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CN100449737C - Thin film transistor array substrate and method of manufacturing the same - Google Patents

Thin film transistor array substrate and method of manufacturing the same Download PDF

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Publication number
CN100449737C
CN100449737C CNB2006100514903A CN200610051490A CN100449737C CN 100449737 C CN100449737 C CN 100449737C CN B2006100514903 A CNB2006100514903 A CN B2006100514903A CN 200610051490 A CN200610051490 A CN 200610051490A CN 100449737 C CN100449737 C CN 100449737C
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insulating layer
organic insulating
thin film
film transistor
contact
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CN1832149A (en
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李淑琴
胡冠彣
杨智钧
江怡禛
黄国有
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AUO Corp
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AU Optronics Corp
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Abstract

The invention relates to a thin film transistor array substrate and a manufacturing method thereof, wherein the manufacturing method comprises the following steps: a thin film transistor is formed on the active area of the substrate and the contact pad is formed on the peripheral area of the substrate. An inorganic insulating layer and an organic insulating layer are sequentially formed to cover the thin film transistor and the contact pad. And patterning the organic insulating layer. And etching the inorganic insulating layer uncovered by the organic insulating layer with sulfur hexafluoride/oxygen to form a first contact window with a first inclined side wall on the peripheral region and a second contact window with a second inclined side wall on the active region, and leaving a part of the organic insulating layer on the peripheral region. Wherein the flow ratio of sulfur hexafluoride/oxygen is approximately between 0.33 and 0.42. A patterned conductor protection layer is formed on the contact window.

Description

薄膜晶体管阵列基板及其制造方法 Thin film transistor array substrate and manufacturing method thereof

技术领域 technical field

本发明是有关于一种薄膜晶体管及其制造方法,且特别是有关于一种使用此薄膜晶体管阵列基板的显示面板。The present invention relates to a thin film transistor and its manufacturing method, and in particular to a display panel using the thin film transistor array substrate.

背景技术 Background technique

近年来光电相关技术不断推陈出新,加上数字化时代的到来,进而推动了液晶显示器市场的蓬勃发展。液晶显示器(Liquid Crystal Displayer;LCD)因具有高画质、体积小、重量轻、低电压驱动、低消耗功率及应用范围广等优点,故广泛地应用于可携式电视、移动电话、笔记本型计算机、桌上型显示器以及投影电视等消费性电子或计算机产品,并已取代阴极射线管(Cathode Ray Tube;CRT)成为显示器的主流。In recent years, optoelectronic-related technologies have been continuously introduced, coupled with the arrival of the digital age, which has further promoted the vigorous development of the liquid crystal display market. Liquid Crystal Display (LCD) is widely used in portable TVs, mobile phones, notebooks, etc. Consumer electronics or computer products such as computers, desktop monitors, and projection TVs have replaced cathode ray tubes (Cathode Ray Tube; CRT) as the mainstream of displays.

一般液晶显示器的主体为液晶单元,主要是由两片透明基板以及被封于基板之间的液晶所构成。目前液晶显示器是以薄膜晶体管(Thin FilmTransistor;TFT)液晶显示器为主,而一般薄膜晶体管液晶显示器的制作可大致区分为薄膜晶体管阵列(TFT Array)工艺、彩色滤光片(Color Filter)工艺、液晶显示单元组装(LC Cell Assembly)工艺与液晶显示模块(Liquid CrystalModule;LCM)工艺。Generally, the main body of a liquid crystal display is a liquid crystal unit, which is mainly composed of two transparent substrates and a liquid crystal sealed between the substrates. At present, liquid crystal displays are mainly thin film transistor (Thin Film Transistor; TFT) liquid crystal displays, and the production of general thin film transistor liquid crystal displays can be roughly divided into thin film transistor array (TFT Array) technology, color filter (Color Filter) technology, liquid crystal Display unit assembly (LC Cell Assembly) process and liquid crystal display module (Liquid CrystalModule; LCM) process.

其中液晶显示模块组装工艺是将金属框、液晶显示面板与背光模块(Backlight Module)加以组合的组装过程,组合后则完成整个液晶显示屏幕的制造。一般常用的模块组装技术包括芯片玻璃接合(Chip on Glass;COG)、芯片薄膜接合(Chip on Film;COF)与自动卷带式芯片接合(Tape AutomaticBounding;TAB)等。Among them, the liquid crystal display module assembly process is an assembly process in which a metal frame, a liquid crystal display panel and a backlight module (Backlight Module) are combined, and the manufacture of the entire liquid crystal display screen is completed after the combination. Commonly used module assembly technologies include Chip on Glass (COG), Chip on Film (COF) and Tape Automatic Bounding (TAB).

请参照第1图,绘示一种公知的液晶显示器的结构俯示图。在第1图中,液晶显示器具有下玻璃102、上玻璃104、液晶显示面板106、信号接触垫区(data pad portion)108与栅接触垫区(gate pad portion)110。其中,液晶显示面板106上具有许多液晶胞(cell)(未绘示),且每个液晶胞上均具有一个像素电极。由第1图可知,下玻璃102并完全没有与上玻璃104互相重叠,而下玻璃102的外围保留部分的空间作为信号接触垫区108与栅接触垫区110,以电连接驱动集成电路(integrated circuits;IC)。Please refer to FIG. 1 , which shows a top view of the structure of a known liquid crystal display. In FIG. 1 , the LCD has a lower glass 102 , an upper glass 104 , a liquid crystal display panel 106 , a data pad portion 108 and a gate pad portion 110 . Wherein, the liquid crystal display panel 106 has many liquid crystal cells (not shown), and each liquid crystal cell has a pixel electrode. It can be seen from FIG. 1 that the lower glass 102 does not overlap with the upper glass 104 at all, and the space reserved in the periphery of the lower glass 102 is used as the signal contact pad region 108 and the gate contact pad region 110 to electrically connect the integrated circuit (integrated circuit). circuits; IC).

