dimensional woven fabrics
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/27Adaptation for use in or on movable bodies
    • H01Q1/273Adaptation for carrying or wearing by persons or animals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/36Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith
    • H01Q1/364Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith using a particular conducting material, e.g. superconductor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/36Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith
    • H01Q1/364Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith using a particular conducting material, e.g. superconductor
    • H01Q1/368Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith using a particular conducting material, e.g. superconductor using carbon or carbon composite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/36Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith
    • H01Q1/38Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith formed by a conductive layer on an insulating support
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/48Earthing means; Earth screens; Counterpoises
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • D10B2101/122Nanocarbons
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/021Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
    • D10B2321/0211Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/04Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons
    • D10B2321/042Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons polymers of fluorinated hydrocarbons, e.g. polytetrafluoroethene [PTFE]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Woven Fabrics (AREA)

Abstract

本发明公开了一种耐腐蚀柔性可穿戴天线,其特征在于,包括上层的辐射元层、中间层的介质基体层和下层的接地板层,所述辐射元层和接地板层采用导电纱线,通过馈电线连接;介质基体层采用非导电纱线;所述辐射元层、介质基体层和接地板层采用三维正交结构,均由经纱和纬纱组成,经纱和纬纱之间相互垂直并且没有交织,通过捆绑纱在纬纱上沿经纱方向交织将辐射元层、介质基体层和接地板层绑成一个整体。制备方法包括:选择非导电纱线,测试其介电常数,设计辐射元尺寸,采用三维织造的方法得到耐腐蚀柔性可穿戴天线。本发明所得的可穿戴天线采用耐腐蚀纱线进行织造,整体性好,易共形,可以随弯曲进行调整,具有稳定的电磁辐射性能,应用前景广泛。

The invention discloses a corrosion-resistant flexible wearable antenna, which is characterized by comprising an upper radiating element layer, a middle layer of a dielectric base layer and a lower grounding plate layer, and the radiating element layer and the grounding plate layer are made of conductive yarns , connected by feeder lines; the dielectric base layer adopts non-conductive yarn; the radiation element layer, the dielectric base layer and the ground plane layer adopt a three-dimensional orthogonal structure, all composed of warp yarns and weft yarns, and the warp yarns and weft yarns are perpendicular to each other and have no Interweaving, the radiating element layer, the medium base layer and the grounding plate layer are bound into a whole by interlacing the binding yarn on the weft yarn along the warp direction. The preparation method includes: selecting a non-conductive yarn, testing its dielectric constant, designing the size of a radiation element, and adopting a three-dimensional weaving method to obtain a corrosion-resistant flexible wearable antenna. The wearable antenna obtained by the invention is woven with corrosion-resistant yarn, has good integrity, is easy to conform, can be adjusted with bending, has stable electromagnetic radiation performance, and has wide application prospects.

Description

一种耐腐蚀柔性可穿戴天线及其制备方法Corrosion-resistant flexible wearable antenna and preparation method thereof

技术领域technical field

本发明属于天线领域,具体涉及一种耐腐蚀柔性可穿戴天线及其制备方法。The invention belongs to the field of antennas, and in particular relates to a corrosion-resistant flexible wearable antenna and a preparation method thereof.

背景技术Background technique

目前,无线通信技术在军事国防、科研探测、工业生产、医疗、以及民用通讯等领域有着广泛的应用,同时,随着人体中心网络的发展,各种可穿戴无线通信设备应运而生。而天线作为无线通信中必不可少的一个组成单元,其应该具有适应各种工作环境、在恶劣的环境条件下保持性能的能力。传统的通信天线为突出结构,其占空间较大,且不耐外力、易损坏,有令使用者行动受阻,暴露位置的风险。因此,在可穿戴天线领域,具有片状结构、尺寸较小的微带天线得到了广泛的运用。将微带天线放置于服装的背部等相对平整部位是目前可穿戴领域的常见办法。At present, wireless communication technology has a wide range of applications in the fields of military defense, scientific research and exploration, industrial production, medical treatment, and civil communication. As an indispensable component in wireless communication, the antenna should have the ability to adapt to various working environments and maintain performance under harsh environmental conditions. The traditional communication antenna is a protruding structure, which occupies a large space, is not resistant to external force, and is easily damaged, which may hinder the user's movement and expose the position. Therefore, in the field of wearable antennas, microstrip antennas with a sheet-like structure and small size have been widely used. Placing the microstrip antenna on a relatively flat part such as the back of the garment is a common method in the current wearable field.

