CN100457960C - Shielding with isolation layer and process equipment comprising same - Google Patents
Shielding with isolation layer and process equipment comprising same Download PDFInfo
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- CN100457960C CN100457960C CNB200610075368XA CN200610075368A CN100457960C CN 100457960 C CN100457960 C CN 100457960C CN B200610075368X A CNB200610075368X A CN B200610075368XA CN 200610075368 A CN200610075368 A CN 200610075368A CN 100457960 C CN100457960 C CN 100457960C
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- 238000001704 evaporation Methods 0.000 claims abstract description 119
- 230000008020 evaporation Effects 0.000 claims abstract description 119
- 238000000034 method Methods 0.000 claims abstract description 53
- 230000005540 biological transmission Effects 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 239000000758 substrate Substances 0.000 claims description 38
- 238000012546 transfer Methods 0.000 claims description 17
- 238000004140 cleaning Methods 0.000 claims description 13
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 10
- 238000007740 vapor deposition Methods 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims 15
- 230000008021 deposition Effects 0.000 claims 4
- 150000002500 ions Chemical class 0.000 claims 1
- 238000002955 isolation Methods 0.000 abstract description 89
- 238000005019 vapor deposition process Methods 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 238000010586 diagram Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 238000001883 metal evaporation Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000013461 design Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000003908 quality control method Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
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- 239000004065 semiconductor Substances 0.000 description 1
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Abstract
Description
技术领域 technical field
本发明是关于一种屏蔽装置及配合使用的蒸镀工艺设备;具体而言,本发明关于一种屏蔽装置及配合使用的蒸镀工艺设备,供于基板上进行蒸镀工艺。The present invention relates to a shielding device and vapor deposition process equipment used in conjunction with it; specifically, the present invention relates to a shielding device and vapor deposition process equipment used in conjunction with it, which are used for vapor deposition on a substrate.
背景技术 Background technique
蒸镀工艺已广泛应用于薄膜工艺、半导体晶圆工艺及其它的精密工艺上。一般的蒸镀工艺是将待蒸镀的基板与屏蔽结合,再行送入蒸镀室中进行蒸镀程序。屏蔽上均有多个预设微小开孔,藉此蒸镀材料得以穿透屏蔽而沉积于基板上的预设位置,以形成所需的成品。Evaporation process has been widely used in thin film process, semiconductor wafer process and other precision processes. The general evaporation process is to combine the substrate to be evaporated with the shield, and then send it into the evaporation chamber to perform the evaporation process. There are a plurality of preset tiny openings on the shield, so that the evaporated material can penetrate through the shield and be deposited on the predetermined position on the substrate to form the desired finished product.
图1a所示为习知的蒸镀室40、基板30及屏蔽10。如图1a所示,为求蒸镀的对位精确,必需将屏蔽10与受蒸镀的基板30紧密结合。此外,屏蔽10与基板30紧密结合可避免蒸镀图案晕开的情形。FIG. 1 a shows a
图1b所示为习知技术中蒸镀工艺设备,主要包括有机蒸镀室41、金属蒸镀室43、封装室45及其间的传送室90。结合的屏蔽10与基板30于上述的蒸镀工艺设备中进行蒸镀程序。FIG. 1 b shows the evaporation process equipment in the prior art, which mainly includes an organic evaporation chamber 41 , a metal evaporation chamber 43 , an encapsulation chamber 45 and a transfer chamber 90 therebetween. The combined
由于屏蔽10与基板30于蒸镀程序中紧密结合,因此屏蔽的清洁程度便对后续成品的良率有相当程度的影响。若屏蔽上沾染过多的附着物,则会在工艺中转移至基板30上并形成暗点。因此传统的工艺中需定期将屏蔽10移出蒸镀工艺设备之外并加以清洁,以去除其上的附着物。然而由于屏蔽10本身的机械强度问题,其表面多未加工处理。因此屏蔽10表面所沾染的附着物不易清除,而导致清洁程序的难度提高。Since the
发明内容 Contents of the invention
本发明的主要目的在于提供一种屏蔽装置,具有较高的重复利用性。The main purpose of the present invention is to provide a shielding device with high reusability.