请参照第2图,绘示公知液晶显示面板中的一种于外围区域的接触垫的结构剖面示意图。在第2图中,接触垫122位于基板120上,且无机绝缘层124与有机保护层126依序覆盖于基板120与接触垫122之上。于接触垫122上的无机绝缘层124与有机保护层126内具有一接触窗128,且导体保护层130位于无机绝缘层124与有机保护层126之上、接触窗128内,以电连接接触垫122。Please refer to FIG. 2 , which is a schematic cross-sectional view of a contact pad in a peripheral region of a conventional liquid crystal display panel. In FIG. 2 , the contact pads 122 are located on the substrate 120 , and the inorganic insulating layer 124 and the organic protection layer 126 sequentially cover the substrate 120 and the contact pads 122 . There is a contact window 128 in the inorganic insulating layer 124 and the organic protective layer 126 on the contact pad 122, and the conductor protective layer 130 is located on the inorganic insulating layer 124 and the organic protective layer 126, in the contact window 128, to electrically connect the contact pad 122.

一般在液晶显示模块组装工艺中,利用TAB技术将驱动IC与位于液晶显示面板中的接触垫122连接在一起,且在接触垫122与驱动IC之间会贴附一层异向导电膜(anisotropic conductive film,ACF),以电连接接触垫122与驱动IC。再者,液晶显示模块组装工艺中,亦可使用COG(chip on glass)技术将驱动IC与位于液晶显示面板中的接触垫122连接在一起。  然而,当实施上述技术且接触垫122无法准确地与驱动IC对准时,则有必要进行重工工艺(IC Rework),先将驱动IC与接触垫122分开之后再重新粘贴一次。然而,在重工工艺中会使用有机溶剂(例如丙酮)进行驱动IC与接触垫122的分离,无可避免的,重工工艺中的有机溶剂会影响到有机保护层126的安定性,且由于原本无机绝缘层124与有机保护层126间的粘着力就较弱,所以将驱动IC从接触垫122上移除掉时,部分的有机保护层126与位于有机保护层126上的导体保护层130也会在重工工艺时一起被移除掉。如此一来,则造成有机保护层126与导体保护层130损坏,进而降低生产良率,并同时增加制造成本。Generally, in the liquid crystal display module assembly process, the driver IC and the contact pad 122 located in the liquid crystal display panel are connected together using TAB technology, and a layer of anisotropic conductive film (anisotropic film) is attached between the contact pad 122 and the driver IC. conductive film, ACF), to electrically connect the contact pad 122 with the driving IC. Furthermore, in the assembly process of the liquid crystal display module, the driving IC and the contact pads 122 in the liquid crystal display panel can also be connected together by using COG (chip on glass) technology. However, when the above technique is implemented and the contact pad 122 cannot be accurately aligned with the driver IC, it is necessary to perform a rework process (IC Rework), first separating the driver IC from the contact pad 122 and then pasting it again. However, an organic solvent (such as acetone) will be used to separate the driver IC from the contact pad 122 in the rework process. It is inevitable that the organic solvent in the rework process will affect the stability of the organic protective layer 126, and due to the original inorganic The adhesion between the insulating layer 124 and the organic protection layer 126 is weak, so when the driver IC is removed from the contact pad 122, part of the organic protection layer 126 and the conductor protection layer 130 on the organic protection layer 126 will also be damaged. Removed together when recrafting. In this way, the organic protection layer 126 and the conductor protection layer 130 are damaged, thereby reducing the production yield and increasing the manufacturing cost.

有鉴于此,美国专利第6,650,380号提出一种改善上述缺点的方法,其于形成接触窗之后移除接触垫上的有机保护层,让后续形成的导体保护层直接覆盖于粘着性较佳的无机保护层上。然而,由第3A图(其沿着第3B图中的A-A’、B-B’、C-C’剖面线的公知液晶显示面板中的薄膜晶体管阵列基板的剖面结构示意图)可看出,此方法的最大难处在于,因源极/漏极206a、206b上方的第二接触窗216b与接触垫204、208上方的第一接触窗216a、216c为同时形成,若将接触垫204、208上的有机保护层212完全移除掉时,蚀刻后的源极/漏极206a、206b上方的第二接触窗216b的有机保护层212与无机绝缘层210的侧壁会呈现近似垂直的轮廓(profile),所以在后续沉积像素电极214b覆盖于有机保护层212时会产生阶梯覆盖性不佳的问题。In view of this, U.S. Patent No. 6,650,380 proposes a method to improve the above-mentioned shortcomings, which removes the organic protection layer on the contact pad after forming the contact window, so that the subsequently formed conductor protection layer directly covers the inorganic protection layer with better adhesion. layer. However, it can be seen from Figure 3A (the schematic cross-sectional structure diagram of the thin-film transistor array substrate in the known liquid crystal display panel along the AA', BB', and CC' section lines in Figure 3B) , the biggest difficulty of this method is that since the second contact window 216b above the source/drain electrodes 206a, 206b and the first contact window 216a, 216c above the contact pads 204, 208 are formed at the same time, if the contact pads 204, 208 When the organic protection layer 212 on the top is completely removed, the sidewalls of the organic protection layer 212 and the inorganic insulating layer 210 of the second contact window 216b above the etched source/drain electrodes 206a, 206b will present an approximately vertical profile ( profile), so when the subsequent deposition of the pixel electrode 214b covers the organic protective layer 212, there will be a problem of poor step coverage.

因此,有必要提供一种新的薄膜晶体管的制造方法,以解决后续驱动IC重工工艺时因使用有机溶剂而影响有机保护层的安定性,进而造成接触垫上的导体保护层破裂的问题,且能同时降低导体保护层形成时的阶梯覆盖的困难度,以提高产品良率。Therefore, it is necessary to provide a new method of manufacturing thin film transistors to solve the problem that the stability of the organic protective layer is affected by the use of organic solvents during the subsequent IC rework process, thereby causing the conductor protective layer on the contact pad to break. At the same time, the difficulty of step coverage during the formation of the conductor protection layer is reduced, so as to improve the product yield.

发明内容 Contents of the invention

因此本发明的目的就是在提供一种薄膜晶体管阵列基板及其制造方法,用以降低导体保护层的形成时的阶梯覆盖的难度。Therefore, the object of the present invention is to provide a thin film transistor array substrate and a manufacturing method thereof, which are used to reduce the difficulty of step coverage during the formation of the conductor protection layer.

本发明的另一目的是在提供一种薄膜晶体管阵列基板及其制造方法,以解决于后续驱动IC的重工工艺中,因使用有机溶剂而使有机保护层膨润,进而在IC重工工艺中易拨离造成接触垫上的导体保护层破裂的问题。Another object of the present invention is to provide a thin film transistor array substrate and its manufacturing method to solve the problem of swelling of the organic protective layer due to the use of organic solvents in the subsequent reworking process of driving ICs, which is easy to cause in the IC reworking process Problems with detachment causing cracking of the conductor shield on the contact pads.