微带天线大体上由辐射元,介质基片,接地板三层元件构成。传统微带天线均使用铜片等刚性材料,无法弯曲、共形能力差,在人体穿戴使用的过程中会因弯折而影响性能、缩短使用寿命。近年来,国内外有利用毛毡等纺织材料作为介质基片、和使用更薄的导电元件以提升天线共形能力的研究,取得了一定的成果。但是,天线依然由三层分离的片状结构粘贴而成,在一些恶劣环境,如高温或外力冲击的情况、以及弯折的条件下,容易出现分层和断裂的现象,对天线造成损坏;除此之外,传统天线多采用不耐腐蚀的材料,因此不适用于化工生产、消防等工作环境特殊的情况中。然而这类工作的环境非常危险,在作业过程中,和外界保持通信联络是至关重要的。The microstrip antenna is generally composed of three layers of radiating element, dielectric substrate and grounding plate. Traditional microstrip antennas use rigid materials such as copper sheets, which cannot be bent and have poor conformal ability. In the process of wearing and using the human body, the performance will be affected and the service life will be shortened due to bending. In recent years, there have been studies at home and abroad using textile materials such as felt as dielectric substrates and using thinner conductive elements to improve the conformal capability of the antenna, and some achievements have been achieved. However, the antenna is still made of three-layer separated sheet-like structures. In some harsh environments, such as high temperature or external force impact, and bending conditions, delamination and fracture are prone to occur, causing damage to the antenna; In addition, traditional antennas mostly use materials that are not resistant to corrosion, so they are not suitable for special working environments such as chemical production and fire protection. However, the environment of this type of work is very dangerous, and it is crucial to maintain communication with the outside world during the operation.

发明内容SUMMARY OF THE INVENTION

本发明所要解决的技术问题是提供一种耐腐蚀柔性可穿戴天线及其制备方法,解决目前可穿戴天线不具柔软性,不易共形,无法应用在恶劣环境的条件下的问题,同时解决层合式微带天线在弯曲过程中的所产生的分层破坏现象。The technical problem to be solved by the present invention is to provide a corrosion-resistant flexible wearable antenna and a preparation method thereof, so as to solve the problems that the current wearable antenna has no flexibility, is not easy to conform, and cannot be used in harsh environments, and at the same time solves the problems of lamination The phenomenon of delamination caused by the bending process of the microstrip antenna.

为了解决上述技术问题,本发明提供了一种耐腐蚀柔性可穿戴天线,其特征在于,包括上层的辐射元层、中间层的介质基体层和下层的接地板层,所述辐射元层和接地板层采用导电纱线,通过馈电线连接;介质基体层采用非导电纱线;所述辐射元层、介质基体层和接地板层采用三维正交结构,均由经纱和纬纱组成,经纱和纬纱之间相互垂直并且没有交织,通过捆绑纱在纬纱上沿经纱方向交织将辐射元层、介质基体层和接地板层绑成一个整体。In order to solve the above technical problems, the present invention provides a corrosion-resistant flexible wearable antenna, which is characterized in that it includes an upper radiating element layer, a middle layer of a dielectric base layer, and a lower grounding plate layer, the radiating element layer and the ground plane layer. The floor layer adopts conductive yarn, which is connected by feeding lines; the medium base layer adopts non-conductive yarn; the radiation element layer, the medium base layer and the ground plane layer adopt a three-dimensional orthogonal structure, which are all composed of warp yarns and weft yarns. Warp yarns and weft yarns They are perpendicular to each other and are not interwoven, and the radiation element layer, the medium base layer and the grounding plate layer are bound into a whole by interlacing the binding yarns on the weft yarns along the warp direction.

优选地,所述导电纱线为碳纳米管纱线、金属纤维、导电涂层纤维和碳纤维中的任意一种或多种的混纺纤维。Preferably, the conductive yarn is a blended fiber of any one or more of carbon nanotube yarn, metal fiber, conductive coating fiber and carbon fiber.

优选地,所述非导电纱线为高强高模聚乙烯纤维(超高分子量聚乙烯纤维)、聚四氟乙烯纤维和芳纶纤维中的任意一种或多种混纺纤维。Preferably, the non-conductive yarn is any one or more blended fibers of high-strength and high-modulus polyethylene fibers (ultra-high molecular weight polyethylene fibers), polytetrafluoroethylene fibers and aramid fibers.

优选地,所述非导电纱线的介电损耗小于0.01。Preferably, the dielectric loss of the non-conductive yarn is less than 0.01.

更优选地,所述高强高模聚乙烯的介电常数为2.2~2.4,聚四氟乙烯的介电常数为1.8~2.2,芳纶的介电常数为3.3。More preferably, the dielectric constant of the high-strength and high-modulus polyethylene is 2.2-2.4, the dielectric constant of the polytetrafluoroethylene is 1.8-2.2, and the dielectric constant of the aramid is 3.3.

本发明还提供了上述的耐腐蚀柔性可穿戴天线的制备方法,其特征在于,包括以下步骤:The present invention also provides the above-mentioned preparation method of the corrosion-resistant flexible wearable antenna, which is characterized by comprising the following steps:

步骤1:选择非导电纱线,在三维织机上将其织造成三维正交织物,测试并计算其介电常数和介电损耗;根据所得到的介电常数,通过天线设计经验公式计算辐射元的基本尺寸;Step 1: Select non-conductive yarn, weave it into a three-dimensional orthogonal fabric on a three-dimensional loom, test and calculate its dielectric constant and dielectric loss; according to the obtained dielectric constant, calculate the radiation element through the antenna design empirical formula the basic size;