本发明的另一目的在于提供一种屏蔽装置,可提高生产成品的良率。Another object of the present invention is to provide a shielding device that can improve the yield of finished products.
本发明的另一目的在于提供一种屏蔽装置,具有较高的可清洁性。Another object of the present invention is to provide a shielding device with high cleanability.
本发明的另一目的在于提供一种蒸镀工艺设备,可有效地清洁使用后的屏蔽装置。Another object of the present invention is to provide an evaporation process equipment that can effectively clean the shielding device after use.
本发明的另一目的在于提供一种蒸镀工艺设备,可提高生产成品的良率。Another object of the present invention is to provide an evaporation process equipment that can improve the yield of finished products.
本发明的屏蔽装置供与基板配合使用,主要包含屏蔽本体及隔离层。屏蔽本体包含对应于蒸镀源的蒸镀源面。隔离层则形成于蒸镀源面上,使屏蔽本体位于隔离层及基板之间。隔离层的接触角大于蒸镀源面的接触角。此外,隔离层的表面张力大于蒸镀源面的表面张力。因此附着物附着于隔离层的附着力小于附着于蒸镀源面时的附着力。换言之,即附着于隔离层上的附着物较易清除。The shielding device of the present invention is used in conjunction with the substrate, and mainly includes a shielding body and an isolation layer. The shielding body includes an evaporation source surface corresponding to the evaporation source. The isolation layer is formed on the evaporation source surface, so that the shielding body is located between the isolation layer and the substrate. The contact angle of the isolation layer is larger than that of the evaporation source surface. In addition, the surface tension of the isolation layer is greater than that of the evaporation source surface. Therefore, the adhesion of the attachment to the isolation layer is smaller than that of the attachment to the evaporation source surface. In other words, the attachments attached to the isolation layer are easier to remove.
在较佳实施例中,隔离层由等离子体诱发聚合碳氟化合物所构成,且具80度以上的接触角。In a preferred embodiment, the isolation layer is made of plasma-induced polymerized fluorocarbon and has a contact angle greater than 80 degrees.
本发明亦包含使用上述屏蔽装置的蒸镀工艺设备,主要包含:蒸镀单元、隔离层形成单元及屏蔽传输装置。隔离层形成单元与蒸镀单元连接。屏蔽传输装置分别连接至蒸镀单元及隔离层形成单元的内部。在屏蔽装置藉由屏蔽传输装置送入蒸镀单元内进行蒸镀程序前,需先进入隔离层形成单元处理。当屏蔽装置于隔离层形成单元中完成反应并形成隔离层后,屏蔽传输装置将形成有隔离层的屏蔽装置传送至蒸镀单元进行蒸镀程序。The present invention also includes evaporation process equipment using the above shielding device, which mainly includes: an evaporation unit, an isolation layer forming unit and a shielding transmission device. The isolation layer forming unit is connected to the vapor deposition unit. The shield transmission device is respectively connected to the interior of the vapor deposition unit and the isolation layer forming unit. Before the shielding device is sent into the evaporation unit by the shielding transfer device to perform the evaporation process, it needs to enter the isolation layer forming unit for processing. After the shielding device completes the reaction in the isolation layer forming unit and forms the isolation layer, the shielding transfer device transfers the shielding device with the isolation layer to the evaporation unit for evaporation.