本发明的又一目的在于提供一种薄膜晶体管阵列基板及其制造方法,以提高产品良率并降低制造成本。Another object of the present invention is to provide a thin film transistor array substrate and a manufacturing method thereof, so as to improve product yield and reduce manufacturing cost.

根据本发明的目的,提出一种薄膜晶体管阵列基板及其制造方法。根据本发明的一优选实施例,提供基板,再分别于基板上的有源区域与外围区域上形成薄膜晶体管与接触垫。其中薄膜晶体管具有栅极、源极与漏极。接着,在薄膜晶体管与接触垫上依序形成无机绝缘层与有机绝缘层。其中,上述的无机绝缘层的厚度为0.3微米(μm),有机绝缘层的厚度大致上介于5.3微米(μm)至5.6微米(μm)之间。According to the object of the present invention, a thin film transistor array substrate and a manufacturing method thereof are proposed. According to a preferred embodiment of the present invention, a substrate is provided, and thin film transistors and contact pads are respectively formed on the active region and the peripheral region on the substrate. The thin film transistor has a gate, a source and a drain. Next, an inorganic insulating layer and an organic insulating layer are sequentially formed on the thin film transistor and the contact pad. Wherein, the above-mentioned inorganic insulating layer has a thickness of 0.3 micrometers (μm), and the organic insulating layer has a thickness roughly between 5.3 micrometers (μm) and 5.6 micrometers (μm).

利用一半调式光罩对有机绝缘层曝光显影,以于基板上的无机绝缘层上形成至少一个第一接触窗及至少一个第二接触窗,并且分别暴露出位于接触垫上及漏极上的无机绝缘层。其中,外围区域上的有机绝缘层的厚度小于有源区域上的有机绝缘层的厚度Expose and develop the organic insulating layer by using a half-tone mask to form at least one first contact window and at least one second contact window on the inorganic insulating layer on the substrate, and expose the inorganic insulating layer on the contact pad and the drain electrode respectively layer. wherein the thickness of the organic insulating layer on the peripheral region is smaller than the thickness of the organic insulating layer on the active region

随后,以六氟化硫/氧气蚀刻有机绝缘层及接触窗所暴露的无机绝缘层,直至暴露出接触垫以及漏极为止。其中,六氟化硫/氧气的流量比大致上介于0.33~0.42之间。Subsequently, the organic insulating layer and the inorganic insulating layer exposed by the contact window are etched with sulfur hexafluoride/oxygen until the contact pad and the drain are exposed. Wherein, the flow ratio of sulfur hexafluoride/oxygen is roughly between 0.33-0.42.

此时,于接触垫与源极上方会分别形成具有第一倾斜侧壁的第一接触窗与具有第二倾斜侧壁的第二接触窗,且在外围区域上会残留厚度较薄的有机绝缘层,有源区域上也会残留厚度较厚的有机绝缘层。其中,具有第一倾斜侧壁的第一接触窗的角度小于具有第二倾斜侧壁的第二接触窗的角度,且具有第一倾斜侧壁的第一接触窗的角度优选介于20°~50°之间,具有第二倾斜侧壁的第二接触窗的角度优选介于60°~80°之间。At this time, a first contact window with a first slanted sidewall and a second contact window with a second slanted sidewall are respectively formed above the contact pad and the source electrode, and a thinner organic insulating layer remains on the peripheral region. layer, and a thicker organic insulating layer remains on the active region. Wherein, the angle of the first contact window with the first inclined sidewall is smaller than the angle of the second contact window with the second inclined sidewall, and the angle of the first contact window with the first inclined sidewall is preferably between 20°~ The angle of the second contact window with the second inclined sidewall is preferably between 60° and 80°.

最后,形成图案化导体保护层于第一接触窗与第二接触窗上。其中,残留于外围区上部分的有机绝缘层厚度大致上介于0.3微米(μm)至0.5微米(μm)之间。Finally, a patterned conductor protection layer is formed on the first contact window and the second contact window. Wherein, the thickness of the organic insulating layer remaining on the upper portion of the peripheral region is approximately between 0.3 micrometer (μm) and 0.5 micrometer (μm).

本发明的一优选实施例中,为了防止外围区域上的有机绝缘层残留于接触垫上,更可以在以六氟化硫/氧气蚀刻有机绝缘层与接触窗所暴露出来的部分无机绝缘层至暴露出接触垫与漏极的步骤后,以氧气为蚀刻剂蚀刻有机绝缘层,以确保接触垫上没有残留有机绝缘层。In a preferred embodiment of the present invention, in order to prevent the organic insulating layer on the peripheral region from remaining on the contact pads, the part of the inorganic insulating layer exposed by etching the organic insulating layer and the contact window with sulfur hexafluoride/oxygen can be further exposed. After the step of removing the contact pad and the drain electrode, the organic insulating layer is etched with oxygen as an etchant to ensure that no organic insulating layer remains on the contact pad.

由上述可知,应用本发明的方法可以于后续将形成导体保护层的第一接触窗与第二接触窗的侧壁上蚀刻出较为平缓的轮廓,以降低导体保护层的形成时的阶梯覆盖的难度。且应用本发明的方法更可以解决于后续驱动IC的重工工艺中,因有机溶剂的使用而影响有机保护层的安定性,又加上原本无机绝缘层与有机保护层间的粘着力就比较不足,进而造成接触垫上的导体保护层破裂的问题。此外,本发明的方法更可以提高产品良率,并同时降低制造成本。From the above, it can be known that applying the method of the present invention can subsequently etch out relatively gentle contours on the sidewalls of the first contact window and the second contact window for forming the conductor protection layer, so as to reduce the step coverage during the formation of the conductor protection layer. difficulty. Moreover, the application of the method of the present invention can further solve the problem that the stability of the organic protective layer is affected by the use of organic solvents in the subsequent heavy-duty process of driving ICs, and the adhesion between the original inorganic insulating layer and the organic protective layer is relatively insufficient. , which in turn causes the problem of cracking of the conductor protection layer on the contact pad. In addition, the method of the present invention can improve product yield and reduce manufacturing cost at the same time.