步骤2:选择导电纱线,与步骤1中非导电纱线一起在三维织机上进行织造三维正交结构,使得导电纱线分别位于最上层和最下层,作为辐射元层和接地板层,使得导电纱线位于中间层,作为介质基体层;所述辐射元层、介质基体层和接地板层均由经纱和纬纱组成,经纱和纬纱之间相互垂直并且没有交织,通过捆绑纱在纬纱上沿经纱方向交织将多层织物捆绑成一个整体,得到耐腐蚀柔性可穿戴天线。Step 2: Select conductive yarns, and weave a three-dimensional orthogonal structure on a three-dimensional loom together with the non-conductive yarns in Step 1, so that the conductive yarns are located on the uppermost layer and the lowermost layer, respectively, as the radiation element layer and the grounding plate layer, so that The conductive yarn is located in the middle layer as a medium base layer; the radiation element layer, the medium base layer and the ground plane layer are all composed of warp yarns and weft yarns, and the warp yarns and weft yarns are perpendicular to each other and are not interwoven. The interlacing in the warp direction binds the multi-layer fabrics into a whole, resulting in a corrosion-resistant flexible wearable antenna.

优选的,所述步骤1中天线设计的频率为0.5~10GHz,可以随需求调整,可以为2.4GHz应用于商用无线传输领域,也可以是其它频段应用于不同的领域。Preferably, the frequency of the antenna design in the step 1 is 0.5-10 GHz, which can be adjusted as required, and can be 2.4 GHz for commercial wireless transmission, or other frequency bands for different fields.

优选地,所述步骤1中非导电纱线为高强高模聚乙烯纤维、聚四氟乙烯纤维和芳纶纤维中的任意一种或多种的混纺纤维;非导电纱线的介电损耗小于0.01。Preferably, in the step 1, the non-conductive yarn is a blended fiber of any one or more of high-strength and high-modulus polyethylene fiber, polytetrafluoroethylene fiber and aramid fiber; the dielectric loss of the non-conductive yarn is less than 0.01.

更优选地,所述高强高模聚乙烯的介电常数为2.2~2.4,聚四氟乙烯的介电常数为1.8~2.2,芳纶的介电常数为3.3。More preferably, the dielectric constant of the high-strength and high-modulus polyethylene is 2.2-2.4, the dielectric constant of the polytetrafluoroethylene is 1.8-2.2, and the dielectric constant of the aramid is 3.3.

优选的,所述步骤2中导电纱线为碳纳米管纱线、金属纤维、导电涂层纤维和碳纤维中的任意一种或多种的混纺纤维。Preferably, in the step 2, the conductive yarn is a blended fiber of any one or more of carbon nanotube yarn, metal fiber, conductive coating fiber and carbon fiber.

与现有技术相比,本发明的有益效果在于:Compared with the prior art, the beneficial effects of the present invention are:

(1)本发明结合纺织三维织造技术与天线设计技术,获得一种耐腐蚀的柔性可穿戴天线,将天线的无线信号传输功能赋予到织物上,获得一种新型的智能纺织品。(1) The present invention combines textile three-dimensional weaving technology and antenna design technology to obtain a corrosion-resistant flexible wearable antenna, and imparts the wireless signal transmission function of the antenna to the fabric to obtain a new type of smart textile.

(2)本发明获得的耐腐蚀的柔性可穿戴天线采用三维正交结构,经纬纱之间容易相互滑移,使天线结构形状可以随人体运动而改变,同时保持天线性能的稳定性。(2) The corrosion-resistant flexible wearable antenna obtained by the present invention adopts a three-dimensional orthogonal structure, and the warp and weft yarns are easy to slip with each other, so that the structure and shape of the antenna can be changed with the movement of the human body, while maintaining the stability of the antenna performance.

(3)本发明获得的耐腐蚀的柔性可穿戴天线为三维一体结构,相对于层合式微带天线具有抗分层的特点。(3) The corrosion-resistant flexible wearable antenna obtained by the present invention is a three-dimensional integrated structure, and has the characteristics of anti-delamination compared with the laminated microstrip antenna.

(4)本发明获得的耐腐蚀的柔性可穿戴天线完全由纱线织造而成,具有良好的柔性和共形能力,同时可以织造进服装当中,达到隐形的效果。(4) The corrosion-resistant flexible wearable antenna obtained by the present invention is completely woven from yarn, has good flexibility and conformability, and can be woven into clothing to achieve an invisible effect.

(5)本发明获得的柔性可穿戴天线由耐腐蚀材料构成,其化学性质稳定,具有在恶劣条件下可以正常工作且不易腐蚀损坏。(5) The flexible wearable antenna obtained by the present invention is composed of corrosion-resistant materials, which have stable chemical properties, can work normally under harsh conditions, and are not easily damaged by corrosion.

(6)本发明获得的耐腐蚀的柔性可穿戴天线在军事国防、科研探测、化工生产、石油、消防等领域具有广阔的应用前景。(6) The corrosion-resistant flexible wearable antenna obtained by the present invention has broad application prospects in the fields of military national defense, scientific research and exploration, chemical production, petroleum, fire protection and the like.