附图说明 Description of drawings
图1a为习知技术中蒸镀装置及屏蔽装置的示意图;Figure 1a is a schematic diagram of an evaporation device and a shielding device in the prior art;
图1b为习知技术中蒸镀工艺设备的示意图;Fig. 1b is the schematic diagram of evaporation process equipment in the prior art;
图2为本发明中蒸镀单元与屏蔽装置的实施例示意图;2 is a schematic diagram of an embodiment of an evaporation unit and a shielding device in the present invention;
图3为本发明中屏蔽装置实施例的组件分解图;Fig. 3 is an exploded view of components of an embodiment of a shielding device in the present invention;
图4为本发明中隔离层形成单元及屏蔽装置的实施例示意图;4 is a schematic diagram of an embodiment of an isolation layer forming unit and a shielding device in the present invention;
图5为隔离层与接触面的接触角示意图;Fig. 5 is a schematic diagram of the contact angle between the isolation layer and the contact surface;
图6为本发明另一实施例示意图;Fig. 6 is a schematic diagram of another embodiment of the present invention;
图7为本发明蒸镀工艺设备实施例的示意图;7 is a schematic diagram of an embodiment of the evaporation process equipment of the present invention;
图8为本发明蒸镀工艺设备另一实施例的示意图;8 is a schematic diagram of another embodiment of the evaporation process equipment of the present invention;
图9为本发明蒸镀工艺设备另一实施例的示意图。FIG. 9 is a schematic diagram of another embodiment of the evaporation process equipment of the present invention.
主要组件符号说明Explanation of main component symbols
10屏蔽10 Shield
30基板30 substrates
40蒸镀室40 evaporation chamber
41有机蒸镀室41 organic evaporation chamber
43金属蒸镀室43 metal evaporation chamber
45封装室45 packaging chamber
90传送室90 Teleportation Room
100屏蔽装置100 shielding device
110屏蔽本体110 shield body
111蒸镀源面111 evaporation source surface
113接触面113 contact surface
130隔离层130 isolation layer
150基板隔离层150 substrate isolation layer
300基板300 substrates
350蒸镀源350 evaporation source
400等离子体反应室400 plasma reaction chamber
410碳氟气体导入装置410 fluorocarbon gas introduction device
500液滴500 droplets
510切线510 tangent
600蒸镀单元600 evaporation units
610蒸镀室610 evaporation chamber
700隔离层形成单元700 isolation layer forming units
750屏蔽清洁单元750 shielded cleaning unit
800屏蔽传输装置800 shielded transmission device
810第一传输方向810 first transmission direction
820第二传输方向820 second transmission direction
900传输室900 Transfer Room
具体实施方式 Detailed ways
本发明提供一种屏蔽装置100,供在蒸镀工艺中与基板300配合使用。本发明同时包含一种使用上述屏蔽装置100的蒸镀工艺设备。在较佳实施例中,蒸镀工艺是包含有机蒸镀、化学蒸镀及其它适用于精密工艺的蒸镀工艺。此外,此处所言的基板300优选包含传统基板、薄膜及其它可进行蒸镀工艺的材料。The present invention provides a shielding device 100 for use with a
如图2及图3所示,本发明的屏蔽装置100主要包含屏蔽本体110及隔离层130。屏蔽本体110包含蒸镀源面111,蒸镀源面111为屏蔽本体110对应于蒸镀源350的一面。在较佳实施例中,屏蔽本体110由极薄的金属材质所构成。然而在不同实施例中,屏蔽本体110亦可由其它适于作为蒸镀屏蔽的材质所构成。此外,屏蔽本体110上具有多个微开孔,藉此蒸镀材料得以穿透屏蔽本体110而沉积于基板300上的预设位置。As shown in FIG. 2 and FIG. 3 , the shielding device 100 of the present invention mainly includes a shielding
如图2所示,隔离层130形成于蒸镀源面111上,且位于蒸镀源面111及蒸镀源350之间。换言之,屏蔽本体110位于隔离层130及基板300之间。在较佳实施例中,隔离层130以等离子体诱发聚合的方式形成于蒸镀源面111上。因此隔离层130亦具有多个微开孔,以对应于屏蔽本体110上的微开孔。然而在不同实施例中,隔离层130亦可以例如贴附、溅镀等其它方式形成于蒸镀源面111上。As shown in FIG. 2 , the