附图说明 Description of drawings

为让本发明的上述和其它目的、特征、优点与实施例能更明显易懂,附图的详细说明如下:In order to make the above and other objects, features, advantages and embodiments of the present invention more comprehensible, the detailed description of the accompanying drawings is as follows:

第1图,绘示一种公知的液晶显示器的结构俯示图。FIG. 1 shows a top view of the structure of a known liquid crystal display.

第2图,绘示公知液晶显示面板中的一种于外围区域的接触垫的结构剖面示意图。FIG. 2 is a schematic cross-sectional view of a contact pad in a peripheral region of a conventional liquid crystal display panel.

第3A图,沿着第3B图中的A-A’、B-B’、C-C’剖面线的公知液晶显示面板中的薄膜晶体管阵列基板的剖面结构示意图。Fig. 3A is a schematic cross-sectional structure diagram of a thin film transistor array substrate in a known liquid crystal display panel along the lines A-A', B-B', and C-C' in Fig. 3B.

第3B图,绘示一种公知薄膜晶体管阵列基板的俯视示意图。FIG. 3B is a schematic top view of a conventional thin film transistor array substrate.

第4图,其绘示依照本发明优选实施例的一种薄膜晶体管阵列基板的俯视示意图。FIG. 4 is a schematic top view of a thin film transistor array substrate according to a preferred embodiment of the present invention.

第5A~5G图,其沿着第4图中的I-I’、J-J’、K-K’剖面线的一种制造薄膜晶体管阵列基板的工艺步骤的结构示意图。Figures 5A to 5G are structural schematic diagrams of a process step for manufacturing a thin film transistor array substrate along the I-I', J-J', and K-K' section lines in Figure 4.

【主要组件符号说明】[Description of main component symbols]

10:栅极线         14:栅接触垫区        20:信号电极10: Gate line 14: Gate contact pad area 20: Signal electrode

32:栅接触垫       50、60、206a、206b:源/漏极电极32: Gate contact pad 50, 60, 206a, 206b: Source/drain electrodes

70a、70a’、216a、216c:第一接触窗70a, 70a', 216a, 216c: first contact windows

102:下玻璃        106:液晶显示面板102: Lower glass 106: Liquid crystal display panel

110:栅接触垫区    122、204、208:接触垫110: Gate contact pad area 122, 204, 208: Contact pads

126:有机保护层    130、214a、214c、42a、42b:导体保护层126: Organic protective layer 130, 214a, 214c, 42a, 42b: Conductor protective layer

202、302:绝缘层   306:欧姆接触层       312:半调式光罩202, 302: insulating layer 306: ohmic contact layer 312: half-tone mask

320:第一倾斜侧壁  322:第二倾斜侧壁320: First sloped side wall 322: Second sloped side wall

12:影像显示区     15:接触垫区12: Image display area 15: Contact pad area

16:信号接触垫区   30:栅极16: Signal contact pad area 30: Gate

40、214b:像素电极 52:信号接触垫40, 214b: pixel electrode 52: signal contact pad

70b、70b’、216b:第二接触窗70b, 70b', 216b: second contact window

104:上玻璃        108:信号接触垫区104: Upper glass 108: Signal contact pad area

120、200:基板     124、210、308:无机绝缘层120, 200: Substrate 124, 210, 308: Inorganic insulating layer

128:接触窗        206:无机保护层128: Contact window 206: Inorganic protective layer

300:基板          304:半导体层300: substrate 304: semiconductor layer

212、310、310a、310b、310c、310a’、310b’、310c’:有机绝缘层212, 310, 310a, 310b, 310c, 310a', 310b', 310c': organic insulating layer

A-A’、B-B’、C-C’、I-I’、J-J’、K-K’:剖面线A-A', B-B', C-C', I-I', J-J', K-K': hatching

具体实施方式 Detailed ways

请参照第4图,其绘示依照本发明一优选实施例的一种薄膜晶体管阵列基板的俯视示意图。在第4图中,薄膜晶体管阵列基板包含影像显示区12、接触垫区15。其中,接触垫区15包含栅接触垫区14与信号接触垫区16。栅接触垫区14与信号接触垫区16电连接驱动IC(未绘示)。Please refer to FIG. 4 , which shows a schematic top view of a thin film transistor array substrate according to a preferred embodiment of the present invention. In FIG. 4 , the TFT array substrate includes an image display area 12 and a contact pad area 15 . Wherein, the contact pad region 15 includes a gate contact pad region 14 and a signal contact pad region 16 . The gate contact pad region 14 and the signal contact pad region 16 are electrically connected to a driving IC (not shown).

影像显示区12具有薄膜晶体管(thin film transistor;TFT)、像素电极40、栅极线(扫描线)10与信号线或信号电极(数据线)20。其中,薄膜晶体管更包含栅极30、源/漏极电极50和60。像素电极40会透过第二接触窗70b电连接漏极电极60。The image display area 12 has thin film transistors (thin film transistors; TFTs), pixel electrodes 40 , gate lines (scanning lines) 10 and signal lines or signal electrodes (data lines) 20 . Wherein, the thin film transistor further includes a gate 30 , source/drain electrodes 50 and 60 . The pixel electrode 40 is electrically connected to the drain electrode 60 through the second contact window 70b.

栅接触垫区14位于栅极线10的末端,用以电连接驱动IC(未绘示)。且栅接触垫区14包含栅接触垫32、导体保护层42b。其中,栅接触垫32会与栅极线10连接,且导体保护层42b会与栅驱动IC(未绘示)连接。The gate contact pad region 14 is located at the end of the gate line 10 for electrically connecting to a driving IC (not shown). And the gate contact pad region 14 includes a gate contact pad 32 and a conductor protection layer 42b. Wherein, the gate contact pad 32 is connected to the gate line 10 , and the conductor protection layer 42 b is connected to the gate driving IC (not shown).

信号接触垫区16位于信号线20的末端,用以电连接驱动IC(未绘示)。且信号接触垫区16包含信号接触垫52、导体保护层42a。其中,信号接触垫52会与信号线20连接,且导体保护层42a会与信号驱动IC(未绘示)连接。The signal contact pad area 16 is located at the end of the signal line 20 for electrically connecting to a driver IC (not shown). And the signal contact pad area 16 includes a signal contact pad 52 and a conductor protection layer 42a. Wherein, the signal contact pad 52 is connected to the signal line 20 , and the conductor protection layer 42 a is connected to the signal driving IC (not shown).