附图说明Description of drawings

图1为本发明耐腐蚀柔性可穿戴天线的结构示意图;1 is a schematic structural diagram of a corrosion-resistant flexible wearable antenna of the present invention;

图2为本发明耐腐蚀柔性可穿戴天线的俯视图;2 is a top view of the corrosion-resistant flexible wearable antenna of the present invention;

图3为本发明耐腐蚀柔性可穿戴天线的前视图;3 is a front view of the corrosion-resistant flexible wearable antenna of the present invention;

图4为本发明耐腐蚀柔性可穿戴天线的右视图;4 is a right side view of the corrosion-resistant flexible wearable antenna of the present invention;

图5为本发明耐腐蚀柔性可穿戴天线的尺寸图;Fig. 5 is the dimension drawing of the corrosion-resistant flexible wearable antenna of the present invention;

附图标记说明:1-辐射元层,2-介质基体层,3-接地板层,4-捆绑纱。Explanation of reference numerals: 1-radiating element layer, 2-dielectric base layer, 3-ground plate layer, 4-bundling yarn.

具体实施方式Detailed ways

下面结合具体实施例,进一步阐述本发明。应理解,这些实施例仅用于说明本发明而不用于限制本发明的范围。此外应理解,在阅读了本发明讲授的内容之后,本领域技术人员可以对本发明作各种改动或修改,这些等价形式同样落于本申请所附权利要求书所限定的范围。The present invention will be further described below in conjunction with specific embodiments. It should be understood that these examples are only used to illustrate the present invention and not to limit the scope of the present invention. In addition, it should be understood that after reading the content taught by the present invention, those skilled in the art can make various changes or modifications to the present invention, and these equivalent forms also fall within the scope defined by the appended claims of the present application.

天线设计经验公式:Antenna design empirical formula:

LG=L+0.2λg 式1-6;LG=L+0.2λ g formula 1-6;

WG=L+0.2λg 式1-7;WG=L+0.2λ g formula 1-7;

其中fr为中心频率,εr为织物介质基板的介电常数,h为柔性天线厚度,c为真空中的光速,W和L分别为辐射元1宽和长,λ0为自由空间波长,WG和LG为成品柔性微带天线的宽和长。where f r is the center frequency, ε r is the dielectric constant of the fabric dielectric substrate, h is the thickness of the flexible antenna, c is the speed of light in vacuum, W and L are the width and length of the radiating element 1, respectively, λ 0 is the free-space wavelength, WG and LG are the width and length of the finished flexible microstrip antenna.

实施例1Example 1

如图1~4所示,本实施例提供了一种耐腐蚀柔性可穿戴天线,包括上层的辐射元层1、中间层的介质基体层2和下层的接地板层3,所述辐射元层1和接地板层3采用耐化学腐蚀的碳纳米管导电纱线,通过馈电线连接;所述的介质基体层2采用聚四氟乙烯纤维;所述辐射元层1、介质基体层2和接地板层3采用三维正交结构,均由经纱和纬纱组成,经纱和纬纱之间相互垂直并且没有交织,通过捆绑纱4在纬纱上沿经纱方向交织将辐射元层1、介质基体层2和接地板层3绑成一个整体。As shown in FIGS. 1 to 4 , this embodiment provides a corrosion-resistant flexible wearable antenna, including an upper radiating element layer 1 , a middle layer dielectric base layer 2 and a lower grounding plate layer 3 . The radiating element layer 1 and the grounding plate layer 3 are made of chemically resistant carbon nanotube conductive yarns, which are connected by feeding lines; the medium base layer 2 is made of polytetrafluoroethylene fibers; the radiation element layer 1, the medium base layer 2 and the connection are used. The floor layer 3 adopts a three-dimensional orthogonal structure, which is composed of warp yarns and weft yarns, and the warp yarns and weft yarns are perpendicular to each other and are not interwoven. Floor layers 3 are tied into one whole.

上述耐腐蚀柔性可穿戴天线的制备方法具体如下:The preparation method of the above-mentioned corrosion-resistant flexible wearable antenna is as follows:

步骤1:以细度为562dtex的聚四氟乙烯纤维(山东森荣新材料股份有限公司)为非导电纱线,在三维织机上将其织造成三维正交织物,测试并计算其介电常数,本实施例所设计的天线工作频率为2.4GHz,所制备的材料其介电常数通过经验公式中工作频率与介电常数之间的理论关系推算为1.9。根据天线设计经验公式,计算得到基于聚四氟乙烯纤维的耐腐蚀柔性可穿戴天线的尺寸参数;Step 1: Use 562dtex PTFE fiber (Shandong Senrong New Material Co., Ltd.) as a non-conductive yarn, woven into a three-dimensional orthogonal fabric on a three-dimensional loom, test and calculate its dielectric constant , the operating frequency of the antenna designed in this embodiment is 2.4 GHz, and the dielectric constant of the prepared material is estimated to be 1.9 through the theoretical relationship between the operating frequency and the dielectric constant in the empirical formula. According to the empirical formula of antenna design, the size parameters of the corrosion-resistant flexible wearable antenna based on PTFE fiber are calculated;