为配合一般设计及品管的要求,隔离层130的厚度优选在5微米(μm)以下,亦即小于或等于5微米。在特殊的工艺中,当隔离层130的厚度介于1微米至5微米之间时,可有效控制所蒸镀时所产生的阴影效应(shadoweffect),以得到所需的蒸镀结果。此外,当蒸镀结果需避免阴影效应的发生时,隔离层130的厚度亦可限制在10纳米(nm)以下。In order to meet the requirements of general design and quality control, the thickness of the
隔离层130优选由碳氟化合物所组成,然而在不同实施例中,隔离层130可为等离子体诱发高分子聚合层。在如图4所示的实施例中,屏蔽本体110被送入等离子体反应室400中,藉由等离子体工艺在蒸镀源面111上形成高分子聚合的隔离层130。此外,在此实施例中优选以碳氟气体作为工作气体,以在蒸镀源面111上形成由等离子体诱发聚合碳氟化合物所形成隔离层130。The
在图4所示的实施例中,屏蔽本体110进行等离子体工艺以形成隔离层130的反应时间依照所需形成的隔离层130厚度而定。在较佳实施例中,反应时间控制于10秒至100秒之间。反应时的温度则以不使屏蔽本体110产生过度形变为原则。在较佳实施例中,反应时的温度控制于室温附近。In the embodiment shown in FIG. 4 , the reaction time for the shielding
如图5所示,隔离层130的接触角θ1大于蒸镀源面111的接触角θ2。此处所言的接触角是以水作为测量的标准液滴500。当液滴500置于待测量的表面时,由液滴500边缘与待测表面的交点所画出的切线510与待测表面所夹于液滴500侧的角度即为接触角。在如图5所示的实施例中,隔离层130优选具有大于80度的接触角。As shown in FIG. 5 , the contact angle θ 1 of the
如图5所示,液滴500在附着于隔离层130时与隔离层130的接触面积为a1;相同的液滴500在附着于蒸镀源面111时与蒸镀源面111的接触面积为a2。由于隔离层130的接触角θ1大于蒸镀源面111的接触角θ2,因此接触面积a1会小于接触面积a2。同理亦可应用于水以外的附着物。相同性质的附着物于附着隔离层130时的接触面积小于附着于蒸镀源面111时的接触面积。换言之,即隔离层130具有较蒸镀源面111为大的表面张力,可使附着物附着时的接触面积减小。As shown in Figure 5, the contact area of the droplet 500 with the
特定表面的表面张力与接触角具有正向相关的关系。当接触角越大时,表示特定表面的表面张力也越大。此处所言的表面张力是指在特定表面与附着物接触时所能提供沿该表面分布的分力。当表面张力弱时,则附着物与该表面的附着关系较密切。当表面张力强时,则附着物与表面的附着关系较微弱。如图5所示,由于隔离层130的表面张力较蒸镀源面111的表面张力为强,故液滴500附着于蒸镀源面111的附着关系较其附着于隔离层130的附着关系为密切。换言之,即附着物附着于蒸镀源面111时较不易分离。The surface tension of a particular surface has a positive correlation with the contact angle. When the contact angle is larger, it means that the surface tension of a specific surface is also larger. The surface tension mentioned here refers to the component force that can be distributed along the surface when a specific surface is in contact with the attachment. When the surface tension is weak, the attachment relationship between the attachment and the surface is relatively close. When the surface tension is strong, the attachment relationship between the attachment and the surface is weak. As shown in Figure 5, since the surface tension of the
附着物的附着力与接触角有负相关的关系,当接触角越大时,附着物的附着力则越小。由于附着物于附着隔离层130时的接触角θ1大于附着于蒸镀源面111时的接触角θ2,故相较于蒸镀源面111,相同性质的附着物对于隔离层130有较小的附着力。换言之,若隔离层130与蒸镀源面111均附着有附着物时,隔离层130上的附着物较易清除。There is a negative correlation between the adhesion of the attachment and the contact angle, and the larger the contact angle, the smaller the adhesion of the attachment. Since the contact angle θ 1 of the attachment when attached to the
在蒸镀过程中,屏蔽装置100上常会附着有不需要的附着物。若未适当清除,往往会影响产品的良率。由于隔离层130具有较蒸镀源面111为大的接触角及表面张力,故以隔离层130覆盖于蒸镀源面上后,可使屏蔽装置100上的附着物清洁难度减低。During the evaporation process, unwanted deposits often adhere to the shielding device 100 . If not properly cleaned, it often affects the yield of the product. Since the