请参照第5A~5G图,其沿着第4图中的I-I’、J-J’、K-K’剖面线的一种制造薄膜晶体管阵列基板的工艺步骤的结构示意图。在第5A~5G图中,I-I’所示为外围区域上的栅极接触垫的剖面结构示意图,J-J’所示为有源区域的薄膜晶体管的剖面结构示意图,K-K’所示为外围区域上的信号接触垫的剖面结构示意图。Please refer to Figures 5A-5G, which are schematic structural diagrams of a process step for manufacturing a thin film transistor array substrate along the I-I', J-J', and K-K' section lines in Figure 4. In Figures 5A to 5G, II' shows the schematic cross-sectional structure of the gate contact pad on the peripheral region, J-J' shows the schematic cross-sectional structure of the thin film transistor in the active region, and K-K' Shown is a schematic cross-sectional structure diagram of the signal contact pads on the peripheral area.

在第5A图中,先沉积导体层(未绘示)于基板300上,再以第一道光罩工艺定义导体层,而分别于有源区域与栅外围区域上形成栅极30与栅接触垫32。其中,基板300优选为玻璃基板、硅基板、陶瓷基板、塑料基板或可挠性基板。导体层的优选材料是钼、铝、铜、铬、钛、银或上述材料的任意组合,且导体层可以是上述材料所形成的单层或多层结构。In FIG. 5A, a conductive layer (not shown) is first deposited on the substrate 300, and then the conductive layer is defined by the first photomask process, and the gate 30 and the gate contact are respectively formed on the active area and the peripheral area of the gate. Pad 32. Wherein, the substrate 300 is preferably a glass substrate, a silicon substrate, a ceramic substrate, a plastic substrate or a flexible substrate. The preferred material of the conductor layer is molybdenum, aluminum, copper, chromium, titanium, silver or any combination of the above materials, and the conductor layer can be a single-layer or multi-layer structure formed of the above materials.

在第5B图中,于基板300、栅极30与栅接触垫32上方依序形成绝缘层302、半导体层304与欧姆接触层306。接着,微影蚀刻半导体层304与欧姆接触层306,直至暴露出外围区域上的绝缘层302以及有源区域上栅极30上方其它部分的绝缘层302为止。其中,上述的绝缘层302的优选材料是氮化硅、氮氧化硅、氧化硅或上述材料所形成的单层或多层结构。半导体层304的优选材料是非晶硅、多晶硅、微晶硅或上述任意组合所形成的群组。上述的欧姆接触层306的优选掺杂材料可为N型掺杂或P型掺杂。In FIG. 5B , an insulating layer 302 , a semiconductor layer 304 and an ohmic contact layer 306 are sequentially formed on the substrate 300 , the gate 30 and the gate contact pad 32 . Next, the semiconductor layer 304 and the ohmic contact layer 306 are lithographically etched until the insulating layer 302 on the peripheral area and other parts of the insulating layer 302 above the gate 30 on the active area are exposed. Among them, the preferred material of the insulating layer 302 is silicon nitride, silicon oxynitride, silicon oxide or a single-layer or multi-layer structure formed of the above-mentioned materials. A preferred material of the semiconductor layer 304 is amorphous silicon, polycrystalline silicon, microcrystalline silicon or a group formed by any combination thereof. The preferred doping material of the aforementioned ohmic contact layer 306 may be N-type doping or P-type doping.

接着,如第5C图所示,沉积金属层(未绘示)于基板300上,再以微影蚀刻工艺定义金属层与殴姆接触层306,以形成源极电极50、漏极电极60与信道区54于有源区域上,且形成信号接触垫52于信号外围区上。其中,上述的金属层的优选材料是钼、铝、铜、铬、钛、银或上述材料的任意组合所形成的合金或多层金属层所组成的群组。Next, as shown in FIG. 5C, a metal layer (not shown) is deposited on the substrate 300, and then the metal layer and the Ohm contact layer 306 are defined by a lithographic etching process to form the source electrode 50, the drain electrode 60 and the The channel area 54 is on the active area, and the signal contact pad 52 is formed on the signal peripheral area. Among them, the preferred material of the above metal layer is molybdenum, aluminum, copper, chromium, titanium, silver or any combination of the above materials formed alloys or a group consisting of multi-layer metal layers.

如第5D图所示,依序于基板300上沉积无机绝缘层308与有机绝缘层310,再提供一半调式光罩312,以进行后续的有机绝缘层310的曝光显影,于多阶曝光之后形成不同厚度的图案化有机绝缘层310。其中上述的无机绝缘层308的材料包括氮化硅、氧化硅、氮氧化硅或上述任意组合所形成的无机绝缘层,且此无机绝缘层308的厚度优选为0.3微米(μm)。上述的有机绝缘层310的材料包括感光材料,且此有机绝缘层310的厚度优选介于5.3微米(μm)至5.6微米(μm)之间。As shown in FIG. 5D, an inorganic insulating layer 308 and an organic insulating layer 310 are sequentially deposited on the substrate 300, and then a half-tone mask 312 is provided for subsequent exposure and development of the organic insulating layer 310, which is formed after multi-level exposure. Patterned organic insulating layer 310 with different thicknesses. The above-mentioned inorganic insulating layer 308 is made of silicon nitride, silicon oxide, silicon oxynitride or any combination thereof, and the thickness of the inorganic insulating layer 308 is preferably 0.3 microns (μm). The above-mentioned material of the organic insulating layer 310 includes a photosensitive material, and the thickness of the organic insulating layer 310 is preferably between 5.3 micrometers (μm) and 5.6 micrometers (μm).