如图5所示,其中W和L分别为辐射元1的宽和长,WG和LG为成品耐腐蚀可柔性穿戴天线的宽和长,FL为微带线的长度,FD为微带线的宽度;其中:W和L均为4.2厘米,WG和LG为12厘米,FL为4厘米,FD为2.2厘米,As shown in Figure 5, where W and L are the width and length of radiating element 1, respectively, WG and LG are the width and length of the finished corrosion-resistant flexible wearable antenna, FL is the length of the microstrip line, and FD is the length of the microstrip line. Width; where: W and L are both 4.2 cm, WG and LG are 12 cm, FL is 4 cm, FD is 2.2 cm,

步骤2:以直径为200μm的碳纳米管纱线(苏州捷迪纳米科技有限公司,型号SCNC-F)为导电纱线制备辐射元层与接地板层,以步骤1中聚四氟乙烯纤维为非导电纱线制备介质基体层,采用多组综框织造工艺,通过控制综框进而控制捆绑纱的运动方式;同时采用多剑竿引纬工艺,控制纬纱的运动方式,织造三维机织正交结构天线;Step 2: Use carbon nanotube yarn with a diameter of 200 μm (Suzhou Jie Di Nano Technology Co., Ltd., model SCNC-F) as the conductive yarn to prepare the radiation element layer and the ground plane layer, and use the polytetrafluoroethylene fiber in step 1 as the conductive yarn. The non-conductive yarn is used to prepare the medium matrix layer, and the weaving process of multiple sets of heald frames is used to control the movement mode of the bundled yarn by controlling the heald frame; at the same time, the multi-rapier weft insertion process is used to control the movement mode of the weft yarn, and weaving a three-dimensional woven orthogonal structure antenna;

首先将聚四氟乙烯纱线和碳纳米管纱线均由筒子架引出,经过机前钢扣进行预分层,捆绑纱6(聚四氟乙烯纱线)穿过综丝眼,经纱分为四层,上下层为碳纳米管纱线,中间两层为聚四氟乙烯纱线,经纱从两页综框的综丝之间穿过,在综框上下分层后形成多层梭口,各层纱线分布由上至下依次为构成辐射元层的碳纳米管纱线、构成介质基体层的两层聚四氟乙烯纤维、构成接地板的碳纳米管纱线;纬纱为聚四氟乙烯纱线,由剑杆引入后,综框上下交替,捆绑纱为聚四氟乙烯纱线完成交织,将经纬纱线捆绑成一个整体,随后钢筘完成打纬,通过电机卷绕完成卷曲工作,往复循环后完成三维织物的织造;First, both the PTFE yarn and the carbon nanotube yarn are drawn out from the creel, and pre-layered through the front steel buckle. The binding yarn 6 (polytetrafluoroethylene yarn) passes through the heddle eyelet, and the warp yarn is divided into Four layers, the upper and lower layers are carbon nanotube yarns, the middle two layers are polytetrafluoroethylene yarns, the warp yarns pass between the healds of the two heald frames, and after the heald frames are layered up and down, a multi-layer shed is formed. The yarn distribution of each layer is, from top to bottom, carbon nanotube yarns constituting the radiation element layer, two layers of polytetrafluoroethylene fibers constituting the medium matrix layer, and carbon nanotube yarns constituting the grounding plate; the weft yarns are polytetrafluoroethylene Vinyl yarn, after being introduced by the rapier, the heald frame alternates up and down, the binding yarn is teflon yarn to complete the interweaving, the warp and weft yarns are bundled into a whole, and then the reed completes the beating, and the winding work is completed by the motor winding. , the weaving of the three-dimensional fabric is completed after the reciprocating cycle;

织造辐射元以外部分时,顶层不引入碳纳米管纱线,也不将经向的碳纳米管纱线织入;织造辐射元时,则将导电纱线织入其中,构成织物结构微带天线。最后获得的三维正交织物经纬密:10根/厘米;捆绑纱密度:10根/厘米。When weaving the parts other than the radiating element, the top layer does not introduce carbon nanotube yarns, nor does the warp carbon nanotube yarns be woven into it; when weaving the radiating elements, conductive yarns are woven into it to form a fabric-structured microstrip antenna. . Warp and weft density of the finally obtained three-dimensional orthogonal fabric: 10 pcs/cm; bundle yarn density: 10 pcs/cm.

制备完成后,检查辐射元贴片的尺寸是否符合参数要求,并且确定织物上下层并没有电流导通,在确认完成后将同轴连接器的底座与馈电芯分别与接地板和馈线相焊接,完成三维正交耐腐蚀柔性可穿戴天线的制备。经测试,在PH值为3的强酸环境放置5小时以后,三维正交耐腐蚀柔性可穿戴天线的驻波比仍为1.5左右,共振频率2.4GHz,增益性能为4dB左右。After the preparation is completed, check whether the size of the radiating element patch meets the parameter requirements, and make sure that the upper and lower layers of the fabric have no current conduction. After the confirmation, the base of the coaxial connector and the feed core are respectively welded to the ground plate and the feeder. , to complete the preparation of a three-dimensional orthogonal corrosion-resistant flexible wearable antenna. After testing, after being placed in a strong acid environment with a pH value of 3 for 5 hours, the standing wave ratio of the three-dimensional orthogonal corrosion-resistant flexible wearable antenna is still about 1.5, the resonance frequency is 2.4GHz, and the gain performance is about 4dB.