图6所示为本发明的另一实施例。在此实施例中,屏蔽装置100上进一步包含接触面113,且接触面113位于蒸镀源面111的反侧。接触面113上形成有基板隔离层150。在较佳实施例中,基板隔离层150以等离子体诱发聚合的方式形成于接触面113上。因此基板隔离层150亦具有多个微开孔,以对应于屏蔽本体110上的微开孔。然而在不同实施例中,基板隔离层150亦可以例如贴附、溅镀等其它方式形成于接触面113上。Figure 6 shows another embodiment of the present invention. In this embodiment, the shielding device 100 further includes a contact surface 113 , and the contact surface 113 is located on the opposite side of the
为配合一般设计及品管的要求,基板隔离层150的厚度较优选在5微米(μm)以下,亦即小于或等于5微米。在特殊的工艺中,当基板隔离层150的厚度介于1微米至5微米之间时,可有效控制所蒸镀时所产生的阴影效应(shadow effect),以得到所需的蒸镀结果。此外,当蒸镀结果需避免阴影效应的发生时,基板隔离层150的厚度亦可限制在10纳米(nm)以下。In order to meet the requirements of general design and quality control, the thickness of the substrate isolation layer 150 is preferably less than 5 micrometers (μm), that is, less than or equal to 5 μm. In a special process, when the thickness of the substrate isolation layer 150 is between 1 micron and 5 microns, the shadow effect generated during evaporation can be effectively controlled to obtain the desired evaporation result. In addition, when the shadow effect needs to be avoided as a result of evaporation, the thickness of the substrate isolation layer 150 can also be limited to less than 10 nanometers (nm).
基板隔离层150优选由碳氟化合物所组成,然而在不同实施例中,基板隔离层150可为等离子体诱发高分子聚合层。基板隔离层150的接触角是大于接触面113的接触角。此处所言的接触角是系以水作为测量的标准液滴。在较佳实施例中,基板隔离层150具有大于80度的接触角。此外,在较佳实施例中,基板隔离层150的形成方式均与隔离层130的形成方式相同或近似。The substrate isolation layer 150 is preferably composed of fluorocarbon, however, in different embodiments, the substrate isolation layer 150 may be a plasma-induced polymer polymerization layer. The contact angle of the substrate isolation layer 150 is greater than that of the contact surface 113 . The contact angle mentioned here is based on water as a standard droplet for measurement. In a preferred embodiment, the substrate isolation layer 150 has a contact angle greater than 80 degrees. In addition, in a preferred embodiment, the formation method of the substrate isolation layer 150 is the same as or similar to that of the
本发明进一步包含使用上述屏蔽装置100的蒸镀工艺设备。如图7所示,本发明的蒸镀工艺设备包含蒸镀单元600、隔离层形成单元700及屏蔽传输装置800。蒸镀单元600优选包含蒸镀室610,如图2所示。在较佳实施例中,蒸镀单元600包含有机蒸镀室及金属蒸镀室等蒸镀装置。然而在不同实施例中,蒸镀单元600亦包含其它类型的蒸镀装置。The present invention further includes evaporation process equipment using the above-mentioned shielding device 100 . As shown in FIG. 7 , the evaporation process equipment of the present invention includes an
隔离层形成单元700与蒸镀单元600连接。在较佳实施例中,如图4所示,隔离层形成单元700包含平板式等离子体反应装置400。然而在不同的实施例中,隔离层形成单元700亦可包含感应耦合电将反应装置等其它等离子体反应装置。此外,所采用的等离子体反应装置400优选具有碳氟气体导入装置410。藉由碳氟气体导入装置410导入碳氟气体作为工作气体,以在屏蔽本体110的蒸镀源面111上形成由等离子体诱发聚合碳氟化合物所形成的隔离层130,或/及在接触面113上形成基板隔离层150。必需注意的是,隔离层形成单元700中进行反应的温度需以不使屏蔽本体110产生形变为原则。在较佳实施例中,反应时的温度控制于室温附近。The isolation
如图7所示,屏蔽传输装置800分别连接至蒸镀单元600及隔离层形成单元700的内部。在屏蔽本体110藉由屏蔽传输装置800送入蒸镀单元600内进行蒸镀程序前,需先进入隔离层形成单元700处理。当屏蔽本体110于隔离层形成单元700中完成反应并形成包含隔离层130的屏蔽装置100后,屏蔽传输装置800沿第一传输方向810将形成有隔离层130的屏蔽装置100传送至蒸镀单元600。在较佳实施例中,当蒸镀单元600内的蒸镀程序完成后,屏蔽传输装置800沿第二传输方向820将使用过的屏蔽装置100反向传送出蒸镀单元600进行清洁及去除附着物的程序。清洁后的屏蔽装置100再送入隔离层形成单元700形成隔离层130。As shown in FIG. 7 , the