接着,如第5E图所示,利用半调式光罩312对有机绝缘层310曝光显影,以于基板300上的无机绝缘层308上形成图案化有机绝缘层310。此时,基板300上的图案化有机绝缘层310中会分别形成第一接触窗70a与第二接触窗70b于栅接触垫32/信号接触垫52以及漏极电极60上方,并暴露出栅接触垫32/信号接触垫52与漏极电极60上方的部分的无机绝缘层308。由于光罩312为半调式光罩,故显影后的有机绝缘层310会因为各区域曝光量的不同,而在不同的区域上有不同厚度。外围区域上的有机绝缘层310a和310c的厚度会小于有源区域上的有机绝缘层310b的厚度。其中,在优选实施例中,外围区域上的有机绝缘层310a和310c的厚度大致上介于0.9微米(μm)至1.4微米(μm)之间,而有源区域上的有机绝缘层310b的厚度大致上介于4.6微米(μm)至4.9微米(μm)之间。Next, as shown in FIG. 5E , the organic insulating layer 310 is exposed and developed by using the half tone mask 312 to form a patterned organic insulating layer 310 on the inorganic insulating layer 308 on the substrate 300 . At this time, the first contact window 70a and the second contact window 70b are respectively formed in the patterned organic insulating layer 310 on the substrate 300 above the gate contact pad 32/signal contact pad 52 and the drain electrode 60, and the gate contact is exposed. The portion of the inorganic insulating layer 308 above the pad 32 /signal contact pad 52 and the drain electrode 60 . Since the photomask 312 is a half-tone photomask, the organic insulating layer 310 after development will have different thicknesses in different regions due to the different exposure levels of each region. The thickness of the organic insulating layers 310a and 310c on the peripheral area may be smaller than the thickness of the organic insulating layer 310b on the active area. Wherein, in a preferred embodiment, the thickness of the organic insulating layers 310a and 310c on the peripheral region is approximately between 0.9 micrometers (μm) and 1.4 micrometers (μm), while the thickness of the organic insulating layer 310b on the active region Roughly between 4.6 microns (μm) and 4.9 microns (μm).

为了解决驱动IC重工工艺中因使用有机溶剂而造成接触垫上的导体保护层破裂的问题,且能同时降低导体保护层的形成时的阶梯覆盖性不佳的问题,本发明的一优选实施例藉由改变蚀刻条件,以于后续将形成导体保护层的第一接触窗与第二接触窗的侧壁上形成倾斜侧壁。请参照第5F图。在第5F图中,以有机绝缘层310a、310b和310c为罩幕,且以六氟化硫/氧气为蚀刻剂进行蚀刻工艺,蚀刻未为有机绝缘层310a、310b和310c所覆盖的无机绝缘层308,直至暴露出部分的栅接触垫32、信号接触垫52以及漏极电极60为止。In order to solve the problem that the conductor protective layer on the contact pad is broken due to the use of organic solvents in the IC rework process, and can simultaneously reduce the problem of poor step coverage during the formation of the conductor protective layer, a preferred embodiment of the present invention uses By changing the etching conditions, inclined sidewalls are formed on the sidewalls of the first contact window and the second contact window where the conductor protection layer will be formed later. Please refer to Figure 5F. In Figure 5F, the organic insulating layers 310a, 310b, and 310c are used as masks, and the etching process is performed using sulfur hexafluoride/oxygen as an etchant, and the inorganic insulating layers not covered by the organic insulating layers 310a, 310b, and 310c are etched. layer 308 until a portion of the gate contact pad 32 , the signal contact pad 52 and the drain electrode 60 are exposed.

如第5F图所示,由于六氟化硫/氧气的流量比控制在介于0.33~0.42之间,所以蚀刻后于外围区域与有源区域上所形成的第一接触窗70a’与第二接触窗70b’分别具有第一倾斜侧壁320与第二倾斜侧壁322。此时,在外围区域上会残留部分的有机绝缘层310a’和310c’,有源区域上也会残留厚度较高的有机绝缘层310b’,且栅接触垫32与信号接触垫52上已无有机绝缘层310a’和310c’。As shown in Figure 5F, since the flow ratio of sulfur hexafluoride/oxygen is controlled between 0.33-0.42, the first contact window 70a' and the second contact window 70a' formed on the peripheral area and the active area after etching The contact window 70b' has a first inclined sidewall 320 and a second inclined sidewall 322 respectively. At this time, part of the organic insulating layers 310a' and 310c' will remain on the peripheral area, and a relatively thick organic insulating layer 310b' will remain on the active area, and there are no more on the gate contact pad 32 and the signal contact pad 52. The organic insulating layers 310a' and 310c'.

其中,上述的第一倾斜侧壁320与栅接触垫32/信号接触垫52之间形成的第一夹角小于第二倾斜侧壁322与漏极电极60之间形成的第二夹角。在外围区域上的第一夹角较佳介于20°~50°之间,且于有源区域上的第二夹角较佳介于60°~80°之间。上述残留于外围区域上的有机绝缘层310a’和310c’的厚度较佳介于0.3微米(μm)至0.5微米(μm)之间。Wherein, the first included angle formed between the first inclined sidewall 320 and the gate contact pad 32 /signal contact pad 52 is smaller than the second included angle formed between the second inclined sidewall 322 and the drain electrode 60 . The first included angle on the peripheral area is preferably between 20°-50°, and the second included angle on the active area is preferably between 60°-80°. The thickness of the organic insulating layers 310a' and 310c' remaining on the peripheral region is preferably between 0.3 micrometer (μm) and 0.5 micrometer (μm).

最后,如第5G图所示,形成导体保护层(未绘示)于有机绝缘层310a’、310b’和310c’上,并填满外围区域与有源区域上的第一接触窗70a’与第二接触窗70b’。再以一道光罩工艺对导体保护层进行微影蚀刻工艺,以形成图案化导体保护层,而分别于有源区域与外围区域上定义出像素电极40与导体保护层42a、42b。其中,上述的导体保护层的材料优选为铟锡氧化物、铝锌氧化物、铟锌氧化物、氧化铟、氧化锡或上述任意组合所形成的导体保护层。Finally, as shown in FIG. 5G, a conductive protection layer (not shown) is formed on the organic insulating layers 310a', 310b' and 310c', and fills the first contact window 70a' and the first contact window 70a' on the peripheral area and the active area. The second contact window 70b'. Then, a photomask process is performed on the conductive protection layer to form a patterned conductive protection layer, and the pixel electrode 40 and the conductive protection layers 42a, 42b are defined on the active area and the peripheral area respectively. Wherein, the material of the above-mentioned conductor protection layer is preferably indium tin oxide, aluminum zinc oxide, indium zinc oxide, indium oxide, tin oxide or a conductor protection layer formed by any combination of the above.