实施例2Example 2

如图1~4所示,本实施例提供了一种耐腐蚀柔性可穿戴天线,包括上层的辐射元层1、中间层的介质基体层2和下层的接地板层3,所述辐射元层1和接地板层3采用耐化学腐蚀的碳纳米管导电纱线,通过馈电线连接;所述的介质基体层2采用聚四氟乙烯纤维;所述辐射元层1、介质基体层2和接地板层3采用三维正交结构,均由经纱和纬纱组成,经纱和纬纱之间相互垂直并且没有交织,通过捆绑纱4在纬纱上沿经纱方向交织将辐射元层1、介质基体层2和接地板层3绑成一个整体。As shown in FIGS. 1 to 4 , this embodiment provides a corrosion-resistant flexible wearable antenna, including an upper radiating element layer 1 , a middle layer dielectric base layer 2 and a lower grounding plate layer 3 . The radiating element layer 1 and the grounding plate layer 3 are made of chemically resistant carbon nanotube conductive yarns, which are connected by feeding lines; the medium base layer 2 is made of polytetrafluoroethylene fibers; the radiation element layer 1, the medium base layer 2 and the connection are used. The floor layer 3 adopts a three-dimensional orthogonal structure, which is composed of warp yarns and weft yarns, and the warp yarns and weft yarns are perpendicular to each other and are not interwoven. Floor layers 3 are tied into one whole.

上述耐腐蚀柔性可穿戴天线的制备方法具体如下:The preparation method of the above-mentioned corrosion-resistant flexible wearable antenna is as follows:

步骤1:以细度为222dtex,型号为SP200的高强高模聚乙烯纤维(上海斯瑞科技有限公司)为非导电纱线,在三维织机上将其织造成三维正交织物,测试并计算其介电常数和介电损耗,本实施例所设计的天线工作频率为1.5GHz,所制备的材料其介电常数通过经验公式中工作频率与介电常数之间的理论关系推算为1.3。根据天线设计经验公式,计算得到基于高强高模聚乙烯纤维的耐腐蚀柔性可穿戴天线的尺寸参数;Step 1: Using the high-strength and high-modulus polyethylene fiber (Shanghai Sirui Technology Co., Ltd.) with a fineness of 222dtex and a model of SP200 as a non-conductive yarn, weaving it into a three-dimensional orthogonal fabric on a three-dimensional loom, testing and calculating its dielectric Constant and dielectric loss, the working frequency of the antenna designed in this embodiment is 1.5GHz, and the dielectric constant of the prepared material is calculated to be 1.3 through the theoretical relationship between the working frequency and the dielectric constant in the empirical formula. According to the antenna design empirical formula, the size parameters of the corrosion-resistant flexible wearable antenna based on high-strength and high-modulus polyethylene fibers are calculated;

如图5所示,其中W和L分别为辐射元1的宽和长,WG和LG为成品耐腐蚀可柔性穿戴天线的宽和长,FL为微带线的长度,FD为微带线的宽度;其中:W和L均为4.8厘米,WG和LG为14厘米,FL为4.2厘米,FD为2厘米,As shown in Figure 5, where W and L are the width and length of radiating element 1, respectively, WG and LG are the width and length of the finished corrosion-resistant flexible wearable antenna, FL is the length of the microstrip line, and FD is the length of the microstrip line. Width; where: W and L are both 4.8 cm, WG and LG are 14 cm, FL is 4.2 cm, FD is 2 cm,

步骤2:将厚度为22.1μm的碳纳米管膜(中国科学院苏州纳米技术与纳米仿生研究)制备成膜卷纱,作为导电纱线制备辐射元层与接地板层,以步骤1中高强高模聚乙烯纤维为非导电纱线制备介质基体层,采用多组综框织造工艺,通过控制综框进而控制捆绑纱的运动方式;同时采用多剑竿引纬工艺,控制纬纱的运动方式,织造三维机织正交结构天线;Step 2: The carbon nanotube film with a thickness of 22.1 μm (Suzhou Nanotechnology and Nano-Bionics Research, Chinese Academy of Sciences) was prepared into a film-forming winding yarn, which was used as a conductive yarn to prepare the radiation element layer and the grounding plate layer. The high-strength and high-modulus polyethylene in step 1 The fibers are non-conductive yarns to prepare the medium matrix layer. The multi-group heald frame weaving process is used to control the movement of the bundled yarns by controlling the heald frames. At the same time, the multi-rapier weft insertion process is used to control the movement of the weft yarns to weave three-dimensional woven fabrics. Orthogonal structure antenna;

织造方法同实施例1,最后获得的三维正交织物经纬密:12根/厘米;捆绑纱密度:10根/厘米。The weaving method is the same as that of Example 1, and the warp and weft density of the finally obtained three-dimensional orthogonal fabric is 12 pieces/cm; the bundled yarn density is 10 pieces/cm.