在如图8所示的实施例中,本发明的蒸镀工艺设备进一步包含传输室900。传输室900连通蒸镀单元600及隔离层形成单元700,且容纳屏蔽传输装置800的中段部分。藉由传输室900的设置,可减少屏蔽装置100在传输过程遭受污染的可能性。In the embodiment shown in FIG. 8 , the evaporation process equipment of the present invention further includes a
在如图9所示的实施例中,本发明的蒸镀工艺设备进一步包含屏蔽清洁单元750。屏蔽清洁单元750优选分别藉由屏蔽传输装置800连接蒸镀单元600及隔离层形成单元700。当蒸镀单元600内的蒸镀程序完成后,屏蔽传输装置800将使用过的屏蔽装置100传送至屏蔽清洁单元750进行清洁及去除附着物的程序。清洁后的屏蔽装置100再送入隔离层形成单元700形成隔离层130或/及基板隔离层150。以上所言的清洁及去除附着物程序包含干式及湿式的清洁方式,以及其它具有类似功能的清洁方式。In the embodiment shown in FIG. 9 , the evaporation process equipment of the present invention further includes a
本发明已由上述相关实施例加以描述,然而上述实施例仅为实施本发明的范例。必需指出的是,已揭露的实施例并未限制本发明的范围。相反地,包含于权利要求所述的精神及范围的修改及等同设置均包含于本发明的范围内。The present invention has been described by the above-mentioned related embodiments, however, the above-mentioned embodiments are only examples for implementing the present invention. It must be pointed out that the disclosed embodiments do not limit the scope of the present invention. On the contrary, modifications and equivalent arrangements included in the spirit and scope described in the claims are included in the scope of the present invention.
Claims (12)
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| FI20080248L (en) * | 2008-03-28 | 2009-09-29 | Savcor Face Group Oy | Chemical gas coating and method for forming gas coating |
| CN106702319A (en) * | 2017-03-30 | 2017-05-24 | 京东方科技集团股份有限公司 | Evaporation method |
| CN106978589B (en) * | 2017-04-20 | 2019-03-08 | 京东方科技集团股份有限公司 | Retaining device and evaporated device for evaporated device |
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|---|---|---|---|---|
| US5154797A (en) * | 1991-08-14 | 1992-10-13 | The United States Of America As Represented By The Secretary Of The Army | Silicon shadow mask |
| US5268068A (en) * | 1992-12-08 | 1993-12-07 | International Business Machines Corporation | High aspect ratio molybdenum composite mask method |
| US5744214A (en) * | 1997-01-30 | 1998-04-28 | International Business Machines Corporation | Corrosion resistant molybdenum mask |
| US6524431B1 (en) * | 2000-11-10 | 2003-02-25 | Helix Technology Inc. | Apparatus for automatically cleaning mask |
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|---|---|---|---|---|
| US5154797A (en) * | 1991-08-14 | 1992-10-13 | The United States Of America As Represented By The Secretary Of The Army | Silicon shadow mask |
| US5268068A (en) * | 1992-12-08 | 1993-12-07 | International Business Machines Corporation | High aspect ratio molybdenum composite mask method |
| US5744214A (en) * | 1997-01-30 | 1998-04-28 | International Business Machines Corporation | Corrosion resistant molybdenum mask |
| US6524431B1 (en) * | 2000-11-10 | 2003-02-25 | Helix Technology Inc. | Apparatus for automatically cleaning mask |
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