在本发明的一优选实施例中,为了防止外围区域上的有机绝缘层310a’与310c’残留于栅接触垫32与信号接触垫52之上,更可以在以六氟化硫/氧气蚀刻部分的有机绝缘层310a、310b和310c以与门接触垫32、信号接触垫52与漏极电极60上方暴露出来的部分无机绝缘层308的步骤之后,以氧气为蚀刻剂蚀刻有机绝缘层310a’与310c’,以确保有机绝缘层310a’与310c’未残留于栅接触垫32与信号接触垫52上。其中,上述的氧气的流量优选为500sccm。In a preferred embodiment of the present invention, in order to prevent the organic insulating layers 310a' and 310c' on the peripheral region from remaining on the gate contact pad 32 and the signal contact pad 52, the part can be etched with sulfur hexafluoride/oxygen After the step of using the organic insulating layer 310a, 310b and 310c of the exposed part of the inorganic insulating layer 308 above the AND gate contact pad 32, the signal contact pad 52 and the drain electrode 60, the organic insulating layer 310a' and the organic insulating layer 310a' are etched with oxygen as an etchant. 310c′ to ensure that the organic insulating layers 310a′ and 310c′ do not remain on the gate contact pad 32 and the signal contact pad 52 . Among them, the above-mentioned flow rate of oxygen is preferably 500 sccm.

由上述可知,应用本发明的方法可以利用调整六氟化硫/氧气的蚀刻条件,以于后续将形成导体保护层的第一接触窗与第二接触窗的侧壁上蚀刻出一较为平缓的轮廓,以降低导体保护层的形成时的阶梯覆盖的难度。且应用本发明的方法更可以解决于后续驱动IC的重工工艺中,因有机溶剂的使用而影响有机保护层的安定性,又加上原本无机绝缘层与有机保护层间的粘着力就比较不足,进而造成接触垫上的导体保护层破裂的问题。此外,本发明的方法更可以提高产品良率,并同时降低制造成本。From the above, it can be known that applying the method of the present invention can utilize the adjustment of the etching conditions of sulfur hexafluoride/oxygen to etch out a relatively gentle layer on the sidewalls of the first contact window and the second contact window that will form the conductor protection layer later. profile to reduce the difficulty of step coverage during the formation of the conductor protective layer. Moreover, the application of the method of the present invention can further solve the problem that the stability of the organic protective layer is affected by the use of organic solvents in the subsequent heavy-duty process of driving ICs, and the adhesion between the original inorganic insulating layer and the organic protective layer is relatively insufficient. , which in turn causes the problem of cracking of the conductor protection layer on the contact pad. In addition, the method of the present invention can improve product yield and reduce manufacturing cost at the same time.

虽然本发明已以一优选实施例揭露如上,然其并非用以限定本发明,任何本领域普通技术人员,在不脱离本发明的精神和范围内,当可作各种的更动与润饰,因此本发明的保护范围当视权利要求所界定者为准。Although the present invention has been disclosed above with a preferred embodiment, it is not intended to limit the present invention. Any person skilled in the art may make various modifications and modifications without departing from the spirit and scope of the present invention. Therefore, the scope of protection of the present invention should be defined by the claims.

Claims (23)