制备完成后,检查辐射元贴片的尺寸是否符合参数要求,并且确定织物上下层并没有电流导通,在确认完成后将同轴连接器的底座与馈电芯分别与接地板和馈线相焊接,完成三维正交耐腐蚀柔性可穿戴天线的制备。经测试,在PH值为3的强酸环境放置5小时以后,三维正交耐腐蚀柔性可穿戴天线的驻波比仍为1.4左右,共振频率1.5GHz,增益性能为2.5dB左右。After the preparation is completed, check whether the size of the radiating element patch meets the parameter requirements, and confirm that the upper and lower layers of the fabric have no current conduction. After the confirmation is completed, the base of the coaxial connector and the feeder core are respectively welded to the ground plate and the feeder. , to complete the preparation of a three-dimensional orthogonal corrosion-resistant flexible wearable antenna. After testing, after being placed in a strong acid environment with a pH value of 3 for 5 hours, the standing wave ratio of the three-dimensional orthogonal corrosion-resistant flexible wearable antenna is still about 1.4, the resonance frequency is 1.5GHz, and the gain performance is about 2.5dB.

实施例3Example 3

如图1~4所示,本实施例提供了一种耐腐蚀柔性可穿戴天线,包括上层的辐射元层1、中间层的介质基体层2和下层的接地板层3,所述辐射元层1和接地板层3采用耐化学腐蚀的碳纳米管导电纱线,通过馈电线连接;所述的介质基体层2采用聚四氟乙烯纤维;所述辐射元层1、介质基体层2和接地板层3采用三维正交结构,均由经纱和纬纱组成,经纱和纬纱之间相互垂直并且没有交织,通过捆绑纱4在纬纱上沿经纱方向交织将辐射元层1、介质基体层2和接地板层3绑成一个整体。As shown in FIGS. 1 to 4 , this embodiment provides a corrosion-resistant flexible wearable antenna, including an upper radiating element layer 1 , a middle layer dielectric base layer 2 and a lower grounding plate layer 3 . The radiating element layer 1 and the grounding plate layer 3 are made of chemically resistant carbon nanotube conductive yarns, which are connected by feeding lines; the medium base layer 2 is made of polytetrafluoroethylene fibers; the radiation element layer 1, the medium base layer 2 and the connection are used. The floor layer 3 adopts a three-dimensional orthogonal structure, which is composed of warp yarns and weft yarns, and the warp yarns and weft yarns are perpendicular to each other and are not interwoven. Floor layers 3 are tied into one whole.

上述耐腐蚀柔性可穿戴天线的制备方法具体如下:The preparation method of the above-mentioned corrosion-resistant flexible wearable antenna is as follows:

步骤1:以细度为158tex的芳纶纤维(kevlar129)(美国杜邦公司)为非导电纱线,在三维织机上将其织造成三维正交织物,测试并计算其介电常数和介电损耗,本实施例所设计的天线工作频率为5GHz,所制备的材料其介电常数通过经验公式中工作频率与介电常数之间的理论关系推算为2.4。根据天线设计经验公式,计算得到基于芳纶纤维的耐腐蚀柔性可穿戴天线的尺寸参数;Step 1: Take aramid fiber (kevlar129) (DuPont, USA) with a fineness of 158tex as a non-conductive yarn, and weave it into a three-dimensional orthogonal fabric on a three-dimensional loom, test and calculate its dielectric constant and dielectric loss , the operating frequency of the antenna designed in this embodiment is 5 GHz, and the dielectric constant of the prepared material is estimated to be 2.4 through the theoretical relationship between the operating frequency and the dielectric constant in the empirical formula. According to the antenna design empirical formula, the size parameters of the corrosion-resistant flexible wearable antenna based on aramid fiber are calculated;

如图5所示,其中W和L分别为辐射元1的宽和长,WG和LG为成品耐腐蚀可柔性穿戴天线的宽和长,FL为微带线的长度,FD为微带线的宽度;其中:W和L均为4厘米,WG和LG为12厘米,FL为3.8厘米,FD为1.8厘米,As shown in Figure 5, where W and L are the width and length of radiating element 1, respectively, WG and LG are the width and length of the finished corrosion-resistant flexible wearable antenna, FL is the length of the microstrip line, and FD is the length of the microstrip line. Width; where: W and L are both 4 cm, WG and LG are 12 cm, FL is 3.8 cm, FD is 1.8 cm,

步骤2:以直径为200μm的碳纳米管纱线(苏州捷迪纳米科技有限公司,型号SCNC-F)为导电纱线制备辐射元层与接地板层,以步骤1中芳纶纤维为非导电纱线制备介质基体层,采用多组综框织造工艺,通过控制综框进而控制捆绑纱的运动方式;同时采用多剑竿引纬工艺,控制纬纱的运动方式,织造三维机织正交结构天线;Step 2: Use carbon nanotube yarn with a diameter of 200 μm (Suzhou Jiedi Nano Technology Co., Ltd., model SCNC-F) as the conductive yarn to prepare the radiation element layer and the ground plane layer, and use the aramid fiber in step 1 as the non-conductive yarn The yarn is used to prepare the medium matrix layer, and the multi-group heald frame weaving process is used to control the movement mode of the bundled yarn by controlling the heald frame; at the same time, the multi-rapier weft insertion process is used to control the movement mode of the weft yarn, and weaving a three-dimensional woven orthogonal structure antenna ;

织造方法同实施例1,最后获得的三维正交织物经纬密:5根/厘米;捆绑纱密度:5根/厘米。The weaving method is the same as that of Example 1, and the warp and weft density of the finally obtained three-dimensional orthogonal fabric: 5 pieces/cm; the density of binding yarns: 5 pieces/cm.