1.一种薄膜晶体管阵列基板的制造方法,包含:1. A method for manufacturing a thin film transistor array substrate, comprising: 形成至少一个薄膜晶体管于基板的有源区域上与至少一个接触垫于该基板的外围区域之上,且该薄膜晶体管具有栅极、源极与漏极;forming at least one thin film transistor on the active area of the substrate and at least one contact pad on the peripheral area of the substrate, and the thin film transistor has a gate, a source and a drain; 形成无机绝缘层覆盖该薄膜晶体管与该接触垫;forming an inorganic insulating layer covering the thin film transistor and the contact pad; 形成有机绝缘层于该无机绝缘层上;forming an organic insulating layer on the inorganic insulating layer; 图案化该有机绝缘层以形成至少一个第一接触窗及至少一个第二接触窗,并分别暴露出位于该接触垫上及该源极/该漏极上的该无机绝缘层,且该外围区域上的该有机绝缘层的厚度小于该有源区域上的该有机绝缘层的厚度;patterning the organic insulating layer to form at least one first contact window and at least one second contact window, and respectively exposing the inorganic insulating layer on the contact pad and the source/drain, and on the peripheral region The thickness of the organic insulating layer is smaller than the thickness of the organic insulating layer on the active region; 以六氟化硫/氧气蚀刻该有机绝缘层及该第一和第二接触窗所暴露的该无机绝缘层至暴露出该接触垫及该源极/该漏极为止,以分别在第一接触窗的侧壁上形成第一倾斜侧壁及在第二接触窗的侧壁上形成第二倾斜侧壁,并残留部分该有机绝缘层于该外围区域之上,其中该六氟化硫/氧气的流量比介于0.33~0.42之间;以及Etching the organic insulating layer and the inorganic insulating layer exposed by the first and second contact windows with sulfur hexafluoride/oxygen until the contact pad and the source/drain are exposed, so that the first contact forming a first inclined sidewall on the sidewall of the window and forming a second inclined sidewall on the sidewall of the second contact window, and leaving part of the organic insulating layer on the peripheral region, wherein the sulfur hexafluoride/oxygen The flow ratio is between 0.33 and 0.42; and 形成图案化导体保护层于该第一和第二接触窗上。A patterned conductor protection layer is formed on the first and second contact windows. 2.如权利要求1的方法,其中该接触垫与该栅极同时形成。2. The method of claim 1, wherein the contact pad is formed simultaneously with the gate. 3.如权利要求1的方法,其中该接触垫与该源极及该漏极同时形成。3. The method of claim 1, wherein the contact pad is formed simultaneously with the source and the drain. 4.如权利要求1的方法,其中该无机绝缘层的厚度为0.3微米。4. The method of claim 1, wherein the thickness of the inorganic insulating layer is 0.3 microns. 5.如权利要求1的方法,其中该有机绝缘层的厚度介于5.3微米至5.6微米。5. The method of claim 1, wherein the organic insulating layer has a thickness ranging from 5.3 microns to 5.6 microns. 6.如权利要求1的方法,其中该外围区域上的该有机绝缘层的厚度介于0.9微米至1.4微米之间。6. The method of claim 1, wherein the thickness of the organic insulating layer on the peripheral region is between 0.9 μm and 1.4 μm. 7.如权利要求1的方法,其中该有源区上的该有机绝缘层的厚度介于4.6微米至4.9微米之间。7. The method of claim 1, wherein the thickness of the organic insulating layer on the active region is between 4.6 microns and 4.9 microns. 8.如权利要求1的方法,其中以六氟化硫/氧气蚀刻该有机绝缘层及该第一和第二接触窗所暴露的该无机绝缘层至暴露出该接触垫及该源极/该漏极步骤之后,更包含:8. The method of claim 1, wherein the organic insulating layer and the inorganic insulating layer exposed by the first and second contact windows are etched with sulfur hexafluoride/oxygen to expose the contact pad and the source/the After the drain step, further include: 以氧气蚀刻该有机绝缘层,以确保有机绝缘层未残留于该接触垫上,且该氧气流量为500sccm。The organic insulating layer is etched with oxygen to ensure that the organic insulating layer does not remain on the contact pad, and the oxygen flow rate is 500 sccm. 9.如权利要求8的方法,其中残留于该外围区上部分的该有机绝缘层厚度介于0.3微米至0.5微米。9. The method of claim 8, wherein the thickness of the organic insulating layer remaining on the peripheral region is between 0.3 μm and 0.5 μm. 10.如权利要求1的方法,其中该无机绝缘层的材料包括氮化硅、氧化硅、氮氧化硅或上述任意组合所形成的组。10. The method of claim 1, wherein the material of the inorganic insulating layer comprises silicon nitride, silicon oxide, silicon oxynitride or a group formed by any combination thereof. 11.如权利要求1的方法,其中该有机绝缘层的材料包括感光材料。11. The method of claim 1, wherein a material of the organic insulating layer comprises a photosensitive material. 12.如权利要求1的方法,其中该图案化导体保护层的材料包括铟锡氧化物、铝锌氧化物、铟锌氧化物、氧化铟、氧化锡或上述任意组合所形成的组。12. The method of claim 1, wherein the material of the patterned conductor protection layer comprises indium tin oxide, aluminum zinc oxide, indium zinc oxide, indium oxide, tin oxide or a group formed by any combination thereof. 13.如权利要求1的方法,其中该第一接触窗的第一倾斜侧壁与该接触垫之间的角度小于该第二接触窗的第二倾斜侧壁与该源极/该漏极之间的角度。13. The method of claim 1, wherein an angle between the first sloped sidewall of the first contact and the contact pad is smaller than that between the second sloped sidewall of the second contact and the source/drain angle between. 14.如权利要求13的方法,其中该具有第一倾斜侧壁的该第一接触窗的角度介于20°~50°之间。14. The method of claim 13, wherein an angle of the first contact window having a first inclined sidewall is between 20°˜50°. 15.如权利要求13的方法,其中该具有第二倾斜侧壁的该第二接触窗的角度介于60°~80°之间。15. The method of claim 13, wherein an angle of the second contact window having a second sloped sidewall is between 60° and 80°. 16.一种薄膜晶体管阵列基板,包括:16. A thin film transistor array substrate, comprising: 至少一个薄膜晶体管,设置于基板的有源区上,且该薄膜晶体管具有栅极、源极及漏极;At least one thin film transistor is disposed on the active area of the substrate, and the thin film transistor has a gate, a source and a drain; 至少一个接触垫,设置于该基板的外围区上;at least one contact pad disposed on the peripheral area of the substrate; 无机绝缘层,设置于该薄膜晶体管与该接触垫上;an inorganic insulating layer disposed on the thin film transistor and the contact pad; 有机绝缘层,设置于该无机绝缘层上,且该无机绝缘层与该有机绝缘层内具有至少一个第一接触窗以暴露出该接触垫及至少一个第二接触窗以暴露出该漏极/该源极,该第一接触窗的侧壁与该接触垫之间形成第一夹角及该第二接触窗的侧壁与该漏极/该源极之间形成第二夹角,其中,该外围区上的该有机绝缘层的厚度小于该有源区上的该有机绝缘层的厚度,且该第一夹角小于该第二夹角;以及The organic insulating layer is disposed on the inorganic insulating layer, and the inorganic insulating layer and the organic insulating layer have at least one first contact window to expose the contact pad and at least one second contact window to expose the drain/ For the source, a first angle is formed between the sidewall of the first contact window and the contact pad, and a second angle is formed between the sidewall of the second contact window and the drain/source, wherein, The thickness of the organic insulating layer on the peripheral region is smaller than the thickness of the organic insulating layer on the active region, and the first included angle is smaller than the second included angle; and 导体保护层,设置于该第一和第二接触窗上。The conductor protection layer is arranged on the first and second contact windows. 17.如权利要求16的薄膜晶体管阵列基板,其中该外围区上的该有机绝缘层的厚度介于0.3微米至0.5微米之间。17. The thin film transistor array substrate of claim 16, wherein the thickness of the organic insulating layer on the peripheral region is between 0.3 microns and 0.5 microns. 18.如权利要求16的薄膜晶体管阵列基板,其中无机绝缘层的厚度为0.3微米。18. The thin film transistor array substrate according to claim 16, wherein the thickness of the inorganic insulating layer is 0.3 microns. 19.如权利要求16的薄膜晶体管阵列基板,其中该第一夹角的角度范围介于20°~50°之间。19. The thin film transistor array substrate of claim 16, wherein the angle range of the first included angle is between 20°-50°. 20.如权利要求16的薄膜晶体管阵列基板,其中该第二夹角的角度范围介于60°~80°之间。20. The thin film transistor array substrate as claimed in claim 16, wherein the angle range of the second included angle is between 60°-80°. 21.如权利要求16的薄膜晶体管阵列基板,其中该无机绝缘层的材料包括氮化硅、氧化硅、氮氧化硅或上述任意组合所形成的组。21. The thin film transistor array substrate according to claim 16, wherein the material of the inorganic insulating layer comprises silicon nitride, silicon oxide, silicon oxynitride or a group formed by any combination thereof. 22.如权利要求16的薄膜晶体管阵列基板,其中该有机绝缘层的材料包括感光材料。22. The thin film transistor array substrate as claimed in claim 16, wherein the material of the organic insulating layer comprises a photosensitive material. 23.如权利要求16的薄膜晶体管阵列基板,其中该导体保护层的材料包括铟锡氧化物、铝锌氧化物、铟锌氧化物、氧化铟、氧化锡或上述任意组合所形成的组。23. The thin film transistor array substrate according to claim 16, wherein the material of the conductor protection layer comprises indium tin oxide, aluminum zinc oxide, indium zinc oxide, indium oxide, tin oxide or a group formed by any combination thereof.
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