制备完成后,检查辐射元贴片的尺寸是否符合参数要求,并且确定织物上下层并没有电流导通,在确认完成后将同轴连接器的底座与馈电芯分别与接地板和馈线相焊接,完成三维正交耐腐蚀柔性可穿戴天线的制备。经测试,在PH值为3的强酸环境放置5小时以后,三维正交耐腐蚀柔性可穿戴天线的驻波比仍为1.6左右,共振频率5GHz,增益性能为3dB左右。After the preparation is completed, check whether the size of the radiating element patch meets the parameter requirements, and confirm that the upper and lower layers of the fabric have no current conduction. After the confirmation is completed, the base of the coaxial connector and the feeder core are respectively welded to the ground plate and the feeder. , to complete the preparation of a three-dimensional orthogonal corrosion-resistant flexible wearable antenna. After testing, after being placed in a strong acid environment with a pH value of 3 for 5 hours, the standing wave ratio of the three-dimensional orthogonal corrosion-resistant flexible wearable antenna is still about 1.6, the resonance frequency is 5GHz, and the gain performance is about 3dB.

Claims (7)

1. a kind of corrosion-resistant flexible wearable antenna, which is characterized in that the medium of radiation element layer (1), middle layer including upper layer The ground panel (3) of base layer (2) and lower layer, the radiation element layer (1) and ground panel (3) use conductive yarn, pass through feedback Electric wire connection;Dielectric matrix layer uses non-conducting yarns;The radiation element layer (1), dielectric matrix layer (2) and ground panel (3) It using three-dimensional orthogonal structure, is made of warp thread and weft yarn, is mutually perpendicular between warp thread and weft yarn and does not interweave, pass through bundle It ties up yarn (4) and radiation element layer (1), dielectric matrix layer (2) and ground panel (3) is tied up into one along warp thread direction intertexture on weft yarn It is whole.
2. corrosion-resistant flexible wearable antenna as described in claim 1, which is characterized in that the conductive yarn is carbon nano-tube yarn The blend fibre of any one or more in line, metallic fiber, conductive coating fiber and carbon fiber;The non-conducting yarns are Any one or more blend fibre in high-strength high-modulus polyethylene fiber, polytetrafluoroethylene fibre and aramid fiber.
3. the preparation method of corrosion-resistant flexible wearable antenna as claimed in claim 1 or 2, which comprises the following steps:
Step 1: selection non-conducting yarns are weaved into three-dimensional orthogonal fabric on three-dimensional loom, test and calculate its dielectric Constant and dielectric loss;According to obtained dielectric constant, the basic size of radiation element is calculated by Antenna Design empirical equation;
Step 2: selection conductive yarn carries out the positive knot of weaving three-dimensional together with non-conducting yarns in step 1 on three-dimensional loom Structure, so that conductive yarn is located at top layer and lowest level, as radiation element layer (1) and ground panel (3), so that conductive yam Line is located at middle layer, as dielectric matrix layer (2);The radiation element layer (1), dielectric matrix layer (2) and ground panel (3) by Warp thread and weft yarn composition, are mutually perpendicular between warp thread and weft yarn and do not interweave, by bundled yarn along warp thread side on weft yarn Multilayer fabric is bundled into an entirety to interweaving, obtains corrosion-resistant flexible wearable antenna.
4. the preparation method of corrosion-resistant flexible wearable antenna as claimed in claim 3, which is characterized in that day in the step 1 The frequency of line design is 0.5~10GHz.
5. the preparation method of corrosion-resistant flexible wearable antenna as claimed in claim 3, which is characterized in that non-in the step 1 Conductive yarn is the blended of any one or more in high-strength high-modulus polyethylene fiber, polytetrafluoroethylene fibre and aramid fiber Fiber;The dielectric loss of non-conducting yarns is less than 0.01.
6. the preparation method of corrosion-resistant flexible wearable antenna as claimed in claim 6, which is characterized in that the high-strength and high-modulus is poly- The dielectric constant of ethylene is 2.2~2.4, and the dielectric constant of polytetrafluoroethylene (PTFE) is 1.8~2.2, and the dielectric constant of aramid fiber is 3.3.
7. the preparation method of corrosion-resistant flexible wearable antenna as claimed in claim 3, which is characterized in that led in the step 2 Electric yarn is the blended fibre of any one or more in carbon nanotube yarn, metallic fiber, conductive coating fiber and carbon fiber Dimension.
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